CN101544800A - Formula of environment-friendly edge sealing strip - Google Patents
Formula of environment-friendly edge sealing strip Download PDFInfo
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- CN101544800A CN101544800A CN200810028245A CN200810028245A CN101544800A CN 101544800 A CN101544800 A CN 101544800A CN 200810028245 A CN200810028245 A CN 200810028245A CN 200810028245 A CN200810028245 A CN 200810028245A CN 101544800 A CN101544800 A CN 101544800A
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- soap
- calcium zinc
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- 238000007789 sealing Methods 0.000 title claims 7
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 20
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 19
- 239000003381 stabilizer Substances 0.000 claims abstract description 15
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000463 material Substances 0.000 claims abstract description 13
- 239000004709 Chlorinated polyethylene Substances 0.000 claims abstract description 11
- 239000002131 composite material Substances 0.000 claims abstract description 6
- 239000000126 substance Substances 0.000 claims abstract description 5
- 239000000344 soap Substances 0.000 claims description 22
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 15
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 12
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 9
- 239000004593 Epoxy Substances 0.000 claims description 7
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 claims description 7
- 235000012424 soybean oil Nutrition 0.000 claims description 7
- 239000003549 soybean oil Substances 0.000 claims description 7
- 239000005639 Lauric acid Substances 0.000 claims description 5
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 5
- -1 oxyphenisatin ester Chemical class 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 239000004902 Softening Agent Substances 0.000 claims 6
- 238000005461 lubrication Methods 0.000 claims 4
- 150000002148 esters Chemical class 0.000 claims 2
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims 2
- 239000003921 oil Substances 0.000 claims 2
- 235000019198 oils Nutrition 0.000 claims 2
- 229940049964 oleate Drugs 0.000 claims 2
- 229960003241 oxyphenisatine Drugs 0.000 claims 2
- VACCAVUAMIDAGB-UHFFFAOYSA-N sulfamethizole Chemical compound S1C(C)=NN=C1NS(=O)(=O)C1=CC=C(N)C=C1 VACCAVUAMIDAGB-UHFFFAOYSA-N 0.000 claims 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract description 18
- 239000004014 plasticizer Substances 0.000 abstract description 10
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract description 9
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 5
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 125000005498 phthalate group Chemical class 0.000 abstract description 2
- 239000004605 External Lubricant Substances 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- 235000019589 hardness Nutrition 0.000 abstract 1
- 230000000704 physical effect Effects 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 14
- 239000000203 mixture Substances 0.000 description 12
- 239000012748 slip agent Substances 0.000 description 11
- 235000021355 Stearic acid Nutrition 0.000 description 8
- 238000001125 extrusion Methods 0.000 description 8
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 8
- 239000008117 stearic acid Substances 0.000 description 8
- 238000009472 formulation Methods 0.000 description 7
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- GJYCVCVHRSWLNY-UHFFFAOYSA-N 2-butylphenol Chemical compound CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 3
- 239000005642 Oleic acid Substances 0.000 description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 3
- 235000011037 adipic acid Nutrition 0.000 description 3
- 239000001361 adipic acid Substances 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000001514 detection method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 206010028980 Neoplasm Diseases 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000004958 brain cell Anatomy 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000002703 mutagenesis Methods 0.000 description 1
- 231100000350 mutagenesis Toxicity 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
Landscapes
- Lubricants (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
本发明涉及复合材料技术领域，特别涉及一种环保封边条的配方；该配方包含以下组成物质：聚氯乙烯、碳酸钙、氯化聚乙烯、外滑剂、钙锌稳定剂、增塑剂；本发明通过使用不同配比的增塑剂，可以制备出软硬度不同的封边条材料；本发明不但不影响PVC的力学性、阻燃性、高强度耐气候性等物理性能，而且聚氯乙烯用料少，成本低廉，产品中不含邻苯二甲酸盐和重金属，避免了这些物质对人体造成损害，从而实现环保要求。The invention relates to the technical field of composite materials, and in particular to a formula of an environmentally friendly edge banding strip; the formula comprises the following constituent substances: polyvinyl chloride, calcium carbonate, chlorinated polyethylene, an external lubricant, a calcium zinc stabilizer, and a plasticizer; the invention can prepare edge banding strip materials with different hardnesses by using plasticizers in different proportions; the invention not only does not affect the physical properties of PVC such as mechanical properties, flame retardancy, high-strength weather resistance, etc., but also uses less polyvinyl chloride and has low cost; the product does not contain phthalates and heavy metals, thereby avoiding the damage of these substances to the human body, thereby achieving environmental protection requirements.
