Hy_hu_1731834827

Vedclass
Subject : Chemistry Paper Set : 1

Standard : 11
Hy hu Date : 17-11-2024
Total Mark : 800 Time : 0H:0M
............ Chemistry - Section A (MCQ) ............ (A) + 21 . 2h∏ (B) 0

√
(C) 2
h∏
(D) 2. 2h∏
(1) In an atom, an electron is moving with a speed of 600 m/s (12) The quantum number ′ m′ of a free gaseous atom is
with an accuracy of 0.005%. Certainity with which the associated with [AIIMS 2003]
position of the electron can be located is
(h = 6.6 × 10−34 kg m2 s−1 , mass of electron, (A) The effective volume of the orbital
em = 9.1 × 10−31 kg) : [AIEEE 2009] (B) The shape of the orbital
(A) 5.10 × 10−3 m (B) 1.92 × 10−3 m (C) The spatial orientation of the orbital
(C) 3.84 × 10−3 m (D) 1.52 × 10−4 m (D) The energy of the orbital in the absence of a magnetic
(2) Number of spectral lines obtained in He spectra, when an
+ field
electron makes transition from fifth excited state to first (13) Given
excited state will be [JEE MAIN 2024] (A) n = 5, ml = +1
(A) 11 (B) 10 (B) n = 2, l = 1, ml = −1, ms = −1/2
(C) 12 (D) 13 The maximum number of electron(s) in an atom that can
have the quantum numbers as given in (A) and (B) are
(3) Number of orbitats in h sub-shell is respectively [JEE MAIN 2013]
(A) 11 (B) 15 (A) 25 and 1 (B) 8 and 1
(C) 17 (D) 19 (C) 2 and 4 (D) 4 and 1
(4) Which set of quantum numbers is not possible for last (14) An electron has kinetic energy 2.8 × 10−23 J. de-Broglie
electron of ′ Al′ (Z = 13) : − value of n, l, m, s respectively wavelength will be nearly(me = 9.1 × 10−31 kg)
(A) 3, 1, −1, −1 2 (B) 3, 0, 0, +1 2 (A) 9.28 × 10−4 m (B) 9.28 × 10−7 m
(C) 3, 1, 0, +1
2 (D) 3, 1, 1, −1
2 (C) 9.28 × 10−8 m (D) 9.28 × 10−10 m
(5) The radius of which of the following orbit is same as that of (15) Two radiations having energies E1 and E2 as 15 eV and
the first Bohr’s orbit of hydrogen atom [IIT 2004] 45 eV respectively then the relationship in between λ1 and
(A) He+ (n = 2) (B) Li2+ (n = 2) λ2 will be
(C) Li2+ (n = 3) (D) Be3+ (n = 2) (A) λ1 = λ2 (B) λ1 = 3λ2
(6) Quantum No. l = 2 and m = 0 represent which orbital : (C) λ1 = λ2 /3 (D) λ1 = 9λ2
(A) dxy (B) d2x − y 2 (16) Normally, the time taken in the transition is :
(C) d2z (D) dzx (A) Zero (B) 1
(7) The radius of electron in the first excited state of hydrogen (C) 10−5 sec (D) 10−8 sec
atom is (17) CO has same electrons as or the ion that is isoelectronic
(A) a0 (B) 4a0 with CO is [IIT 1982 , AIPMT 1997]
(C) 2a0 (D) 8a0 (A) N2+ (B) CN −
(8) In Bohr’s model of atom when an electron jumps from n = 1 (C) O2+ (D) O2−
to n = 3, how much energy will be absorbed (18) What is the maximum wavelength in the Lyman series of
(A) 2.15 × 10−10 ergs (B) 0.1911 × 10−10 ergs He+ ion ?
(C) 2.389 × 10−10 ergs (D) 0.239 × 10−10 ergs (A) 3R (B) 3R
1
(9) The orbital angular momentum of 3p electron is (C) 1

R (D) 2R
√ √
(A) 3h (B) 6h (19) The nitride ion in lithium nitride is composed of [AIPMT 2001]
√ h (A) 7P + 7e (B) 10P + 7e
(C) zero (D) 3 2π
(10) The mass of the proton is 1840 times that of electron. If a (C) 7P + 10e (D) 10P + 10e
proton is accelerated through a potential difference of V (20) Given below are two statements:
volts, the kinetic energy of the proton would be Statement-I: The orbitals having same energy are called as
(A) 1 eV (B) 1 keV degenerate orbitals.
Statement-II: In hydrogen atom, 3p and 3 d orbitals are not
(C) 1840 eV (D) 1849 keV degenerate orbitals.
(11) The orbital angular momentum of an electron in 2s orbitals is In the light of the above statements, choose the most
1
appropriate answer from the options given [JEE MAIN 2024] (A)
(A) Statement-I is true but Statement-II is false
(B) Both Statement-I and Statement-II are true.
(C) Both Statement-I and Statement-II are false
(D) Statement-I is false but Statement-II is true
(21) In which of the following transition photon of maximum
energy is absorbed
(A) 1 to 2 (B) 2 to 3 (B)
(C) 1 to ∞ (D) ∞ to 1
(22) The quantum number which specifies the location of an
electron as well as energy is
(A) Principal quantum number
(B) Azimuthal quantum number
(C) Spin quantum number
(D) Magnetic quantum number (C)
(23) The electrons identified by quantum numbers n and l :

(A) n = 4, l = 1 (B) n = 4, l = 0
(C) n = 3, l = 2 (D) n = 3, l = 1
can be placed in order of increasing energy as : [AIEEE 2012]
(A) (C) < (D) < (B) < (A) (B) (D) < (B) < (C) < (A)
(C) (B) < (D) < (A) < (C) (D) (A) < (C) < (B) < (D)
(24) Which electron is associated with the least energy
(D)
(A) n = 3, l = 2, m = −2, s = + 12
(B) n = 4, l = 0, m = 0, s = + 21
(C) n = 4, l = 1, m = +1, s = + 12
(D) n = 5, l = 0, m = 0, s = + 21
(25) According to Bohr’s theory, the angular momentum of an

electron in 5th orbit is [AIEEE 2006]
(A) 10 h/π (B) 2.5 h/π
(31) For the energy levels in an atom which one of the following
(C) 25 h/π (D) 1.0 h/π
statements is correct ?
(26) Which of the following is not isoelectronic (A) the 4s sub-energy level is at a higher energy that the 3d
(A) N a+ (B) M g 2+ sub-energy level
(C) O2− (D) Cl− (B) The 5th main energy level can have maximum of 50
(27) The maximum wavelength of radiation that can ionise a electrons
o
sodium atom is 2414 A . The ionisation energy of sodium per (C) The second principal energy level can have four orbitals
mole shall be and contain a maximum of 8 electrons
(A) 241.4 J mol−1 (B) 497.7 J mol−1
(D) Both (b) and (c)
(C) 241.4 k J mol−1 (D) 497.7 k J mol−1
(28) Which of the following sets of quantum numbers is not (32) The shortest wavelength of hydrogen atom in Lyman series
possible ? is λ. The longest wavelength in Balmer series of He+ is [JEE
MAIN 2023]
(A) n = 4, l = 1, m = 0, s = +1/2
(A) 5
(B) 9λ
(B) n = 4, l = 3, m = −3, s = −1/2
9λ 5
(C) 36λ
(D) 5λ
(C) n = 4, l = −1, m = +2, s = −1/2 5 9
(D) n = 4, l = 1, m = 0, s = −1/2 (33) What is the maximum wavelength line in the Lyman series
of He+ ion ?
(29) The energy of an electron in the 3rd orbit of a hydrogenic (A) 3R (B) 1/3R
atom is −E. The energy of an electron in the first orbit will
be (C) 4/4R (D) None of these
(A) − 3E (B) − E/3
(34) The electron in the nth orbit of Li2+ is excited to (n + 1)
(C) − E/9 (D) − 9E orbit using the radiation of energy 1.47 × 10−17 J (as shown
(30) Which of the following plots of radial probability function in the diagram). The value of n is .....Given
4πr2 Ψ2r is incorrectly labelled RH = 2.18 × 10−18 J [JEE MAIN 2023]
2
(44) Match the columns and choose correct option
Column −I Column −II
(a) 4s (p) Circular orbit
around nucleus
(b) 4p (q) Non directional or-
bital
(A) 2 (B) 3
(c) 1s (r) Angular momentum
(C) 1 (D) 4
= 2h/π
(35) One energy difference between the states n = 2 and n = 3
(d) 3d (s) Radial node is zero
is E eV in hydrogen atom. The ionization potential of H
atom is ........... E (A) a − p, b − q, c − r, d − s (B) a − q, b − r, c − p, d − s
(A) 3.2 (B) 5.6
(C) a − s, b − r, c − q, d − p (D) a − p, b − r, c − s, d − q
(C) 7.2 (D) 13.2 (45) The maximum number of electrons that can have principal
(36) The maximum number of electrons that can be quantum number, n = 3, and spin quantum number,
accommodated in ′ f ′ sub shell is ms = −1/2, is [IIT 2011]
(A) 2 (B) 8 (A) 2 (B) 7
(C) 32 (D) 14 (C) 9 (D) 5
(37) Pick out the isoelectronic structures from the following (46) The energy of an electron in the first Bohr orbit of Hatom is
CH3+ H3 O+ N H3 CH3− [IIT 1993] −13.6 eV . The possible energy value (s) of the excited state
I II III IV
(s) for electrons in Bohr orbits to hydrogen is(are) ............. eV
(A) I and II (B) I and IV [IIT 1998]
(C) I and III (D) II, III and IV (A) −3.4 (B) −4.2
(38) The nitride ion in lithium nitride is composed of (C) −6.8 (D) +6.8
(A) 7 protons +10 electrons (47) How many electrons can fit in the orbital for which n = 3
(B) 10 protons +10 electrons and l = 1 ? [NEET 2016]
(A) 6 (B) 2
(C) 7 protons +7 protons
(C) 10 (D) 14
(D) 10 protons +7 electrons
(48) The kinetic energy of an electron in the second Bohr orbit of
(39) Assertion : Absorption spectrum consists of some bright a hydrogen atom is [ a0 is Bohr radius]: [IIT 2012]
lines separated by dark spaces. (A) 4π2hma2
2
(B) 16πh2 ma2
2
Reason : Emission spectrum consists of dark lines. [AIIMS 2002] 0 0
(A) If both Assertion and Reason are correct and the Reason (C) (D)
2 2
h h
32π 2 ma20 64π 2 ma20
is a correct explanation of the Assertion.
(49) The value of Planck’s constant is 6.63 × 10−34 J s. The speed
(B) If both Assertion and Reason are correct but Reason is of light is 3 × 1017 nm s−1 . Which value is closest to the
not a correct explanation of the Assertion. wavelength in nanometer of a quantum of light with
(C) If the Assertion is correct but Reason is incorrect. frequency of 6 × 1018 s−1 ? [NEET 2013]
(A) 50 (B) 75
(D) If both the Assertion and Reason are incorrect.
(C) 10 (D) 25
(40) Be′ s 4th electron will have four quantum numbers
nlms (50) A surface ejects electrons when hitted by green light but
(A) 1 0 0 +1/2 (B) 1 1 +1 +1/2 not. When hitted by yellow light. Will electrons be ejected if
the surface is hitted by red light :
(C) 2 0 0 −1/2 (D) 2 1 0 +1/2 (A) Yes
(41) The energy required to break one mole of Cl − Cl bonds in
(B) No
Cl2 is 242 kJ mol−1 . The longest wavelength of light
capable of breaking a single Cl − Cl bond is ............ nm (C) Yes, if the red beam is quite intense
(C = 3 × 108 ms−1 and NA = 6.02 × mol−1 ). [AIEEE 2010]
(D) Yes, if the red beam continues to fall upon the surface
(A) 594 (B) 640 for a long time
(C) 700 (D) 494 (51) What will be the ratio of wavelength of third line of Balmer
(42) Which of the following sets of quantum numbers represent series in He⊕ ion spectrum to the first line of balmer series
an impossible arrangement in Li+2 ion spectrum
n l m ms [IIT 1986] (A) 5 : 3 (B) 125 : 189
(A) 3 2 −2 (+) 12 (B) 4 0 0 (−) 12
(C) 27 : 20 (D) 125 : 84
(C) 3 2 −3 (+) 12 (D) 5 3 0 (−) 1
2 (52) The energies E1 and E2 of two radiations are 25 eV and
(43) A cricket ball of 0.5 kg is moving with a velocity of 50 eV respectively. The relation between their wavelengths
100 m/ sec. The wavelength associated with its motion is i.e., λ1 and λ2 will be
(A) 1/100 cm (B) 6.6 × 10−34 m (A) λ1 = λ2 (B) λ1 = 2λ2
(C) 1.32 × 10−35 m (D) 6.6 × 10−28 m (C) λ1 = 4λ2 (D) λ1 = 1/2λ2
3
(53) If the ionization energy of He+ is 8.68 × 10−18 J , then the Reason : It belongs to p− subshell. [AIIMS 2011]
energy of Be+3 ion in the second orbit is:- ( Z of Be = 4) (A) If both Assertion and Reason are correct and the Reason
(A) −4.9 × 10−18 J (B) −44.1 × 10−18 J is a correct explanation of the Assertion.
(C) −11.025 × 10−18 J (D) −8.68 × 10−18 J (B) If both Assertion and Reason are correct but Reason is
(54) The following sets of quantum numbers represent four not a correct explanation of the Assertion.
electrons in an atom (C) If the Assertion is correct but Reason is incorrect.
(i) n = 4, l = 1 (ii) n = 4, l = 0
(iii) n = 3, l = 2 (iv) n = 3, l = 1 (D) If both the Assertion and Reason are incorrect.
The sequence representing increasing order of energy, is (64) The ratio of the radius of the first three Bohr orbits is
[AIEEE 2012]
(A) 1 : 12 : 13 (B) 1 : 2 : 3
(A) (iii) < (i) < (iv) < (ii) (B) (iv) < (ii) < (iii) < (i)
(C) 1 : 4 : 9 (D) 1 : 8 : 27
(C) (i) < (iii) < (ii) < (iv) (D) (ii) < (iv) < (i) < (iii)
(65) The difference in wavelength of first and second spectral
(55) The ionization energy of hydrogen atom is −13.6 eV. The o
energy required to excite the electron in a hydrogen atom lines of lyman series in Li+2 ion spectrum is ................ A
from the ground state to the first excited state is (A) 190 (B) 182.1
(Avogadro’s constant = 6.022 × 1023 ) (C) 27 (D) 21.1
(A) 1.69 × 10−20 J (B) 1.69 × 10−23 J
(66) The orientation of an atomic orbital is governed by [AIPMT 2006]
(C) 1.69 × 1023 J (D) 1.69 × 1025 J (A) principal quantum number
rd
(56) If the radius of the 3 Bohr’s orbit of hydrogen atom is r3 (B) azimuthal quantum number
and the radius of 4th Bohr’s orbit is r4 . Then .... [JEE MAIN 2022]
(A) r4 = 169
r3 (B) r4 = 16 (C) spin quantum number
9 r3
(C) r4 = 34 r3 (D) r4 = 43 r3 (D) magnetic quantum number.
(57) A 124 W bulb converts only 15 % of the energy supplied to (67) An atom emits energy equal to 4 × 10−12 erg. To which part
it into visible light of wavelength 640 nm . How many of electromagnetic spectrum it belongs :
photons are emitted by the light bulb in one second (A) U V region (B) Visible region
(A) 4 × 1019 (B) 6 × 1019 (C) IR region (D) Microwave region
(C) 8 × 1018 (D) 3 × 1019 photon (68) Given : The mass of electron is 9.1 × 10−31 Kg Planck
(58) Which of the following oxides of nitrogen is isoelectronic constant is 6.62 × 10−34 Js , the uncertainty involved in the
with CO2 [AIPMT 1990]
o
measurement of velocity within a distance of 0.1 A is
(A) N O2 (B) N2 O (A) 5.79 × 106 ms−1 (B) 5.79 × 107 ms−1
(C) N O (D) N2 O2 (C) 5.79 × 108 ms−1 (D) 5.79 × 105 ms−1
(59) In potassium atom, electronic energy level is in the (69) Number of protons, neutrons and electrons in the element
following order 89 Y is
231
(A) 4s > 3d (B) 4s < 2p (A) 89, 231, 89 (B) 89, 89, 242
(C) 4s < 3d (D) 4s > 4p (C) 89, 142, 89 (D) 89, 71, 89
(60) The electrons are more likely to be found [JEE MAIN 2019] (70) What is the potential energy of the electron in the L− shell
of the hydrogen atom? .............. eV
(A) −13.6 (B) −6.8
(C) −10.2 (D) −3.4
(71) The frequency of a certain line of lyman series of atomic
spectrum of H atom satisfy the following condition
(i) It is the sum of frequency of another lyman line and
balmer line.
(A) in the region a and b (B) in the region a and c (ii) It is the sum of frequency of a certain line, lyman line
and a paschen line
(C) only in the region a (D) only in the region c (iii) It is the sum of frequency of a lyman and a paschen line
(61) Choose the pair whose ions have the similar electronic but no bracket line
configuration To what transition does this frequency correspond?
(A) Lithium and sodium (B) Potassium and calcium (A) n2 = 3 to n1 = 1 (B) n2 = 3 to n1 = 2
(C) Sodium and potassium (D) Both (a) and (c) (C) n2 = 2 to n1 = 1 (D) n2 = 4 to n1 = 1
(62) Ratio of time period of electron in first and third orbit of H− (72) In a potassium atom, electronic energy levels are in the
atom would be following order
(A) 1 : 18 (B) 1 : 27 (A) 4s > 3d (B) 4s > 4p
(C) 1 : 2 (D) 27 : 1 (C) 4s < 3d (D) 4s < 3p
(63) Assertion : An orbital designated by n = 3, l = 1 has double (73) Values of the four quantum numbers for the last electron in
dumb-bell shape. the atom are n = 4, l = 1, m = +1 and s = −1/2. Atomic
4
number of the atom will be %
(A) 22 (B) 32 (A) 30 (B) 40
(C) 31 (D) 36 (C) 50 (D) 100
(74) Energy levels A, B, C of a certain atom corresponds to (83) Radius of the nucleus is equal to 10−12 cm. and that of the
increasing values of energy, i.e., EA < EB < EC . If λ1 , λ2 atom is equal to 10−8 cm. What is the fraction of the volume
and λ3 are the wavelength of radiations corresponding to of the atom occupied by nucleus ?
the transitions C to B, B to A and C to A respectively,
(A) 1012 (B) 10−12
which of the following statement is correct :
(C) 10−20 (D) 10−4
(84) Which set of quantum numbers are not possible from the
following
(A) n = 3, l = 2, m = 0, s = − 12
(B) n = 3, l = 2, m = −2, s = − 21
(A) λ3 = λ1 + λ2 (B) λ3 = λ1 λ2
λ1 +λ2
(C) n = 3, l = 3, m = −3, s = − 21
(C) λ1 + λ2 + λ3 = 0 (D) λ23 = λ21 + λ22
(75) An isotone of 32 Ge76 is (D) n = 3, l = 0, m = 0, s = − 12
(i) 32 Ge77 (ii) 33 As77 (85) The energy of electron in hydrogen atom in its grounds state
(iii) 34 Se77 (iv) 34 Se78 is −13.6 eV . The energy of the level corresponding to the
(A) Only (i) and (ii) (B) Only (ii) and (iii) quantum number equal to 5 is ............. eV
(C) Only (ii) and (iv) (D) (ii), (iii) and (iv) (A) −0.54 (B) −0.85
(76) Which one of the following is not the characteristic of (C) −0.64 (D) −0.40
Planck’s quantum theory of radiation [AIIMS 1991]
(86) The uncertainty in momentum of an electron is
(A) The energy is not absorbed or emitted in whole number 1 × 10−5 kg − m/s. The uncertainty in its position will be
or multiple of quantum (h = 6.62 × 10−34 kg − m2 /s) [AIPMT 1999]
(B) Radiation is associated with energy (A) 1.05 × 10−28 m (B) 1.05 × 10−26 m
(C) Radiation energy is not emitted or absorbed conti- (C) 5.27 × 10−30 m (D) 5.25 × 10−28 m
nuously but in the form of small packets called quanta (87) Number of waves made by Bohr’s electron in one complete
(D) This magnitude of energy associated with a quantum is revolution in 3rd orbit
proportional to the frequency (A) 1 (B) 2
(77) What accelerating potential must be imparted to a proton (C) 3 (D) 4
o
beam to give it an effective λ = 0.05 A . (88) The frequency of an electromagnetic radiation is 2 × 106 Hz.
(V = 33 volt) (mp = 1.672 × 10−27 kg) What is its wavelength in metres (Velocity of light
(A) 4.95 × 106 V (B) 4.95 × 105 V = 3 × 108 ms−1 )
(C) 2.475 × 106 V (D) 2.475 × 105 V (A) 6.0 × 1014 (B) 1.5 × 104
(78) What will be the mass of a particle if uncertainty in its (C) 1.5 × 102 (D) 0.66 × 10−2
position is 10−8 m and uncertainty in velocity is
(89) The quantum numbers for the outermost electron of an
5.26 × 10−25 m s−1 ? ............... kg
element are given below as n = 2, l = 0, m = 0, s = + 12 .
(A) 0.01 (B) 100 The atoms is
(C) 1 (D) 10 (A) Lithium (B) Beryllium
o
(79) What is the radius of Bohr’s fifth orbit for B +4 . .................. A (C) Hydrogen (D) Boron
(A) 4.645 (B) 1.645 (90) The total number of orbitals in an energy level designated
by principal quantum number n is equal to [AIIMS 1997]
(C) 3.645 (D) 2.645
(A) 2n (B) 2n2
(80) Two electrons occupying the same orbital are distinguished
by [NEET 2016] (C) n (D) n2
(A) azimuthal quantum number (91) If the electron jumps from 7.00 eV energy level to 5.0 eV
(B) spin quantum number energy level, it :
(A) Absorbs 2.0 eV kinetic energy
(C) principal quantum number
(B) Absorbs 2.0 eV potential energy
(D) magnetic quantum number
(C) Emits 2.0 eV electrical energy
(81) If the shortest wavelength in Lyman series of hydrogen
atom is A, then the longest wavelength in Paschen series of (D) Emits 2.0 eV photon
He+ is [JEE MAIN 2017]
(92) The wave number of the first Lyman transition in H atom
(A) 5A (B) 9A
9 5 spectrum is equal to the wave number of second balmer
(C) 36A
5 (D) 36A
7
transition in the spectrum of
(82) Find the % difference (approximate) in deBorglie (A) Li2+ (B) Be3+
wavelength if the temperature of gas become double ............. (C) He+ (D) B 4+
5
(93) Maximum number of electrons in a subshell of an atom is azimuthal quantum number and magnetic quantum number
determined by the following [AIPMT 2009] are −3.4eV, 2 and 0 respectively. Which of the following
(A) 2l + 1 (B) 4l − 2 statement(s) is(are) true for the state Ψ ?
(1) It has 2 angular nodes
(C) 2n2 (D) 4l + 2 (2) It has 3 radial nodes
(94) What is the wavelength of light required to raise an electron (3) It is a 4d state
in the O7+ ion from n = 1 to shell to n = 2 shell ............... nm (4) The nuclear charge experienced by the electron in this
(A) 3.8 (B) 38 state is less than 2e, where e is the magnitude of the
electronic charge. [IIT 2019]
(C) 19 (D) 1.9
(A) 1, 3 (B) 1, 4
(95) Minimum de-Broglie wavelength is associated with
(A) Electron (B) Proton (C) 1, 2 (D) 1, 2, 3
(C) CO2 molecule (D) SO2 molecule

