CN100540642C - 水溶性金属加工用润滑剂 - Google Patents
水溶性金属加工用润滑剂 Download PDFInfo
- Publication number
- CN100540642C CN100540642C CNB2004800049169A CN200480004916A CN100540642C CN 100540642 C CN100540642 C CN 100540642C CN B2004800049169 A CNB2004800049169 A CN B2004800049169A CN 200480004916 A CN200480004916 A CN 200480004916A CN 100540642 C CN100540642 C CN 100540642C
- Authority
- CN
- China
- Prior art keywords
- acid
- metal
- water
- salt
- metal salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000314 lubricant Substances 0.000 title claims abstract description 49
- 238000005555 metalworking Methods 0.000 title claims abstract description 32
- 229910052751 metal Inorganic materials 0.000 claims abstract description 53
- 239000002184 metal Substances 0.000 claims abstract description 51
- 150000003839 salts Chemical class 0.000 claims abstract description 48
- 239000002253 acid Substances 0.000 claims abstract description 38
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 10
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims abstract description 8
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 6
- 150000008301 phosphite esters Chemical class 0.000 claims abstract description 4
- 238000012545 processing Methods 0.000 claims description 13
- -1 boric acid ester Chemical class 0.000 claims description 8
- 239000003112 inhibitor Substances 0.000 claims description 4
- 239000006078 metal deactivator Substances 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 2
- 239000004327 boric acid Substances 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 230000015556 catabolic process Effects 0.000 claims 1
- 238000006731 degradation reaction Methods 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
- 238000005238 degreasing Methods 0.000 abstract description 6
- 239000002736 nonionic surfactant Substances 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 4
- 239000002585 base Substances 0.000 description 18
- 239000003921 oil Substances 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 150000007942 carboxylates Chemical class 0.000 description 6
- 229910019142 PO4 Inorganic materials 0.000 description 5
- ZTBLWUZDEWQUFK-UHFFFAOYSA-L dipotassium;2-(6-ethylpentadecyl)propanedioate Chemical compound [K+].[K+].CCCCCCCCCC(CC)CCCCCC(C([O-])=O)C([O-])=O ZTBLWUZDEWQUFK-UHFFFAOYSA-L 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 5
- 239000010452 phosphate Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 238000006065 biodegradation reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 description 3
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 3
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- YWWVWXASSLXJHU-AATRIKPKSA-N (9E)-tetradecenoic acid Chemical compound CCCC\C=C\CCCCCCCC(O)=O YWWVWXASSLXJHU-AATRIKPKSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- YNQGVRJFSHTULP-UHFFFAOYSA-N 11-hydroxyhexadecanoic acid Chemical compound CCCCCC(O)CCCCCCCCCC(O)=O YNQGVRJFSHTULP-UHFFFAOYSA-N 0.000 description 2
- YZZWFTBVPUSMSP-UHFFFAOYSA-N 2-ethyl-2-pentadecylpropanedioic acid Chemical compound CCCCCCCCCCCCCCCC(CC)(C(O)=O)C(O)=O YZZWFTBVPUSMSP-UHFFFAOYSA-N 0.000 description 2
- WFCSWCVEJLETKA-UHFFFAOYSA-N 2-piperazin-1-ylethanol Chemical compound OCCN1CCNCC1 WFCSWCVEJLETKA-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- IQWKYRKBHFUUKH-UHFFFAOYSA-N 8,13-dimethylicosanedioic acid Chemical compound OC(=O)CCCCCCC(C)CCCCC(C)CCCCCCC(O)=O IQWKYRKBHFUUKH-UHFFFAOYSA-N 0.000 description 2
