Sankalp sheet FIITJEE

Subject: CHEMISTRY Topic : Aomic structure Date of Distribution :

Single Correct

1. The wave number of electromagnetic radiation emitted during the transition of electron in between two levels of Li +2
ion whose principal quantum numbers sum is 4 and difference is 2 is:
(A) 3.5 RH (B) 4 RH (C) 8 RH (D) 8/9 RH

2. A gas absorbs photon of 300nm and re-emits 2 photons, if one of it has wavelength 450nm; the other has
(A) 750nm (B) 150nm (C) 900nm (D) none
3. If is the threshold wavelength for photoelectric emission, λ the wavelength of light falling on the surface of a
metal and m, the mass of e–, then the velocity of ejected e– is given by

(A) (B) (C) (D) None

4. H, D and He+ are all one electron species. The wavelengths of radiations emitted for their downward transitions from
1st excited state to ground state are λ1, λ2 and λ3 respectively. Then approximately:
(A) 4λ1 = 2λ2 = 2λ3 (B) λ1 = 2λ2 = λ3 (C) λ1 = λ2 = 2λ3 (D) λ1 = λ2= 4λ3

5 Which of the following graphs of radial part of wave-function versus distance from nucleus is/are incorrectly
labeled?

6. Which one of the following is not a ‘ f ’ orbital ?

(A) (B)

(C) (D)

7. Consider the following plots for 2s-orbital :

x, y and z are respectively,

(A) (B)

(C) (D)

8. Two gases He and Ne at 1270C and 270C ,calculate the ratio of the de Broglie’s wave length for Ne to He gases is
(A) 1: 1.94 (B) 1: 3.43 (C ) 1: 4.141 (D) 1: 8.987

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Multi Correct
9. Which is/ are correct statements
(A) The difference in angular momentum associated with the electron present in consecutive orbits of H-atoms

(B) Zn2+ and Cu+ have the same magnetic momentum

(C) Frequency of spectral line in a H-atom is in the order of

(D) On moving away from the nucleus, kinetic energy of electron decreases.
10. Which is/ are correct statement for following
(A) have maximum magnetic moment (B) Only is diamagnetic
(C) have maximum magnetic moment (D) have minimum exchange energy.
11. Which of the following is/are true
(A) ‘3s’ orbital is spherically symmetrical with two nodes

(B) has lobes of electron density in XY plane along X and Y axis.

(C) The radial probability curves of 1s, 3p and 5d have one, two and three peaks respectively.

(D) has zero electron density in XY plane

12. Which of the following is/are NOT correctly matched ?
2s 2p
(A) ↑ ↑ ↑ ↑ No rule is violated

(B) ↑ ↑ ↓ ↑ All the three rules Aufbau, Pauli and Hund’s rules are
↑ violated

(C) ↑↓ ↑ ↓ ↑ Pauli and Hund’s rules are violated

↓

(D) ↑ ↑ ↑ ↑ Aufbau and Hund’s rule are violated

↑

13. Which of the following statement is/are True?

(A) Probability distribution graph for 3S electron is

(B) V+4 have magnetic moment (spin only) is 1.73 BM

(C) |ψ|2 is the measure of probability density of an electron in an orbital .
(D) 4π |ψ|2 r2 is the radial probability function of an electron at a distance r from the nucleus.

14. The relationship λ = ; λ is de Broglie wavelength and p is the linear momentum; is true for
(A) Photons (B) Protons (C) Electrons (D) Positrons

15. The angular momentum of electron can have the value(s)

(A) 0.5 (B) (C) 1.5 (D) 2

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16. In a certain electronic transition from the quantum ‘n’ to the ground state in atomic hydrogen in one or more than
one steps, no line belonging to the bracket series is observed. What wave numbers may be observed in Balmer
series? [ R = Rydberg constant]

(A) (B) (C) (D)

17. Which of the following statements is/are correct

(A) have the same paramagnetic character
(B) Both are paramagnetic
(C) of orbital angular momentum is quantized
(D) orbital angular momentum of an electron in S subshell has a fixed value

18. Which of the following statement is True?

(A) Value of e/m is independent to nature of gas in cathode ray tube
(B) spin angular momemtum of an electron in 2S orbital is zero
(C) e/m decreases on increase in voltage applied in cathode ray tube.
(D) Value of e/m is independent to nature of gas in canal ray tube

Matrix matching
19. Match the Column – I with Column – II
Column – I Column – II
(A) No. of radial nodes for 4d orbital. (p) 1
(B) l-value (azimuthal quantum no.) for the differentiating electron of Cl. (q) 4
(C) K.E. energy of an electron in eV, if we supply 16.6 eV to the electron present in the first
(r) 3
excited state of He+.
(D) The work function of the metal in eV, if we struck it with light of 100nm and the emitted
(s) 2
electron has K.E. 8.4 eV is

20.
Column I Column II

(A) Time period (p)

Proportional to

(B) Velocity of electron (q) Inversely proportional to n

(C) Energy of electron (r) Proportional to n2

(D) Radius of nth orbit (s) Inversely proportional to n2

21.
Column I Column II

(A) Isotopes (p) CO & NO+

(B) Isobars (q) 6 C14 & 7N15

(C) Isotones (r) 18 Ar40 & 19K40

(D) Isosters (s) 1 H1 & 1H3

22
. Match the following:
Column I Column II

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(A) If P.E. = –13.6 eV (p) 21
(B) Ionization energy of electron from 2 nd (q) 10
shell of Na10+
(C) Number of spectral lines when (r) Total energy = –6.8 eV
electron jumps from 7th to 3rd shell.
(D) Number of spectral lines when (s) 411.4 eV
electron comes from 7th shell to 1st
shell

NUMERICALS

1. The element Uub ,number of electrons in outer most subshell are ---------

2. The schrodinger wave equation for Hydrogen atom is

Where a0 is Bohr’s radius. If the radial node in 2s be at r = 4a0 then x would be equal to _____.