(102) Which of the following has maximum energy [AIIMS 2002]
(96) Beryllium’s fourth electron will have the four quantum (A)
numbers :
(A) n = 1, l = 0, m = 0, s = +1/2
(B) n = 1, l = 1, m = 1, s = +1/2
(C) n = 2, l = 0, m = 0, s = −1/2
(B)
(D) n = 2, l = 1, m = 0, s = +1/2
(97) Ejection of the photoelectron from metal in the
photoelectric effect experiment can be stopped by applying
0.5 V when the radiation of 250 nm is used. The work
function of the metal is ................ eV [JEE MAIN 2018]
(C)
(A) 4 (B) 5.5
(C) 4.5 (D) 5
(98) The value of the energy for the first excited state of
hydrogen atom will be ............. eV
(A) −13.6 (B) −3.40 (D)
(C) −1.51 (D) −0.85
(99) Based on equation E = −2.178 × 10−18 J Zn2 certain
2
conclusions are written. Which of them is not correct ?

(A) For n = 1, the electron has a more negative energy than
it does for n = 6 which means that the electron is more (103) In Bohr’s model, atomic radius of the first orbit is γ, the
lossely bound in the smallest allowed orbit. radius of the 3rd orbit, is
(A) γ/3 (B) γ
(B) The negative sign in equation simply means that the
energy of electron bound to the nucleus is lower than it (C) 3γ (D) 9γ
would be if the electrons were at the infinite distance
from the nucleus (104) Which of the following set of quantum number is not valid
[AIIMS 2001]
(C) Larger the value of n, the larger is the orbit radius
(A) n = 1, l = 2 (B) n = 2, m = 1
(D) Equation can be used to calculate the change in energy
when the electron change orbit (C) m = 3, l = 0 (D) n = 4, l = 2
(100) Observe the following graph for the de-Broglie wavelength (105) At temperature T , the average kinetic energy of any particle
of a hypothetical charged particle (q = 1.6 × 10−19 C). Find is 23 KT . The de Broglie wavelength follows the order [JEE
the mass of the particle (h = 6.0 × 10−34 J − s) MAIN 2015]
(A) Visible photon > Thermal neutron > Thermal electron

(B) Thermal proton > Thermal electron > Visible photon
(C) Thermal proton > Visible photon > Thermal electron
(D) Visible photon > Thermal electron > Thermal neutron
(106) Given below are two statements:

Statement I : Bohr’s theory accounts for the stability and
line spectrum of Li+ ion.
(A) 45 × 10−49 kg (B) 45 × 10−45 kg Statement II : Bohr’s theory was unable to explain the
splitting of spectral lines in the presence of a magnetic field.
(C) 4.5 × 10−45 kg (D) 4.5 × 10−45 gm In the light of the above statements, choose the most
(101) The ground state energy of hydrogen atom is −13.6eV . appropriate answer from the options given below: [JEE MAIN
Consider an electronic state Ψ of He− whose energy, 2021]
6
(A) Both statement I and statement II are true. (117) The orbital angular momentum of an electron in an s orbital
is
(B) Statement I is false but statement II is true. (A) 1 (B) 0
(C) Both statement I and statement II are false. √
(C) 2
2h
∏ (D) all of these
(D) Statement I is true but statement II is false.
(118) The observation of line spectrum of hydrogen atom
(107) If the radius of first orbit of H atom is a0 , the de-Broglie indicates that
wavelength of an electron in the third orbit is [AIEEE 2012] (A) the electrons do not lose energy when in stationary
(A) 4πa0 (B) 8πa0 states
(C) 6πa0 (D) 2πa0 (B) there is emission of energy when a sample of hydrogen
(108) The subshell that arises after f is called g subshell. is heated
(a) How many g orbital are present in the g subshell ? (C) an electron in excited state loss energy continuously
(b) In what principal electronic shell whould the g subshell
first occur and what is the total number of orbitals in this (D) an electron in excited state loses energy in the form of
principal shell ? bundles or packets of energy
(A) (a)3; (b)1s (B) (a)9; (b)3s (119) Uncertainity in position of an electron and helium atom is
same. If uncertainity in momentum of electron is 32 × 105
(C) (a)3; (b)2s (D) (a)9; (b)2s
then uncertainity in momentum of helium atom is
(109) If the potential energy of the electron is −10 eV what is (A) 32 × 105 (B) 16 × 105
total energy? ................ eV
(A) −20 (B) +20 (C) 8 × 105 (D) 4 × 105
(C) +5 (D) −5 (120) The number of correct statements from the following
A. For 1 s orbital, the probability density is maximum at the
(110) If radius of second Bohr orbit of the He+ ion is 105.8 pm, nucleus.
what is the radius of third Bohr orbit of Li2+ ion? [NEET 2022] B. For 2s orbital, the probability density first increases to
(A) 15.87 pm (B) 1.587 pm maximum and then decreases sharply to zero.
(C) 158.7 Å (D) 158.7 pm C. Boundary surface diagrams of the orbitals encloses a
region of 100% probability of finding the electron.
(111) Consider the ground state of (Z = 24). The numbers of D. p and d-orbitals have 1 and 2 angular nodes respectively.
electrons with the azimuthal quantum numbers, l = 1 and 2 E. Probability density of p-orbital is zero at the nucleus. [JEE
are, respectively [AIEEE 2004] MAIN 2023]
(A) 16 and 4 (B) 12 and 5 (A) 3 (B) 4
(C) 12 and 4 (D) 16 and 5 (C) 2 (D) 5
(112) What is the value of azimuthal quantum number for ′ g ′ sub
(121) The emission spectrum of hydrogen is found to satisfy the
shell ?
expression for the ( energy change.
) ∆E (in joules) such that
(A) 3 (B) 4
∆E = 2.18 × 10 n2 − n2 J where n1 = 1, 2, 3. . . .. and n2
1 1
(C) 6 (D) 5 1 2
= 2, 3, 4....... The spectral lines correspond to Paschen series
(113) According to the Bohr theory, which of the following to
transitions in the hydrogen atom will give rise to the least (A) n1 = 1 and n2 = 2, 3, 4
energetic photon ? [AIPMT 2011]
(B) n1 = 3 and n2 = 4, 5, 6
(A) n = 6 to n = 1 (B) n = 5 to n = 4
(C) n1 = 1 and n2 = 3, 4, 5
(C) n = 6 to n = 5 (D) n = 5 to n = 3
(114) The energy of an electron in the first Bohr orbit of hydrogen (D) n1 = 2 and n2 = 3, 3, 5
atom is −2.18 × 10−18 J. Its energy in the third Bohr orbit is (122) Which statement relating to the spectrum of H atom is false
......... [JEE MAIN 2023] :
(A) 1
27 of this value (A) The lines can be defined by quantum number
(B) One third of this value (B) The lines of longest wavelength in the Balmer series
corresponds to the transition between n − 3 and n = 2
(C) Three times of this value
levels
(D) 1
th of this value
9 (C) The spectral lines are closer together at longer
(115) Which of the following sets is possible for quantum numbers wavelength
(A) n = 4, l = 3, m = −2, s = 0 (D) A continuum occurs at n = ∞
(B) n = 4, l = 4, m = +2, s = − 12 (123) The number of photons emitted by a monochromatic (single
(C) n = 4, l = 4, m = −2, s = + 12 frequency) infrared range finder of power 1 mW and
wavelength of 1000 nm, in 0.1 second is x × 1013 . The value
(D) n = 4, l = 3, m = −2, s = + 12 of x is ..... .
(116) Which of the following atoms and ions are isoelectronic i.e. (Nearest
( integer) )
have the same number of electrons with the neon atom h = 6.63 × 10−34 Js, c = 3.00 × 108 ms−1 [JEE MAIN 2021]
(A) F − (B) Oxygen atom (A) 50 (B) 500
(C) M g (D) N − (C) 5 (D) 663
7
(124) The energy of an electron revolving in nth Bohr’s orbit of an first orbit of hydrogen atom = . . . . . . . . . × 105 ms−1
atom is given by the expression (nearest integer) [JEE MAIN 2024]
(A) En = − 2π nm2 he2 z (B) En = − 2π nme (A) 22 (B) 25
2 4 2 2 2 2 2
z
2 h2
(C) En = − 2π nme
2
2 h2
z 4 2
(D) En = − 2πm
2 2 4
e z (C) 30 (D) 35
n2 h 2
(125) Which of the following pair is not isoelectronic species? (At. (134) In ground state of He⊕ ion how much energy is supplied to
no. Sm, 62; Er, 68 : Y b, 70 : Lu, 71; Eu, 63 : T b, 65; Tm, 69) electron so that second line of Balmer series is obtained in
[JEE MAIN 2022] its spectrum ................. eV
(A) Sm2+ and Er3+ (B) Y b2+ and Lu3+ (A) 51 (B) 48.36
(C) T b2+ and T m4+ (D) both (A) and (C) are true (C) 10.2 (D) None of these
(126) The specific charge of proton is 9.6 × 106 C kg −1 then for an
α-particle it will be (135) The ratio of two of the first four Bohr’s orbits of the
hydrogen atom are in the ratio 1 : 4 The energy difference
(A) 38.4 × 107 C kg −1 (B) 19.2 × 107 C kg −1
between them may be
(C) 2.4 × 107 C kg −1 (D) 4.8 × 107 C kg −1 (A) Either 12.09 eV or 10.2 eV
(127) Which of the following quantum number is not obtained by
(B) Either 2.55 eV or 10.2 eV
the solution of Schrodinger wave equation
(A) magnetic quantum number (C) Either 13.6 eV or 3.4 eV
(B) principal quantum number (D) Either 3.4 eV or 0.85 eV
(C) spin quantum number (136) In the nuclear transmutation 94 Be + X −→ 84 Be + Y (X, Y )

(D) azimuthal quantum number is (are)
(A) (γ, n) (B) (p, D) (C) (n, D) (D) (γ, p) [IIT 2013]
(128) The ratio of velocity of electron in second orbit of He+ to (A) (A, B) (B) (B, D)
third orbit of B +4 is
(A) 53 (B) 35 (C) (B, C) (D) (A, C)
(C) 3
2 (D) 2
3
(137) Correct energy value order is :-
(129) The de-Broglie wavelength of a particle of mass 6.63 g (A) ns np nd(n − 1)f (B) ns np(n − 1)d (n − 2)f
moving with a velocity of 100 ms−1 is [JEE MAIN 2014] (C) ns np(n − 1)d (n − 1)f (D) ns(n − 1)d n(n − 1)f
(A) 10−33 m (B) 10−35 m
(138) The electrons, identified by quantum by numbers n and l,
(C) 10−31 m (D) 10−25 m (i) n = 4, l = 1 (ii) n = 4, l = 0 (iii) n = 3, l = 2
(130) The graph between |ψ| and r(radial distance) is shown
2
(iv) n = 3, l = 1 can be placed in order of increasing energy,
below. This represents [JEE MAIN 2019] from the lowest to highest, as [IIT 1999]
(A) (iv) < (ii) < (iii) < (i) (B) (ii) < (iv) < (i) < (iii)
(C) (i) < (iii) < (ii) < (iv) (D) (iii) < (i) < (iv) < (ii)
(139) Electrons are emitted with zero velocity from a metal