- MXOJYOYEIQYFRR-UHFFFAOYSA-N 8,9-diphenylhexadecanedioic acid Chemical compound C=1C=CC=CC=1C(CCCCCCC(=O)O)C(CCCCCCC(O)=O)C1=CC=CC=C1 MXOJYOYEIQYFRR-UHFFFAOYSA-N 0.000 description 2
- ZKAKOLZJPBSNNJ-UHFFFAOYSA-N 9,12-dimethylicosa-8,12-dienedioic acid Chemical compound OC(=O)CCCCCCC=C(C)CCC(C)=CCCCCCCC(O)=O ZKAKOLZJPBSNNJ-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- YZXBAPSDXZZRGB-DOFZRALJSA-N arachidonic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O YZXBAPSDXZZRGB-DOFZRALJSA-N 0.000 description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 2
- 239000012964 benzotriazole Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 235000011180 diphosphates Nutrition 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- HPSSZFFAYWBIPY-UHFFFAOYSA-N malvalic acid Chemical compound CCCCCCCCC1=C(CCCCCCC(O)=O)C1 HPSSZFFAYWBIPY-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 2
- UTOPWMOLSKOLTQ-UHFFFAOYSA-N octacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O UTOPWMOLSKOLTQ-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- GPOGLVDBOFRHDV-UHFFFAOYSA-N (2-nonylphenyl) dihydrogen phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(O)O GPOGLVDBOFRHDV-UHFFFAOYSA-N 0.000 description 1
- YHGJECVSSKXFCJ-KUBAVDMBSA-N (6Z,9Z,12Z,15Z,18Z,21Z)-tetracosahexaenoic acid Chemical compound CC\C=C/C\C=C/C\C=C/C\C=C/C\C=C/C\C=C/CCCCC(O)=O YHGJECVSSKXFCJ-KUBAVDMBSA-N 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- IJBFSOLHRKELLR-BQYQJAHWSA-N (e)-dodec-5-enoic acid Chemical compound CCCCCC\C=C\CCCC(O)=O IJBFSOLHRKELLR-BQYQJAHWSA-N 0.000 description 1
- SBLKVIQSIHEQOF-OWOJBTEDSA-N (e)-octadec-9-enedioic acid Chemical compound OC(=O)CCCCCCC\C=C\CCCCCCCC(O)=O SBLKVIQSIHEQOF-OWOJBTEDSA-N 0.000 description 1
- GQVYBECSNBLQJV-QXMHVHEDSA-N (z)-tridec-2-enoic acid Chemical compound CCCCCCCCCC\C=C/C(O)=O GQVYBECSNBLQJV-QXMHVHEDSA-N 0.000 description 1
- OXFSTTJBVAAALW-UHFFFAOYSA-N 1,3-dihydroimidazole-2-thione Chemical compound SC1=NC=CN1 OXFSTTJBVAAALW-UHFFFAOYSA-N 0.000 description 1
- RAIPHJJURHTUIC-UHFFFAOYSA-N 1,3-thiazol-2-amine Chemical compound NC1=NC=CS1 RAIPHJJURHTUIC-UHFFFAOYSA-N 0.000 description 1
- OGYGFUAIIOPWQD-UHFFFAOYSA-N 1,3-thiazolidine Chemical compound C1CSCN1 OGYGFUAIIOPWQD-UHFFFAOYSA-N 0.000 description 1
- RUFPHBVGCFYCNW-UHFFFAOYSA-N 1-naphthylamine Chemical class C1=CC=C2C(N)=CC=CC2=C1 RUFPHBVGCFYCNW-UHFFFAOYSA-N 0.000 description 1
- MACMNSLOLFMQKL-UHFFFAOYSA-N 1-sulfanyltriazole Chemical class SN1C=CN=N1 MACMNSLOLFMQKL-UHFFFAOYSA-N 0.000 description 1
- FRPZMMHWLSIFAZ-UHFFFAOYSA-N 10-undecenoic acid Chemical compound OC(=O)CCCCCCCCC=C FRPZMMHWLSIFAZ-UHFFFAOYSA-N 0.000 description 1
- URWDPDWPICLURE-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O.CC(C)CCCCCCCCCCCCCCC(O)=O URWDPDWPICLURE-UHFFFAOYSA-N 0.000 description 1
- SNPQRYOQWLOTFA-UHFFFAOYSA-N 2,2-dimethyl-1,3-thiazolidine Chemical compound CC1(C)NCCS1 SNPQRYOQWLOTFA-UHFFFAOYSA-N 0.000 description 1
- GIXFALHDORQSOQ-UHFFFAOYSA-J 2,4,6,8-tetraoxido-1,3,5,7,2$l^{5},4$l^{5},6$l^{5},8$l^{5}-tetraoxatetraphosphocane 2,4,6,8-tetraoxide Chemical compound [O-]P1(=O)OP([O-])(=O)OP([O-])(=O)OP([O-])(=O)O1 GIXFALHDORQSOQ-UHFFFAOYSA-J 0.000 description 1
- GZMAAYIALGURDQ-UHFFFAOYSA-N 2-(2-hexoxyethoxy)ethanol Chemical compound CCCCCCOCCOCCO GZMAAYIALGURDQ-UHFFFAOYSA-N 0.000 description 1
- DQMLFUMEBNHPPB-UHFFFAOYSA-N 2-Methylthiazolidine Chemical compound CC1NCCS1 DQMLFUMEBNHPPB-UHFFFAOYSA-N 0.000 description 1
