CN107200952A - A kind of tasteless environment-friendly type PVC edge band and preparation method thereof - Google Patents
A kind of tasteless environment-friendly type PVC edge band and preparation method thereof Download PDFInfo
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- CN107200952A CN107200952A CN201710353385.3A CN201710353385A CN107200952A CN 107200952 A CN107200952 A CN 107200952A CN 201710353385 A CN201710353385 A CN 201710353385A CN 107200952 A CN107200952 A CN 107200952A
- Authority
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- China
- Prior art keywords
- parts
- edge band
- antioxidant
- friendly type
- type pvc
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- Pending
Links
- 230000009967 tasteless effect Effects 0.000 title claims abstract description 55
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 97
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 96
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 60
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims abstract description 47
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 37
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 36
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 31
- 239000011347 resin Substances 0.000 claims abstract description 26
- 229920005989 resin Polymers 0.000 claims abstract description 26
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- 239000000314 lubricant Substances 0.000 claims abstract description 23
- 239000002994 raw material Substances 0.000 claims abstract description 23
- 239000004605 External Lubricant Substances 0.000 claims abstract description 22
- 239000004014 plasticizer Substances 0.000 claims abstract description 17
- 239000002131 composite material Substances 0.000 claims abstract description 16
- 239000000654 additive Substances 0.000 claims abstract description 15
- 230000000996 additive effect Effects 0.000 claims abstract description 15
- 239000003381 stabilizer Substances 0.000 claims abstract description 15
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 claims abstract description 14
- 230000004224 protection Effects 0.000 claims abstract description 13
- 230000007613 environmental effect Effects 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 62
- 235000006708 antioxidants Nutrition 0.000 claims description 35
- 239000000463 material Substances 0.000 claims description 25
- 238000002156 mixing Methods 0.000 claims description 20
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 16
- 239000012188 paraffin wax Substances 0.000 claims description 15
- 239000004611 light stabiliser Substances 0.000 claims description 14
- 238000001125 extrusion Methods 0.000 claims description 13
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 9
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 9
- TXQVDVNAKHFQPP-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CO)(CO)CO TXQVDVNAKHFQPP-UHFFFAOYSA-N 0.000 claims description 9
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 9
- 239000008116 calcium stearate Substances 0.000 claims description 9
- 235000013539 calcium stearate Nutrition 0.000 claims description 9
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 9
- 239000004200 microcrystalline wax Substances 0.000 claims description 9
- 235000019808 microcrystalline wax Nutrition 0.000 claims description 9
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 claims description 9
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 9
- 238000006116 polymerization reaction Methods 0.000 claims description 9
- 229910000077 silane Inorganic materials 0.000 claims description 9
- 235000012424 soybean oil Nutrition 0.000 claims description 9
- 239000003549 soybean oil Substances 0.000 claims description 9
- -1 Stearyl Amines Chemical class 0.000 claims description 8
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 claims description 8
- 239000011248 coating agent Substances 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 8
- 150000002148 esters Chemical class 0.000 claims description 8
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 8
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 239000000758 substrate Substances 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- ZQBAKBUEJOMQEX-UHFFFAOYSA-N phenyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 4
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical group [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 claims description 4
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 claims description 3
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 claims description 3
- VETPHHXZEJAYOB-UHFFFAOYSA-N 1-n,4-n-dinaphthalen-2-ylbenzene-1,4-diamine Chemical compound C1=CC=CC2=CC(NC=3C=CC(NC=4C=C5C=CC=CC5=CC=4)=CC=3)=CC=C21 VETPHHXZEJAYOB-UHFFFAOYSA-N 0.000 claims description 3
- NDRPHZPVTSFYLH-UHFFFAOYSA-N 2,4,6-tris(2-butoxyphenyl)-1,3,5-triazine Chemical class C(CCC)OC1=C(C=CC=C1)C1=NC(=NC(=N1)C1=C(C=CC=C1)OCCCC)C1=C(C=CC=C1)OCCCC NDRPHZPVTSFYLH-UHFFFAOYSA-N 0.000 claims description 3
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 3
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 claims description 3
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 claims description 3
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 claims description 3
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 claims description 3
- 229960000969 phenyl salicylate Drugs 0.000 claims description 3
- 229960003656 ricinoleic acid Drugs 0.000 claims description 3
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical compound CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- PRWJPWSKLXYEPD-UHFFFAOYSA-N 4-[4,4-bis(5-tert-butyl-4-hydroxy-2-methylphenyl)butan-2-yl]-2-tert-butyl-5-methylphenol Chemical compound C=1C(C(C)(C)C)=C(O)C=C(C)C=1C(C)CC(C=1C(=CC(O)=C(C=1)C(C)(C)C)C)C1=CC(C(C)(C)C)=C(O)C=C1C PRWJPWSKLXYEPD-UHFFFAOYSA-N 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 244000025254 Cannabis sativa Species 0.000 claims 1
- 239000003610 charcoal Substances 0.000 claims 1
- 239000006084 composite stabilizer Substances 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 6
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 abstract description 5
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 4
- 230000000694 effects Effects 0.000 description 14
- 238000012545 processing Methods 0.000 description 14
