CN100550396C - Pixel and forming method thereof, storage capacitor, display panel and photoelectric device - Google Patents
Pixel and forming method thereof, storage capacitor, display panel and photoelectric device Download PDFInfo
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Abstract
一种像素及其形成方法,以及一种存储电容、显示面板及光电装置。存储电容设置于基板上,此存储电容包括半导体层、第一介电层、第一导电层、第二介电层以及第二导电层。其中半导体层设置于基板上,第一介电层则覆盖半导体层及基板,第一导电层部分设置于第一介电层上。第二介电层设置于第一导电层上,且第二介电层与第一导电层的侧边具有一斜度。而第二导电层则部分设置于第二介电层上。本发明可以提升存储电容的电容值,并保持像素呈像的稳定性。
A pixel and a method for forming the same, as well as a storage capacitor, a display panel and an optoelectronic device. The storage capacitor is disposed on a substrate, and the storage capacitor includes a semiconductor layer, a first dielectric layer, a first conductive layer, a second dielectric layer and a second conductive layer. The semiconductor layer is disposed on the substrate, the first dielectric layer covers the semiconductor layer and the substrate, and the first conductive layer is partially disposed on the first dielectric layer. The second dielectric layer is disposed on the first conductive layer, and the sides of the second dielectric layer and the first conductive layer have an inclination. The second conductive layer is partially disposed on the second dielectric layer. The present invention can increase the capacitance value of the storage capacitor and maintain the stability of the pixel image.
Description
技术领域 technical field
本发明涉及一种平板显示器,特别是涉及一种平板显示器的存储电容。The invention relates to a flat panel display, in particular to a storage capacitor of the flat panel display.
背景技术 Background technique
平板显示器的显示区是由数个像素所构成。每一像素具有一像素电极及一连接该像素电极的薄膜晶体管,且通过信号线传输信号给薄膜晶体管来开启或关闭。在像素电极提供电压之后,薄膜晶体管将关闭,直至下次由扫描线开启薄膜晶体管时再次重新将电压写入像素电极或自像素电极删除。The display area of a flat panel display is composed of several pixels. Each pixel has a pixel electrode and a thin film transistor connected to the pixel electrode, and the signal line transmits a signal to the thin film transistor to turn on or off. After the pixel electrode provides the voltage, the thin film transistor will be turned off until the voltage is written into or deleted from the pixel electrode again when the thin film transistor is turned on by the scan line next time.
然而,为了在下一次扫描线开启薄膜晶体管之前,能保持原先写入像素电极的电压,需要存储电容(Storage Capacitor,Cst)来增加整体的电容量,而使写入像素电极的电压能够保持一较长的时间。存储电容所能存储的电量和其两电极的面积成正比,且与其两电极之间的距离成反比。However, in order to maintain the voltage originally written into the pixel electrode before the next scan line turns on the thin film transistor, a storage capacitor (Storage Capacitor, C st ) is needed to increase the overall capacitance, so that the voltage written into the pixel electrode can be kept constant. longer time. The amount of electricity that a storage capacitor can store is proportional to the area of its two electrodes and inversely proportional to the distance between its two electrodes.
然而,由于对产品分辨率的要求日益增高,造成像素尺寸逐渐减小,为了不影响开口率,存储电容的面积势必将被压缩,造成电容量的下降。此外,由公知制造工艺所制得的存储电容,其介电层厚度至少要大于3000埃使得存储电容的电量的存储能力受到进一步的限制。为了能提升存储电容的电容值,以保持像素呈像的稳定性成为一重要的课题。However, due to the increasingly higher requirements for product resolution, the pixel size is gradually reduced. In order not to affect the aperture ratio, the area of the storage capacitor must be compressed, resulting in a decrease in capacitance. In addition, the thickness of the dielectric layer of the storage capacitor manufactured by the known manufacturing process must be at least greater than 3000 angstroms The storage capacity of the electric quantity of the storage capacitor is further restricted. In order to increase the capacitance of the storage capacitor, maintaining the stability of the pixel image becomes an important issue.
发明内容 Contents of the invention
本发明提供一种存储电容及其制造方法,能提升存储电容的电容值。The invention provides a storage capacitor and a manufacturing method thereof, which can increase the capacitance value of the storage capacitor.
本发明提出一种存储电容,其包括设置于基板上的半导体层,覆盖于半导体层与基板上的第一介电层,设置于部分第一介电层上的第一导电层,设置于第一导电层上的第二介电层,以及设置于部分第二介电层上的第二导电层。而第二介电层与第一导电层的堆叠侧边具有一斜度(taper)。The present invention proposes a storage capacitor, which includes a semiconductor layer disposed on a substrate, a first dielectric layer covering the semiconductor layer and the substrate, a first conductive layer disposed on part of the first dielectric layer, and disposed on the second dielectric layer. A second dielectric layer on a conductive layer, and a second conductive layer disposed on part of the second dielectric layer. The stacked sides of the second dielectric layer and the first conductive layer have a taper.
如上所述的存储电容,其中,该第一导电层及该第二导电层中至少一个包括透明材料、非透明材料、或上述之组合。The storage capacitor as described above, wherein at least one of the first conductive layer and the second conductive layer comprises a transparent material, a non-transparent material, or a combination thereof.
如上所述的存储电容,其中,该第一介电层及该第二介电层中至少一个包括有机材料、无机材料或上述之组合。In the above storage capacitor, at least one of the first dielectric layer and the second dielectric layer comprises organic material, inorganic material or a combination thereof.
如上所述的存储电容,其中,该半导体层包括单晶硅、多晶硅、非晶硅、微晶硅、或上述之组合。The storage capacitor as described above, wherein the semiconductor layer comprises single crystal silicon, polycrystalline silicon, amorphous silicon, microcrystalline silicon, or a combination thereof.
如上所述的存储电容,其中,该半导体层为掺杂N型、P型的该半导体层或上述之组合。The above-mentioned storage capacitor, wherein the semiconductor layer is doped with N-type, P-type or a combination thereof.
如上所述的存储电容,其中,该半导体层包括至少一第一掺杂区及至少一非掺杂区。In the above storage capacitor, the semiconductor layer includes at least one first doped region and at least one non-doped region.
如上所述的存储电容,其中,该半导体层包括至少一第一掺杂区、至少一非掺杂区及至少一轻掺杂区。In the above storage capacitor, the semiconductor layer includes at least one first doped region, at least one non-doped region and at least one lightly doped region.
