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DK473485A - Med overgangsmetalkompleks katalyserede reaktioner - Google Patents

Med overgangsmetalkompleks katalyserede reaktioner Download PDF

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Publication number
DK473485A
DK473485A DK473485A DK473485A DK473485A DK 473485 A DK473485 A DK 473485A DK 473485 A DK473485 A DK 473485A DK 473485 A DK473485 A DK 473485A DK 473485 A DK473485 A DK 473485A
Authority
DK
Denmark
Prior art keywords
transition metal
metal complex
catalyzed reactions
complex catalyzed
diorganophosphite
Prior art date
Application number
DK473485A
Other languages
English (en)
Other versions
DK473485D0 (da
Inventor
Ernest Billig
Anthony George Abatjoglou
David Robert Bryant
Rex Eugene Muray
John Michael Maher
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of DK473485D0 publication Critical patent/DK473485D0/da
Publication of DK473485A publication Critical patent/DK473485A/da

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C07F15/008—Rhodium compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65744—Esters of oxyacids of phosphorus condensed with carbocyclic or heterocyclic rings or ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6578—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and sulfur atoms with or without oxygen atoms, as ring hetero atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
    • B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Steroid Compounds (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Saccharide Compounds (AREA)
  • Materials For Medical Uses (AREA)
DK473485A 1984-02-17 1985-10-16 Med overgangsmetalkompleks katalyserede reaktioner DK473485A (da)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US58135284A 1984-02-17 1984-02-17
US06/685,025 US4599206A (en) 1984-02-17 1984-12-28 Transition metal complex catalyzed reactions
PCT/US1985/000231 WO1985003702A1 (en) 1984-02-17 1985-02-15 Transition metal complex catalyzed reactions

Publications (2)

Publication Number Publication Date
DK473485D0 DK473485D0 (da) 1985-10-16
DK473485A true DK473485A (da) 1985-12-11

Family

ID=27078299

Family Applications (1)

Application Number Title Priority Date Filing Date
DK473485A DK473485A (da) 1984-02-17 1985-10-16 Med overgangsmetalkompleks katalyserede reaktioner

Country Status (21)

Country Link
US (1) US4599206A (da)
EP (1) EP0155508B1 (da)
JP (1) JPH0645633B2 (da)
KR (1) KR920010519B1 (da)
AT (1) ATE83230T1 (da)
AU (2) AU579144B2 (da)
BR (1) BR8505278A (da)
CA (1) CA1262915A1 (da)
CS (1) CS271311B2 (da)
DE (1) DE3586878T2 (da)
DK (1) DK473485A (da)
ES (3) ES8609185A1 (da)
FI (1) FI88709C (da)
HU (1) HU202176B (da)
MX (1) MX164254B (da)
NO (1) NO165915C (da)
PL (2) PL251973A1 (da)
RO (1) RO92321B (da)
SG (1) SG32193G (da)
WO (1) WO1985003702A1 (da)
YU (1) YU44255B (da)

Families Citing this family (160)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2710040A (en) * 1953-10-29 1955-06-07 Joseph L Boyd Bending machine
US4737588A (en) * 1984-12-28 1988-04-12 Union Carbide Corporation Transition metal complex catalyzed reactions
US4668651A (en) * 1985-09-05 1987-05-26 Union Carbide Corporation Transition metal complex catalyzed processes
US4748261A (en) 1985-09-05 1988-05-31 Union Carbide Corporation Bis-phosphite compounds
US4885401A (en) * 1985-09-05 1989-12-05 Union Carbide Corporation Bis-phosphite compounds