3. Depict number of nodal planes for ψ320.

4. The ratio of de-Broglie wavelength of electron in 3rd Bohrs orbit of hydrogen atom and 1st orbit of hydrogen atom
is ( Assuming the radius of 1st orbit is r)

5. Energy required to stop the ejection of electrons from Cu-plate 0.27 eV. Calculate the work function (in eV) When
radiation of strikes the plate.

6. How many of the following statements is/are correct?

(1) The orbital angular momentum for a d-electron is .

(2) The number of orbitals in a shell with principal quantum number is .

(3) The set of quantum numbers for the last unpaired electron of atom is
(4) The ratio of energy in the first Bohr orbit of H – atom to the electron in the first excited state of
Be3+ is 1:4.

(5) The electronic configuration of Co ends with 3d 74s2.

(6) The order of energy of subshells in a given principle quantum level for an H-atom are
ns<np<nd<….

(7) in silver atom (at.no. 47) , 23 electrons have a spin of one type and 24 electrons have a spin
of opposite type.
.

7. Number of spectral lines obtained when an electron jumps from n=5 to ground state for an H-
atom such that no spectral in Balmer series

8. The uncertainty in the location of circulating electron is equal to its de Broglie wavelength. The minimum
percent error in its measurement of velocity under this circumstance will be approximately.

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KEY AND SOLUTION

Single Option Correct :-

1.(c)

= = =8

2.(c)

=>

3. (C)

h = +1/2m

=> hc = 1/2m => =v

4. (D)

For H, For D

= ,

For , =

5.(D)

33d

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6. (A)

Cube term should be present.

7. (B)
Plot I :
Plot II :
Plot III : z =

8. (A)

Multiple Option Correct

9. (B.C.D)

A .mvr =

B.

C.

, =

D. KE = 1/2m =

10 (AB)

A.

B.

C.

D.

11. (A,B,C)

A. Number of node = n-1

B.

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C.

1s 5d
3p

r r r
r
rr r

12. (A,C,D)

A. Aufbau rule violated

B. All the three rule Aufbau , pauli’s & Hund’s rule violated.

C. Only Hund’s rule violated

D. Aufbau & pauli’s Rule violated.

13. (A,B,C,D)

V+4 (Z=23) has only one unpaired electron

14, [B,C,D]

, valid for microscopic particle, not photon

15. [A,B,C,D]

mvr = , n = 1,2,3,4 ………….

16.[A,C]

[HINT] No transitions are allowed from nth level to 4th level and 4th to any other level

17. (A,C,D)

A. = ,

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B.

C. Z-Component of orbital angular momentum is zero

D. Orbital angular momemtum of an electron in s orbital is zero

18.(A,C)

B. h/2π , here s=1/2 (n) , n= no of unpaired electrons

C. e/m decreases with increase in voltage in cathode ray tube as speed of electron and relative
mass increases
D. e/m depends on type of gas in canal ray tube

19. (A)- p; (B)- p; (C)- r (D)- q

(A) No of radial nodes : n-l-1 =4-2-1 =1

(B).Outer most electron enters into 3p

(C). En = E1s × = 13.6 eV En= E0 + K.E

(D). En= E0 + K.E

20. (A)- p; (B)- q; (C)- s (D)- r

(A) p

(B) q

(C) s

(D) r

21.( A)-S,(B)-R,(C)-Q,(D)-P

Isotopes: same nos of protons but different nos of electron

Isobars : Different nos of protons and different nos of neutrons
Isotones: Different nos of protons and same nos of neutrons
Isosters: Same nos of atoms and same nos of electrons

22. (A)- r; (B)- s; (C)- q; (D)-p

NUMERICALS

1. 2

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Uub =112 , Electronic configuration [ Rn] 5f 6d 7s ,
14 10 2

2. 2

for a radial node ψ2 = 0 thus on solving the equation we have

a0x2 = 4ao => x2 = 4 => x = 2

3. 0
The given subshell is 3dz2

4. 3
for 1st orbit

for 3rd orbit

5. 5
Ephoton = work function + ½ mv2

…(i)

from equation (i)

6. 5

(1) The orbital angular momentum for a d-electron is .

(2) The number of orbitals in a shell with principal quantum number is n2

(3) The set of quantum numbers for the last unpaired electron of atom is
(4) The ratio of energy in the first Bohr orbit of H – atom to the electron in the first excited state of
Be3+ is 1:4.

(5) The electronic configuration of Co ends with 3d 74s2.

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(6) The energy of subshells in a given principle quantum level for an H-atom are equal .

(7) in silver atom (at.no. 47) , 23 electrons have a spin of one type and 24 electrons have a spin
of opposite type.

.
7. 7
Exclude spectral lines n → 2 and 2→ 1

8. 8

Δx = λ ⇒ ΔV =

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