surface when it is exposed to radiation of wavelenght
o
8000 A. What should be the maximum velocity of emitted
electron when the same metal surface is exposed to
o ( )
radiation of wavelength 5000 A ? h = 6.6 × 10−34 J.s
(A) 5.74 × 106 ms−1 (B) 5.74 × 105 ms−1
(A) 1s orbital (B) 3s orbital (C) 5.74 × 104 ms−1 (D) 5.74 × 107 ms−1
(C) 2s orbital (D) 2p orbital
(140) The set of quantum number for the 19th electrons in
(131) The four quantum number for the valence shell electron or chromium is
last electron of sodium (Z = 11 ) is (A) n = 4, l = 0, s = +1/2 or −1/2
(A) n = 2, l = 1, m = −1, s = − 12
(B) n = 3, l = 2, m = 1, s = +1/2 or −1/2
(B) n = 3, l = 0, m = 0, s = + 12
(C) n = 3, l = 2, m = −1, s = +1/2 or −1/2
(C) n = 3, l = 2, m = −2, s = − 12
(D) n = 4, l = 1, m = 0, s = +1/2 or −1/2
(D) n = 3, l = 2, m = 2, s = + 12
(141) Which of the following set of quantum numbers are allowed
(132) When electronic transition occurs from higher energy state ?
to lower energy state with energy difference equal to ∆E
(A) n = 1, l = 1, m = 1, s = 12
electron volts, the wavelength of the line emitted is
approximately equal to (B) n = 2, l = 1, m = 1, s = 1
(A) 12395
∆E × 10
−10
m (B) 12395
∆E × 10 m
10
(C) n = 3, l = 0, m = −1, s = 1
2
(C) 12395
∆E × 10−10 cm (D) 12395
∆E × 1010 cm (D) n = 3, l = 1, m = 1, s = 1
2
(133) The value of Rydberg constant (RH ) is 2.18 × 10 J. The
−18
velocity of electron having mass 9.1 × 10−31 kg in Bohr’s (142) Which one is the wrong statement? [NEET 2017]
8
(A) The uncertainty principle is ∆E × ∆t ≥ h (153) Not considering the electronic spin, the degeneracy of the
4π
second excited state (n = 3) of H atom is 9 , while the
(B) Half filled and fully filled orbitals have greater stability degeneracy of the second excited state of H − is [IIT 2015]
due to greater exchange energy, greater symmetry and
more balanced arrangement. (154) When light of wavelength 248 nm falls on a metal of
threshold energy 3.0 eV , the de-Broglie wavelength of
(C) The energy of 2s− orbital is less than the energy of 2p− emitted electrons is ............. Å
orbital in case of hydrogen like atoms. (Round√off to the Nearest Integer).
(D) de-Broglie’s wavelength is given by λ = mvh
, where m = [Use : 3 = 1.73, h = 6.63 × 10−34 Js
mass of the particle, v = group velocity of the particle. me = 9.1 × 10−31 kg;]c = 3.0 × 108 ms−1
1eV = 1.6 × 10−19 J [JEE MAIN 2021]
(143) The four quantum numbers of the outermost orbital of K
(atomic no. = 19 ) are (155) The kinetic energy of an electron in the second Bohr orbit of
h2
(A) n = 2, l = 0, m = 0, s = + 12 a hydrogen atom is equal to xma 2 . The value of 10x is ........ .
0
(a0 is radius of Bohr’s orbit) (Nearest integer) [Given :
(B) n = 4, l = 0, m = 0, s = + 12
π = 3.14] [JEE MAIN 2021]
(C) n = 3, l = 1, m = 1, s = + 12
(156) The uncertainity in the location of circulating electron is
(D) n = 4, l = 2, m = −1, s = + 12 equal in it’s de-Broglie wavelength the minimum percent
(144) Which of the following set of quantum numbers belong to error in it’s measurement of velocity under this
highest energy cicumstances will be approximately
(A) n = 4, l = 0, m = 0, s = + 12 (157) For n = 3 energy level, the number of possible orbitals (all
kinds) are
(B) n = 3, l = 0, m = 0, s = + 12
(158) Which orbit of Be+3 has the same orbit radius as that of the
(C) n = 3, l = 1, m = 1, s = + 12
ground state of hydrogen atom
(D) n = 3, l = 2, m = 1, s = + 12
(159) Assume that the radius of the first Bohr orbit of hydrogen
(145) Which of the following are isoelectronic and isostructural atom is 0.6Å. The radius of the third Bohr orbit of He+ is
N O3− , CO32− , ClO3− , SO3 [IIT 2003] .................. picometer. (Nearest Integer) [JEE MAIN 2023]
(A) N O3− , CO32− (B) SO3 , N O3−
(160) Consider the following set of quantum numbers
(C) ClO3− , CO32− (D) CO32− , SO3 n l ml
(146) Which one of the following should be most stable
A 3 3 −3
(A) H2+ (B) H +
B 3 2 −2
(C) H (D) H −
C 2 1 +1
(147) The number of radial node/s for 3p orbital is: [JEE MAIN 2024]
(A) 1 (B) 4 D 2 2 +2
The number of correct sets of quantum numbers is ..... . [JEE
(C) 2 (D) 3 MAIN 2022]
(148) A certain orbital has no angular nodes and two radial nodes.
The orbital is [JEE MAIN 2021] (161) The de-Broglie’s wavelength of an electron in the 4th orbit is
. . . . . . . . πa0 . (a0 = Bohr’s radius) [JEE MAIN 2024]
(A) 2 s (B) 3 s
(C) 3 p (D) 2 p (162) The electronic configuration of a dipositive ion M 2+ is
2, 8, 14 and its atomic mass is 56. The number of neutrons in
(149) Which of the following is not permissible arrangement of
the nucleus would be :
electrons in an atom
(A) n = 3 ; l = 2 ; m = −2 ; s = − 12 (163) If the velocity of hydrogen molecule is 5 × 104 cm sec−1 ,
o
(B) n = 4 ; l = 0 ; m = 0 ; s = − 12 then its de-Broglie wavelength is ............. A
(C) n = 5 ; l = 3 ; m = 0 ; s = + 12 (164) A photon of 300 nm is absorbed by a gas and then re-emits

two photons. One re-emitted photon has wavelength
(D) n = 3 ; l = 2 ; m = −3 ; s = − 12 496 nm , the wavelength of second re-emitted photon is
(150) The limiting line in Balmer series will have a frequency of
(165) A certain atomic transition from an excited state to the
(Rydberg constant,R∞ = 3.29 × 1015 cycles/s ) [AIEEE 2012]
ground state of the hydrogen atom in one or more steps
(A) 8.22 × 1014 s−1 (B) 3.29 × 1015 s−1 give rise to four line in the ultraviolet region of the
(C) 3.65 × 1014 s−1 (D) 5.26 × 1013 s−1 spectrum. How many lines does this transition produce in
the infrared region of the spectrum
.......... Chemistry - Section B (NUMERIC) .......... (166) A metal surface is exposed to 500 nm radiation. The
threshold frequency of the metal for photoelectric current is
(151) The electronic configuration of a dipositive metal M 2+ is 4.3 × 1014 Hz. The velocity of ejected electron is
2, 8, 14 and its atomic weight is 56 a.m.u. The number of ....... × 105 ms−1 (Nearest integer) ]
neutrons in its nuclei would be [Use : h = 6.63 × 10−34 Js, me = 9.0 × 10−31 kg [JEE MAIN 2021]
(152) The number of orbitals in the fourth principal quantum (167) How many spectral line of Balmer series present in visible
number will be region : [AIIMS 2019]
9
(168) The number of electrons present in all the completely filled (179) The wavelength of an electron of kinetic energy
subshells having n = 4 and s = + 12 is)______________. 4.50 × 10−29 J is . . . .. × 10−5 m. (Nearest integer)Given :
(Where n = principal quantum number and s = spin mass of electron is 9 × 10−31 kg, h = 6.6× 10−34 Js [JEE MAIN
quantum number) [JEE MAIN 2024] 2023]
(169) The wave no. of the first line of Balmer series of H atom is (180) If the sum of (n + l) is 6 ; how many e−1 s would have clock
15200 cm−1 . What is wave number of the first line of Lyman wise spin associated with this energy leval
series of Li ................ cm
2+ −1
(181) The uncertainties in the velocities of two particles, A and B
(170) Following figure shows spectrum of an ideal black body at are 0.05 and 0.02 ms−1 respectively. The mass of B is five
four different temperatures. The number of correct times to that of the mass of A. What is the ratio of
statement/s from the following is ............... uncertainties ∆x
∆xA
B
in their positions ? [AIIMS 2008]
A. T4 > T3 > T2 > T1 (182) The number of orbitals with n = 5, ml = +2 is ...... . (Round
B. The black body consists of particles performing simple off to the Nearest Integer) [JEE MAIN 2021]
harmonic motion.
C. The peak of the spectrum shifts to shorter wavelength as (183) Frequency of the de-Broglie wave of election in Bohr’s first
temperature increases. orbit of hydrogen atom is. . . . . . . . . . ×1013 Hz (nearest
D. Tv11 = Tv22 = Tv33 ̸= constant integer).
E. The given spectrum could be explained using [Given : RH ( Rydberg constant) = 2.18 × 10−18 J.
quantisation of energy. [JEE MAIN 2023] h( Plank’s constant ) = 6.6 × 10−34 J.s. ] [JEE MAIN 2024]
(184) The I.P. of a hydrogen like species is 36 eV . What is the
value of second excitation energy ............ eV
(185) Nitrogen atom has an atomic number of 7 and oxygen has
an atomic number 8. The total number of electrons in a
nitrate ion will be
(186) An accelerated electron has a speed of 5 × 106 ms−1 with
an uncertainty of 0.02 %. The uncertainty in finding its
location while in motion is x × 10−9 m. The value of x is ......
(Nearest integer)
[Use mass of electron ]
= 9.1 × 10−31 kg, h = 6.63 × 10−34 J s, π = 3.14 [JEE MAIN
2021]
(171) Total number of spectral lines when electron jumps from 8th
(187) If the wavelength for an electron emitted from H atom is
orbit to 2nd orbit :
3.3 × 10−10 m, then energy absorbed by the electron in its
(172) When the excited electron of a H atom from n = 5 drops to ground state compared to minimum energy required for its
the ground state, the maximum number of emission lines escape from the atom, is .......times. (Nearest integer).
observed are....... [JEE MAIN 2022] [Given : h = 6.626 × 10−34 Js,Mass of electron
= 9.1 × 10−31 ] [JEE MAIN 2022]
(173) Photon having wavelength 310 nm is used to break the
bond of A2 molecule having bond energy 288 kJ mol−1 (188) Maximum number of electrons in a subshell with l = 3 and
then % of energy of photon converted to the K.E. is n = 4 is [AIPMT 2012]
o
[hc = 12400 ev A , 1 eV /atom = 96 kJ/mol] (189) Maximum number of electrons present in ′ N ′ shell is
(174) The number of atomic orbitals from the following having 5 (190) Total number of ions from the following with noble gas
radial nodes is ........ 7s, 7p, 6s, 8p, 8d [JEE MAIN 2023] configuration is__________.
Sr2+ (Z = 38), Cs+ (Z = 55), La2+ (Z = 57)Pb2+
(175) The work function (ϕ) of some metals is listed below. The (Z = 82), Yb2+ (Z = 70) and Fe2+ (Z = 26) [JEE MAIN 2024]
number of metals which will show photoelectric effect
when light of 300 nm wavelength falls on the metal is (191) A source of monochromatic radiation of wavelength 400 nm
provides 1000 J of energy in 10 seconds. When this radiation
Metal Li Na K Mg Cu Ag Fe Pt W
[IIT falls on the surface of sodium, x × 1020 electrons are ejected
ϕ(eV )2.4 2.3 2.2 3.7 4.8 4.3 4.7 6.3 4.75 per second. Assume that wavelength 400 nm is sufficient
2011] for ejection of electron from the surface of sodium metal.
The
( value of x is−34....... )(Nearest integer)
(176) The wavelength of electrons accelerated from rest through h = 6.626 × 10 Js [JEE MAIN 2021]
a potential difference of 40 kV is X × 10−12 m. The value of x
is ....... (Nearest integer) (192) If the work function of a metal is 6.63 × 10−19 J, the
Given : Mass of electrons = 9.1 × 10 −31
kg maximum wavelength of the photon required to remove a
Charge on an electron = 1.6 × 10−19 C photoelectron from the metal is .... nm. (Nearest integer)
Planck’s constant = 6.63 × 10−34 Js [JEE MAIN 2021] [Given : h = 6.63 × 10−34 J s, and c = 3 × 108 m s−1 ] [JEE
MAIN 2022]
(177) The number of s-electrons present in an ion with 55 protons
in its unipositive state is [JEE MAIN 2023] (193) The number of incorrect statement /s about the black body
from the following is .........
(178) The ionization energy of sodium in kJmol−1 . If (A) Emit or absorb energy in the form of electromagnetic
electromagnetic radiation of wavelength 242 nm is just radiation
sufficient to ionize sodium atom is____. [JEE MAIN 2024] (B) Frequency distribution of the emitted radiation
10
depends on temperature
(C) At a given temperature, intensity vs frequency curve
passes through a maximum value
(D) The maximum of the intensity vs frequency curve is at a
higher frequency at higher temperature compared to that at
lower temperature [JEE MAIN 2023]
(194) The work function for a metal is 4 eV. To emit a photo
electron of zero velocity from the surface of the metal, the
o
wavelength of incident light should be : ................ A
(195) What is the maximum number of electrons which can be
accommodated in an atom in which the highest principal
quantum number value is 4
(196) The number of waves made by a Bohr electron in an orbit of
maximum magnetic quantum number 3 is
(197) The minimum uncertainty in the speed of an electron in an
one dimensional region of length 2ao
(Where a0 = Bohr radius 52.9pm ) is kms−1
(Given : Mass of electron = 9.1 × 10−31 kg, Planck’s constant
h = 6.63 × 10−34 Js ) [JEE MAIN 2022]
(198) Electromagnetic radiation of wavelength 663 nm is just
sufficient to ionise the atom of metal A. The ionization
energy of metal A in kJ mol−1 is ...... .
(Rounded-off
[ to the nearest integer)
h = 6.63 × 10−34 Js, c =] 3.00 × 108 ms−1 ,
NA = 6.02 × 1023 mol−1 [JEE MAIN 2021]
(199) For hydrogen atom, energy of an electron in first excited
state is −3.4eV, KE. of the same electron of hydrogen atom
is xeV. Value of x is. . . . . . .×10−1 eV. (Nearest integer) [JEE
MAIN 2024]
(200) What is the maximum numbers of electrons that can be

associated with the following set of quantum numbers?
n = 3, l = 1 and m = −1 [NEET 2013]
11
Vedclass
Hy hu Date : 17-11-2024
Standard : 11
Total Mark : 800 (Answer Key) Time : 0H:0M
Chemistry - Section A (MCQ)
1-B 2-B 3-A 4-B 5-D 6-C 7-B 8-B 9-D 10 - A

11 - B 12 - C 13 - B 14 - C 15 - B 16 - D 17 - B 18 - B 19 - C 20 - A
21 - C 22 - A 23 - B 24 - B 25 - B 26 - D 27 - D 28 - C 29 - D 30 - A
31 - D 32 - B 33 - B 34 - C 35 - C 36 - D 37 - D 38 - A 39 - D 40 - C
41 - D 42 - C 43 - C 44 - B 45 - C 46 - A 47 - A 48 - C 49 - A 50 - B
51 - D 52 - B 53 - D 54 - B 55 - B 56 - B 57 - B 58 - B 59 - C 60 - B
61 - D 62 - B 63 - D 64 - C 65 - D 66 - D 67 - B 68 - A 69 - C 70 - B
71 - D 72 - C 73 - D 74 - B 75 - C 76 - A 77 - D 78 - A 79 - D 80 - B
81 - D 82 - A 83 - B 84 - C 85 - A 86 - C 87 - C 88 - C 89 - A 90 - D
91 - D 92 - C 93 - D 94 - D 95 - D 96 - C 97 - C 98 - B 99 - A 100 - A
101 - A 102 - B 103 - D 104 - A 105 - D 106 - B 107 - C 108 - D 109 - D 110 - D
111 - B 112 - D 113 - C 114 - D 115 - D 116 - A 117 - B 118 - D 119 - A 120 - A
121 - B 122 - C 123 - A 124 - C 125 - D 126 - D 127 - C 128 - B 129 - A 130 - C
131 - B 132 - A 133 - A 134 - C 135 - B 136 - A 137 - D 138 - A 139 - B 140 - A
141 - D 142 - C 143 - B 144 - D 145 - A 146 - D 147 - A 148 - B 149 - D 150 - A
Chemistry - Section B (NUMERIC)
151 - 30 152 - 16 153 - 3 154 - 9 155 - 3155 156 - 8 157 - 9 158 - 2 159 - 270 160 - 2
161 - 8 162 - 30 163 - 4 164 - 759 165 - 3 166 - 5 167 - 4 168 - 16 169 - 738720 170 - 2
171 - 21 172 - 10 173 - 25 174 - 3 175 - 4 176 - 6 177 - 10 178 - 494 179 - 7 180 - 9
181 - 2 182 - 3 183 - 658 184 - 32 185 - 32 186 - 58 187 - 2 188 - 14 189 - 32 190 - 2
191 - 2 192 - 300 193 - 0 194 - 3100 195 - 32 196 - 4 197 - 548 198 - 180 199 - 34 200 - 2
12
Vedclass
Hy hu Date : 17-11-2024
Standard : 11
Total Mark : 800 (Solutions) Time : 0H:0M
Solution:(Correct Answer:D)
............ Chemistry - Section A (MCQ) ............ o
(d) rH = 0.529 nz A
2
(1) In an atom, an electron is moving with a speed of 600 m/s For hydrogen ; n = 1 and z = 1 therefore
o
with an accuracy of 0.005%. Certainity with which the rH = 0.529 A
position of the electron can be located is For Be3+ : Z = 4 and n = 2 Therefore
(h = 6.6 × 10−34 kg m2 s−1 , mass of electron,
o
= 0.529 A.
2
rBe3+ = 0.529×2
4
em = 9.1 × 10−31 kg) : [AIEEE 2009]
(A) 5.10 × 10−3 m (B) 1.92 × 10−3 m (6) Quantum No. l = 2 and m = 0 represent which orbital :
(C) 3.84 × 10−3 m (D) 1.52 × 10−4 m (A) dxy (B) d2x − y 2
(C) d2z (D) dzx
Solution:(Correct Answer:B)
% error in velocity = ∆VV × 100 Solution:(Correct Answer:C)
∴ 0.005 = ∆V600 × 100 Quantum numbers 1 = 2 and m = 0 represent dz2 orbital.
⇒ ∆v = 3 × 10−2 Note: For s, p, d and f orbitals, the value of the azmithual
According to Heisenberg uncertainty principle, quantum number ′ l′ is 0, 1, 2, 3
∆x · m∆V ≥ 4π h
When l = 2, m can have values −2, −1, 0, +1, +2.
⇒ ∆x = 4πm∆V h
A d-subshell can have five different orientations and orbitals
6.63×10−34
⇒ ∆x = 4×3.14×9.1×10 −31 ×3×10−2 corresponding to these orientations are
= 1.92 × 10−3 m dxy , dxz , dyz , dx2 −y2 dz2
(2) Number of spectral lines obtained in He+ spectra, when an (7) The radius of electron in the first excited state of hydrogen
electron makes transition from fifth excited state to first atom is
excited state will be [JEE MAIN 2024] (A) a0 (B) 4a0
(A) 11 (B) 10 (C) 2a0 (D) 8a0
(C) 12 (D) 13
Solution:(Correct Answer:B) (b) r ∝ n2 (excited state n = 2)
5th excited state ⇒ n1 = 6 r = 4a0
1st excited state ⇒ n2 = 2
∆n = n1 − n2 = 6 − 2 = 4 (8) In Bohr’s model of atom when an electron jumps from n = 1
Maximum number of spectral lines to n = 3, how much energy will be absorbed
= ∆n(∆n+1)
2 = 4(4+1)
2 = 10 (A) 2.15 × 10−10 ergs (B) 0.1911 × 10−10 ergs
(3) Number of orbitats in h sub-shell is (C) 2.389 × 10−10 ergs (D) 0.239 × 10−10 ergs
(A) 11 (B) 15
(C) 17 (D) 19 Energy of an atom when n = 1
−1
(1)2 = −1312kJmol
E1 = − 1312
Solution:(Correct Answer:A)
Similarly energy when n = 3, (E3 )
(a) s p d f g h
= − 1312
l=012345 (3)2
Number of orbitals = 5 × 2 + 1 = 11 = −145.7kJmol−1

