CN108988115B - A Novel Same Threshold Equivalent Dual Band Mid-Infrared Pulse Laser and Laser Output Method - Google Patents
A Novel Same Threshold Equivalent Dual Band Mid-Infrared Pulse Laser and Laser Output Method Download PDFInfo
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Abstract
本发明公开了一种新型同阈值等效双波段中红外脉冲激光器及激光输出方法,涉及中近红外激光技术领域,本发明包括沿水平方向顺次设置的1150nmLD泵浦源、第一二色镜、第二二色镜、第一聚焦透镜、双包层掺钬氟化物增益光纤、第一准直镜和镀金反射镜,还包括设置于第一二色镜上方的1950nmLD泵浦源,第一准直镜与镀金反射镜之间沿水平方向顺次设置有第二聚焦透镜、锑烯二维可饱和吸收材料和第二准直镜,本发明可实现同阈值的~3微米和~2.1微米双波带连续激光的输出,并且通过调整1150nmLD泵浦源和1950nmLD泵浦源的功率占比,能够实现~3微米和~2.1微米双波长脉冲激光的同步等效率输出,能够广泛应用于多材料加工、医疗手术等领域。
The invention discloses a novel dual-band mid-infrared pulse laser with the same threshold value and a laser output method, and relates to the technical field of mid-near-infrared lasers. The invention includes a 1150 nm LD pump source and a first dichroic mirror arranged in sequence along a horizontal direction. , a second dichroic mirror, a first focusing lens, a double-clad holmium-doped fluoride gain fiber, a first collimating mirror and a gold-coated mirror, and a 1950nm LD pump source disposed above the first dichroic mirror, the first A second focusing lens, an antimonene two-dimensional saturable absorbing material and a second collimating mirror are sequentially arranged between the collimating mirror and the gold-plated reflecting mirror along the horizontal direction. The output of dual-band CW laser, and by adjusting the power ratio of the 1150nm LD pump source and the 1950nm LD pump source, can achieve synchronous equal-efficiency output of ~3μm and ~2.1μm dual-wavelength pulsed lasers, which can be widely used in multi-materials Processing, medical surgery and other fields.
Description
技术领域technical field
本发明涉及中近红外激光技术领域,更具体的是涉及一种新型同阈值等效双波段中红外脉冲激光器及激光输出方法。The invention relates to the technical field of mid-near-infrared lasers, and more particularly to a novel mid-infrared pulsed laser with the same threshold and equivalent dual-band and a laser output method.
背景技术Background technique
随着光纤激光技术的不断发展,中红外脉冲光纤激光器逐渐引起了国内外众多学者的关注,其潜在的应用主要有军事防御、激光微创手术、中红外光谱学、长波中红外泵浦源等。由于目前高功率半导体激光器的商用产品不断成熟,二极管泵浦源掺铒和掺钬的氟化物光纤激光器是实现高能量高峰值功率的中红外激光脉冲的佼佼者。大体而言,有两种方式可用于实现这种脉冲激光链,分别是调Q和锁模方式,其中,锁模光纤激光器能够实现超短高峰值功率的激光脉冲输出,目前被动锁模光纤激光器在~3微米波段已实现产生飞秒量级的高峰值功率可达37kW的脉冲激光;然而调Q光纤激光器可有效地实现更高能量的脉冲激光输出,在过去的数十年里,大量的实验产生~3微米调Q光纤激光主要采用主动调Q方式(诸如:声光调Q、电光调Q及机械调Q)和被动调Q(诸如:半导体可饱和吸收镜、透射型金属掺杂晶体、石墨烯、拓扑绝缘体以及黑磷等新型二维材料),相比于固态的主动调Q光纤激光方式,被动调Q光纤激光器成本低,结构简单而且紧实,更重要的是无需额外加入附加的电驱动系统来实现调Q。With the continuous development of fiber laser technology, mid-infrared pulsed fiber laser has gradually attracted the attention of many scholars at home and abroad. Its potential applications mainly include military defense, laser minimally invasive surgery, mid-infrared spectroscopy, long-wave mid-infrared pump source, etc. . Due to the continuous maturity of commercial products of high-power semiconductor lasers, diode-pumped erbium- and holmium-doped fluoride fiber lasers are outstanding for achieving high-energy, high-peak-power mid-infrared laser pulses. Generally speaking, there are two ways to realize this pulsed laser chain, namely Q-switching and mode-locking. Among them, the mode-locked fiber laser can realize the laser pulse output of ultra-short and high peak power. At present, the passive mode-locked fiber laser A pulsed laser with femtosecond peak power up to 37kW has been achieved in the ~3 micron waveband; however, Q-switched fiber lasers can effectively achieve higher-energy pulsed laser output. In the past few decades, a large number of The experimentally produced ~3 micron Q-switched fiber laser mainly adopts active Q-switching methods (such as: acousto-optic Q-switching, electro-optical Q-switching and mechanical Q-switching) and passive Q-switching (such as: semiconductor saturable absorber mirrors, transmission type metal-doped crystals) , graphene, topological insulators and new two-dimensional materials such as black phosphorus), compared with solid-state active Q-switched fiber lasers, passive Q-switched fiber lasers have low cost, simple and compact structure, and more importantly, no additional additional The electric drive system to achieve Q-switching.