如上所述的存储电容,其中,还包括蚀刻终止层,具有至少一第一部分,设置于部分第二介电层上。The above storage capacitor, further comprising an etching stop layer having at least a first portion disposed on a portion of the second dielectric layer.
如上所述的存储电容,其中,还包括蚀刻终止层,具有至少一第一部分及至少一第二部分,该第一部分设置于该第二介电层的两端其中之一上,该第二部分设置于远离该第二介电层的另一端上。The storage capacitor as described above, further comprising an etch stop layer having at least one first portion and at least one second portion, the first portion is disposed on one of the two ends of the second dielectric layer, and the second portion It is disposed on the other end away from the second dielectric layer.
如上所述的存储电容,其中,该第二介电层的厚度实质上小于3000埃 The storage capacitor as described above, wherein the thickness of the second dielectric layer is substantially less than 3000 angstroms
如上所述的存储电容,其中,该第二介电层的厚度实质上小于1000埃 The storage capacitor as described above, wherein the thickness of the second dielectric layer is substantially less than 1000 angstroms
如上所述的存储电容,其中,该第二介电层的厚度实质上介于200埃至3000埃 The above-mentioned storage capacitor, wherein the thickness of the second dielectric layer is substantially between 200 angstroms to 3000 Angstroms
如上所述的存储电容,其中,该第二导电层电性连接于该半导体层。The above storage capacitor, wherein the second conductive layer is electrically connected to the semiconductor layer.
如上所述的存储电容,其中,该蚀刻终止层包括含硅材料层。The above storage capacitor, wherein the etch stop layer includes a silicon-containing material layer.
本发明提出的存储电容,适用于一种像素之中。像素设置于基板上,并包括切换元件区及电容区。此像素包括半导体层、第一介电层、第一导电层、第二介电层、内层介电层、源/漏极、保护层以及第二导电层。其中半导体层设置于基板上,第一介电层覆盖半导体层及基板。第一导电层则分别设置于切换元件区及电容区的第一介电层上。第二介电层则位于第一导电层上。部分蚀刻终止层设置于切换元件区的第二介电层上。内层介电层覆盖于基板上。源/漏极设置于该切换元件区的部分内层介电层上,且电性连接于切换元件区上的半导体层。保护层用于覆盖基板。第二导电层设置于部分保护层上,且电性连接该源/漏极其中之一,并经由保护层中及该内层介电层中至少一开口,设置于部分第二介电层上。The storage capacitor proposed by the present invention is suitable for a kind of pixel. The pixel is arranged on the substrate and includes a switching element area and a capacitor area. The pixel includes a semiconductor layer, a first dielectric layer, a first conductive layer, a second dielectric layer, an inner dielectric layer, a source/drain, a protection layer and a second conductive layer. The semiconductor layer is arranged on the substrate, and the first dielectric layer covers the semiconductor layer and the substrate. The first conductive layer is respectively disposed on the first dielectric layer in the switching element area and the capacitor area. The second dielectric layer is located on the first conductive layer. Part of the etch stop layer is disposed on the second dielectric layer in the switching element region. The inner dielectric layer covers the substrate. The source/drain is disposed on a part of the inner dielectric layer of the switching element region, and is electrically connected to the semiconductor layer on the switching element region. A protective layer is used to cover the substrate. The second conductive layer is disposed on a part of the protective layer, and is electrically connected to one of the source/drain electrodes, and is disposed on a part of the second dielectric layer through at least one opening in the protective layer and the inner dielectric layer. .
如上所述的像素,其中,该第一导电层及该第二导电层中至少一个包括透明材料、非透明材料、或上述之组合。The aforementioned pixel, wherein at least one of the first conductive layer and the second conductive layer comprises a transparent material, a non-transparent material, or a combination thereof.
如上所述的像素,其中,该第一介电层、该第二介电层及该内层介电层中至少一个包括有机材料、无机材料或上述之组合。In the aforementioned pixel, at least one of the first dielectric layer, the second dielectric layer and the inner dielectric layer comprises organic material, inorganic material or a combination thereof.
如上所述的像素,其中,该半导体层包括单晶硅、多晶硅、非晶硅、微晶硅、或上述之组合。The aforementioned pixel, wherein the semiconductor layer comprises single crystal silicon, polycrystalline silicon, amorphous silicon, microcrystalline silicon, or a combination thereof.
如上所述的像素,其中,该切换元件区及该电容区上的该半导体层中至少一个为掺杂N型、P型的该半导体层或上述之组合。The aforementioned pixel, wherein at least one of the semiconductor layer on the switching element region and the capacitor region is doped with N-type, P-type semiconductor layer or a combination thereof.
如上所述的像素,其中,该切换元件区及该电容区上的该半导体层中至少一个包括至少一第一掺杂区及至少一非掺杂区。The aforementioned pixel, wherein at least one of the switching element region and the semiconductor layer on the capacitor region includes at least one first doped region and at least one non-doped region.
如上所述的像素,其中,该切换元件区及该电容区上的该半导体层中至少一个包括至少一第一掺杂区、至少一非掺杂区及至少一轻掺杂区。The above pixel, wherein at least one of the switching element region and the semiconductor layer on the capacitor region includes at least one first doped region, at least one non-doped region and at least one lightly doped region.
如上所述的像素,其中,另一部分蚀刻终止层具有至少一第一部分,设置于部分第二介电层上。The aforementioned pixel, wherein another part of the etch stop layer has at least a first part disposed on a part of the second dielectric layer.
如上所述的像素,其中,另一部分蚀刻终止层具有至少一第一部分及至少一第二部分,该第一部分设置于该第二介电层的两端其中之一上,该第二部分设置于远离该第二介电层的另一端上。The above pixel, wherein another part of the etch stop layer has at least one first part and at least one second part, the first part is arranged on one of the two ends of the second dielectric layer, and the second part is arranged on on the other end away from the second dielectric layer.
如上所述的像素,其中,该蚀刻终止层包括含硅材料层。The above pixel, wherein the etch stop layer includes a silicon-containing material layer.
如上所述的像素,其中,该第二介电层与该第一导电层的堆叠侧边实质上具有斜度(taper)。The aforementioned pixel, wherein the stacked sides of the second dielectric layer and the first conductive layer substantially have a taper.
