CN101267797B - 包含凝胶网络的洗发剂 - Google Patents
包含凝胶网络的洗发剂 Download PDFInfo
- Publication number
- CN101267797B CN101267797B CN2006800341372A CN200680034137A CN101267797B CN 101267797 B CN101267797 B CN 101267797B CN 2006800341372 A CN2006800341372 A CN 2006800341372A CN 200680034137 A CN200680034137 A CN 200680034137A CN 101267797 B CN101267797 B CN 101267797B
- Authority
- CN
- China
- Prior art keywords
- shampoo composition
- gel network
- sulfate
- shampoo
- surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002453 shampoo Substances 0.000 title claims abstract description 146
- 239000000203 mixture Substances 0.000 claims abstract description 211
- 239000004094 surface-active agent Substances 0.000 claims abstract description 91
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 77
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 47
- 238000002844 melting Methods 0.000 claims abstract description 41
- 230000008018 melting Effects 0.000 claims abstract description 41
- 230000007704 transition Effects 0.000 claims abstract description 38
- 238000000034 method Methods 0.000 claims abstract description 18
- 238000002156 mixing Methods 0.000 claims abstract description 15
- 239000008365 aqueous carrier Substances 0.000 claims abstract description 11
- 238000005192 partition Methods 0.000 claims abstract description 3
- 230000003750 conditioning effect Effects 0.000 claims description 35
- 239000003795 chemical substances by application Substances 0.000 claims description 22
- 239000002245 particle Substances 0.000 claims description 17
- 229920000642 polymer Polymers 0.000 claims description 15
- -1 Lauryl Sulfate Diethanolamine Sulfate Chemical compound 0.000 claims description 14
- 230000008021 deposition Effects 0.000 claims description 12
- 229920006317 cationic polymer Polymers 0.000 claims description 10
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 claims description 10
- 229920001296 polysiloxane Polymers 0.000 claims description 10
- 239000000375 suspending agent Substances 0.000 claims description 10
- 238000000113 differential scanning calorimetry Methods 0.000 claims description 9
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 8
- 239000003205 fragrance Substances 0.000 claims description 8
- 208000001840 Dandruff Diseases 0.000 claims description 7
- 239000003945 anionic surfactant Substances 0.000 claims description 5
- 229960000735 docosanol Drugs 0.000 claims description 5
- 239000003906 humectant Substances 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 229940057950 sodium laureth sulfate Drugs 0.000 claims description 5
- 229930003231 vitamin Natural products 0.000 claims description 5
- 235000013343 vitamin Nutrition 0.000 claims description 5
- 239000011782 vitamin Substances 0.000 claims description 5
- 229940088594 vitamin Drugs 0.000 claims description 5
- 150000001413 amino acids Chemical class 0.000 claims description 3
- BTFJIXJJCSYFAL-UHFFFAOYSA-N arachidyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 3
- 229920000881 Modified starch Polymers 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- 235000019426 modified starch Nutrition 0.000 claims description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims 4
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 claims 4
- LIFHMKCDDVTICL-UHFFFAOYSA-N 6-(chloromethyl)phenanthridine Chemical compound C1=CC=C2C(CCl)=NC3=CC=CC=C3C2=C1 LIFHMKCDDVTICL-UHFFFAOYSA-N 0.000 claims 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 2
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 claims 2
- 229940063953 ammonium lauryl sulfate Drugs 0.000 claims 2
- QVBODZPPYSSMEL-UHFFFAOYSA-N dodecyl sulfate;2-hydroxyethylazanium Chemical compound NCCO.CCCCCCCCCCCCOS(O)(=O)=O QVBODZPPYSSMEL-UHFFFAOYSA-N 0.000 claims 2
- 229940069822 monoethanolamine lauryl sulfate Drugs 0.000 claims 2
- 229910052700 potassium Inorganic materials 0.000 claims 2
- 239000011591 potassium Substances 0.000 claims 2
- ONQDVAFWWYYXHM-UHFFFAOYSA-M potassium lauryl sulfate Chemical compound [K+].CCCCCCCCCCCCOS([O-])(=O)=O ONQDVAFWWYYXHM-UHFFFAOYSA-M 0.000 claims 2
- 229940116985 potassium lauryl sulfate Drugs 0.000 claims 2
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 claims 1
- CYPKANIKIWLVMF-UHFFFAOYSA-N 2-[(2-oxo-3,4-dihydro-1h-quinolin-5-yl)oxy]acetic acid Chemical compound N1C(=O)CCC2=C1C=CC=C2OCC(=O)O CYPKANIKIWLVMF-UHFFFAOYSA-N 0.000 claims 1
- BMYCCWYAFNPAQC-UHFFFAOYSA-N 2-[dodecyl(methyl)azaniumyl]acetate Chemical compound CCCCCCCCCCCCN(C)CC(O)=O BMYCCWYAFNPAQC-UHFFFAOYSA-N 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- 244000037364 Cinnamomum aromaticum Species 0.000 claims 1
- 235000014489 Cinnamomum aromaticum Nutrition 0.000 claims 1
- 244000007835 Cyamopsis tetragonoloba Species 0.000 claims 1
- 108010077895 Sarcosine Proteins 0.000 claims 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims 1
- PSXQIPIUCAJREC-UHFFFAOYSA-M [Na+].OS(=O)(=O)c1ccccc1.CCCCCCCCCCCCOS([O-])(=O)=O Chemical compound [Na+].OS(=O)(=O)c1ccccc1.CCCCCCCCCCCCOS([O-])(=O)=O PSXQIPIUCAJREC-UHFFFAOYSA-M 0.000 claims 1
- JWTLFOISPSJINB-UHFFFAOYSA-L disodium tridecylbenzene sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCCc1ccccc1 JWTLFOISPSJINB-UHFFFAOYSA-L 0.000 claims 1
- OXVXWUDYARFPLN-UHFFFAOYSA-N ethylazanium;hydron;sulfate Chemical compound CC[NH3+].OS([O-])(=O)=O OXVXWUDYARFPLN-UHFFFAOYSA-N 0.000 claims 1
- BOUCRWJEKAGKKG-UHFFFAOYSA-N n-[3-(diethylaminomethyl)-4-hydroxyphenyl]acetamide Chemical compound CCN(CC)CC1=CC(NC(C)=O)=CC=C1O BOUCRWJEKAGKKG-UHFFFAOYSA-N 0.000 claims 1
- 229960003975 potassium Drugs 0.000 claims 1
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 claims 1
- 229940079776 sodium cocoyl isethionate Drugs 0.000 claims 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 claims 1
- 229940082004 sodium laurate Drugs 0.000 claims 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 claims 1
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 claims 1
- 229940079862 sodium lauryl sarcosinate Drugs 0.000 claims 1
- 239000000499 gel Substances 0.000 description 125
- 239000012071 phase Substances 0.000 description 71
- 210000004209 hair Anatomy 0.000 description 58
- OYINQIKIQCNQOX-UHFFFAOYSA-M 2-hydroxybutyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCC(O)C[N+](C)(C)C OYINQIKIQCNQOX-UHFFFAOYSA-M 0.000 description 22
- 210000003491 skin Anatomy 0.000 description 20
- 230000008901 benefit Effects 0.000 description 15
- 239000004615 ingredient Substances 0.000 description 13
- 239000002904 solvent Substances 0.000 description 13
- 239000000126 substance Substances 0.000 description 11
- 125000004432 carbon atom Chemical group C* 0.000 description 10
- 125000002091 cationic group Chemical group 0.000 description 10
- 239000007787 solid Substances 0.000 description 10
- 239000000047 product Substances 0.000 description 9
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 244000303965 Cyamopsis psoralioides Species 0.000 description 7
- 150000001298 alcohols Chemical class 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 6
- 125000000129 anionic group Chemical group 0.000 description 6
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 6
- 210000004761 scalp Anatomy 0.000 description 6
- 239000002537 cosmetic Substances 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 229920002545 silicone oil Polymers 0.000 description 5
- GHOKWGTUZJEAQD-ZETCQYMHSA-N (D)-(+)-Pantothenic acid Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-ZETCQYMHSA-N 0.000 description 4
- QYYMDNHUJFIDDQ-UHFFFAOYSA-N 5-chloro-2-methyl-1,2-thiazol-3-one;2-methyl-1,2-thiazol-3-one Chemical compound CN1SC=CC1=O.CN1SC(Cl)=CC1=O QYYMDNHUJFIDDQ-UHFFFAOYSA-N 0.000 description 4
- 229940100484 5-chloro-2-methyl-4-isothiazolin-3-one Drugs 0.000 description 4
- 239000013543 active substance Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 description 4
- 238000010348 incorporation Methods 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000003755 preservative agent Substances 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 4
- TYWMIZZBOVGFOV-UHFFFAOYSA-N tetracosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCO TYWMIZZBOVGFOV-UHFFFAOYSA-N 0.000 description 4
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 229940047662 ammonium xylenesulfonate Drugs 0.000 description 3
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 description 3
- 239000003093 cationic surfactant Substances 0.000 description 3
- 239000002738 chelating agent Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000284 extract Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- HESSGHHCXGBPAJ-UHFFFAOYSA-N n-[3,5,6-trihydroxy-1-oxo-4-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyhexan-2-yl]acetamide Chemical compound CC(=O)NC(C=O)C(O)C(C(O)CO)OC1OC(CO)C(O)C(O)C1O HESSGHHCXGBPAJ-UHFFFAOYSA-N 0.000 description 3
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- 210000002374 sebum Anatomy 0.000 description 3
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 3
- 239000004299 sodium benzoate Substances 0.000 description 3
- 235000010234 sodium benzoate Nutrition 0.000 description 3
- YBJHBAHKTGYVGT-ZKWXMUAHSA-N (+)-Biotin Chemical compound N1C(=O)N[C@@H]2[C@H](CCCCC(=O)O)SC[C@@H]21 YBJHBAHKTGYVGT-ZKWXMUAHSA-N 0.000 description 2
- MRAMPOPITCOOIN-VIFPVBQESA-N (2r)-n-(3-ethoxypropyl)-2,4-dihydroxy-3,3-dimethylbutanamide Chemical compound CCOCCCNC(=O)[C@H](O)C(C)(C)CO MRAMPOPITCOOIN-VIFPVBQESA-N 0.000 description 2
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- GHOKWGTUZJEAQD-UHFFFAOYSA-N Chick antidermatitis factor Natural products OCC(C)(C)C(O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-UHFFFAOYSA-N 0.000 description 2
- SNPLKNRPJHDVJA-ZETCQYMHSA-N D-panthenol Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCCO SNPLKNRPJHDVJA-ZETCQYMHSA-N 0.000 description 2
- 206010019049 Hair texture abnormal Diseases 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 2
- 241000282372 Panthera onca Species 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- 229930003316 Vitamin D Natural products 0.000 description 2