目前新型的二维材料的兴起主要集中在石墨烯、拓扑绝缘体以及透射型的金属双硫化物,由于它们具有优异的理化特性而有望成为一种新型的电光调制器件。2004年二维石墨烯材料首次被发现,且于2009年被用于实现~1.55微米波段的掺铒光纤脉冲激光;2013年,亚利桑那州大学韦晨等人首次实现基于石墨烯材料的~3微米掺铒氟化物调Q脉冲激光的输出,由于该种材料的可调制深度较低导致极低的吸收效率,从而不是非常适合用于产生短脉冲调Q激光。此后,拓扑绝缘体及透射型的金属双硫化物等材料被用于产生~3微米掺铒/钬氟化物光纤脉冲激光,尽管拓扑绝缘体可以在宽带范围内有较大的调制深度,但是它较复杂的制备过程难以在两个不同的元件上组合;此外,宽带透射型的金属双硫化物由于可以在其材料内部引入一些缺陷而使得能级适用于中红外波段,但其制造过程也相对复杂繁琐。At present, the rise of new two-dimensional materials mainly focuses on graphene, topological insulators and transmissive metal dichalcogenides, which are expected to become a new type of electro-optical modulation devices due to their excellent physical and chemical properties. In 2004, two-dimensional graphene materials were first discovered, and in 2009, they were used to realize erbium-doped fiber pulsed lasers in the ~1.55-micron waveband; in 2013, Wei Chen et al. The output of erbium-doped fluoride Q-switched pulsed lasers is not very suitable for short-pulse Q-switched lasers because of the extremely low absorption efficiency due to the low modulation depth of this material. Since then, topological insulators and transmissive metal dichalcogenides have been used to generate ~3 μm erbium/holmium fluoride fiber pulsed lasers. Although topological insulators can have a large modulation depth in the broadband range, it is more complex It is difficult to combine the two different components in the preparation process of the broadband transmission type; in addition, the broadband transmission type metal dichalcogenide can make the energy level suitable for the mid-infrared band due to the introduction of some defects inside its material, but its manufacturing process is also relatively complicated and cumbersome. .
近年来,黑磷因其具有独一无二的直接带隙层而备受关注,它由第五族元素组合而成且带隙可调范围在~0.3eV到~2eV,这使其非常适用于近红外乃至中红外光电开关上,但是在实验过程中,黑磷极易在周围环境下被氧化,致使其性能衰减且进一步增加与空气中存在的水和氧气进行热效应反应。相比前面的二维材料,锑烯作为一种新型的二维材料,具有优良的特性,诸如:较高的稳定性,较大的携带载流子能力,极好的热传导性,应变诱导带隙转化及宽带吸收等,正是由于该种材料具有宽带可饱和吸收特性,再加之~3微米波段脉冲能量能够在浅层软组织中被有效吸收,这非常适用于医疗无热损伤组织切除,同时~2.1微米脉冲激光在激光手术中能够很好的起到凝血作用;另外,在多材料加工中同阈值等效的~3微米脉冲和~2.1微米脉冲也起到非常重要的作用,因此,结合新型锑烯二维材料实现同阈值等效稳定的双波段(~3微米和~2.1微米)中红外脉冲激光输出是一种新的技术手段,该种双波段中红外脉冲激光器在许多实际应用中起到显著的作用。In recent years, black phosphorus has attracted much attention due to its unique direct bandgap layer, which is composed of group V elements and has a tunable bandgap in the range of ~0.3eV to ~2eV, which makes it very suitable for near-infrared Even on mid-infrared photoelectric switches, but during the experiment, black phosphorus is easily oxidized in the surrounding environment, causing its performance to deteriorate and further increase its thermal effect reaction with water and oxygen in the air. Compared with the previous two-dimensional materials, antimonene, as a new type of two-dimensional material, has excellent properties, such as: higher stability, greater carrier carrying capacity, excellent thermal conductivity, strain-induced band It is precisely because this material has broadband saturable absorption characteristics, and the pulse energy in the ~3 micron band can be effectively absorbed in the superficial soft tissue, which is very suitable for medical tissue resection without thermal damage. The ~2.1 micron pulsed laser can play a good role in coagulation in laser surgery; in addition, the ~3 micron pulse and ~2.1 micron pulse equivalent to the threshold value also play a very important role in multi-material processing. Therefore, combined with A new type of antimonene two-dimensional material to achieve equivalently stable dual-band (~3 μm and ~2.1 μm) mid-infrared pulsed laser output at the same threshold is a new technical means. This kind of dual-band mid-infrared pulsed laser has many practical applications. play a significant role.
