CN104293244B - A kind of transparent nail-free glue and preparation method thereof - Google Patents
A kind of transparent nail-free glue and preparation method thereof Download PDFInfo
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- CN104293244B CN104293244B CN201410581479.2A CN201410581479A CN104293244B CN 104293244 B CN104293244 B CN 104293244B CN 201410581479 A CN201410581479 A CN 201410581479A CN 104293244 B CN104293244 B CN 104293244B
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- 239000003292 glue Substances 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000000945 filler Substances 0.000 claims abstract description 13
- 239000013008 thixotropic agent Substances 0.000 claims abstract description 11
- 150000001875 compounds Chemical class 0.000 claims abstract description 9
- 229920001577 copolymer Polymers 0.000 claims abstract description 9
- 239000003381 stabilizer Substances 0.000 claims abstract description 9
- 239000003960 organic solvent Substances 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 5
- 229920005989 resin Polymers 0.000 claims description 26
- 239000011347 resin Substances 0.000 claims description 26
- 238000003756 stirring Methods 0.000 claims description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 13
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 11
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 11
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 11
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 9
- 239000004611 light stabiliser Substances 0.000 claims description 8
- 229910002012 Aerosil® Inorganic materials 0.000 claims description 7
- 239000003208 petroleum Substances 0.000 claims description 7
- 150000003505 terpenes Chemical class 0.000 claims description 7
- 235000007586 terpenes Nutrition 0.000 claims description 7
- 238000007599 discharging Methods 0.000 claims description 6
- 238000009472 formulation Methods 0.000 claims description 6
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 6
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 5
- 229950011008 tetrachloroethylene Drugs 0.000 claims description 5
- 229940123457 Free radical scavenger Drugs 0.000 claims description 4
- 229920005987 OPPANOL® Polymers 0.000 claims description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
- 150000001723 carbon free-radicals Chemical class 0.000 claims description 4
- 229910052906 cristobalite Inorganic materials 0.000 claims description 4
- NKDDWNXOKDWJAK-UHFFFAOYSA-N dimethoxymethane Chemical compound COCOC NKDDWNXOKDWJAK-UHFFFAOYSA-N 0.000 claims description 4
- 238000009826 distribution Methods 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 4
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 239000002516 radical scavenger Substances 0.000 claims description 4
- QSRJVOOOWGXUDY-UHFFFAOYSA-N 2-[2-[2-[3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoyloxy]ethoxy]ethoxy]ethyl 3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C)=CC(CCC(=O)OCCOCCOCCOC(=O)CCC=2C=C(C(O)=C(C)C=2)C(C)(C)C)=C1 QSRJVOOOWGXUDY-UHFFFAOYSA-N 0.000 claims description 3
- OKOBUGCCXMIKDM-UHFFFAOYSA-N Irganox 1098 Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NCCCCCCNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 OKOBUGCCXMIKDM-UHFFFAOYSA-N 0.000 claims description 3
- 239000000440 bentonite Substances 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- 239000000084 colloidal system Substances 0.000 abstract description 7
- 230000032683 aging Effects 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 description 10
- 239000000853 adhesive Substances 0.000 description 8
- 229920002689 polyvinyl acetate Polymers 0.000 description 5
- 239000011118 polyvinyl acetate Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- -1 tert butyl phenolic resin Chemical compound 0.000 description 5
- 239000003963 antioxidant agent Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229920006132 styrene block copolymer Polymers 0.000 description 4
- 150000003440 styrenes Chemical class 0.000 description 4
- 230000003078 antioxidant effect Effects 0.000 description 3
- 239000013535 sea water Substances 0.000 description 3
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 230000002596 correlated effect Effects 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229920002742 polystyrene-block-poly(ethylene/propylene) -block-polystyrene Polymers 0.000 description 2
- 229920002743 polystyrene-poly(ethylene-ethylene/propylene) block-polystyrene Polymers 0.000 description 2
- 229920002725 thermoplastic elastomer Polymers 0.000 description 2
- 235000018185 Betula X alpestris Nutrition 0.000 description 1
- 235000018212 Betula X uliginosa Nutrition 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 238000007718 adhesive strength test Methods 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of transparent nail-free glue and preparation method thereof, it is characterised in that be mainly composed of high-molecular copolymer, transparent tacking agent, filler, thixotropic agent, compound stabilizer, organic solvent.The invention have the advantage that the 1. use transparency preferably high-molecular copolymer and tackifier, both ensure that preferable cementability, and given again the transparency that nail-free glue is good, be widely portable to the occasion higher to colloid transparency requirement；2. using high refractive index filler and high transparency thixotropic agent, colloid transparency is high, and thixotropy is good；3. adding compound stabilizer, weatherability, ageing resistance and anti-ultraviolet property are all greatly improved.