如上所述的像素,其中,该第二介电层的厚度实质上小于3000埃 The pixel as above, wherein the thickness of the second dielectric layer is substantially less than 3000 Angstroms
如上所述的像素,其中,该第二介电层的厚度实质上小于1000埃 The pixel as above, wherein the thickness of the second dielectric layer is substantially less than 1000 Angstroms
如上所述的像素,其中,该第二介电层的厚度实质上介于200埃至3000埃 The pixel as described above, wherein the thickness of the second dielectric layer is substantially between 200 Angstroms to 3000 Angstroms
如上所述的像素,其中,还包括连接层,以电性连接该切换元件区及该电容区上的该半导体层。The aforementioned pixel further includes a connecting layer for electrically connecting the switching element region and the semiconductor layer on the capacitor region.
如上所述的像素,其中,该连接层包括单晶硅、多晶硅、非晶硅、微晶硅、透明材料、非透明材料、或上述之组合。The aforementioned pixel, wherein the connecting layer comprises single crystal silicon, polycrystalline silicon, amorphous silicon, microcrystalline silicon, transparent material, non-transparent material, or a combination thereof.
本发明所提供的像素适用于显示面板中,显示面板包括上述像素以及信号线。The pixel provided by the present invention is applicable to a display panel, and the display panel includes the above-mentioned pixel and signal lines.
本发明所提供的显示面板则适用于组装成显示器。显示器包括背光源及上述的显示面板。背光源作为显示器主要光线来源。The display panel provided by the invention is suitable for being assembled into a display. The display includes a backlight source and the above-mentioned display panel. The backlight is the main source of light for the display.
本发明所提供的显示器可适用于一种光电装置。光电装置包括电子元件及上述的显示器。The display provided by the invention can be applied to an optoelectronic device. The optoelectronic device includes electronic components and the above-mentioned display.
本发明另外提出一种像素的制造方法,此像素设置于基板上,并具有切换元件区及电容区。此方法包括:形成至少一半导体层于切换元件区与电容区的该基板上;形成至少一第一介电层,以覆盖半导体层与基板;依次形成至少一第一导电层、至少一第二介电层及至少一蚀刻终止层于第一介电层上;图案化第一导电层、第二介电层及蚀刻终止层以便在切换元件区上形成一栅极堆叠及在电容区之上形成一电容堆叠;形成至少一内层介电层,以覆盖栅极堆叠、电容堆叠及第一介电层;形成至少一源/漏极于切换元件区的部分内层介电层上,其中源/漏极电性连接于切换元件区的半导体层;形成至少一保护层,以覆盖源/漏极及内层介电层;图案化保护层及内层介电层,以形成接触窗及开口于保护层之中,且开口暴露出该蚀刻终止层;选择性蚀刻该蚀刻终止层,直至部分第二介电层暴露出来为止;以及形成至少一第二导电层于部分保护层上,其中第二导电层经由接触窗电性连接于源/漏极其中之一,并经由保护层中的开口设置于所暴露出的部分第二介电层上。The invention further provides a manufacturing method of a pixel, the pixel is arranged on a substrate and has a switching element area and a capacitor area. The method includes: forming at least one semiconductor layer on the substrate of the switching element region and the capacitor region; forming at least one first dielectric layer to cover the semiconductor layer and the substrate; sequentially forming at least one first conductive layer, at least one second a dielectric layer and at least one etch stop layer on the first dielectric layer; patterning the first conductive layer, the second dielectric layer and the etch stop layer to form a gate stack on the switching element area and on the capacitor area forming a capacitor stack; forming at least one inner dielectric layer to cover the gate stack, the capacitor stack and the first dielectric layer; forming at least one source/drain on a part of the inner dielectric layer in the switching element region, wherein The source/drain is electrically connected to the semiconductor layer in the switching element region; at least one protective layer is formed to cover the source/drain and the inner dielectric layer; the protective layer and the inner dielectric layer are patterned to form a contact window and opening in the protection layer, and the opening exposes the etching stop layer; selectively etching the etching stop layer until part of the second dielectric layer is exposed; and forming at least one second conductive layer on part of the protection layer, wherein The second conductive layer is electrically connected to one of the source/drain electrodes through the contact window, and is disposed on the exposed part of the second dielectric layer through the opening in the protective layer.
如上所述的形成方法,其中,该第一导电层及该第二导电层中至少一个包括透明材料、非透明材料、或上述之组合。The above forming method, wherein at least one of the first conductive layer and the second conductive layer comprises a transparent material, a non-transparent material, or a combination thereof.
如上所述的形成方法,其中,该第一介电层、该第二介电层及该内层介电层中至少一个包括有机材料、无机材料或上述之组合。The above forming method, wherein at least one of the first dielectric layer, the second dielectric layer and the inner dielectric layer comprises organic material, inorganic material or a combination thereof.
如上所述的形成方法,其中,该半导体层包括单晶硅、多晶硅、非晶硅、微晶硅、或上述之组合。The forming method as described above, wherein the semiconductor layer comprises single crystal silicon, polycrystalline silicon, amorphous silicon, microcrystalline silicon, or a combination thereof.
如上所述的形成方法,其中,该切换元件区及该电容区上的该半导体层中至少一个为掺杂N型、P型的该半导体层或上述之组合。The above forming method, wherein at least one of the semiconductor layer on the switching element region and the capacitor region is doped with N-type, P-type semiconductor layer or a combination thereof.
如上所述的形成方法,其中,该切换元件区及该电容区上的该半导体层中至少一个,包括至少一第一掺杂区及至少一非掺杂区。The forming method as described above, wherein at least one of the switching element region and the semiconductor layer on the capacitor region includes at least one first doped region and at least one non-doped region.
如上所述的形成方法,其中,该切换元件区及该电容区上的该半导体层中至少一个包括至少一第一掺杂区、至少一非掺杂区及至少一轻掺杂区。The above forming method, wherein at least one of the semiconductor layer on the switching element region and the capacitor region includes at least one first doped region, at least one non-doped region and at least one lightly doped region.
如上所述的形成方法,其中,该蚀刻终止层包括含硅材料层。The above forming method, wherein the etch stop layer includes a silicon-containing material layer.
如上所述的形成方法,其中,该第二介电层与该第一导电层的堆叠侧边实质上具有斜度。The above forming method, wherein the stacked sides of the second dielectric layer and the first conductive layer substantially have a slope.