- KHPFIDDXCRYEHS-UHFFFAOYSA-N 2-butyloctadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(C(O)=O)CCCC KHPFIDDXCRYEHS-UHFFFAOYSA-N 0.000 description 1
- RZUDZAJRBFRQLS-UHFFFAOYSA-N 2-dodecylpropanedioic acid Chemical compound CCCCCCCCCCCCC(C(O)=O)C(O)=O RZUDZAJRBFRQLS-UHFFFAOYSA-N 0.000 description 1
- IPKIIZQGCWXJFM-UHFFFAOYSA-N 2-methyl-1-(4-nitrophenyl)sulfonylaziridine Chemical compound CC1CN1S(=O)(=O)C1=CC=C([N+]([O-])=O)C=C1 IPKIIZQGCWXJFM-UHFFFAOYSA-N 0.000 description 1
- SAOSCTYRONNFTC-UHFFFAOYSA-N 2-methyl-decanoic acid Chemical compound CCCCCCCCC(C)C(O)=O SAOSCTYRONNFTC-UHFFFAOYSA-N 0.000 description 1
- ADLXTJMPCFOTOO-FPLPWBNLSA-N 2-nonenoic acid Chemical compound CCCCCC\C=C/C(O)=O ADLXTJMPCFOTOO-FPLPWBNLSA-N 0.000 description 1
- QWGQAJUZRWMSJR-UHFFFAOYSA-N 2-propyloctadec-9-enoic acid Chemical compound CCCCCCCCC=CCCCCCCC(C(O)=O)CCC QWGQAJUZRWMSJR-UHFFFAOYSA-N 0.000 description 1
- WMRCTEPOPAZMMN-UHFFFAOYSA-N 2-undecylpropanedioic acid Chemical compound CCCCCCCCCCCC(C(O)=O)C(O)=O WMRCTEPOPAZMMN-UHFFFAOYSA-N 0.000 description 1
- WXBXVVIUZANZAU-UHFFFAOYSA-N 2E-decenoic acid Natural products CCCCCCCC=CC(O)=O WXBXVVIUZANZAU-UHFFFAOYSA-N 0.000 description 1
- KFJDQPJLANOOOB-UHFFFAOYSA-N 2h-benzotriazole-4-carboxylic acid Chemical compound OC(=O)C1=CC=CC2=NNN=C12 KFJDQPJLANOOOB-UHFFFAOYSA-N 0.000 description 1
- JSIAIROWMJGMQZ-UHFFFAOYSA-N 2h-triazol-4-amine Chemical compound NC1=CNN=N1 JSIAIROWMJGMQZ-UHFFFAOYSA-N 0.000 description 1
- HZIUHEQKVCPTAJ-UHFFFAOYSA-N 3-(2-ethylhexoxyphosphonoyloxymethyl)heptane Chemical compound CCCCC(CC)COP(=O)OCC(CC)CCCC HZIUHEQKVCPTAJ-UHFFFAOYSA-N 0.000 description 1
- UOOWECZOWUNYLA-CMDGGOBGSA-N 3-methyl-2-nonenoic acid Chemical compound CCCCCC\C(C)=C\C(O)=O UOOWECZOWUNYLA-CMDGGOBGSA-N 0.000 description 1
- OCVLSHAVSIYKLI-UHFFFAOYSA-N 3h-1,3-thiazole-2-thione Chemical compound SC1=NC=CS1 OCVLSHAVSIYKLI-UHFFFAOYSA-N 0.000 description 1
- KRHMGQFGGUBDJI-UHFFFAOYSA-N 4-ethyl-1-(2-hydroxyethoxy)octan-2-ol Chemical compound CCCCC(CC)CC(O)COCCO KRHMGQFGGUBDJI-UHFFFAOYSA-N 0.000 description 1
- STDXFMGAJMQOFF-UHFFFAOYSA-N 4-methyl lauric acid Chemical compound CCCCCCCCC(C)CCC(O)=O STDXFMGAJMQOFF-UHFFFAOYSA-N 0.000 description 1
- NFOBWBPFHRTVJQ-UHFFFAOYSA-N 4-methyltetradecanoic acid Chemical compound CCCCCCCCCCC(C)CCC(O)=O NFOBWBPFHRTVJQ-UHFFFAOYSA-N 0.000 description 1
- ROYFWQWGQUTENN-JXMROGBWSA-N 5-methyl-2-undecenoic acid Chemical compound CCCCCCC(C)C\C=C\C(O)=O ROYFWQWGQUTENN-JXMROGBWSA-N 0.000 description 1
- GDTPUEHGUWCYRY-UHFFFAOYSA-N 5-methyl-octadecanoic acid Chemical compound CCCCCCCCCCCCCC(C)CCCC(O)=O GDTPUEHGUWCYRY-UHFFFAOYSA-N 0.000 description 1
- HRQKXMSCZPCUSK-UHFFFAOYSA-N 5-methyltridec-2-enoic acid Chemical compound CCCCCCCCC(C)CC=CC(O)=O HRQKXMSCZPCUSK-UHFFFAOYSA-N 0.000 description 1
- NNNVXFKZMRGJPM-UHFFFAOYSA-N 6-Hexadecenoic acid Natural products CCCCCCCCCC=CCCCCC(O)=O NNNVXFKZMRGJPM-UHFFFAOYSA-N 0.000 description 1
- UCWJHQIJYSNORM-UHFFFAOYSA-N 6-propylnonanoic acid Chemical compound CCCC(CCC)CCCCC(O)=O UCWJHQIJYSNORM-UHFFFAOYSA-N 0.000 description 1
- YWWVWXASSLXJHU-UHFFFAOYSA-N 9E-tetradecenoic acid Natural products CCCCC=CCCCCCCCC(O)=O YWWVWXASSLXJHU-UHFFFAOYSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- KLSJWNVTNUYHDU-UHFFFAOYSA-N Amitrole Chemical compound NC1=NC=NN1 KLSJWNVTNUYHDU-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- MGJJRXIEFROZLZ-UHFFFAOYSA-N CCCCCCCCCCCCOP(O)=O Chemical compound CCCCCCCCCCCCOP(O)=O MGJJRXIEFROZLZ-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical class OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- YYVJAABUJYRQJO-UHFFFAOYSA-N Isomyristic acid Natural products CC(C)CCCCCCCCCCC(O)=O YYVJAABUJYRQJO-UHFFFAOYSA-N 0.000 description 1