Description
技术领域： Technical field:
本发明涉及复合材料技术领域，特别涉及一种环保封边条的配方。The invention relates to the technical field of composite materials, in particular to a formula for an environmentally friendly edge banding.
背景技术： Background technique:
家居装饰中常用的封边条一般分原木封边条和传统聚氯乙烯(PVC)封边条，原木封边条制作简单，但成本昂贵，其原料主要来源于树木的原木皮；近年来，各国为了保护森林资源，限制林木的砍伐，使得原木封边条的原料来源受限制；为此，人们想到用PVC代替原木皮作为制作封边条的主原料；目前，PVC的大都含有有毒物质邻苯二甲酸盐，且大都是使用重金属盐稳定剂，尤其是铅系稳定剂；但是铅等重金属伤害人的脑细胞，致癌致突变，对人的健康有着较为严重的损害。The edge bands commonly used in home decoration are generally divided into log edge bands and traditional polyvinyl chloride (PVC) edge bands. The log edge bands are simple to make, but the cost is expensive. In order to protect forest resources, countries limit the felling of trees, which limits the raw material source of log edge banding; for this reason, people think of using PVC instead of log bark as the main raw material for making edge banding; at present, most of PVC contains toxic substances Phthalates, and most of them use heavy metal salt stabilizers, especially lead-based stabilizers; but heavy metals such as lead can damage human brain cells, cause cancer and mutagenesis, and have serious damage to human health.
发明内容： Invention content:
本发明的目的在于克服现有技术的不足，而提供一种了对人体无损害的环保封边条的配方。The purpose of the present invention is to overcome the deficiencies of the prior art, and provide a formula of an environmentally friendly edge banding that does no damage to the human body.
为实现上述目的，本发明采用的技术方案是：In order to achieve the above object, the technical scheme adopted in the present invention is:
一种环保封边条的配方，按重量百分比计，该配方包含以下组份：A formulation of an environmentally friendly edge banding, which comprises the following components by weight percentage:
聚氯乙烯 40％～70％PVC 40%～70%
碳酸钙 20％～40％Calcium Carbonate 20%～40%
氯化聚乙烯 0.5％～1.5％Chlorinated polyethylene 0.5%～1.5%
外滑剂 0.3％～0.7％External slip agent 0.3%～0.7%
钙锌稳定剂 1％～5％Calcium zinc stabilizer 1%～5%
增塑剂 5％～30％Plasticizer 5%～30%
其中外滑剂为：硬酸酯、已二酸、季戊四酸的聚合物；钙锌稳定剂为固体复合钙锌稳定剂，可为硬脂酸皂、月桂酸皂或油酸皂，其中优选硬脂酸皂。Wherein the slip agent is: the polymer of stearate, adipic acid, pentaerythronic acid; the calcium zinc stabilizer is a solid composite calcium zinc stabilizer, which can be stearic acid soap, lauric acid soap or oleic acid soap, wherein Stearic acid soap is preferred.
其中，按重量百分比计，该配方包含以下组份：Wherein, by weight percentage, the formula comprises the following components:
聚氯乙烯 45％～60％PVC 45%～60%
碳酸钙 25％～35％Calcium Carbonate 25%～35%
氯化聚乙烯 0.8％～1.2％Chlorinated polyethylene 0.8%～1.2%
外滑剂 0.4％～0.6％External slip agent 0.4%～0.6%
钙锌稳定剂 2％～4％Calcium zinc stabilizer 2%～4%
增塑剂 5％～25％Plasticizer 5%～25%
其中外滑剂为：硬酸酯、已二酸、季戊四酸的聚合物；钙锌稳定剂为固体复合钙锌稳定剂，可为硬脂酸皂、月桂酸皂或油酸皂，其中优选硬脂酸皂。Wherein the slip agent is: the polymer of stearate, adipic acid, pentaerythronic acid; the calcium zinc stabilizer is a solid composite calcium zinc stabilizer, which can be stearic acid soap, lauric acid soap or oleic acid soap, wherein Stearic acid soap is preferred.