如上所述的形成方法,其中,该第二介电层的厚度实质上小于3000埃 The forming method as described above, wherein the thickness of the second dielectric layer is substantially less than 3000 Angstroms
如上所述的形成方法,其中,该第二介电层的厚度实质上小于1000埃 The forming method as described above, wherein the thickness of the second dielectric layer is substantially less than 1000 Angstroms
如上所述的形成方法,其中,该第二介电层的厚度实质上为200埃至3000埃 The forming method as described above, wherein the thickness of the second dielectric layer is substantially 200 angstroms to 3000 Angstroms
如上所述的形成方法,其中,该栅极堆叠包括该第一导电层、该第二介电层及该蚀刻终止层。The above forming method, wherein the gate stack includes the first conductive layer, the second dielectric layer and the etch stop layer.
如上所述的形成方法,其中,在图案化该第一导电层、该第二介电层及该蚀刻终止层,以便在该切换元件区上形成栅极堆叠及在该电容区之上形成电容堆叠的步骤时,使用具有不同透光度的掩模的黄光工艺,以删除该栅极堆叠上的部分蚀刻终止层。The forming method as described above, wherein the first conductive layer, the second dielectric layer and the etch stop layer are patterned so as to form a gate stack on the switching element region and a capacitor on the capacitor region During the stacking step, a yellow light process using masks with different transmittances is used to remove part of the etch stop layer on the gate stack.
如上所述的形成方法,其中,该栅极堆叠包括该第一导电层。The above forming method, wherein the gate stack includes the first conductive layer.
如上所述的形成方法,其中,该蚀刻终止层的厚度为约200埃至约3000埃。The above forming method, wherein the etch stop layer has a thickness of about 200 angstroms to about 3000 angstroms.
如上所述的形成方法,其中,在图案化该保护层及该内层介电层的步骤中,该内层介电层与该蚀刻终止层具有不同的蚀刻速率。The above forming method, wherein, in the step of patterning the passivation layer and the ILD layer, the ILD layer and the etch stop layer have different etching rates.
如上所述的形成方法,其中,在选择性蚀刻该蚀刻终止层的步骤中,该蚀刻终止层与该第二介电层具有不同的蚀刻速率。The forming method as described above, wherein, in the step of selectively etching the etch stop layer, the etch stop layer and the second dielectric layer have different etching rates.
本发明可以提升存储电容的电容值,并保持像素呈像的稳定性。与传统的存储电容相比较下,上述的存储电容不仅可将介电层的厚度降低至3000埃以下,使电容量大为提升外,还可依需求自行控制电容介电层的厚度,同时保有较佳的开口率。The invention can increase the capacitance value of the storage capacitor and maintain the stability of the pixel image. Compared with traditional storage capacitors, the above storage capacitors can not only reduce the thickness of the dielectric layer to 3000 Angstroms In addition to greatly improving the capacitance, the thickness of the dielectric layer of the capacitor can also be controlled according to the requirements, while maintaining a better aperture ratio.
为让本发明的上述和其他目的、特征和优点能更明显易懂,下面特列举较佳实施例,并配合附图,作详细说明。In order to make the above and other objects, features and advantages of the present invention more comprehensible, preferred embodiments are listed below and described in detail with accompanying drawings.
附图说明 Description of drawings
为让本发明的上述和其他目的、特征、优点与实施例能更明显易懂,附图的详细说明如下:In order to make the above and other objects, features, advantages and embodiments of the present invention more comprehensible, the detailed description of the accompanying drawings is as follows:
图1根据显示本发明一个实施例的一种液晶显示器中像素的俯视图。FIG. 1 shows a top view of a pixel in a liquid crystal display according to an embodiment of the present invention.
图2A-2E显示图1的像素各层的俯视图。2A-2E show top views of various layers of the pixel of FIG. 1 .
图3显示图1的像素沿AA’线的剖面图。FIG. 3 shows a cross-sectional view of the pixel of FIG. 1 along line AA'.
图4A-4F显示图3的像素在各工艺阶段剖面图。4A-4F show cross-sectional views of the pixel of FIG. 3 at various process stages.
图5显示根据本发明一个实施例的双栅极像素的俯视图。FIG. 5 shows a top view of a dual-gate pixel according to one embodiment of the present invention.
图6是本发明的光电装置的示意图。Fig. 6 is a schematic diagram of an optoelectronic device of the present invention.
其中,附图标记说明如下:Wherein, the reference signs are explained as follows:
100:像素 102:切换元件区100: pixel 102: switching element area
104:电容区 106:基板104: capacitor area 106: substrate