- 241000721662 Juniperus Species 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- XQVWYOYUZDUNRW-UHFFFAOYSA-N N-Phenyl-1-naphthylamine Chemical compound C=1C=CC2=CC=CC=C2C=1NC1=CC=CC=C1 XQVWYOYUZDUNRW-UHFFFAOYSA-N 0.000 description 1
- 229920001774 Perfluoroether Polymers 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- VENIIVIRETXKSV-BQYQJAHWSA-N Ximenynic acid Chemical compound CCCCCC\C=C\C#CCCCCCCCC(O)=O VENIIVIRETXKSV-BQYQJAHWSA-N 0.000 description 1
- VENIIVIRETXKSV-UHFFFAOYSA-N Xionenynic acid Natural products CCCCCCC=CC#CCCCCCCCC(O)=O VENIIVIRETXKSV-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- LJOUMIFRRRQONS-KTKRTIGZSA-N [(z)-octadec-9-enoxy]boronic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCOB(O)O LJOUMIFRRRQONS-KTKRTIGZSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229940114079 arachidonic acid Drugs 0.000 description 1
- 235000021342 arachidonic acid Nutrition 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- KHAVLLBUVKBTBG-UHFFFAOYSA-N caproleic acid Natural products OC(=O)CCCCCCCC=C KHAVLLBUVKBTBG-UHFFFAOYSA-N 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- AZSFNUJOCKMOGB-UHFFFAOYSA-K cyclotriphosphate(3-) Chemical compound [O-]P1(=O)OP([O-])(=O)OP([O-])(=O)O1 AZSFNUJOCKMOGB-UHFFFAOYSA-K 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 229940008099 dimethicone Drugs 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- PKWPSDPYZFTKMB-UHFFFAOYSA-N dioctoxyborinic acid Chemical compound CCCCCCCCOB(O)OCCCCCCCC PKWPSDPYZFTKMB-UHFFFAOYSA-N 0.000 description 1
- HTDKEJXHILZNPP-UHFFFAOYSA-N dioctyl hydrogen phosphate Chemical compound CCCCCCCCOP(O)(=O)OCCCCCCCC HTDKEJXHILZNPP-UHFFFAOYSA-N 0.000 description 1
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 1
- 239000001177 diphosphate Substances 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical class [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 1
- HITGSTMNTATVPP-UHFFFAOYSA-L dipotassium;8,13-dimethylicosanedioate Chemical compound [K+].[K+].[O-]C(=O)CCCCCCC(C)CCCCC(C)CCCCCCC([O-])=O HITGSTMNTATVPP-UHFFFAOYSA-L 0.000 description 1
- ASQKVSNYBNCYBV-UHFFFAOYSA-L dipotassium;butyl phosphate Chemical compound [K+].[K+].CCCCOP([O-])([O-])=O ASQKVSNYBNCYBV-UHFFFAOYSA-L 0.000 description 1
- GWTCIAGIKURVBJ-UHFFFAOYSA-L dipotassium;dodecyl phosphate Chemical compound [K+].[K+].CCCCCCCCCCCCOP([O-])([O-])=O GWTCIAGIKURVBJ-UHFFFAOYSA-L 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- PMRYVIKBURPHAH-UHFFFAOYSA-N methimazole Chemical compound CN1C=CNC1=S PMRYVIKBURPHAH-UHFFFAOYSA-N 0.000 description 1
- WRKCIHRWQZQBOL-UHFFFAOYSA-N octyl dihydrogen phosphate Chemical compound CCCCCCCCOP(O)(O)=O WRKCIHRWQZQBOL-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920005862 polyol Chemical class 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229940096992 potassium oleate Drugs 0.000 description 1
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- NNNVXFKZMRGJPM-KHPPLWFESA-N sapienic acid Chemical compound CCCCCCCCC\C=C/CCCCC(O)=O NNNVXFKZMRGJPM-KHPPLWFESA-N 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229940045870 sodium palmitate Drugs 0.000 description 1