- 239000002250 absorbent Substances 0.000 description 8
- 230000002745 absorbent Effects 0.000 description 8
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical group CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 238000013329 compounding Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 239000011592 zinc chloride Substances 0.000 description 3
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 235000019256 formaldehyde Nutrition 0.000 description 2
- 238000009776 industrial production Methods 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000000191 radiation effect Effects 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical group CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 230000002079 cooperative effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000002500 effect on skin Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000007348 radical reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 230000005476 size effect Effects 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F292/00—Macromolecular compounds obtained by polymerising monomers on to inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to edge band technical field, and in particular to a kind of tasteless environment-friendly type PVC edge band and preparation method thereof, the tasteless environment-friendly type PVC edge band includes the raw material of following parts by weight：0.5 1.5 parts of 75 125 parts of polyvinyl chloride resin, 8 25 parts of nm-class active calcium carbonate, 6 32 parts of tasteless environment-friendly plasticizer, 3 33 parts of modified additive, 3 13 parts of the taste agent that disappears, environmentally friendly 2.5 6.5 parts of calcium-zinc composite stabilizing agent, 0.3 1.5 parts of in-lubricant, 0.5 2.0 parts of external lubricant, 0.1 0.8 parts of ultra-violet absorber, 0.2 1.5 parts of antioxidant and toner.The tasteless environment-friendly type PVC edge band of the present invention does not contain phthalate, heavy metal and other harmful substances, and environmental protection, odorlessness, and weatherability are strong, high impact-resistant, comprehensive physical excellent performance.
Description
Technical field
The present invention relates to edge band technical field, and in particular to a kind of tasteless environment-friendly type PVC edge band and preparation method thereof.
Background technology
Edge band is the material being protected, decorated to the section of Furniture panel, beautified, and its major function is disconnected to sheet material
Face carries out sealing, reaches from the unfavorable factor during environment and use（Predominantly moisture）Destruction to sheet material, and prevent
Formaldehyde volatilization inside sheet material, while reaching the effect for making a piece of furniture show clear, the riotous with colour decoration of wood grain.It is existing
Edge band is with polyvinyl chloride（PVC）Based on edge band, polyvinyl chloride edge band is that, using polyvinyl chloride as primary raw material, addition is helped
The thermoplastic coiled material of agent, together mixing compacting.There are the decorative patterns such as wood grain, marble, woven design, figure in the surface of polyvinyl chloride edge band
Case, while lustrous surface is soft, the sense of reality and third dimension with timber；With certain chemicals-resistant, corrosion resistance.Due to
Traditional PVC edge bands are odor profiles larger, there is certain pollution to environment, and Long Term Contact is unfavorable for health.
The content of the invention
In order to overcome shortcoming and defect present in prior art, it is an object of the invention to provide a kind of tasteless environment-friendly type
PVC edge bands, the tasteless environment-friendly type PVC edge band does not contain phthalate, heavy metal and other harmful substances, environmental protection,
Odorlessness, and weatherability is strong, high impact-resistant, comprehensive physical excellent performance.
Another object of the present invention is to provide a kind of preparation method of tasteless environment-friendly type PVC edge band, the preparation method
Step is simple, convenient operation and control, steady quality, and production efficiency is high, and production cost is low, can large-scale industrial production.
The purpose of the present invention is achieved through the following technical solutions：A kind of tasteless environment-friendly type PVC edge band, including following weight
The raw material of part：
75-125 parts of polyvinyl chloride resin
8-25 parts of nm-class active calcium carbonate
Tasteless environment-friendly plasticizer 6-32 parts
3-33 parts of modified additive
Disappear 3-13 parts of taste agent
Environmentally friendly calcium-zinc composite stabilizing agent 2.5-6.5 parts
0.3-1.5 parts of in-lubricant
0.5-2.0 parts of external lubricant
0.1-0.8 parts of ultra-violet absorber
0.2-1.5 parts of antioxidant
0.5-1.5 parts of toner.
It is preferred that, the polyvinyl chloride resin is SG-5 type polyvinyl chloride resin of the degree of polymerization in 1000-1100.The present invention is by using poly-
The right SG-5 type polyvinyl chloride resins in 1000-1100 are the intensity of obtained PVC edge bands, rigidity, toughness, heat-resisting and low temperature resistant
Better, and moulding processability is good for property.
The nm-class active calcium carbonate is particle diameter in 10-100nm and connect through silane coupler modified processing and polyvinyl chloride
The treated nm-class active calcium carbonate of branch.
The nm-class active calcium carbonate is prepared by following steps：Nm-class active calcium carbonate is carried out using silane coupler
After surface modification treatment, by the polyvinyl chloride monomer graft polymerization to nano-calcium carbonate surface under the conditions of gamma Rays.
First passing through coupling agent treatment makes organic molecule absorption on the surface of nm-class active calcium carbonate, and further radiation effects can be poly-
VCM occurs polymerization and is grafted on the organic molecule of nano-calcium carbonate, while radiation effects can also make calcium carbonate
The hydroxyl structure that surface hydrolysis is produced produces free radical, and then triggers the polymerization of polyvinyl chloride monomer, improves connecing for Paris white
Branch rate.