如图3所示,为一种基于二维纳米材料石墨烯调Q的掺铒ZBLAN光纤激光器结构图,其采用被动调Q的方式实现~3微米波段激光脉冲的输出,其中,976nm泵浦激光二极管作为泵浦源,泵浦光通过准直透镜、二色镜及聚焦透镜耦合进掺铒ZBLAN增益光纤,再将石墨烯光纤镜与增益光纤尾部直接连接,最终~3微米调Q激光脉冲由靠近976nm泵浦激光二极管的二色镜导出,并对输出脉冲激光滤波后进行探测。石墨烯光纤镜是将石墨烯沉积在光纤镜上作为有效可饱和吸器件,以实现腔内激光脉冲的形成,滤波器用于滤除输出激光中的残余泵浦光,通过改变增益光纤的长度以及泵浦光源的功率来实现不同状态下的~3微米激光脉冲输出,但这种激光器存在以下缺点:As shown in Figure 3, it is a structural diagram of an erbium-doped ZBLAN fiber laser based on the Q-switching of two-dimensional nanomaterial graphene, which adopts passive Q-switching to realize the output of laser pulses in the ~3 micron waveband. Among them, the 976nm pump laser The diode is used as the pump source, the pump light is coupled into the erbium-doped ZBLAN gain fiber through the collimating lens, the dichroic mirror and the focusing lens, and then the graphene fiber mirror is directly connected to the tail of the gain fiber. The dichroic mirror near the 976nm pump laser diode is derived and the output pulsed laser is filtered for detection. Graphene fiber mirror is to deposit graphene on the fiber mirror as an effective saturable absorption device to realize the formation of intracavity laser pulses. The filter is used to filter out the residual pump light in the output laser. By changing the length of the gain fiber and the The power of the pump light source can be used to achieve ~3 micron laser pulse output in different states, but this laser has the following disadvantages:
1、由于该激光器是利用二维纳米材料石墨烯作为可饱和吸收体实现被动调Q脉冲输出,石墨烯材料的可调制深度较低,因此导致其对泵浦光的吸收效率较低,从而不能有效的产生稳定的短脉冲调Q激光;1. Since the laser uses two-dimensional nanomaterial graphene as a saturable absorber to achieve passive Q-switched pulse output, the modulation depth of graphene material is low, resulting in a low absorption efficiency of pump light, so it cannot be used. Effectively generate stable short pulse Q-switched laser;
2、将石墨烯沉积于光纤镜上,使得实验操作难度变大,同时直接将石墨烯光纤镜与增益光纤尾部相连接,将实验操作的精准度提高,不易于简单操作,且残余的泵浦光能量较集中的打在材料上,极易使材料损伤,大大降低~3微米激光转换效率;2. The graphene is deposited on the fiber mirror, which makes the experimental operation more difficult. At the same time, the graphene fiber mirror is directly connected to the tail of the gain fiber, which improves the accuracy of the experimental operation, which is not easy to operate, and the residual pumping When the light energy is concentrated on the material, it is very easy to damage the material and greatly reduce the laser conversion efficiency of ~3 microns;
3、该激光器只能实现~3微米单波长激光脉冲的产生,不可同时获取~2.1微米激光,适用性较窄。3. The laser can only generate ~3 micron single-wavelength laser pulses, and cannot acquire ~2.1 micron lasers at the same time, so the applicability is narrow.
如图4所示,为一种基于二维材料黑磷调Q的掺铒ZBLAN光纤脉冲激光器结构图,其采用976nm半导体激光器作为激光泵浦源泵浦掺铒ZBLAN增益光纤实现~3微米被动调Q脉冲激光输出,其中,泵浦激光二极管通过准直聚焦透镜F1后,经二色镜F2耦合进掺铒增益光纤中,增益光纤另一端光出射至两个全反镜M1、M2对光路进行调整,最终射入到涂覆有二维材料黑磷的金镜上,并实现脉冲激光的调制;涂覆有二维材料黑磷的金镜是通过液相剥离法制备出来的,其作为反射型可饱和吸收镜,掺铒增益光纤左端面及涂覆有二维材料黑磷的金镜作为激光器的谐振腔,靠近976nm泵浦源的二色镜用以导引~3微米激光输出,通过改变976nm泵浦源的功率大小获取输出脉冲不同状态波形及脉冲相应的功率等特性,但这种激光器存在以下缺点:As shown in Figure 4, it is a structural diagram of an erbium-doped ZBLAN fiber pulsed laser based on two-dimensional black phosphorus Q-switching. It uses a 976nm semiconductor laser as a laser pump source to pump an erbium-doped ZBLAN gain fiber to achieve ~3 micron passive modulation. Q pulsed laser output, in which the pump laser diode is coupled into the erbium-doped gain fiber through the dichroic mirror F2 after passing through the collimating focusing lens F1, and the light from the other end of the gain fiber exits to the two total reflection mirrors M1 and M2 for the optical path. adjusted, and finally injected into the gold mirror coated with two-dimensional material black phosphorus, and the modulation of the pulsed laser was realized; the gold mirror coated with two-dimensional material black phosphorus was prepared by the liquid phase exfoliation method, which acts as a reflection type saturable absorption mirror, the left end face of the erbium-doped gain fiber and the gold mirror coated with two-dimensional material black phosphorus are used as the resonator of the laser, and the dichroic mirror close to the 976nm pump source is used to guide the laser output of ~3 microns. Change the power of the 976nm pump source to obtain the waveform of the output pulse in different states and the corresponding power of the pulse, but this laser has the following shortcomings:
1、由于该激光器是基于二维材料黑磷作为可饱和吸收体实现被动调Q脉冲输出,黑磷由液相剥离法制备而沉积在金镜上,其表面裸露于空气当中极易与氧气发生氧化作用,致使其性能衰减,且更进一步增加与空气中存在的水和氧气进行热效应反应,因此导致其对系统的调制能力降低,使得吸收效率较低,从而不利于调Q脉冲的稳定形成;1. Since the laser is based on the two-dimensional material black phosphorus as a saturable absorber to achieve passive Q-switched pulse output, black phosphorus is prepared by liquid phase exfoliation and deposited on the gold mirror. Oxidation causes its performance to attenuate, and further increases the thermal effect reaction with water and oxygen in the air, thus reducing its modulation ability to the system and making the absorption efficiency low, which is not conducive to the stable formation of Q-switched pulses;
2、将二维材料黑磷沉积于金镜表面,易损坏金镜且不利于金镜的再次利用,且制备成本高,使得实验装备造价昂贵;2. The two-dimensional material black phosphorus is deposited on the surface of the gold mirror, which is easy to damage the gold mirror and is not conducive to the reuse of the gold mirror, and the preparation cost is high, making the experimental equipment expensive;
3、该激光器的激光出射波长单一,对于一些要求多波长激光输出的应用就不再适用,限制了激光器的应用潜力。3. The laser output wavelength of the laser is single, which is no longer applicable to some applications requiring multi-wavelength laser output, which limits the application potential of the laser.