US4774361A (en) * 1986-05-20 1988-09-27 Union Carbide Corporation Transition metal complex catalyzed reactions
US4835299A (en) * 1987-03-31 1989-05-30 Union Carbide Corporation Process for purifying tertiary organophosphites
US5059710A (en) * 1988-08-05 1991-10-22 Union Carbide Chemicals And Plastics Technology Corporation Ionic phosphites and their use in homogeneous transition metal catalyzed processes
US5113022A (en) * 1988-08-05 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Ionic phosphites used in homogeneous transition metal catalyzed processes
US5001274A (en) * 1989-06-23 1991-03-19 Union Carbide Chemicals And Plastics Company Inc. Hydroformylation process
US5210318A (en) * 1990-05-04 1993-05-11 Union Carbide Chemicals & Plastics Technology Corporation Catalysts and processes useful in producing 1,3-diols and/or 3-hydroxyldehydes
DE4026406A1 (de) * 1990-08-21 1992-02-27 Basf Ag Rhodiumhydroformylierungskatalysatoren mit bis-phosphit-liganden
JPH06503808A (ja) * 1990-08-31 1994-04-28 ザ　ガヴァナーズ　オヴ　ザ　ユニヴァーシティ　オヴ　アルバータ 新規の遷移金属触媒先駆物質を用いるメタノールのカルボニル化
US5087763A (en) * 1990-11-09 1992-02-11 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process
JP2946790B2 (ja) * 1991-03-14 1999-09-06 三菱化学株式会社 アルデヒド類の製造法
US5177019A (en) * 1991-05-20 1993-01-05 Eastman Kodak Company Method of quantitative analysis of organophosphorus compounds
TW213465B (da) * 1991-06-11 1993-09-21 Mitsubishi Chemicals Co Ltd
US5360938A (en) * 1991-08-21 1994-11-01 Union Carbide Chemicals & Plastics Technology Corporation Asymmetric syntheses
US5292785A (en) * 1992-05-05 1994-03-08 Ciba-Geigy Corporation Bis-phosphite stabilized compositions
US5312996A (en) * 1992-06-29 1994-05-17 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process for producing 1,6-hexanedials
US5310890A (en) * 1992-07-22 1994-05-10 Ciba-Geigy Corporation Carbohydrate substituted dibenzoi(d,g)(1,3,2)dioxaphosphocin stabilizers
US5310889A (en) * 1992-07-22 1994-05-10 Ciba-Geigy Corporation Carbohydrate substituted dibenzo(d,f)(1,3,2)dioxaphosphepin stabilizers
US5364950A (en) * 1992-09-29 1994-11-15 Union Carbide Chimicals & Plastics Technology Corporation Process for stabilizing phosphite ligands in hydroformylation reaction mixtures
DE4242723A1 (de) * 1992-12-17 1994-06-23 Hoechst Ag Verfahren zur Herstellung von Aldehyden
ES2130359T3 (es) * 1993-07-22 1999-07-01 Gen Electric Esteres neoalquil alquiliden-2,2'-bisfenil y bifenil fosfito.
JP3553952B2 (ja) * 1993-11-23 2004-08-11 イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー モノオレフィンのヒドロシアン化法およびそのための触媒組成物
DE69519020T2 (de) 1994-04-14 2001-05-17 E.I. Du Pont De Nemours And Co., Wilmington Nickel und phosphinebidentat enthaltende katalysatorzusammen- setzungen zur hydrocyanierung von monoolefinen
US5512695A (en) * 1994-04-14 1996-04-30 E. I. Du Pont De Nemours And Company Bidentate phosphite and nickel catalyst compositions for hydrocyanation of monoolefins
US5543536A (en) * 1994-04-26 1996-08-06 E. I. Du Pont De Nemours And Company Monodentate phosphite and nickel catalyst composition for monoolefin hydrocyanation
US5633418A (en) * 1994-07-18 1997-05-27 Mitsubishi Chemical Corporation Method for dimerizing an olefin
US5756855A (en) * 1994-08-19 1998-05-26 Union Carbide Chemicals & Plastics Technology Corporation Stabilization of phosphite ligands in hydroformylation process