The particle diameter of filler is smaller, and the tensile strength and impact strength to packing material are more beneficial, and the present invention is by selecting
Nm-class active calcium carbonate is as filler and controls its particle diameter in 10-100nm, and its crystal structure and Electronic Structure there occurs
Change, generates quantum size effect, small-size effect, skin effect and macroscopic quantum effect that ordinary calcium carbonate does not have
Should, therefore with good toughened and reinforced effect, it, which is added, can improve bending strength and bending bullet in the edge band of the present invention
The stability of property modulus and heat distortion temperature and size；Filler is to play its effect and control with the good compatibility of resin
The key of addition, the present invention is using the nano active carbonic acid treated through silane coupler modified processing and polyvinyl chloride graft
Calcium, can improve the compatibility of nm-class active calcium carbonate and polyvinyl chloride resin, so as to improve the intensity of material.
It is preferred that, the tasteless environment-friendly plasticizer is by 1-5 parts of soybean oil, 3-12 parts of dioctyl adipate and hexamethylene 1,2-
2-15 parts of compositions of dioctyl phthalate diisononyl esters.
Environment-friendly type PVC edge band of the present invention employs environment-friendly plasticizer, without phthalate, heavy metal and other
Harmful substance, with excellent tack, weatherability and wearability, epoxidized soybean oil can catch in PVC degradeds the chlorine that produces from
Son, terminates the radical reaction of PVC degradeds, significantly improves light resistance, the heat resistance of PVC edge bands；Point of dioctyl adipate
Son amount is suitable with PVC therefore fabulous with PVC compatibilities, is not easy to volatilization；Hexamethylene 1, increases based on 2- dioctyl phthalate diisononyl esters
Mould agent, have that intermiscibility is good, plasticizing efficiency is high, it is nontoxic it is not volatile, the features such as weather resisteant is strong, with epoxidized soybean oil and adipic acid two
Monooctyl ester, which is shared, can suitably increase the hardness of PVC edge bands, and hexamethylene 1, and 2- dioctyl phthalate diisononyl esters also have antibiotic property
And anti-flammability, necessary to both performances are all household goods.
It is preferred that, the modified additive is made up of 1-15 parts of 1-8 parts of CPE, 1-10 parts of ACR and MBS.
CPE, ACR, MBS are impact modified auxiliary agent, but different, the CPE that stresses direction of three（Haloflex）Tool
There is optimal low-temperature impact performance, and price is minimum, but plasticizing rate is slower, ACR（Methyl methacrylate, acrylate
Deng the copolymer of monomer）Weatherability it is excellent, low temperature toughness reinforcing and other effects is general, but its processing effect is optimal, used in compounding processing
Plasticizing rate can be accelerated in auxiliary agent, shorten modified and mixing and find time, production cost is reduced and prevent fusion time is long from leading
Cause product excessively soft；MBS（Methyl methacrylate, butadiene, styrene copolymer）The weatherability of resin is worst, but its is low
Warm toughening effect is optimal, and because structure is close with PVC, therefore, relative transparency highest minimum to PVC Color influences, and
Processing effect is not also poor；The composite auxiliary for processing of the present invention realizes the high performance-price ratio of PVC edge bands by the compounding pattern.
The plasticizer of the present invention can cooperate with composite modified auxiliary agent to play plasticization effect jointly, and plasticizer has
Beneficial to the scattered of compounding processing aid, make that the processing effect of compounding processing aid is more obvious, both complement each other so that this hair
Bright PVC edge bands have good toughness, weatherability, shock resistance, appropriate hardness and relatively low production cost.
It is preferred that, the environmentally friendly calcium-zinc composite stabilizing agent is with weight to compare 50%-80% by calcium stearate and zinc stearate：
The mixture of 20%-50% compositions.
Zinc stearate is used as PVC non-toxic heat stabilizer, suppresses initial coloring and lubricity is good, no sulfide staining, but
Thermal stability is limited, and the zinc chloride of formation has catalytic degradation effect to PVC, is compounded with calcium stearate, calcium stearate and ZnCl2
Reaction, it is suppressed that ZnCl2The catalytic action thermally decomposed to PVC, extends PVC heat-stable time.
It is preferred that, the taste agent that disappears is by 1-3 parts of white carbon, 1-5 parts of groups of 1-5 parts of sodium acid carbonate and glycerin monostearate
Into.
The present invention strictly controls its weight proportion by using the above-mentioned three kinds taste agent that disappear, and can adsorb and fast decoupled PVC
In smell, the environmental protection of obtained PVC edge bands, odorlessness.
