CN101475722B - Formula of environment-friendly edge sealing strip - Google Patents
Formula of environment-friendly edge sealing strip Download PDFInfo
- Publication number
- CN101475722B CN101475722B CN200810029626XA CN200810029626A CN101475722B CN 101475722 B CN101475722 B CN 101475722B CN 200810029626X A CN200810029626X A CN 200810029626XA CN 200810029626 A CN200810029626 A CN 200810029626A CN 101475722 B CN101475722 B CN 101475722B
- Authority
- CN
- China
- Prior art keywords
- parts
- environment
- edge banding
- stabilizer
- calcium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000007789 sealing Methods 0.000 title description 20
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000003381 stabilizer Substances 0.000 claims abstract description 16
- 239000006057 Non-nutritive feed additive Substances 0.000 claims abstract description 12
- 239000000314 lubricant Substances 0.000 claims abstract description 12
- 239000002131 composite material Substances 0.000 claims abstract description 11
- 239000012744 reinforcing agent Substances 0.000 claims abstract 4
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 23
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical group CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 23
- 235000021355 Stearic acid Nutrition 0.000 claims description 14
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical group CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 14
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 14
- 239000008117 stearic acid Substances 0.000 claims description 14
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical group [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 12
- 235000013539 calcium stearate Nutrition 0.000 claims description 12
- 239000004014 plasticizer Substances 0.000 claims description 10
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 238000005728 strengthening Methods 0.000 claims description 8
- 239000004709 Chlorinated polyethylene Substances 0.000 claims description 6
- 239000008116 calcium stearate Substances 0.000 claims description 5
- 230000007613 environmental effect Effects 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims 3
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims 3
- 229920000058 polyacrylate Polymers 0.000 claims 2
- 239000004800 polyvinyl chloride Substances 0.000 abstract description 21
- 229920000915 polyvinyl chloride Polymers 0.000 abstract description 20
- 239000000463 material Substances 0.000 abstract description 7
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 3
- 150000003839 salts Chemical class 0.000 abstract description 3
- 239000003607 modifier Substances 0.000 abstract 1
- 230000000704 physical effect Effects 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 11
- 150000002148 esters Chemical class 0.000 description 9
- 238000001125 extrusion Methods 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 7
- 239000000203 mixture Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000004567 concrete Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 3
- 238000003854 Surface Print Methods 0.000 description 2
- 238000009775 high-speed stirring Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000004958 brain cell Anatomy 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000002703 mutagenesis Methods 0.000 description 1
- 231100000350 mutagenesis Toxicity 0.000 description 1
Landscapes
- Sealing Material Composition (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
本发明涉及复合材料技术领域，特别涉及一种环保封边条的配方，通过在聚氯乙烯中添加稳定剂、补强剂、润滑剂、苯乙烯改性剂、加工助剂等物质，可以制备出软硬度不同的PVC材料，本发明不但不影响PVC的力学性、阻燃性、高强度耐气候性等物理性能，添加加工助剂，降低了加工温度，提高了产品的平整度，而且聚氯乙烯用料少，成本低廉，使得封边条产品性能优越；产品中不含重金属盐稳定剂，不会对人的健康有损害，是环境友好型产品。The invention relates to the technical field of composite materials, and in particular to a formula of an environmentally friendly edge banding strip. By adding stabilizers, reinforcing agents, lubricants, styrene modifiers, processing aids and other substances into polyvinyl chloride, PVC materials with different softness and hardness can be prepared. The invention not only does not affect the physical properties of PVC such as mechanical properties, flame retardancy, high-strength weather resistance, but also adds processing aids to reduce processing temperature and improve the flatness of products. In addition, less polyvinyl chloride materials are used and the cost is low, so that the edge banding strip product has excellent performance. The product does not contain heavy metal salt stabilizers and will not harm human health, and is an environmentally friendly product.
Description
Technical field:
The present invention relates to technical field of composite materials, particularly a kind of prescription of environment-friendly edge sealing tape.
Background technology:
Edge sealing bar commonly used in the home decoration generally divides log edge sealing bar and traditional polyvinyl chloride (PVC) edge sealing bar, and log edge sealing bar is made simple, but the cost costliness, its raw material is mainly derived from the log skin of trees; In recent years, various countries are in order to protect forest resources, and the felling of restriction forest makes that the raw material sources of log edge sealing bar are restricted; For this reason, adopt PVC to replace the log skin as the main raw material of making the edge sealing bar; At present, mostly be to use the heavy metallic salt stablizer, especially lead is stablizer; But the brain cell of heavy metal harm people such as lead, carcinogenic mutagenesis has comparatively severe impairment to people's health.
Summary of the invention:
The objective of the invention is at the deficiencies in the prior art, and a kind of prescription that does not contain the environment-friendly edge sealing tape of heavy metal stabilizer is provided.
