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CHEMISTRY
1 The explanation for presence of three unpaired 6 An electron in an atom jumps in such a way that its
electrons in the nitrogen atom can be given by:- kinetic energy changes from x to . The change in
(1) Pauli's exclusion principle potential energy will be :-
(2) Hund's rule (1) (2)
(3) Aufbau principle
(3) (4)
(4) Uncertainity principle
2 The energy of the second bohr orbit in the
7 The number of electrons in Cu (Z = 29) for which n
+ℓ+m=7
hydrogen atom is – 3.41 eV. The energy of the
second Bohr orbit of He+ ion would be :- (1) 1 (2) 2
(1) – 0.85 eV (2) – 13.64 eV (3) 6 (4) 10
(3) – 1.70 eV (4) – 6.82 eV 8 If the kinetic energy of an electron is increased 4
3 The mass of a particle is 10 – 10 g and its radius is
times, the wavelength of the de-Broglie wave
associated with it would become :
2×10 – 4 cm. If its velocity is 10 – 6 cm sec – 1 with
0.0001% uncertainty in measurement, the (1) Four times
uncertainty in its position is : (2) Two times
(1) 5.2 × 10 – 8 m (2) 5.2 × 10 – 7 m (3) Half times
(3) 5.2 × 10 – 6 m (4) 5.2 × 10 – 9 m (4) One fourth times
4 If a0 be the radius of first Bohr's orbit of H-atom, 9 Two atoms are said to be isobars if :-
the de-Broglie's wavelength of an electron
(1) They have same atomic number but different
revolving in the second Bohr's orbit will be :
mass number
(1) 4a0 (2) 4 π a0
(2) They have same number of electrons but
(3) 2 π a0 (4) 3 π a0 different number of neutrons.
5 Which of the following sets of quantum number (3) they have same number of neutrons but
belong to highest energy :- different number of electrons.
(1) n = 4, ℓ = 0, m = 0, s = + (4) sum of the number of protons and neutrons is
same but the number of protons is different.
(2) n = 3, ℓ = 0, m = 0, s = +
10 What is the ratio of time periods (T1/T2) in second
(3) n = 3, ℓ = 1, m = 1, s = + orbit of hydrogen atom to third orbit of He+ ion ?
(1) (2)
(4) n = 3, ℓ = 2, m = 1, s = +
(3) (4) Zero

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11 The uncertainity in position of electron is equal to 15 Among the following transitions in hydrogen and
uncertainity in momentum of electron, then what hydrogen like ion spectrum, which one emits light
will be the uncertainity in velocity of electron ? of longest wave length ?
(1) (2) (1) n = 2 to n = 1 for H
(2) n = 4 to n = 3 for Li+2
(3) (4)
(3) n = 4 to n = 3 for He+
12 The frequency of radiation emitted when the (4) n = 5 to n = 2 for H
electron falls from n = 4 to n = 1 in a H-atom will 16 Two particles A and B are in motion. Momentum
be : of B is half the momentum of A. If de-Broglie's
(Given R = 1.1 × 107 m – 1, C = 3 × 108 m/sec) :- wavelength of A is 5 × 10 – 8 metre, calculate de-
(1) 3.09 × 1015 s – 1 (2) 2.00 × 1015 s – 1 Broglie's wavelength of particle B :-
(3) 1.54 × 1015 s – 1 (4) 1.03 × 1015 s – 1 (1) 10 – 9 m (2) 5 × 10 – 8 m
13 The orbital diagram in which both the Pauli (3) 10 – 7 m (4) 5 × 10 – 7 m
exclusion principle is violated? 17 In ground state of He ⊕ ion how much energy is
(1) supplied to electron so that second line of Balmer
series is obtained in its spectrum :-
(2) (1) 10.2 eV (2) 48.36 eV
(3) 51 eV (4) 102 eV
(3)
18 The maximum probability of finding electron in the
dxy orbital is -
(4)
(1) Along the x axis