It is preferred that, the in-lubricant be aliphatic acid, butyl stearate, glycerin monostearate, ethylene bis stearamide,
In oleamide, pentaerythritol stearate, N, N- ethylenebis Stearyl Amine and N, N- ethylenebis ricinoleic acid acid amide extremely
Few one kind.In-lubricant has good compatibility with polymer, its cohesion between polymeric inner plays reduction polymer molecule
The effect of power, so as to improve the interior frictional heat of plastic melt and the mobility of melt.It is more highly preferred to, the in-lubricant is
By pentaerythritol stearate, glycerin monostearate and ethylene bis stearamide with weight ratio 1:0.5-1.5:1.5-2.5 group
Into mixture.
The external lubricant be atoleine, solid paraffin, natural paraffin wax, microcrystalline wax, chlorinated paraffin, Tissuemat E and
At least one of OPE.The effect of external lubricant mainly improves the heat of polymer melt and processing coating apparatus
The friction of metal surface, it is poor with polymer compatibility, easily toward external migration out of melt, so can be in plastic melt and gold
The thin layer of the interface formation lubrication of category.It is more highly preferred to, the external lubricant is poly- by chlorinated paraffin, microcrystalline wax and oxidation
Ethylene waxes compare 0.8-1.2 with weight:1:1.4-2.2 the mixture of composition.
The present invention is used cooperatively by using in-lubricant and external lubricant, and strictly controls its weight proportion, can be with
Material is improved the mobility of material and the release property of product in process, difficulty of processing can be reduced, save the energy and disappear
Consumption.
It is preferred that, the ultra-violet absorber is phenyl salicylate, Ultraviolet Absorber UV-P, ultra-violet absorber UV-
O, ultra-violet absorber UV-9, ultraviolet absorbent UV-531, ultra-violet absorber UVP-327, ultra-violet absorber RMB,
Light stabilizer AM-101, light stabilizer 744, light stabilizer HPT and 2,4,6- tri- (2 ' n-butoxyphenyl) -1,3,5- triazines
At least one of.The present invention is by using above-mentioned ultra-violet absorber, and the effect that it absorbs ultraviolet is good.It is more highly preferred to,
The ultra-violet absorber is with weight ratio by ultraviolet absorbent UV-531, ultra-violet absorber RMB and light stabilizer 744
0.8-1.2:0.5-1.5:The mixture of 1 composition.The present invention is by using above-mentioned three kinds of ultra-violet absorber compounding uses, and sternly
Lattice control its weight proportion, and ultraviolet can be absorbed strongly, with excellent cooperative effect.
It is preferred that, the antioxidant is antioxidant 1010, antioxidant 1076, irgasfos 168, antioxidant 164, antioxygen
In agent CA, antioxidant DNP, anti-oxidant DLTP, antioxidant TNP, antioxidant TPP, antioxidant MB and antioxidant 264
It is at least one.The present invention is by using above-mentioned antioxidant, and its antioxidant effect is good.It is more highly preferred to, the antioxidant is by resisting
Oxygen agent 1010, antioxidant 1076 and irgasfos 168 compare 1-2 with weight:0.8-1.2:The mixture of 1 composition.The present invention is by adopting
With above-mentioned three kinds of antioxidant compounding uses, and its weight proportion is strictly controlled, can delay or suppress entering for material oxidation process
OK, so as to prevent the aging of material and extend its service life.
The present invention is capable of the weatherability of Reinforced PVC edge band, and pass through by using ultra-violet absorber and antioxidant
The specific selection of ultra-violet absorber and the compounded combination of antioxidant, realize the compatibility being formulated with edge band of the present invention, protect
Hold the intact performance of edge band.
The toner is at least one of ultramarine toner, phthalocyanine blue and titanium dioxide.The present invention by using above-mentioned toner,
Obtained PVC edge bands color and luster is good.
A kind of preparation method of tasteless environment-friendly type PVC edge band, comprises the following steps：
（1）Above-mentioned raw materials mixing is weighed by the parts by weight of constitutive material, is stirred；
（2）Raw material after stirring is granulated, then base material is made in extrusion；
（3）In substrate surface simulated grain pattern, pattern is finally crossed into UV coating protections, tasteless environment-friendly type PVC edge band is made.
The step（1）In, speed of agitator is 1200-1600rpm, and whipping temp is 110-150 DEG C, and mixing time is
10-30min。
The step（2）In, extrusion temperature is 120-200 DEG C, and extruded velocity is 0.1-5km/h.
The beneficial effects of the present invention are：The tasteless environment-friendly type PVC edge band of the present invention does not contain phthalate, again
Metal and other harmful substances, environmental protection, odorlessness, and weatherability are strong, high impact-resistant, comprehensive physical excellent performance.
The preparation method step of the present invention is simple, convenient operation and control, steady quality, and production efficiency is high, and production cost is low,
Can large-scale industrial production.
Embodiment
For the ease of the understanding of those skilled in the art, with reference to embodiment, the present invention is further illustrated, real
The content that the mode of applying is referred to not limitation of the invention.
Embodiment 1
A kind of tasteless environment-friendly type PVC edge band, includes the raw material of following parts by weight：
75 parts of polyvinyl chloride resin
8 parts of nm-class active calcium carbonate
Tasteless 6 parts of environment-friendly plasticizer
3 parts of modified additive
Disappear 3 parts of taste agent
Environmentally friendly 2.5 parts of calcium-zinc composite stabilizing agent
0.3 part of in-lubricant
0.5 part of external lubricant
0.1 part of ultra-violet absorber
0.2 part of antioxidant
0.5 part of toner.