The energy absorbed when an electron jumps from n = 1 to
(4) Which set of quantum numbers is not possible for last n=3
electron of ′ Al′ (Z = 13) : − value of n, l, m, s respectively E3 − E1 = −145.7 − (−1312) = 1166.3kJmol−1
(A) 3, 1, −1, −1 (B) 3, 0, 0, +1
1166.3
= 6.023×10 23 = 193.6 × 10
−23
kJ
]
= 193.6 × 10 J [1 Joule = 107 ergs
−20
2 2
(C) 3, 1, 0, +1
2 (D) 3, 1, 1, −1
2 ⇒ 193.6 × 10−13 ergs = 0.1936 × 10−10 ergs
(9) The orbital angular momentum of 3p electron is
√ √
(5) The radius of which of the following orbit is same as that of (A) 3h (B) 6h
√ h
the first Bohr’s orbit of hydrogen atom [IIT 2004] (C) zero (D) 3 2π
(A) He+ (n = 2) (B) Li2+ (n = 2)
(C) Li2+ (n = 3) (D) Be3+ (n = 2)
13
(10) The mass of the proton is 1840 times that of electron. If a Solution:(Correct Answer:C)
proton is accelerated through a potential difference of V (c) Formula for de-Broglie wavelength is √
volts, the kinetic energy of the proton would be
λ= h
or λ = h
⇒ eV = 12 mv 2 or ν = 2eV
(A) 1 eV (B) 1 keV
p mv m
−34
h 6.62×10
λ = √2meV = √2×9.1×10 −31 ×2.8×10−23
(C) 1840 eV (D) 1849 keV
λ = 9.28 × 10−8 meter.
We know that: (15) Two radiations having energies E1 and E2 as 15 eV and
Kinetic energy = Relative charge × accelerating potential 45 eV respectively then the relationship in between λ1 and
K.E. = 1e × 1 kV λ2 will be
K.E. = 1 keV (A) λ1 = λ2 (B) λ1 = 3λ2
(11) The orbital angular momentum of an electron in 2s orbitals is (C) λ1 = λ2 /3 (D) λ1 = 9λ2
(A) + 12 . 2h∏ (B) 0 Solution:(Correct Answer:B)
√ E1 = 15 eV ⇒ λhc1 = 15 eV.........(i)
(C) 2h∏ (D) 2. 2h∏
E2 = 45 eV ⇒ λhc2 = 45 eV.........(ii)
Solution:(Correct Answer:B) λ2 1
λ1 = 3
The orbital angular momentum of an electron in the 2s−
λ1 = 3λ2
orbital is zero. For a given subshell with azimuthal quantum
number l, the orbital angular momentum is given by the (16) Normally, the time taken in the transition is :
expression
√ (A) Zero (B) 1
h
L = 2π 1(1 + 1)
√
For 2s orbital, 1 = 0 so L = 2πh
0(0 + 1) = 0 (C) 10−5 sec (D) 10−8 sec
(12) The quantum number ′ m′ of a free gaseous atom is Solution:(Correct Answer:D)

associated with [AIIMS 2003]
(17) CO has same electrons as or the ion that is isoelectronic
(A) The effective volume of the orbital with CO is [IIT 1982 , AIPMT 1997]
(B) The shape of the orbital (A) N2+ (B) CN −
(C) The spatial orientation of the orbital (C) O2+ (D) O2−
(D) The energy of the orbital in the absence of a magnetic Solution:(Correct Answer:B)
field (b) CO and CN − are isoelectronic.
Solution:(Correct Answer:C) CO = 6 + 8 = 14 and CN − = 6 + 7 + 1 = 14.
The magnetic quantum number (m), to describe the
(18) What is the maximum wavelength in the Lyman series of
orientation in space of a particular orbital. It is called the
He+ ion ?
magnetic quantum number because the effect of different
(A) 3R (B) 3R
1
orientations of orbitals was first observed in the presence of
a magnetic field. The magnetic quantum number (m) (C) 1
R (D) 2R
determines the number of orbitals and their orientation
within a subshell. Consequently, its value depends on the ( ) ( )
orbital angular momentum quantum number l. λ = R.Z − n12 = R × 4 11 − 14
1 2 1
n2
Given a certain l, m is an interval ranging from −l to +l, so it
1 2
1
= 3R and λ= 1
can be zero, a negative integer, or a positive integer.
λ 3R
(19) The nitride ion in lithium nitride is composed of [AIPMT 2001]

(13) Given
(A) 7P + 7e (B) 10P + 7e
(A) n = 5, ml = +1
(B) n = 2, l = 1, ml = −1, ms = −1/2 (C) 7P + 10e (D) 10P + 10e
The maximum number of electron(s) in an atom that can
Solution:(Correct Answer:C)
have the quantum numbers as given in (A) and (B) are
respectively [JEE MAIN 2013] Lithium nitride is Li3 N . Here, nitride ion is N with −3
charge. Since atomic no. of nitrogen is 7 .
(A) 25 and 1 (B) 8 and 1
So, the number of protons is 7 and number of electrons will
(C) 2 and 4 (D) 4 and 1 be 7 + 3 = 10.
(i) n = 5 means l = 0, 1, 2, 3, 4 Statement-I: The orbitals having same energy are called as
since m = +1 degenerate orbitals.
hence total no. of electrons will be = 0 (from s) +2 (from p) Statement-II: In hydrogen atom, 3p and 3 d orbitals are not
+2 (fron d) +2 (from f ) +2 (from g) degenerate orbitals.
=0+2+2+2+2=8 In the light of the above statements, choose the most
(ii) n = 2, l = 1, ml = −1, ms = −1/2 represent 2p orbital appropriate answer from the options given [JEE MAIN 2024]
with one electron
(A) Statement-I is true but Statement-II is false
(14) An electron has kinetic energy 2.8 × 10−23 J. de-Broglie
(B) Both Statement-I and Statement-II are true.
wavelength will be nearly(me = 9.1 × 10−31 kg)
(A) 9.28 × 10−4 m (B) 9.28 × 10−7 m (C) Both Statement-I and Statement-II are false
(C) 9.28 × 10−8 m (D) 9.28 × 10−10 m (D) Statement-I is false but Statement-II is true
14
Solution:(Correct Answer:A) (26) Which of the following is not isoelectronic
For single electron species the energy depends upon (A) N a+ (B) M g 2+
principal quantum number ’ n ’ only. So, statement II is
(C) O2− (D) Cl−
false.
Statement I is correct definition of degenerate orbitals.
(21) In which of the following transition photon of maximum

energy is absorbed Solution:(Correct Answer:D)
(A) 1 to 2 (B) 2 to 3 (d) N a+ = 1s2 2s2 2p6
M g + + = 1s2 2s2 2p6
(C) 1 to ∞ (D) ∞ to 1 O2− = 1s2 2s2 2p6
Cl− = 1s2 2s2 2p6 3s2 3p6
1 to 2 ⇒ 10.2 ev
1 to ∞ ⇒ 13.6 ev maxm energy absorbed
2 to 3 ⇒ 1.89 ev
∞ to 1 ⇒ energy release. (27) The maximum wavelength of radiation that can ionise a
o
sodium atom is 2414 A . The ionisation energy of sodium per
(22) The quantum number which specifies the location of an mole shall be
electron as well as energy is (A) 241.4 J mol−1 (B) 497.7 J mol−1
(A) Principal quantum number (C) 241.4 k J mol−1 (D) 497.7 k J mol−1
(B) Azimuthal quantum number
(C) Spin quantum number
(D) Magnetic quantum number Solution:(Correct Answer:D)
It’s Obvious
(28) Which of the following sets of quantum numbers is not
possible ?
(23) The electrons identified by quantum numbers n and l :
(A) n = 4, l = 1, m = 0, s = +1/2
(A) n = 4, l = 1 (B) n = 4, l = 0
(C) n = 3, l = 2 (D) n = 3, l = 1 (B) n = 4, l = 3, m = −3, s = −1/2
can be placed in order of increasing energy as : [AIEEE 2012]
(C) n = 4, l = −1, m = +2, s = −1/2
(A) (C) < (D) < (B) < (A) (B) (D) < (B) < (C) < (A)
(D) n = 4, l = 1, m = 0, s = −1/2
(C) (B) < (D) < (A) < (C) (D) (A) < (C) < (B) < (D)
(a)n = 4, l = 1(p − subshell ), so 4p
(b) = 4, l = 0 ( s− subshell), so 4s Solution:(Correct Answer:C)
(c)n = 3, l = 2(d -subshell), so 3d
(d)n = 3, l = 1 ( p− subshell), so 3p
Accroding to the Bohr (n + l) rule, Enery order of the
subshell : 3p < 4s < 3d < 4p (29) The energy of an electron in the 3rd orbit of a hydrogenic
atom is −E. The energy of an electron in the first orbit will
(24) Which electron is associated with the least energy be
(A) n = 3, l = 2, m = −2, s = + 12 (A) − 3E (B) − E/3
(B) n = 4, l = 0, m = 0, s = + 21 (C) − E/9 (D) − 9E
(C) n = 4, l = 1, m = +1, s = + 12
(D) n = 5, l = 0, m = 0, s = + 21
Solution:(Correct Answer:B) According to Bohr’s theory, energy of electron in nth orbit is
inversely proportional to square of n2 . e.g. E ∝ n12
(25) According to Bohr’s theory, the angular momentum of an given, energy of electron in 3 rd orbit, E3 = −E − −(1) Let
electron in 5th orbit is [AIEEE 2006] energy in 1 st orbit is E1 Then, E1 /E3 = (3)2 /(1)2 = 9
(A) 10 h/π (B) 2.5 h/π E1 = 9E3
from equation (1), E1 = −9E
(C) 25 h/π (D) 1.0 h/π
Hence, option (d) is correct
Formula of angular momentum of an electron,
mvr = nh
2π
here n = 5 (30) Which of the following plots of radial probability function
∴ mvr = 2π5h
= 2.5 πh 4πr2 Ψ2r is incorrectly labelled
15
(A) (33) What is the maximum wavelength line in the Lyman series
of He+ ion ?
(A) 3R (B) 1/3R
(C) 4/4R (D) None of these
For He+ , Z = 2 [ ]
Wave number, v̄ = λ1 = RZ 2 n12 − n12
1 2
For Lyman series, n1 = 1 and for maximum wavelength, n2
(B) has to be the smallest possible energy level.
∴ n2 = 2
Therefore, [ ]
λmax = 4R 1 − 4
1 1 1
⇒ λmax = 3R 1
(34) The electron in the nth orbit of Li2+ is excited to (n + 1)

orbit using the radiation of energy 1.47 × 10−17 J (as shown
in the diagram). The value of n is .....Given
(C) RH = 2.18 × 10−18 J [JEE MAIN 2023]
(A) 2 (B) 3
(C) 1 (D) 4
(D)
( )
∆E = RH Z 2 n12 − n12
1 2 ( )
1.47 × 10−17 = 2.18 × 10−15 × 9 1
n2 − 1
(n+1)2
1.47
1.96= 34 = 1
n2 − 1
(n+1)2
So, n = 1
(35) One energy difference between the states n = 2 and n = 3

is E eV in hydrogen atom. The ionization potential of H
Solution:(Correct Answer:A) atom is ........... E
(A) 3.2 (B) 5.6
(31) For the energy levels in an atom which one of the following
statements is correct ? (C) 7.2 (D) 13.2
(A) the 4s sub-energy level is at a higher energy that the 3d Solution:(Correct Answer:C)
sub-energy level E3 − E2 = E(eV ) or −E E1
9 + 4 =E
1
(B) The 5th main energy level can have maximum of 50 ∴ E1 = 5 = 7.2 E
36E
electrons
(36) The maximum number of electrons that can be
(C) The second principal energy level can have four orbitals accommodated in ′ f ′ sub shell is
and contain a maximum of 8 electrons
(A) 2 (B) 8
(D) Both (b) and (c)
(C) 32 (D) 14
Solution:(Correct Answer:D) Solution:(Correct Answer:D)
(d) Maximum no. of electrons in a subshell = 2(2l + 1) for
(32) The shortest wavelength of hydrogen atom in Lyman series f − subshell, l = 3 so 14 electrons accommodated in f −
is λ. The longest wavelength in Balmer series of He+ is [JEE subshell.
MAIN 2023]
(A) 5
9λ (B) 9λ
5
(37) Pick out the isoelectronic structures from the following
CH3+ H3 O+ N H3 CH3− [IIT 1993]
(C) 36λ
5 (D) 5λ
9 I II III IV
(A) I and II (B) I and IV
( )
For H : λ1 = RH × 1(2 112 −) ∞12 (C) I and III (D) II, III and IV
λ + = RH × 2 × 4 − 9
1 2 1 1
He Solution:(Correct Answer:D)
From (1) and (2)
λHe+
(d) CH3+ = 6 + 3 − 1 = 8e− ,
9
λ = 5
λHe+ = λ × 95 H3 O+ = 3 + 8 − 1 = 10e− ,
λHe+ = 9λ5 N H3 = 7 + 3 = 10e− , CH3− = 6 + 3 + 1 = 10e−
16
(38) The nitride ion in lithium nitride is composed of Solution:(Correct Answer:C)
(A) 7 protons +10 electrons (c) From de Broglie equation
−34
λ = mvh
= 6.62×10
0.5×100 = 1.32 × 10
−35
m.
(B) 10 protons +10 electrons
(C) 7 protons +7 protons (44) Match the columns and choose correct option
Column −I Column −II
(D) 10 protons +7 electrons
(a) 4s (p) Circular orbit
Solution:(Correct Answer:A) around nucleus
(a) In case of N 3− , p = 7 and e− = 10 (b) 4p (q) Non directional or-
bital
(39) Assertion : Absorption spectrum consists of some bright
(c) 1s (r) Angular momentum
lines separated by dark spaces. = 2h/π
Reason : Emission spectrum consists of dark lines. [AIIMS 2002]
(d) 3d (s) Radial node is zero
(A) If both Assertion and Reason are correct and the Reason
is a correct explanation of the Assertion. (A) a − p, b − q, c − r, d − s (B) a − q, b − r, c − p, d − s
(B) If both Assertion and Reason are correct but Reason is (C) a − s, b − r, c − q, d − p (D) a − p, b − r, c − s, d − q
not a correct explanation of the Assertion.
(C) If the Assertion is correct but Reason is incorrect.
(45) The maximum number of electrons that can have principal
(D) If both the Assertion and Reason are incorrect.
quantum number, n = 3, and spin quantum number,
ms = −1/2, is [IIT 2011]
(A) 2 (B) 7
Absorption spectrum consists of dark lines separated by
bright space and emission spectrum consists of bright lines. (C) 9 (D) 5
(40) Be′ s 4th electron will have four quantum numbers
nlms For a shell with principal quantum number ’ n ’, maximum
(A) 1 0 0 +1/2 (B) 1 1 +1 +1/2 number of electrons that can occupy the shell = 2n2
For n = 3, maximum number of electrons = 2 × 32 = 18
(C) 2 0 0 −1/2 (D) 2 1 0 +1/2 Half of them will have ms = − 12 and the other half will have
m5 = + 12 .
Solution:(Correct Answer:C) ∴ Maximum number of electrons with ms = − 21 and n = 3
Electronic config for Be is 1s2 2s2 . Fourth electron is in s is 18
2 or 9 .
orbital so n = 2, l = 0, m = 0 and s = −1/2
(46) The energy of an electron in the first Bohr orbit of Hatom is
(41) The energy required to break one mole of Cl − Cl bonds in −13.6 eV . The possible energy value (s) of the excited state
Cl2 is 242 kJ mol−1 . The longest wavelength of light (s) for electrons in Bohr orbits to hydrogen is(are) ............. eV
capable of breaking a single Cl − Cl bond is ............ nm [IIT 1998]
(C = 3 × 108 ms−1 and NA = 6.02 × mol−1 ). [AIEEE 2010] (A) −3.4 (B) −4.2
(A) 594 (B) 640 (C) −6.8 (D) +6.8
(C) 700 (D) 494 Solution:(Correct Answer:A)
Solution:(Correct Answer:D) (a) Values of energy in the excited state = − 13.6
n2 eV
= −13.6 = −3.4 eV
Energy required to break one Cl2 molecule = 242×103
J 4
6.02×1023 in which n = 2, 3, 4 etc.
As E = hc
λ
So λ = hc
E
(47) How many electrons can fit in the orbital for which n = 3
−34
×3×108 ×6.02×1023
= 6.626×10 242×10 3
and l = 1 ? [NEET 2016]
= 494 × 10−9 m (A) 6 (B) 2
= 494 nm (C) 10 (D) 14
(42) Which of the following sets of quantum numbers represent Solution:(Correct Answer:A)
an impossible arrangement For n = 3 and l = 1, the subshell is 3p and a particular 3p
n l m ms [IIT 1986] orbital can accommodate only 6 electrons.
(A) 3 2 −2 (+) 12 (B) 4 0 0 (−) 12
(48) The kinetic energy of an electron in the second Bohr orbit of
(C) 3 2 −3 (+) 12 (D) 5 3 0 (−) 1
2 a hydrogen atom is [ a0 is Bohr radius]: [IIT 2012]
(A) 4π2hma2 (B) 16πh2 ma2
2 2
Solution:(Correct Answer:C) 0 0
(c) If l = 2, m ̸= −3.= (−m to +m). (C) h2

