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AR083876A1 - 5-halogenopirazolcarboxamidas - Google Patents

5-halogenopirazolcarboxamidas

Info

Publication number
AR083876A1
AR083876A1 ARP110104253A ARP110104253A AR083876A1 AR 083876 A1 AR083876 A1 AR 083876A1 AR P110104253 A ARP110104253 A AR P110104253A AR P110104253 A ARP110104253 A AR P110104253A AR 083876 A1 AR083876 A1 AR 083876A1
Authority
AR
Argentina
Prior art keywords
optionally substituted
alkyl
groups
different
alkoxy
Prior art date
Application number
ARP110104253A
Other languages
English (en)
Original Assignee
Bayer Cropscience Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Cropscience Ag filed Critical Bayer Cropscience Ag
Publication of AR083876A1 publication Critical patent/AR083876A1/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/16—Halogen atoms or nitro radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • C07F7/0812—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)

Abstract

La presente se refiere a 5-halógenopirazol(tio)carboxamidas, su procedimiento de preparación, su uso como agentes activos fungicidas, particularmente en forma de composiciones fungicidas, y métodos para el control de hongos fitopatógenos, especialmente de plantas, usando estos compuestos o composiciones.Reivindicación 1: 1-Metil-3-dihalógenometil 5-halogenopirazolcarboxamidas de la fórmula (1) en la que T representa un átomo de oxígeno o azufre; R representa hidrógeno, alquil C1-6-sulfonilo, alcoxi C1-4-alquilo C1-4, haloalquil C1-4-sulfonilo, haloalcoxi C1-4-alquilo-C1-4 o formilo; Hal1 y Hal2 representan independientemente entre sí cloro o flúor; L representa fenilo que puede estar sustituido con hasta 4 grupos R1 idénticos o diferentes; Q representa fenilo que puede estar sustituido con hasta 5 grupos Rb iguales o diferentes; o Q representa halógeno; nitro; ciano; isonitrilo; hidroxilo; amino; sulfanilo; pentafluoro-l6-sulfanilo; formilo; formiloxi; formilamino; hidroxiimino-alquilo C1-8 opcionalmente sustituido; alcoxiimino C1-8-alquilo C1-8 opcionalmente sustituido; alqueniloxiimino C2-8-alquilo C1-8 opcionalmente sustituido; alquiniloxiimino C2-8-alquilo C1-8 opcionalmente sustituido; benciloxiimino-alquilo C1-8 opcionalmente sustituido; carboxilo; carbamoilo; N-hidroxicarbamoilo; carbamato; alquilo C1-16 opcionalmente sustituido; alquenilo C2-8 opcionalmente sustituido; alquinilo C2-8 opcionalmente sustituido; alcoxi C1-16 opcionalmente sustituido; alquil C1-8-sulfanilo opcionalmente sustituido; alquil C1-8-sulfinilo opcionalmente sustituido; alquil C1-8-sulfonilo opcionalmente sustituido; alquil C1-8-amino opcionalmente sustituido; dialquil C1-8-amino opcionalmente sustituido; alqueniloxi C2-8 opcionalmente sustituido; alquiniloxi C3-8 opcionalmente sustituido; cicloalquilo C3-8 opcionalmente sustituido; cicloalquilo C3-8-alquilo C1-8 opcionalmente sustituido; cicloalquil C3-8-cicloalquilo C3-8 opcionalmente sustituido; cicloalquil C3-8-alquenilo C2-8 opcionalmente sustituido; cicloalquil C3-8-alquinilo C2-8 opcionalmente sustituido; tri(alquil C1-8)sililo opcionalmente sustituido; tri(alquil C1-8)sililo-alquilo C1-8 opcionalmente sustituido; alquil C1-8-carbonilo opcionalmente sustituido; alquil C1-8-carboniloxi opcionalmente sustituido; alquil C1-8-carbonilamino opcionalmente sustituido; alcoxi C1-8-carbonilo opcionalmente sustituido; alquiloxi C1-8-carboniloxi opcionalmente sustituido; alquilcarbamoilo C1-8 opcionalmente sustituido; dialquilcarbamoilo C1-8 opcionalmente sustituido; alquil C1-8-aminocarboniloxi opcionalmente sustituido; dialquil C1-8-aminocarboniloxi opcionalmente sustituido; N-(alquil C1-8)-hidroxicarbamoilo opcionalmente sustituido; alcoxicarbamoilo C1-8 opcionalmente sustituido; N-(alquil C1-8)alcoxicarbamoilo C1-8 opcionalmente sustituido; arilalquilo C1-8 que está opcionalmente sustituido con hasta 6 grupos Rb idénticos o diferentes; arilalquenilo C2-8 que está opcionalmente sustituido con hasta 6 grupos Rb idénticos o diferentes; arilalquinilo C2-8 que está opcionalmente sustituido con hasta 6 grupos Rb idénticos o diferentes; ariloxi que está opcionalmente sustituido con hasta 6 grupos Rb idénticos o diferentes; arilsulfanilo que está opcionalmente sustituido con hasta 6 grupos Rb idénticos o diferentes; arilamino que está opcionalmente sustituido con hasta 6 grupos Rb idénticos o diferentes; arilalquiloxi C1-8 que está opcionalmente sustituido con hasta 6 grupos Rb idénticos o diferentes; arilalquil C1-8-sulfanilo que está opcionalmente