由于目前大多数实验基于新型二维材料实现被动调Q脉冲中红外激光的波长主要在~3微米和~3.5微米,缺少~3微米和~2.1微米双波长连续激光的同步阈值输出,并且常用的二维材料主要有石墨烯、拓扑绝缘体以及黑磷等,但由于这些二维材料各自有不同的理化特性缺陷而不能实现长期稳定且宽带工作的调Q激光脉冲。Since most of the current experiments are based on new two-dimensional materials to achieve passive Q-switched pulsed mid-infrared lasers, the wavelengths are mainly ~3 microns and ~3.5 microns, lacking the synchronous threshold output of ~3 microns and ~2.1 microns dual-wavelength CW lasers, and the commonly used Two-dimensional materials mainly include graphene, topological insulators, and black phosphorus. However, due to the different physical and chemical properties of these two-dimensional materials, long-term stable and broadband operation of Q-switched laser pulses cannot be achieved.
发明内容SUMMARY OF THE INVENTION
本发明的目的在于:为了解决现有的基于新型二维材料实现被动调Q脉冲中红外激光的波长主要在~3微米和~3.5微米,缺少~3微米和~2.1微米双波长连续激光的同步阈值输出的问题,本发明提供一种新型同阈值等效双波段中红外脉冲激光器及激光输出方法。The purpose of the present invention is: in order to solve the problem that the wavelengths of the existing passive Q-switched pulse mid-infrared lasers based on new two-dimensional materials are mainly ~3 microns and ~3.5 microns, and lack of synchronization of ~3 microns and ~2.1 microns dual-wavelength continuous lasers To solve the problem of threshold output, the present invention provides a novel dual-band mid-infrared pulse laser with the same threshold equivalent and a laser output method.
本发明为了实现上述目的具体采用以下技术方案:The present invention specifically adopts the following technical solutions in order to achieve the above object:
新型同阈值等效双波段中红外脉冲激光器,包括沿水平方向顺次设置的1150nmLD泵浦源、第一二色镜、第二二色镜、第一聚焦透镜、双包层掺钬氟化物增益光纤、第一准直镜和镀金反射镜,其特征在于:还包括设置于第一二色镜上方的1950nmLD泵浦源,所述第一二色镜与第二二色镜均倾斜设置,A new type of equivalent dual-band mid-infrared pulsed laser with the same threshold value, including a 1150nm LD pump source, a first dichroic mirror, a second dichroic mirror, a first focusing lens, and a double-clad holmium-doped fluoride gain The optical fiber, the first collimating mirror and the gold-plated reflecting mirror are characterized in that: it further comprises a 1950 nm LD pump source arranged above the first dichroic mirror, and the first dichroic mirror and the second dichroic mirror are both arranged obliquely,
其中,所述1150nmLD泵浦源用于产生连续泵浦激光A;1950nmLD泵浦源用于产生连续泵浦激光B;第一二色镜对连续泵浦激光A高透,对连续泵浦激光B高反,用于对连续泵浦激光A与连续泵浦激光B进行合束;第二二色镜对连续泵浦激光A和连续泵浦激光B高透,对~3微米和~2.1微米激光高反,用于将产生的~3微米和~2.1微米激光引导输出;所述第一聚焦透镜用于将连续泵浦激光A和连续泵浦激光B聚焦到双包层掺钬氟化物增益光纤中,以及用于对产生的~3微米和~2.1微米激光进行准直;双包层掺钬氟化物增益光纤用于产生~3微米和~2.1微米激光;第一准直镜用于对~3微米和~2.1微米激光进行准直并入射到镀金反射镜上;镀金反射镜对~3微米和~2.1微米激光高反,用于提供整个激光腔的反馈;所述双包层掺钬氟化物增益光纤的左端面和镀金反射镜围成谐振腔。The 1150nm LD pump source is used to generate the CW pump laser A; the 1950nm LD pump source is used to generate the CW pump laser B; High reflectivity, used to combine continuous pump laser A and continuous pump laser B; the second dichroic mirror is highly transparent to continuous pump laser A and continuous pump laser B, and is suitable for ~3 micron and ~2.1 micron lasers High reflection, used to guide the generated ~3 micron and ~2.1 micron lasers to output; the first focusing lens is used to focus the continuous pump laser A and the continuous pump laser B to the double-clad holmium-doped fluoride gain fiber , and for collimating the resulting ~3 micron and ~2.1 micron lasers; double-clad holmium-doped fluoride gain fiber for ~3 micron and ~2.1 micron laser generation; first collimator for ~3 micron and ~2.1 micron lasers The 3-micron and ~2.1-micron lasers are collimated and incident on a gold-coated mirror; the gold-coated mirror is highly reflective to the ~3-micron and ~2.1-micron lasers to provide feedback throughout the laser cavity; the double-clad holmium-fluorine-doped The left end face of the compound gain fiber and the gold-coated mirror form a resonant cavity.
进一步的,所述第一准直镜与镀金反射镜之间沿水平方向顺次设置有第二聚焦透镜、锑烯二维可饱和吸收材料和第二准直镜,所述第二聚焦透镜用于对~3微米和~2.1微米激光进行聚焦,并激射到锑烯二维可饱和吸收材料上;锑烯二维可饱和吸收材料对~3微米和~2.1微米激光进行被动调Q;第二准直镜对~3微米和~2.1微米激光再次进行准直并入射到镀金反射镜上。Further, a second focusing lens, an antimonene two-dimensional saturable absorbing material and a second collimating mirror are arranged in sequence along the horizontal direction between the first collimating mirror and the gold-plated reflecting mirror. For focusing the ~3 micron and ~2.1 micron lasers, and lasing on the antimonene two-dimensional saturable absorber material; the antimonene two-dimensional saturable absorber material passively Q-switches the ~3 micron and ~2.1 micron lasers; the first The ~3 micron and ~2.1 micron lasers were again collimated by two collimating mirrors and incident on the gold-coated mirrors.