107:轻掺杂区 108:半导体层107: lightly doped region 108: semiconductor layer
109:沟道区 110:第一介电层109: channel region 110: first dielectric layer
112:第一导电层 113:残留层112: first conductive layer 113: residual layer
114:第二介电层 115:残留层114: Second dielectric layer 115: Residual layer
116:牺牲层 117:电容堆叠116: Sacrificial layer 117: Capacitor stack
118:栅极堆叠 120:内层介电层118: Gate stack 120: Inner dielectric layer
122:源/漏极 124:源/漏极122: source/drain 124: source/drain
126:保护层 128:开口126: protective layer 128: opening
130:接触窗 132:像素电极130: Contact window 132: Pixel electrode
132a:电极 136:信号线132a: Electrode 136: Signal line
134:扫描线 140:栅极134: Scanning line 140: Gate
138:栅极 200:光电装置138: grid 200: photoelectric device
210:显示面板 220:电子元件210: Display panel 220: Electronic components
具体实施方式 Detailed ways
请参照图1,其显示根据本发明一个实施例的一种液晶显示器中的像素俯视示意图。在图1中,像素100位于基板106上、由扫描线134与信号线136交错所划分出来的区域,其具有一切换元件区102与一电容区104。在本实施例中,于电容区104处设有一电容堆叠117,而于切换元件区102处设有一薄膜晶体管,用以作为像素的开关控制,其中薄膜晶体管的栅极堆叠118与扫描线134连接,源/漏极122则分别和信号线136与位于切换元件区102处的半导体层108作电性连接,另一源/漏极124则与电容区104处的半导体层108以及像素电极132电性连接。此外,电容区104处的电容堆叠117作为存储电容使用,电容堆叠117包括有部分半导体层108与部分第一导电层112、电极132a以及位于两两间的介电层(未显示),其中电极132a为像素电极132的一部分。Please refer to FIG. 1 , which shows a schematic top view of pixels in a liquid crystal display according to an embodiment of the present invention. In FIG. 1 , the
图2A-2E显示如图1所示的像素各层的俯视图。如图2A所示,首先,基板106上具有一半导体层108,而于切换元件区102处的半导体层108,则预先定义出半导体层108何处为第一掺杂区105及沟道区109,而沟道区109,因未掺杂任何杂质,也称为未掺杂区。2A-2E show top views of various layers of the pixel shown in FIG. 1 . As shown in FIG. 2A, firstly, there is a
请参照图2B,在半导体层108之上具有由第一介电层所形成的绝缘层(未显示),在电容区104的半导体层108的绝缘层上依次具有第一导电层112、第二介电层(未显示)以及牺牲层(未显示)。而于切换元件区102处的半导体层108的沟道区109上,则设有栅极堆叠118,且栅极堆叠118与扫描线134相连。在本实施例中,是以在第一导电层形成后,即,栅极堆叠118形成后,以第一掺杂工艺使得半导体层预先定义出半导体层何处为第一掺杂区105及沟道区109之处,形成第一掺杂区及沟道区为例。此外,于沟道区109的两侧之一中,则是以栅极堆叠118为掩模进行第二掺杂工艺,选择性定义出的掺杂区107。由于掺杂区107的浓度,较佳地,实质上小于第一掺杂区105的浓度,因此也称为轻掺杂区107。而第一掺杂区105也称为重掺杂区或源/漏区。虽然,第一掺杂区105、沟道区109及轻掺杂区107为本实施例在不同时间形成的,但也可在同一时间形成。其次,形成第一掺杂区105、轻掺杂区107及沟道区109也可选择性的在栅极堆叠118形成之前通过一道黄光工艺及一离子植入工艺来形成,例如:形成光致抗蚀剂于半导体层108或第一介电层上,经由曝光过程使得光致抗蚀剂形成阶梯状(stepped)或斜坡状(taper),并利用第一掺杂工艺来同时形成第一掺杂区105、轻掺杂区107及沟道区109、或是在栅极堆叠118形成之前通过一道黄光工艺及一离子植入工艺来形成,例如:形成光致抗蚀剂于第一介电层或第一导电层上,经黄光及蚀刻工艺使得第一介电层及/或第一导电层形成阶梯状(stepped)或斜坡状(taper),并利用第一掺杂工艺来同时形成第一掺杂区105、轻掺杂区107及沟道区109。其次,于不同时间形成轻掺杂区107与第一掺杂区105及沟道区109,则可选择于第一掺杂区105及沟道区109形成于半导体层形成之后、该第一介电层形成之后及第一导电层之后其中之一,再形成光致抗蚀剂于半导体层108上、第一介电层及第一导电层上其中之一,经由曝光过程使得光致抗蚀剂暴露出预定的轻掺杂区107位置,并利用第二掺杂工艺来形成轻掺杂区107。Please refer to FIG. 2B, an insulating layer (not shown) formed by a first dielectric layer is provided on the
接着,如图2C所示,于基板106上设有一内层介电层(未显示),以覆盖上述所有形成的元件。而于栅极堆叠118远离电容区104之一侧的内层介电层上,则设有源/漏极122,其电性连接于信号线136与半导体层108的第一掺杂区105。而于栅极堆叠118靠近电容区104的另一侧的内层介电层上,则设有源/漏极124经由一孔洞(未标注)与半导体层的第一掺杂区105电性连接。Next, as shown in FIG. 2C , an interlayer dielectric layer (not shown) is provided on the
再来,如图2D所示,于基板上设置一保护层(未显示),以覆盖所有元件。并且于保护层、内层介电层及牺牲层(未显示)中形成开口128,以暴露出下方的第二介电层114,同时于源/漏极124上方设置接触窗130于保护层中以暴露出部分源/漏极124。此外,接触窗130可选择实质上对准或不对准孔洞(未标注)。Next, as shown in FIG. 2D , a protective layer (not shown) is disposed on the substrate to cover all components. And an
最后,如图2E所示,一像素电极132设置于保护层(未显示)之上,并且填入接触窗130与开口128,进而电性连接源/漏极124,并且形成电容堆叠117中的一电极132a。较佳地,像素电极132是顺序地形成于该接触窗130与开口128中。Finally, as shown in FIG. 2E , a
接着,下文中将详述上述存储电容与像素各层的结构,而为了简化附图并易于解说,图3对应于图1的AA’线绘制。如图3所示,基板106及位于其上的半导体层108具有切换元件区102及电容区104。作为存储电容的电容堆叠117位于电容区104之上,包括有半导体层108、第一介电层110、第一导电层112、第二介电层114以及电极132a。存储电容的两侧壁为内层介电层120所覆盖。如图所示,第一介电层110则覆盖于半导体层108及基板106上。于部分第一介电层110上,则依次具有第一导电层112与第二介电层114,此外,第二介电层114与第一导电层112的堆叠侧边实质上具有一斜度(taper),也称为一斜坡结构。保护层126覆盖于已形成的结构之上。保护层126中具有一开口128暴露出部分或全部的第二介电层114。像素电极132部分设置于保护层126上且设置于开口128内,而位于开口128底部的像素电极作为存储电容的一个电极132a。残留层113、115在删除牺牲层(未显示)的工艺中残留于第二介电层114之上的牺牲层。因此,残留层113、115可选择性的分别位于第二介电层114的一端之上、全部位于第二介电层114的一端之上(例如:只有一个以上的残留层113/115)、或残留层113、115不存在于电容区104的第二介电层114上,但不限于此,残留层113/115也能设置于部分第二介电层114上,例如:实质上位于远离第二介电层的两端之上、实质上位于第二介电层的中央处、或其它位置、或上述之组合。其次,本发明的实施例是以两个残留层为实施实例,也能实施于一个残留层或不具有残留层的情形。Next, the structure of the storage capacitor and each layer of the pixel will be described in detail below, and in order to simplify the drawing and facilitate explanation, FIG. 3 is drawn corresponding to the line AA' of FIG. 1 . As shown in FIG. 3 , the