Description
Technical field
The present invention relates to adhesive area, be specifically related to a kind of transparent nail-free glue and preparation method thereof.
Background technology
Nail-free glue is that one has the features such as adhering speed is fast, intensity is high, applied widely, solid content is high, easy construction, is widely used in the novel adhesive of the industries such as decorations, Furniture manufacture, advertisement art, five metals.At present nail-free glue just by its easy construction, without nail, adhesive strength advantages of higher, favored by users.But, when the materials such as some glasswares, clear sheet, handicraft are bonding, generally require and use transparent adhesive to improve its aesthetics, but the nail-free glue circulated in the market is the opaquest, the needs of people are can not meet, its popularization of extreme influence.
A kind of nail-free glue for architectural decoration disclosed in CN101550320B, raw material has styrene analog thermoplastic elastomer, modified rosin, Petropols, solvent, filler, it is applicable to most of building and ornament materials, but the materials such as styrene analog thermoplastic elastomer used are oxidizable, and the filler that uses is opaque, colloid is caused the most not have the transparency；201210569445.2 disclosed a kind of high-strength low-temperature-resistant is combined nail-free glue and preparation method thereof, the technical scheme taked comprises neoprene, SBS synthetic rubber, tert butyl phenolic resin, Petropols, solvent, filler, aerosil, coupling agent, magnesia, triethanolamine, antifreeze, amines antioxidants, cryogenic conditions can be well adapted to, use adhesive property is excellent, but gained colloid is opaque；201310436008.8 disclosed a kind of environment-friendlyand and decorative nail-free glue and preparation method thereof, comprise rubber elastomer, solvent misture, reinforcer, thixotropic agent, solvent, antioxidant, environmentally friendly, easy to use, product adhesive strength is high, excellent durability, equally exists the opaque problem of colloid；201310436009.2 disclosed a kind of Environment-friendlynail-free nail-free glue for construction and preparation method thereof, polyvinyl acetate resin, reinforcer, solvent, thixotropic agent, coupling agent, plasticizer, dispersant is used to make, environmental friendliness, easy construction, bonding without nail, adhesive strength is high, and ageing-resistant performance is excellent, opaque because using common fillers equally.
As can be seen here, develop a kind of transparent nail-free glue and there is the biggest practicality and necessity.
Summary of the invention
The invention aims to overcome techniques as described above defect, it is provided that a kind of transparent nail-free glue, also provide the preparation method of above-mentioned nail-free glue simultaneously.
A kind of transparent nail-free glue of the present invention is achieved in that its formula proportioning includes:
High-molecular copolymer
10～25 parts
Transparent tacking agent
15～30 parts
Filler
5～15 parts
Thixotropic agent
5～15 parts
Compound stabilizer
0.5～2.5 part
Organic solvent
10～30 parts；
Described high-molecular copolymer is at least one in Oppanol, polyvinyl acetate, hydrogenated styrene block copolymers, at least one during wherein hydrogenated styrene block copolymers is SEBS, SEPS, SEEPS；
Described transparent tacking agent is at least one in rosin resin, terpene resin, tackifier AT-90X, hydrogenated petroleum resin, and wherein rosin resin, terpene resin, Ghana's look number of hydrogenated petroleum resin are 0#；
Described filler is at least one in cristobalite powder, nano-glass powder, transparent powder；
Described thixotropic agent is at least one in aerosil, organobentonite, and wherein the average particle size distribution of aerosil is 7～20nm, bentonite average particle size distribution < 76 μm；
Described compound stabilizer is hindered phenol antioxygen, carbon free radical scavenger and the mixture of light stabilizer composition, it is 0.5～2: 1～3: 0.5～2 by weight ratio, at least one during wherein hindered phenol antioxygen is antioxidant 1076, antioxidant 1098, antioxidant 245, carbon free radical scavenger is HP-136, light stabilizer is UV-292, in LS-770, hindered amine as light stabilizer 770 at least one；
Described organic solvent is at least one in hexamethylene, dimethoxym ethane, ethyl acetate, acetone, tetrachloro-ethylene.
The preparation method of described transparent nail-free glue, comprises the following steps:
By formulation weight part proportioning, being added by organic solvent in reactor, under stirring, add high-molecular copolymer, transparent tackifying resin, stir, add filler, thixotropic agent and compound stabilizer, stirring, to being completely dissolved, is filtered discharging, is obtained transparent nail-free glue.
A kind of transparent nail-free glue of the present invention has the advantage that
1. use the transparency preferably high-molecular copolymer and tackifier, both ensure that preferable cementability, and given again the transparency that nail-free glue is good, be widely portable to the occasion higher to colloid transparency requirement；
2. using high refractive index filler and high transparency thixotropic agent, colloid transparency is high, and thixotropy is good；
3. adding compound stabilizer, weatherability, ageing resistance and anti-ultraviolet property are all greatly improved.