US5512696A (en) * 1995-07-21 1996-04-30 E. I. Du Pont De Nemours And Company Hydrocyanation process and multidentate phosphite and nickel catalyst composition therefor
TW315370B (da) * 1994-10-07 1997-09-11 Du Pont
US5672766A (en) * 1994-12-12 1997-09-30 Mitsubishi Chemical Corporation Method for producing aldehydes
US5675041A (en) * 1995-01-18 1997-10-07 Exxon Research & Engineering Company Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide, hydrogen, ethylene, and acetylene
US5520722A (en) * 1995-01-18 1996-05-28 Exxon Research And Engineering Company Multiunsaturates removal process
US5516965A (en) * 1995-01-18 1996-05-14 Exxon Research And Engineering Company Unsaturates recovery and recycle process
US5821378A (en) * 1995-01-27 1998-10-13 E. I. Du Pont De Nemours And Company Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles
IN187044B (da) * 1995-01-27 2002-01-05 Du Pont
US5728893A (en) * 1995-12-06 1998-03-17 Union Carbide Chemicals & Plastics Technology Corporation Process using multistaged reactors
US5654455A (en) * 1995-12-21 1997-08-05 Ciba-Geigy Corporation Tris-phosphite ligands and their use in transitioin metal catalyzed processes
US5892119A (en) * 1996-11-26 1999-04-06 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
US5962744A (en) * 1998-03-27 1999-10-05 The Research Foundation Of State University Of New York Process for hydrocarbonylations in supercritical carbon dioxide
JP3847466B2 (ja) * 1998-09-01 2006-11-22 三菱化学株式会社 オレフィンのヒドロホルミル化反応方法
JP3921853B2 (ja) * 1998-12-10 2007-05-30 三菱化学株式会社 アルデヒド類及びアルコール類の製造方法
CN1163463C (zh) 1998-12-10 2004-08-25 三菱化学株式会社 醛的制备方法
JP3928315B2 (ja) * 1998-12-14 2007-06-13 三菱化学株式会社 アルデヒドの製造方法
US6610891B1 (en) 1999-12-03 2003-08-26 Mitsubishi Chemical Corporation Method of producing aldehydes
WO2001051441A1 (en) * 2000-01-12 2001-07-19 Eastman Chemical Company Hydroformylation method for making aldehydes from sterically hindered olefins
JP3864668B2 (ja) * 2000-05-01 2007-01-10 三菱化学株式会社 アルデヒド類の製造方法
DE10027505A1 (de) * 2000-06-06 2001-12-13 Studiengesellschaft Kohle Mbh Chirale Monophosphite als Liganden für die asymmetrische Übergangsmetall-katalysierte Hydrierung
GB0021715D0 (en) * 2000-09-05 2000-10-18 Ici Plc Recovery of metals
DE10058383A1 (de) 2000-11-24 2002-05-29 Oxeno Olefinchemie Gmbh Neue Phosphininverbindungen und deren Metallkomplexe
DE10140086A1 (de) 2001-08-16 2003-02-27 Oxeno Olefinchemie Gmbh Neue Phosphitverbindungen und neue Phosphitmetallkomplexe
DE10148551A1 (de) 2001-10-01 2003-04-10 Bayer Ag Chirale Monophosphorverbindungen
DE10149349A1 (de) * 2001-10-06 2003-04-17 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 6-Methylheptan-2-on und dessen Verwendung
US7196230B2 (en) * 2002-03-11 2007-03-27 Union Carbide Chemicals & Plastics Technology Corporation Phosoxophite ligands and use thereof in carbonylation processes
DE10220801A1 (de) 2002-05-10 2003-11-20 Oxeno Olefinchemie Gmbh Verfahren zur Rhodium-katalysierten Hydroformylierung von Olefinen unter Reduzierung der Rhodiumverluste
BR0313866A (pt) 2002-08-31 2005-07-05 Oxeno Olefinchemie Gmbh Processo para a hidroformilação de compostos olefinicamente insaturados, especialmente olefinas na presença de ésteres de ácido carbÈnico cìclicos
US7294729B2 (en) * 2002-10-15 2007-11-13 Union Carbide Chemicals & Plastics Technology Corporation Bis-chelating ligand and use thereof in carbonylation processes
JP2007509093A (ja) * 2003-10-21 2007-04-12 ビーエーエスエフ　アクチェンゲゼルシャフト アルデヒドの連続的な製造方法