接着,请再参照图3,在切换元件区102的基板106之上具有半导体层108,第一介电层110覆盖半导体层108及基板106。一栅极堆叠118位于切换元件区102的第一介电层110上。栅极堆叠118包括第一导电层112及第二介电层114,另可选择性的包括牺牲层116。内层介电层120覆盖于基板106上。源/漏极122/124设置于切换元件区102的部分内层介电层120上,且电性连接于切换元件区102上的半导体层108。保护层126则覆盖于基板106上。像素电极132设置于部分保护层126上,且电性连接源/漏极124。半导体层108具有一沟道区109实质上位于栅极堆叠118的下方,而在沟道区109的两侧之一中具有至少一轻掺杂区107,本发明的实施例是以沟道区109的两侧具有轻掺杂区107为实施实例,但不限于此结构。源/漏极122/124与半导体层108的接触点分别位于轻掺杂区107的外侧,也就是连接于半导体层108的第一掺杂区105。此外,上述第一介电层、第二介电层、内层介电层及保护层中至少一个包括有机材料(如:光致抗蚀剂、聚甲基丙酰酸甲酯、聚碳酸酯、聚醇类、聚烯类、聚亚胺类(polyimide)、苯并环丁烯(Benzocyclobutene,BCB)、parylene-N(PA)、含碳氧氢硅化物、或其它材料、或上述之组合)、无机材料(如:氧化硅、氮化硅、氮氧化硅、碳化硅、或其它材料、或上述之组合)、或上述之组合。Next, please refer to FIG. 3 , there is a
请参阅图4A-4F,显示根据本发明上述图3的像素各工艺的阶段剖面图。请参见图4A,为对应至图2A沿AA’线的剖面图。此像素设置于基板106上,并且可区分为切换元件区102与电容区104。于基板106上形成半导体层108。接着,图案化半导体层108,并于图案化后以一掩模层遮蔽部分半导体层108于预定形成沟道区之处,对半导体层进行第一掺杂工艺,以形成第一掺杂区105与非掺杂区,其中非掺杂区作为沟道区109。半导体层108的形成方法与图案化方法,例如可为化学气相沉积法以及光刻,但不限于此,也可选择其它方法,例如:涂布法、网版印刷法、喷墨印刷法、或其它方法来形成图案化半导体层108。在此实施例中,半导体层108可为含硅材料,例如单晶硅、多晶硅、非晶硅、微晶硅、或其它含硅的材料、或上述之任意组合。而上述的第一掺杂工艺可为N掺杂或/及P掺杂,以使半导体层108成为N型、P型的半导体或上述之组合。Please refer to FIGS. 4A-4F , which show cross-sectional views of each process stage of the above-mentioned pixel in FIG. 3 according to the present invention. Please refer to FIG. 4A, which is a cross-sectional view corresponding to FIG. 2A along line AA'. The pixel is disposed on the
图4B为对应至图2B沿AA’线的剖面图。首先,在删除掩模层后,则于半导体层108与基板106上,形成第一介电层110。再于第一介电层110上,形成第一导电层112、第二介电层114及牺牲层116,较佳地,是依次形成上述层别(第一导电层112、第二介电层114及牺牲层116)。然后,图案化第一导电层112、第二介电层114及牺牲层116,较佳地,是同时图案化上述层别(第一导电层112、第二介电层114及牺牲层116),以分别于切换元件区102及电容区104之上形成栅极堆叠118与部分电容堆叠117。而为了降低短沟道效应,可以栅极堆叠118为掩模进行第二掺杂工艺,进而于沟道区109中至少一侧选择性地形成轻掺杂区107,进而使半导体层108包括非掺杂区、轻掺杂区107以及第一掺杂区105。然而,半导体层也可选择性地仅包括非掺杂区及第一掺杂区。其次,必需说明的是,上述掺杂工艺是以二次掺杂工艺来形成非掺杂区、轻掺杂区107以及第一掺杂区105于半导体层中,然而,不限于此,也可选择性地同时形成,例如:形成光致抗蚀剂于图案化半导体层108上,经由曝光过程使得光致抗蚀剂形成阶梯状(stepped)或斜坡(taper),并利用第一掺杂工艺来同时形成第一掺杂区105、轻掺杂区107及沟道区109或是通过一道黄光工艺、一道蚀刻工艺及一离子植入工艺来形成,例如:蚀刻第一介电层使其形成阶梯状或斜坡,并利用第一掺杂工艺来同时形成第一掺杂区105、轻掺杂区107及沟道区109。此外,本实施例是以在图案化半导体层时,即施行第一掺杂程序,但也可选择性地于形成第一介电层后,形成一道黄光工艺、一道蚀刻工艺及一离子植入工艺其中至少二个,来使得图案化半导体层同时形成或非同时形成第一掺杂区105、轻掺杂区107及沟道区109。或是形成第一介电层后,施行第一掺杂程序,以形成第一掺杂区105及沟道区109后,再于栅极堆叠或图案化第一导电层形成后,再以栅极堆叠及/或掩模层施行第二掺杂程序或图案化第一导电层及/或掩模层施行第二掺杂程序,以形成轻掺杂区。或是形成栅极堆叠或图案化第一导电层后,形成一道黄光工艺、一道蚀刻工艺及一离子植入工艺其中至少二个,来使得图案化半导体层同时形成或非同时形成第一掺杂区105、轻掺杂区107及沟道区109。Fig. 4B is a cross-sectional view corresponding to Fig. 2B along line AA'. First, after removing the mask layer, the
在此实施例中,图案化第一导电层112、第二介电层114及牺牲层116的步骤时,可使用一般光掩模的黄光工艺。此外,上述牺牲层116包括含硅材料层(如:非晶硅、单晶硅、多晶硅、微晶硅,或其它含硅的材料、或上述之组合),而第二介电层114的厚度实质上为200埃至3000埃较佳地实质上小于1000埃但不限于此。而牺牲层的厚度较佳地介于约200埃至约3000埃但不限于此。图案化之后的栅极堆叠及电容堆叠中至少一个堆叠侧边实质上具有一斜度(taper),斜度实质上小于90度,较佳地,斜度实质上小于70度,但不限于此。另外,图案化第一导电层112、第二介电层114及牺牲层116的步骤时也可选择性地使用具有不同透光度的光掩模(如:半色调光掩模、绕射光掩模、栅状图案光掩模、或其它类似的光掩模)的黄光工艺,来形成栅极堆叠及电容堆叠,运用不同透光度的光掩模来进行蚀刻工艺可将栅极堆叠上方的牺牲层116一并删除。In this embodiment, during the step of patterning the first
请参照图4C,为对应至图2C沿AA’线的剖面图。在栅极堆叠118、部分电容堆叠117及第一介电层110上,形成内层介电层120。然后,图案化切换元件区102处的部分内层介电层120及第一介电层110,以暴露出部分半导体层108表面。内层介电层120的形成方法,例如可为化学气相沉积法,但不限于此,也可选择其它方法,例如:涂布法、网版印刷法、喷墨印刷法、或其它方法来形成内层介电层120。接着,再于切换元件区102的部分内层介电层120上,形成源/漏极122/124,以与半导体层108的第一掺杂区105电性连接。Please refer to FIG. 4C, which is a cross-sectional view corresponding to FIG. 2C along line AA'. On the
请参照图4D,为对应图2D沿AA’线的剖面图。在源/漏极122/124及内层介电层120上,形成保护层126。接着,以牺牲层116作为蚀刻终止层,图案化保护层126及内层介电层120,以分别于切换元件区102及电容区104,形成接触窗130及开口128。进而于开口128处暴露出部分或全部牺牲层116,以及于接触窗130处暴露出部分或全部源/漏极124。Please refer to FIG. 4D, which is a cross-sectional view corresponding to FIG. 2D along line AA'. On the source/