Detailed description of the invention
The present invention will be described for following example, but the present invention is not limited to these examples system.Modifying the detailed description of the invention of the present invention or portion of techniques feature is carried out equivalent, without deviating from the spirit of the present invention program, it all should be contained in the middle of the technical scheme scope that the present invention is claimed.
Embodiment 1
By formulation weight part proportioning, by in hexamethylene 8 parts, dimethoxym ethane 1 part, 1 part of addition reactor of acetone, under stirring, add Oppanol 10 parts, rosin resin 10 parts, terpene resin 10 parts, hydrogenated petroleum resin 10 parts, stir, add cristobalite powder 15 parts, aerosil 15 parts, antioxidant 1076 0.125 part, HP-136 0.25 part, UV-292
0.125 part, stirring, to being completely dissolved, is filtered discharging, is obtained transparent nail-free glue.
Embodiment 2
By formulation weight part proportioning, by in hexamethylene 8 parts, 8 parts of acetone, 4 parts of addition reactors of tetrachloro-ethylene, under stirring, add polyvinyl acetate 20 parts, rosin resin 8 parts, tackifier AT-90X 8 parts, hydrogenated petroleum resin 4 parts, stir, add 5 parts of nano-glass powder, aerosil 10 parts, 1,098 0.4 parts of antioxidant, HP-136 0.2 part, LS-770
0.4 part, stirring, to being completely dissolved, is filtered discharging, is obtained transparent nail-free glue.
Embodiment 3
By formulation weight part proportioning, by in hexamethylene 10 parts, dimethoxym ethane 2 parts, 8 parts of ethyl acetate, 10 parts of addition reactors of tetrachloro-ethylene, under stirring, add SEBS 25 parts, rosin resin 7 parts, terpene resin 4 parts, tackifier AT-90X 4 parts, stirring, add transparent powder 10 parts, organobentonite BP-186B 5 parts, 245 0.7 parts of antioxidant, HP-136 1.7 parts, hindered amine as light stabilizer 770 0.7 parts, stirring is to being completely dissolved, filter discharging, obtain transparent nail-free glue.
Comparative example 4
By formulation weight part proportioning, by in hexamethylene 8 parts, 8 parts of acetone, 4 parts of addition reactors of tetrachloro-ethylene, under stirring, add polyvinyl acetate 20 parts, rosin resin 20 parts, stirring, add 15 parts of calcium carbonate, precipitated silica 10 parts, stirring is to being completely dissolved, filter discharging, obtain nail-free glue.
Embodiment 1～3, comparative example 4 nail-free glue correlated performance use following methods test:
1. the mensuration of non-volatile content: be measured according to the mensuration of standard GB/T 2793-1995 adhesive non-volatile content.
2. initial adhesive strength and the mensuration of tensile shear strength: take 2.5cm × 2.5cm birch plate 2 pieces, weighs glue about 0.05g, is spread evenly across one end 2.5cm × 2.0cm of smooth front plate, another block is not coated with, after being overlapped by two boards, being placed in the fixture of fixation pressure, room temperature places 5min.Pressure relief, ambient temperatare sets to 0 .5h, carries out initial adhesive strength test with puller system；After sample is at room temperature placed 24h, carry out tensile shear strength test with puller system.
3. transparency measures: nail-free glue is made the uniform test piece that thickness is 6mm, uses transparency meter to test, and measured value is within 0～100, and 0 represents fully transparent, and 100 represent the opaquest.
Embodiment 1～3, comparative example 4 gained the correlated performance test result of a kind of nail-free glue as shown in table 1 below.
Table 1
As can be seen from the above table, a kind of transparent nail-free glue of the present invention is compared with prior art (comparative example 4), and adhesive property is good, and transparency properties is excellent.
Main material
1. Oppanol, polyvinyl acetate, SEBS(styrene-ethylene-butylene-styrene block copolymer), SEPS(styrene ethylene-propylene-styrene type block copolymer), SEEPS(styrene-[ethene-(ethylene-propylene)]-styrene block copolymer), commercially available, technical grade；
2. rosin resin
Model: CY-RL90
Supplier: state-run Wuming County is towards swallow forest farm rosin factory；
3. terpene resin
Model: TR95-106
Supplier: the upper emerging Industrial Co., Ltd. of seawater；
4. hydrogenated petroleum resin
Model: Regalite-S5090
Supplier: the upper emerging Industrial Co., Ltd. of seawater；
5. tackifier AT-90X
Softening point (ring and ball method, DEG C): 88～93 colourities :≤2
Supplier: the upper emerging Industrial Co., Ltd. of seawater；
6. cristobalite powder
Supplier: the East Sea, Lianyun Harbour Fu Cai mineral article Co., Ltd；
7. nano-glass powder
Supplier: Xi Li Chemical Co., Ltd. of Foshan City；
8. transparent powder
Supplier: Shunde District of Foshan City Yu Feng powder body material Co., Ltd；
9. organobentonite
Model: BP-186B, BP-186D
Supplier: Zhejiang Ward industry group；
10. antioxidant 1076
Supplier: Tianjin Zhong Xinkaitai Chemical Co., Ltd.；
11. antioxidant 1098
Supplier: bright Chemical Co., Ltd. of Nanjing Holley；
12. antioxidant 245
Supplier: Hubei Ju Sheng Science and Technology Ltd.；
13.HP-136
Supplier: Yuyao City Ou Li plastifies Co., Ltd；
14.UV-292
Supplier: new Yuhua Import and Export Co., Ltd. of Changshu City；
15.LS-770
Supplier: Xiangfan City's gold is translated into Fine Chemical Co., Ltd；
16. hindered amine as light stabilizer 770
Supplier: Nangong City Sheng Hua chemical industry Co., Ltd.
