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Chemistry (11th )
Prarambh 2025
Structure of Atom
1. Statement-I: The isotopes protium, 5. Two electromagnetic radiations have
deuterium and tritium have difference in wave numbers in the ratio 2 : 3. Their
their physical properties. energies per quanta will be in the ratio
Statement-II: The isotopes protium, (A) 3 : 2 (B) 9 : 4
deuterium and tritium differ in number of (C) 4 : 9 (D) 2 : 3
neutrons. 6. Statement-I: The radiant energy is
(A) Both Statement-I and Statement II absorbed or emitted in whole number or
are correct multiple of quantum.
(B) Both Statement-I and Statement- II Statement-II: Radiation energy is
are not correct. emitted or absorbed continuously but in
(C) Statement-I is correct but Statement- the form of small packets called quanta.
II is not correct. (A) Both Statement-I and Statement II
are correct
(D) Statement-I is not correct, but
Statement-II is correct (B) Both Statement-I and Statement- II
are not correct.
2. The mass charge ratio for A+ ion is 1.97
× 10–7 kg C–1. Calculate the mass of (C) Statement-I is correct but Statement-
A atom. II is not correct
(A) 9.1 × 10–26 kg (B) 3.1 × 10–25 kg (C) (D) Statement-I is not correct but
3.16 × 10–26 kg (D) 9.1 × 10–25 kg Statement-II is correct
3. Statement-I: Only 1 in 20,000  7. The energy of a radiation of wavelength
particles bounce back during Rutherford 8000 Å is E1 and energy of a radiation of
scattering experiment. wavelength 16000 Å is E2. If E1 = t × E2
then value of t is
Statement-II: Most of the space inside
atom is occupied. 8. Calculate frequency of a photon having
an energy of 2 electron volt.
(A) Both Statement-I and Statement II
are correct (A) 4.8 × 1014 s–1 (B) 4.8 × 1010s–1
(B) Both Statement-I and Statement- II (C) 2.0 × 1014s–1 (D) 3.5 × 10–7s–1
are not correct. 9. If the radius of first orbit of H–atom is x
(C) Statement-I is correct but Statement- Å, then the radius of the second orbit of
II is not correct. Li2+ ion will be
(D) Statement-I is not correct. but 4x
(A) x Å (B) Å
Statement-II is correct 3
4. The increasing order for the values of 9x
(C) Å (D) 4x Å
e/m (charge/mass) is: 2
(A) e, p, n,  (B) n, p, e,  10. The ratio of circumference of third and
(C) n, p, , e (D) n, , p, e second orbits of He+ ion is
(A) 3 :2 (B) 2 : 3
(C) 9 : 4 (D) 4 : 9
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11. How much distance an electron revolving 14. Line spectra is characteristic of:
in 3rd orbit of He+ ion will travel in one (A) Molecules (B) Atoms
second. (C) Radicals (D) None of these
(A) 1.458 × 106 m (B) 3.28 × 106 m
(C) 4.862 × 105 m (D) 2.917 × 106 m 15. Find the value of wave number (v) in
12. If velocity of an electron in 1st orbit of H terms of Rydberg’s constant, when
atom is V and the velocity of electron in transition of electron takes place between
3rd orbit of Li+2 is k.V. The value of k is two energy levels of He+ ion whose sum
13.6 2 is 4 and difference is 2.
En = − Z eV /atom (Z = atomic
n2 8R 32R
number) (A) (B)
9 9
13. The energy of an electron moving in nth 3R
Bohr’s orbit of an element is given by (C) (D) None of these
4
−13.6 2
En = Z eV/atom (Z = atomic 16. Transition of an electron from n = 3 to n
n2 = 1 level in H- atom results in
number). The graph of E vs. Z2 (keeping
(A) Emission spectrum
“n” constant) will be :
(B) Band spectrum
(C) Infrared spectrum
(D) X-ray spectrum

(A) 17. The uncertainty in measuring the speed

of a particle is zero. Uncertainty in
measuring its position will be.
h
(A) Zero (B)
4
h
(C) (D) infinite
4m
(B)
18. Statement-I: De Broglie dual character
and Heisenberg uncertainty principle are
significant only for microscopic moving
particle.
Statement-II: De Broglie dual character
and Heisenberg uncertainty principle are
(C) not applicable to all moving particles.
(A) Both Statement-I and Statement II
are correct
(B) Both Statement-I and Statement- II
are not correct.
(C) Statement-I is correct but Statement-
II is not correct
(D) (D) Statement-I is not correct but
Statement-II is correct
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19. An -particle is accelerated through a (A) Both Statement-I and Statement II
potential difference of V volts starting are correct
from rest. The de Broglie’s wavelength (B) Both Statement-I and Statement- II
associated with it is: are not correct.