进一步的,所述锑烯二维可饱和吸收材料以液相剥离法制备得到,并且沉积于CaF2基低上。Further, the antimonene two-dimensional saturable absorbing material is prepared by a liquid phase exfoliation method, and is deposited on a CaF 2 -based substrate.
进一步的,所述双包层掺钬氟化物增益光纤的左端面与水平面夹角为0°角,右端面与水平面夹角为8°斜角,用于防止寄生激光振荡。Further, the angle between the left end face and the horizontal plane of the double-clad holmium fluoride gain fiber is 0°, and the angle between the right end face and the horizontal plane is an oblique angle of 8°, which is used to prevent parasitic laser oscillation.
进一步的,所述双包层掺钬氟化物增益光纤中的能级变化过程为:连续泵浦激光A将5I8/2能级上的部分基态粒子抽运到5I6/2能级上,实现基态吸收过程A5I8/2→5I6/2,为5I6/2能级累积基态粒子,实现5I6/2能级与5I7/2能级间的粒子数反转,使从5I6/2能级上的粒子跃迁到5I7/2能级产生~3微米激光;Further, the energy level change process in the double-clad holmium-doped fluoride gain fiber is: the continuous pumping laser A pumps part of the ground state particles on the 5 I 8/2 energy level to the 5 I 6/2 energy level. , realize the ground state absorption process A 5 I 8/2 → 5 I 6/2 , accumulate ground state particles for the 5 I 6/2 energy level, and realize the particles between the 5 I 6/2 energy level and the 5 I 7/2 energy level Number inversion, so that the particle transition from the 5 I 6/2 energy level to the 5 I 7/2 energy level produces a ~3 micron laser;
连续泵浦激光B将5I8/2能级上的部分基态粒子抽运到5I7/2能级上,实现基态吸收过程B5I8/2→5I7/2,为5I7/2能级累积基态粒子,实现5I7/2能级与5I8/2能级间的粒子数反转,使5I7/2能级上的粒子跃迁到5I8/2能级产生~2.1微米激光。The continuous pumping laser B pumps part of the ground state particles on the 5 I 8/2 energy level to the 5 I 7/2 energy level, and realizes the ground state absorption process B 5 I 8/2 → 5 I 7/2 , which is 5 I The 7/2 energy level accumulates ground-state particles, realizing the population inversion between the 5 I 7/2 energy level and the 5 I 8/2 energy level, so that the particles on the 5 I 7/2 energy level transition to 5 I 8/2 The energy level produces a ~2.1 micron laser.
新型同阈值等效双波段中红外脉冲激光器的激光输出方法,包括如下步骤:The laser output method of a new type of equivalent dual-band mid-infrared pulsed laser with the same threshold includes the following steps:
S1:开启1150nmLD泵浦源和1950nmLD泵浦源,1150nmLD泵浦源产生连续泵浦激光A,1950nmLD泵浦源产生连续泵浦激光B;S1: Turn on the 1150nm LD pump source and the 1950nm LD pump source, the 1150nm LD pump source generates continuous pump laser A, and the 1950nm LD pump source generates continuous pump laser B;
S2:连续泵浦激光A和连续泵浦激光B经第一二色镜合束后,通过第二二色镜及第一聚焦透镜耦合进双包层掺钬氟化物增益光纤,在双包层掺钬氟化物增益光纤中连续泵浦激光A使部分基态粒子从5I6/2能级辐射到5I7/2能级产生~3微米激光,连续泵浦激光B使部分基态粒子从5I7/2能级辐射到5I8/2能级产生~2.1微米激光;S2: After the continuous pump laser A and the continuous pump laser B are combined by the first dichroic mirror, they are coupled into the double-clad holmium fluoride gain fiber through the second dichroic mirror and the first focusing lens. The continuous pumping laser A in the holmium-doped fluoride gain fiber makes part of the ground state particles radiate from the 5 I 6/2 energy level to the 5 I 7/2 energy level to generate ~3 μm laser light, and the continuous pumping laser B makes part of the ground state particles radiate from the 5
S3:分别调节1150nmLD泵浦源和1950nmLD泵浦源的功率,实现同阈值~3微米和~2.1微米双波长连续激光的产生;S3: respectively adjust the power of the 1150nm LD pump source and the 1950nm LD pump source to achieve the generation of dual-wavelength CW lasers with the same threshold of ~3 microns and ~2.1 microns;
S4:产生的~3微米和~2.1微米双波长连续激光经第一准直镜准直后,射到镀金反射镜上,经镀金反射镜反射后由双包层掺钬氟化物增益光纤左端面输出,并通过第一聚焦透镜准直和第二二色镜反射引导输出。S4: The generated ~3 micron and ~2.1 micron dual-wavelength CW lasers are collimated by the first collimating mirror, and then irradiated on the gold-coated mirror. The output is collimated by a first focusing lens and reflected by a second dichroic mirror to guide the output.