所述增塑剂由以下重量百分比的物质组成：Described plasticizer is made up of the material of following percentage by weight:
环氧大豆油 40％～60％Epoxidized soybean oil 40%～60%
苯乙烯 60％～40％。Styrene 60%~40%.
所述增塑剂由以下重量百分比的物质组成：Described plasticizer is made up of the material of following percentage by weight:
环氧大豆油 50％Epoxidized soybean oil 50%
苯乙烯 50％。Styrene 50%.
所述增塑剂由以下重量百分比的物质组成：Described plasticizer is made up of the material of following percentage by weight:
柠檬酸丁酯 40％～80％Butyl citrate 40%～80%
环氧脂肪酸油酚丁酯 20％～60％。Epoxy fatty acid butyl phenolate 20% to 60%.
所述增塑剂由以下重量百分比的物质组成：Described plasticizer is made up of the material of following percentage by weight:
柠檬酸丁酯 50％～70％Butyl citrate 50%～70%
环氧脂肪酸油酚丁酯 30％～50％。Epoxy fatty acid phenol butyl ester 30% to 50%.
本发明的制备方法为：将上述量的原料放进混料设备中搅拌，搅拌速度保持在740～1480转/分钟，搅拌时间控制在15～20分钟，温度保持在90～125℃；搅拌完成后，将上述混合物放入冷却设备中冷却，冷却过程要求有搅拌动作，搅拌速度保持在200～300转/分钟，搅拌时间控制在10～15分钟，温度保持在40～50℃；将上述冷却后的混合物放入挤出成型设备中，使挤出成型设备的料筒温度保持在145～175℃，挤出速度保持在1～1.5kg/min，混合物最后由挤出成型设备的成型模头挤出成型，至此，基材制作完成；在制作好的基材表面印刷图案层，最后在图案层表面印刷透明的保护膜。The preparation method of the present invention is as follows: put the above-mentioned amount of raw materials into the mixing equipment and stir, the stirring speed is kept at 740-1480 rpm, the stirring time is controlled at 15-20 minutes, and the temperature is kept at 90-125°C; the stirring is completed Finally, put the above mixture into the cooling equipment to cool, the cooling process requires a stirring action, the stirring speed is kept at 200-300 rpm, the stirring time is controlled at 10-15 minutes, and the temperature is kept at 40-50°C; the above cooling Put the final mixture into the extrusion molding equipment, keep the barrel temperature of the extrusion molding equipment at 145-175°C, and keep the extrusion speed at 1-1.5kg/min. Extrusion molding, at this point, the base material is completed; the pattern layer is printed on the surface of the prepared base material, and finally a transparent protective film is printed on the surface of the pattern layer.
本发明的有益效果为：本发明通过在聚氯乙烯中添加与之相匹配的增塑剂和外滑剂等物质，根据所添加增塑剂的不同，可以制备出软硬度不同的PVC材料；本发明不但不影响PVC的力学性、阻燃性、高强度耐气候性等物理性能，而且聚氯乙烯用料少，成本低廉；产品中不含邻苯二甲酸盐，与欧洲环保标准比较，本发明邻苯二甲酸盐的含量检测结果如下：The beneficial effects of the present invention are as follows: the present invention can prepare PVC materials with different softness and hardness according to the difference of the added plasticizers by adding matching plasticizers and sliding agents to the polyvinyl chloride. ; The present invention not only does not affect the physical performances such as the mechanical property of PVC, flame retardancy, high-strength weather resistance, and polyvinyl chloride is used less, and cost is low; Does not contain phthalate in the product, meets European environmental protection standard Compare, the content detection result of phthalate of the present invention is as follows:
经美国SGS公司按ASTM F963-07标准检测，不含重金属，避免了这些物质对人体造成损害，从而实现环保要求；重金属检测结果如下表显示：Tested by the American SGS company according to the ASTM F963-07 standard, it does not contain heavy metals, which avoids the damage of these substances to the human body, thereby achieving environmental protection requirements; the heavy metal test results are shown in the following table:
注释：1、毫克/千克＝ppm；2、N.D.＝未检出；3、MDL＝方法检测限。Notes: 1. mg/kg = ppm; 2. N.D. = not detected; 3. MDL = method detection limit.