DE10349343A1 (de) * 2003-10-23 2005-06-02 Basf Ag Stabilisierung von Hydroformylierungskatalysatoren auf Basis von Phosphoramiditliganden
DE102004013514A1 (de) * 2004-03-19 2005-10-06 Oxeno Olefinchemie Gmbh Verfahren zur Hydroformylierung von Olefinen in Anwesenheit von neuen phosphororganischen Verbindungen
US7291748B2 (en) 2005-07-28 2007-11-06 Basf Corporation C10/C7 ester mixtures based on 2-propylheptanol
DE102005042464A1 (de) 2005-09-07 2007-03-08 Oxeno Olefinchemie Gmbh Carbonylierungsverfahren unter Zusatz von sterisch gehinderten sekundären Aminen
DE102006034442A1 (de) * 2006-07-26 2008-01-31 Oxeno Olefinchemie Gmbh Katalysatorvorstufe für einen Rh-Komplexkatalysator
BRPI0719724A2 (pt) 2006-12-07 2014-02-18 Basf Se Composição, uso da composição, kit, uso de um kit, uso de composto, e, método para proteger uma planta contra fungos nocivos
DE102006058682A1 (de) 2006-12-13 2008-06-19 Evonik Oxeno Gmbh Bisphosphitliganden für die übergangsmetallkatalysierte Hydroformylierung
US7586010B2 (en) * 2006-12-21 2009-09-08 Eastman Chemical Company Phosphonite-containing catalysts for hydroformylation processes
BRPI0808297B1 (pt) * 2007-03-20 2017-02-07 Dow Technology Investments Llc processo de hidroformilação
WO2008123740A1 (en) * 2007-04-09 2008-10-16 Lg Chem, Ltd. Catalyst composition including phosphite ligands and hydroformylation method using the same
DE102007023514A1 (de) 2007-05-18 2008-11-20 Evonik Oxeno Gmbh Stabile Katalysatorvorstufe von Rh-Komplexkatalysatoren
EP2200957B2 (en) 2007-09-07 2016-09-14 Dow Global Technologies LLC Hydrogenation of alicyclic dialdehydes to alicyclic diols
US7872156B2 (en) * 2007-12-26 2011-01-18 Eastman Chemical Company Fluorophosphite containing catalysts for hydroformylation processes
US7872157B2 (en) * 2007-12-26 2011-01-18 Eastman Chemical Company Phosphonite containing catalysts for hydroformylation processes
US7708912B2 (en) * 2008-06-16 2010-05-04 Polytronics Technology Corporation Variable impedance composition
EP2257560B1 (en) * 2008-03-28 2013-07-17 Union Carbide Chemicals & Plastics Technology Llc (Formerly Union Carbide Chemicals & Plastics Technology Corporation) Slurry process for phosphoromonochloridite synthesis
EP2297077B1 (en) 2008-07-03 2014-06-04 Dow Technology Investments LLC Process of controlling heavies in a recycle catalyst stream
EP2328857B1 (en) * 2008-08-19 2016-03-23 Dow Technology Investments LLC Hydroformylation process using a symmetric bisphosphite ligand for improved control over product isomers
US8546600B2 (en) * 2008-10-08 2013-10-01 Dow Technology Investments Llc Slurry process for synthesis of bisphosphites and situ use thereof for producing bisphosphite
AU2009313838B2 (en) 2008-11-14 2015-02-05 University Of Kansas Polymer-supported transition metal catalyst complexes and methods of use
DE102009001225A1 (de) 2009-02-27 2010-09-02 Evonik Oxeno Gmbh Verfahren zur Anreicherung eines Homogenkatalysators aus einem Prozessstrom
US7928267B1 (en) 2009-06-22 2011-04-19 Eastman Chemical Company Phosphite containing catalysts for hydroformylation processes
DE102009029050A1 (de) 2009-08-31 2011-03-03 Evonik Oxeno Gmbh Organophosphorverbindungen basierend auf Tetraphenol(TP)-substituierten Strukturen
JP5823967B2 (ja) 2009-10-16 2015-11-25 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー 気相ヒドロホルミル化方法
EP2496654B1 (de) 2009-11-05 2014-04-02 Basf Se Kleb- und dichtstoffe enthaltend ester auf basis von 2-propylheptanol