The polyvinyl chloride resin is SG-5 type polyvinyl chloride resin of the degree of polymerization 1000；The nm-class active calcium carbonate is that particle diameter exists
10nm and the nm-class active calcium carbonate treated through silane coupler modified processing and polyvinyl chloride graft.
The tasteless environment-friendly plasticizer is by 1 part of soybean oil, 3 parts of dioctyl adipate and hexamethylene 1, the different nonyl of 2- dioctyl phthalate two
2 parts of compositions of base ester.
The modified additive is made up of 1 part of 1 part of CPE, 1 part of ACR and MBS.
The taste agent that disappears is made up of 1 part of 1 part of white carbon, 1 part of sodium acid carbonate and glycerin monostearate.
The environmentally friendly calcium-zinc composite stabilizing agent is with weight ratio 50% by calcium stearate and zinc stearate：The mixing of 50% composition
Thing.
The in-lubricant is aliphatic acid or butyl stearate；The external lubricant is atoleine or solid paraffin.
The ultra-violet absorber is phenyl salicylate or Ultraviolet Absorber UV-P.
The antioxidant is antioxidant 1010 or antioxidant 1076；The toner is ultramarine toner.
A kind of preparation method of tasteless environment-friendly type PVC edge band, comprises the following steps：
（1）Above-mentioned raw materials mixing is weighed by the parts by weight of constitutive material, is stirred；
（2）Raw material after stirring is granulated, then base material is made in extrusion；
（3）In substrate surface printed patterns, pattern is finally crossed into UV coating protections, tasteless environment-friendly type PVC edge band is made.
The step（1）In, speed of agitator is 1200rpm, and whipping temp is 110 DEG C, and mixing time is 10min.
The step（2）In, extrusion temperature is 120 DEG C, and extruded velocity is 0.1km/h.
Embodiment 2
A kind of tasteless environment-friendly type PVC edge band, includes the raw material of following parts by weight：
85 parts of polyvinyl chloride resin
12 parts of nm-class active calcium carbonate
Tasteless 13 parts of environment-friendly plasticizer
10 parts of modified additive
Disappear 5.5 parts of taste agent
Environmentally friendly 3.5 parts of calcium-zinc composite stabilizing agent
0.5 part of in-lubricant
0.8 part of external lubricant
0.3 part of ultra-violet absorber
0.5 part of antioxidant
0.8 part of toner.
The polyvinyl chloride resin is SG-5 type polyvinyl chloride resin of the degree of polymerization 1020；The nm-class active calcium carbonate is that particle diameter exists
30nm and the nm-class active calcium carbonate treated through silane coupler modified processing and polyvinyl chloride graft.
The tasteless environment-friendly plasticizer is by 2 parts of soybean oil, 5 parts of dioctyl adipate and hexamethylene 1, the different nonyl of 2- dioctyl phthalate two
6 parts of compositions of base ester.
The modified additive is made up of 4 parts of 3 parts of CPE, 3 parts of ACR and MBS.
The taste agent that disappears is made up of 2 parts of 1.5 parts of white carbon, 2 parts of sodium acid carbonate and glycerin monostearate.
The environmentally friendly calcium-zinc composite stabilizing agent is with weight ratio 60% by calcium stearate and zinc stearate：The mixing of 40% composition
Thing.
The in-lubricant is glycerin monostearate or ethylene bis stearamide；The external lubricant be natural paraffin wax or
Microcrystalline wax.
The ultra-violet absorber is ultra-violet absorber UV-O or ultra-violet absorber UV-9.
The antioxidant is irgasfos 168 or antioxidant 164；The toner is phthalocyanine blue.
A kind of preparation method of tasteless environment-friendly type PVC edge band, comprises the following steps：
（1）Above-mentioned raw materials mixing is weighed by the parts by weight of constitutive material, is stirred；
（2）Raw material after stirring is granulated, then base material is made in extrusion；
（3）In substrate surface printed patterns, pattern is finally crossed into UV coating protections, tasteless environment-friendly type PVC edge band is made.
The step（1）In, speed of agitator is 1300rpm, and whipping temp is 120 DEG C, and mixing time is 15min.
The step（2）In, extrusion temperature is 140 DEG C, and extruded velocity is 1km/h.
Embodiment 3
A kind of tasteless environment-friendly type PVC edge band, includes the raw material of following parts by weight：
100 parts of polyvinyl chloride resin
16 parts of nm-class active calcium carbonate
Tasteless 19 parts of environment-friendly plasticizer
19 parts of modified additive
Disappear 8 parts of taste agent
Environmentally friendly 4.5 parts of calcium-zinc composite stabilizing agent
0.9 part of in-lubricant
1.2 parts of external lubricant
0.5 part of ultra-violet absorber
0.8 part of antioxidant
1.0 parts of toner.