进一步的,将第二聚焦透镜、锑烯二维可饱和吸收材料和第二准直镜置于第一准直镜与镀金反射镜之间,调整锑烯二维可饱和吸收材料于第二聚焦透镜的焦距处,分别调节1150nmLD泵浦源和1950nmLD泵浦源的功率,在S3产生同阈值~3微米和~2.1微米双波长连续激光时,形成弛豫振荡过程,然后S4产生的~3微米和~2.1微米双波长连续激光经第一准直镜准直后,通过第二聚焦透镜将~3微米和~2.1微米双波长连续激光聚焦射入锑烯二维可饱和吸收材料,通过锑烯二维可饱和吸收材料对~3微米和~2.1微米双波长连续激光进行调制,调制后再经第二准直镜射入镀金反射镜上,实现脉宽窄化的高峰值功率的~3微米和~2.1微米双波长脉冲激光的输出。Further, the second focusing lens, the antimonene two-dimensional saturable absorbing material and the second collimating mirror are placed between the first collimating mirror and the gold-coated mirror, and the antimonene two-dimensional saturable absorbing material is adjusted to focus on the second At the focal length of the lens, adjust the power of the 1150nm LD pump source and the 1950nm LD pump source respectively. When S3 generates dual-wavelength continuous lasers with the same threshold of ~3 microns and ~2.1 microns, a relaxation oscillation process is formed, and then the ~3 microns generated by S4 After being collimated by the first collimating lens, the two-wavelength continuous lasers of ~3 microns and ~2.1 microns are focused and injected into the antimonene two-dimensional saturable absorption material through the second focusing lens. The two-dimensional saturable absorbing material modulates the ~3 micron and ~2.1 micron dual-wavelength continuous lasers, and then modulates and then injects into the gold-coated mirror through the second collimating mirror to achieve a high peak power of ~3 microns with narrowed pulse width. and ~2.1 μm dual wavelength pulsed laser output.
进一步的,从第二二色镜后分别测量~3微米和~2.1微米脉冲激光的功率,并分别计算斜效率,调整1150nmLD泵浦源和1950nmLD泵浦源的功率占比,实现~3微米和~2.1微米双波长脉冲激光的同步等效率输出。Further, the powers of the pulsed lasers of ~3 microns and ~2.1 microns were measured from behind the second dichroic mirror, and the slope efficiencies were calculated respectively, and the power ratios of the 1150 nm LD pump source and the 1950 nm LD pump source were adjusted to achieve ~ 3 microns and Synchronous equal-efficiency output of ~2.1 micron dual-wavelength pulsed laser.
本发明的有益效果如下:The beneficial effects of the present invention are as follows:
1、本发明通过利用1150nm和1950nm波段的连续激光泵浦源对双包层掺钬氟化物增益光纤进行混合泵浦的方法,可实现同阈值的~3微米和~2.1微米双波带连续激光的输出,有效的规避了~3微米跃迁饱和现象导致的激光跃迁自终止现象,本发明的方法可实现~3微米激光高效输出,且可降低增益光纤在单波长输出时高产热的问题。1. The present invention can realize the dual-wavelength continuous laser of ~3 microns and ~2.1 microns with the same threshold value by using the continuous laser pump source in the 1150nm and 1950nm bands to perform hybrid pumping on the double-clad holmium-doped fluoride gain fiber. It can effectively avoid the laser transition self-termination phenomenon caused by the ~3 micron transition saturation phenomenon. The method of the present invention can achieve high efficiency ~3 micron laser output, and can reduce the problem of high heat generation when the gain fiber is output at a single wavelength.
2、本发明通过采用液相剥离法制备新型二维材料锑烯,并将其沉积于CaF2基底表面制成透射型可饱和吸收器件,制作成本低,且操作简单,大大降低了实验操作难度,同时简化了系统,且由于锑烯具有较高的稳定性,较大的携带载流子能力,极好的热传导性,应变诱导带隙转化及宽带吸收等独特优势,有利于产生同步~3微米和~2.1微米脉冲激光同时输出。2. The present invention prepares a new two-dimensional material antimonene by adopting a liquid phase exfoliation method, and deposits it on the surface of a CaF 2 substrate to make a transmission-type saturable absorption device. The fabrication cost is low, and the operation is simple, which greatly reduces the difficulty of experimental operation. , at the same time simplifying the system, and due to the unique advantages of antimonene, such as high stability, large carrier carrying capacity, excellent thermal conductivity, strain-induced bandgap conversion and broadband absorption, it is conducive to the generation of synchronization ~3 Micron and ~2.1 micron pulsed lasers were output simultaneously.
3、本发明通过调控1150nm和1950nm泵浦源的功率占比,易实现等效率的输出功率接近的~3微米和~2.1微米被动调Q脉冲激光输出,同时基于新型二维锑烯材料的稳定性,整个系统输出的脉冲激光可在长时间内稳定的工作,本发明的激光器在多材料加工、医疗手术等领域能够广泛应用。3. By adjusting the power ratio of the 1150nm and 1950nm pump sources, the present invention is easy to achieve the output power of ~3 microns and ~2.1 microns passively Q-switched pulsed laser output with the same efficiency, and is based on the stability of the new two-dimensional antimonene material. The pulsed laser output by the whole system can work stably for a long time, and the laser of the present invention can be widely used in the fields of multi-material processing, medical surgery and the like.
附图说明Description of drawings
图1是本发明的整体结构示意图。Figure 1 is a schematic diagram of the overall structure of the present invention.
图2是双包层掺钬氟化物增益光纤简化能级图。Figure 2 is a simplified energy level diagram of a double-clad holmium-doped fluoride gain fiber.
图3是一种基于二维纳米材料石墨烯调Q的掺铒ZBLAN光纤激光器结构图。Figure 3 is a structural diagram of an erbium-doped ZBLAN fiber laser based on two-dimensional nanomaterial graphene Q-switching.
图4是一种基于二维材料黑磷调Q的掺铒ZBLAN光纤脉冲激光器结构图。Figure 4 is a structural diagram of an erbium-doped ZBLAN fiber pulsed laser based on two-dimensional black phosphorus Q-switching.