EP2516372B2 (en) 2009-12-22 2019-08-21 Dow Technology Investments LLC Controlling the normal:iso aldehyde ratio in a mixed ligand hydroformylation process by controlling the syngas partial pressure
US8664451B2 (en) 2009-12-22 2014-03-04 Dow Technology Investments Llc Controlling the normal:ISO aldehyde ratio in a mixed ligand hydroformylation process by controlling the olefin partial pressure
JP2013515061A (ja) 2009-12-22 2013-05-02 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー 混合リガンドヒドロホルミル化プロセスにおけるノルマル：イソアルデヒド比の制御
JP5652052B2 (ja) * 2010-08-24 2015-01-14 三菱化学株式会社 アルデヒドの製造方法
JP2014502254A (ja) 2010-10-05 2014-01-30 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化の方法
SA112330271B1 (ar) * 2011-04-18 2015-02-09 داو تكنولوجى انفستمنتس ال ال سى تخفيف التلوث في عمليات هيدروفورملة عن طريق إضافة الماء
CN102826974B (zh) * 2011-06-17 2015-11-25 中国石油化工股份有限公司 一种丙烯氢甲酰化反应制备丁醛的方法
EP2751122B1 (en) 2011-09-30 2018-10-24 Dow Technology Investments LLC Purification process
DE102011085883A1 (de) 2011-11-08 2013-05-08 Evonik Oxeno Gmbh Neue Organophosphorverbindungen auf Basis von Anthracentriol
IN2014CN04467A (da) 2011-12-20 2015-09-04 Dow Technology Investments Llc
RU2634719C2 (ru) 2012-06-04 2017-11-03 Дау Текнолоджи Инвестментс Ллс Способ гидроформилирования
DE102012105878A1 (de) 2012-07-02 2014-01-02 Oxea Gmbh Verfahren zur Herstellung von Isopentanderivaten
KR102131204B1 (ko) 2012-08-29 2020-07-07 다우 테크놀로지 인베스트먼츠 엘엘씨. 촉매 제조 방법
CN104955568B (zh) 2012-09-25 2017-05-03 陶氏技术投资有限责任公司 用于稳定亚磷酸酯配体抵抗降解的方法
DE102013219508A1 (de) 2012-10-12 2014-04-17 Evonik Degussa Gmbh Gemische konstitutionsisomerer Bisphosphite
DE102013219512A1 (de) 2012-10-12 2014-04-17 Evonik Degussa Gmbh Gemisch aus verschiedenen unsymmetrischen Bisphosphiten und dessen Verwendung als Katalysatorgemisch in der Hydroformylierung
EP2906574B1 (de) 2012-10-12 2016-11-02 Evonik Degussa GmbH Gemisch aus verschiedenen unsymmetrischen bisphosphiten und dessen verwendung als katalysatorgemisch in der hydroformylierung
DE102013219506A1 (de) 2012-10-12 2014-04-17 Evonik Degussa Gmbh Unsymmetrisches Bisphosphit
DE102013219510A1 (de) 2012-10-12 2014-04-17 Evonik Degussa Gmbh Gemisch von Bisphosphiten und dessen Verwendung als Katalysatorgemisch in der Hydroformylierung
US9382180B2 (en) 2012-12-06 2016-07-05 Dow Technology Investments Llc Hydroformylation process
RU2527455C1 (ru) * 2013-03-28 2014-08-27 Открытое акционерное общество "Нефтяная компания "Роснефть" Способ получения альдегидов
RU2536048C2 (ru) * 2013-03-28 2014-12-20 Открытое акционерное общество "Нефтяная компания "Роснефть" Способ региоселективного получения н-пентаналя
CN104248860A (zh) 2013-06-27 2014-12-31 陶氏技术投资有限责任公司 热管理方法
DE102013020320B4 (de) 2013-12-05 2019-04-04 Oxea Gmbh Verfahren zur Herstellung von 2-Methylbuttersäure mit einem vermindertem Gehalt an 3-Methylbuttersäure aus den bei der Herstellung von Pentansäuren anfallenden Nebenströmen
DE102013020322B4 (de) 2013-12-05 2019-04-18 Oxea Gmbh Verfahren zur Gewinnung von 2-Methylbutanal aus den bei der Herstellung von Gemischen isomerer a,ß-ungesättigter Decenale anfallenden Nebenströmen
DE102013020323B3 (de) 2013-12-05 2015-01-08 Oxea Gmbh Verfahren zur Herstellung von isomeren Hexansäuren aus den bei der Herstellung von Pentanalen anfallenden Nebenströmen
CN106103399B (zh) 2013-12-19 2019-07-09 陶氏技术投资有限责任公司 氢甲酰化方法