具体实施方式： Detailed ways:
下面的实施例可以使本专业技术人员更全面的理解本发明，但不以任何方式限制本发明。The following examples can enable those skilled in the art to understand the present invention more comprehensively, but do not limit the present invention in any way.
实施例1Example 1
一种环保封边条的配方，按重量百分比计，该配方包含以下组份：A formulation of an environmentally friendly edge banding, which comprises the following components by weight percentage:
聚氯乙烯 47％PVC 47%
碳酸钙 40％Calcium Carbonate 40%
氯化聚乙烯 1.5％Chlorinated Polyethylene 1.5%
外滑剂 0.5％Slip agent 0.5%
硬脂酸皂 1％Stearic acid soap 1%
环氧大豆油 3％Epoxidized soybean oil 3%
苯乙烯 6％Styrene 6%
其中外滑剂为：硬酸酯、已二酸、季戊四酸的聚合物。Among them, the slip agent is a polymer of stearate, adipic acid, and pentaerythronic acid.
将上述量的原料放进混料设备中搅拌，搅拌速度保持在740～1480转/分钟，搅拌时间控制在15～20分钟，温度保持在90～125℃；搅拌完成后，将上述混合物放入冷却设备中冷却，冷却过程要求有搅拌动作，搅拌速度保持在200～300转/分钟，搅拌时间控制在10～15分钟，温度保持在40～50℃；将上述冷却后的混合物放入挤出成型设备中，使挤出成型设备的料筒温度保持在145～175℃，挤出速度保持在1～1.5kg/min，混合物最后由挤出成型设备的成型模头挤出成型，至此，基材制作完成；在制作好的基材表面印刷图案层，最后在图案层表面印刷透明的保护膜。Put the above amount of raw materials into the mixing equipment and stir, the stirring speed is kept at 740-1480 rpm, the stirring time is controlled at 15-20 minutes, and the temperature is kept at 90-125°C; after the stirring is completed, put the above mixture into Cooling in the cooling equipment, the cooling process requires stirring action, the stirring speed is kept at 200-300 rpm, the stirring time is controlled at 10-15 minutes, and the temperature is kept at 40-50°C; put the above-mentioned cooled mixture into the extrusion In the molding equipment, the barrel temperature of the extrusion molding equipment is kept at 145-175°C, the extrusion speed is kept at 1-1.5kg/min, and the mixture is finally extruded by the molding die of the extrusion molding equipment. So far, basically The material is finished; the pattern layer is printed on the surface of the prepared substrate, and finally a transparent protective film is printed on the surface of the pattern layer.
实施例2Example 2
一种环保封边条的配方，按重量百分比计，该配方包含以下组份：A formulation of an environmentally friendly edge banding, which comprises the following components by weight percentage:
聚氯乙烯 58％PVC 58%
碳酸钙 33％Calcium Carbonate 33%
氯化聚乙烯 1.5％Chlorinated Polyethylene 1.5%
外滑剂 0.5％Slip agent 0.5%
月桂酸皂 2％Lauric Acid Soap 2%
环氧大豆油 2.5％Epoxidized soybean oil 2.5%
苯乙烯 2.5％。Styrene 2.5%.
本实施例的具体制备方法同实施例1。The concrete preparation method of this embodiment is the same as embodiment 1.
实施例3Example 3
一种环保封边条的配方，按重量百分比计，该配方包含以下组份：A formulation of an environmentally friendly edge banding, which comprises the following components by weight percentage:
聚氯乙烯 60％PVC 60%
碳酸钙 25％Calcium Carbonate 25%
氯化聚乙烯 1％Chlorinated Polyethylene 1%
外滑剂 0.5％Slip agent 0.5%
油酸皂 5％Oleic acid soap 5%
环氧大豆油 3.5％Epoxidized soybean oil 3.5%
苯乙烯 5％。Styrene 5%.
本实施例的具体制备方法同实施例1。The concrete preparation method of this embodiment is the same as embodiment 1.