sustituido con hasta 6 grupos Rb idénticos o diferentes; arilalquilamino C1-8 que está opcionalmente sustituido con hasta 6 grupos Rb iguales o diferentes o un grupo biciclo[2.2.1]heptanilo; R1, Rb independientemente entré sí representan halógeno; nitro, ciano, alquilo C1-12; haloalquilo C1-6 que tiene de 1 a 9 átomos de halógeno iguales o diferentes; alcoxi C1-6; haloalcoxi C1-6 que tiene de 1 a 9 átomos de halógeno iguales o diferentes; alquil C1-6-sulfanilo; haloalquil C1-6-sulfanilo que tiene de 1 a 9 átomos de halógeno iguales o diferentes; alquil C1-6-sulfonilo; haloalquil C1-6-sulfonilo que tiene de 1 a 9 átomos de halógeno iguales o diferentes; alquenilo C2-12; alquinilo C2-12; cicloalquilo C3-7; fenilo; tri(alquil C1-8)sililo; tri(alquil C1-8)silil-alquilo C1-8; donde, a menos que se indique otra cosa, un grupo o un sustituyente que está sustituido según la presente está sustituido con uno o más Rb; o Q y R1 junto con el átomo de carbono a los que están unidos forman un anillo heterocíclico saturado o carbocíclico de 5, 6 ó 7 miembros opcionalmente sustituido; o Q y L forman juntos un radical de la fórmula (2), donde el enlace marcado con * está unido a la amida; X representa un enlace sencillo o un enlace doble; Y representa oxígeno, azufre, N(R27) o (CR28R29)(CR30R31)m(CR32R33)n; m representa 0 ó 1; n representa 0 ó 1; R21 y R22 independientemente entre sí representan hidrógeno, halógeno, alquilo C1-4, alcoxi C1-4 o haloalcoxi C1-4; R23, R24, R25 y R26 independientemente entre sí representan hidrógeno, halógeno, alquilo C1-4, haloalquilo C1-4, alcoxi C1-4, haloalcoxi C1-4, alquiIsulfanilo C1-4, haloalquil C1-4-sulfanilo, hidroximetilo, alcoxi C1-4-metilo, C(O)CH3 o C(O)OCH3; R27 representa hidrógeno, alquilo C1-4, bencilo (donde el grupo fenilo está opcionalmente sustituido hasta tres veces con un radical seleccionado independientemente del grupo que consiste en halógeno, alquilo C1-4, haloalquilo C1-4 y alcoxi C1-4), formilo, C(O)-alquilo C1-4 (opcionalmente sustituido con halógeno o alcoxi C1-4), C(=O)O-alquilo C1-6 (opcionalmente sustituido con halógeno, alcoxi C1-4 o ciano) o alcoxi C1-4-alquileno C1-4; R28, R29, R30, R31, R32 y R33 independientemente entre sí representan hidrógeno, halógeno, hidroxilo, alcoxi C1-4, alquilo C1-6 [opcionalmente sustituido con halógeno, hidroxilo, alcoxi C1-4, =O, arilo, O-C(O)-alquilo C1-4 o un anillo carbocíclico de 3 - 7 miembros (que está él mismo opcionalmente sustituido con hasta tres grupos metilo)] o alquenilo C2-6 [opcionalmente sustituido con halógeno, hidroxilo, alcoxi C1-4, =O, arilo, O-C(O)-alquilo C1-4 o un anillo carbocíclico de 3 - 7 miembros (que está él mismo opcionalmente sustituido con hasta tres grupos metilo)] o un anillo saturado de 3 - 7 miembros (que está opcionalmente sustituido con hasta tres grupos metilo y contiene opcionalmente un heteroátomo seleccionado del grupo que consiste en nitrógeno y oxígeno); o R28 y R29 junto con el átomo de carbono al que están unidos forman un grupo CO o un anillo carbocíclico de tres a cinco miembros (que está opcionalmente sustituido con hasta tres grupos metilo y contiene opcionalmente hasta dos heteroátomos seleccionados independientemente del grupo que consiste en nitrógeno y oxígeno); o R28 y R29 forman juntos un alquilideno C1-6 (que está opcionalmente sustituido con hasta cuatro grupos que pueden ser iguales o diferentes y que se pueden seleccionar de la lista que consiste en flúor, cloro, bromo y metilo) o un grupo cicloalquilideno C3-6 (que está opcionalmente sustituido con hasta tres grupos metilo).
ARP110104253A 2010-11-15 2011-11-14 5-halogenopirazolcarboxamidas AR083876A1 (es)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
EP10191270 2010-11-15
EP10191269 2010-11-15
EP10191740 2010-11-18
EP10191761 2010-11-18
US41682810P 2010-11-24 2010-11-24
EP11356008 2011-06-09

Publications (1)

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AR083876A1 true AR083876A1 (es) 2013-03-27

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US (1) US9375004B2 (es)
EP (1) EP2640707B1 (es)
JP (1) JP5833663B2 (es)
CN (2) CN103391925B (es)
AR (1) AR083876A1 (es)
BR (1) BR112013012082A2 (es)
MX (1) MX2013005407A (es)
WO (1) WO2012065947A1 (es)

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BR112013012082A2 (pt) 2016-07-19
CN107266368A (zh) 2017-10-20
US20130296269A1 (en) 2013-11-07
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US9375004B2 (en) 2016-06-28
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