- QYSXJUFSXHHAJI-XFEUOLMDSA-N Vitamin D3 Natural products C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)CCCC(C)C)=C/C=C1\C[C@@H](O)CCC1=C QYSXJUFSXHHAJI-XFEUOLMDSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical compound NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 description 2
- 235000001014 amino acid Nutrition 0.000 description 2
- 229940024606 amino acid Drugs 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 229940069078 citric acid / sodium citrate Drugs 0.000 description 2
- 238000005352 clarification Methods 0.000 description 2
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 2
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000008278 cosmetic cream Substances 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 238000011067 equilibration Methods 0.000 description 2
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 description 2
- 150000002194 fatty esters Chemical class 0.000 description 2
- 239000003324 growth hormone secretagogue Substances 0.000 description 2
- 230000003779 hair growth Effects 0.000 description 2
- IRHTZOCLLONTOC-UHFFFAOYSA-N hexacosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCO IRHTZOCLLONTOC-UHFFFAOYSA-N 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- VAMFXQBUQXONLZ-UHFFFAOYSA-N icos-1-ene Chemical compound CCCCCCCCCCCCCCCCCCC=C VAMFXQBUQXONLZ-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000003020 moisturizing effect Effects 0.000 description 2
- CNNRPFQICPFDPO-UHFFFAOYSA-N octacosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCO CNNRPFQICPFDPO-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229940101267 panthenol Drugs 0.000 description 2
- 229940055726 pantothenic acid Drugs 0.000 description 2
- 235000019161 pantothenic acid Nutrition 0.000 description 2
- 239000011713 pantothenic acid Substances 0.000 description 2
- 235000020957 pantothenol Nutrition 0.000 description 2
- 239000011619 pantothenol Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- LXNHXLLTXMVWPM-UHFFFAOYSA-N pyridoxine Chemical compound CC1=NC=C(CO)C(CO)=C1O LXNHXLLTXMVWPM-UHFFFAOYSA-N 0.000 description 2
- 235000013599 spices Nutrition 0.000 description 2
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 2
- APJYDQYYACXCRM-UHFFFAOYSA-N tryptamine Chemical compound C1=CC=C2C(CCN)=CNC2=C1 APJYDQYYACXCRM-UHFFFAOYSA-N 0.000 description 2
- 235000019166 vitamin D Nutrition 0.000 description 2
- 239000011710 vitamin D Substances 0.000 description 2
- 229940046008 vitamin d Drugs 0.000 description 2
- 239000002888 zwitterionic surfactant Substances 0.000 description 2
- WTVHAMTYZJGJLJ-UHFFFAOYSA-N (+)-(4S,8R)-8-epi-beta-bisabolol Natural products CC(C)=CCCC(C)C1(O)CCC(C)=CC1 WTVHAMTYZJGJLJ-UHFFFAOYSA-N 0.000 description 1
- RGZSQWQPBWRIAQ-CABCVRRESA-N (-)-alpha-Bisabolol Chemical compound CC(C)=CCC[C@](C)(O)[C@H]1CCC(C)=CC1 RGZSQWQPBWRIAQ-CABCVRRESA-N 0.000 description 1
- OMDQUFIYNPYJFM-XKDAHURESA-N (2r,3r,4s,5r,6s)-2-(hydroxymethyl)-6-[[(2r,3s,4r,5s,6r)-4,5,6-trihydroxy-3-[(2s,3s,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]methoxy]oxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@H](O)[C@H](O)O1 OMDQUFIYNPYJFM-XKDAHURESA-N 0.000 description 1
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- 229960002666 1-octacosanol Drugs 0.000 description 1
- 229940094997 1-tetracosanol Drugs 0.000 description 1
- FPIPGXGPPPQFEQ-UHFFFAOYSA-N 13-cis retinol Natural products OCC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-UHFFFAOYSA-N 0.000 description 1
- DWHIUNMOTRUVPG-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-(2-dodecoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCO DWHIUNMOTRUVPG-UHFFFAOYSA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- NJLKZOZYTRRDBO-UHFFFAOYSA-N 3-iodopropyl n-butylcarbamate Chemical compound CCCCNC(=O)OCCCI NJLKZOZYTRRDBO-UHFFFAOYSA-N 0.000 description 1
- POJWUDADGALRAB-PVQJCKRUSA-N Allantoin Natural products NC(=O)N[C@@H]1NC(=O)NC1=O POJWUDADGALRAB-PVQJCKRUSA-N 0.000 description 1
- 241001116389 Aloe Species 0.000 description 1
- DCXYFEDJOCDNAF-UHFFFAOYSA-N Asparagine Natural products OC(=O)C(N)CC(N)=O DCXYFEDJOCDNAF-UHFFFAOYSA-N 0.000 description 1
- 239000001884 Cassia gum Substances 0.000 description 1
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 241000694440 Colpidium aqueous Species 0.000 description 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
- 239000001692 EU approved anti-caking agent Substances 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000005770 Eugenol Substances 0.000 description 1
- 229920000926 Galactomannan Polymers 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- BIVBRWYINDPWKA-VLQRKCJKSA-L Glycyrrhizinate dipotassium Chemical compound [K+].[K+].O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@H]1CC[C@]2(C)[C@H]3C(=O)C=C4[C@@H]5C[C@](C)(CC[C@@]5(CC[C@@]4(C)[C@]3(C)CC[C@H]2C1(C)C)C)C(O)=O)C([O-])=O)[C@@H]1O[C@H](C([O-])=O)[C@@H](O)[C@H](O)[C@H]1O BIVBRWYINDPWKA-VLQRKCJKSA-L 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 241000208680 Hamamelis mollis Species 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 229940124091 Keratolytic Drugs 0.000 description 1
- MLSJBGYKDYSOAE-DCWMUDTNSA-N L-Ascorbic acid-2-glucoside Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O[C@@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)=C1O MLSJBGYKDYSOAE-DCWMUDTNSA-N 0.000 description 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- DCXYFEDJOCDNAF-REOHCLBHSA-N L-asparagine Chemical compound OC(=O)[C@@H](N)CC(N)=O DCXYFEDJOCDNAF-REOHCLBHSA-N 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- HNDVDQJCIGZPNO-YFKPBYRVSA-N L-histidine Chemical compound OC(=O)[C@@H](N)CC1=CN=CN1 HNDVDQJCIGZPNO-YFKPBYRVSA-N 0.000 description 1
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 description 1
- OUYCCCASQSFEME-QMMMGPOBSA-N L-tyrosine Chemical compound OC(=O)[C@@H](N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-QMMMGPOBSA-N 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- 244000246386 Mentha pulegium Species 0.000 description 1
- 235000016257 Mentha pulegium Nutrition 0.000 description 1
- 235000004357 Mentha x piperita Nutrition 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- FPIPGXGPPPQFEQ-BOOMUCAASA-N Vitamin A Natural products OC/C=C(/C)\C=C\C=C(\C)/C=C/C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-BOOMUCAASA-N 0.000 description 1
- 229930003427 Vitamin E Natural products 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- UJNOLBSYLSYIBM-WISYIIOYSA-N [(1r,2s,5r)-5-methyl-2-propan-2-ylcyclohexyl] (2r)-2-hydroxypropanoate Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1OC(=O)[C@@H](C)O UJNOLBSYLSYIBM-WISYIIOYSA-N 0.000 description 1
- HGXHGHZOBLDERL-UHFFFAOYSA-N [NH4+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O Chemical compound [NH4+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O HGXHGHZOBLDERL-UHFFFAOYSA-N 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 1
- 229960000458 allantoin Drugs 0.000 description 1
- 230000000172 allergic effect Effects 0.000 description 1
- 235000011399 aloe vera Nutrition 0.000 description 1
- RGZSQWQPBWRIAQ-LSDHHAIUSA-N alpha-Bisabolol Natural products CC(C)=CCC[C@@](C)(O)[C@@H]1CCC(C)=CC1 RGZSQWQPBWRIAQ-LSDHHAIUSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229940083920 ammonium laureth-3 sulfate Drugs 0.000 description 1
- 229940035676 analgesics Drugs 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000000730 antalgic agent Substances 0.000 description 1
- 239000000058 anti acne agent Substances 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229940124340 antiacne agent Drugs 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 229940067599 ascorbyl glucoside Drugs 0.000 description 1
- 235000009582 asparagine Nutrition 0.000 description 1
- 229960001230 asparagine Drugs 0.000 description 1
- 239000003212 astringent agent Substances 0.000 description 1
- 208000010668 atopic eczema Diseases 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 235000020958 biotin Nutrition 0.000 description 1
- 239000011616 biotin Substances 0.000 description 1
- 229960002685 biotin Drugs 0.000 description 1
- 229940036350 bisabolol Drugs 0.000 description 1
- HHGZABIIYIWLGA-UHFFFAOYSA-N bisabolol Natural products CC1CCC(C(C)(O)CCC=C(C)C)CC1 HHGZABIIYIWLGA-UHFFFAOYSA-N 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 239000004067 bulking agent Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229940045824 c30-50 alcohols Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 235000019318 cassia gum Nutrition 0.000 description 1
- SVURIXNDRWRAFU-OGMFBOKVSA-N cedrol Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@@H]1[C@@](O)(C)CC2 SVURIXNDRWRAFU-OGMFBOKVSA-N 0.000 description 1
- 229940026455 cedrol Drugs 0.000 description 1
- PCROEXHGMUJCDB-UHFFFAOYSA-N cedrol Natural products CC1CCC2C(C)(C)C3CC(C)(O)CC12C3 PCROEXHGMUJCDB-UHFFFAOYSA-N 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 229960004106 citric acid Drugs 0.000 description 1
- 239000010634 clove oil Substances 0.000 description 1
- 238000003181 co-melting Methods 0.000 description 1
- 239000005515 coenzyme Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000008406 cosmetic ingredient Substances 0.000 description 1
- 239000003398 denaturant Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229940008099 dimethicone Drugs 0.000 description 1
- 229940101029 dipotassium glycyrrhizinate Drugs 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 150000004141 diterpene derivatives Chemical class 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000001493 electron microscopy Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000008387 emulsifying waxe Substances 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 239000010642 eucalyptus oil Substances 0.000 description 1
- 229940044949 eucalyptus oil Drugs 0.000 description 1
- 229960002217 eugenol Drugs 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 229930182830 galactose Natural products 0.000 description 1
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 230000003370 grooming effect Effects 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 239000008266 hair spray Substances 0.000 description 1
- 239000013003 healing agent Substances 0.000 description 1
- HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 235000001050 hortel pimenta Nutrition 0.000 description 1
- 229960004337 hydroquinone Drugs 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000002198 insoluble material Substances 0.000 description 1
- 229920000831 ionic polymer Polymers 0.000 description 1
- SVURIXNDRWRAFU-UHFFFAOYSA-N juniperanol Natural products C1C23C(C)CCC3C(C)(C)C1C(O)(C)CC2 SVURIXNDRWRAFU-UHFFFAOYSA-N 0.000 description 1
- 230000001530 keratinolytic effect Effects 0.000 description 1
- 239000003410 keratolytic agent Substances 0.000 description 1
- BEJNERDRQOWKJM-UHFFFAOYSA-N kojic acid Chemical compound OCC1=CC(=O)C(O)=CO1 BEJNERDRQOWKJM-UHFFFAOYSA-N 0.000 description 1
- 229960004705 kojic acid Drugs 0.000 description 1
- WZNJWVWKTVETCG-UHFFFAOYSA-N kojic acid Natural products OC(=O)C(N)CN1C=CC(=O)C(O)=C1 WZNJWVWKTVETCG-UHFFFAOYSA-N 0.000 description 1
- 238000002356 laser light scattering Methods 0.000 description 1
- 229940031674 laureth-7 Drugs 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 229960003511 macrogol Drugs 0.000 description 1
- 229940078752 magnesium ascorbyl phosphate Drugs 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 229930003658 monoterpene Natural products 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 238000000399 optical microscopy Methods 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940023735 panthenyl ethyl ether Drugs 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000003658 preventing hair loss Effects 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- FGVVTMRZYROCTH-UHFFFAOYSA-N pyridine-2-thiol N-oxide Chemical class [O-][N+]1=CC=CC=C1S FGVVTMRZYROCTH-UHFFFAOYSA-N 0.000 description 1
- 235000008160 pyridoxine Nutrition 0.000 description 1
- 239000011677 pyridoxine Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- VIDTVPHHDGRGAF-UHFFFAOYSA-N selenium sulfide Chemical compound [Se]=S VIDTVPHHDGRGAF-UHFFFAOYSA-N 0.000 description 1
- 229960005265 selenium sulfide Drugs 0.000 description 1
- 230000036332 sexual response Effects 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 231100000051 skin sensitiser Toxicity 0.000 description 1
- 238000000235 small-angle X-ray scattering Methods 0.000 description 1
- 229960002668 sodium chloride Drugs 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- CVPADSYHPKIYAH-UHFFFAOYSA-M sodium;docosyl sulfate Chemical compound [Na+].CCCCCCCCCCCCCCCCCCCCCCOS([O-])(=O)=O CVPADSYHPKIYAH-UHFFFAOYSA-M 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000000527 sonication Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 230000000699 topical effect Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- HTJNEBVCZXHBNJ-XCTPRCOBSA-H trimagnesium;(2r)-2-[(1s)-1,2-dihydroxyethyl]-3,4-dihydroxy-2h-furan-5-one;diphosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.OC[C@H](O)[C@H]1OC(=O)C(O)=C1O HTJNEBVCZXHBNJ-XCTPRCOBSA-H 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical group CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- 150000003648 triterpenes Chemical class 0.000 description 1
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 235000010374 vitamin B1 Nutrition 0.000 description 1
- 239000011691 vitamin B1 Substances 0.000 description 1
- 150000003710 vitamin D derivatives Chemical class 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- 229940011671 vitamin b6 Drugs 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 238000004736 wide-angle X-ray diffraction Methods 0.000 description 1
- 229940118846 witch hazel Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0295—Liquid crystals
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/042—Gels
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
- C11D3/2013—Monohydric alcohols linear fatty or with at least 8 carbon atoms in the alkyl chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Emergency Medicine (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Cosmetics (AREA)
Abstract
本发明公开了洗发剂组合物，所述洗发剂组合物包含：(a)按所述洗发剂组合物的重量计约5％至约50％的一种或多种去污表面活性剂；(b)分散的凝胶网络相，所述凝胶网络相包含按所述洗发剂组合物的重量计(i)至少约0.05％的一种或多种脂肪醇；(ii)至少约0.01％的一种或多种第二表面活性剂；和(iii)水；和(c)按所述洗发剂组合物的重量计至少约20％的含水载体，并且其中所述分散的凝胶网络相具有至少约38℃的熔融转变温度。本发明公开了一种制备洗发剂组合物的方法，所述方法包括以下步骤：(a)在足以使第二表面活性剂和水分配进脂肪醇中的温度下，混合脂肪醇、第二表面活性剂和水以形成预混物；(b)将该预混物冷却至脂肪醇的链熔融温度以下以形成凝胶网络；(c)将该凝胶网络加到一种或多种去污表面活性剂和含水载体中以形成洗发剂组合物，所述组合物包含具有至少约38℃的熔融转变温度的分散的凝胶网络相。
Description
发明领域
本发明涉及一种用于毛发清洁和护理的洗发剂组合物，所述组合物包含含有脂肪醇的分散的凝胶网络相。更具体地讲，本发明涉及上述洗发剂组合物，其中所述分散的凝胶网络相具有至少约38℃的熔融转变温度。
发明背景
由于与周围环境接触以及由于头皮分泌皮脂，人的毛发会变脏。毛发变脏会使其具有脏污感，并且看上去也不美观。变脏的毛发需要经常清洗。
洗发剂通过除去过量污垢和皮脂来清洁毛发。但是，洗发可使毛发处于潮湿、缠结和通常不易整理的状态。毛发变干后，由于除去了毛发的天然油脂以及其它天然调理和保湿成分，毛发经常处于干燥、蓬乱、无光泽或卷曲的状态。此外，干燥后的毛发上会留下更多的静电，会影响梳理并导致通常称为“飞散的毛发”的状况。
已经开发了各种缓解这些洗发后问题的方法。这些方法包括从在使用洗发剂之后使用毛发调理剂(如免洗型和洗去型产品)到试图用一种产品同时清洁和调理毛发的毛发调理洗发剂。
为了提供在清洁洗发剂基础上的毛发调理有益效果，人们已建议了多种调理活性物质。然而，许多这些活性物质具有使毛发具有脏污感或涂层感并影响洗发剂清洁功效的缺点。
已知洗发剂组合物中凝聚层的形成对于提供毛发调理有益效果是有利的。使用阳离子聚合物以形成凝聚层是本领域(例如在PCT公布WO93/08787和WO 95/01152中)已知的。然而，这些洗发剂组合物对于递送湿发调理是好的，但不能够递送令人满意的干发光滑感。
基于前文所述，需要这样一种调理洗发剂，其能够对干发提供改善的调理有益效果，同时既不影响清洁功效，也不在它干燥时对毛发提供负面感觉。具体地讲，存在如下需求，即当毛发干燥时向其提供长效保湿感觉、平滑感觉和整理性控制而不使毛发感觉油腻，而当毛发湿润时提供柔软性和易梳理性。
最近，已建议使用包含分散的脂肪醇凝胶网络相的洗发剂组合物，以在不影响清洁功效的情况下获得改善的润湿感和干调理有益效果。在上述洗发剂组合物中，所述脂肪醇是固态结晶凝胶网络相的形式，其意味着所述脂肪醇以多层囊泡及层片状排列于所述分散相中。据信，所述凝胶网络的该物理结构允许所述脂肪醇以片状沉积在毛发上，以所述脂肪醇分子的脂肪末端远离毛发的方式排列，并且形成低摩擦表面，这有助于改善调理有益效果。对于用于上述洗发剂组合物，授予Wells等人(“Wells”)的U.S.2003/0223952 A1公开了具有约16至约18个碳原子的脂肪醇是最优选的。另外，Wells举例说明了只包含鲸蜡(即，C16)醇和硬脂(即，C18)醇组合的洗发剂组合物。
尽管该方法通常导致获得所述有益效果，但现已发现与如Wells所公开优选的且举例说明的那些洗发剂组合物相比，包含分散的脂肪醇凝胶网络相的洗发剂组合物在标准的物理稳定性方案下是最为储存稳定的，并且还令人惊讶地递送极好的干调理有益效果，其中所述分散的脂肪醇凝胶网络相具有至少约38℃的熔融转变温度。
发明概述
本发明涉及一种洗发剂组合物，该组合物包括：(a)按所述洗发剂组合物的重量计约5％至约50％的一种或多种去污表面活性剂；(b)分散的凝胶网络相，其包含：(i)按所述洗发剂组合物的重量计至少约0.05％的一种或多种脂肪醇，(ii)按所述洗发剂组合物的重量计至少约0.01％的一种或多种第二表面活性剂；和(iii)水；以及(c)按所述洗发剂组合物的重量计至少约20％的含水载体；其中所述分散的凝胶网络相依照差示扫描量热法测量具有至少约38℃的熔融转变温度。
本发明还涉及一种制备上述洗发剂组合物的方法。
本发明还涉及一种使用上述洗发剂组合物的方法。
对于本领域的技术人员来说，通过阅读本说明书的公开内容，本发明的这些和其它特征、方面和优点将变得显而易见。
发明详述
虽然本说明书通过特别指出并清楚地要求保护本发明的权利要求作出结论，但应该相信由下列说明可更好地理解本发明。
除非另外指明，所有的百分比、份数和比率均按本发明组合物的总重量计。有关所列成分的所有重量均基于活性物质的含量，因此除非另外指明，不包括可能包括在市售原料中的溶剂或副产物。本文中，术语“重量百分比”可表示为“wt.％”。
除非另外指明，本发明中所用的所有分子量均为重均分子量，以克/摩尔表示。
本文所用术语“电荷密度”是指聚合物上的正电荷数与所述聚合物的分子量的比率。
本文中“包括”是指可加入不影响最终结果的其它步骤和成分。此术语包括术语“由...组成”和“基本上由...组成”。本发明组合物和方法/过程可包括、由和基本上由本文所述的本发明基本元素和限制以及本文所述的任何附加或任选成分、组分、步骤或限制所组成。
本文所用术语“聚合物”应包括通过一种类型单体或两种类型单体(即共聚物)或更多种类型的单体的聚合而制得的物质。
本文所用术语“洗发剂”是指用于清洁和调理毛发或皮肤(包括头皮、面部和身体)的组合物。
本文所用术语“适于施用到人的毛发上”是指所描述的组合物或其组分适合与人类毛发、头皮和皮肤接触而没有不当的毒性、不相容性、不稳定性、变应性反应等。
本文所用术语“水溶性的”是指所述物质溶于本发明的组合物的水中。通常，25℃时所述物质应以按水溶剂的重量计0.1％，优选以1％，更优选以5％，最优选以15％的浓度溶于水中。
本发明所述洗发剂组合物包含一种或多种去污表面活性剂、分散的凝胶网络相和含水载体，所述凝胶网络相具有至少约38℃的熔融转变温度。下文详述了这些基本组件中的每一个以及优选或任选的组件。
A.去污表面活性剂
本发明的洗发剂组合物包含一种或多种去污表面活性剂。所述去污表面活性剂组分被包括在本发明的洗发剂组合物中以提供清洁性能。所述去污表面活性剂可选自阴离子去污表面活性剂、两性离子或两性去污表面活性剂、或它们的组合。这些表面活性剂应与本文所述的基本组分在物理和化学上是相容的，或换句话讲不应不适当地损害产品的稳定性、美观性或性能。
用于本文组合物的合适的阴离子去污表面活性剂组分包括已知用于毛发护理或其它个人护理清洁组合物中的那些。组合物中的阴离子表面活性剂组分的浓度应足以提供所需的清洁和起泡效果，并且按所述组合物的重量计通常为约5％至约50％，优选约8％至约30％，更优选约10％至约25％，甚至更优选约12％至约22％。
适合用于本文组合物中的两性离子或两性去污表面活性剂包括已知用于毛发护理或其它个人清洁组合物中的那些。上述两性去污表面活性剂的浓度优选在约0.5％至约20％，优选约1％至约10％的范围内。适宜的两性离子或两性表面活性剂的非限制性实例描述于授予Bolich Jr.等人的美国专利5,104,646和5,106,609中。
本发明的组合物还可包含附加的表面活性剂来与上文所述的阴离子去污表面活性剂组分组合使用。合适的附加表面活性剂包括阳离子和非离子表面活性剂。
适用于所述组合物中的其它阴离子、两性离子、两性、阳离子、非离子或任选的附加表面活性剂的非限制性实施例描述于McCutcheon的“Emulsifiers and Detergents”(1989年刊，M.C.Publishing Co.出版)和美国专利3,929,678、2,658,072、2,438,091和2,528,378中。
B.分散的凝胶网络相
本发明所述的洗发剂组合物包含含有一种或多种脂肪醇的分散的凝胶网络相。本发明选用脂肪醇或不同脂肪醇的混合物使得所述分散的凝胶网络相(即，作为掺入并分散于最终洗发剂组合物中的相)具有至少约38℃的熔融转变温度，所述凝胶网络相在下文中将更详细地描述。
所述分散的凝胶网络相包括在本发明的洗发剂组合物中以提供调理有益效果。如本文所用，术语“凝胶网络”是指层状或多孔的固体结晶相，其包含至少一种以下详细说明的脂肪醇、至少一种以下详细说明的第二表面活性剂、以及水或其它合适的溶剂。所述层状或多孔的相包含双层，其由包含脂肪醇和第二表面活性剂的第一层和包含水或其它合适溶剂的第二层交替组成。如本文所用，术语“固体结晶”是指层状或多孔相的结构，其在温度低于所述凝胶网络中层的熔融转变温度下形成，所述凝胶网络包含一种或多种脂肪醇，所述熔融转变温度为至少约27℃(即，约略高于室温)。所述熔融转变温度可通过差示扫描量热法测量，该方法在下文中描述。
为了澄清起见，至少27℃的所述熔融转变温度是指直接高于“固体结晶”定义的那部分，是与本发明洗发剂组合物所述分散的凝胶网络相所述熔融转变温度(至少约38℃)不同的数值。换言之，如上所述的层状或多孔相可以是固体结晶(即，至少27℃)，但是上述固体结晶层状多孔相未必是本发明所述洗发剂组合物分散的凝胶网络相(即，至少38℃)。
包含例如脂肪醇的凝胶网络已在化妆用霜膏和护发剂中使用多年。然而，这样的化妆用霜膏和护发剂典型包含非常低的量(即使含的话)的去污表面活性剂。因此，上述已知产品不向毛发或皮肤提供清洁和调理的组合。
一般来讲，凝胶网络还由G.M.Eccleston的“Functions of MixedEmulsifiers and Emulsifying Waxes in Dermatological Lotions and Creams”，Colloids and Surfaces A：Physiochem.and Eng.Aspects123-124(1997)169-182；和G.M Eccleston的“The Microstructure of SemisolidCreams”，Pharmacy International，第7卷，63-70(1986)所描述。
在本发明的一个实施例中，分散的凝胶网络相是预成形的。如本文所用，术语“预成形的”是指脂肪醇、第二表面活性剂、以及水或其它合适溶剂至少百分之五十的混合物，在被加入到洗发剂组合物的其它组分中时，基本上是固体结晶相。
依照本发明的该实例，将本发明的凝胶网络组分制备成单独的预混物，其在冷却后接着与去污表面活性剂和洗发剂组合物的其它组分混合。所述凝胶网络组分的制备更详细地描述于下文名称为“制备洗发剂组合物方法”的部分以及所述实施例中。
随后将冷却的和预成形的凝胶网络组分加至洗发剂组合物的其中组分(包括去污表面活性剂组分)中。不受理论的约束，据信将冷却的和预成形的凝胶网络组分与去污表面活性剂和洗发剂组合物的其它组分混合，使得在最终洗发剂组合物中形成充分平衡的层状分散体(ELD)。所述ELD是分散的层状或多孔相，其由预成形的凝胶网络组分与去污表面活性剂、水、以及洗发剂组合物中可能存在的其它任选组分(例如盐)充分平衡而产生。该平衡在预成形的凝胶网络组分与洗发剂组合物的其它组分混合后进行，并且在开始后约24小时之内有效地完成。其中形成ELD的洗发剂组合物为毛发提供改善的湿的和干的调理有益效果。此外，如果包含凝胶网络组分的组分(即脂肪醇和第二表面活性剂与水混合)作为单独的组分与洗发剂组合物的其它组分一起添加到一个混合步骤中，并且不作为单独冷却的预成形凝胶网络组分，所述ELD就不会形成。
为了澄清起见，如本文所用术语“ELD”是指与所述短语“分散的凝胶网络相”相同的本发明所述洗发剂组合物组分。因此，在依照本发明的洗发剂组合物中，所述ELD具有至少约38℃的熔融转变温度。
如上所述，所述ELD通过将冷却的和预成形的凝胶网络组分和所述去污表面活性剂以及所述洗发剂组合物的其它组分混合而形成。当所述ELD和预成形的凝胶网络组分都包含脂肪醇、第二表面活性剂和水一起以层状或多孔的固体结晶相的形式的时候，与所述预成形的凝胶网络组分的那些相比，在所述ELD某些物理特性之间存在差异。在与所述去污表面活性剂以及所述洗发剂组合物的其它组分混合之前，所述预成形的凝胶网络组分基本由脂肪醇、第二表面活性剂和水组成。在混合时，所述凝胶网络的层状结构充当模板，被溶胀并和所述去污表面活性剂以及所述洗发剂组合物的其它组分，如盐和香料平衡。因此，据信在所述预成形的凝胶网络组分和所述ELD之间某些物理特性的这些差异与迁移一致，例如，去污表面活性剂、盐和香料迁移至所述凝胶网络相。
例如，对于上述预成形的凝胶网络组分，参见下文“凝胶网络实施例4”中所述，通过差示扫描量热法测量，所述熔融转变温度约68.3℃。另外，通过小角X射线散射测量所述d-间距约31.8nm，而通过广角X射线衍射测量，所述脂肪醇链间距约0.41nm。在将所述预成形的凝胶网络组分与所述去污表面活性剂和所述洗发剂组合物的其它组分混合后，形成了所述ELD。参见下文“洗发剂实施例4”中所述，所述ELD具有约41.8℃较低的熔融转变温度和约9.0nm的较低的d-间距。值得注意地，所述脂肪醇链间距没有实质的变化，这表示所述脂肪醇链仍冻结在所述ELD中，恰如它们在所述预成形的凝胶网络组分中一样。
因此，凝胶网络在预混物和最终的洗发剂组合物中以ELD的形式存在可通过本领域技术人员已知的方法确认，如X射线分析、光学显微镜法、电子显微镜法、以及差示扫描量热法。下文描述了差示扫描量热法的方法。对于X射线分析方法，参见U.S.2006/0024256 A1。
在本发明的一个实施方案中，在所述洗发剂组合物(即，所述ELD)中分散的凝胶网络相的标度尺寸从约10nm至约500nm范围。在另一个实施方案中，在所述洗发剂组合物中分散的凝胶网络相的标度尺寸在约0.5μm至约10μm的范围内。在另一个实施方案中，在所述洗发剂组合物中分散的凝胶网络相的标度尺寸在约10μm至约150μm的范围内。
在所述洗发剂组合物中分散的凝胶网络相的标度尺寸的分布可使用Horiba型LA 910激光散射粒径分布分析仪(Horiba仪，Inc.IrvineCalifornia，USA)，用激光散射技术测量。本发明洗发剂组合物中的标度尺寸的分布可通过将1.75g的洗发剂组合物与30mL的3％NH4Cl、20mL的2％Na2HPO4·7H2O和10mL的1％月桂基聚氧乙烯醚-7混合以形成混合物来测量。然后将该混合物搅拌5分钟。当合乎所用的单独的Horiba仪之时，取在1mL至40mL范围内，包含75mL的3％NH4Cl、50mL的2％Na2HPO4·7H2O和25mL的1％月桂基聚氧乙烯醚-7的样本，然后注入到Horiba仪中，直至所述Horiba仪读数在88％T至92％T之间，标度尺寸测量所必须的时候。一旦获得该读数，2分钟循环经过Horiba仪后开始进行测量，以提供所述标度尺寸量度。使用所述洗发剂组合物的样本进行后续测量，所述样本被在存在于洗发剂组合物中所有脂肪物质的熔融转变温度以上加热，使得所述凝胶网络组分熔融。该后续的测量允许进行所述洗发剂中所有剩余物质的标度尺寸分布，然后可以与最初的样本的标度尺寸分布比较并参与分析。