The polyvinyl chloride resin is SG-5 type polyvinyl chloride resin of the degree of polymerization 1050；The nm-class active calcium carbonate is that particle diameter exists
50nm and the nm-class active calcium carbonate treated through silane coupler modified processing and polyvinyl chloride graft.
The tasteless environment-friendly plasticizer is by 3 parts of soybean oil, 8 parts of dioctyl adipate and hexamethylene 1, the different nonyl of 2- dioctyl phthalate two
8 parts of compositions of base ester.
The modified additive is made up of 8 parts of 5 parts of CPE, 6 parts of ACR and MBS.
The taste agent that disappears is made up of 3 parts of 2 parts of white carbon, 3 parts of sodium acid carbonate and glycerin monostearate.
The environmentally friendly calcium-zinc composite stabilizing agent is with weight ratio 65% by calcium stearate and zinc stearate：The mixing of 35% composition
Thing.
The in-lubricant is oleamide or pentaerythritol stearate；The external lubricant is chlorinated paraffin or polyethylene
Wax.
The ultra-violet absorber is ultraviolet absorbent UV-531 or ultra-violet absorber UVP-327.
The antioxidant is antioxidant CA, antioxidant DNP or anti-oxidant DLTP；The toner is titanium dioxide.
A kind of preparation method of tasteless environment-friendly type PVC edge band, comprises the following steps：
（1）Above-mentioned raw materials mixing is weighed by the parts by weight of constitutive material, is stirred；
（2）Raw material after stirring is granulated, then base material is made in extrusion；
（3）In substrate surface printed patterns, pattern is finally crossed into UV coating protections, tasteless environment-friendly type PVC edge band is made.
The step（1）In, speed of agitator is 1400rpm, and whipping temp is 130 DEG C, and mixing time is 20min.
The step（2）In, extrusion temperature is 160 DEG C, and extruded velocity is 2.5km/h.
Embodiment 4
A kind of tasteless environment-friendly type PVC edge band, includes the raw material of following parts by weight：
115 parts of polyvinyl chloride resin
10 parts of nm-class active calcium carbonate
Tasteless 26 parts of environment-friendly plasticizer
26 parts of modified additive
Disappear 10.5 parts of taste agent
Environmentally friendly 5.5 parts of calcium-zinc composite stabilizing agent
1.2 parts of in-lubricant
1.6 parts of external lubricant
0.6 part of ultra-violet absorber
1.2 parts of antioxidant
1.2 parts of toner.
The polyvinyl chloride resin is SG-5 type polyvinyl chloride resin of the degree of polymerization 1080；The nm-class active calcium carbonate is that particle diameter exists
80nm and the nm-class active calcium carbonate treated through silane coupler modified processing and polyvinyl chloride graft.
The tasteless environment-friendly plasticizer is by 4 parts of soybean oil, 10 parts of dioctyl adipate and hexamethylene 1, and 2- dioctyl phthalate two is different
12 parts of compositions of nonyl ester.
The modified additive is made up of 12 parts of 6 parts of CPE, 8 parts of ACR and MBS.
The taste agent that disappears is made up of 4 parts of 2.5 parts of white carbon, 4 parts of sodium acid carbonate and glycerin monostearate.
The environmentally friendly calcium-zinc composite stabilizing agent is with weight ratio 70% by calcium stearate and zinc stearate：The mixing of 30% composition
Thing.
The in-lubricant is N, N- ethylenebis Stearyl Amine or N, N- ethylenebis ricinoleic acid acid amide；The outer profit
Lubrication prescription is OPE.
The ultra-violet absorber is ultra-violet absorber RMB or light stabilizer AM-101.
The antioxidant is antioxidant TNP or antioxidant TPP；The toner is ultramarine toner.
A kind of preparation method of tasteless environment-friendly type PVC edge band, comprises the following steps：
（1）Above-mentioned raw materials mixing is weighed by the parts by weight of constitutive material, is stirred；
（2）Raw material after stirring is granulated, then base material is made in extrusion；
（3）In substrate surface printed patterns, pattern is finally crossed into UV coating protections, tasteless environment-friendly type PVC edge band is made.
The step（1）In, speed of agitator is 1500rpm, and whipping temp is 140 DEG C, and mixing time is 25min.
The step（2）In, extrusion temperature is 180 DEG C, and extruded velocity is 4km/h.
Embodiment 5
A kind of tasteless environment-friendly type PVC edge band, includes the raw material of following parts by weight：
125 parts of polyvinyl chloride resin
25 parts of nm-class active calcium carbonate
Tasteless 32 parts of environment-friendly plasticizer
33 parts of modified additive
Disappear 13 parts of taste agent
Environmentally friendly 6.5 parts of calcium-zinc composite stabilizing agent
1.5 parts of in-lubricant
2.0 parts of external lubricant
0.8 part of ultra-violet absorber
1.5 parts of antioxidant
1.5 parts of toner.
The polyvinyl chloride resin is SG-5 type polyvinyl chloride resin of the degree of polymerization 1100；The nm-class active calcium carbonate is that particle diameter exists
100nm and the nm-class active calcium carbonate treated through silane coupler modified processing and polyvinyl chloride graft.