14 Which of the following statements is incorrect ? (2) Along the y axis

(1) The concepts of "Penetration" and shielding (3) At an angle of 45º from the x and y axis
are important in deciding the energetic (4) At an angle of 90º from the x and y axis
ordering of orbitals in multielectron atoms 19 Magnetic moment of X3+ ion of 3d series is
(2) A wave function can have positive and BM. What is atomic number of X3+ ?
negative values. (1) 25 (2) 26
(3) "Radial nodes" can have appearance in radial (3) 27 (4) 28
probability distribution functions
(4) The shape of an orbital is given by the
20 The radius of nucleus is 1.25 × 10 – 13 A1/3 cm [A =
mass number = 64], [atomic radius = 10 – 8m], what
principal quantum number is the fraction of atomic volume occupied by
nucleus ?
(1) 1.25 × 10 – 13 (2) 1.0 × 10 – 11
(3) 2.56 × 10 – 13 (4) 2.69 × 10 – 13

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21 The radii of two of the first four Bohr' orbits of the 26 The atom A, B, C have the configuration
hydrogen atom are in the ratio 1 : 4. The energy A ⟶ [Z(90) + n(146)], B ⟶ [Z(92) + n(146)], C
difference between them may be :- ⟶ [Z(90) + n(148)] So that :-
(1) Either 12.09 eV or 3.4 eV (a) A and C - Isotones
(b) A and C - Isotopes
(2) Either 2.55 eV or 10.2 eV (c) A and B - Isobars
(3) Either 13.6 eV or 3.4 eV (d) B and C - Isobars
(4) Either 3.4 eV or 0.85 eV (e) B and C - Isotopes
The wrong statement's are:-
22 In Ψ 321 the sum of angular momentum, spherical
(1) a, b only (2) c, d, e only
nodes and angular node is :-
(3) a, c, d only (4) a, c, e only
(1) (2)
27 Which is the correct relationship :-
(3) (4) (1) E of H = E of He+ = E of Li+2 = E of Be+3
1 2 3 4
23 The ratio of ionisation energies of Li2+ and Be+3 is (2) E1 (H) = E2 (He+) = E3 (Li+2) = E4 (Be+3)
(1) (2) (3) E1 (H) = 2 E2 (He+) = 3 E3 (Li+2) = 4 E4 (Be+3)
(3) (4) (4) None
28 According to Bohr's atomic theory, which of the
24 Which of the following quantum number is not following is correct ?
represented correctly :-
(1) Potential energy of electron
(1) n = 3, = 2 m = 1 s = +1/2
(2) n = 3, = 2 m = +2 s = – 1/2 (2) The product of velocity of electron and
(3) n = 4, = 1 m = +1 s = +1/2 principle quantum number (n) ∝ Z2

(4) n = 2, (3) Frequency of revolution of electron in an

= 0 m = +1 s = – 1/2
25 If velocity of electron in 2nd orbit of H-atom is 'X', orbit
its velocity in 5th orbit is :- (4) Coulombic force of attraction on the electron
(1) (2)

(3) (4)

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29 Incorrect statement is :- 33 Which one is a wrong statement ?
(1) Total energy of electron in third orbit of Li+2 (1) Total orbital angular momentum of electron in
ion is ‘s’ orbital is equal to zero
(2) An orbital is designated by three quantum
(2) Potential energy of e – in second orbit of numbers while an electron in an atom is
hydrogen atom is 6.8 eV designated by four quantum numbers
(3) Kinetic energy of e – in third orbit of He+ is (3) The value of m for is zero
equal to (4) The electronic configuration of N atom is
(4) All of the above are wrong
30 Which one represent is in ground state
configuration
34 d6 configuration will result in total spin of –
(1)
(1) 3/2 (2) 1/2 (3) 2 (4) 1

(2)
35 In H-atom, if 'x' is the radius of the first Bohr orbit,
de Broglie wavelength of an electron in 3rd orbit is:
(1) 3 π x (2) 6 π x (3) (4)
(3)
36 Let mass of electron is half, mass of proton is two
times and mass of neutron is three fourth of
(4) orignal. The find out new atomic wt. of O16 atom
(1) Increases by 37.5%
31 If angular momentum of 2nd
orbit of H atom is x, (2) Remain constant
then angular momentum of first excited state of
He+ ion will be :- (3) Increases by 12.5%