本发明的洗发剂组合物包含分散的脂肪醇凝胶网络相(即，所述ELD相)的量，按所述洗发剂组合物重量计大于约0.1％，优选为约1％至约60％，并且更优选为约5％至约40％。
1.脂肪醇
本发明的凝胶网络组分包含至少一种脂肪醇。可选择单独的脂肪醇化合物或两个或更多个不同的脂肪醇化合物的组合，前提条件是以所述ELD的形式所得的分散的凝胶网络相(即，作为掺入并分散到最终洗发剂组合物中的相)，依照差示扫描量热法测量，具有至少约38℃的熔融转变温度。所述熔融转变温度将在下文中更详细地论述。
适用于本发明的脂肪醇是具有约18至约70个碳原子的那些，并且在一个实施方案中，为约18至约60个碳原子，在另一个实施方案中为约18至约50个碳原子，在另一个实施方案中为约18至约40个碳原子，并且在另一个实施方案中为约18至约22个碳原子。这些脂肪醇可以为直链或支链醇，并且可以为饱和或不饱和的。合适的脂肪醇的非限制性实例包括硬脂醇、二十烷醇、二十二醇、C21脂肪醇(1-二十一醇)、C23脂肪醇(1-二十三醇)、C24脂肪醇(二十四烷醇、1-二十四烷醇)、C26脂肪醇(1-二十六醇)、C28脂肪醇(1-二十八醇)、C30脂肪醇(1-三十烷醇)、C20-40醇(例如，Performacol 350和425醇，得自New PhaseTechnologies)、C30-50醇(例如，Performacol 550醇)、C40-60醇(例如，Performacol 700醇)、以及它们的混合物。
包含一种或多种具有约18至约70个碳原子的脂肪醇的不同脂肪醇的混合物还可包含相当量的一种或多种脂肪醇，或其它具有少于约18个碳原子或大于约70个碳原子的脂肪两亲物也被认为是在本发明的范围内，前提条件是所得的分散的凝胶网络相具有至少约38℃的熔融转变温度。
上述适用于本发明的脂肪醇可以是天然或蔬菜来源，或它们可以是合成来源。
本发明的洗发剂组合物包含作为分散的凝胶网络相一部分的脂肪醇，其含量为按所述洗发剂组合物的重量计约0.05％至约14％，优选约0.5％至约10％，并且更优选约1％至约8％。
在本发明的一个实施方案中，凝胶网络组分中的脂肪醇对第二表面活性剂的重量比率大于约1∶9，优选大于约1∶5至约100∶1，更优选大于约1∶1至约50∶1。
2.分散的凝胶网络相熔融转变温度
依照本发明，所述分散的凝胶网络相依照差示扫描量热法测量具有至少约38℃的熔融转变温度。在一个实施方案中，所述分散的凝胶网络相具有约38℃至约80℃的熔融转变温度。在另一个实施方案中，所述分散的凝胶网络相具有约40℃至约60℃的熔融转变温度。在另一个实施方案中，所述分散的凝胶网络相具有约40℃至约55℃的熔融转变温度。在另一个实施方案中，所述分散的凝胶网络相具有约40℃至约50℃的熔融转变温度。
据信，在本发明所述洗发剂组合物中，一种或多种脂肪醇的使用导致具有至少约38℃的熔融转变温度的分散的凝胶网络相的形成。与包含具有低于约38℃的熔融转变温度的分散凝胶网络的洗发剂组合物相比，在有助于改善所述洗发剂组合物物理稳定性的同时，还令人惊奇地递送极好的干调理有益效果。
如上所述，合适的脂肪醇或不同脂肪醇混合物的选择提供了所得的具有至少约38℃的熔融转变温度的分散的凝胶网络相。另外，某些第二表面活性剂的选择可有助于获得至少约38℃的熔融转变温度的所得的分散的凝胶网络相。
可使用依照下列方法的差示扫描量热法获得分散的凝胶网络相的所述熔融转变温度。利用TA Instruments Q100 DSC，将大约50mg的凝胶网络预混物或包含凝胶网络的最终洗发剂组合物置于不锈钢高容积DSC中。将样本和空的参照盘一起置于仪器中。使用以下条件/温度程序分析样本：氮气吹扫，在5.00℃平衡，直至达到等温线2.00分钟。以3.00℃/min的速率使温度慢慢达到90.00℃。每个样本分析两次。所得的DSC数据使用TA Instruments Universal Analysis Software分析。
使用DSC测量凝胶网络的熔融过渡温度还由T.de Vringer等人的“Colloid and Polymer Science”第265卷，第448至457页(1987年)；和H.M.Ribeiro等人的“Intl.J.of Cosmetic Science”第26卷，第47至59页(2004年)所描述。
3.第二表面活性剂
本发明的凝胶网络组分还包含第二表面活性剂。如本文所用，“第二表面活性剂”是指一种或多种表面活性剂，其与脂肪醇和水混合以形成本发明的凝胶网络，作为预混物从洗发剂组合物的其它组分中分离出来。所述第二表面活性剂从洗发剂组合物中分离出来，并且除了洗发剂组合物中去污表面活性剂组分。然而，所述第二表面活性剂可以是相同或不同类型的表面活性剂，或者是如上所述的去污表面活性剂，或者选自以上所述的去污表面活性剂的那些。
本发明的洗发剂组合物包含作为预成形的分散的凝胶网络相一部分的第二表面活性剂，其含量按所述洗发剂组合物的重量计为约0.01％至约15％，优选约0.1％至约10％，并且更优选约0.3％至约5％。
合适的第二表面活性剂包括阴离子、两性离子、两性、阳离子和非离子表面活性剂。优选地，所述第二表面活性剂选自阴离子、阳离子和非离子表面活性剂、以及它们的混合物。对于适用于本发明的第二表面活性剂另外的论述参见U.S.2006/0024256 A1。
此外，在本发明的一个实施例中，可选择具有链长为约16至约22个碳原子的具有疏水尾部基团的某些第二表面活性剂，有助于获得具有至少约38℃的熔融转变温度的所得的分散的凝胶网络相。对于上述第二表面活性剂，所述疏水尾部基团可以是烷基、链烯基(包含最多3个双键)、烷基芳族或支链的烷基。在这样的实施例中，优选所述第二表面活性剂存在于所述凝胶网络组分中，相对于所述脂肪醇的重量比率为约1∶5至约5∶1。
不止一种以上指定类型的表面活性剂混合物可用作本发明的第二表面活性剂。
4.水或合适的溶剂
本发明的凝胶网络组分还包含水或合适的溶剂。水或合适的溶剂和第二表面活性剂一起有助于脂肪醇的溶胀。这继而导致凝胶网络的形成和稳定。如本文所用，术语“合适的溶剂”是指可用于本发明凝胶网络之中的任何溶剂，或者与水结合用于本发明凝胶网络的形成中的任何溶剂。
本发明的洗发剂组合物包含作为预成形的分散的凝胶网络相一部分的水或合适的溶剂，其量为当依照本发明与脂肪醇和第二表面活性剂组合时适合形成凝胶网络的量。
在一个优选的实施方案中，本发明的洗发剂组合物包含按所述洗发剂组合物的重量计至少约0.05％的作为预成形的分散的凝胶网络相一部分的水或合适的溶剂。
在本发明的另一个实施方案中，洗发剂组合物以相对于脂肪醇至少约1∶1的重量比率的量包含作为预成形的分散的凝胶网络相一部分的水或合适的溶剂。
C.含水载体
本发明的洗发剂组合物包含含水载体。本发明的组合物典型为可倾倒的液体形式(在环境条件下)。因此，所述组合物包含含水载体，其含量按所述组合物的重量计为约20％至约95％，优选约60％至约85％。含水载体可包含水，或水与有机溶剂的易混溶的混合物，但优选包含水和最少或浓度不大的有机溶剂，除了另外作为其它必要或任选组分的微量组分附带地掺入组合物中的那些。
D.附加组分
本发明的组合物还可包含一种或多种已知用于护发或个人护理产品的任选组分，前提条件是该任选组分与本文所述基本组分物理和化学地相容，或不会不适当地损害产品的稳定性、美观性或性能。这样的任选组分的各自的浓度按所述组合物的重量计可为约0.001％至约10％。
用于该组合物的任选组分的非限制性实施例包括阳离子聚合物、调理剂(烃油、脂肪族酯、硅氧烷)、去头屑剂、悬浮剂、粘度改性剂、染料、非挥发性溶剂或稀释剂(水溶性和不溶性的)、珠光助剂、泡沫促进剂、额外的表面活性剂或非离子助表面活性剂、灭虱剂、pH调节剂、香料、防腐剂、螯合剂、蛋白质、皮肤活性剂、防晒剂、紫外线吸收剂和维生素。
1.沉积助剂
本发明的洗发剂组合物可包含沉积助剂。包含沉积助剂以有效地增强凝胶网络组分的沉积。沉积助剂可包含任何可增强凝胶网络从洗发剂中沉积到毛发和/或头皮上的物质。
洗发剂组合物中沉积助剂的浓度应足以有效增强凝胶网络组分的沉积，并且其范围按所述洗发剂组合物重量计为约0.05％至约5％，优选约0.075％至约2.5％，更优选约0.1％至约1.0％。
在本发明的一个实施方案中，沉积助剂为阳离子聚合物。优选的阳离子聚合物所具有的阳离子电荷密度在所述组合物欲使用的pH下为至少约0.9meq/g，优选至少约1.2meq/g，更优选至少约1.5meq/g，但同时优选小于约7meq/g，更优选小于约5meq/g。所述pH的范围通常将为约pH3至约pH9，优选介于约pH4和约pH8之间。本文所用术语聚合物的“阳离子电荷密度”是指聚合物上的正电荷数与所述聚合物分子量的比率。上述适宜阳离子聚合物的平均分子量通常介于约10,000至1千万之间，优选为介于约50,000至约5百万之间，更优选为介于约100,000至约3百万之间。
适用于组合物的阳离子聚合物包括多糖聚合物，如阳离子纤维素衍生物和阳离子淀粉衍生物，如羟乙基纤维素与三甲基铵取代的环氧化物反应生成的盐。其它合适的阳离子聚合物包括阳离子瓜耳胶衍生物，如瓜耳羟丙基三甲基氯化铵。也合适的阳离子聚合物包括具有基于单体对单体的甘露糖与半乳糖比率大于2∶1的半乳甘露聚糖聚合物衍生物，如桂皮胶羟丙基三甲基氯化铵。
2.分散的颗粒
本发明组合物可以包括分散的颗粒。用于本发明中的颗粒原先可以是无机的、合成的或半合成的。如果存在于本发明的组合物中，所掺入的分散颗粒的量按所述组合物的重量计为约0.025％至约20％，优选约0.05％至约10％，更优选约0.1％至约5％，甚至更优选约0.25％至约3％，并且还更优选约0.5％至约2％。
3.非离子聚合物
具有的分子量大于约1000的聚亚烷基二醇可用于本发明。可用的是具有以下通式的那些：
其中R95选自H、甲基以及它们的混合物。可用于本发明的聚乙二醇聚合物是PEG-2M(也称为Polyox WSR N-10，作为PEG-2,000得自Union Carbide)、PEG-5M(也称为Polyox WSR N-35和Polyox WSRN-80，作为PEG-5,000和聚乙二醇300,000得自Union Carbide)、PEG-7M(也称为Polyox WSR N-750，得自Union Carbide)、PEG-9M(也称为Polyox WSR N-3333，得自Union Carbide)和PEG-14M(也称为WSRN-3000，得自Union Carbide)。
4.附加的调理剂
除了分散的凝胶网络相以外，本发明的组合物还可包含一种或多种调理剂。调理剂包括用于向毛发和/或皮肤提供特定调理有益效果的物质。用于本发明组合物中的调理剂典型包括水不溶性、水分散性、非挥发性、可形成乳化液体颗粒的液体。适用于所述组合物中的调理剂是通常以硅氧烷(如硅氧烷油、阳离子硅氧烷、硅橡胶纯胶料、高折射硅氧烷和硅氧烷树脂)、有机调理油(如烃油、聚烯烃和脂肪族酯)或它们组合为特征的那些调理剂，或是在含水表面活性剂基质中另外形成液态可分散颗粒的那些调理剂。
在一个实施方案中，本发明所述洗发剂组合物还包含非挥发性的硅氧烷油。对于一个不透明组合物的实施例，所述洗发剂组合物包含具有粒度为约1μm至约50μm的非挥发性的硅氧烷油，所述粒度在所述洗发剂组合物中测量。本发明的一个向毛发施用小颗粒的实施方案中，所述洗发剂组合物包含具有粒度为约100nm至约1μm的非挥发性的硅氧烷油，所述粒度在所述洗发剂组合物中测量。对于实际上澄清组合物的实施例，所述洗发剂组合物包含具有粒度小于约100nm的非挥发性的硅氧烷油，所述粒度在所述洗发剂组合物中测量。
当存在时，按所述组合物重量计，所述一种或多种调理剂的量为约0.01％至约10％，优选为约0.1％至约8％，更优选为约0.2％至约4％。
所述调理剂可以存在于所述的分散的凝胶网络相中或可以作为单独的组分添加至最终的洗发剂组合物中，使得它们主要存在于洗发剂的连续相中。
5.去头皮屑活性物质
本发明的组合物还可包含去头皮屑活性物质。去头皮屑活性物质的适宜非限制性实例包括吡啶硫酮盐、唑类、硫化硒、颗粒状硫、角质层分离剂、以及它们的混合物。上述去头皮屑活性物质应该在物理和化学上与组合物的基本组分相容，并且不会不适当地破坏产品的稳定性、美观性或性能。
当存在于所述组合物中时，去头皮屑活性物质的含量按所述组合物重量计为约0.01％至约5％，优选约0.1％至约3％，并且更优选约0.3％至约2％。
6.湿润剂
本发明的组合物可以包含湿润剂。本发明的湿润剂选自多元醇、水溶性烷氧基化非离子聚合物以及它们的混合物。当用于本文时，润湿剂优选地以按所述组合物的重量计约0.1％至约20％，更优选约0.5％至约5％的量存在。
7.悬浮剂
本发明的组合物还可以包含悬浮剂，悬浮剂的浓度有效用于将水不溶性物质以分散形式悬浮在组合物中，或用于调节组合物的粘度。这样的浓度范围按所述组合物重量计为约0.1％至约10％，优选约0.3％至约5.0％。
可用于本发明的悬浮剂包括结晶的悬浮剂，它可以被分类为酰基衍生物、长链氧化胺、以及它们的混合物。这些悬浮剂描述于美国专利4,741,855中。这些优选的悬浮剂包括优选具有约16至约22个碳原子的脂肪酸乙二醇酯。更优选硬脂酸乙二醇酯，一硬脂酸酯和二硬脂酸酯均优选，但尤其优选包含少于约7％一硬脂酸酯的二硬脂酸酯。
8.其它任选组分
本发明的组合物可包含其它任选组分。任选组分可存在于分散的凝胶网络相中，或者可作为单独组分加入最终的洗发剂组合物中。
例如，本发明的组合物可包含水溶性和水不溶性的维生素，如维生素B1、B2、B6、B12、C、泛酸、泛基乙基醚、泛醇、生物素及其衍生物、和维生素A、D、E、以及它们的衍生物。本发明组合物还可包含水溶性和水不溶性的氨基酸，如天冬酰胺、丙氨酸、吲哚、谷氨酸及其盐、和酪氨酸、色胺、赖氨酸、组氨酸、以及它们的盐。本发明组合物还可包含用于防止毛发损失的物质和毛发生长刺激物或毛发生长刺激剂。
任何其它合适的任选组分也可包括在本发明的组合物中，例如通常用于指定产品类型中的那些成分。“CTFA Cosmetic Ingredient Handbook”第十版(2004年)(由Cosmetic，Toiletry，and Fragrance Association，Inc.，Washington，D.C.出版)描述了可加入本文组合物中的多种非限制性物质。这些成分种类的实例包括但不限于：研磨剂、吸收剂、美观组分(如香料和芳香剂、颜料、染色剂/着色剂、精油、皮肤增感剂、收敛剂等(例如丁香油、薄荷醇、樟脑、桉树油、丁子香酚、乳酸薄荷酯、金缕梅馏出液))、抗痤疮剂、抗结块剂、消泡剂、抗微生物剂(例如丁基氨基甲酸碘丙酯)、抗菌剂、杀真菌剂、抗氧化剂、粘合剂、生物添加剂、缓冲剂、增量剂、螯合剂、化学添加剂、着色剂、化妆收敛剂、化妆杀菌剂、变性剂、药物收敛剂、外用止痛剂、成膜剂或成膜物质(例如有助于所述组合物的成膜性质和亲和性的聚合物(例如二十碳烯和乙烯基吡咯烷酮的共聚物))、遮光剂、pH调节剂、植物衍生物、植物提取物、植物组织提取物、植物种子提取物、植物油、药材、药材提取物、防腐剂、推进剂、还原剂、皮脂控制剂、螯合剂、皮肤增白和增亮剂(例如对苯二酚、曲酸、抗坏血酸、抗坏血酸磷酸镁、抗坏血酸基葡糖苷、吡哆素)、酶、辅酶、皮肤调理剂(例如湿润剂和吸留性试剂)、皮肤抚慰剂和/或康复剂和衍生物(例如泛醇和衍生物，如乙基泛醇、芦荟、泛酸及其衍生物、尿囊素、红没药醇、以及甘草酸二钾盐)、皮肤处理剂(例如维生素D化合物、单萜系化合物、二萜系化合物和三萜系化合物、β-亚诺抗氧化添加剂、雪松醇)、增稠剂(包括一价盐或二价盐，如氯化钠)、和维生素、它们的衍生物、以及它们的组合。
当某些油溶的组分，如香料和芳香剂、氨基酸、水不溶性的维生素等等，存在于所述分散的凝胶网络相中的时候，或者通过将上述组分直接掺入到所述凝胶网络组分预混物或者单独掺入到所述洗发剂组合物并因此一定量的上述组分在平衡过程中迁移到所述分散的凝胶网络相中的时候，它们可有效地沉积在毛发和/或皮肤上。通过它们存在于所述分散的凝胶网络相中而获得油溶的组分在毛发和/或皮肤上非常有效的沉积，包含不少于约60％的具有约3或更高的Clog P的成分的油溶的组分组合物是优选的。对于关于Clog P的进一步论述以及如何就多种物质确定其数值，参见例如美国专利5,849,310和5,500,154以及EP 1 533 364。
E.制备洗发剂组合物的方法
本发明的一个方面涉及一种制备本发明的洗发剂组合物的方法。制备洗发剂组合物的方法包括：(a)在足以使第二表面活性剂和水分配到脂肪醇中的温度下，混合脂肪醇、第二表面活性剂和水以形成预混物；(b)将该预混物冷却至脂肪醇的链熔融温度以下以形成凝胶网络；(c)将该凝胶网络加到一种或多种去污表面活性剂和含水载体中以形成洗发剂组合物，所述的组合物包含具有至少约38℃的熔融转变温度的凝胶网络相。
如上所述，在本发明的一个实施方案中，将凝胶网络组分制备成单独的预混物，其在冷却后，接着与洗发剂组合物的其它组分混合。更具体地讲，本发明的凝胶网络组分可通过将脂肪醇、第二表面活性剂和水加热到约75℃至约90℃的温度范围内并且混合而制备。通过例如将所述混合物通过热交换器，将该混合物冷却到约27℃至约35℃的温度范围内。作为该冷却步骤的结果，至少约百分之五十的所述脂肪醇和所述第二表面活性剂混合物结晶形成结晶的凝胶网络。
制备凝胶网络组分的可供选择的方法包括超声波降解和/或研磨脂肪醇、第二表面活性剂和水，同时加热这些组分，以减小熔融的脂肪醇相的粒度。这导致脂肪醇相的表面积增加，其使得第二表面活性剂和水使脂肪醇相溶胀。制备凝胶网络的另一种合适的变型包括首先加热和混合脂肪醇和第二表面活性剂，然后将该混合物加到水中。
F.使用方法
以常规方式使用本发明的组合物，以清洁和调理毛发或皮肤，包括头皮、面部和身体。通常，本发明处理毛发或皮肤的方法包括将本发明的组合物施用于毛发或皮肤。更具体地讲，将有效量的所述组合物施用到优选已用水润湿的毛发或皮肤上，然后将所述组合物冲洗掉。该有效量范围通常为约1g至约50g，优选为约1g至约20g。对毛发的施用典型地包括将组合物施用到整个毛发以使大部分或所有毛发与组合物接触。
用于处理毛发或皮肤的方法包括以下步骤：(a)用水润湿毛发或皮肤；(b)向毛发或皮肤施用有效量的洗发剂组合物；和(c)用水漂洗皮肤或毛发的施用区域。这些步骤可以按需要重复多次，以达到所需的清洁和调理有益效果。
在一个实施方案中，本发明的洗发剂组合物有利地用来处理受损毛发。受损毛发可包括选自烫过的毛发、氧化着色的毛发和机械损伤的毛发的毛发。
在另一个实施方案中，洗发剂组合物用来处理皮肤，如头皮、面部和身体。
此发明的洗发剂组合物可作为液体、固体、半固体、薄片、凝胶使用，可放置于加有推进剂的加压容器中，或以泵式喷雾形式使用。选择所述产品的粘度，以适合所需的形式。
非限制性实例
如下实施例中举例说明的洗发剂组合物举例说明了本发明洗发剂组合物的具体实施方案，但不是旨在对其进行限制。在不背离本发明精神和范围的条件下，技术人员可以进行其它的改变。本发明洗发剂组合物的这些示例的实施方案为毛发提供增强的调理有益效果。
如下实施例中举例说明的洗发剂组合物通过常规配制和混合方法制备，其中的一个实施例如下文所述。除非另外指明，所有示例的量以重量百分比列出，除了微量组分以外，如稀释剂、防腐剂、有色溶液、假想成分、植物药物等。除非另外指明，所有百分比均基于重量。
凝胶网络预混物的制备
为了制备凝胶网络预混物，将约20％的水加热至约74℃，并且将所述脂肪醇和第二表面活性剂(例如，二十二烷基三甲基氯化铵(Varisoft BT-85)或月桂基聚氧乙烯醚硫酸钠)加入其中。加入之后，将该混合物通过研磨机和热交换器，在其中将它冷却到约35℃。该冷却步骤的结果是脂肪醇、第二表面活性剂和水形成结晶凝胶网络。
对于不同脂肪醇的混合物，在掺入水中之前预混合脂肪醇物质可能是有益的。这可通过以下步骤完成：将不同的脂肪醇一起共熔，并且利用该熔融物或冷却成固相，并且将其连同第二表面活性剂一起掺入热水中。另一种变型可以是将一种或多种脂肪醇和第二表面活性剂在掺入水中之前共熔。
凝胶网络预混物实施例1至14
以下实施例举例说明了与去污表面活性剂和本发明最终洗发剂组合物的其它组分结合之前的凝胶网络预混物的具体实施方案。其意图是可将以下每个凝胶网络预混物的实施例作为分散相掺入依照本发明的洗发剂组合物中。
| 成分 | 1 | 2 | 3 | 4 | 5 | 6 | 7 |
| 水 | 88.78％ | 88.78％ | 88.78％ | 82.75％ | 86.14％ | 88.79％ | 88.79％ |
| 硬脂醇 | 9.90％ | 4.95％ | 4.29％ | 4.95％ | 7.42％ | 7.42％ | |
| 二十二醇 | 9.90％ | 4.95％ | |||||
| Lanette 22(1) | 4.29％ | 4.95％ | |||||
| C20-40醇(2)(Perf.350) | 2.47％ | ||||||
| C30-50醇(2)(Perf.425) | 2.47％ | ||||||
| 月桂基聚氧乙烯醚-3硫酸钠(28％活性物质) | 8.64％ | 3.93％ |
| 二十二烷基三甲基氯化铵，Varisoft BT-85(3) | 1.29％ | 1.29％ | 1.29％ | 1.29％ | 1.29％ | ||
| 5-氯-2-甲基-4-异噻唑啉-3-酮，Kathon CG | 0.03％ | 0.03％ | 0.03％ | 0.03％ | 0.03％ | 0.03％ | 0.03％ |
| 在最大峰值处DSC熔融转变，以℃计 | 68.3 | 67.3 | 44.1和78.6 | 37.7，44.4和79.3 |
(1)得自Cognis Corp.
(2)以Performacol系列(350，425)得自New Phase Technologies
(3)得自Croda Chemicals
| 成分 | 8 | 9 | 10 | 11 | 12 | 13 | 14 |
| 水 | 88.54％ | 88.97％ | 88.97％ | 88.78％ | 88.78％ | 82.76％ | 86.15％ |
| 鲸蜡醇 | 5.57％ | 1.97％ | |||||
| 硬脂醇 | 4.29％ | 3.00％ | 3.53％ | 2.14％ | 4.95％ | 2.14％ | 2.47％ |
| 二十烷醇 | 4.29％ | ||||||
| 二十二醇 | 6.43％ | ||||||
| Lanette 22(1) | 6.43％ | 7.42％ | |||||
| C40-60醇(2) | 4.95％ | ||||||
| 二十二烷基硫酸钠(100％活性物质) | 2.42％ | 5.50％ | |||||
| 月桂基聚氧乙烯醚-3硫酸钠(28％活性物质) | 8.64％ | 8.64％ | 3.93％ | ||||
| 二十二烷基三甲基氯化铵，Varisoft BT-85(3) | 2.85％ | 1.29％ | |||||
| 5-氯-2-甲基-4-异噻唑啉-3-酮，Kathon CG | 0.03％ | 0.03％ | 0.03％ | 0.03％ | 0.03％ | 0.03％ | 0.03％ |
| 在最大峰值处DSC熔融转变，以℃计 | 70.1 | 70.4 |
(1)得自Cognis Corp.