附图标记:1、1150nmLD泵浦源;2、1950nmLD泵浦源;3、第一二色镜;4、第二二色镜;5、第一聚焦透镜;6、双包层掺钬氟化物增益光纤;7、第一准直镜;8、第二聚焦透镜;9、锑烯二维可饱和吸收材料;10、第二准直镜;11、镀金反射镜;12、5I8/2能级;13、5I7/2能级;14、5I6/2能级;15、基态吸收过程A;16、基态吸收过程B;17、~3微米激光;18、~2.1微米激光。Reference numerals: 1. 1150 nm LD pump source; 2, 1950 nm LD pump source; 3, first dichroic mirror; 4, second dichroic mirror; 5, first focusing lens; 6, double-clad holmium-doped fluoride Gain fiber; 7. First collimating mirror; 8. Second focusing lens; 9. Antimonene two-dimensional saturable absorbing material; 10. Second collimating mirror; 11. Gold-coated mirror; 12, 5 I 8/2 Energy level; 13, 5 I 7/2 energy level; 14, 5 I 6/2 energy level; 15, ground state absorption process A; 16, ground state absorption process B; 17, ~3 micron laser; 18, ~2.1 micron laser .
具体实施方式Detailed ways
为了本技术领域的人员更好的理解本发明,下面结合附图和以下实施例对本发明作进一步详细描述。For those skilled in the art to better understand the present invention, the present invention will be further described in detail below with reference to the accompanying drawings and the following embodiments.
实施例1Example 1
如图1所示,本实施例提供一种新型同阈值等效双波段中红外脉冲激光器,包括沿水平方向顺次设置的1150nmLD泵浦源1、第一二色镜3、第二二色镜4、第一聚焦透镜5、双包层掺钬氟化物增益光纤6、第一准直镜7和镀金反射镜8,还包括设置于第一二色镜3上方的1950nmLD泵浦源2,所述第一二色镜3与第二二色镜4均倾斜设置,具体倾斜角度根据实际情况而定,双包层掺钬氟化物增益光纤的左端面与水平面夹角为0°角,右端面与水平面夹角为8°斜角,As shown in FIG. 1 , this embodiment provides a novel dual-band mid-infrared pulsed laser with the same threshold value, which includes a 1150 nm LD pump source 1 , a first dichroic mirror 3 , and a second dichroic mirror arranged in sequence along the horizontal direction. 4. The first focusing
其中,所述1150nmLD泵浦源1用于产生连续泵浦激光A;1950nmLD泵浦源2用于产生连续泵浦激光B;第一二色镜3对连续泵浦激光A高透,对连续泵浦激光B高反,用于对连续泵浦激光A与连续泵浦激光B进行合束;第二二色镜4对连续泵浦激光A和连续泵浦激光B高透,对~3微米和~2.1微米激光高反,用于将产生的~3微米和~2.1微米激光引导输出;所述第一聚焦透镜5用于将连续泵浦激光A和连续泵浦激光B聚焦到双包层掺钬氟化物增益光纤6中,以及用于对产生的~3微米和~2.1微米激光进行准直;双包层掺钬氟化物增益光纤6用于产生~3微米和~2.1微米激光;第一准直镜7用于对~3微米和~2.1微米激光进行准直并入射到镀金反射镜11上;镀金反射镜11对~3微米和~2.1微米激光高反,用于提供激光腔的反馈;所述双包层掺钬氟化物增益光纤6的左端面和镀金反射镜围成谐振腔。Among them, the 1150nm LD pump source 1 is used to generate the continuous pump laser A; the 1950nm LD pump source 2 is used to generate the continuous pump laser B; the first dichromatic mirror 3 is highly transparent to the continuous pump laser A, and The pump laser B has high reflection and is used to combine the continuous pump laser A and the continuous pump laser B; the second dichroic mirror 4 is highly transparent to the continuous pump laser A and the continuous pump laser B, and is suitable for ~3 microns and The ~2.1 micron laser is highly reflective, used to guide the generated ~3 micron and ~2.1 micron lasers to output; the first focusing lens 5 is used to focus the continuous pump laser A and the continuous pump laser B to the double cladding doping Holmium fluoride gain fiber 6, and for collimating the generated ~3 micron and ~2.1 micron lasers; double-clad holmium fluoride gain fiber 6 for generating ~3 micron and ~2.1 micron lasers; first The collimating mirror 7 is used for collimating the ~3 micron and ~2.1 micron lasers and incident on the gold-coated mirror 11; the gold-coated mirror 11 is highly reflective to the ~3 micron and ~2.1 micron lasers and is used to provide feedback of the laser cavity ; The left end face of the double-clad holmium-doped fluoride gain fiber 6 and the gold-coated mirror surround a resonant cavity.