于图案化的过程中,若使用蚀刻方法,则为了避免发生过度蚀刻的情形,内层介电层120与牺牲层116两者具有不同的蚀刻速率,以进行选择性蚀刻。据此,于删除开口128处的内层介电层120后,所暴露出的牺牲层116表面,会使蚀刻速率趋于减缓。当然,也可选择性地使用其它方式,来形成所需的图案化。In the patterning process, if an etching method is used, in order to avoid over-etching, the
接着,图4E也为对应图2D沿AA’线的剖面图。于图4E中,图案化电容区104的开口128处所露出的牺牲层116。在以蚀刻工艺图案化牺牲层116时,可选择性地在电容区104处的第二介电层114两端上,保留残留层113与115、或者,仅于部分第二介电层114的任一端上,保留含任一残留层113或115、或者是将残留层113与115完全删除、或是残留层113/115设置于部分第二介电层上,例如:实质上位于远离第二介电层的两端之上、实质上位于第二介电层的中央处、或其它位置、或上述之组合,这视开口128完全或部分暴露出牺牲层116而定。不过,无论牺牲层116是否残留于第二介电层114之上,都不会对整个存储电容的电性造成任何的影响。Next, FIG. 4E is also a cross-sectional view corresponding to FIG. 2D along line AA'. In FIG. 4E , the
同样地,在图案化时,为了避免过度蚀刻的情形发生,牺牲层116与第二介电层114也具有不同蚀刻速率,因此在删除电容区104处的牺牲层116后,所露出的部分第二介电层114表面,会使蚀刻速率再度下降。较佳地,牺牲层116与第二介电层114的蚀刻选择比实质上大于或实质上等于2,也就是,牺牲层116的蚀刻速率实质上大于第二介电层114的蚀刻速率。而本发明的上述实施例中的牺牲层116与第二介电层114分别是以非晶硅层与氧化硅层为实施例,但不限于此,也可分别选择性地选择牺牲层116的蚀刻速率实质上大于第二介电层114的蚀刻速率的材料。因此,以非晶硅层所构成的牺牲层116为实例,其蚀刻速率约为200A/min至约为10000A/min,而以氧化硅层所构成的第二介电层114为实例,其蚀刻速率约为小于或约等于100A/min。所以,非晶硅层与氧化硅层的蚀刻选择比实质上约为2至约为100,也就是说,二者的蚀刻选择比实质上大于或实质上等于2,且非晶硅层的蚀刻速率实质上大于氧化硅层,但不限于此实例中的材料及其相关资讯。Similarly, during patterning, in order to avoid excessive etching, the
请参照图4F,为对应图2E沿AA’线的剖面图。在图4F中,一第二导电层形成于部分保护层126上,以作为像素电极132使用。其中于切换元件区102处的源/漏极124上所形成的像素电极132,可进而与图案化半导体层108的第一掺杂区105电性连接。而于电容区104处保护层126中的开口128所暴露出的部分第二介电层114上所形成的像素电极132,则作为电极堆叠117中的一个电极132a。Please refer to FIG. 4F, which is a cross-sectional view corresponding to FIG. 2E along line AA'. In FIG. 4F , a second conductive layer is formed on a portion of the
在上述实施例中,第一导电层及第二导电层中至少一个包括透明材料(如:铟锡氧化物、铝锌氧化物、铟锌氧化物、镉锡氧化物、或其它材料、或上述之组合)、非透明材料(如:金、银、铜、铁、锡、铅、镉、钼、钕、钛、钽、鋡、钨、或上述材料的合金、或上述材料的氮化物、或上述材料的氧化物、或上述材料的氮氧化合物、或其它材料、或上述之组合)、或上述之组合。至于第一介电层、第二介电层、内层介电层及保护层中至少一个包括有机材料(如:光致抗蚀剂、聚甲基丙酰酸甲酯、聚碳酸酯、聚醇类、聚烯类、或其它材料、或上述之组合)、无机材料(如:氧化硅、氮化硅、氮氧化硅、碳化硅、或其它材料、或上述之组合)、或上述之组合。其次,本发明的像素电极是以透明材料(如:铟锡氧化物、铝锌氧化物、铟锌氧化物、镉锡氧化物、或其它材料、或上述之组合)为实例,也可选择性地使用非透明材料(如:金、银、铜、铁、锡、铅、镉、钼、钕、钛、钽、鋡、钨、或上述材料的合金、或上述材料的氮化物、或上述材料的氧化物、或上述材料的氮氧化合物、或其它材料、或上述之组合)、或半穿透反射的材料(如:部分为透明材料,而另一部分为非透明材料、材料本身就具有半穿透反射性质等)。In the above embodiments, at least one of the first conductive layer and the second conductive layer includes a transparent material (such as: indium tin oxide, aluminum zinc oxide, indium zinc oxide, cadmium tin oxide, or other materials, or the above-mentioned Combination), non-transparent materials (such as: gold, silver, copper, iron, tin, lead, cadmium, molybdenum, neodymium, titanium, tantalum, tantalum, tungsten, or alloys of the above materials, or nitrides of the above materials, or Oxides of the above materials, or oxynitrides of the above materials, or other materials, or a combination of the above), or a combination of the above. As for at least one of the first dielectric layer, the second dielectric layer, the inner layer dielectric layer and the protective layer includes an organic material (such as: photoresist, polymethyl methacrylate, polycarbonate, poly Alcohols, polyolefins, or other materials, or a combination of the above), inorganic materials (such as: silicon oxide, silicon nitride, silicon oxynitride, silicon carbide, or other materials, or a combination of the above), or a combination of the above . Secondly, the pixel electrode of the present invention is an example of a transparent material (such as: indium tin oxide, aluminum zinc oxide, indium zinc oxide, cadmium tin oxide, or other materials, or a combination of the above). Non-transparent materials (such as: gold, silver, copper, iron, tin, lead, cadmium, molybdenum, neodymium, titanium, tantalum, tantalum, tungsten, or alloys of the above materials, or nitrides of the above materials, or the above materials Oxides of the above materials, or nitrogen oxide compounds of the above materials, or other materials, or a combination of the above), or semi-transparent reflective materials (such as: part is a transparent material, while the other part is a non-transparent material, the material itself has a semi-transparent transflective properties, etc.).