(2)以Performacol系列(700)得自New Phase Technologies
(3)得自Croda Chemicals
最终洗发剂组合物的制备
为了制备最终的洗发剂组合物，首先形成表面活性剂溶液预混物。为了制备该表面活性剂溶液预混物，将约6％至约9％的月桂基聚氧乙烯醚-3硫酸钠或月桂基聚氧乙烯醚-3硫酸铵、阳离子聚合物和约0％至约5％的水在搅拌下加入加套的混合罐中，并且加热至约74℃。向罐中的该溶液中加入柠檬酸、柠檬酸钠、苯甲酸钠和乙二胺四乙酸二钠，并使其分散。然后将乙二醇二硬脂酸酯(EGDS)加到混合容器中并且熔化。在EGDS被完全分散后(例如，约10分钟后)，将防腐剂加入并且混合到表面活性剂溶液中。这种混合物穿过研磨机和换热器，它在换热器中冷却至约35℃，然后被收集在整理罐中。该冷却步骤的结果是，EGDS结晶以形成蜡质结晶悬浮液。这些组分的混合物为表面活性剂溶液预混物。
接下来，将如上所述制备的表面活性剂溶液预混物和凝胶网络预混物混合在一起。在充分搅拌下加入剩余的表面活性剂、香料、聚二甲基硅氧烷、氯化钠或用于粘度调节的二甲苯磺酸铵、以及剩余的水以确保均匀的混合物。该混合物为最终的洗发剂组合物，其包含作为分散相的凝胶网络预混物。
依照本发明的最终洗发剂组合物的优选粘度，在27℃下当用Wells-Brookfield型RVTDCP粘度计测量时(使用CP-41锥，并且板在3分钟处为2/s)，其范围为约5Pa.s(5000cP)至约15Pa.s(15,000厘泊)。
必要时可调节pH以提供适于施用到人的毛发上的本发明洗发剂组合物，并且可基于具体的去污表面活性剂、脂肪醇和/或其它组分的选择而变化。
洗发剂实施例1至20
以下实施例举例说明了本发明最终洗发剂组合物的具体实施方案，其分别包含以上选择的示例性凝胶网络预混物作为分散相。
| 成分 | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 |
| 月桂基聚氧乙烯醚硫酸钠 | 10.00 | 10.00 | 10.00 | 10.00 | 10.00 | 10.00 | 10.00 | 10.00 | 10.00 | 8.5 |
| 月桂基硫酸钠 | 1.50 | 1.50 | 1.50 | 1.50 | 1.50 | 1.50 | 1.50 | 1.50 | 1.50 | 3.00 |
| 椰油酰氨基丙基甜菜碱 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 |
| 凝胶网络1 | 27.3 | |||||||||
| 凝胶网络2 | 27.3 | |||||||||
| 凝胶网络3 | 27.3 | |||||||||
| 凝胶网络4 | 27.3 | 27.3 | ||||||||
| 凝胶网络5 | 27.3 | |||||||||
| 凝胶网络6 | 27.3 | |||||||||
| 凝胶网络7 | 27.3 | |||||||||
| 凝胶网络13 | 27.3 | |||||||||
| 凝胶网络14 | 27.3 | |||||||||
| 瓜耳羟丙基三甲基氯化铵(1) |
| 瓜耳羟丙基三甲基氯化铵(2) | 0.40 | 0.40 | 0.40 | 0.40 | 0.40 | 0.40 | 0.40 | 0.40 | 0.40 | 0.40 |
| 瓜耳羟丙基三甲基氯化铵(3) | ||||||||||
| 聚季铵-10(7) | ||||||||||
| 聚二甲基硅氧烷(9) | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 |
| 乙二醇二硬脂酸酯 | 1.5 | 1.5 | 1.5 | 1.5 | 3.0 | 1.5 | 1.5 | 3.0 | 3.0 | 3.0 |
| 5-氯-2-甲基-4-异噻唑啉-3-酮，Kathon CG | 0.0005 | 0.0005 | 0.0005 | 0.0005 | 0.0005 | 0.0005 | 0.0005 | 0.0005 | 0.0005 | 0.0005 |
| 苯甲酸钠 | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| 乙二胺四乙酸二钠 | 0.13 | 0.13 | 0.13 | 0.13 | 0.13 | 0.13 | 0.13 | 0.13 | 0.13 | 0.13 |
| 香料 | 0.70 | 0.70 | 0.70 | 0.70 | 0.70 | 0.70 | 0.70 | 0.70 | 0.70 | 0.70 |
| 柠檬酸/二水合柠檬酸钠 | pH适量 | pH适量 | pH适量 | pH适量 | pH适量 | pH适量 | pH适量 | pH适量 | PH适量 | pH适量 |
| 氯化钠/二甲苯磺酸铵 | 粘度适量 | 粘度适量 | 粘度适量 | 粘度适量 | 粘度适量 | 粘度适量 | 粘度适量 | 粘度适量 | 粘度适量 | 粘度适量 |
| 水 | 适量 | 适量 | 适量 | 适量 | 适量 | 适量 | 适量 | 适量 | 适量 | 适量 |
| 在洗发剂凝胶网络(ELD)中，在最大峰值处DSC熔融转变，以℃计 | 40.8 | 51.5 | 43.4 | 41.8 | 42.2 | 40.5 | 41.2 | 42.5 | 42.1 | 41.7 |
(1)Jaguar C17，得自Rhodia
(2)ADPP-5043HMW(具有1,200,000的分子量和2.0meq/g的电荷密度)，得自Aqualon/Hercules
(3)ADPP-5043LMW(具有500,000的分子量和2.0meq/g的电荷密度)，得自Aqulaon/Hercules
(4)Polymer KG30M，得自Amerchol/Dow Chemical
(5)Viscasil 330M，得自General Electric Silicones
| 成分 | 11 | 12 | 13 | 14 | 15 | 16 | 17 | 18 | 19 | 20 |
| 月桂基聚氧乙烯醚硫酸钠 | 10.00 | 10.00 | 10.00 | 10.00 | 10.00 | 10.00 | 6.00 | 7.65 | 10.00 | 8.5 |
| 月桂基硫酸钠 | 1.50 | 1.50 | 1.50 | 1.50 | 3.00 | 6.00 | 10.00 | 6.35 | 1.50 | 3.00 |
| 椰油酰氨基丙基甜菜碱 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 0.00 | 0.00 | 0.00 | 2.00 | 2.00 |
| 凝胶网络1 | 27.3 | 27.3 | ||||||||
| 凝胶网络9 | 27.3 | |||||||||
| 凝胶网络10 | 27.3 | |||||||||
| 凝胶网络4 | 13.65 | 27.3 | 27.3 | |||||||
| 凝胶网络5 | 27.3 | 27.3 | ||||||||
| 凝胶网络11 | 27.3 | |||||||||
| 瓜耳羟丙基三甲基氯化铵(1) | 0.20 | 0.3 |
| 瓜耳羟丙基三甲基氯化铵(2) | 0.40 | 0.40 | 0.40 | 0.40 | 0.40 | 0.10 | ||||
| 瓜耳羟丙基三甲基氯化铵(3) | 0.40 | |||||||||
| 聚季铵-10(4) | 0.40 | |||||||||
| 聚二甲基硅氧烷(9) | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 |
| 乙二醇二硬脂酸酯 | 1.5 | 1.5 | 1.5 | 1.5 | 3.0 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 |
| 5-氯-2-甲基-4-异噻唑啉-3-酮，Kathon CG | 0.0005 | 0.0005 | 0.0005 | 0.0005 | 0.0005 | 0.0005 | 0.0005 | 0.0005 | 0.0005 | 0.0005 |
| 苯甲酸钠 | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| 乙二胺四乙酸二钠 | 0.13 | 0.13 | 0.13 | 0.13 | 0.13 | 0.13 | 0.13 | 0.l3 | 0.13 | 0.13 |
| 香料 | 0.70 | 0.70 | 0.70 | 0.70 | 0.70 | 0.70 | 0.70 | 0.70 | 0.70 | 0.70 |
| 柠檬酸/二水合柠檬酸钠 | pH适量 | pH适量 | pH适量 | pH适量 | pH适量 | pH适量 | pH适量 | pH适量 | pH适量 | pH适量 |
| 氯化钠/二甲苯磺酸铵 | 粘度适量 | 粘度适量 | 粘度适量 | 粘度适量 | 粘度适量 | 粘度适量 | 粘度适量 | 粘度适量 | 粘度适量 | 粘度适量 |
| 水 | 适量 | 适量 | 适量 | 适量 | 适量 | 适量 | 适量 | 适量 | 适量 | 适量 |
| 在洗发剂(ELD)中凝胶网络中，在最大峰值处的DSC熔融转变，以℃计 | 39.0 | 40.1 | 41.7 | 38.0 | ||||||
| ELD的标度尺寸(分散GN相) | 31祄 | 0.01祄 | 1祄 | 4祄 |
(1)Jaguar C17，得自Rhodia
(2)ADPP-5043HMW(具有～1,200,000的分子量和2.0meq/g的电荷密度)，得自Aqualon/Hercules
(3)ADPP-5043LMW(具有～500,000的分子量和2.0meq/g的电荷密度)，得自Aqulaon/Hercules
(4)Polymer KG30M，得自Amerchol/Dow Chemical
(5)Viscasil 330M，得自General Electric Silicones
在发明详述中引用的所有文献的相关部分均以引用方式并入本文中。任何文献的引用不可解释为是对其作为本发明的现有技术的认可。当本书面文献中术语的任何含义或定义与以引用方式并入本文的文献中的术语的任何含义或定义冲突时，将以赋予本书面文献中的术语的含义或定义为准。
尽管已用具体实施方案来说明和描述了本发明，但对于本领域的技术人员显而易见的是，在不背离本发明的精神和保护范围的情况下可作出许多其它的变化和修改。因此，有意识地在附加的权利要求书中包括属于本发明范围内的所有这些变化和修改。
Claims (14)
1.一种洗发剂组合物，所述洗发剂组合物包含：
a)按所述洗发剂组合物的重量计5％至50％的一种或多种去污表面活性剂；
b)分散的凝胶网络相，所述凝胶网络相包含：
i)按所述洗发剂组合物的重量计至少0.05％的一种或多种脂肪醇；
ii)按所述洗发剂组合物的重量计至少0.01％的一种或多种选自的阴离子表面活性剂的第二表面活性剂；和
iii)水；和
c)按所述洗发剂组合物的重量计至少20％的含水载体；
其中依照差示扫描量热法测量，所述分散的凝胶网络相具有40℃至60℃的熔融转变温度，
而且其中所述脂肪醇选自二十烷醇、二十二醇和其混合物。
2.如权利要求1所述的洗发剂组合物，其中所述分散的凝胶网络相以按所述洗发剂组合物的重量计1％至60％的量存在。
3.如权利要求1所述的洗发剂组合物，其中所述分散的凝胶网络相具有在所述洗发剂组合物中测得的10nm至500nm的标度尺寸。
4.如权利要求1所述的洗发剂组合物，其中所述分散的凝胶网络相具有在所述洗发剂组合物中测得的0.5μm至10μm的标度尺寸。
5.如权利要求1所述的洗发剂组合物，其中所述分散的凝胶网络相具有在所述洗发剂组合物中测得的10μm至150μm的标度尺寸。
6.如权利要求1所述的洗发剂组合物，其中所述阴离子表面活性剂选自由下列物质组成的组：十二烷基硫酸铵、月桂基聚氧乙烯醚硫酸铵、月桂基硫酸三乙基胺、月桂基聚氧乙烯醚硫酸三乙基胺、月桂基硫酸三乙醇胺、月桂基聚氧乙烯醚硫酸三乙醇胺、月桂基硫酸单乙醇胺、月桂基聚氧乙烯醚硫酸单乙醇胺、月桂基硫酸二乙醇胺、月桂基聚氧乙烯醚硫酸二乙醇胺、月桂酸甘油单酯硫酸钠、月桂基硫酸钠、月桂基聚氧乙烯醚硫酸钠、月桂基硫酸钾、月桂基聚氧乙烯醚硫酸钾、月桂基肌氨酸钠、月桂酰肌氨酸钠、月桂基肌氨酸、椰油基肌氨酸、椰油基硫酸铵、十二烷酰基硫酸铵、椰油基硫酸钠、月桂酰硫酸钠、椰油基硫酸钾、月桂基硫酸钾、月桂基硫酸三乙醇胺、月桂基硫酸三乙醇胺、椰油基硫酸一乙醇胺、月桂基硫酸单乙醇胺、十三烷基苯磺酸钠、十二烷基苯磺酸钠、椰油基羟乙基磺酸钠、以及它们的混合物。
7.如权利要求1所述的洗发剂组合物，其中所述第二表面活性剂以相对于所述脂肪醇1∶5至5∶1的重量比率存在。
8.如权利要求1所述的洗发剂组合物，所述组合物还包含附加组分，所述附加成分选自由下列组成的组：沉积助剂、分散的颗粒、非离子聚合物、附加的调理剂、去头皮屑活性物质、湿润剂、悬浮剂、香料、氨基酸和水不溶性的维生素。
9.如权利要求8所述的洗发剂组合物，其中所述沉积助剂是阳离子聚合物，选自由下列聚合物组成的组：纤维素衍生物、淀粉衍生物、瓜耳衍生物和桂皮衍生物，并且具有10,000至10,000,000的分子量和0.9meq/g至7.0meq/g的电荷密度。
10.如权利要求8所述的洗发剂组合物，其中所述悬浮剂为结晶的悬浮剂。
11.如权利要求8所述的洗发剂组合物，其中所述附加的调理剂是硅氧烷调理剂，所述硅氧烷调理剂具有在所述洗发剂组合物中测得的1mm至50μm的粒度。
12.如权利要求8所述的洗发剂组合物，其中所述附加的调理剂是硅氧烷调理剂，所述硅氧烷调理剂具有在所述洗发剂组合物中测得的100nm至1μm的粒度。
13.如权利要求8所述的洗发剂组合物，其中所述附加的调理剂是硅氧烷调理剂，所述硅氧烷调理剂具有在所述洗发剂组合物中测得的小于100nm的粒度。
14.如权利要求1所述的洗发剂组合物，其通过包括以下步骤的方法制备：
a)在足以使所述第二表面活性剂和所述水分配到所述脂肪醇中的温度下，混合脂肪醇、第二表面活性剂和水以形成预混物；
b)将所述预混物冷却至所述脂肪醇的链熔融温度以下以形成凝胶网络；
c)将所述凝胶网络添加至一种或多种去污表面活性剂和一种含水载体以形成洗发剂组合物，所述组合物包含熔融转变温度为至少38℃的分散的凝胶网络相。
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/228,770 | 2005-09-16 | ||
| US11/228,770 US8349301B2 (en) | 2002-06-04 | 2005-09-16 | Shampoo containing a gel network |
| US11/475,484 | 2006-06-27 | ||
| US11/475,484 US8361448B2 (en) | 2002-06-04 | 2006-06-27 | Shampoo containing a gel network |
| PCT/IB2006/052457 WO2007031884A1 (en) | 2005-09-16 | 2006-07-18 | Shampoo containing a gel network |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101267797A CN101267797A (zh) | 2008-09-17 |
| CN101267797B true CN101267797B (zh) | 2013-01-02 |
Family
ID=36241038
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2005800515952A Active CN101267796B (zh) | 2005-09-16 | 2005-12-12 | 包含凝胶网络的洗发剂 |
| CN2006800341372A Active CN101267797B (zh) | 2005-09-16 | 2006-07-18 | 包含凝胶网络的洗发剂 |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2005800515952A Active CN101267796B (zh) | 2005-09-16 | 2005-12-12 | 包含凝胶网络的洗发剂 |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US8349301B2 (zh) |
| EP (2) | EP1924237A1 (zh) |
| JP (2) | JP5079700B2 (zh) |
| CN (2) | CN101267796B (zh) |
| AU (1) | AU2005336930B2 (zh) |
| BR (2) | BRPI0520546A2 (zh) |
| CA (1) | CA2621660C (zh) |
| ES (1) | ES2850202T3 (zh) |
| MX (1) | MX311278B (zh) |
| WO (1) | WO2007040571A1 (zh) |
Families Citing this family (119)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3851312B2 (ja) * | 2002-04-22 | 2006-11-29 | ザ プロクター アンド ギャンブル カンパニー | 水性界面活性剤組成物中に亜鉛含有物質を含むパーソナルケア組成物 |
| US9381382B2 (en) * | 2002-06-04 | 2016-07-05 | The Procter & Gamble Company | Composition comprising a particulate zinc material, a pyrithione or a polyvalent metal salt of a pyrithione and a gel network |
| US8361450B2 (en) * | 2002-06-04 | 2013-01-29 | The Procter & Gamble Company | Shampoo containing a gel network and a non-guar galactomannan polymer derivative |
| US8361448B2 (en) * | 2002-06-04 | 2013-01-29 | The Procter & Gamble Company | Shampoo containing a gel network |
| US8470305B2 (en) * | 2002-06-04 | 2013-06-25 | The Procter & Gamble Company | Shampoo containing a gel network |
| US8491877B2 (en) * | 2003-03-18 | 2013-07-23 | The Procter & Gamble Company | Composition comprising zinc-containing layered material with a high relative zinc lability |
| US8367048B2 (en) * | 2002-06-04 | 2013-02-05 | The Procter & Gamble Company | Shampoo containing a gel network |
| US8349302B2 (en) * | 2002-06-04 | 2013-01-08 | The Procter & Gamble Company | Shampoo containing a gel network and a non-guar galactomannan polymer derivative |
| US8349301B2 (en) | 2002-06-04 | 2013-01-08 | The Procter & Gamble Company | Shampoo containing a gel network |
| GB0229733D0 (en) * | 2002-12-23 | 2003-01-29 | Unilever Plc | Hair treatment compositions |
| US20070048344A1 (en) * | 2005-08-31 | 2007-03-01 | Ali Yahiaoui | Antimicrobial composition |
| US20070048358A1 (en) * | 2005-08-31 | 2007-03-01 | Schorr Phillip A | Antimicrobial substrates |
| US20070048356A1 (en) * | 2005-08-31 | 2007-03-01 | Schorr Phillip A | Antimicrobial treatment of nonwoven materials for infection control |
| US20070048345A1 (en) * | 2005-08-31 | 2007-03-01 | Kimberly-Clark Worldwide, Inc. | Antimicrobial composition |
| US20070218021A1 (en) * | 2006-03-20 | 2007-09-20 | Azur Skin International | Non-irritating sunscreen composition |
| ES2656344T3 (es) * | 2006-09-29 | 2018-02-26 | The Procter & Gamble Company | Composiciones de uso oral que contienen redes de gel |
| US8530399B2 (en) | 2006-11-08 | 2013-09-10 | Conopco Inc. | Conditioning shampoo compositions |
| JP5155334B2 (ja) * | 2006-12-21 | 2013-03-06 | ザ プロクター アンド ギャンブル カンパニー | アミノシリコーン及び天然由来のカチオン性ポリマーを含むパーソナルケア組成物 |
| US20100322888A1 (en) * | 2007-02-08 | 2010-12-23 | Arimino Co., Ltd. | Emulsion Composition for Hair Treating Agents |
| US20090035340A1 (en) * | 2007-07-30 | 2009-02-05 | Kimberly-Clark Worldwide, Inc. | Preservative compositions for moist wipes |
| US9968535B2 (en) * | 2007-10-26 | 2018-05-15 | The Procter & Gamble Company | Personal care compositions comprising undecyl sulfates |
| US10251839B2 (en) * | 2008-01-22 | 2019-04-09 | Igi Laboratories, Inc. | Lipid vesicles derived from olive oil fatty acids |
| WO2009107062A2 (en) * | 2008-02-25 | 2009-09-03 | The Procter & Gamble Company | Hair care compositions comprising sucrose polyesters |
| US8518381B2 (en) | 2008-03-28 | 2013-08-27 | The Procter & Gamble Company | Processes of making oral compositions containing gel networks |
| CA2725807A1 (en) * | 2008-05-26 | 2009-12-03 | Meat & Livestock Australia Limited | Biodiesel additive |
| CN102164578B (zh) | 2008-06-25 | 2014-08-27 | 宝洁公司 | 具有较高屈服点和较高的脂肪族化合物至凝胶基质转化率的毛发调理组合物 |
| CN102215807A (zh) * | 2008-06-25 | 2011-10-12 | 宝洁公司 | 包含二十二烷基三甲基氯化铵并具有较高屈服点的毛发调理组合物 |
| DE102008030138A1 (de) | 2008-06-27 | 2009-12-31 | Beiersdorf Ag | Haarspülung mit Amphotensid und besonderer Lagerstabilität |
| CA2731106A1 (en) | 2008-08-15 | 2010-02-18 | Jennifer Beth Ponder | Benefit compositions comprising polyglycerol esters |
| MX2011004857A (es) * | 2008-11-07 | 2011-08-03 | Unilever Nv | Composicion acondicionada de champu que comprende un gel acuoso acondicionador. |
| MX2011006125A (es) * | 2008-12-09 | 2011-07-20 | Procter & Gamble | Metodo para preparar una composicion para el cuidado personal que comprende un surfactante y un compuesto graso de alto punto de fusion. |
| EP2437720A2 (en) * | 2009-06-04 | 2012-04-11 | The Procter & Gamble Company | Multiple product system for hair |
| EP2440646B1 (en) | 2009-06-08 | 2013-03-06 | The Procter & Gamble Company | Process for making a cleaning composition employing direct incorporation of concentrated surfactants |
| EP2445475B1 (en) * | 2009-06-24 | 2017-01-11 | Unilever PLC | Concentrated shampoo |
| WO2010149460A2 (en) * | 2009-06-24 | 2010-12-29 | Unilever Plc | Composition |
| JP5849047B2 (ja) * | 2009-06-24 | 2016-01-27 | ユニリーバー・ナームローゼ・ベンノートシヤープ | ゲルネットワーク構造のふけ防止シャンプー |
| MX338420B (es) * | 2009-08-20 | 2016-04-15 | Procter & Gamble | Composiciones para el cuidado del cabello que comprenden un primer y un segundo poliester de sacarosa. |
| EP2531169B1 (en) * | 2010-02-01 | 2014-12-03 | Unilever PLC, A Company Registered in England and Wales under Company no. 41424 | Shampoo containing a gel network |