- GGXKEBACDBNFAF-UHFFFAOYSA-M sodium;hexadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCC([O-])=O GGXKEBACDBNFAF-UHFFFAOYSA-M 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 125000005472 straight-chain saturated fatty acid group Chemical group 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 150000003557 thiazoles Chemical class 0.000 description 1
- 150000003548 thiazolidines Chemical class 0.000 description 1
- WXBXVVIUZANZAU-CMDGGOBGSA-N trans-2-decenoic acid Chemical compound CCCCCCC\C=C\C(O)=O WXBXVVIUZANZAU-CMDGGOBGSA-N 0.000 description 1
- ZRXZRUIXXDQGSN-UHFFFAOYSA-N triazole-2,4-diamine Chemical class NC=1C=NN(N)N=1 ZRXZRUIXXDQGSN-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- SNDRYHUSDCHSDJ-UHFFFAOYSA-N tributyl(dodecyl)phosphanium Chemical compound CCCCCCCCCCCC[P+](CCCC)(CCCC)CCCC SNDRYHUSDCHSDJ-UHFFFAOYSA-N 0.000 description 1
- OKBQUWUVZGPEQZ-UHFFFAOYSA-N tributyl(hexadecyl)phosphanium Chemical compound CCCCCCCCCCCCCCCC[P+](CCCC)(CCCC)CCCC OKBQUWUVZGPEQZ-UHFFFAOYSA-N 0.000 description 1
- GAJQCIFYLSXSEZ-UHFFFAOYSA-N tridecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCOP(O)(O)=O GAJQCIFYLSXSEZ-UHFFFAOYSA-N 0.000 description 1
- 239000001226 triphosphate Substances 0.000 description 1
- 235000011178 triphosphate Nutrition 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 1
- 229960002703 undecylenic acid Drugs 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/042—Metal salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/049—Phosphite
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
- C10M2223/061—Metal salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/061—Esters derived from boron
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/245—Soft metals, e.g. aluminum
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
本发明提供一种水溶性金属加工用润滑剂，它特别适合用于铝材料的加压加工，并同时具有优良的加工性能和脱脂性能。该水溶性金属加工用润滑剂包含85质量%或更少的水(A)；5-75质量%的有机羧酸金属盐(B)，其中羧酸残基总计具有8或更多个碳原子并且酸/碱摩尔比为1∶0.5-1.1；1-50质量%的至少一种选自以下组的金属盐(C)：有机磷酸酯金属盐、有机亚磷酸酯金属盐、有机膦酸酯金属盐和有机硼酸酯金属盐，它们均具有总计8或更多个碳原子的烷基；和10-80质量%的非离子型表面活性剂(D)。
Description
技术领域
本发明涉及一种水溶性金属加工用润滑剂，更具体涉及一种优选用于金属材料(例如：钢、不锈钢、铝合金和铜)的锻造、加压加工、拉伸、减薄加工、弯曲、滚轧或压延，尤其是用于铝材料加压加工的水溶性金属加工用润滑剂。
背景技术
通常地，基于矿物油或基于蜡的加工油已经用于铝材料的加压加工。然而，基于矿物油的加工油由于缺乏形成令人满意油膜的性能，所以显示出差的加工性能，而基于蜡的加工油由于蜡在水中的不溶性，所以显示出差的脱脂性能。因此，需要开发具有优良加工性能和脱脂性能的金属加工用润滑剂。几种类型的水溶性金属加工用润滑剂已经公开于以下文献：例如由聚亚氧烷基乙二醇和二元羧酸组成的水溶性金属加工用润滑剂(日本专利公开(kokoku)No.39-14568)；具有14个或更多个碳原子的多元羧酸组成的水溶性金属加工用润滑剂(日本专利申请未决公开(kokai)No.58-160396)；由C12-C42脂族二羧酸和烷醇胺的反应产物组成的水溶性金属加工用润滑剂(日本专利申请未决公开(kokai)No.61-40400)；以及特定的磷酸酯(日本专利申请未决公开(kokai)No.2001-214183)。然而，这些水溶性金属加工用润滑剂并不令人满意，需要对其性能进行进一步改进。
发明内容
在这种情况下完成了本发明，本发明目的在于提供一种具有优良加工性能和脱脂性能的水溶性金属加工用润滑剂。
为了达到该目的，本发明人进行了深入研究，并且发现可以使用这样的水溶性金属加工用润滑剂来实现该目的，该水溶性金属加工用润滑剂以预定比例包含水、特定有机羧酸金属盐、特定有机磷酸酯金属盐或类似化合物，以及非离子型表面活性剂。本发明在此发现基础上完成。
因此，本发明的要点如下。
1.一种水溶性金属加工用润滑剂，包含85质量％或更少的水(A)；5-75质量％的有机羧酸金属盐(B)，其中羧酸残基总计具有8或更多个碳原子并且酸/碱摩尔比为1∶0.5-1.1；1-50质量％的至少一种选自以下组的金属盐(C)：有机磷酸酯金属盐、有机亚磷酸酯金属盐、有机膦酸酯金属盐和有机硼酸酯金属盐，它们均具有总计8或更多个碳原子的烷基；和10-80质量％的非离子型表面活性剂(D)。
2.一种如上述1所述的水溶性金属加工用润滑剂，进一步包含0.01-10质量％的生物降解抑制剂和/或金属去活化剂(E)。
3.一种如上述1所述的水溶性金属加工用润滑剂，其中包含75质量％或更少的用作组分(A)的水。
4.一种如上述1-3中任一项所述的水溶性金属加工用润滑剂，其中用作组分(B)或(C)的金属盐为碱金属盐、二价金属盐或三价金属盐。
5.一种如上述1所述的水溶性金属加工用润滑剂，它在40℃下的运动粘度是5-10,000mm2/s。
6.一种如上述1所述的水溶性金属加工用润滑剂，其中用于加工的金属是铝。
实施本发明的最佳方式
本发明的水溶性金属加工用润滑剂包含85质量％或更少的用作组分(A)的水，基于润滑剂的总量。水含量优选为75质量％，更优选50质量％或更低，尤其优选40质量％或更低。当水含量超过85质量％时，其加工性能降低。
用作水溶性金属加工用润滑剂组分(B)的有机羧酸金属盐具有总计8或更多个碳原子的羧酸根残基，并且其酸/碱摩尔比为1∶0.5-1.1。当羧酸根残基总计具有7或更少的碳原子时，其加工性能较差。因此，羧酸根残基优选具有12或更多个碳原子，更优选12-40个碳原子。当酸/碱摩尔比在1∶0.5-1.1的范围之外时，其加工性能较差。有机羧酸的实例包括以下。
(1)直链饱和脂肪酸：壬酸、月桂酸、棕榈酸、硬脂酸、山萮酸和褐煤酸。
(2)支化饱和脂肪酸：2-甲基癸酸、6-丙基壬酸、4-甲基月桂酸、12-甲基十三烷酸、4-甲基十四烷酸、2-乙基十四烷酸、14-甲基十七烷酸、16-甲基十七烷酸(异硬脂酸)、5-甲基十八烷酸和2-丁基十八烷酸。