150 0.286 (C) Statement-I is correct but Statement
(A) Å (B) Å II is not correct
V V
0.101 0.983 (D) Statement-I is not correct but
(C) Å (D) Å Statement-II is correct
V V
23. Which of the following statement(s)
20. The de Broglie wavelength of a tennis
is/are true about wave function?
ball of mass 60 g moving with a velocity
of 10 m/s is approximately 10-z m. The (I) When an electron is in energy state,
value of Z is. (Planck’s constant, h = 6 × the wave function corresponding to
10–34 Js) that energy state, contains all
information about the electron.
21. Which of the following radial
distribution graphs corresponds to l = 2 (II) It is a mathematical function whose
for H atom for the least value of n for value depends upon the coordinates
which l = 2 is allowed? of the electron in the atom and does
not carry an physical meaning.
(III) Wave functions of hydrogen or
hydrogen like species with one
(A) electron are called atomic orbitals
The correct set of the statement (s)
is.
(A) Only I and III
(B) Only III
(B) (C) Only I and II
(D) All I, II and III
24. For a system (such as an atom or a
molecule with no change in energy with
time), the Schrodinger equation is written
(C) as
E
(A) Ĥ = (B) Ĥ = E

(C) Ĥ = E +  (D) Ĥ = E − 
25. The minimum angular momentum of an
(D) electron with the magnetic quantum
numbers –1, 0, +1 is
3h h
22. Statement-I: There are 3 angular nodes (A) (B)
2 
and 2 radial nodes in 5d subshell.
2h 3h
Statement-II: The number of radial nodes (C) (D)
and angular nodes in a subshell are  2
(n-/-1) and “l” respectively.
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26. An electron has principal quantum 31. In potassium, the order of energy level
number 3. The number of its (i) subshells for 19th electron is
and (ii) orbitals would be respectively: (A) 3s > 3d (B) 4s < 3d
(A) 3 and 5 (B) 3 and 7 (C) 4s > 4p (D) 4s = 3d
(C) 3 and 9 (D) 2 and 5 32. In a set of degenerate orbitals, the
27. Which one of the following set of electrons distribute themselves to retain
quantum numbers is not possible for similar spins as far as possible. This
electron in the ground state of an atom statement is attributed to:
with atomic number 19? (A) Pauli’s exclusion principle
(A) n = 2, l = 0, m = 0 (B) Aufbau principles
(B) n = 2, l = l, m = 0 (C) Hund’s Rule
(C) n = 3, l = l. m = –1 (D) Slater rule
(D) n = 3, l = 2, m = +2 33. The (spin only) magnetic moment order
28. Which one of the following is the set of is correctly given in
correct quantum numbers of an electron (A) Fe2+ < Fe3+ < Mn4+ < Cr3+
in 3𝑑 orbital? (B) Cr3+ = Mn4+ < Fe2+ < Fe3+
(A) 𝑛 = 3, 𝑙 = 0, 𝑚 = 0, 𝑠 = −1/2 (C) Cr3+ = Mn4+ < Fe3+ < Fe2+
(B) 𝑛 = 2, 𝑙 = 3, 𝑚 = 0, 𝑠 = +1/2 (D) Fe2+ < Fe3+ < Mn3+ < Cr4+
(C) 𝑛 = 3, 𝑙 = 1, 𝑚 = 0, 𝑠 = −1/2 34. Magnetic moment of X3+ ion of 3d series
(D) 𝑛 = 3, 𝑙 = 2, 𝑚 = 1, 𝑠 = +1/2 is 35 BM. What is atomic number of
29. The electrons would go to lower energy X3+?
levels first and then to higher energy
(A) 24 (B) 26
levels according to which of the
following (C) 25 (D) 20
(A) Aufbau principle 35. In a multi-electron atom, which of the
following orbitals described by the three
(B) Pauli’s exclusion principle
quantum numbers will have the same
(C) Hund’s rule of maximum energy in the absence of magnetic and
multiplicity electric fields?
(D) Heisenberg’s uncertainty principle (I) n = 1, 1 = 0, m = 0
30. Which one is a wrong statement? (II) n = 2, 1 = 0, m = 0
(A) total orbital angular momentum of (III) n = 2, 1 = 1, m = 1
electron in s-orbital is equal to zero.
(IV)n = 3, 1 = 2, m = 1
(B) An orbital is designated by three
quantum numbers while an electron (V) n = 3, 1 = 2, m = 0
in an atom is designated by four (A) IV and V (B) III and IV
quantum number. (C) II and III (D) I and II
(C) The electron configuration of N atom 36. Which of the following option does not
is represent ground state electronic
configuration of an atom?
(A) 1s2 2s2 2p6 3s2 3p6 3d8 4s2
(B) 1s2 2s2 2p6 3s2 3p6 3d9 4s2
(C) 1s2 2s2 2p6 3s2 3p6 3d10 4s1
(D) The value of m for dz2 is zero.