| BR112012024084A2 (pt) * | 2010-03-26 | 2016-08-23 | Unilever Nv | composição de xampu método de fabricação de uma composição de xampu |
| MX2012011139A (es) * | 2010-03-29 | 2012-11-12 | Unilever Nv | Composicion para el cuidado del cabello que comprende siloxano modificado con alquilo. |
| US8889612B2 (en) | 2010-04-19 | 2014-11-18 | The Procter & Gamble Company | Method of laundering fabric using a compacted liquid laundry detergent composition |
| JP2013525393A (ja) * | 2010-04-30 | 2013-06-20 | ユニリーバー・ナームローゼ・ベンノートシヤープ | 組成物 |
| EP2395070A1 (en) | 2010-06-10 | 2011-12-14 | The Procter & Gamble Company | Liquid laundry detergent composition comprising lipase of bacterial origin |
| EA201390073A1 (ru) | 2010-07-08 | 2013-07-30 | Унилевер Н.В. | Композиция для ухода за волосами |
| CA2803902A1 (en) * | 2010-07-15 | 2012-01-19 | The Procter & Gamble Company | Method of cleansing hair |
| US8658582B2 (en) | 2010-12-07 | 2014-02-25 | L'oreal | Clear cosmetic compositions containing lipophilic materials |
| CA2840215A1 (en) | 2011-06-22 | 2012-12-27 | Abhijit S. BAPAT | Conjugate-based antifungal and antibacterial prodrugs |
| PL2744881T3 (pl) * | 2011-08-15 | 2016-07-29 | Procter & Gamble | Kompozycja detergentowa zawierająca związki pirydynol-n-tlenków |
| WO2013040331A2 (en) | 2011-09-15 | 2013-03-21 | The Procter & Gamble Company | Method for preparing personal care composition comprising surfactant system and high melting point fatty compound |
| JP5930436B2 (ja) * | 2011-10-07 | 2016-06-08 | ザ プロクター アンド ギャンブル カンパニー | ゲル網状組織を含有するシャンプー組成物 |
| CA2869961C (en) * | 2012-04-20 | 2017-01-17 | John David Carter | Hair care composition comprising metathesized unsaturated polyol esters |
| JP5986290B2 (ja) * | 2012-04-20 | 2016-09-06 | ザ プロクター アンド ギャンブル カンパニー | メタセシス化不飽和ポリオールエステルを含むヘアケア組成物 |
| BR112014031284B8 (pt) | 2012-06-15 | 2019-11-05 | Lubrizol Advanced Mat Inc | composição, produto de cuidado pessoal, e, modificador de reologia |
| CN104582679B (zh) * | 2012-07-27 | 2017-10-24 | 巴斯夫欧洲公司 | 包含硫酸化泊洛沙姆的个人护理组合物及其制备和使用方法 |
| EP2914576B1 (en) * | 2012-12-28 | 2018-01-31 | Rohm and Haas Company | Aqueous dispersion of fatty amide |
| US9867768B2 (en) | 2013-03-08 | 2018-01-16 | Lubrizol Advanced Materials, Inc. | Foaming performance in cleansing compositions through the use of nonionic, amphiphilic polymers |
| CN105050567B (zh) | 2013-04-05 | 2018-04-27 | 宝洁公司 | 包含预乳化的制剂的个人护理组合物 |
| WO2014177189A1 (en) * | 2013-04-30 | 2014-11-06 | Rhodia Operations | Translucent gel system |
| MX2015015909A (es) | 2013-05-22 | 2016-03-09 | Procter & Gamble | Metodo para lograr mejor reologia, deposito y aceptacion cosmetica del producto por parte del consumidor. |
| US9931287B2 (en) | 2013-06-03 | 2018-04-03 | Formula Xo, Inc. | Simple micro-particulate suspension of behentrimonium chloride with favorable distributive and adsorptive properties |
| AU2014276460A1 (en) | 2013-06-04 | 2015-12-24 | Vyome Biosciences Pvt. Ltd. | Coated particles and compositions comprising same |
| US20140377206A1 (en) * | 2013-06-19 | 2014-12-25 | The Procter & Gamble Company | System use of shampoo and hair conditioning composition comprising mono-long alkyl amine and/or polyol |
| US20150011450A1 (en) * | 2013-07-03 | 2015-01-08 | The Procter & Gamble Company | Amphoteric Ter-Polymers For Use in Personal Care Compositions |
| WO2015003878A1 (en) * | 2013-07-12 | 2015-01-15 | Unilever Plc | Shampoo composition |
| WO2015110510A1 (en) * | 2014-01-23 | 2015-07-30 | Unilever Plc | Use of a hair conditioning composition for styling the hair |
| US9642787B2 (en) | 2014-04-25 | 2017-05-09 | The Procter & Gamble Company | Method of inhibiting copper deposition on hair |
| US9642788B2 (en) | 2014-04-25 | 2017-05-09 | The Procter & Gamble Company | Shampoo composition comprising gel matrix and histidine |
| US9586063B2 (en) | 2014-04-25 | 2017-03-07 | The Procter & Gamble Company | Method of inhibiting copper deposition on hair |
| KR101840160B1 (ko) * | 2014-06-13 | 2018-03-19 | 가부시키가이샤 시세이도 | α겔 중간체 조성물 및 상기 조성물을 사용한 α겔 함유 O/W 유화화장료의 제조방법 |
| WO2015190306A1 (ja) | 2014-06-13 | 2015-12-17 | 株式会社 資生堂 | αゲル中間体組成物、及び該組成物を用いたαゲル含有Ｏ／Ｗ乳化化粧料の製造方法 |
| US10806688B2 (en) | 2014-10-03 | 2020-10-20 | The Procter And Gamble Company | Method of achieving improved volume and combability using an anti-dandruff personal care composition comprising a pre-emulsified formulation |
| US10912719B2 (en) | 2014-10-20 | 2021-02-09 | The Procter And Gamble Company | Personal care composition and method of making |
| EP3031892B1 (en) * | 2014-12-12 | 2020-02-26 | The Procter and Gamble Company | A process for making a consumer goods product comprising a benefit delivery composition |
| EP3031893B1 (en) * | 2014-12-12 | 2017-11-08 | The Procter and Gamble Company | A process for making a consumer goods product comprising a benefit delivery composition |
| EP3031891B1 (en) * | 2014-12-12 | 2019-03-20 | The Procter and Gamble Company | A multi-compartment laundry detergent water-soluble pouch |
| US9993404B2 (en) | 2015-01-15 | 2018-06-12 | The Procter & Gamble Company | Translucent hair conditioning composition |
| FR3034011B1 (fr) * | 2015-03-25 | 2018-05-18 | L'oreal | Procede de traitement cosmetique des cheveux |
| US10632054B2 (en) | 2015-04-02 | 2020-04-28 | The Procter And Gamble Company | Method for hair frizz reduction |
| US10660835B2 (en) | 2015-04-02 | 2020-05-26 | The Procter And Gamble Company | Method for hair frizz reduction |
| US10358625B2 (en) * | 2015-07-17 | 2019-07-23 | S. C. Johnson & Son, Inc. | Non-corrosive cleaning composition |
| US10561591B2 (en) | 2015-12-04 | 2020-02-18 | The Procter And Gamble Company | Hair care regimen using compositions comprising moisture control materials |
| EP3405168B1 (en) | 2016-01-20 | 2025-01-22 | The Procter & Gamble Company | Hair conditioning composition comprising monoalkyl glyceryl ether |
| CA3026108A1 (en) * | 2016-06-10 | 2017-12-14 | Clarity Cosmetics Inc. | Non-comedogenic hair and scalp care formulations and method for use |
| WO2018005453A1 (en) | 2016-06-27 | 2018-01-04 | The Procter & Gamble Company | Shampoo composition containing a gel network |
| US10945935B2 (en) | 2016-06-27 | 2021-03-16 | The Procter And Gamble Company | Shampoo composition containing a gel network |
| WO2018045584A1 (zh) * | 2016-09-12 | 2018-03-15 | 拉芳家化股份有限公司 | 一种含头发保湿复合剂的香波组合物 |
| WO2018045582A1 (zh) * | 2016-09-12 | 2018-03-15 | 拉芳家化股份有限公司 | 一种含保湿复合剂的护发养发组合物 |
| US20180098923A1 (en) | 2016-10-10 | 2018-04-12 | The Procter & Gamble Company | Personal care compositions substantially free of sulfated surfactants and containing a gel network |
| US10980723B2 (en) | 2017-04-10 | 2021-04-20 | The Procter And Gamble Company | Non-aqueous composition for hair frizz reduction |
| JP6933709B2 (ja) | 2017-04-13 | 2021-09-08 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | 離散粒子及び水性ベース組成物を含む製品組成物 |
| CN108031403B (zh) * | 2017-11-24 | 2019-10-25 | 江南大学 | 一种羧酸盐型阴离子Gemini表面活性剂的泡沫体系 |
| US20190216697A1 (en) * | 2018-01-18 | 2019-07-18 | Nohbo,LLC | Hygiene product pod and methods of using same |
| EP3801443A1 (en) | 2018-06-05 | 2021-04-14 | The Procter & Gamble Company | Clear cleansing composition |
| JP7358398B2 (ja) | 2018-06-21 | 2023-10-10 | ユニリーバー・アイピー・ホールディングス・ベスローテン・ヴェンノーツハップ | パーソナルクレンジング組成物 |
| WO2020061556A1 (en) * | 2018-09-21 | 2020-03-26 | Isp Investments Llc | Lamellar gel based personal care compositions, process for preparing the same and method of use thereof |
| US11931441B2 (en) | 2018-10-10 | 2024-03-19 | The Procter & Gamble Company | Personal care product customized by discrete particles and method of apply thereof |
| WO2020089319A1 (en) * | 2018-11-01 | 2020-05-07 | Hfc Prestige International Holding Switzerland S.A.R.L | Silicone free hair conditioning composition |
| CN113164787B (zh) | 2018-12-14 | 2023-11-03 | 宝洁公司 | 包含片状微胶囊的洗发剂组合物 |
| CN115192473B (zh) * | 2018-12-29 | 2024-06-11 | 莱雅公司 | 用于护理皮肤的套装 |
| EP3937905A4 (en) * | 2019-03-14 | 2022-12-28 | Crescita Therapeutics Inc. | RINSING COMPOSITIONS AND THEIR USES FOR THE ADMINISTRATION OF ACTIVE AGENTS |
| CN113766909A (zh) * | 2019-04-26 | 2021-12-07 | 联合利华知识产权控股有限公司 | 头发调理组合物 |
| US12343411B2 (en) | 2019-05-31 | 2025-07-01 | L'oreal | Compositions and methods for treating keratinous substrates |
| US11896689B2 (en) | 2019-06-28 | 2024-02-13 | The Procter & Gamble Company | Method of making a clear personal care comprising microcapsules |
| WO2021113209A1 (en) * | 2019-12-01 | 2021-06-10 | The Procter & Gamble Company | Hair conditioner compositions containing behenamidopropyl dimethylamine |
| MX2022005532A (es) * | 2019-12-01 | 2022-06-08 | Procter & Gamble | Composiciones acondicionadoras para el cabello con un sistema de conservacion que contiene benzoato de sodio y glicoles y/o esteres de glicerilo. |
| US11932448B2 (en) | 2020-02-14 | 2024-03-19 | The Procter & Gamble Company | Bottle adapted for storing a liquid composition with an aesthetic design suspended therein |
| WO2021202656A1 (en) * | 2020-03-31 | 2021-10-07 | L'oreal | Hair care compositions comprising polyol, c2-6 monoalcohol and cationic surfactant |
| JP7594085B2 (ja) | 2020-08-11 | 2024-12-03 | ザ プロクター アンド ギャンブル カンパニー | ブラシシルバリネートエシレートを含有するクリーンリンスヘアコンディショナー組成物 |
| US11633338B2 (en) | 2020-08-11 | 2023-04-25 | The Procter & Gamble Company | Moisturizing hair conditioner compositions containing brassicyl valinate esylate |
| MX2023001046A (es) | 2020-08-11 | 2023-02-16 | Procter & Gamble | Composiciones acondicionadoras para el cabello de viscosidad baja que contienen esilato de valinato de brassicilo. |
| CA3201309A1 (en) | 2020-12-01 | 2022-06-09 | The Procter & Gamble Company | Aqueous hair conditioner compositions containing solubilized anti-dandruff actives |
| US12053130B2 (en) | 2021-02-12 | 2024-08-06 | The Procter & Gamble Company | Container containing a shampoo composition with an aesthetic design formed by bubbles |
| JP2024503889A (ja) | 2021-02-12 | 2024-01-29 | ザ プロクター アンド ギャンブル カンパニー | 泡によって形成された審美的デザインを有するシャンプー組成物を収容する容器 |
| US11633072B2 (en) | 2021-02-12 | 2023-04-25 | The Procter & Gamble Company | Multi-phase shampoo composition with an aesthetic design |
| EP4507667A1 (en) | 2022-04-11 | 2025-02-19 | The Procter & Gamble Company | Personal care composition containing a biosurfactant |
| US20240156706A1 (en) | 2022-10-31 | 2024-05-16 | The Procter & Gamble Company | Personal care composition containing a biosurfactant |
| US20250195357A1 (en) | 2022-12-16 | 2025-06-19 | The Procter & Gamble Company | Clear scalp composition with discrete particles |
| US20240277598A1 (en) | 2023-02-10 | 2024-08-22 | The Procter & Gamble Company | Silicone-free conditioning shampoo composition |
| CN117281752A (zh) * | 2023-08-25 | 2023-12-26 | 广东泛华生物科技有限公司 | 一种具有头皮和头发清洁保湿效果的组合物及其制备方法和应用 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005048959A1 (en) * | 2003-11-14 | 2005-06-02 | The Procter & Gamble Company | Personal care composition containing a cleansing phase and a benefit phase |
| CN1658830A (zh) * | 2002-06-04 | 2005-08-24 | 宝洁公司 | 包含凝胶网络的洗发剂 |
Family Cites Families (173)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US34584A (en) | 1862-03-04 | Improvement in rakes for harvesters | ||
| BE406221A (zh) | 1933-11-15 | |||
| US2326733A (en) | 1941-05-07 | 1943-08-10 | Us Ind Alcohol Co | Accelerator of vulcanization |
| US2438091A (en) | 1943-09-06 | 1948-03-16 | American Cyanamid Co | Aspartic acid esters and their preparation |
| BE498391A (zh) | 1944-10-16 | |||
| BE498392A (zh) | 1945-11-09 | |||
| US2528378A (en) | 1947-09-20 | 1950-10-31 | John J Mccabe Jr | Metal salts of substituted quaternary hydroxy cycloimidinic acid metal alcoholates and process for preparation of same |
| US2658072A (en) | 1951-05-17 | 1953-11-03 | Monsanto Chemicals | Process of preparing amine sulfonates and products obtained thereof |
| US2694668A (en) | 1952-03-10 | 1954-11-16 | Abbott Lab | Liquid multiple vitamin preparation and process of preparing the same |
| US2798053A (en) | 1952-09-03 | 1957-07-02 | Goodrich Co B F | Carboxylic polymers |
| US2826551A (en) | 1954-01-04 | 1958-03-11 | Simoniz Co | Nontangling shampoo |
| US2809971A (en) | 1955-11-22 | 1957-10-15 | Olin Mathieson | Heavy-metal derivatives of 1-hydroxy-2-pyridinethiones and method of preparing same |