(3)直链单烯不饱和脂肪酸：顺-2-壬烯酸、癸烯酸、10-十一碳烯酸、5-十二碳烯酸、2-十三碳烯酸、5-十四碳烯酸、肉豆蔻脑酸、顺-6-十六碳烯酸、反-9-十八碳烯二酸、油酸、顺-9-十碳烯酸、反-13-二十二碳烯酸和芥酸。
(4)支化单烯不饱和脂肪酸：3-甲基-2-壬烯酸、5-甲基-2-十一碳烯酸、5-甲基-2-十三碳烯酸和2-丙基-9-十八碳烯酸。
(5)多烯不饱和脂肪酸：hiragoic acid、亚油酸、亚麻酸、花生四烯酸、鰶鱼酸和尼生酸。
(6)炔酸：塔日酸、硬脂炔酸和西门木炔酸。
(7)脂环族脂肪酸：锦葵酸、副大风子酸和大风子烯酸。
(8)含氧的脂肪酸：桧酸、11-羟基十六烷酸(jalpinolic acid)、蓖麻油酸和十八碳三烯-4-酮酸。
(9)二元酸：癸二酸、十二烷二羧酸、十三烷二羧酸、乙基十六烷二羧酸、8，13-二甲基二十烷二酸(例如：IPS-22，Okamura Oil Mill，Lt d.的产品)，9，12-二甲基-8，12-二十碳二烯二酸(例如：IPU-22，Okamura Oil Mill，Ltd.的产品)以及8，9-二苯基十六烷二酸(ST-2P，Okamura Oil Mill，Ltd.的产品)。
在这些有机羧酸中，优选油酸、芥酸、棕榈酸、乙基十六烷二羧酸、8，13-二甲基二十烷二酸、9，12-二甲基-8，12-二十碳二烯二酸和8，9-二苯基十六烷二酸。
优选的形成上述有机羧酸金属盐的金属元素实例包括碱金属如锂、钠和钾；二价或三价金属元素如镁、钙、锌和铝。这些有机羧酸金属盐可以单独使用，也可以两种或多种结合使用。
有机羧酸金属盐的使用量为5-75质量％，优选5-60质量％，更优选10-40质量％，其基于润滑剂的总量。当金属盐的含量低于5质量％时，加工性能较差，然而当含量超过75质量％时，润滑剂则具有过高的粘度，使得处理如涂布性能变得困难。
本发明水溶性金属加工用润滑剂的组分(C)是至少一种选自以下组的金属盐：有机磷酸酯金属盐、有机亚磷酸酯金属盐、有机膦酸酯金属盐和有机硼酸酯金属盐，它们均具有总计8或更多个碳原子的烷基。当碳原子总数为7或更少时，加工性能较差。因此，碳原子总数优选为12或更多，更优选12-40。
上述有机磷酸酯金属盐由通式(1)或(2)表示：
R1O(R2O)P(＝O)OMe ...(1)
R3OP(＝O)(OMe)2 ...(2)
其中R1和R2各自表示总计具有8或更多个碳原子的烷基；R3表示具有8或更多个碳原子的烷基；和Me表示金属元素。
具体的实例包括辛基酸式磷酸酯金属盐、indecyl酸式磷酸酯金属盐、十三烷基酸式磷酸酯金属盐、油基酸式磷酸酯金属盐和月桂基磷酸酯金属盐。
可选地，还可以使用有机二磷酸酯；和有机多磷酸酯例如焦磷酸酯、三磷酸酯、三偏磷酸酯和四偏磷酸酯。
上述有机亚磷酸酯金属盐由通式(3)或(4)表示：
R1O(R2O)POMe ...(3)
R3OP(OMe)2 ...(4)
其中R1、R2、R3和Me具有如上相同的含义。
具体实例包括亚磷酸二油醇酯金属盐和壬基苯基亚磷酸酯金属盐。
上述有机膦酸酯金属盐由通式(5)或(6)表示：
R1(R2O)P(＝O)OMe ...(5)
R3P(＝O)(OMe)2 ...(6)
其中R1、R2、R3和Me具有如上所定义的相同含义。
具体实例包括单月桂基膦酸酯金属盐和单-2-乙基己基2-乙基己基膦酸酯金属盐。
上述有机硼酸酯由通式(7)或(8)表示：
R1O(R2O)BOMe ...(7)
R3OB(OMe)2 ...(8)
其中R1、R2、R3和Me具有如上述定义的相同含义。
具体实例包括二辛基硼酸酯金属盐和油基硼酸酯金属盐。
上述组分(C)的酸/碱摩尔比优选为1∶0.5-1.1。
组分(C)可以单独使用或两种或更多种结合使用。组分(C)的使用量为1-50质量％，优选2-20质量％，更优选5-10质量％，其以润滑剂的总量为基准。当组分(C)的含量小于1质量％时，加工性能较差，然而当含量超过50质量％时，不能获得与增加量相应的效果，这在经济上是不利的。
用作本发明水溶性金属加工用润滑剂的组分(D)的非离子型表面活性剂优选为乙二醇衍生物、丙三醇衍生物或多元醇衍生物。优选的非离子型表面活性剂的实例包括2-乙基己基二甘醇、一缩二丙二醇、丙三醇、二甘醇已醚和环氧乙烷-环氧丙烷共聚物(例如Nippon Oil &Fats Co.，Ltd.的产品Unilube 75DE2620、75DE25和50MB2)。组分(D)的分子量优选为15,000或更少，更优选50-13,000。组分(D)可以单独使用或两种或更多种结合使用。组分(D)的使用量是10-80质量％，优选20-60质量％，其以润滑剂的总量为基准。当使用量小于10质量％时，不能充分获得分散其它添加剂的效果，然而当使用量超过80质量％时，就不能获得与增加量相一致的效果，这在经济上是不利的。
用于本发明水溶性金属加工用润滑剂的上述组分(E)为生物降解抑制剂和/或金属去活化剂。
对生物降解抑制剂的类型没有特殊限定，其实例包括2，4-二羟基N-苯甲酰苯胺类化合物；巯基酰氨基羧酸类化合物或其盐；噻唑烷类化合物如二甲基噻唑烷、甲基噻唑烷和噻唑烷；聚乙烯亚胺；2-膦酰基丁烷-1，2，4-三羧酸或其盐；1-羟基乙叉基-1，1-二膦酸或其盐；三正丁基正十六烷基磷鎓、三正丁基正十二烷基磷鎓、四羟甲基磷鎓及其盐；和羟乙基哌嗪。这些物质可以单独使用或两种或更多种结合使用。
对金属去活化剂的类型没有特殊限定，其实例包括苯并三唑；羧基苯并三唑；噻唑如2-巯基噻唑和2-氨基噻唑；三唑如3-氨基三唑、4-氨基三唑、2，5-二氨基三唑、3-巯基三唑和3-氨基-5-三唑；和咪唑如2-巯基咪唑和2-巯基-1-甲基咪唑。这些物质可以单独使用或两种或更多种结合使用。
上述组分(E)的使用量优选为0.01-10质量％，其以润滑剂的总量为基准。当使用量小于0.01质量％时，加工性能可能较差，然而当使用量超过10质量％时，有时候就不能得到与增加量相应的效果，这在经济上是不利的。
从加工性能考虑，本发明水溶性金属加工用润滑剂的pH值优选为7-12，在40℃下的运动粘度优选为5-10,000mm2/s。当运动粘度小于5时，加工性能可能较差，然而当粘度超过10,000时，操作特性如涂布性能可能受到损害。
在不脱离本发明范围的情况下，根据需要可以将其它添加剂如抗氧化剂和消泡剂适当引入本发明的水溶性金属加工用润滑剂。这些添加剂可以单独使用或两种或更多种结合使用。
抗氧化剂的实例包括胺类例如烷基化的二苯胺、苯基-α-萘胺和烷基化的α-萘胺；酚类例如2，6-二叔丁基对甲酚；和含硫物质类，消泡剂的实例包括二甲聚硅氧烷和氟代醚。
根据需要所使用的上述添加剂的总量优选为10质量％或更少，更优选5质量％或更少，其以润滑剂的总量为基准。
实施例
接下来将通过实施例更详细地描述本发明，但是不应当认为其限制本发明。
实施例1-24和对比实施例1-7
(1)水溶性金属加工用润滑剂的制备
在所有情况下，将列于表1的组分按表1中所详列的量(以各自润滑剂的总量为基准)加入到水中，从而制备各自水溶性金属加工用润滑剂。表1中，通过将组分与水混合，接着除去水来制备水含量为0的润滑剂。
(2)性能评估
通过下列方法评估各个润滑剂的性能。结果显示于表1中。
1.润滑性测试
通过Bauden测试测定摩擦系数。
板样品：A5182，钢球：SUJ2(3/16英寸)，载荷：5千克，速度：20毫米/秒，滑动长度：50毫米，测试温度：室温(25℃)
2.脱脂测试
将各个润滑剂样品施加于板样品(A5182，80×60)，然后将板样品放置24小时。冲洗后，测定脱脂部分的百分比区域(％)。
3.生物降解测试
根据使用Easicult M的测试方法进行。
4.抗腐蚀测试
将板样品(A5182)在60℃下浸入各个润滑剂(30cc)中，在3天浸渍后观察板样品的外观。
5.测定运动粘度
根据JIS K 2283测定。
6.圆筒拉伸性能测试
冲头A：镀Cr的，冲头B：没有镀Cr的，板样品：铝A6022，冲头直径：Φ40，形成速度：200毫米/秒
评估：通过形成高度(mm)
7.板滑动测试
模具A：镀Cr的，模具B：没有镀Cr的，板样品：铝A6022，滑动速度：200毫米/秒
评估：通过摩擦系数
8.鼓凸测试