(1) x (2) 2x (4) Decreases by 25%

(3) (4) 4x
37 Which of the following statements in relation to the
hydrogen atom is correct
32 r3 : r4 of Li2+ atom will be :- (1) 3s orbital is lower in energy than 3p orbital
(1) 3 : 4 (2) 9 : 16 (2) 3p orbital is lower in energy than 3d orbital
(3) 16 : 9 (4) 4 : 25 (3) 3s and 3p orbitals are lower in energy than 3d
orbital
(4) 3s, 3p and 3d orbitals all have the same
energy.

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38 If Hund’s rule is followed, magnetic moment of 43 Wave number of spectral line for a given transition
Fe2+, Mn+ and Cr all having 24 electrons will be in is x cm – 1 for He+, then its value for Be3+ for same
order - transition :-
(1) Fe2+ < Mn+ < Cr (1) x (2) 4x (3) (4) 2x
(2) Fe2+ < Cr = Mn+ 44
(3) Fe2+ = Mn+ < Cr
(4) Mn2+ = Cr < Fe2+
39 Calculate the ratio of maximum wavelength of
for the atom, correct statement is
Lyman and Balmer series
(1) 27 : 5 (2) 5 : 27 (1) λ 3 = λ 1 + λ 2 (2) λ =
3

(3) 3 : 4 (4) 4 : 3 (3) λ 1 + λ 2 + λ 3 = 0 (4)

40 The difference in angular momentum associated 45 If uncertainty in position and momentum are equal
with the electron in two successive orbits of then uncertainty in velocity is
hydrogen atom is
(1) (2)
(1) (2)
(3) (4)
(3) (4)

41 46 Average atomic weight of an element M is 51.7. If

If there are three possible values for two isotopes of M, M50 and M52 are present then
the spin quantum number ms, then electronic calculate percentage occurance of M50 in nature.
configuration of k(19) will be - (1) 85% (2) 15%
(1) 1s32s32p93s33p1 (3) 75% (4) 25%
3 2 6 2
(2) 1s 2s 2p 3s 3p 4s 6 1
47 How many electrons in calcium have = 0 ?
(3) 1s22s22p93s23p4 (1) 6 (2) 8
(4) None is correct (3) 10 (4) 12
42 The figure indicates the energy level diagram for 48 The energies E1 and E2 of two radiations are 25 eV
the origin of six spectral lines in emission and 50 eV respectively. The relation between Their
spectrum(e.g. line no. 5 arises from the transition wavelength λ 1 and λ 2 will be :-
from level B to X) which of the following spectral
(1) λ 1 = (2) λ 1 = λ 2
lines will not occur in the absorption spectrum : –
(3) λ 1 = 2 λ 2 (4) λ 1 = 4 λ 2

(1) 1, 2, 3 (2) 3, 2
(3) 4, 5, 6 (4) 3, 2, 1
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49 S1 : Potential energy of the two opposite charge 50 Match the following –
system increases with the decrease in distance. Energy of ground state of
S2 : When an electron make transition from higher (a) (i) +6.04 eV
He+
orbit to lower orbit it's kinetic energy increases.
Potential energy of I orbit
S3 : When an electron make transition from lower –
(b) of (ii)
energy to higher energy state its potential energy 27.2 eV
H-atom
increases.
S4 : 11eV photon can free an electron from the 1st Kinetic energy of II excited
(c) (iii) 54.4 eV
excited state of He+ ion. state of He+
(1) TTTT (2) FTTF –
(d) Ionisation potential of He+ (iv)
54.4 eV
(3) TFFT (4) FFFF
(1) A – (i), B – (ii), C – (iii), D – (iv)
(2) A – (iv), B – (iii), C – (ii), D – (i)
(3) A – (iv), B – (ii), C – (i), D – (iii)
(4) A – (ii), B – (iii), C – (i), D – (iv)

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