The tasteless environment-friendly plasticizer is by 5 parts of soybean oil, 12 parts of dioctyl adipate and hexamethylene 1, and 2- dioctyl phthalate two is different
15 parts of compositions of nonyl ester.
The modified additive is made up of 15 parts of 8 parts of CPE, 10 parts of ACR and MBS.
The taste agent that disappears is made up of 5 parts of 3 parts of white carbon, 5 parts of sodium acid carbonate and glycerin monostearate.
The environmentally friendly calcium-zinc composite stabilizing agent is with weight ratio 80% by calcium stearate and zinc stearate：The mixing of 20% composition
Thing.
The in-lubricant is aliphatic acid；The external lubricant is atoleine.
The ultra-violet absorber be light stabilizer 744, light stabilizer HPT or 2,4,6- tri- (2 ' n-butoxyphenyl)-
1,3,5- triazines.
The antioxidant is antioxidant MB or antioxidant 264；The toner is phthalocyanine blue.
A kind of preparation method of tasteless environment-friendly type PVC edge band, comprises the following steps：
（1）Above-mentioned raw materials mixing is weighed by the parts by weight of constitutive material, is stirred；
（2）Raw material after stirring is granulated, then base material is made in extrusion；
（3）In substrate surface printed patterns, pattern is finally crossed into UV coating protections, tasteless environment-friendly type PVC edge band is made.
The step（1）In, speed of agitator is 1600rpm, and whipping temp is 150 DEG C, and mixing time is 30min.
The step（2）In, extrusion temperature is 200 DEG C, and extruded velocity is 5km/h.
Embodiment 6
The difference of the present embodiment and above-described embodiment 1 is：
The in-lubricant is with weight ratio 1 by pentaerythritol stearate, glycerin monostearate and ethylene bis stearamide:
0.5:The mixture of 1.5 compositions.
The external lubricant is with weight ratio 0.8 by chlorinated paraffin, microcrystalline wax and OPE:1:1.4 composition
Mixture.
The ultra-violet absorber be by ultraviolet absorbent UV-531, ultra-violet absorber RMB and light stabilizer 744 with
Weight compares 0.8:0.5:The mixture of 1 composition.
The antioxidant is with weight ratio 1 by antioxidant 1010, antioxidant 1076 and irgasfos 168:0.8:1 composition it is mixed
Compound.
Embodiment 7
The difference of the present embodiment and above-described embodiment 2 is：
The in-lubricant is with weight ratio 1 by pentaerythritol stearate, glycerin monostearate and ethylene bis stearamide:
0.8:The mixture of 1.8 compositions.
The external lubricant is with weight ratio 0.9 by chlorinated paraffin, microcrystalline wax and OPE:1:1.6 composition
Mixture.
The ultra-violet absorber be by ultraviolet absorbent UV-531, ultra-violet absorber RMB and light stabilizer 744 with
Weight compares 0.9:0.8:The mixture of 1 composition.
The antioxidant is with weight ratio 1.2 by antioxidant 1010, antioxidant 1076 and irgasfos 168:0.9:1 composition
Mixture.
Embodiment 8
The difference of the present embodiment and above-described embodiment 3 is：
The in-lubricant is with weight ratio 1 by pentaerythritol stearate, glycerin monostearate and ethylene bis stearamide:
1:The mixture of 2 compositions.
The external lubricant is with weight ratio 1 by chlorinated paraffin, microcrystalline wax and OPE:1:1.8 compositions
Mixture.
The ultra-violet absorber be by ultraviolet absorbent UV-531, ultra-violet absorber RMB and light stabilizer 744 with
Weight compares 1:1:The mixture of 1 composition.
The antioxidant is with weight ratio 1.5 by antioxidant 1010, antioxidant 1076 and irgasfos 168:1:1 composition it is mixed
Compound.
Embodiment 9
The difference of the present embodiment and above-described embodiment 4 is：
The in-lubricant is with weight ratio 1 by pentaerythritol stearate, glycerin monostearate and ethylene bis stearamide:
1.2:The mixture of 2.2 compositions.
The external lubricant is with weight ratio 1.1 by chlorinated paraffin, microcrystalline wax and OPE:1:2 compositions
Mixture.
The ultra-violet absorber be by ultraviolet absorbent UV-531, ultra-violet absorber RMB and light stabilizer 744 with
Weight compares 1.1:1.2:The mixture of 1 composition.
The antioxidant is with weight ratio 1.8 by antioxidant 1010, antioxidant 1076 and irgasfos 168:1.1:1 composition
Mixture.
Embodiment 10
The difference of the present embodiment and above-described embodiment 5 is：
The in-lubricant is with weight ratio 1 by pentaerythritol stearate, glycerin monostearate and ethylene bis stearamide:
1.5:The mixture of 2.5 compositions.
The external lubricant is with weight ratio 1.2 by chlorinated paraffin, microcrystalline wax and OPE:1:2.2 composition
Mixture.