(D) 1s2 2s2 2p6 3s2 3p6 3d5 4s1
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37. If radius of the nucleus is 3.5 × 10–15 m (A) ng = nr (B) ng < nr
then if the space or volume occupied by (C) ng > nr (D) unpredictable
the nucleus is y × 10–43 m3, the value of 45. If r1 is the radius of the first orbit of
10y is……… [Nearest Integer] hydrogen atom, then the radii of second,
3−
38. Consider an imaginary ion 48 22 X . The third and fourth orbits in terms of r1 are
nucleus contains ‘a’% more neutrons (A) r12, r13, r14 (B) 8r1, 27r1, 64r1
than the number of electrons in the ion. (C) 4r1, 9r1, 16r1 (D) 2r1, 6r1, 8r1
The value of ‘a’ is …………… [Nearest 46. Statement-I: The energy of an excited
Integer] H-atom is –1.51 eV. Angular momentum
39. The charge on the atom containing 17 of e– in the given orbit will be 3h/2π.
protons, 18 neutrons and 18 electrons is: Statement-II: Angular momentum of e–
(A) +1 (B) –2 in the given orbit will be nh/2π.
(C) –1 (D) Zero (A) Both Statement-I and Statement II
40. Number of protons, neutrons & electrons are correct
in the element 89231 is: (B) Both Statement-I and Statement- II
(A) 89, 231, 89 (B) 89, 89, 242 are not correct.
(C) 89, 142, 89 (D) 89, 71, 89 (C) Statement-I is correct but Statement-
II is not correct
41. A bulb of 40 W is producing a light of
wavelength 620 nm with 80% efficiency (D) Statement-I is not correct but
then the number of photons emitted by Statement-II is correct
the bulb in 20 seconds are 47. The statement that does not belong to
(A) 2 × 1018 (B) 1018 Bohr’s model of atom, is
(C) 1021 (D) 2 × 1021 (A) Energy of the electrons in the orbit is
quantized
42. Find out the number of photons emitted
by a 60 watt bulb in one minute, if (B) The electron in the orbit nearest to
wavelength of an emitted photons is 620 the nucleus is in lowest energy state
nm. (C) Electrons revolve in different orbits
around the nucleus.
(A) 1.125 × 1022 (B) 7 × 1022
(D) The electrons emit energy during
(C) 1.125 × 1020 (D) 2.1 × 1015
revolution due to the presence of
43. One quantum is absorbed per gaseous Coulombic forces of attraction.
molecule of Br2 for converting into Br
48. The frequency of radiation emitted when
atoms. If light absorbed has wavelength
the electron falls from n = 4 to n = 1 in a
5000 Å, calculate energy required in
hydrogen atom will be (Given, ionisation
kJ/mol.
energy of H = 2.18 × 10–18 J atom–1 and h
(A) 250 kJ/mol = 6.625 × 10–34 Js)
(B) 239.4 kJ/mol (A) 1.54 × 1015 s–1 (B) 1.03 × 1015 s–1
(C) 320 kJ/mol (C) 3.08 × 1015 s–1 (D) 2.00 × 1015 s–1
(D) 239.4 J/mol 49. What is the shortest wavelength line in
44. A green bulb and a red bulb arc emitting the Paschen series of Li2+ ion?
the radiations with equal power. The R 9
correct relation between numbers of (A) (B)
9 R
photons emitted by the bulbs per second
1 9R
is (C) (D)
R 4
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50. No. of visible lines when an electron 56. What possibly can be the ratio of the de
returns from 5th orbit to ground state in Broglie wavelengths for two electrons
H spectrum is.. each having zero initial energy and
51. Statement-I: The atomic spectrum of an accelerated through 50 volts and 200
element is called the finger print of that volts?
element. Statement-II: The spectrum of (A) 3 : 10 (B) 10 : 3
two different elements can be exactly (C) 1 : 2 (D) 2 : 1
similar. 57. The plot of orbital wave function  (r) as
(A) Both Statement-I and Statement II a function of distance r of the electron
are correct from the nucleus for 2s orbital is
(B) Both Statement-I and Statement- II
are not correct.
(C) Statement-I is correct but Statement-
II is not correct
(D) Statement-I is not correct but
Statement-II is correct (A)
52. Electronic transition in He+ ion takes
place from n2 to n1 shell such that:
2 n2 + 3n1= 18
2n2 – 3n1 = 6
What will be the total number of photons
emitted when electrons transit to n1 shell (B)
(A) 21 (B) 15
(C) 20 (D) 10
53. Which of the following has least De
Broglie ?