此外,本发明上述实施例所述的像素也可具有双栅极的结构或双栅极以上的结构,如图5所示的栅极138与140为双栅极结构。由于像素结构的种种变化为本领域普通技术人员所熟知,因此不再一一赘述。其次,上述实施例的切换元件区上的切换元件是以顶栅型结构为实施例,但不限于此,也可选择性的使用其它形式的顶栅型结构、底栅型结构、其它切换元件结构。In addition, the pixel described in the above-mentioned embodiments of the present invention may also have a double-gate structure or a double-gate structure, and the
另外,本发明上述实施例所述的像素100中的栅极堆叠及电容堆叠的结构,都是以在栅极堆叠上具有牺牲层116保留于第二介电层上,但并不限于此,也可选择性地将部分牺牲层116保留于电容堆叠的第二介电层上、栅极堆叠上的第二介电层没有牺牲层116、电容堆叠上的第二介电层没有牺牲层116、或上述之组合。其次,本发明上述实施例的电容区及切换元件区上的半导体层是以整体形成的为实施例,但不限于此,也可选择电容区及切换元件区上的半导体层是断开的,而经由一连接层(未显示)连接电容区及切换元件区上的半导体层,或电容区及切换元件区上的半导体层是整体形成的,再经由一连接层(未显示)连接电容区及切换元件区上的半导体层,以增加其电子传输能力。其中,该连接层的材料包括透明材料(如:铟锡氧化物、铝锌氧化物、铟锌氧化物、镉锡氧化物、或其它材料、或上述之组合)、非透明材料(如:金、银、铜、铁、锡、铅、镉、钼、钕、钛、钽、鋡、钨、或上述材料的合金、或上述材料的氮化物、或上述材料的氧化物、或上述材料的氮氧化合物、或含硅的材料、或其它材料、或上述之组合)、或上述之组合。换言之,连接层可选择性地在第一导电层、半导体层、第二导电层及源极/漏极其中至少之一形成的同时来形成。In addition, the structures of the gate stack and the capacitor stack in the
图6是本发明的光电装置的示意图。请参照图6,本发明上述的实施例所述的显示面板210也应用于一光电装置200中,且显示面板210包括一矩阵基板(未显示)及一相对应于该矩阵基板的共用电极基板(未显示),该矩阵基板具有多个本发明上述的实施例所述的像素100。此光电装置300还具有一与显示面板210连接的电子元件220,如:控制元件、操作元件、处理元件、输入元件、存储元件、驱动元件、发光元件(如:无机发光二极管、有机发光二极管、冷阴极灯管、平面灯管、热阴极灯管、外部电极灯管、或其它类型灯管、或上述之组合)、感测元件(如:触控元件、光感测元件、温度感测元件、图象感测元件、或其它类型、或上述之组合)、充电元件、加热元件、保护元件、或其它功能元件、或上述之组合。而光电装置的类型包括便携式产品(如手机、摄像机、照相机、笔记本电脑、游戏机、手表、音乐播放器、电子邮件收发器、地图导航器、电子相片、或类似的产品)、影音产品(如影音放映器或类似的产品)、屏幕、电视、户内或户外看板、或投影仪内的面板等。另外,显示面板210包括液晶显示面板(如:透射型面板、半透射型面板、反射型面板、双面显示型面板、垂直配向型面板(VA)、平面切换型面板(IPS)、多域垂直配向型面板(MVA)、扭曲向列型面板(TN)、超扭曲向列型面板(STN)、图案垂直配向型面板(PVA)、超级图案垂直配向型面板(S-PVA)、改进的超大视角型面板(ASV)、边界电场切换型面板(FFS)、连续焰火状排列型面板(CPA)、轴对称排列微单元面板(ASM)、光学补偿弯曲排列型面板(OCB)、超级平面切换型面板(S-IPS)、改进的超级平面切换型面板(AS-IPS)、极端边缘电场切换型面板(UFFS)、高分子稳定配向型面板(PSA)、双视角型面板(dual-view)、三视角型面板(triple-view)、或彩色滤光片组合于矩阵之上(color filter on array;COA)型面板、或矩阵组合于彩色滤光片之上(array oncolor filter;AOC)型面板、或其它型面板、或上述之组合)、有机电激发光显示面板,至于选何面板,视其面板中的像素电极及漏极中至少一个所电性接触的材料,如:液晶层、有机发光层(如:小分子、高分子、或上述之组合)、或上述之组合而定。Fig. 6 is a schematic diagram of an optoelectronic device of the present invention. Please refer to FIG. 6, the
依据本发明的上述实施例可知,与传统的存储电容相比较下,上述制造工艺所制得的存储电容,不仅可将介电层的厚度降低至3000埃以下,使电容量大为提升外,还可依需求自行控制电容介电层的厚度,同时保有较佳的开口率。According to the above-mentioned embodiment of the present invention, compared with the traditional storage capacitor, the storage capacitor manufactured by the above manufacturing process can not only reduce the thickness of the dielectric layer to 3000 Angstroms In addition to greatly improving the capacitance, the thickness of the dielectric layer of the capacitor can also be controlled according to the requirements, while maintaining a better aperture ratio.
虽然本发明已以一实施例揭示如上,然其并非用以限定本发明,任何本领域普通技术人员,在不脱离本发明的精神和范围内,当可作各种的更动与润饰,因此本发明的保护范围当视随附的权利要求所界定的范围为准。Although the present invention has been disclosed above with an embodiment, it is not intended to limit the present invention. Any person skilled in the art can make various changes and modifications without departing from the spirit and scope of the present invention. Therefore, The protection scope of the present invention should be determined by the scope defined by the appended claims.
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