(D) h2
32π 2 ma20 64π 2 ma20
(43) A cricket ball of 0.5 kg is moving with a velocity of Solution:(Correct Answer:C)

100 m/ sec. The wavelength associated with its motion is mv (4a0 ) = πh
(A) 1/100 cm (B) 6.6 × 10−34 m so, v = 4mπa
h
0
so KE = 21 mv 2 = 12 m · h2
= h2
(C) 1.32 × 10−35 m (D) 6.6 × 10−28 m 16m2 π 2 a20 32mπ 2 a20
17
(49) The value of Planck’s constant is 6.63 × 10−34 J s. The speed Solution:(Correct Answer:B)
of light is 3 × 1017 nm s−1 . Which value is closest to the (i) 4 p (ii) 4 s
wavelength in nanometer of a quantum of light with (iii) 3 d (iv) 3 p
frequency of 6 × 1018 s−1 ? [NEET 2013] According to Bohr Bury’s (n + l) rule, increasing order of
(A) 50 (B) 75 energy will be (iv) < (ii) < (iii) < (i).
Note : If the two orbitals have same value of (n + l) then
(C) 10 (D) 25
the orbital with lower value of n will be filled first.
λ= C
= 3×1017 nms−1
= 50nm (55) The ionization energy of hydrogen atom is −13.6 eV. The
6×1013 s−1
energy required to excite the electron in a hydrogen atom
V
(50) A surface ejects electrons when hitted by green light but from the ground state to the first excited state is
not. When hitted by yellow light. Will electrons be ejected if (Avogadro’s constant = 6.022 × 1023 )
the surface is hitted by red light : (A) 1.69 × 10−20 J (B) 1.69 × 10−23 J
(A) Yes
(C) 1.69 × 1023 J (D) 1.69 × 1025 J
(B) No
(C) Yes, if the red beam is quite intense (b) E = −13.6 −13.6
= −3.4 eV
n2 = 4
(D) Yes, if the red beam continues to fall upon the surface We know that energy required for excitation
for a long time ∆E = E2 − E1 = −3.4 − (−13.6) = 10.2 eV
Therefore energy required for excitation of electron per
Solution:(Correct Answer:B) atom = 6.02×10
10.2
23 = 1.69 × 10
−23
J
Energy of red light < Energy of yellow light
∴ Energy of yellow light is less then threshold energy, it (56) If the radius of the 3rd Bohr’s orbit of hydrogen atom is r3
implied energy of red light is less then threshold energy. and the radius of 4th Bohr’s orbit is r4 . Then .... [JEE MAIN 2022]
(A) r4 = 169
r3 (B) r4 = 16 9 r3
(51) What will be the ratio of wavelength of third line of Balmer
series in He⊕ ion spectrum to the first line of balmer series (C) r4 = 43 r3 (D) r4 = 43 r3
in Li+2 ion spectrum
(A) 5 : 3 (B) 125 : 189 2
r = 0.529 × nZ
(C) 27 : 20 (D) 125 : 84 2
r3 = 0.529 × 31
Solution:(Correct Answer:D) r4 = 0.529 × 41
2
( )
v̄ = λ1 = RZ 2 n12 − n12
2
r4 4 16
1 2 r3 = 3 2 = 9
v̄(He+ ) R·4( 14 − 25
1
) 21
84 r4 = 16r 3
v̄ = R·9( 14 − 19 )
= 25
5 = 125
9
(L−2
1 )
4
λ(He+ ) (57) A 124 W bulb converts only 15 % of the energy supplied to

∴ = 125
λ(L+2 ) 84 it into visible light of wavelength 640 nm . How many
photons are emitted by the light bulb in one second
(52) The energies E1 and E2 of two radiations are 25 eV and
(A) 4 × 1019 (B) 6 × 1019
50 eV respectively. The relation between their wavelengths
i.e., λ1 and λ2 will be (C) 8 × 1018 (D) 3 × 1019 photon
(A) λ1 = λ2 (B) λ1 = 2λ2
(C) λ1 = 4λ2 (D) λ1 = 1/2λ2 124×0.15
−19
640 ×1.6×10
1240
Solution:(Correct Answer:B) 124×16 × 10

= 124×640 19
× 0.15
Given the value of E1 = 25eV and E2 = 50eV = 6 × 10 19
E1 = λhc1 , E2 = λhc2
By divide E1 and E2 (58) Which of the following oxides of nitrogen is isoelectronic
⇒ 50
25
= λλ21 with CO2 [AIPMT 1990]
λ1 = 2λ2 (A) N O2 (B) N2 O
(53) If the ionization energy of He+ is 8.68 × 10−18 J , then the (C) N O (D) N2 O2
energy of Be+3 ion in the second orbit is:- ( Z of Be = 4)
(A) −4.9 × 10−18 J (B) −44.1 × 10−18 J
(b) N2 O = 14 + 8 = 22
(C) −11.025 × 10−18 J (D) −8.68 × 10−18 J CO2 = 6 + 16 = 22.
(59) In potassium atom, electronic energy level is in the
(54) The following sets of quantum numbers represent four following order
electrons in an atom (A) 4s > 3d (B) 4s < 2p
(i) n = 4, l = 1 (ii) n = 4, l = 0 (C) 4s < 3d (D) 4s > 4p
(iii) n = 3, l = 2 (iv) n = 3, l = 1
The sequence representing increasing order of energy, is Solution:(Correct Answer:C)
[AIEEE 2012] The ′ 4s′ orbital is having lower energy than ′ 3d′ orbital
(A) (iii) < (i) < (iv) < (ii) (B) (iv) < (ii) < (iii) < (i) The (n + 1) Value of ′ 4s′ orbital is lower than that of ′ 3d′
(C) (i) < (iii) < (ii) < (iv) (D) (ii) < (iv) < (i) < (iii) orbital.
18
(60) The electrons are more likely to be found [JEE MAIN 2019] Solution:(Correct Answer:D)
(66) The orientation of an atomic orbital is governed by [AIPMT 2006]

(A) principal quantum number
(B) azimuthal quantum number
(C) spin quantum number
(D) magnetic quantum number.
(A) in the region a and b (B) in the region a and c
(C) only in the region a (D) only in the region c Magnetic orbital quantum number
Solution:(Correct Answer:B) It is denoted by ml .
At a & c, probability of finding electron is maximum It gives information about the spatial orientation of the
orbital with respect to the standard set of co-ordinate axis.
The explanation for the incorrect option
Azimuthal quantum numbers tell about the shape of the
orbital.
The spin quantum number denotes the orientation of the
spin of the electron.
The principal quantum number determines the size and to
large extent the energy of the orbital.
So, options (A), (B) and (D) are incorrect.
(61) Choose the pair whose ions have the similar electronic Hence, option (C) is correct. The orientation of an atomic
configuration orbital is governed by magnetic quantum numbers.
(A) Lithium and sodium (B) Potassium and calcium
(67) An atom emits energy equal to 4 × 10−12 erg. To which part
(C) Sodium and potassium (D) Both (a) and (c)
of electromagnetic spectrum it belongs :
Solution:(Correct Answer:D) (A) U V region (B) Visible region
(62) Ratio of time period of electron in first and third orbit of H− (C) IR region (D) Microwave region
atom would be
(A) 1 : 18 (B) 1 : 27 Solution:(Correct Answer:B)
The wavelength corresponding to energy 4 × 10−12 ergs is
(C) 1 : 2 (D) 27 : 1 hC −34
×3×108
λ = ∆E = 6.62×10
4×10−12 ×10−7
Solution:(Correct Answer:B) = 4.965 × 10−7 m = 4965 Å . . .
T ∝ n3 Visible region extends from 3800 Å . . . − 7600 Å . . .
(63) Assertion : An orbital designated by n = 3, l = 1 has double
dumb-bell shape. (68) Given : The mass of electron is 9.1 × 10−31 Kg Planck
Reason : It belongs to p− subshell. [AIIMS 2011] constant is 6.62 × 10−34 Js , the uncertainty involved in the
o
(A) If both Assertion and Reason are correct and the Reason measurement of velocity within a distance of 0.1 A is
is a correct explanation of the Assertion. (A) 5.79 × 106 ms−1 (B) 5.79 × 107 ms−1
(B) If both Assertion and Reason are correct but Reason is (C) 5.79 × 108 ms−1 (D) 5.79 × 105 ms−1
not a correct explanation of the Assertion.
(C) If the Assertion is correct but Reason is incorrect. h
∆x · m∆v = 4π
(D) If both the Assertion and Reason are incorrect. h
⇒ ∆v = 4mπ∆x = 4×9.1×10−316.63×10−34
×3.14×(0.1×10−10 )
Solution:(Correct Answer:D) ⇒ ∆v = 4×9.1×3.14
6.63
× 108 ms−1
The orbital has dumb-bell shape and belongs to p− subshell. ⇒ ∆v = 5.79 × 106 ms−1
(64) The ratio of the radius of the first three Bohr orbits is (69) Number of protons, neutrons and electrons in the element
(A) 1 : 12 : 13 (B) 1 : 2 : 3 89 Y is
231
(C) 1 : 4 : 9 (D) 1 : 8 : 27 (A) 89, 231, 89 (B) 89, 89, 242

Solution:(Correct Answer:C) (C) 89, 142, 89 (D) 89, 71, 89
th
Radius of n Bohr orbit, rn =
2
0.529 nZ
Å
=⇒ rn ∝ n2 Solution:(Correct Answer:C)
Thus ratio of first three Bohr orbit is r1 : r2 : r3 = 12 : 22 : 32 (c) In Xe231
89 number of protons and electrons is 89 and No.
=⇒ r1 : r2 : r3 = 1 : 4 : 9 of neutrons = A − Z = 231 − 89 = 142.
(65) The difference in wavelength of first and second spectral (70) What is the potential energy of the electron in the L− shell
o
lines of lyman series in Li+2 ion spectrum is ................ A of the hydrogen atom? .............. eV
(A) 190 (B) 182.1 (A) −13.6 (B) −6.8
(C) 27 (D) 21.1 (C) −10.2 (D) −3.4
19
Solution:(Correct Answer:B) Solution:(Correct Answer:C)
The principal quantum number for L-shell is 2 we know that Isotones have same number of neutrons.
energy of an electron in nth bohr’s orbit is given by, 32 Ge n = 76 − 32 = 44
76
En = − 13.6eV
n2 (i) 32 Ge77 n = 77 − 32 = 45
but Potential energy of electron = −2 (En ) = − 27.2eV
n2
(iii) 33 As77 n = 77 − 33 = 44
Therefore, for n = 2 (iii) 34 Se77 n = 77 − 34 = 43
P.E. = − 27.2eV
4 = −6.8eV (iv) 34 Se78 n = 78 − 34 = 44
(71) The frequency of a certain line of lyman series of atomic

(76) Which one of the following is not the characteristic of
spectrum of H atom satisfy the following condition
Planck’s quantum theory of radiation [AIIMS 1991]
(i) It is the sum of frequency of another lyman line and
balmer line. (A) The energy is not absorbed or emitted in whole number
(ii) It is the sum of frequency of a certain line, lyman line or multiple of quantum
and a paschen line (B) Radiation is associated with energy
(iii) It is the sum of frequency of a lyman and a paschen line
but no bracket line (C) Radiation energy is not emitted or absorbed conti-
To what transition does this frequency correspond? nuously but in the form of small packets called quanta
(A) n2 = 3 to n1 = 1 (B) n2 = 3 to n1 = 2 (D) This magnitude of energy associated with a quantum is
proportional to the frequency
(C) n2 = 2 to n1 = 1 (D) n2 = 4 to n1 = 1
Solution:(Correct Answer:D) Solution:(Correct Answer:A)
(a) Energy is always absorbed or emitted in whole number
(72) In a potassium atom, electronic energy levels are in the
or multiples of quantum.
following order
(A) 4s > 3d (B) 4s > 4p
(77) What accelerating potential must be imparted to a proton
(C) 4s < 3d (D) 4s < 3p o
beam to give it an effective λ = 0.05 A .
Solution:(Correct Answer:C) (V = 33 volt) (mp = 1.672 × 10−27 kg)
(c) According to Aufbau’s principle. (A) 4.95 × 106 V (B) 4.95 × 105 V
(73) Values of the four quantum numbers for the last electron in (C) 2.475 × 106 V (D) 2.475 × 105 V
the atom are n = 4, l = 1, m = +1 and s = −1/2. Atomic
number of the atom will be Solution:(Correct Answer:D)
(A) 22 (B) 32
(C) 31 (D) 36 (78) What will be the mass of a particle if uncertainty in its
position is 10−8 m and uncertainty in velocity is
Solution:(Correct Answer:D) 5.26 × 10−25 m s−1 ? ............... kg
(d) Atomic number is 36 and element is Kr. (A) 0.01 (B) 100
(74) Energy levels A, B, C of a certain atom corresponds to (C) 1 (D) 10
increasing values of energy, i.e., EA < EB < EC . If λ1 , λ2
and λ3 are the wavelength of radiations corresponding to Solution:(Correct Answer:A)
the transitions C to B, B to A and C to A respectively, ∆x.m∆v = 4π h
which of the following statement is correct : h
m = 4π∆x∆v
6.62×10−34
= 4×3.14×10 −8 ×5.28×10−25
= 0.099 × 10−1
= 0.01 kg
o
(79) What is the radius of Bohr’s fifth orbit for B +4 . .................. A
(A) λ3 = λ1 + λ2 (B) λ3 = λ1 λ2
(A) 4.645 (B) 1.645
λ1 +λ2
(C) λ1 + λ2 + λ3 = 0 (D) λ23 = λ21 + λ22

(C) 3.645 (D) 2.645
As we know, Solution:(Correct Answer:D)
E = hv = hc λ
E3 − E1 = (E3 − E2 ) + (E2 − E1 )
hc hc hc (80) Two electrons occupying the same orbital are distinguished
λ3 = λ1 + λ2 by [NEET 2016]
1 1 1
λ3 = λ1 + λ2 (A) azimuthal quantum number
λ3 = λλ11+λ
λ2
(B) spin quantum number