CN104725170B (zh) 2013-12-19 2019-08-23 陶氏技术投资有限责任公司 加氢甲酰化方法
PL3126319T3 (pl) 2014-03-31 2020-01-31 Dow Technology Investments Llc Proces hydroformylowania
US10501486B2 (en) 2014-05-14 2019-12-10 Dow Technology Investments Llc Stabilized organophosphorous compounds
DE102014209534A1 (de) 2014-05-20 2015-11-26 Evonik Degussa Gmbh Neue Monophosphitliganden mit einer Carbonat-Gruppe
DE102014209532A1 (de) 2014-05-20 2015-11-26 Evonik Degussa Gmbh Neue Monophosphitliganden mit einer tert-Butyloxycarbonyl-Gruppe
DE202014007140U1 (de) 2014-09-08 2014-10-22 Basf Se Öl-basierte Bohrflüssigkeiten mit Copolymeren aus Styrol, (Meth)acrylaten von C10-Alkoholgemischen und (Meth)acrylsäure
DE202014007136U1 (de) 2014-09-08 2014-10-16 Basf Se Härtbare Zusammensetzung, hergestellt mit einem aus (Meth)acrylaten von C10-Alkoholgemischen aufgebauten Copolymer
ES2626367T3 (es) * 2014-12-04 2017-07-24 Evonik Degussa Gmbh Monofosfitos que presentan un componente biarilo asimétrico
EP3031817B1 (de) 2014-12-04 2019-05-01 Evonik Degussa GmbH Terphenyl-2-oxy-phosphite als liganden in hydroformylierungskatalysatoren
MY184826A (en) 2014-12-04 2021-04-24 Dow Technology Investments Llc Hydroformylation process
ES2670512T3 (es) * 2014-12-04 2018-05-30 Evonik Degussa Gmbh Ésteres monofosfitos de 9-antrol como ligandos para catalizadores de hidroformilación
DE102015207860A1 (de) 2015-04-29 2016-11-03 Evonik Degussa Gmbh Neue Monophosphitverbindungen mit einer Methylgruppe
DE102015207864A1 (de) 2015-04-29 2016-11-03 Evonik Degussa Gmbh Neue Monophosphitverbindungen mit einer Ethergruppe
DE102015207866A1 (de) 2015-04-29 2016-11-03 Evonik Degussa Gmbh Neue Monophosphitverbindungen mit einer Estergruppe
DE102015207870A1 (de) 2015-04-29 2016-11-03 Evonik Degussa Gmbh Neue Monophosphitverbindungen mit einer Sulfonatgruppe
EP3147290A1 (de) * 2015-09-22 2017-03-29 Evonik Degussa GmbH Monophosphite, die ein binol-derivat aufweisen
EP3147289B1 (de) 2015-09-22 2017-11-22 Evonik Degussa GmbH Monophosphite, die ein teilhydriertes binol-derivat aufweisen
EP3147288A1 (de) 2015-09-22 2017-03-29 Evonik Degussa GmbH Monophosphite, die ein cyclododecanol aufweisen
TWI709566B (zh) 2015-09-30 2020-11-11 美商陶氏科技投資公司 用於製造有機磷化合物的方法
TWI709568B (zh) 2015-09-30 2020-11-11 美商陶氏科技投資公司 用於製造有機磷化合物的方法
JP6908602B2 (ja) 2015-11-10 2021-07-28 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー アルデヒドの生成プロセス
EP3414220B1 (en) 2016-02-11 2021-10-13 Dow Technology Investments LLC Processes for converting olefins to alcohols, ethers, or combinations thereof
DE102016205883A1 (de) 2016-04-08 2017-10-12 Evonik Degussa Gmbh Pinakolester von Antracen-9-yloxy substituierten Dioxaphospholanen
EP3296303A1 (de) * 2016-09-16 2018-03-21 Evonik Degussa GmbH Monophosphite mit methylenverbrücktem diphenol und diphenylphenylrest
TWI788364B (zh) 2017-06-23 2023-01-01 美商陶氏科技投資有限公司 氫甲醯化反應製程
WO2019083700A1 (en) 2017-10-25 2019-05-02 Dow Technology Investments Llc PROCESS FOR REDUCING THE FORMATION OF HEAVY MINERALS IN A SOLUTION COMPRISING ALDEHYDE COMPOUNDS FORMED DURING A HYDROFORMYLATION PROCESS
JP7269238B2 (ja) 2017-11-13 2023-05-08 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセスからロジウムを回収するためのプロセス
TWI793216B (zh) 2017-12-07 2023-02-21 美商陶氏科技投資公司 氫甲醯化方法
KR20210098486A (ko) 2018-11-29 2021-08-10 다우 테크놀로지 인베스트먼츠 엘엘씨. 히드로포르밀화 공정
US10538472B1 (en) 2019-02-14 2020-01-21 Dairen Chemical Corporation Extraction process for high-boiling aldehyde product separation and catalyst recovery