板样品：铝，冲头球形头直径：Φ100，镀Cr钢，形成速度：200毫米/秒
评估：通过鼓凸高度(mm)
9.可焊性测试
当润滑剂保留在样品上时对板样品进行弧光焊接。观察样品的弧光焊接部分的外观。
组分
A1 7-乙基十六烷二羧酸钾(酸/碱摩尔比为1∶0.9)
A2 油酸钾(酸/碱摩尔比1∶0.9)
A3 棕榈酸钠(酸/碱摩尔比1∶0.9)
A4 乙酸钠(酸/碱摩尔比1∶0.9)
A5 7-乙基十六烷二羧酸钾(酸/碱摩尔比为1∶1)
A6 7-乙基十六烷二羧酸钾(酸/碱摩尔比为1∶0.6)
A7 7-乙基十六烷二羧酸钾(酸/碱摩尔比为1∶0.3)
A8 7-乙基十六烷二羧酸钾(酸/碱摩尔比为1∶1.2)
A9 8，13-二甲基二十烷二酸钾(酸/碱摩尔比为1∶0.9)
A10 9，12-二甲基-8，12-二十碳二烯二酸钾(酸/碱摩尔比1∶0.9)
A11 8，9-二苯基十六烷二酸钾(酸/碱摩尔比1∶0.9)
A12 芥酸(酸/碱摩尔比1∶0.9)
B1 酸式磷酸单、二辛酯(酸/碱摩尔比1∶0.9)
B2 单月桂基磷酸钾(酸/碱摩尔比1∶0.9)
B3 单丁基磷酸钾(酸/碱摩尔比1∶0.9)
C1 一缩二丙二醇
C2 丙三醇
C3 环氧乙烷-环氧丙烷共聚物(NOF Corporation的产品，75DE2620)
D1 羟乙基哌嗪
E1 苯并三唑
对比实施例4：矿物油(运动粘度(40℃)；30mm2/s)+硫化油(10质量％)
对比实施例5：石蜡+磷酸三甲苯酯(10质量％)
工业实用性
根据本发明，可以提供一种水溶性金属加工用润滑剂，它特别适用于铝材料的加压加工，并具有优良的加工性能(例如润滑性、圆筒拉伸性、板滑动性、鼓凸成形性和可焊性)和脱脂性能。
Claims (6)
1.一种水溶性金属加工用润滑剂，它包含85质量％或更少的水(A)；5-75质量％的有机羧酸金属盐(B)，其中羧酸残基总计具有8或更多个碳原子并且酸/碱摩尔比为1∶0.5-1.1；1-50质量％的至少一种选自以下组的金属盐(C)：有机磷酸酯金属盐、有机亚磷酸酯金属盐、有机膦酸酯金属盐和有机硼酸酯金属盐，它们均具有总计8或更多个碳原子的烷基；和10-80质量％的非离子型表面活性剂(D)。
2.权利要求1所述的水溶性金属加工用润滑剂，它进一步包含0.01-10质量％的生物降解抑制剂和/或金属去活化剂(E)。
3.权利要求1所述的水溶性金属加工用润滑剂，其中包含75质量％或更少的用作组分(A)的水。
4.权利要求1所述的水溶性金属加工用润滑剂，其中用作组分(B)或(C)的金属盐为碱金属盐、二价金属盐或三价金属盐。
5.权利要求1所述的水溶性金属加工用润滑剂，它在40℃下的运动粘度是5-10,000mm2/s。
6.权利要求1所述的水溶性金属加工用润滑剂，其中进行加工的金属是铝。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003025477A JP4456817B2 (ja) | 2003-02-03 | 2003-02-03 | 水溶性金属加工用潤滑剤 |
| JP025477/2003 | 2003-02-03 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1753979A CN1753979A (zh) | 2006-03-29 |
| CN100540642C true CN100540642C (zh) | 2009-09-16 |
Family
ID=32844108
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004800049169A Expired - Fee Related CN100540642C (zh) | 2003-02-03 | 2004-02-03 | 水溶性金属加工用润滑剂 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US7833951B2 (zh) |
| JP (1) | JP4456817B2 (zh) |
| CN (1) | CN100540642C (zh) |
| WO (1) | WO2004069968A1 (zh) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4880880B2 (ja) * | 2004-03-31 | 2012-02-22 | 出光興産株式会社 | 水系金属材料加工用潤滑剤組成物 |
| JP3872492B2 (ja) * | 2005-06-01 | 2007-01-24 | 日本パーカライジング株式会社 | 固体に対する水系潤滑皮膜処理剤 |
| CN101432403B (zh) | 2006-04-28 | 2013-05-29 | 日产自动车株式会社 | 低摩擦润滑组件 |
| JP5232372B2 (ja) * | 2006-09-26 | 2013-07-10 | 株式会社ネオス | 水溶性金属加工油剤組成物 |
| JP5379487B2 (ja) * | 2006-09-29 | 2013-12-25 | 出光興産株式会社 | 圧縮型冷凍機用潤滑油、及びそれを用いた冷凍装置 |
| US20090149359A1 (en) * | 2007-12-10 | 2009-06-11 | Hundley Lloyd E | Formulation of a metal working fluid |
| JP5329126B2 (ja) * | 2008-05-27 | 2013-10-30 | Ｊｆｅスチール株式会社 | ラミネート金属板ｄｉ成形用水性クーラントおよびラミネート金属板のｄｉ成形方法 |
| CN103184095A (zh) * | 2011-12-28 | 2013-07-03 | 奎克化学公司 | 用于铝冷轧的水溶液润滑剂 |
| JP7024944B2 (ja) * | 2016-08-26 | 2022-02-24 | 出光興産株式会社 | 金属加工油組成物、及び金属加工方法 |
| DE102016122498A1 (de) * | 2016-11-22 | 2018-05-24 | Sms Group Gmbh | Verfahren zur hydrostatischen Abstützung von Arbeitswalzen für das Kaltwalzen hochfester und/oder dünner Bänder |
| DE102017215713A1 (de) * | 2017-09-06 | 2019-03-07 | Sms Group Gmbh | Verfahren zum Betrieb einer walz- oder hüttentechnischen Anlage |
| EP3620502A1 (de) * | 2018-09-10 | 2020-03-11 | Carl Bechem Gmbh | Zusammensetzung zur herstellung einer schmiermittelzusammensetzung |
| CN110951532B (zh) * | 2019-12-23 | 2022-03-11 | 苏州铱诺化学材料有限公司 | 铝翅片水性冲压油及其制备方法 |
| CN115537259B (zh) * | 2022-09-15 | 2023-11-03 | 湖北省化学工业研究设计院 | 一种不锈钢丝拉拔加工用的水基润滑剂及其制备方法 |
| WO2024106521A1 (ja) * | 2022-11-17 | 2024-05-23 | Ｅｎｅｏｓ株式会社 | 水溶性加工油原液組成物、及び、金属の加工方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1053638A (zh) * | 1990-01-23 | 1991-08-07 | 日本波克乃成株式会社 | 具有优良润滑性的金属表面处理组合物 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1513881A (en) * | 1974-07-12 | 1978-06-14 | Castrol Ltd | Hydraulic fluids |