新型同阈值等效双波段中红外脉冲激光器的激光输出方法,包括如下步骤:The laser output method of a new type of equivalent dual-band mid-infrared pulsed laser with the same threshold includes the following steps:
S1:开启1150nmLD泵浦源1和1950nmLD泵浦源2,1150nmLD泵浦源1产生连续泵浦激光A,1950nmLD泵浦源2产生连续泵浦激光B;S1: Turn on 1150 nm LD pump source 1 and 1950 nm
S2:连续泵浦激光A和连续泵浦激光B经第一二色镜3合束后,通过第二二色镜4及第一聚焦透镜5耦合进双包层掺钬氟化物增益光纤6,在双包层掺钬氟化物增益光纤6中连续泵浦激光A使5I6/2能级14上的粒子辐射到5I7/2能级13产生~3微米激光17,连续泵浦激光B使5I7/2能级13上的粒子辐射到5I8/2能级12产生~2.1微米激光18;S2: After the continuous pump laser A and the continuous pump laser B are combined by the first dichroic mirror 3, they are coupled into the double-clad holmium-doped
所述双包层掺钬氟化物增益光纤6中的能级变化过程为:连续泵浦激光A将5I8/2能级12上的部分基态粒子抽运到5I6/2能级14上,实现基态吸收过程A155I8/2→5I6/2,为5I6/2能级14累积基态粒子,实现5I6/2能级14与5I7/2能级13间的粒子数反转,使从5I6/2能级14上的粒子跃迁到5I7/2能级13产生~3微米激光17;The energy level change process in the double-clad holmium
连续泵浦激光B将5I8/2能级12上的部分基态粒子抽运到5I7/2能级13上,实现基态吸收过程B165I8/2→5I7/2,为5I7/2能级13累积基态粒子,实现5I7/2能级13与5I8/2能级12间的粒子数反转,使5I7/2能级13上的粒子跃迁到5I8/2能级12产生~2.1微米激光18;The continuous pumping laser B pumps part of the ground state particles on the 5 I 8/2 energy level 12 to the 5 I 7/2 energy level 13, and realizes the ground state absorption process B16 5 I 8/2 → 5 I 7/2 , which is The 5 I 7/2 energy level 13 accumulates ground-state particles, and the population inversion between the 5 I 7/2 energy level 13 and the 5 I 8/2 energy level 12 is realized, and the particles on the 5 I 7/2 energy level 13 transition. To 5 I 8/2 energy level 12 to generate ~2.1
S3:分别调节1150nmLD泵浦源1和1950nmLD泵浦源2的功率,实现同阈值~3微米和~2.1微米双波长连续激光的产生,具体是:S3: Adjust the power of the 1150nm LD pump source 1 and the 1950nm
适当调节1150nmLD泵浦源1和1950nmLD泵浦源2的功率,使它们之间的功率占比分别满足:Properly adjust the power of 1150nmLD pump source 1 and
1150nmLD泵浦源1功率占比为:35%<P1150/(P1150+P1950)<50%;The power ratio of 1150nm LD pump source 1 is: 35%<P 1150 /(P 1150 +P 1950 )<50%;
1950nmLD泵浦源2功率占比为:50%<P1950/(P1150+P1950)<75%;The power ratio of 1950nm
S4:产生的~3微米和~2.1微米双波长连续激光经第一准直镜7准直后,射到镀金反射镜11上,经镀金反射镜11反射后由双包层掺钬氟化物增益光纤6左端面输出,并通过第一聚焦透镜5准直和第二二色镜4反射引导输出。S4: The generated dual-wavelength continuous lasers of ~3 microns and ~2.1 microns are collimated by the
实施例2Example 2
本实施例在实施例1的基础之上进一步优化,具体是:This embodiment is further optimized on the basis of Embodiment 1, specifically:
所述第一准直镜7与镀金反射镜11之间沿水平方向顺次设置有第二聚焦透镜8、锑烯二维可饱和吸收材料9和第二准直镜10,所述第二聚焦透镜8用于对~3微米和~2.1微米激光进行聚焦,并激射到锑烯二维可饱和吸收材料9上;锑烯二维可饱和吸收材料9对~3微米和~2.1微米激光进行被动调Q;第二准直镜10对~3微米和~2.1微米激光再次进行准直并入射到镀金反射镜11上,所述锑烯二维可饱和吸收材料以液相剥离法制备得到,并且沉积于CaF2基低上。A second focusing
将第二聚焦透镜8、锑烯二维可饱和吸收材料9和第二准直镜10置于第一准直镜7与镀金反射镜11之间,调整锑烯二维可饱和吸收材料9于第二聚焦透镜8的焦距处,分别调节1150nmLD泵浦源1和1950nmLD泵浦源2的功率,使它们的功率占比满足实施例中的条件,在S3产生同阈值~3微米和~2.1微米双波长连续激光时,形成弛豫振荡过程,然后S4产生的~3微米和~2.1微米双波长连续激光经第一准直镜7准直后,通过第二聚焦透镜8将~3微米和~2.1微米双波长连续激光聚焦射入锑烯二维可饱和吸收材料9,通过锑烯二维可饱和吸收材料9对~3微米和~2.1微米双波长连续激光进行调制,调制后再经第二准直镜10射入镀金反射镜11上,所述弛豫过程中由于信号强弱的差异会被锑烯二维可饱和吸收材料9进行调制,当激光功率较高时,该部分激光可有效透过锑烯二维可饱和吸收材料9,当激光功率较低时,该部分激光将会被锑烯二维可饱和吸收材料9所吸收,从而在激光振荡过程中不断循环上述过程,使脉冲激光光强强的地方不断变强,弱的地方不断被吸收,最终实现脉宽窄化的高峰值功率的~3微米和~2.1微米双波长脉冲激光的输出。The second focusing
实施例3Example 3
本实施例在实施例2的基础之上进一步优化,具体是:This embodiment is further optimized on the basis of
从第二二色镜4后分别测量~3微米和~2.1微米脉冲激光的功率,并分别计算斜效率,调整1150nmLD泵浦源和1950nmLD泵浦源的功率占比满足实施例1中的条件,并使计算得到的两斜效率之间的差值浮动低于2%,实现~3微米和~2.1微米双波长脉冲激光的同步等效率输出。From the second
以上所述,仅为本发明的较佳实施例,并不用以限制本发明,本发明的专利保护范围以权利要求书为准,凡是运用本发明的说明书及附图内容所作的等同结构变化,同理均应包含在本发明的保护范围内。The above descriptions are only preferred embodiments of the present invention and are not intended to limit the present invention. The scope of patent protection of the present invention is subject to the claims. Any equivalent structural changes made by using the contents of the description and drawings of the present invention, Similarly, all should be included in the protection scope of the present invention.
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