JP7547397B2 (ja) 2019-06-27 2024-09-09 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー 貴金属回収のためのヒドロホルミル化プロセスから溶液を調製するプロセス
KR102686720B1 (ko) * 2019-07-04 2024-07-18 주식회사 엘지화학 하이드로포밀화 반응용 촉매 조성물 및 이를 이용한 알데히드의 제조방법
KR102768893B1 (ko) * 2019-09-27 2025-02-14 주식회사 엘지화학 인계 리간드를 포함하는 하이드로포밀화 반응용 촉매 조성물 및 이를 이용한 하이드로포밀화 방법
WO2021091687A1 (en) 2019-11-05 2021-05-14 Dow Technology Investments Llc Processes for recovery of rhodium from a hydroformylation process
CN114929660A (zh) 2019-12-19 2022-08-19 陶氏技术投资有限责任公司 用于制备异戊二烯和包含至少六个碳原子的单烯烃的方法
JP2023553108A (ja) 2020-12-14 2023-12-20 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセスにおける触媒金属の責務を改善するためのプロセス
US20230406802A1 (en) 2020-12-22 2023-12-21 Dow Technology Investments Llc Hydroformylation reaction processes
MX2024005136A (es) 2021-11-11 2024-05-16 Dow Technology Investments Llc Procesos para recuperar rodio a partir de procesos de hidroformilacion.
CN118317940A (zh) 2021-11-29 2024-07-09 三菱化学株式会社 醛的制造方法
JP7639833B2 (ja) 2021-12-14 2025-03-05 三菱ケミカル株式会社 アルデヒドの製造方法及びアルコールの製造方法、並びに触媒組成物
EP4448170A1 (en) 2021-12-16 2024-10-23 Dow Technology Investments LLC Compounds, transition metal complex hydroformylation catalyst precuror compositions comprising such compounds, and hydroformylation processes
WO2023114578A1 (en) 2021-12-16 2023-06-22 Dow Technology Investments Llc Transition metal complex hydroformylation catalyst precuror compositions comprising such compounds, and hydroformylation processes
WO2024228768A1 (en) 2023-05-04 2024-11-07 Dow Technology Investments Llc Hydroformylation process
GB202307175D0 (en) 2023-05-15 2023-06-28 Johnson Matthey Davy Technologies Ltd Process for hydrogenating a substrate
WO2025029349A1 (en) 2023-08-03 2025-02-06 Dow Technology Investments Llc Hydroformylation process
WO2025029369A1 (en) 2023-08-03 2025-02-06 Dow Technology Investments Llc Process for improving rhodium/phosphite- based homogenous hydroformylation catalyst activity
GB202404300D0 (en) 2024-03-26 2024-05-08 Johnson Matthey Davy Technologies Ltd Process for the production of 2-alkylalkanol

Family Cites Families (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3213155A (en) * 1961-05-19 1965-10-19 Exxon Research Engineering Co Monoolefin isomerization process
US3476699A (en) * 1961-12-18 1969-11-04 Argus Chem Polyvinyl chloride and olefin polymer compositions having improved resistance to deterioration comprising an organic phosphite ester having at least one aromatic polycarbocyclic group
NL297350A (da) * 1962-08-31
US3297631A (en) * 1965-10-24 1967-01-10 Exxon Research Engineering Co Novel phenolic phosphorus stabilizers for polyolefins
US3437720A (en) * 1966-08-03 1969-04-08 Weston Chemical Corp Carboxylated hydroxy phosphites
US3527809A (en) * 1967-08-03 1970-09-08 Union Carbide Corp Hydroformylation process
US3491024A (en) * 1967-09-15 1970-01-20 Hooker Chemical Corp 2,6-disubstituted primary aryl phosphites,their salts and phosphorodihalidites and processes for the manufacture thereof
US3655832A (en) * 1969-02-18 1972-04-11 Argus Chem Polycarbocyclic phenolic phosphites
JPS4510729Y1 (da) * 1969-06-02 1970-05-15
JPS4840326B1 (da) * 1970-12-15 1973-11-30
US4148830A (en) * 1975-03-07 1979-04-10 Union Carbide Corporation Hydroformylation of olefins
US4247486A (en) * 1977-03-11 1981-01-27 Union Carbide Corporation Cyclic hydroformylation process