| JPS6286096A (ja) | 1985-10-14 | 1987-04-20 | Yushiro Do Brazil Ind Chem Ltd | 塑性加工用潤滑剤 |
| JPS62129388A (ja) | 1985-11-29 | 1987-06-11 | Yushiro Do Brazil Ind Chem Ltd | 塑性加工用潤滑剤 |
| JPS62149795A (ja) | 1985-12-25 | 1987-07-03 | Yushiro Chem Ind Co Ltd | 塑性加工用潤滑剤 |
| US5368758A (en) * | 1992-10-13 | 1994-11-29 | The Lubrizol Corporation | Lubricants, greases and aqueous fluids containing additives derived from dimercaptothiadiazoles |
| US5561104A (en) * | 1992-10-15 | 1996-10-01 | Nippon Oil Co., Ltd. | Hydraulic working oil composition for buffers |
| US6310011B1 (en) * | 1994-10-17 | 2001-10-30 | The Lubrizol Corporation | Overbased metal salts useful as additives for fuels and lubricants |
| JPH11279581A (ja) * | 1998-03-26 | 1999-10-12 | Kyodo Yushi Co Ltd | 金属加工用水溶性油剤 |
| DE19833894A1 (de) * | 1998-07-28 | 2000-02-03 | Fuchs Dea Schmierstoffe Gmbh & | Wassermischbares Kühlschmierstoff-Konzentrat |
| US6103673A (en) * | 1998-09-14 | 2000-08-15 | The Lubrizol Corporation | Compositions containing friction modifiers for continuously variable transmissions |
| JP2000309793A (ja) | 1999-04-27 | 2000-11-07 | Nippon Parkerizing Co Ltd | 金属材料塑性加工用水系潤滑剤 |
| JP2002234112A (ja) | 2001-02-07 | 2002-08-20 | Kobe Steel Ltd | 成形加工用アルミニウム又はアルミニウム合金板 |
| JP2002226884A (ja) | 2001-02-07 | 2002-08-14 | Yuukou Shoji Kk | 金属の塑性加工用水性潤滑剤 |
| JP2002309281A (ja) | 2001-04-18 | 2002-10-23 | Neos Co Ltd | アルミニウム・アルミニウム合金用水溶性加工油組成物 |
-
2003
- 2003-02-03 JP JP2003025477A patent/JP4456817B2/ja not_active Expired - Fee Related
-
2004
- 2004-02-03 CN CNB2004800049169A patent/CN100540642C/zh not_active Expired - Fee Related
- 2004-02-03 WO PCT/JP2004/001062 patent/WO2004069968A1/ja active Application Filing
- 2004-02-03 US US10/544,345 patent/US7833951B2/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1053638A (zh) * | 1990-01-23 | 1991-08-07 | 日本波克乃成株式会社 | 具有优良润滑性的金属表面处理组合物 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20060240996A1 (en) | 2006-10-26 |
| WO2004069968A1 (ja) | 2004-08-19 |
| CN1753979A (zh) | 2006-03-29 |
| JP4456817B2 (ja) | 2010-04-28 |
| US7833951B2 (en) | 2010-11-16 |
| JP2004262960A (ja) | 2004-09-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100540642C (zh) | 水溶性金属加工用润滑剂 | |
| WO2015146908A1 (ja) | 水溶性金属加工油および金属加工用クーラント | |
| WO2011001554A1 (ja) | さび止め油組成物 | |
| JP2009242743A (ja) | 水溶性金属加工用潤滑剤 | |
| JP2009185084A (ja) | グリース組成物及び軸受 | |
| JP2557755B2 (ja) | 水可溶性潤滑剤組成物 | |
| CN111886326B (zh) | 水溶性金属加工油剂和金属加工方法 | |
| KR20180096608A (ko) | 금속 가공 유체 | |
| CN105754698A (zh) | 水溶性镁合金加工液 | |
| WO2006019548A1 (en) | Food grade lubricant compositions | |
| US20060205613A1 (en) | Grease composition for harnesses | |
| WO2015146909A1 (ja) | 水溶性金属加工油および金属加工用クーラント | |
| JP5281007B2 (ja) | 水性金属加工油剤 | |
| JP4398673B2 (ja) | 水溶性金属加工用潤滑剤 | |
| JP2613117B2 (ja) | 防錆兼金属加工油組成物 | |
| CA2466737C (en) | Aqueous functional fluids with antioxidants | |
| US4830768A (en) | Metalworking lubricant composition containing propoxylated fatty alcohol | |
| TW200536934A (en) | Water-based lubricant composition for metal working | |
| JP2012224795A (ja) | 水系作動液 | |
| JP3135007B2 (ja) | 塑性加工用潤滑剤 | |
| JPH11323363A (ja) | 水性冷間鍛造潤滑剤 | |
| JPH1143685A (ja) | 冷間圧延油組成物 | |
| JPH0641772A (ja) | 水溶性防錆剤組成物 | |
| JP6836037B2 (ja) | 塑性加工用潤滑油組成物 | |
| US20240336865A1 (en) | Novel additive mixture |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20090916 Termination date: 20160203 |