2
(75) An isotone of 32 Ge is
76
(C) principal quantum number
(i) 32 Ge77 (ii) 33 As77
(iii) 34 Se77 (iv) 34 Se78 (D) magnetic quantum number
(A) Only (i) and (ii) (B) Only (ii) and (iii)
(C) Only (ii) and (iv) (D) (ii), (iii) and (iv)
20
(81) If the shortest wavelength in Lyman series of hydrogen Solution:(Correct Answer:A)
atom is A, then the longest wavelength in Paschen series of (a) Energy of ground stage (E0 ) = −13.6 eV and energy
He+ is [JEE MAIN 2017] level = 5
(A) 5A9 (B) 9A
5 n2 eV = 52 = 25 = −0.54 eV .
E5 = −13.6 −13.6 −13.6
(C) 36A
(D) 36A
(86) The uncertainty in momentum of an electron is
5 7
Solution:(Correct Answer:D) 1 × 10−5 kg − m/s. The uncertainty in its position will be
For Lyman series (short wavelength) (h = 6.62 × 10−34 kg − m2 /s) [AIPMT 1999]
n1 = 1, n(2 = ∞ ) (A) 1.05 × 10−28 m (B) 1.05 × 10−26 m
1
λ = Rz
2 1
− n12
n21
( 2 ) (C) 5.27 × 10−30 m (D) 5.25 × 10−28 m
⇒ A1 = 12 R 11 − ∞ 1
⇒ A1 = R
Longest wavelength = 1st line Solution:(Correct Answer:C)
n1 = 3, n(2 = 4 )
(c) According to ∆x × ∆p = 4π h
32 − 42 ⇒ λ = 36
1 2 1 1 1 R7
λ = Rz −34
−30
−5 ×4×3.14 = 5.27 × 10
h 6.62×10
R= A 1 ∆x = ∆p×4π = 1×10 m.
A ×7
1
1
= ⇒ 1
= 7
⇒λ= 36 A
λ 36 λ 36 A 7
(87) Number of waves made by Bohr’s electron in one complete
(82) Find the % difference (approximate) in deBorglie revolution in 3rd orbit
wavelength if the temperature of gas become double ............. (A) 1 (B) 2
% (C) 3 (D) 4
(A) 30 (B) 40
(C) 50 (D) 100 Solution:(Correct Answer:C)
Solution:(Correct Answer:A) 2πr = nλ
λ= √ h = KE = 32 KT
2m(K.E.) (88) The frequency of an electromagnetic radiation is 2 × 106 Hz.
⇒λ ∝ √1T ⇒ λ2 = λ1
√
2 What is its wavelength in metres (Velocity of light
λ
√1 −λ1 = 3 × 108 ms−1 )
of charge = f −i
× 100 = 2
× 100
√1
−1
ℓ λ1
(A) 6.0 × 1014 (B) 1.5 × 104
= 2
× 100 = 30%
1 (C) 1.5 × 102 (D) 0.66 × 10−2
(83) Radius of the nucleus is equal to 10−12 cm. and that of the
atom is equal to 10−8 cm. What is the fraction of the volume Solution:(Correct Answer:C)
of the atom occupied by nucleus ? (c) When c = ν × λ than λ = c
ν = 3×108
2×106 = 1.5 × 102 m
(A) 1012 (B) 10−12
(C) 10−20 (D) 10−4 (89) The quantum numbers for the outermost electron of an
element are given below as n = 2, l = 0, m = 0, s = + 12 .
Solution:(Correct Answer:B) The atoms is
A nucleus is the positively charged center of the atom (A) Lithium (B) Beryllium
consisting of protons and neutrons. It’s also known as the
’atomic nucleus’. Nearly all the mass of an atom is contained (C) Hydrogen (D) Boron
within the nucleus, since protons and neutrons have much
more mass than electrons
according to qes. Volume of nucleus (a) The electronic configuration must be 1s2 2s1 . Hence, the
( )3 element is lithium (z = 3).
= 43 πr3 = 43 π 10−12 cm3
( )3
Volume of atom = 43 π 10−8 cm3
VN 10−36 (90) The total number of orbitals in an energy level designated
Vatom = 10−24 by principal quantum number n is equal to [AIIMS 1997]
VN −12
Vatom = 10 (A) 2n (B) 2n2
(84) Which set of quantum numbers are not possible from the (C) n (D) n2
following
(A) n = 3, l = 2, m = 0, s = − 12 Solution:(Correct Answer:D)
(d) No. of electrons= 2n2 hence no. of orbital = 2n2
= n2 .
(B) n = 3, l = 2, m = −2, s = − 12 2
(C) n = 3, l = 3, m = −3, s = − 12 (91) If the electron jumps from 7.00 eV energy level to 5.0 eV
(D) n = 3, l = 0, m = 0, s = − 12 energy level, it :
(A) Absorbs 2.0 eV kinetic energy
(c) If n = 3 then l = 0 to n − 1 & m = −l to +l (B) Absorbs 2.0 eV potential energy
(C) Emits 2.0 eV electrical energy
(85) The energy of electron in hydrogen atom in its grounds state
is −13.6 eV . The energy of the level corresponding to the (D) Emits 2.0 eV photon
quantum number equal to 5 is ............. eV
(A) −0.54 (B) −0.85 Solution:(Correct Answer:D)
(C) −0.64 (D) −0.40 emit 2.0 ev photon. because 7.0 − 5.0 (work function ) = 2.0
21
(92) The wave number of the first Lyman transition in H atom Solution:(Correct Answer:B)
spectrum is equal to the wave number of second balmer (b) E = −13.6 −13.6
= −13.6 = −3.40 eV
n2 eV = 22 4
transition in the spectrum of
(A) Li2+ (B) Be3+ (99) Based on equation E = −2.178 × 10−18 J Zn2 certain
2
(C) He+ (D) B 4+ conclusions are written. Which of them is not correct ?
(A) For n = 1, the electron has a more negative energy than
Solution:(Correct Answer:C) it does for n = 6 which means that the electron is more
lossely bound in the smallest allowed orbit.
(93) Maximum number of electrons in a subshell of an atom is (B) The negative sign in equation simply means that the
determined by the following [AIPMT 2009] energy of electron bound to the nucleus is lower than it
(A) 2l + 1 (B) 4l − 2 would be if the electrons were at the infinite distance
(C) 2n2 (D) 4l + 2 from the nucleus
(C) Larger the value of n, the larger is the orbit radius
Total number of subshells = (2l + 1) (D) Equation can be used to calculate the change in energy
∴ Maximum number of electrons in the subshell when the electron change orbit
= 2(2l + 1) = 4l + 2
(94) What is the wavelength of light required to raise an electron The lowest possible energy state is the one in which the
in the O7+ ion from n = 1 to shell to n = 2 shell ............... nm electrons are most tightly bound, and it’s called the ground
(A) 3.8 (B) 38 state. In the ground state there is more force of attraction
which means elections in ground state are tightly bounded.
(C) 19 (D) 1.9
(100) Observe the following graph for the de-Broglie wavelength
of a hypothetical charged particle (q = 1.6 × 10−19 C). Find
the mass of the particle (h = 6.0 × 10−34 J − s)
(95) Minimum de-Broglie wavelength is associated with
(A) Electron (B) Proton
(C) CO2 molecule (D) SO2 molecule
(d) λ = mv
h
. For same velocity λ ∝ m
1
.
SO2 molecule has least wavelength because their molecular
mass is high.
(96) Beryllium’s fourth electron will have the four quantum

numbers :
(A) 45 × 10−49 kg (B) 45 × 10−45 kg
(A) n = 1, l = 0, m = 0, s = +1/2
(C) 4.5 × 10−45 kg (D) 4.5 × 10−45 gm
(B) n = 1, l = 1, m = 1, s = +1/2
(C) n = 2, l = 0, m = 0, s = −1/2
√ h = 12
2m×q
(D) n = 2, l = 1, m = 0, s = +1/2 6×10−34
√ = 12
2×m×1.6×10−19
Solution:(Correct Answer:C) 36 × 10 × 4 = 2 × 1.6 × 10−19 × m
−68
m = 45 × 10−49 kg Ans.
(97) Ejection of the photoelectron from metal in the
(101) The ground state energy of hydrogen atom is −13.6eV .
photoelectric effect experiment can be stopped by applying
Consider an electronic state Ψ of He− whose energy,
0.5 V when the radiation of 250 nm is used. The work
azimuthal quantum number and magnetic quantum number
function of the metal is ................ eV [JEE MAIN 2018]
are −3.4eV, 2 and 0 respectively. Which of the following
(A) 4 (B) 5.5
statement(s) is(are) true for the state Ψ ?
(C) 4.5 (D) 5 (1) It has 2 angular nodes
(2) It has 3 radial nodes
Solution:(Correct Answer:C) (3) It is a 4d state
(4) The nuclear charge experienced by the electron in this
o
λ = 250 nm = 2500 A
E = hc 12400 state is less than 2e, where e is the magnitude of the
λ = 2500 = 4.96 eV
KE = stopping potential = 0.5 eV electronic charge. [IIT 2019]
E = W0 + K.E. (A) 1, 3 (B) 1, 4
4.96 = W0 + 0.5
(C) 1, 2 (D) 1, 2, 3
W0 = 4.46 ≈ 4.5 eV
(98) The value of the energy for the first excited state of # − 3.4 = −13.6×4
hydrogen atom will be ............. eV
n2
n=4
(A) −13.6 (B) −3.40 #ℓ = 2
(C) −1.51 (D) −0.85 #m = 0
22
√
Angular nodes = ℓ = 2 v = 3KT
Radial nodes = (n − ℓ − 1) = 1
m
De-broglie wavelength
nℓ = 4d state h
= λ = mv = √h3KT
m m
(102) Which of the following has maximum energy [AIIMS 2002] λ ∝ √1m
h
λ = √3KT m
(A) Mass of electron < mass of neutron
λ (electron) > λ (neutron)

Statement I : Bohr’s theory accounts for the stability and
line spectrum of Li+ ion.
(B) Statement II : Bohr’s theory was unable to explain the
splitting of spectral lines in the presence of a magnetic field.
In the light of the above statements, choose the most
appropriate answer from the options given below: [JEE MAIN
2021]
(C) (A) Both statement I and statement II are true.

(B) Statement I is false but statement II is true.
(C) Both statement I and statement II are false.
(D) Statement I is true but statement II is false.
(D)
Statement−I is false since Bohr’s theory accounts for the
stability
( and spectrum of single electronic species
eg : He+ , Li2+ etc )
Statement−II is true.
It’s Obvious (107) If the radius of first orbit of H atom is a0 , the de-Broglie
wavelength of an electron in the third orbit is [AIEEE 2012]
(A) 4πa0 (B) 8πa0
(103) In Bohr’s model, atomic radius of the first orbit is γ, the
radius of the 3rd orbit, is (C) 6πa0 (D) 2πa0
(A) γ/3 (B) γ
(C) 3γ (D) 9γ rH = a 0 n 2
r = a0 × (3)2 = 9a0
mvr = nh 2π ;
(d) r ∝ n2 nh 3h
mv = 2πr = 2π×9a = 6πha0
For I st orbit γ = 1 0
For III rd orbit = γ ∝ 32 = 9 λ = mv = h × 6πa0 = 6πa0

h h
So it will 9γ.
(108) The subshell that arises after f is called g subshell.
(104) Which of the following set of quantum number is not valid (a) How many g orbital are present in the g subshell ?
[AIIMS 2001]
(b) In what principal electronic shell whould the g subshell
first occur and what is the total number of orbitals in this
(A) n = 1, l = 2 (B) n = 2, m = 1
principal shell ?
(C) m = 3, l = 0 (D) n = 4, l = 2 (A) (a)3; (b)1s (B) (a)9; (b)3s
Solution:(Correct Answer:A) (C) (a)3; (b)2s (D) (a)9; (b)2s
It’s Obvious
(105) At temperature T , the average kinetic energy of any particle (109) If the potential energy of the electron is −10 eV what is
is 32 KT . The de Broglie wavelength follows the order [JEE total energy? ................ eV
MAIN 2015] (A) −20 (B) +20
(A) Visible photon > Thermal neutron > Thermal electron (C) +5 (D) −5
(B) Thermal proton > Thermal electron > Visible photon
(C) Thermal proton > Visible photon > Thermal electron
(D) Visible photon > Thermal electron > Thermal neutron (110) If radius of second Bohr orbit of the He+ ion is 105.8 pm,
what is the radius of third Bohr orbit of Li2+ ion? [NEET 2022]
Solution:(Correct Answer:D) (A) 15.87 pm (B) 1.587 pm
Kinetic energy of any particle = 3
2 KT (C) 158.7 Å (D) 158.7 pm
Also K.E. = 12 mv 2
2 mv = 2 KT ⇒ v = m
1 2 3 2 3KT
23
Acc. to Bohr’s atomic model (116) Which of the following atoms and ions are isoelectronic i.e.
3rd orbit of Li+2 have the same number of electrons with the neon atom
2
r ∝ nz n1 = 3, Z1 = 3
⇒ 2nd orbit of He+ n2 = 2, Z2 = 2 (A) F − (B) Oxygen atom
(r3 )L+2 n21
(r2 ) + = n2 × Z1
Z2
He 2
(C) M g (D) N −
(r3 )Li+2
2×2 × 3
= 3×3 2
105.8pm Solution:(Correct Answer:A)
(r3 )Li+2 = 158.7 pm (a) F − have the same number of electrons with the neon
atom.
(111) Consider the ground state of (Z = 24). The numbers of
electrons with the azimuthal quantum numbers, l = 1 and 2 (117) The orbital angular momentum of an electron in an s orbital
are, respectively [AIEEE 2004] is
(A) 16 and 4 (B) 12 and 5 (A) 1 (B) 0
√
(C) 12 and 4 (D) 16 and 5 (C) 2
2h
∏ (D) all of these
Solution:(Correct Answer:B) Solution:(Correct Answer:B)

√
(b) 24 Cr → 1s2 , 2s2 , 2p6 , 3s2 , 3p6 , 3d5 , 4s1 Angular momentum in an orbital = 2π h
ℓ(ℓ + 1)
l=1 l=1 l=2 ℓ = 0 for s orbital, hence orbital angular momentum = 0
(We know that for p the value of l = 1 and for d, l = 2) ℓ = 1 for p orbital √
For l = 1 total number of electron = 12 Angular momentum = 2π h
(1 + 1) × 1 = √h2π
For l = 2 total number of electron = 5.
(118) The observation of line spectrum of hydrogen atom
(112) What is the value of azimuthal quantum number for ′ g ′ sub indicates that
shell ? (A) the electrons do not lose energy when in stationary
(A) 3 (B) 4 states
(C) 6 (D) 5 (B) there is emission of energy when a sample of hydrogen
is heated
(C) an electron in excited state loss energy continuously
(113) According to the Bohr theory, which of the following (D) an electron in excited state loses energy in the form of
transitions in the hydrogen atom will give rise to the least bundles or packets of energy
energetic photon ? [AIPMT 2011]
(A) n = 6 to n = 1 (B) n = 5 to n = 4 Solution:(Correct Answer:D)
(C) n = 6 to n = 5 (D) n = 5 to n = 3 (119) Uncertainity in position of an electron and helium atom is

same. If uncertainity in momentum of electron is 32 × 105
[ ] then uncertainity in momentum of helium atom is
E = hCλ = hCRH n21 − n22
1 1
(A) 32 × 105 (B) 16 × 105
where n2 > n1
(C) 8 × 105 (D) 4 × 105
Energy of photon obtained from the transition n = 6 to
n = 5 will have least energy. Solution:(Correct Answer:A)
According to Heisenberg’s Uncertainity principle:
(114) The energy of an electron in the first Bohr orbit of hydrogen ∆x.∆p ≥ h/4π
atom is −2.18 × 10−18 J. Its energy in the third Bohr orbit is therefore for a known amount of uncertainty in position, all
......... [JEE MAIN 2023] particles will have same uncertainty in momentum. given
(A) 1
of this value ∆pe = 32 × 105
thus, ∆pHe = 32 × 105
27
(B) One third of this value option A is correct

(C) Three times of this value
(120) The number of correct statements from the following
(D) 1
9 th of this value A. For 1 s orbital, the probability density is maximum at the
nucleus.
Solution:(Correct Answer:D) B. For 2s orbital, the probability density first increases to
En = −2.18×10−18 Z 2 maximum and then decreases sharply to zero.
C. Boundary surface diagrams of the orbitals encloses a
n2
i.e. En ∝ n21
region of 100% probability of finding the electron.
(115) Which of the following sets is possible for quantum numbers D. p and d-orbitals have 1 and 2 angular nodes respectively.
E. Probability density of p-orbital is zero at the nucleus. [JEE
(A) n = 4, l = 3, m = −2, s = 0
MAIN 2023]
(B) n = 4, l = 4, m = +2, s = − 12 (A) 3 (B) 4
(C) n = 4, l = 4, m = −2, s = + 12 (C) 2 (D) 5
(D) n = 4, l = 3, m = −2, s = + 12 Solution:(Correct Answer:A)
A, D and E statements are correct.
Solution:(Correct Answer:D) For 2s orbital, the probability density first decreases and
It’s Obvious then increases.
At any distance from nucleus the probability density of
24
finding electron is never zero and it always have some finite Solution:(Correct Answer:C)
value.
(125) Which of the following pair is not isoelectronic species? (At.
no. Sm, 62; Er, 68 : Y b, 70 : Lu, 71; Eu, 63 : T b, 65; Tm, 69)
[JEE MAIN 2022]
(A) Sm2+ and Er3+ (B) Y b2+ and Lu3+
(C) T b2+ and T m4+ (D) both (A) and (C) are true
(121) The emission spectrum of hydrogen is found to satisfy the Sm2+ → electron = 60
expression for the ( energy change.
) ∆E (in joules) such that Er3+ → electron = 65
∆E = 2.18 × 10 n2 − n2 J where n1 = 1, 2, 3. . . .. and n2
1 1 T b2+ → electron = 63
1 2
= 2, 3, 4....... The spectral lines correspond to Paschen series T m4+ → electron = 65
to all are (not isoelectronic)
(A) n1 = 1 and n2 = 2, 3, 4
(126) The specific charge of proton is 9.6 × 106 C kg −1 then for an
(B) n1 = 3 and n2 = 4, 5, 6 α-particle it will be
(C) n1 = 1 and n2 = 3, 4, 5 (A) 38.4 × 107 C kg −1 (B) 19.2 × 107 C kg −1
(D) n1 = 2 and n2 = 3, 3, 5 (C) 2.4 × 107 C kg −1 (D) 4.8 × 107 C kg −1
Solution:(Correct Answer:B) Solution:(Correct Answer:D)