US4094855A (en) * 1976-07-30 1978-06-13 Ciba-Geigy Corporation Hindered phenyl phosphites
US4148430A (en) 1977-05-25 1979-04-10 Innovative Business Forms, Inc. Business form
CA1104587A (en) * 1977-06-21 1981-07-07 Peter J. Davidson Catalytic hydroformylation of internal olefins
US4288391A (en) * 1978-01-03 1981-09-08 Ciba-Geigy Corporation Alkylated 2,2'-biphenylene phosphites
US4196117A (en) * 1978-01-03 1980-04-01 Ciba-Geigy Corporation Alkylated 1,1'-biphenyl-2,2'-diyl phosphites and stabilized compositions
US4351759A (en) * 1978-01-03 1982-09-28 Ciba-Geigy Corporation Alkylated 2,2'-biphenylene phosphites and stabilized compositions
DE2837027A1 (de) * 1978-08-24 1980-03-06 Bayer Ag Neue phosphorigsaeureester und ihre verwendung zur stabilisierung von polyamiden
US4298541A (en) * 1979-02-12 1981-11-03 Exxon Research & Engineering Co. Trihydrocarbyl silyl-substituted alkyl diaryl phosphine transition metal complexes and their use as homogeneous catalysts
DE2965158D1 (en) * 1979-03-21 1983-05-11 Davy Mckee London Hydroformylation process
DE2965157D1 (en) * 1979-03-21 1983-05-11 Davy Mckee London Process for the production of aldehydes by hydroformylation of alkenes
US4283562A (en) * 1979-10-26 1981-08-11 Union Carbide Corporation Hydroformylation process using stable rhodium catalyst
JPS5699246A (en) * 1980-01-10 1981-08-10 Adeka Argus Chem Co Ltd Stabilized synthetic resin composition
GB2068377B (en) * 1980-02-04 1983-09-28 Shell Int Research Process for the hydroformylation of olefins
US4330678A (en) * 1980-02-04 1982-05-18 Shell Oil Company Process for the hydroformylation of olefins
US4374219A (en) * 1980-11-24 1983-02-15 Ciba-Geigy Corporation Alkanolamine ester of 1,1-biphenyl-2,2-diyl-and alkylidene-1,1-biphenyl-2,2-diyl-cyclic phosphites
US4318845A (en) * 1980-11-24 1982-03-09 Ciba-Geigy Corporation Alkanolamine esters of 1,1'-biphenyl-2,2'-diyl-and alkylidene-1,1'-biphenyl-2,2'-diyl-cyclic phosphites
EP0054986A1 (en) * 1980-12-22 1982-06-30 Shell Internationale Researchmaatschappij B.V. A process for the hydroformylation of olefins
CA1186342A (en) * 1981-03-12 1985-04-30 Anthony G. Abatjoglou Process for removing hydroperoxides and aldehydes from allyl-alkyl ether
US4388476A (en) * 1981-05-01 1983-06-14 Eastman Kodak Company Hydroformylation process with rhodium catalyst and oxygen stabilization thereof
US4400548A (en) * 1981-08-17 1983-08-23 Union Carbide Corporation Hydroformylation process using bisphosphine monooxide ligands
ATE26696T1 (de) * 1982-06-11 1987-05-15 Davy Mckee London Hydroformylierungsverfahren.
ATE16475T1 (de) * 1982-06-11 1985-11-15 Davy Mckee London Hydroformylierungsverfahren.
ATE28183T1 (de) * 1982-06-11 1987-07-15 Davy Mckee London Hydroformylierungsverfahren.
DE3234701A1 (de) * 1982-09-18 1984-04-05 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur herstellung von aldehyden
DE3341035A1 (de) * 1983-11-12 1985-05-23 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur herstellung von aldehyden
GB8334359D0 (en) * 1983-12-23 1984-02-01 Davy Mckee Ltd Process
CA1259331A (en) * 1984-03-30 1989-09-12 Gregory J. Dembowski Process for recovery of phosphorus ligand from vaporized aldehyde
US5059710A (en) * 1988-08-05 1991-10-22 Union Carbide Chemicals And Plastics Technology Corporation Ionic phosphites and their use in homogeneous transition metal catalyzed processes

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