| US2786847A (en) | 1956-07-23 | 1957-03-26 | Reilly Tar & Chem Corp | 2-mercapto, alkanol pyridine-nu-oxides |
| US3152046A (en) | 1956-11-09 | 1964-10-06 | Kapral Ales Maria | Selenium disulfide dispersions |
| GB849433A (en) | 1957-08-22 | 1960-09-28 | Raymond Woolston | Hair washing preparations |
| US3155591A (en) | 1961-12-06 | 1964-11-03 | Witco Chemical Corp | Hair rinse compostions of polyoxypropylene quaternary ammonium compounds |
| US3236733A (en) | 1963-09-05 | 1966-02-22 | Vanderbilt Co R T | Method of combatting dandruff with pyridinethiones metal salts detergent compositions |
| US3332880A (en) | 1965-01-04 | 1967-07-25 | Procter & Gamble | Detergent composition |
| US3761418A (en) | 1967-09-27 | 1973-09-25 | Procter & Gamble | Detergent compositions containing particle deposition enhancing agents |
| US3590035A (en) | 1967-12-21 | 1971-06-29 | Procter & Gamble | Process for preparing pyridine n-oxide carbanion salts |
| US3773770A (en) | 1968-09-30 | 1973-11-20 | Procter & Gamble | Process for preparing pyridine n-oxide carbanion salts and derivatives thereof |
| US3589999A (en) | 1968-10-25 | 1971-06-29 | Ionics | Deionization process |
| US3852441A (en) | 1970-12-14 | 1974-12-03 | Procter & Gamble | Synergistic mixtures of diphenylbismuth acetate and the zinc salt of 1-hydroxy-2-pyridine thione effect as antibacterial and antifungal agents |
| US3940482A (en) | 1971-04-21 | 1976-02-24 | Colgate-Palmolive Company | Solubilization of the zinc salt of 1-hydroxy-2-pyridinethione |
| US3753196A (en) | 1971-10-05 | 1973-08-14 | Kulite Semiconductor Products | Transducers employing integral protective coatings and supports |
| US3958581A (en) | 1972-05-17 | 1976-05-25 | L'oreal | Cosmetic composition containing a cationic polymer and divalent metal salt for strengthening the hair |
| CA1018893A (en) | 1972-12-11 | 1977-10-11 | Roger C. Birkofer | Mild thickened shampoo compositions with conditioning properties |
| US3964500A (en) | 1973-12-26 | 1976-06-22 | Lever Brothers Company | Lusterizing shampoo containing a polysiloxane and a hair-bodying agent |
| US4217914A (en) | 1974-05-16 | 1980-08-19 | L'oreal | Quaternized polymer for use as a cosmetic agent in cosmetic compositions for the hair and skin |
| US4422853A (en) | 1974-05-16 | 1983-12-27 | L'oreal | Hair dyeing compositions containing quaternized polymer |
| US3959461A (en) | 1974-05-28 | 1976-05-25 | The United States Of America As Represented By The Secretary Of Agriculture | Hair cream rinse formulations containing quaternary ammonium salts |
| US3929678A (en) | 1974-08-01 | 1975-12-30 | Procter & Gamble | Detergent composition having enhanced particulate soil removal performance |
| US4089945A (en) | 1975-06-30 | 1978-05-16 | The Procter & Gamble Company | Antidandruff shampoos containing metallic cation complex to reduce in-use sulfide odor |
| AT365448B (de) | 1975-07-04 | 1982-01-11 | Oreal | Kosmetische zubereitung |
| US4197865A (en) | 1975-07-04 | 1980-04-15 | L'oreal | Treating hair with quaternized polymers |
| US4055655A (en) | 1975-07-21 | 1977-10-25 | National Research Laboratories | Complexes of heavy metal ions and polyfunctional organic ligands used as antimicrobial agents |
| US4152416A (en) | 1976-09-17 | 1979-05-01 | Marra Dorothea C | Aerosol antiperspirant compositions delivering astringent salt with low mistiness and dustiness |
| US4161526A (en) | 1978-07-20 | 1979-07-17 | Sterling Drug Inc. | Zinc salt prevention or removal of discoloration in pyrithione, pyrithione salt and dipyrithione compositions |
| US4663158A (en) | 1979-07-02 | 1987-05-05 | Clairol Incorporated | Hair conditioning composition containing cationic polymer and amphoteric surfactant and method for use |
| US4507280A (en) | 1979-07-02 | 1985-03-26 | Clairol Incorporated | Hair conditioning composition and method for use |
| NZ194560A (en) | 1979-08-10 | 1984-05-31 | Unilever Ltd | Deodorant compositions containing zinc carbonate |
| US4323683A (en) | 1980-02-07 | 1982-04-06 | The Procter & Gamble Company | Process for making pyridinethione salts |
| US4345080A (en) | 1980-02-07 | 1982-08-17 | The Procter & Gamble Company | Pyridinethione salts and hair care compositions |
| US4379753A (en) | 1980-02-07 | 1983-04-12 | The Procter & Gamble Company | Hair care compositions |
| US4387090A (en) | 1980-12-22 | 1983-06-07 | The Procter & Gamble Company | Hair conditioning compositions |
| FR2478467A1 (fr) | 1980-03-21 | 1981-09-25 | Fabre Sa Pierre | Nouvelles compositions utiles notamment dans le traitement et la prevention des pellicules et contenant des derives metalliques de l'acide thiobenzoique |
| US4529586A (en) | 1980-07-11 | 1985-07-16 | Clairol Incorporated | Hair conditioning composition and process |
| US4364387A (en) | 1980-12-18 | 1982-12-21 | Abbott Laboratories | Connecting device for medical liquid containers |
| US4470982A (en) | 1980-12-22 | 1984-09-11 | The Procter & Gamble Company | Shampoo compositions |
| US4364837A (en) | 1981-09-08 | 1982-12-21 | Lever Brothers Company | Shampoo compositions comprising saccharides |
| ATE12730T1 (de) | 1981-10-21 | 1985-05-15 | Beecham Group Plc | Topische bakterizide zusammensetzungen. |
| US4565647B1 (en) | 1982-04-26 | 1994-04-05 | Procter & Gamble | Foaming surfactant compositions |
| DE3472103D1 (en) | 1983-07-06 | 1988-07-21 | Kao Corp | Finely powdered polyvalent metal salts of 2-mercaptopyridine-n-oxide, method for producing the same, and antibacterial compositions comprising the same |
| US4604272A (en) | 1984-07-06 | 1986-08-05 | Wacker-Chemie Gmbh | Process for the preparation of silicon tetrachloride |
| CA1261276A (en) | 1984-11-09 | 1989-09-26 | Mark B. Grote | Shampoo compositions |
| USRE34584E (en) | 1984-11-09 | 1994-04-12 | The Procter & Gamble Company | Shampoo compositions |
| US4608183A (en) | 1985-01-14 | 1986-08-26 | Board Of Governors Of Wayne State University | Synergistic antimicrobial or biocidal mixtures including isothiazolones |
| US4788006A (en) | 1985-01-25 | 1988-11-29 | The Procter & Gamble Company | Shampoo compositions containing nonvolatile silicone and xanthan gum |
| DE3504242A1 (de) | 1985-02-08 | 1986-08-14 | Henkel KGaA, 4000 Düsseldorf | Verfahren zur herstellung von tertiaeren etheraminen |
| US4666616A (en) | 1985-04-30 | 1987-05-19 | Board Of Governers Of Wayne State University | Synergistic antimicrobial or biocidal mixtures |
| GB2177108B (en) | 1985-07-10 | 1989-07-19 | Procter & Gamble | Shampoo compositions and method |
| US4704272A (en) | 1985-07-10 | 1987-11-03 | The Procter & Gamble Company | Shampoo compositions |
| US4686254A (en) | 1985-08-05 | 1987-08-11 | The B. F. Goodrich Company | Suspension composition for aqueous surfactant systems |
| HU200729B (en) | 1986-02-05 | 1990-08-28 | Mikrokemia Ipari Kisszoevetkez | Process for producing basic zinc carbonate |
| US5154847A (en) * | 1986-06-16 | 1992-10-13 | Helene Curtis, Inc. | Antidandruff shampoo composition having improved suspension properties |
| US4834767A (en) | 1987-06-10 | 1989-05-30 | Gaf Corporation | Compositions used in permanent alteration of hair color |
| US4885107A (en) | 1987-05-08 | 1989-12-05 | The Procter & Gamble Company | Shampoo compositions |
| US4898585A (en) | 1988-05-18 | 1990-02-06 | Baxter Healthcare Corporation | Implantable patient-activated fluid delivery device with bolus injection port |
| US5186928A (en) * | 1989-02-20 | 1993-02-16 | Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. | Shampoo composition |
| US5726137A (en) | 1989-06-21 | 1998-03-10 | Colgate-Palmolive Company | Low silicone hair conditioning shampoo and non-silicone hair conditioning/style control shampoo |
| US4997641A (en) | 1990-04-09 | 1991-03-05 | Colgate-Palmolive Company | Hair conditioning shampoo containing C6 -C10 alkyl sulfate or alkyl alkoxy sulfate |
| US5202048A (en) | 1989-06-30 | 1993-04-13 | The Procter & Gamble Company | Personal cleansing product with odor compatible bulky amine cationic polymer with reduced odor characteristics |
| US5106609A (en) | 1990-05-01 | 1992-04-21 | The Procter & Gamble Company | Vehicle systems for use in cosmetic compositions |
| US5104646A (en) | 1989-08-07 | 1992-04-14 | The Procter & Gamble Company | Vehicle systems for use in cosmetic compositions |
| US5114898A (en) | 1990-01-18 | 1992-05-19 | Board Of Trustees Operating Michigan State University | Layered double hydroxide sorbents for the removal of SOx from flue gas and other gas streams |
| US5057153A (en) | 1990-05-03 | 1991-10-15 | Olin Corporation | Paint containing high levels of a pyrithione salt plus a copper salt |
| US5034218A (en) | 1990-07-13 | 1991-07-23 | Helene Curtis, Inc. | Stable conditioning shampoo containing compatible anionic surfactant/cationic conditioning agent-non-volatile silicone emulsion |
| EP0610407B1 (en) | 1991-10-29 | 1996-08-28 | The Procter & Gamble Company | Shampoo compositions with silicone, cationic polymer, and oily liquid conditioning agents |
| US5248445A (en) | 1992-01-30 | 1993-09-28 | Helene Curtis, Inc. | Stable conditioning shampoo containing fatty acid |
| IL104233A0 (en) | 1992-01-30 | 1993-05-13 | Curtis Helene Ind Inc | Stable conditioning shampoo containing fatty acid/fatty alcohol blend |
| US5696169A (en) | 1992-03-13 | 1997-12-09 | Otsuka Pharmaceutical Co., Ltd. | Antibacterial and antifungal activity method, therapeutic method of infectious diseases and preserving method of cosmetics |
| US5227156A (en) | 1992-04-14 | 1993-07-13 | Amway Corporation | Use of zinc compounds to stabilize a thiazolinone preservative in an anti-dandruff shampoo |
| ZA931613B (en) | 1992-04-15 | 1993-11-15 | Curtis Helene Ind Inc | Conditioning shampoo composition and method of preparing and using the same |
| US5576279A (en) | 1993-05-17 | 1996-11-19 | Helene Curtis, Inc. | Stable conditioning shampoo containing an anionic surfactant a fatty alcohol, and polyethyleneimine |
| CA2123532A1 (en) | 1993-05-17 | 1994-11-18 | Daniel R. Pyles | Stable conditioning shampoo containing an anionic surfactant, a fatty alcohol, a silicone conditioner and polyethyleneimine |
| BR9406986A (pt) | 1993-06-30 | 1996-03-12 | Procter & Gamble | Xampus condicionadores contendo cátions de metal polivalente |
| WO1995020939A1 (en) | 1994-02-02 | 1995-08-10 | The Procter & Gamble Company | Hair care compositions containing low melting point fatty alcohol and an ethylene oxide/propylene oxide polymer |
| US5462589A (en) | 1994-02-22 | 1995-10-31 | Mississippi Forest Products Laboratory | Synergistic wood preservative compositions |
| US5478501A (en) | 1994-04-07 | 1995-12-26 | The Andrew Jergens Company | Bathing composition containing coated cationic polymer |
| US5466425A (en) | 1994-07-08 | 1995-11-14 | Amphion International, Limited | Biological decontamination system |
| US5614538A (en) | 1994-12-05 | 1997-03-25 | Olin Corporation | Synergistic antimicrobial composition containing pyrithione and alcohol |
| FR2728163A1 (fr) | 1994-12-20 | 1996-06-21 | Oreal | Composition cosmetique, dermatologique ou pharmaceutique stable contenant du disulfure de selenium et au moins un sel de zinc |
| US5562995A (en) | 1995-02-03 | 1996-10-08 | Olin Corporation | Discoloration prevention in pyrithione-containing coating compositions |
| US5939203A (en) | 1995-02-03 | 1999-08-17 | Arch Chemicals, Inc. | Discoloration prevention in pyrithione-containing coating compositions |
| DE19504914C1 (de) * | 1995-02-15 | 1995-11-16 | Goldwell Gmbh | Haarwaschmittel |
| US5928671A (en) | 1995-04-25 | 1999-07-27 | Winthrop University Hospital | Method and composition for inhibiting bacteria |
| US5518774A (en) | 1995-06-26 | 1996-05-21 | Olin Corporation | In-can and dry coating antimicrobial |
| FR2738482B1 (fr) | 1995-09-07 | 1997-10-24 | Oreal | Composition conditionnante et detergente a usage capillaire |
| EP0865272B1 (en) | 1995-10-16 | 2002-03-20 | The Procter & Gamble Company | Conditioning shampoo compositions having improved stability |
| WO1997014396A1 (en) | 1995-10-16 | 1997-04-24 | The Procter & Gamble Company | Conditioning shampoo compositions |
| WO1997014405A1 (en) | 1995-10-16 | 1997-04-24 | The Procter & Gamble Company | Conditioning shampoos containing polyalkylene glycol |
| US5854319A (en) | 1995-11-30 | 1998-12-29 | Lambent Technologies Inc | Reactive silicone emulsions containing amino acids |