(q) (q)
In the emission spectra of hydrogen atom, Paschen series is (d) m α
= 12 m p
= 12 × 9.6 × 107 = 4.8 × 107 C kg −1
the one where the transition from higher energy states to
third energy state takes place. (127) Which of the following quantum number is not obtained by
i.e. nf = n1 = 3 and ni = n2 > 3 the solution of Schrodinger wave equation
(A) magnetic quantum number
(122) Which statement relating to the spectrum of H atom is false
: (B) principal quantum number
(A) The lines can be defined by quantum number
(C) spin quantum number
(B) The lines of longest wavelength in the Balmer series
(D) azimuthal quantum number
corresponds to the transition between n − 3 and n = 2
levels
(C) The spectral lines are closer together at longer Schrodinger equation is written in the form of Ψ.
wavelength d2 Ψ d2 Ψ d2 Ψ 8π 2 m
dx2 + dy 2 + dzz 2 + h2 × (E − C) × Ψ = 0
(D) A continuum occurs at n = ∞ The solution of this equation provides a set of numbers,
called quantum numbers, which describe energies of the
Solution:(Correct Answer:C) electron in atoms, information about the shape and
orientations of the most probable distribution of electrons
(123) The number of photons emitted by a monochromatic (single around the nucleus. These quantum numbers are the
frequency) infrared range finder of power 1 mW and principal, azimuthal and magnetic quantum numbers but
wavelength of 1000 nm, in 0.1 second is x × 1013 . The value spin quantum is not associated with Schrodinger equation.
of x is ..... . The spin quantum number is associated with spin of the
(Nearest integer) electron in doublets of the orbital.
( )
h = 6.63 × 10−34 Js, c = 3.00 × 108 ms−1 [JEE MAIN 2021]
(A) 50 (B) 500 (128) The ratio of velocity of electron in second orbit of He+ to
third orbit of B +4 is
(C) 5 (D) 663 (A) 53 (B) 35
Solution:(Correct Answer:A) (C) 3
2 (D) 2
3
Energy emitted in 0.1 sec.
= 0.1 sec · ×10−3 sJ Solution:(Correct Answer:B)
= 10−4 J He +
Z V2 2/2
V ∝ = = 3
If ′ n′ photons of λ = 1000 nm are emitted,
n V B +4 5/3 5
3
then ; 10−4 = n × hc λ
⇒ 10−4 = n×6.63×10
−34
×3×108 (129) The de-Broglie wavelength of a particle of mass 6.63 g
1000×10−9
moving with a velocity of 100 ms−1 is [JEE MAIN 2014]
⇒ n = 5.02 × 1014 = 50.2 × 1013
⇒ 50 (nearest integer) (A) 10−33 m (B) 10−35 m
(C) 10−31 m (D) 10−25 m
(124) The energy of an electron revolving in nth Bohr’s orbit of an
atom is given by the expression Solution:(Correct Answer:A)
(A) En = − 2π nm2 he2 z (B) En = − 2π nme
2 4 2 2 2 2 2
2 h2
z
De Broglie wavelength (λ) = mv
h
−34
6.63×10 −33
(C) En = − 2π nme (D) En = − 2πm 6.63×10−3 ×100 = 10 m
2 4 2 2 2 4
z e z
2 h2 n2 h 2
25
(130) The graph between |ψ| and r(radial distance) is shown (134) In ground state of He⊕ ion how much energy is supplied to
2
below. This represents [JEE MAIN 2019] electron so that second line of Balmer series is obtained in
its spectrum ................. eV
(A) 51 (B) 48.36
(C) 10.2 (D) None of these
( )
E = 13.6 × 1/ni2 − 1/nf 2 × Z 2 eV
z = 2 (atomic no. of Helium)
For Balmer series;
ni = 2 and nf
( = 4 (i.e. second
) line of balmer series)
E = 13.6 × 1/22 − 1/42 × Z 2 eV
(A) 1s orbital (B) 3s orbital E = 10.2 eV
(C) 2s orbital (D) 2p orbital
(135) The ratio of two of the first four Bohr’s orbits of the
Solution:(Correct Answer:C) hydrogen atom are in the ratio 1 : 4 The energy difference
between them may be
As we know that for s− orbital graph start from top and no.
of radial node = n − l − 1 For 2s orbital it will = 2 − 0 − 1 = 1 (A) Either 12.09 eV or 10.2 eV
∴ The graph is of 2s (B) Either 2.55 eV or 10.2 eV
(C) Either 13.6 eV or 3.4 eV
(D) Either 3.4 eV or 0.85 eV
Rn1 n2
= n12 = 14 , ∴ nn21 = 12 , 42 , 63 etc
Rn2 2
Among the first four orbits n1 and n2 can be 1 and 2 or 2
and 4
Energy difference can be :
E2→1 = 10.2 eV
(131) The four quantum number for the valence shell electron or E4→2 = 2.55 eV
last electron of sodium (Z = 11 ) is
(A) n = 2, l = 1, m = −1, s = − 12 (136) In the nuclear transmutation 94 Be + X −→ 84 Be + Y (X, Y )
is (are)
(B) n = 3, l = 0, m = 0, s = + 12 (A) (γ, n) (B) (p, D) (C) (n, D) (D) (γ, p) [IIT 2013]
(C) n = 3, l = 2, m = −2, s = − 12 (A) (A, B) (B) (B, D)
(D) n = 3, l = 2, m = 2, s = + 12 (C) (B, C) (D) (A, C)
4 Be + X −→ 4 Be + Y
9 8
(b) N a11 = 2, 8, 1= 1s2 , 2s2 2p6 , 3s1
If X is γ0 γ then Y is 0 n1
0
n = 3, l = 0, m = 0, s = +1/2
If X is 1 P 1 then Y is 1 D2
(132) When electronic transition occurs from higher energy state (137) Correct energy value order is :-
to lower energy state with energy difference equal to ∆E (A) ns np nd(n − 1)f (B) ns np(n − 1)d (n − 2)f
electron volts, the wavelength of the line emitted is
approximately equal to (C) ns np(n − 1)d (n − 1)f (D) ns(n − 1)d n(n − 1)f
(A) 12395
∆E × 10
−10
m (B) 12395
∆E × 10 m
10
(C) 12395
∆E × 10−10 cm (D) 12395
∆E × 1010 cm
(138) The electrons, identified by quantum by numbers n and l,
Solution:(Correct Answer:A) (i) n = 4, l = 1 (ii) n = 4, l = 0 (iii) n = 3, l = 2
hc
λ = ∆E = 6.62×10 Js×3×10 ms
−34 8 −1
(iv) n = 3, l = 1 can be placed in order of increasing energy,
E×1.602×10−19 J
= 12395 × 10−10
m from the lowest to highest, as [IIT 1999]
(A) (iv) < (ii) < (iii) < (i) (B) (ii) < (iv) < (i) < (iii)
(133) The value of Rydberg constant (RH ) is 2.18 × 10−18 J. The (C) (i) < (iii) < (ii) < (iv) (D) (iii) < (i) < (iv) < (ii)
velocity of electron having mass 9.1 × 10−31 kg in Bohr’s
first orbit of hydrogen atom = . . . . . . . . . × 105 ms−1 Solution:(Correct Answer:A)
(nearest integer) [JEE MAIN 2024] According to afbau rule energy is more for more (n + l)
(A) 22 (B) 25 value.
and if (n + l) is Same, then n will less no. has less energy
(C) 30 (D) 35 (i) n + l = 0
(ii) n + l = 4
Solution:(Correct Answer:A) (ii) n = 3, l = 2 n + l = 5
V = 2.18 × 106 × Zn (iv) n + l = 4
= 21.8 × 105 × 11 ≈ 22 × 105 (nearest) (iv) < (ii) < (iii) < (i)
26
(139) Electrons are emitted with zero velocity from a metal Solution:(Correct Answer:D)
surface when it is exposed to radiation of wavelenght (d) Orbitals are 4s, 3s, 3p and 3d. Out of these 3d has
o
8000 A. What should be the maximum velocity of emitted highest energy.
electron when the same metal surface is exposed to
o ( )
radiation of wavelength 5000 A ? h = 6.6 × 10−34 J.s (145) Which of the following are isoelectronic and isostructural
(A) 5.74 × 106 ms−1 (B) 5.74 × 105 ms−1 N O3− , CO32− , ClO3− , SO3 [IIT 2003]
(C) 5.74 × 104 ms−1 (D) 5.74 × 107 ms−1 (A) N O3− , CO32− (B) SO3 , N O3−
Solution:(Correct Answer:B) (C) ClO3− , CO32− (D) CO32− , SO3
(140) The set of quantum number for the 19th electrons in Solution:(Correct Answer:A)
chromium is (a) N O3− and CO32− consist of same electron and show
(A) n = 4, l = 0, s = +1/2 or −1/2 same isostructural.
(B) n = 3, l = 2, m = 1, s = +1/2 or −1/2
(146) Which one of the following should be most stable
(C) n = 3, l = 2, m = −1, s = +1/2 or −1/2
(A) H2+ (B) H +
(D) n = 4, l = 1, m = 0, s = +1/2 or −1/2
(C) H (D) H −
(141) Which of the following set of quantum numbers are allowed
(d)H − is most stable due to its full filled 1s-orbital.
?
(A) n = 1, l = 1, m = 1, s = 12
(147) The number of radial node/s for 3p orbital is: [JEE MAIN 2024]
(B) n = 2, l = 1, m = 1, s = 1 (A) 1 (B) 4
(C) n = 3, l = 0, m = −1, s = 1
2 (C) 2 (D) 3
(D) n = 3, l = 1, m = 1, s = 1
2
For 3p : n = 3, ℓ = 1
Number of radial node = n − ℓ − 1
(142) Which one is the wrong statement? [NEET 2017]
=3−1−1=1
(A) The uncertainty principle is ∆E × ∆t ≥ h
4π
(B) Half filled and fully filled orbitals have greater stability (148) A certain orbital has no angular nodes and two radial nodes.
due to greater exchange energy, greater symmetry and The orbital is [JEE MAIN 2021]
more balanced arrangement. (A) 2 s (B) 3 s
(C) The energy of 2s− orbital is less than the energy of 2p− (C) 3 p (D) 2 p
orbital in case of hydrogen like atoms.
(D) de-Broglie’s wavelength is given by λ = mvh
, where m = Solution:(Correct Answer:B)
mass of the particle, v = group velocity of the particle. 1 = 0 ⇒ ′ s′ orbital
n−l−1=2
n−1=2
In H−like atom energy of 2s = 2p orbital n=3
(143) The four quantum numbers of the outermost orbital of K
(atomic no. = 19 ) are (149) Which of the following is not permissible arrangement of
(A) n = 2, l = 0, m = 0, s = + 12 electrons in an atom
(A) n = 3 ; l = 2 ; m = −2 ; s = − 21
(B) n = 4, l = 0, m = 0, s = + 12
(B) n = 4 ; l = 0 ; m = 0 ; s = − 12
(C) n = 3, l = 1, m = 1, s = + 12
(C) n = 5 ; l = 3 ; m = 0 ; s = + 12
(D) n = 4, l = 2, m = −1, s = + 12
(D) n = 3 ; l = 2 ; m = −3 ; s = − 21
(b) K19 = 1s2 , 2s2 2p6 , 3s2 3p6 , 4s1
for 4s1 electrons.
n = 4, l = 0, m = 0 and s = + 12 . when l = 2 then
possible value of m is
(144) Which of the following set of quantum numbers belong to −l to +l
highest energy so m = −3 is not possible
(A) n = 4, l = 0, m = 0, s = + 12
(150) The limiting line in Balmer series will have a frequency of
(B) n = 3, l = 0, m = 0, s = + 12
(Rydberg constant,R∞ = 3.29 × 1015 cycles/s ) [AIEEE 2012]
(C) n = 3, l = 1, m = 1, s = + 12 (A) 8.22 × 1014 s−1 (B) 3.29 × 1015 s−1
(D) n = 3, l = 2, m = 1, s = + 12 (C) 3.65 × 1014 s−1 (D) 5.26 × 1013 s−1
27
−34
66.3×10−10 m
Solution:(Correct Answer:A) 7.6 × 10−25 =
= 6.63 10
( ) 7.6
v̄ = λ1 = RH Z n12 − n12 = 8.72 × 10−10 m
1 2 ≈ 9 × 10−10 m
In Balmer series n1 = 2 & n2 = 3, 4, 5....
= 9o
Last line of the spectrum is called series limit.
Limiting line is the line of shortest wavelength and high (155) The kinetic energy of an electron in the second Bohr orbit of
enegry when n2 = ∞ a hydrogen atom is equal to xma h2
2 . The value of 10x is ........ .
15
∴ v̄ = λ1 = RnH2 = 3.29×10
4
0
(a0 is radius of Bohr’s orbit) (Nearest integer) [Given :
1
= 8.22 × 1014 s−1 π = 3.14] [JEE MAIN 2021]
Solution:
.......... Chemistry - Section B (NUMERIC) .......... nh
mvr = 2π
n2 h2 h2
(151) The electronic configuration of a dipositive metal M 2+ is K.E. = 8π 2 mr2 = 8π2 4m(4a
( ) 2
2
0)
2, 8, 14 and its atomic weight is 56 a.m.u. The number of 4

= 8π2 ×16 ma2 h
neutrons in its nuclei would be 0
⇒ x = 315.507
⇒ 10x = 3155 (nearest integer)
Solution:
(a) Metal is 56 M 2+ (2, 8, 14) (156) The uncertainity in the location of circulating electron is
than n = A − Z = 56 − 26 = 30. equal in it’s de-Broglie wavelength the minimum percent
error in it’s measurement of velocity under this
(152) The number of orbitals in the fourth principal quantum cicumstances will be approximately
number will be
Solution:
Solution: ∆x = λ
h
(d) No. of electrons= 2n2 hence no. of orbital = 2n2
= n2 . ∆x × ∆V = 4πm
2
h
⇒ 42 = 16 λ × ∆V = 4πm
h h
mv × ∆V = 4πm
(153) Not considering the electronic spin, the degeneracy of the
V % = 4π × 100 = 8
∆V 1
second excited state (n = 3) of H atom is 9 , while the
degeneracy of the second excited state of H − is [IIT 2015] (157) For n = 3 energy level, the number of possible orbitals (all
kinds) are
Solution:
Solution:
Single electron species don’t follow the (n + ℓ ) rule but
multi electron species do. (d) When n = 3 shell, the orbitals are n2 = 32 = 9 .
Ground state of H − = 1s2 No. of electrons = 2n2
Hence no. of orbital = 2n2 = n2 .
2
First excited state of H − = 1s1 , 2s1

Second excited state of H − = 1s1 , 2s0 , 2p1 (158) Which orbit of Be+3 has the same orbit radius as that of the
Image ground state of hydrogen atom
(3 degenerate orbitals)
Solution:
From Bohr’s atomic model, atomic radius for nth state is
given by the formula,
2
r = 0.059 nz A
(154) When light of wavelength 248 nm falls on a metal of Since for Be, z = 4
n2 12
threshold energy 3.0 eV , the de-Broglie wavelength of 4 = 1
emitted electrons is ............. Å Hence, n = 2
(Round√off to the Nearest Integer). (159) Assume that the radius of the first Bohr orbit of hydrogen
[Use : 3 = 1.73, h = 6.63 × 10−34 Js atom is 0.6Å. The radius of the third Bohr orbit of He+ is
me = 9.1 × 10−31 kg;]c = 3.0 × 108 ms−1 .................. picometer. (Nearest Integer) [JEE MAIN 2023]
1eV = 1.6 × 10−19 J [JEE MAIN 2021]
Solution:
Solution: r ∝ nZ
2
Energy incident = hcλ rHe+ = rH × n2

6.63×10−34 ×3.0×108 Z
= 248×10 −9 ×1.6×10−19 eV (3)2
rHe+ = 0.6 × 2
= 6.63×3×100
248×1.6 = 2.7Å
= 0.05eV × 100 = 5eV
rHe+ = 270 pm
Now using E = ϕ + K.E
5 = 3 + K.E (160) Consider the following set of quantum numbers
K.E. = 2eV = 3.2 × 10−19 J
n l ml
for debroglie wavelength λ = h
mv
K.E = 12 mv 2 A 3 3 −3
√
so v = 2KE m
B 3 2 −2
hence λ = √2KE×m
h
C 2 1 +1
6.63×10−34
= √2×3.2×10 −19 ×9.1×10−31
D 2 2 +2
28
The number of correct sets of quantum numbers is ..... . [JEE 5 → 4, 5 → 3 and 4 → 3
MAIN 2022] Therefore the infrared region of the spectrum, 3 lines are
produced.
Solution: Hence, te correct option is C
Quantum no. of set (B) and (C) can be correct.
(166) A metal surface is exposed to 500 nm radiation. The
(A) and (D) are wrong as n = ℓ is not possible.
threshold frequency of the metal for photoelectric current is
4.3 × 1014 Hz. The velocity of ejected electron is
(161) The de-Broglie’s wavelength of an electron in the 4th orbit is
....... × 105 ms−1 (Nearest integer)
. . . . . . . . πa0 . (a0 = Bohr’s radius) [JEE MAIN 2024] ]
[Use : h = 6.63 × 10−34 Js, me = 9.0 × 10−31 kg [JEE MAIN 2021]
Solution: Solution:
2πru = nλd v : speed of electron having max. K.E.
2πa0 nz = nλd
2
⇒ from Einstein equation : E = ϕ + K · E· max
2
2πa0 41 = 4λd ⇒ hcλ = hv0 + 2 mv
1 2
−34
×3×10
= 6.63 × 10−34 × 4.3 × 1014 + 12 mv2
8
λd = 8πa0 ⇒ 6.63×10
500×10−9
−20
⇒ 6.63×30×10
5 = 6.63 × 4.3 × 10−20 + 21 mv2
(162) The electronic configuration of a dipositive ion M 2+ is ⇒ 11.271 × 10 −20
J = 21 × 9 × 10−31 × v2
2, 8, 14 and its atomic mass is 56. The number of neutrons in ⇒ v = 5 × 10 m/sec
5
the nucleus would be :
Solution:
e = (2 + 8 + 14) = 24
Here, mass number : A = 56
Z = No. of protons = No. of electrons in the neutral atom
= 24 + 2 = 26
Mass Number = 56
(167) How many spectral line of Balmer series present in visible
No. Of Neutrons = Mass No. − Atomic No. = 56 − 26 = 30
region : [AIIMS 2019]
(163) If the velocity of hydrogen molecule is 5 × 104 cm sec−1 , Solution:
o
then its de-Broglie wavelength is ............. A For balmer series,
n1 = 2 and n2 = 3, 4, 5, 6, . . . . . .
Solution: In balmer series, four spectral lines are available in visible
(b) According to de-Broglie region. These spectral lines have wavelengths greater than
λ = mvh
= 6.62×10−20 erg. sec 400 nm and smaller than 700 nm.
2
×5×104 cm/ sec
6.023×1023
o
= 6.62×10−27 ×6.023 ×1023
cm= 4 × 10−8 cm = 4 A. (168) The number of electrons present in all the completely filled
2 ×5 ×104
subshells having n = 4 and s = + 12 is)______________.
(164) A photon of 300 nm is absorbed by a gas and then re-emits (Where n = principal quantum number and s = spin
two photons. One re-emitted photon has wavelength quantum number) [JEE MAIN 2024]
496 nm , the wavelength of second re-emitted photon is Solution:
Solution: n = 4 can have,
E = E1 + E2 4s 4q 4d 4f
∴ hc hc
λ = λ1 + λ2
hc
Total e −
2 6 10 14
1 1 1
300 = 496 + λ2 Total 1 3 5 7
λ2 = 300 − 496 = 300×496 e− with
1 1 1 196
∴ λ2 = 196 = 759 nm
300×496 S = + 21
So, Ans.16
(169) The wave no. of the first line of Balmer series of H atom is
15200 cm−1 . What is wave number of the first line of Lyman
series of Li2+ ................ cm−1
(165) A certain atomic transition from an excited state to the Solution:

RH ×[ 14 − 91 ] 5
ground state of the hydrogen atom in one or more steps 15200
1 = RH ×9[ 11 − 41 ]
= 9×4
9×3 = 5
9×9×3
give rise to four line in the ultraviolet region of the
λ 4
1
= 15200
×9×9× 3 = 738720
spectrum. How many lines does this transition produce in λ 5
the infrared region of the spectrum (170) Following figure shows spectrum of an ideal black body at
four different temperatures. The number of correct
Solution: statement/s from the following is ...............
Let the four lines are observed in the ultraviolet region of A. T4 > T3 > T2 > T1
the spectrum. B. The black body consists of particles performing simple
These correspond to the transitions harmonic motion.
5 → 1, 4 → 1, 3 → 1 and 2 → 1 C. The peak of the spectrum shifts to shorter wavelength as
The possible transitions in the IR region are temperature increases.
29
D. Tv11 = Tv22 = Tv33 ̸= constant (174) The number of atomic orbitals from the following having 5
E. The given spectrum could be explained using radial nodes is ........ 7s, 7p, 6s, 8p, 8d [JEE MAIN 2023]
quantisation of energy. [JEE MAIN 2023]
Solution:
Radial node = n − ℓ − 1
7s ⇒ R · N = 7 − 0 − 1 = 6
7p ⇒ R · N = 7 − 1 − 1 = 5
6s ⇒ R · N = 6 − 0 − 1 = 5
8p ⇒ R · N = 8 − 1 − 1 = 6
8d ⇒ R · N = 8 − 2 − 1 = 5
So, Answer is 3
(175) The work function (ϕ) of some metals is listed below. The
number of metals which will show photoelectric effect
when light of 300 nm wavelength falls on the metal is
Metal Li Na K Mg Cu Ag Fe Pt W
[IIT
Solution: ϕ(eV )2.4 2.3 2.2 3.7 4.8 4.3 4.7 6.3 4.75
2011]
The spectrum of Black body radiation is explained using
quantization of energy. With increase in temperature, peak Solution:
of spectrum shifts to shorter wavelength or higher
the enrgy associated with incident photon hc
frequency. For above graph −34
λ
×3×108
→ T1 > T 2 > T 3 > T 4 . ⇒ E = 6.6×10
300×10−90 J
−34
E in eV = 300×10 ×.3×10 8
6.6×10
−9 ×1.6×10−19 = 4.16eV
(171) Total number of spectral lines when electron jumps from 8th So, number fo metal showing phote -electric effects whill be
orbit to 2nd orbit : (4), i, e, Li, na, K, M g, .
Solution: (176) The wavelength of electrons accelerated from rest through
n1 = 8, n2 = 2 a potential difference of 40 kV is X × 10−12 m. The value of x
The total number of the spectral line is given by the is ....... (Nearest integer)
equation: Given : Mass of electrons = 9.1 × 10−31 kg
N = (n2 − n1 ) (n2 − n1 + 1) /2 Charge on an electron = 1.6 × 10−19 C
So, Planck’s constant = 6.63 × 10−34 Js [JEE MAIN 2021]
N = (8 − 2)(8 − 2 + 1)/2
N = 6 × 7/2 Solution:
N = 42/2 De-broglie-wave length of electron:
N = 21 λc = √ h
2m(KE)
(172) When the excited electron of a H atom from n = 5 drops to ∵ e− is accelerated from rest ⇒ KE = q × V
h
the ground state, the maximum number of emission lines λ = √2mqv
observed are....... [JEE MAIN 2022]
−34
6.63×10
= √2×1.6×10−19 ×9.1×10−31 ×40×103
= 0.614 × 10−11 m
Solution:
= 6.16 × 10−12 m
Maximum number of emission lines from nth energy state to Nearest integer = 6
ground state is given by: OR
= n(n−1)
2 = 5(5−1)
2 2 = 10 lines.
= 20 = 12.3
√ Å
V
= 200 = 6.15 × 10−12 m
12.3
(177) The number of s-electrons present in an ion with 55 protons

in its unipositive state is [JEE MAIN 2023]
Solution:
Z = 55[Cs] ⇒ [Xe]6s1
[Cs+ ] ⇒ [Xe] i.e. upto 5s count e− of s-subshell i.e.
1s, 2s, 3s, 4s, 5s ⇒ 10 electrons
(178) The ionization energy of sodium in kJmol−1 . If

(173) Photon having wavelength 310 nm is used to break the electromagnetic radiation of wavelength 242 nm is just
bond of A2 molecule having bond energy 288 kJ mol−1 sufficient to ionize sodium atom is____. [JEE MAIN 2024]
then % of energy of photon converted to the K.E. is
o
[hc = 12400 ev A , 1 eV /atom = 96 kJ/mol] Solution:
E = λ(nm)
1240
eV
Solution: = 242 eV
1240
Energy of one photon = 12400

3100 = 4ev = 4 × 96 = 5.12eV
= 384 kJ mol −1
= 5.12 × 1.6 × 10−19
∴ % of energy converted to K.E. = 384−288
384 = 8.198 × 10−19 J/ atom
96
= 384 × 100 = 25% = 494 kJ/mol
30
(179) The wavelength of an electron of kinetic energy Solution:
4.50 × 10−29 J is . . . .. × 10−5 m. (Nearest integer)Given : (c) Number of electrons in nitrogen = 7 and number of
mass of electron is 9 × 10−31 kg, h = 6.6× 10−34 Js [JEE MAIN electron is oxygen = 8 we know that
2023] formula of nitrate ion is N O3− we also know that number of
electron
Solution: = (1× Number of electrons in nitrogen)
λd = mvh
= √ h = √ 6.6×10−34 +(3× number of electrons in oxygen) +1
2mKE 2×9×10−31 ×4.5×10−29
√6.6×10−34 = (1 × 7) + (3 × 8) + 1 = 32.
= 92 ×10−60
6.6×10−34
= 9×10−30 = 9× 10−4
6.6
(186) An accelerated electron has a speed of 5 × 106 ms−1 with
= 7.3 × 10 m −5 an uncertainty of 0.02 %. The uncertainty in finding its
Therefore Ans = 7 location while in motion is x × 10−9 m. The value of x is ......
(Nearest integer)
(180) If the sum of (n + l) is 6 ; how many e−1 s would have clock [Use mass of electron ]
wise spin associated with this energy leval = 9.1 × 10−31 kg, h = 6.63 × 10−34 J s, π = 3.14 [JEE MAIN
2021]
(181) The uncertainties in the velocities of two particles, A and B
are 0.05 and 0.02 ms−1 respectively. The mass of B is five Solution:
times to that of the mass of A. What is the ratio of
100 × 5 × 10 = 10 m/s
∆v = 0.02 6 3
uncertainties ∆x
∆xA
in their positions ? [AIIMS 2008]
B According to Heisenberg uncertainty principle
∆X · ∆v = 4πh m
Solution: 6.63×10−34
x × 10−9 × 103 = 4×3.14×9.1×10
Using the relation, −31
h X × 10−9 × 103 = 0.058 × 10−3

∆x. ∆v = 4πm −6
x = 0.058×10 = 58
[Heisenberg’ uncertainty principle] 10−9
or ∆x = 4πm.∆v
h
(187) If the wavelength for an electron emitted from H atom is
Thus, ∆xA = 4π×0.05×m
h
....(i) 3.3 × 10−10 m, then energy absorbed by the electron in its
h
∆xB = 4π×0.02×5m ....(ii) ground state compared to minimum energy required for its
Dividing (i) by (ii), we get escape from the atom, is .......times. (Nearest integer).
∆xA 0.02×5 10
∆xB = 0.05 = 5 or 2 [Given : h = 6.626 × 10−34 Js,Mass of electron
= 9.1 × 10−31 ] [JEE MAIN 2022]
(182) The number of orbitals with n = 5, ml = +2 is ...... . (Round
off to the Nearest Integer) [JEE MAIN 2021] Solution:
h
λ = √2mK
Solution: h2
K = 2mλ
For, n = 5 h2
2
43.9×10−68
ℓ = (0, 1, 2, 3, 4) K = 2mλ 2 = 2×9.1×10−31 ×10.89×10−20
If ℓ = 0, m = 0 K = 2.215 × 10−18
ℓ = 1, m = {−1, 0, +1} Eabs = Ereq + K
2.215×10−18
ℓ = 2, m = {−2, −1, 0, +1, +2} Eabs K
Ereq = 1 + Ereq = 1 + 13.6×1.602×10−19 = 2.0166
ℓ = 3, m = {−3, −2, −1, 0, +1, +2, +3}
ℓ = 4, m = {−4, −3, −2, −1, 0, +1, +2, +3, +4} (188) Maximum number of electrons in a subshell with l = 3 and
5d, 5f and 5g subshell contain one-one orbital having n = 4 is [AIPMT 2012]
mℓ = +2
Solution:
(183) Frequency of the de-Broglie wave of election in Bohr’s first n represents the main energy level and / represents the
orbit of hydrogen atom is. . . . . . . . . . ×1013 Hz (nearest subshell. If n = 4 and I = 3, the subshell is 4f If f subshell,
integer). there are 7 orbitals and each orbital can accommodate a
[Given : RH ( Rydberg constant) = 2.18 × 10−18 J. maximum number of electrons, so, maximum number of
h( Plank’s constant ) = 6.6 × 10−34 J.s. ] [JEE MAIN 2024] electrons in 4f subshell = 7 × 2 = 14
Solution: (189) Maximum number of electrons present in ′ N ′ shell is

h
λ = mv
hv
λ = mv Solution:
2
mv2 v (b) Max. no. of electrons in N − shell (n = 4)
h = λ = v (frequency)
Given 12 mv2 = 2.18 × 10−18 J = 2n2 = 2 × 42 = 32.
h = 6.6 × 10−34
−18 (190) Total number of ions from the following with noble gas
v = 4.36×10
6.6×10−34 = 660.60 × 10
13
Hz
configuration is__________.
≈ 661 × 10 Hz
13
Sr2+ (Z = 38), Cs+ (Z = 55), La2+ (Z = 57)Pb2+
(Z = 82), Yb2+ (Z = 70) and Fe2+ (Z = 26) [JEE MAIN 2024]
(184) The I.P. of a hydrogen like species is 36 eV . What is the
value of second excitation energy ............ eV Solution:
(185) Nitrogen atom has an atomic number of 7 and oxygen has [Noble] gas configuration = ns np
2 6
an atomic number 8. The total number of electrons in a Sr2+

= [Kr⌋
[ +]
nitrate ion will be Cs = [Xe]
31
[ 2+ ]
Yb = [Xe]4f14 Solution:
[ 2+ ]
La = [Xe]5 d1 hv = hv0 + KE for zero velocity KE = 0
[ 2+ ]
Pb = [Xe]4f14 5 d10 6 s2 hv = hv0
[ 2+ ]
Fe = [Ar]3 d6 hv = 4eV
hc
λ = 4eV
(191) A source of monochromatic radiation of wavelength 400 nm λ = h×c
4eV
provides 1000 J of energy in 10 seconds. When this radiation
−34
×3×108
= 6.626×10
4×1.6×10−19 = 3100A◦
falls on the surface of sodium, x × 1020 electrons are ejected Hence, the correct option is D
per second. Assume that wavelength 400 nm is sufficient
for ejection of electron from the surface of sodium metal. (195) What is the maximum number of electrons which can be
The
( value of x is ....... (Nearest
) integer) accommodated in an atom in which the highest principal
h = 6.626 × 10−34 Js [JEE MAIN 2021] quantum number value is 4
Solution: Solution:
Total energy provided by (c) Maximum number of electron
Source per second = 1000
10 = 100 J = 2n2 (wheren = 4) = 2 × 42 = 32.
Energy required to eject electron = hc
λ
−34
(196) The number of waves made by a Bohr electron in an orbit of
400×10−9 × 3 × 10
= 6.626×10 8
Number of electrons ejected maximum magnetic quantum number 3 is

100
6.626×10−34 ×3×108
= 400×10−9 Solution:
−7
400×10 ×10 26
= 6.626×3 Negative quantum number has values from −l to +l
= 40×10−20 ∴l=3
Now, l has value from 0 to n − 1,
6.626×3
= 2.01 × 10 20
∴3=n−1
(192) If the work function of a metal is 6.63 × 10−19 J, the n=4
maximum wavelength of the photon required to remove a No. of waves made by Bohr electron = n = 4
photoelectron from the metal is .... nm. (Nearest integer) So, the correct option is B
[Given : h = 6.63 × 10−34 J s, and c = 3 × 108 m s−1 ] [JEE
MAIN 2022]
(197) The minimum uncertainty in the speed of an electron in an
one dimensional region of length 2ao
Solution: (Where a0 = Bohr radius 52.9pm ) is kms−1
6.63×10−34 ×3×108 (Given : Mass of electron = 9.1 × 10−31 kg, Planck’s constant
ϕ = 6.63 × 10−19 J = hc
λ = λ h = 6.63 × 10−34 Js ) [JEE MAIN 2022]
⇒ λ = 3 × 10−7 m = 300 nm
Solution:
(193) The number of incorrect statement /s about the black body
from the following is ......... Heisenberg’s uncertainty principle
(A) Emit or absorb energy in the form of electromagnetic ∆x × ∆px ≥ 4π h
radiation ⇒ 2a0 × m∆vr = 4π h

( minimum )
(B) Frequency distribution of the emitted radiation ⇒ ∆vx = 4π × 2a0 × m
h 1 1
depends on temperature
−34
6.63×10
= 4×3.14×2×52.9×10 −12 ×9.1×10−31
(C) At a given temperature, intensity vs frequency curve = 548273 ms−1
passes through a maximum value = 548.273 km s−1
(D) The maximum of the intensity vs frequency curve is at a = 548 km s−1
higher frequency at higher temperature compared to that at
lower temperature [JEE MAIN 2023] (198) Electromagnetic radiation of wavelength 663 nm is just
sufficient to ionise the atom of metal A. The ionization
Solution: energy of metal A in kJ mol−1 is ...... .
A blackbody can emit and absorb all the wavelengths in (Rounded-off
[ to the nearest integer)
electromagnetic spectrum ⇒ (A) is correct h = 6.63 × 10−34 Js, c =] 3.00 × 108 ms−1 ,
⇒ (B), (C), (D) correct NA = 6.02 × 1023 mol−1 [JEE MAIN 2021]
Solution:
λ × 1000
NA
E = hc
6.63×10−34 ×3×108 ×6.02×1023
= 663×10−9 ×1000
= 3 × 6.02 × 10 kJ
= 180.6 kJ
(199) For hydrogen atom, energy of an electron in first excited

state is −3.4eV, KE. of the same electron of hydrogen atom
is xeV. Value of x is. . . . . . .×10−1 eV. (Nearest integer) [JEE
MAIN 2024]
(194) The work function for a metal is 4 eV. To emit a photo
electron of zero velocity from the surface of the metal, the Solution:
o
wavelength of incident light should be : ................ A null
32
(200) What is the maximum numbers of electrons that can be
associated with the following set of quantum numbers?
n = 3, l = 1 and m = −1 [NEET 2013]
Solution:
The orbital of the electron having = 3, l = 1 and m = −1 is
3pz ( as n/m) and an orbital can have a maximum of two
electrons with opposite spins.
therefore, 3pz orbital contains only two electrons or only 2
electrons are associated with n = 3, l = 1, m = −1
33

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Subject : Chemistry Paper Set : 1

............ Chemistry - Section A (MCQ) ............ (A) + 21 . 2h∏ (B) 0

(9) The orbital angular momentum of 3p electron is (C) 1

(23) The electrons identified by quantum numbers n and l :

(25) According to Bohr’s theory, the angular momentum of an

Reason : Emission spectrum consists of dark lines. [AIIMS 2002] 0 0

(C) r4 = 34 r3 (D) r4 = 43 r3 (D) magnetic quantum number.

(C) CO2 molecule (D) SO2 molecule

conclusions are written. Which of them is not correct ?

(A) Visible photon > Thermal neutron > Thermal electron

(106) Given below are two statements:

(B) principal quantum number (D) Either 3.4 eV or 0.85 eV

(C) spin quantum number (136) In the nuclear transmutation 94 Be + X −→ 84 Be + Y (X, Y )

(139) Electrons are emitted with zero velocity from a metal

(C) n = 5 ; l = 3 ; m = 0 ; s = + 12 (164) A photon of 300 nm is absorbed by a gas and then re-emits

(200) What is the maximum numbers of electrons that can be

Chemistry - Section A (MCQ)

1-B 2-B 3-A 4-B 5-D 6-C 7-B 8-B 9-D 10 - A

Chemistry - Section B (NUMERIC)

Number of orbitals = 5 × 2 + 1 = 11 = −145.7kJmol−1

(12) The quantum number ′ m′ of a free gaseous atom is Solution:(Correct Answer:D)

(19) The nitride ion in lithium nitride is composed of [AIPMT 2001]

(21) In which of the following transition photon of maximum

(34) The electron in the nth orbit of Li2+ is excited to (n + 1)

(35) One energy difference between the states n = 2 and n = 3

(c) If l = 2, m ̸= −3.= (−m to +m). (C) h2

(43) A cricket ball of 0.5 kg is moving with a velocity of Solution:(Correct Answer:C)

λ(He+ ) (57) A 124 W bulb converts only 15 % of the energy supplied to

Solution:(Correct Answer:B) 124×16 × 10

(66) The orientation of an atomic orbital is governed by [AIPMT 2006]

(C) 1 : 4 : 9 (D) 1 : 8 : 27 (A) 89, 231, 89 (B) 89, 89, 242

(71) The frequency of a certain line of lyman series of atomic

(C) λ1 + λ2 + λ3 = 0 (D) λ23 = λ21 + λ22

(B) spin quantum number

(96) Beryllium’s fourth electron will have the four quantum

(106) Given below are two statements:

(C) (A) Both statement I and statement II are true.

For III rd orbit = γ ∝ 32 = 9 λ = mv = h × 6πa0 = 6πa0

Solution:(Correct Answer:B) Solution:(Correct Answer:B)

(C) n = 6 to n = 5 (D) n = 5 to n = 3 (119) Uncertainity in position of an electron and helium atom is

(B) One third of this value option A is correct

Solution:(Correct Answer:B) Solution:(Correct Answer:D)

Solution:(Correct Answer:B) (C) ClO3− , CO32− (D) CO32− , SO3

2, 8, 14 and its atomic weight is 56 a.m.u. The number of 4

First excited state of H − = 1s1 , 2s1

Energy incident = hcλ rHe+ = rH × n2

the nucleus would be :

(165) A certain atomic transition from an excited state to the Solution:

(177) The number of s-electrons present in an ion with 55 protons

(178) The ionization energy of sodium in kJmol−1 . If

Energy of one photon = 12400

h X × 10−9 × 103 = 0.058 × 10−3

Solution: (189) Maximum number of electrons present in ′ N ′ shell is

an atomic number 8. The total number of electrons in a Sr2+

Number of electrons ejected maximum magnetic quantum number 3 is

radiation ⇒ 2a0 × m∆vr = 4π h

(199) For hydrogen atom, energy of an electron in first excited