Claims (1)
1. a transparent nail-free glue, it is characterised in that each component includes by weight ratio:
High-molecular copolymer
10～25 parts
Transparent tacking agent
15～30 parts
Filler
5～15 parts
Thixotropic agent
5～15 parts
Compound stabilizer
0.5～2.5 part
Organic solvent
10～30 parts；
Wherein said high-molecular copolymer is Oppanol；Described transparent tacking agent is at least one in rosin resin, terpene resin, tackifier AT-90X, hydrogenated petroleum resin, and wherein rosin resin, terpene resin, Ghana's look number of hydrogenated petroleum resin are 0#；Described filler is at least one in cristobalite powder, nano-glass powder, transparent powder；Described organic solvent is at least one in hexamethylene, dimethoxym ethane, ethyl acetate, acetone, tetrachloro-ethylene；Described thixotropic agent is at least one in aerosil, organobentonite, and wherein the average particle size distribution of aerosil is 7～20nm, bentonite average particle size distribution < 76 μm；Described compound stabilizer is hindered phenol antioxygen, carbon free radical scavenger and the mixture of light stabilizer composition, it is 0.5～2:1～3:0.5～2 by weight ratio, at least one during wherein hindered phenol antioxygen is antioxidant 1076, antioxidant 1098, antioxidant 245, carbon free radical scavenger is HP-136, light stabilizer is UV-292, in LS-770, hindered amine as light stabilizer 770 at least one；Described preparation method comprises the following steps: by formulation weight part proportioning, organic solvent is added in reactor, under stirring, add high-molecular copolymer, transparent tackifying resin, stirring, add filler, thixotropic agent and compound stabilizer, stirring is to being completely dissolved, filter discharging, obtain transparent nail-free glue.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410581479.2A CN104293244B (en) | 2014-10-27 | 2014-10-27 | A kind of transparent nail-free glue and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410581479.2A CN104293244B (en) | 2014-10-27 | 2014-10-27 | A kind of transparent nail-free glue and preparation method thereof |
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| CN104293244B true CN104293244B (en) | 2016-09-07 |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106753094B (en) * | 2016-12-29 | 2018-11-16 | 台州密得邦粘合材料有限公司 | A kind of aqueous high-strength nail-free glue |
| CN107189718A (en) * | 2017-07-07 | 2017-09-22 | 滁州隆扬农业科技有限公司 | A kind of environmentally friendly nail-free glue for building and preparation method thereof |
| CN112409955A (en) * | 2019-08-20 | 2021-02-26 | 广东顺德三和化工有限公司 | Nail-free glue and preparation method thereof |
| CN115851188B (en) * | 2022-11-21 | 2024-07-09 | 广州立邦涂料有限公司 | Solvent type nail-free adhesive and preparation method and application thereof |
| CN117567962B (en) * | 2024-01-16 | 2024-03-26 | 汕头市炜星工艺实业有限公司 | High-strength high-toughness adhesive, preparation method thereof and application thereof in paper product processing |
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| CN103484040B (en) * | 2013-09-22 | 2016-04-06 | 哥俩好新材料股份有限公司 | A kind of Environment-friendlynail-free nail-free glue for construction and preparation method thereof |
| CN103484043B (en) * | 2013-09-22 | 2015-12-23 | 哥俩好新材料股份有限公司 | A kind of environmental-protection decorative nail-free glue and preparation method thereof |
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Effective date of registration: 20170330 Address after: 528325 Guangdong City, Shunde Province, the town of District, Foshan Ji industrial zone, South Road, No. 4 Patentee after: Shunde Guangdong Three Chemical Co., Ltd. Address before: 528429 Zhongshan Province, Huang Town, the town of large industrial park into the road, No. 43, No. Patentee before: Guangdong Sanhe Chemical Industry Technology Co., Ltd. |
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