For achieving the above object, the technical solution used in the present invention is:
A kind of prescription of environment-friendly edge sealing tape, by weight, this prescription comprises following component:
100～200 parts of polyvinyl chloride
1～100 part in lime carbonate
6～10 parts of stablizers
1～50 part of plasticizer
4～8 parts of strengthening agents
2～5 parts of lubricants
1～10 part of vinylbenzene
1～5 part of processing aid,
Wherein stablizer is a composite calcium zinc stabilizing agent; Plasticizer is a dioctyl phthalate (DOP); Strengthening agent is a chlorinatedpolyethylene; Lubricant is a stearic acid.
A kind of prescription of environment-friendly edge sealing tape, by weight, this prescription comprises following component:
100～150 parts of polyvinyl chloride
1～50 part in lime carbonate
8～10 parts of stablizers
1～20 part of plasticizer
4～6 parts of strengthening agents
2～4 parts of lubricants
1～8 part of vinylbenzene
1～4 part of processing aid
Wherein stablizer is a composite calcium zinc stabilizing agent; Plasticizer is a dioctyl phthalate (DOP); Strengthening agent is a chlorinatedpolyethylene; Lubricant is a stearic acid.
Described composite calcium zinc stabilizing agent is calcium stearate and Zinic stearas according to weight ratio 60～70%: 30～40% compound mixtures.
Described composite calcium zinc stabilizing agent is that calcium stearate and Zinic stearas are according to 70%: 30% compound mixture of weight ratio.
Described processing aid is a polyacrylic ester.
A kind of prescription of environment-friendly edge sealing tape, by weight, this prescription comprises following component:
100 parts of polyvinyl chloride
30 parts in lime carbonate
5.6 parts of calcium stearates
2.4 parts of Zinic stearass
12 parts of dioctyl phthalate (DOP)s
4 parts of chlorinatedpolyethylenees
2 parts of stearic acid
2 parts of vinylbenzene
2 parts of polyacrylic ester.
Preparation method of the present invention is: with polyvinyl chloride, lime carbonate, stablizer, strengthening agent, stearic acid lubricant, phenylethene modified dose, the processing aid of above-mentioned amount, put in the mixing equipment and stir, stirring velocity remains on 150～800 rev/mins, churning time was controlled at 15～20 minutes, and temperature remains on 50～70 ℃; The plasticizer that adds above-mentioned amount carries out rotating speed and is 1200～1500 rev/mins high-speed stirring, and churning time was controlled at 20～25 minutes, and temperature remains on 110～145 ℃; After stirring is finished, above-mentioned mixture is put into extrusion equipment, make the barrel temperature of extrusion equipment remain on 120～195 ℃, extruded velocity remains on 0.2～3km/h, by the molding die extrusion moulding of extrusion equipment, so far, base material completes mixture at last; At the substrate surface printing pattern layer of making, and at the two-layer environmental protection UV of patterned layer surface coverage surface-treated layer, to guarantee the printing pattern layer nondiscoloration.Wear-resisting, resistance to oxidation.
Beneficial effect of the present invention is: the present invention is by adding materials such as stablizer, strengthening agent, lubricant, phenylethene modified dose, processing aid in polyvinyl chloride, can prepare the different PVC material of soft durometer, the present invention does not only influence physicalies such as the mechanical property, flame retardant resistance, high strength weathering resistance of PVC, add processing aid, reduced processing temperature, improved the planeness of product, and the polyvinyl chloride materials are few, with low cost, edge sealing bar product performance are superior; Not containing the heavy metallic salt stablizer in the product, can infringement not arranged to people's health, is environmentally friendly product.
Embodiment:
The following examples can make those skilled in the art more fully understand the present invention, but do not limit the present invention in any way.
Embodiment 1
A kind of prescription of environment-friendly edge sealing tape, by weight, this prescription comprises following component:
100 parts of polyvinyl chloride
30 parts in lime carbonate
5.6 parts of calcium stearates
2.4 parts of Zinic stearass
12 parts of dioctyl phthalate (DOP)s
4 parts of chlorinatedpolyethylenees
2 parts of stearic acid
2 parts of vinylbenzene
2 parts of polyacrylic ester
The preparation method of present embodiment is: with polyvinyl chloride, lime carbonate, composite calcium zinc stabilizing agent, chlorinatedpolyethylene strengthening agent, stearic acid lubricant, phenylethene modified dose, the polyacrylic ester processing aid of above-mentioned amount, put in the mixing equipment and stir, stirring velocity remains on 150 rev/mins, churning time was controlled at 15 minutes, and temperature remains on 50 ℃; The dioctyl phthalate (DOP) plasticizer that adds above-mentioned amount carries out rotating speed and is 1200 rev/mins high-speed stirring, and churning time was controlled at 20 minutes, and temperature remains on 110 ℃; After stirring is finished, said mixture is put into extrusion equipment, make the barrel temperature of extrusion equipment remain on 120 ℃, extruded velocity remains on 1km/h, by the molding die extrusion moulding of extrusion equipment, so far, base material completes mixture at last; At the substrate surface printing pattern layer of making, and at the two-layer environmental protection UV of patterned layer surface coverage surface-treated layer, to guarantee the printing pattern layer nondiscoloration.Wear-resisting, resistance to oxidation.