(A) electron (B) proton
(C) CO2 (D) SO2
54. The uncertainty in the positions of an
electron and proton are equal, the ratio of
the uncertainties in the velocity of an (C)
electron and proton is.
(A) 103 : 1 (B) 1 : 1838
(C) 3672 :1 (D) 1836 :1
55. Calculate the uncertainty in velocity of a
cricket ball of mass 150 g if the
uncertainty in its position is of the order
of 1 Å (h = 6.6 × 10–34 Kg m2 s–1) (D)
(A) 3.499 × 10–24ms–1
(B) 3.499 × 10–21 ms–1
(C) 3.499 × 10–20 ms–1
(D) 3.499 × 1021 ms–1
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58. The region of an orbital where 65. Statement-I: An orbital in an atom can
probability density function reduces to have maximum two electrons and must
zero is called be of opposite spin.
(A) Nodal surface Statement-II: Pauli’s exclusion principle
(B) Nodes states that all the four quantum numbers
(C) Both (a) and (b) of two electrons in an atom cannot be
equal.
(D) None of these
(A) Both Statement-I and Statement-II
59. If probability density |2| is constant on a
are correct
given surface,
(B) Both Statement-I and Statement- II
I.  is constant over the surface.
are not correct.
II. The boundary surface for |2| and || (C) Statement-I is correct but Statement
are different. II is not correct
The correct statement is/are. (D) Statement-I is not correct but
(A) Only I (B) Only II Statement-II is correct.
(C) Both I and II (D) None of these 66. Which of the following electron
60. The number of radial nodal in 3p and 4s configurations is correct for iron, (atomic
orbitals, respectively, we get number 26)?
(A) 1, 3 (B) 3, 1 (A) [Kr]4s1 3d6 (B) [Kr]4s1 3d7
(C) 2, 2 (D) 2, 1 (C) [Ar]4s2 3d6 (D) [Kr]4s2 3d
61. The orbital angular momentum of a 4p 67. Consider the argon atom. For how many
electron will be electrons does this atom have ml = 1?
h h 68. Which of the following electronic
(A) 4. (B) 2.
2 2 configurations have zero spin
h h multiplicity?
(C) 6. (D) 2.
2 4
(A) (B)
62. For which of the following sets of
quantum numbers, an electron will have
the highest energy?
(C) (D)
n l m s
(A) 3 2 1 –1/2 69. The electronic configuration of an
(B) 4 3 –1 +1/2 element in ultimate and penultimate
(C) 4 1 –1 +1/2 orbitals is (n –1)s2 (n –1)p6 (n –1) dx ns2.
(D) 5 0 0 –1/2 If n = 4 and x = 5 then number of protons
63. Which of the following orbitals have e– in the nucleus is
density in b/w axes? (A) 35 (B) < 724
(A) dxy (B) dz2 (C) 25 (D) 30
(C) px (D) dx2– y2 70. Which of the following is the electronic
64. If the numbers of orbitals of a particular configuration of an atom in its first
type were (3l + 1), but spin quantum excited state if that atom is isoelectronic
numbers were only +1/2 and –1/2, then d with O2?
type orbitals will contain a maximum of (A) [Ne]3s2 3p4 (B) [Ne]3s2 3p3 3d1
1 5
_____ electrons. (C) [Ne] 3s 3p (D) None of these
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71. Which of the following indicates 72. The electronic configuration of an
incorrect valence shell configuration? element is 1s2 2s2 2p6 3s2 3p6 3d4 4s2.
(A) W(74) = 5d4 6s2 (A) Excited state (B) Ground state
(B) Pd(46) = 4d10 5s0 (C) Cationic form (D) Anionic form
(C) La(57) = 4f1 6s2
(D) Gd(64) = 4f7 5d1 6s2
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ANSWER KEYS
1. (A) 16. (A) 31. (B) 46. (A) 61. (B)
2. (C 17. (D) 32. (C) 47. (D) 62. (B)
3. (C) 18. (C) 33. (B) 48. (C) 63. (A)
4. (D) 19. (C) 34. (B) 49. (C) 64. (14)
5. (D) 20. (33) 35. (A) 50. (3) 65. (A)
6. (C) 21. (C) 36. (B) 51. (C) 66. (C)
7. (2) 22. (D) 37. (18) 52. (D) 67. (2)
8. (A) 23. (D) 38. (4) 53. (D) 68. (C)
9. (B) 24. (B) 39. (C) 54. (D) 69. (C)
10. (C) 25. (B) 40. (C) 55. (A) 70. (B)
11. (A) 26. (C) 41. (D) 56. (D) 71. (C)
12. (1) 27. (D) 42. (A) 57. (C) 72. (A)
13. (B) 28. (D) 43. (B) 58. (C)
14. (B) 29. (A) 44. (B) 59. (A)
15. (B) 30. (C) 45. (C) 60. (A)