The ultra-violet absorber be by ultraviolet absorbent UV-531, ultra-violet absorber RMB and light stabilizer 744 with
Weight compares 1.2:1.5:The mixture of 1 composition.
The antioxidant is with weight ratio 2 by antioxidant 1010, antioxidant 1076 and irgasfos 168:1.2:1 composition it is mixed
Compound.
The tasteless environment-friendly type PVC edge band of the present invention does not contain phthalate, heavy metal and other harmful substances, ring
Guarantor, odorlessness, burst size of methanal are less than 0.1mg/kg, and weatherability is strong, high impact-resistant, comprehensive physical excellent performance.
Above-described embodiment is the present invention preferably implementation, and in addition, the present invention can be realized with other manner,
Any obvious replacement is within protection scope of the present invention on the premise of not departing from present inventive concept.
Claims (10)
1. a kind of tasteless environment-friendly type PVC edge band, it is characterised in that：Include the raw material of following parts by weight：
75-125 parts of polyvinyl chloride resin
8-25 parts of nm-class active calcium carbonate
Tasteless environment-friendly plasticizer 6-32 parts
3-33 parts of modified additive
Disappear 3-13 parts of taste agent
Environmentally friendly calcium-zinc composite stabilizing agent 2.5-6.5 parts
0.3-1.5 parts of in-lubricant
0.5-2.0 parts of external lubricant
0.1-0.8 parts of ultra-violet absorber
0.2-1.5 parts of antioxidant
0.5-1.5 parts of toner.
2. a kind of tasteless environment-friendly type PVC edge band according to claim 1, it is characterised in that：The polyvinyl chloride resin is polymerization
Spend the SG-5 type polyvinyl chloride resins in 1000-1100；The nm-class active calcium carbonate is particle diameter in 10-100nm and through silane coupled
Agent modification and the treated nm-class active calcium carbonate of polyvinyl chloride graft.
3. a kind of tasteless environment-friendly type PVC edge band according to claim 1, it is characterised in that：The tasteless environmental protection plasticising
Agent is by 1-5 parts of soybean oil, 3-12 parts of dioctyl adipate and hexamethylene 1,2-15 parts of compositions of 2- dioctyl phthalate diisononyl esters.
4. a kind of tasteless environment-friendly type PVC edge band according to claim 1, it is characterised in that：The modified additive is by CPE
1-8 parts, 1-15 parts of compositions of 1-10 parts of ACR and MBS.
5. a kind of tasteless environment-friendly type PVC edge band according to claim 1, it is characterised in that：The taste agent that disappears is by hard charcoal
1-5 parts of compositions of black 1-3 parts, 1-5 parts of sodium acid carbonate and glycerin monostearate.
6. a kind of tasteless environment-friendly type PVC edge band according to claim 1, it is characterised in that：The environmentally friendly Ca Zn composite
Stabilizer is with weight to compare 50%-80% by calcium stearate and zinc stearate：The mixture of 20%-50% compositions.
7. a kind of tasteless environment-friendly type PVC edge band according to claim 1, it is characterised in that：The in-lubricant is fat
Fat acid, butyl stearate, glycerin monostearate, ethylene bis stearamide, oleamide, pentaerythritol stearate, N, N- are sub-
Ethyl double at least one of Stearyl Amines and N, N- ethylenebis ricinoleic acid acid amide；The external lubricant be atoleine,
At least one of solid paraffin, natural paraffin wax, microcrystalline wax, chlorinated paraffin, Tissuemat E and OPE.
8. a kind of tasteless environment-friendly type PVC edge band according to claim 1, it is characterised in that：The ultra-violet absorber
For phenyl salicylate, Ultraviolet Absorber UV-P, ultra-violet absorber UV-O, ultra-violet absorber UV-9, ultra-violet absorber
UV-531, ultra-violet absorber UVP-327, ultra-violet absorber RMB, light stabilizer AM-101, light stabilizer 744, light
At least one of stabilizer HPT and 2,4,6- tri- (2 ' n-butoxyphenyl) -1,3,5- triazines.
9. a kind of tasteless environment-friendly type PVC edge band according to claim 1, it is characterised in that：The antioxidant is antioxygen
It is agent 1010, antioxidant 1076, irgasfos 168, antioxidant 164, antioxidant CA, antioxidant DNP, anti-oxidant DLTP, anti-
At least one of oxygen agent TNP, antioxidant TPP, antioxidant MB and antioxidant 264；The toner is ultramarine toner, phthalein green grass or young crops
At least one of blue and titanium dioxide.
10. a kind of preparation method of tasteless environment-friendly type PVC edge band as described in claim any one of 1-9, it is characterised in that：
Comprise the following steps：
（1）Above-mentioned raw materials mixing is weighed by the parts by weight of constitutive material, is stirred；
（2）Raw material after stirring is granulated, then base material is made in extrusion；
（3）In substrate surface printed patterns, pattern is finally crossed into UV coating protections, tasteless environment-friendly type PVC edge band is made.
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| CN113462005A (en) * | 2021-08-20 | 2021-10-01 | 河南农业大学 | Preparation method of composite material for absorbing and decomposing formaldehyde and VOVs |
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