Embodiment 2
A kind of prescription of environment-friendly edge sealing tape, by weight, this prescription comprises following component:
200 parts of polyvinyl chloride
100 parts in lime carbonate
7 parts of calcium stearates
3 parts of Zinic stearass
50 parts of dioctyl phthalate (DOP)s
8 parts of chlorinatedpolyethylenees
5 parts of stearic acid
10 parts of vinylbenzene
5 parts of polyacrylic ester
The concrete preparation method of present embodiment is with embodiment 1.
Embodiment 3
A kind of prescription of environment-friendly edge sealing tape, by weight, this prescription comprises following component:
100 parts of polyvinyl chloride
1 part in lime carbonate
4.2 parts of calcium stearates
2.4 parts of Zinic stearass
5 parts of dioctyl phthalate (DOP)s
4 parts of chlorinatedpolyethylenees
2 parts of stearic acid
1 part of vinylbenzene
1 part of polyacrylic ester
The concrete preparation method of present embodiment is with embodiment 1.
Embodiment 4
A kind of prescription of environment-friendly edge sealing tape, by weight, this prescription comprises following component:
100 parts of polyvinyl chloride
30 parts in lime carbonate
6.4 parts of calcium stearates
3.2 parts of Zinic stearass
5 parts of dioctyl phthalate (DOP)s
4 parts of chlorinatedpolyethylenees
2 parts of stearic acid
1 part of vinylbenzene
1 part of polyacrylic ester
The concrete preparation method of present embodiment is with embodiment 1.
Embodiment 5
A kind of prescription of environment-friendly edge sealing tape, by weight, this prescription comprises following component:
150 parts of polyvinyl chloride
50 parts in lime carbonate
6 parts of calcium stearates
4 parts of Zinic stearass
20 parts of dioctyl phthalate (DOP)s
6 parts of chlorinatedpolyethylenees
4 parts of stearic acid
8 parts of vinylbenzene
4 parts of polyacrylic ester
The concrete preparation method of present embodiment is with embodiment 1.
Embodiment 6
A kind of prescription of environment-friendly edge sealing tape, by weight, this prescription comprises following component:
120 parts of polyvinyl chloride
30 parts in lime carbonate
5.4 parts of calcium stearates
3.6 parts of Zinic stearass
8 parts of dioctyl phthalate (DOP)s
5 parts of chlorinatedpolyethylenees
3 parts of stearic acid
7 parts of vinylbenzene
3 parts of polyacrylic ester
The concrete preparation method of present embodiment is with embodiment 1.
Claims (6)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810029626XA CN101475722B (en) | 2008-07-22 | 2008-07-22 | Formula of environment-friendly edge sealing strip |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810029626XA CN101475722B (en) | 2008-07-22 | 2008-07-22 | Formula of environment-friendly edge sealing strip |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101475722A CN101475722A (en) | 2009-07-08 |
| CN101475722B true CN101475722B (en) | 2011-05-04 |
Family
ID=40836503
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200810029626XA Expired - Fee Related CN101475722B (en) | 2008-07-22 | 2008-07-22 | Formula of environment-friendly edge sealing strip |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101475722B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102757605A (en) * | 2012-08-10 | 2012-10-31 | 浙江金立达塑材有限公司 | Environment-friendly polyvinyl chloride (PVC) granule for automobile interior decorations |
| CN108976797B (en) * | 2018-06-26 | 2020-12-11 | 浙江威思康塑胶有限公司 | Edge banding made of bisphenol A polysulfone and production method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1597762A (en) * | 2004-08-04 | 2005-03-23 | 芜湖海螺型材科技股份有限公司 | Leadless special-shaped section bar for door and window |
| CN101042016A (en) * | 2007-04-29 | 2007-09-26 | 东莞市华立实业有限公司 | Method for making novel PVC edge banding strip |
| CN101121802A (en) * | 2006-08-10 | 2008-02-13 | 广东科龙电器股份有限公司 | Environmental protection type HPVC door frame |
-
2008
- 2008-07-22 CN CN200810029626XA patent/CN101475722B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1597762A (en) * | 2004-08-04 | 2005-03-23 | 芜湖海螺型材科技股份有限公司 | Leadless special-shaped section bar for door and window |
| CN101121802A (en) * | 2006-08-10 | 2008-02-13 | 广东科龙电器股份有限公司 | Environmental protection type HPVC door frame |
| CN101042016A (en) * | 2007-04-29 | 2007-09-26 | 东莞市华立实业有限公司 | Method for making novel PVC edge banding strip |
Non-Patent Citations (2)
| Title |
|---|
| 《聚氯乙烯加工手册》编写组.聚氯乙烯加工手册.聚氯乙烯加工手册.中国轻工业出版社,1992,(1), * |
| 阎波等.硬相粒子(PS)与弹性体(CPE)增韧聚氯乙烯的研究.中国塑料.1994,8(4),第27-33页. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101475722A (en) | 2009-07-08 |
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Granted publication date: 20110504 Termination date: 20170722 |
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