| WO1997023449A1 (en) | 1995-12-21 | 1997-07-03 | Rhone-Poulenc Inc. | Anionic surfactants having multiple hydrophobic and hydrophilic groups |
| US5674478A (en) | 1996-01-12 | 1997-10-07 | The Procter & Gamble Company | Hair conditioning compositions |
| US5750122A (en) | 1996-01-16 | 1998-05-12 | The Procter & Gamble Company | Compositions for treating hair or skin |
| US5874476A (en) | 1997-07-14 | 1999-02-23 | Rohm And Haas Company | Dihaloformaldoxime carbamates as antimicrobial agents |
| DE19646867C1 (de) | 1996-11-13 | 1997-12-04 | Henkel Kgaa | Kosmetische Zubereitungen |
| US6204297B1 (en) | 1996-11-26 | 2001-03-20 | Rhodia Inc. | Nonionic gemini surfactants |
| DE19710149A1 (de) | 1997-03-12 | 1998-09-17 | Henkel Kgaa | Körperreinigungsmittel |
| DE19711417A1 (de) | 1997-03-19 | 1998-09-24 | Henkel Kgaa | Kosmetische Zubereitungen |
| US6017562A (en) | 1997-04-28 | 2000-01-25 | Arch Chemicals, Inc. | Non-spherical and non-platelet crystalline forms of pyrithione salts |
| US20020012646A1 (en) | 1997-05-06 | 2002-01-31 | Royce Douglas Allan | Shampoo compositions with cationic polymers |
| US5880076A (en) | 1997-08-04 | 1999-03-09 | Lever Brothers Company, Division Of Conopco, Inc. | Compositions comprising glycacarbamate and glycaurea compounds |
| US5939059A (en) | 1997-08-13 | 1999-08-17 | Akzo Nobel Nv | Hair conditioner and 2 in 1 conditioning shampoo |
| FR2772609B1 (fr) | 1997-12-19 | 2004-05-07 | Oreal | Utilisation d'au moins une auxine dans une composition cosmetique |
| US5977036A (en) * | 1998-02-03 | 1999-11-02 | The Procter & Gamble Company | Styling shampoo compositions |
| DE19814608C1 (de) * | 1998-04-01 | 1999-09-23 | Henkel Kgaa | Verfahren zur Herstellung von kosmetischen Reinigungsmitteln mit erhöhter Viskosität |
| GB9807271D0 (en) | 1998-04-03 | 1998-06-03 | Unilever Plc | Hair treatment compositions |
| GB9811754D0 (en) | 1998-06-01 | 1998-07-29 | Unilever Plc | Hair treatment compositions |
| FR2781368B1 (fr) | 1998-07-27 | 2000-09-01 | Oreal | Composition contenant un agent opacifiant ou nacrant et au moins un alcool gras |
| JP4069228B2 (ja) | 1998-09-30 | 2008-04-02 | 東邦化学工業株式会社 | 頭髪用化粧料に優れたコンディショニング特性を与えるカチオン性ポリマー |
| GB9824024D0 (en) | 1998-11-03 | 1998-12-30 | Unilever Plc | Shampoo compositions |
| US6034043A (en) | 1999-04-20 | 2000-03-07 | Lever Brothers Company, Division Of Conopco, Inc. | Mild antimicrobial liquid cleansing formulations comprising polyvalent cation or cations for improving an antimicrobial effectiveness |
| US6358914B1 (en) | 1999-06-17 | 2002-03-19 | Gladys S. Gabriel | Surfactant compositions with enhanced soil release properties containing a cationic gemini surfactant |
| US6495538B2 (en) | 1999-06-23 | 2002-12-17 | Zinc Therapeutics, Canada Inc. | Zinc ionophores as therapeutic agents |
| CA2375975C (en) | 1999-06-25 | 2011-11-22 | Arch Chemicals, Inc. | Pyrithione biocides enhanced by silver, copper, or zinc ions |
| WO2001017492A1 (en) * | 1999-09-03 | 2001-03-15 | The Procter & Gamble Company | A process for forming a hair care composition and a composition formed by same |
| DE19943668A1 (de) | 1999-09-13 | 2001-03-15 | Rwe Dea Ag | Tensidzusammensetzung enthaltend Geminitenside und Co-Amphiphile, ihre Herstellung und ihre Verwendung |
| US20020169283A1 (en) | 1999-10-21 | 2002-11-14 | Lu Peter S. | Clasp-7 transmembrane protein |
| AU2351300A (en) * | 1999-12-02 | 2001-06-12 | Procter & Gamble Company, The | Conditioning shampoo compositions |
| JP2001181145A (ja) * | 1999-12-27 | 2001-07-03 | Lion Corp | 毛髪化粧料 |
| JP4558122B2 (ja) | 2000-01-14 | 2010-10-06 | 株式会社資生堂 | 抗菌防カビ剤及び抗菌防カビ組成物 |
| DE10005162A1 (de) | 2000-02-08 | 2001-08-09 | Henkel Kgaa | Kosmetisches Mittel |
| AU2001250057A1 (en) * | 2000-04-12 | 2001-10-30 | Clairol Incorporated | Cationic emulsifier-enhanced liquid crystal gel network based skin care moisturizing compositions |
| JP4016238B2 (ja) * | 2000-04-28 | 2007-12-05 | ライオン株式会社 | 洗浄剤組成物及び洗浄剤組成物の製造方法 |
| IT1318571B1 (it) | 2000-06-09 | 2003-08-27 | Farmaka Srl | Composizioni cosmetiche per la cura del cuoio capelluto e dei capelli. |
| US20030185779A1 (en) | 2000-09-08 | 2003-10-02 | The Procter & Gamble Company | Hair care kits and heating devices for warming hair care compositions |
| JP2002104940A (ja) | 2000-09-28 | 2002-04-10 | Kawaken Fine Chem Co Ltd | シャンプー組成物 |
| DE10121724A1 (de) | 2001-05-04 | 2002-11-07 | Cognis Deutschland Gmbh | Geminitenside |
| DE10121723A1 (de) | 2001-05-04 | 2002-11-07 | Cognis Deutschland Gmbh | Geminitenside |
| US6608011B2 (en) | 2001-06-11 | 2003-08-19 | Colgate-Palmolive Company | Shampoos with behenyl-alcohol |
| DE10129034A1 (de) | 2001-06-15 | 2002-12-19 | Cognis Deutschland Gmbh | Verdicker für Haarpflegemittel |
| US6540479B2 (en) | 2001-07-16 | 2003-04-01 | William C. Liao | Axial flow fan |
| DE10137925A1 (de) | 2001-08-07 | 2003-02-20 | Cognis Deutschland Gmbh | Geminitenside und Polyethylenglycol |
| DE10150728A1 (de) | 2001-10-13 | 2003-04-17 | Cognis Deutschland Gmbh | Kosmetische und/oder pharmazeutische Zubereitungen |
| DE10150727A1 (de) | 2001-10-13 | 2003-04-17 | Cognis Deutschland Gmbh | Kosmetische und/oder pharmazeutische Zubereitungen |
| DE10150730A1 (de) | 2001-10-13 | 2003-04-17 | Cognis Deutschland Gmbh | Kosmetische und/oder pharmazeutische Zubereitungen |
| US6797683B2 (en) | 2002-03-04 | 2004-09-28 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Ordered liquid crystalline cleansing composition with benefit agent particles |
| US6812192B2 (en) | 2002-03-28 | 2004-11-02 | L'oreal S.A. | Foaming cosmetic compositions, uses for cleansing or make-up removal |
| KR100984906B1 (ko) | 2002-03-29 | 2010-10-01 | 가부시키가이샤 시세이도 | 복합 분체와 이를 포함하는 화장료 |
| MXPA04009515A (es) | 2002-04-22 | 2005-07-26 | Procter & Gamble | Uso de materiales con comportamiento de ionoforos de zinc. |
| JP3851312B2 (ja) | 2002-04-22 | 2006-11-29 | ザ プロクター アンド ギャンブル カンパニー | 水性界面活性剤組成物中に亜鉛含有物質を含むパーソナルケア組成物 |
| US8349301B2 (en) | 2002-06-04 | 2013-01-08 | The Procter & Gamble Company | Shampoo containing a gel network |
| US8367048B2 (en) | 2002-06-04 | 2013-02-05 | The Procter & Gamble Company | Shampoo containing a gel network |
| US9381382B2 (en) | 2002-06-04 | 2016-07-05 | The Procter & Gamble Company | Composition comprising a particulate zinc material, a pyrithione or a polyvalent metal salt of a pyrithione and a gel network |
| US8349302B2 (en) | 2002-06-04 | 2013-01-08 | The Procter & Gamble Company | Shampoo containing a gel network and a non-guar galactomannan polymer derivative |
| US8491877B2 (en) | 2003-03-18 | 2013-07-23 | The Procter & Gamble Company | Composition comprising zinc-containing layered material with a high relative zinc lability |
| US8361450B2 (en) | 2002-06-04 | 2013-01-29 | The Procter & Gamble Company | Shampoo containing a gel network and a non-guar galactomannan polymer derivative |
| US8470305B2 (en) | 2002-06-04 | 2013-06-25 | The Procter & Gamble Company | Shampoo containing a gel network |
| US20050202984A1 (en) | 2003-03-18 | 2005-09-15 | Schwartz James R. | Composition comprising zinc-containing layered material with a high relative zinc lability |
| US9381148B2 (en) | 2003-03-18 | 2016-07-05 | The Procter & Gamble Company | Composition comprising particulate zinc material with a high relative zinc lability |
| US8361448B2 (en) | 2002-06-04 | 2013-01-29 | The Procter & Gamble Company | Shampoo containing a gel network |
| JP2004262805A (ja) | 2003-02-28 | 2004-09-24 | Lion Corp | 毛髪洗浄剤組成物 |
| US20060251605A1 (en) | 2003-03-12 | 2006-11-09 | Belmar Maria T | Method to prepare personal care composition from a concentrate |
| US20040191331A1 (en) | 2003-03-18 | 2004-09-30 | The Procter & Gamble Company | Composition comprising particulate zinc materials having a defined crystallite size |
| JP2004307463A (ja) | 2003-03-26 | 2004-11-04 | Lion Corp | シャンプー組成物 |
| JP2004292387A (ja) | 2003-03-27 | 2004-10-21 | Lion Corp | シャンプー組成物 |
| JP2004292390A (ja) | 2003-03-27 | 2004-10-21 | Lion Corp | 毛髪洗浄剤組成物 |
| JP2005022983A (ja) | 2003-06-30 | 2005-01-27 | Lion Corp | シャンプー組成物の製造方法 |
| US6774096B1 (en) | 2003-10-09 | 2004-08-10 | Colgate-Palmolive Co. | Zinc oxide containing surfactant solution |
| JP2005187342A (ja) | 2003-12-24 | 2005-07-14 | Lion Corp | シャンプー組成物 |
| JP4129645B2 (ja) * | 2004-08-30 | 2008-08-06 | ライオン株式会社 | シャンプー組成物 |
| ES2379799T3 (es) | 2004-08-31 | 2012-05-03 | Hercules Incorporated | Procedimiento para preparar poligalactomanano catiónico de bajo peso molecular con olor reducido |
-
2005
- 2005-09-16 US US11/228,770 patent/US8349301B2/en active Active
- 2005-12-12 EP EP05853907A patent/EP1924237A1/en not_active Ceased
- 2005-12-12 JP JP2008531074A patent/JP5079700B2/ja active Active
- 2005-12-12 AU AU2005336930A patent/AU2005336930B2/en active Active
- 2005-12-12 CA CA2621660A patent/CA2621660C/en active Active
- 2005-12-12 ES ES17155314T patent/ES2850202T3/es active Active
- 2005-12-12 EP EP17155314.2A patent/EP3281619B1/en active Active
- 2005-12-12 BR BRPI0520546-8A patent/BRPI0520546A2/pt not_active Application Discontinuation
- 2005-12-12 CN CN2005800515952A patent/CN101267796B/zh active Active
- 2005-12-12 WO PCT/US2005/045093 patent/WO2007040571A1/en active Application Filing
-
2006
- 2006-07-18 BR BRPI0616042A patent/BRPI0616042B1/pt active IP Right Grant
- 2006-07-18 JP JP2008529716A patent/JP2009507066A/ja active Pending
- 2006-07-18 CN CN2006800341372A patent/CN101267797B/zh active Active
-
2008
- 2008-03-03 US US12/040,980 patent/US8361449B2/en not_active Expired - Lifetime
- 2008-03-14 MX MXPA08003719 patent/MX311278B/es unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1658830A (zh) * | 2002-06-04 | 2005-08-24 | 宝洁公司 | 包含凝胶网络的洗发剂 |
| WO2005048959A1 (en) * | 2003-11-14 | 2005-06-02 | The Procter & Gamble Company | Personal care composition containing a cleansing phase and a benefit phase |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2621660A1 (en) | 2007-04-12 |
| ES2850202T3 (es) | 2021-08-26 |
| BRPI0616042A2 (pt) | 2011-06-07 |
| AU2005336930A1 (en) | 2007-04-12 |
| HK1121959A1 (zh) | 2009-05-08 |
| BRPI0616042B1 (pt) | 2016-08-30 |
| US20080152611A1 (en) | 2008-06-26 |
| AU2005336930B2 (en) | 2012-02-02 |
| EP1924237A1 (en) | 2008-05-28 |
| JP5079700B2 (ja) | 2012-11-21 |
| CA2621660C (en) | 2012-07-17 |
| BRPI0520546A2 (pt) | 2009-05-12 |
| EP3281619A1 (en) | 2018-02-14 |
| WO2007040571A1 (en) | 2007-04-12 |
| JP2009507916A (ja) | 2009-02-26 |
| JP2009507066A (ja) | 2009-02-19 |
| CN101267797A (zh) | 2008-09-17 |
| MX2008003719A (en) | 2008-04-08 |
| US8361449B2 (en) | 2013-01-29 |
| CN101267796B (zh) | 2013-01-02 |
| US8349301B2 (en) | 2013-01-08 |
| MX311278B (en) | 2013-07-08 |
| EP3281619B1 (en) | 2021-01-20 |
| CN101267796A (zh) | 2008-09-17 |
| US20060024256A1 (en) | 2006-02-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101267797B (zh) | 包含凝胶网络的洗发剂 | |
| US8361448B2 (en) | Shampoo containing a gel network | |
| US8349302B2 (en) | Shampoo containing a gel network and a non-guar galactomannan polymer derivative | |
| US8361450B2 (en) | Shampoo containing a gel network and a non-guar galactomannan polymer derivative | |
| CN102014857B (zh) | 包含凝胶网络的洗发剂 | |
| EP2763748B1 (en) | Shampoo composition containing a gel network | |
| JP4708015B2 (ja) | ゲル網状組織を含有するシャンプー | |
| US20050143268A1 (en) | Personal care composition containing a cleansing phase and a benefit phase | |
| CN109803633A (zh) | 基本上不含硫酸化表面活性剂但含有凝胶网络的个人护理组合物 | |
| CA2421028A1 (en) | Shampoo compositions with cationic polymers | |
| JP2000507238A (ja) | ヘアケア組成物 | |
| CN109310586A (zh) | 包含凝胶网络的洗发剂组合物 | |
| EP0939619B1 (fr) | Compositions cosmetiques detergentes et utilisation | |
| JP2002363040A (ja) | 脂肪アルコールの混合物を含む毛髪コンディショニング組成物及び毛髪を処置する化粧方法 | |
| JP5426212B2 (ja) | 水性毛髪洗浄剤 | |
| MXPA06004594A (es) | Composicion de champu anticaspa. | |
| JP2011506280A (ja) | 身体手入れ組成物 | |
| JP2008509942A (ja) | 樹枝状ポリマーを含むヘアケア組成物 | |
| JP2007308448A (ja) | 水性毛髪洗浄剤 | |
| HK1121960B (zh) | 包含凝膠網絡的洗髮劑 | |
| JP2006182729A (ja) | 水性毛髪洗浄剤 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| REG | Reference to a national code |
Ref country code: HK Ref legal event code: DE Ref document number: 1121960 Country of ref document: HK |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| REG | Reference to a national code |
Ref country code: HK Ref legal event code: GR Ref document number: 1121960 Country of ref document: HK |