实施例4Example 4
一种环保封边条的配方，按重量百分比计，该配方包含以下组份：A formulation of an environmentally friendly edge banding, which comprises the following components by weight percentage:
聚氯乙烯 40％PVC 40%
碳酸钙 35％Calcium Carbonate 35%
氯化聚乙烯 0.5％Chlorinated Polyethylene 0.5%
外滑剂 0.5％Slip agent 0.5%
硬脂酸皂 1％Stearic acid soap 1%
柠檬酸丁酯 20％Butyl Citrate 20%
环氧脂肪酸油酚丁酯 3％。Epoxy fatty acid butyl phenolate 3%.
实施例5Example 5
一种环保封边条的配方，按重量百分比计，该配方包含以下组份：A formulation of an environmentally friendly edge banding, which comprises the following components by weight percentage:
聚氯乙烯 46％PVC 46%
碳酸钙 28％Calcium Carbonate 28%
氯化聚乙烯 1％Chlorinated Polyethylene 1%
外滑剂 0.5％Slip agent 0.5%
硬脂酸皂 3％Stearic acid soap 3%
柠檬酸丁酯 15％Butyl Citrate 15%
环氧脂肪酸油酚丁酯 7.5％。Epoxy fatty acid butyl phenol 7.5%.
实施例6Example 6
一种环保封边条的配方，按重量百分比计，该配方包含以下组份：A formulation of an environmentally friendly edge banding, which comprises the following components by weight percentage:
聚氯乙烯 46％PVC 46%
碳酸钙 25％Calcium Carbonate 25%
氯化聚乙烯 1％Chlorinated Polyethylene 1%
外滑剂 0.5％Slip agent 0.5%
硬脂酸皂 5％Stearic acid soap 5%
柠檬酸丁酯 12％Butyl Citrate 12%
环氧脂肪酸油酚丁酯 7.5％。Epoxy fatty acid butyl phenol 7.5%.
Claims (6)
Priority Applications (1)
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| CN200810028245A CN101544800A (en) | 2008-05-23 | 2008-05-23 | Formula of environment-friendly edge sealing strip |
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| CN200810028245A CN101544800A (en) | 2008-05-23 | 2008-05-23 | Formula of environment-friendly edge sealing strip |
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| CN101544800A true CN101544800A (en) | 2009-09-30 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102417675A (en) * | 2011-09-23 | 2012-04-18 | 安徽万朗磁塑集团有限公司 | Material formula and preparation method of novel environment-friendly and environment-friendly antibacterial door seal rubber sleeve |
| CN102985481A (en) * | 2010-05-10 | 2013-03-20 | 陶氏环球技术有限责任公司 | Flexible PVC compositions made with plasticizers derived from renewable sources |
| CN104312046A (en) * | 2014-10-30 | 2015-01-28 | 六安索伊电器制造有限公司 | Environment-friendly refrigerator door seal PVC granule and preparation method thereof |
| CN104312044A (en) * | 2014-10-30 | 2015-01-28 | 安徽电信器材贸易工业有限责任公司 | Oil-resistant polyvinyl chloride cable sheath material and preparation method thereof |
| CN107200952A (en) * | 2017-05-18 | 2017-09-26 | 东莞市兄奕塑胶制品有限公司 | A kind of tasteless environment-friendly type PVC edge band and preparation method thereof |
-
2008
- 2008-05-23 CN CN200810028245A patent/CN101544800A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102985481A (en) * | 2010-05-10 | 2013-03-20 | 陶氏环球技术有限责任公司 | Flexible PVC compositions made with plasticizers derived from renewable sources |
| CN102417675A (en) * | 2011-09-23 | 2012-04-18 | 安徽万朗磁塑集团有限公司 | Material formula and preparation method of novel environment-friendly and environment-friendly antibacterial door seal rubber sleeve |
| CN104312046A (en) * | 2014-10-30 | 2015-01-28 | 六安索伊电器制造有限公司 | Environment-friendly refrigerator door seal PVC granule and preparation method thereof |
| CN104312044A (en) * | 2014-10-30 | 2015-01-28 | 安徽电信器材贸易工业有限责任公司 | Oil-resistant polyvinyl chloride cable sheath material and preparation method thereof |
| CN107200952A (en) * | 2017-05-18 | 2017-09-26 | 东莞市兄奕塑胶制品有限公司 | A kind of tasteless environment-friendly type PVC edge band and preparation method thereof |
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