50 Day's Plan For Chemistry : (Atomic Structure)
1. Which of the following set of quantum number is impossible for an electron ?
(1) n = 1, ℓ = 0, m = 0, s = +1/2
(2) n = 9, ℓ = 7, m = – 6, s = – 1/2
(3) n = 2, ℓ = 1, m = 0, s = +1/2
(4) n = 3, ℓ = 2, m = – 3, s = +1/2
2. What will be the total spin of Fe3+ ion ?
(1) 5/2 (2) 2
(3) 3/2 (4) 1
3. The maximum number of electrons present in an orbit ℓ = 3, is :
(1) 6 (2) 8
(3) 10 (4) 14
4. The correct set of four quantum numbers for the valence electron of rubidium atom (Z = 37) is:-
(1) 5, 0, 0, + ½
(2) 5, 0, 1, – ½
(3) 5, 0, 1, + ½
(4) 6, 0, 0 + ½
5. The number of electrons in Na, having n + l = 3
(1) 4 (2) 6
(3) 7 (4) 8
6. The orbital diagram in which both the Pauli's exclusion principle and Hund's rule are violated, is :-
(1) (2)
(3) (4)
7. Any nf – orbital can accomodate upto : –
(1) 14 electron (2) Six electrons
(3) Two electrons with parallel spin (4) Two electrons with opposite spin
8. The quantum number of 20th electron of Fe(Z = 26) would be : –
(1) 3, 2, – 2, – ½
(2) 3, 2, 0, ½
(3) 4, 0, 0, + ½
(4) 4, 1, – 1, + ½
9. Which of the following set of quantum numbers is correct for the 19th electron of Chromium :-
n ℓ m s
(1) 3 0 0 1/2
(2) 3 2 –2 1/2
(3) 4 0 0 1/2
(4) 4 1 –1 1/2
10. The atomic number of the element having maximum number of unpaired 3p electrons is (in ground state):-
(1) 15 (2) 10
(3) 12 (4) 8
11. The maximum number of electrons in an atom which can have n = 4 is
(1) 4 (2) 8
(3) 16 (4) 32
12. A p-orbital can accommodate upto
(1) Four electrons
(2) Six electrons
(3) Two electrons
(4) Eight electrons
13. Which of the following orbital is with the four lobes present on the axis ?
(1) dz 2 (2) dxy
(3) dyz (4) dx2 −y 2
14. Which of the following electronic configuration is not possible ?
(1) 2p3 (2) 2d5
(3) 4s1 (4) 5f8
15. Maximum number of electrons in a subshell with l = 3 and n = 4 is
(1) 10 (2) 12
(3) 14 (4) 16
16. The number of radial nodes in 4s and 3p orbitals are respectively
(1) 2, 0 (2) 3, 1
(3) 2, 2 (4) 3, 2
17. Number of protons, neutrons and electrons in the element 89Y231 is :-
(1) 89, 231, 89 (2) 89, 89, 242
(3) 89, 142, 89 (4) 89, 71, 89
18. An element M has 25 protons. The number of electron in its M2– anion will be -
(1) 27 (2) 23
(3) 25 (4) 22
19. Find out the nucleus which are isoneutronic :-
14 15 17
(1) 6 C, 7 N, 9 F
12 14 19
(2) 6 C, 7 N, 9 F
14 14 17
(3) 6 C, 7 N, 9 F
14 14 19
(4) 6 C, 7 N, 9 F
20. Average atomic weight of boron is 10.10 and boron exists in two isotopic forms B10 and B11. The
percentage abundance of B10 is
(1) 10% (2) 90%
(3) 50% (4) 20%
21. Atoms 13 17
6 C and 8 O are related to each other as:-
(1) Isotones (2) Isoelectronic
(3) Isodiaphers (4) Isosters
22. An isotone of 76
32 Ge
76
(i) 32 Ge
(ii) 77
33 As
(iii) 77
34 Se
78
(iv) 34 Se
(1) (ii) & (iii)
(2) (i) & (ii)
(3) (ii) & (iv)
(4) (ii) & (iii) & (iv)
23. 11
5 B and 13
6 C are related to each other as :-
(1) Isotope
(2) Isodiapher
(3) Isosters
(4) Isoelectronic
24. Which species are isoelectronic
(NO3 – , CO3 –2, ClO3 – , SO3)
(1) NO3 – , CO3 –2 (2) SO3, NO3 –
(3) ClO3 – , CO3 –2 (4) CO3 –2, SO3
25. X+2 has 10 protons then find number of protons in X –2 :
(1) 10 (2) 12
(3) 14 (4) 16
26. Ratio of mass of neutron and proton is :-
(1) Less than one (2) More than one
(3) Exactly equal to one (4) Can't be predicted
27. The mass no. of an element is 39. The number of neutrons in its nucleus is one more than the number of
protons. The number of protons, neutrons and electrons respectively in its atom would be
(1) 19, 20, 19
(2) 19, 19, 20
(3) 20, 19, 19
(4) 20, 19, 20
28. Compare the energies of two radiations E1 with wavelength 800 nm and E2 with wavelength 400 nm.
(1) E1 = 2E2 (2) E1 = E2
(3) E2 = 2E1 (4) E2 = − 1 E1
2
29. If the Planck’s constant h = 6.6 x 10 –34 Js, the de-Broglie wavelength of a particle having momentum of
3.3 × 10 –24 kg ms –1 will be -
(1) 0.002 Å (2) 0.02 Å
(3) 0.2 Å (4) 2Å
30. The ratio of the energy of a photon of wavelength 3000 Å to that of a photon of wavelength 6000 Å is :
(1) 1 (2) 2
2
(3) 3 1
(4)
3
31. A gas absorbs a photon of 300 nm and emits at two wavelengths. If one of the emissions is at 600 nm, the
other is at :-
(1) 1035 nm (2) 1200 nm
(3) 600 nm (4) 518 nm
32. Which of the following statements is incorrect ?
(1) The frequency of radiation is inversely proportional to its wavelength.
(2) Energy of radiation increases with increase in frequency.
(3) Energy of radiation decreases with increase in wavelength.
(4) The frequency of radiation is directly proportional to its wavelength.
33. Electromagnetic radiations of wavelength 242 nm is just sufficient to ionise sodium atom. Calculate the
ionisation energy of sodium in kJ mol –l.
(1) 494.5 J mol –1 (2) 494.5 kJ mol –1
(3) 494.5 cal mol –1 (4) 600.5 kJ mol –1
34. Which graph shows how the energy E of a photon of light is related to its wavelength ( λ ) ?
(1)
(2)
(3)
(4)
35. The ratio of velocity of electron in second orbit of He+ to third orbit of B+4 is :-
(1) 5 (2) 3
3 5
(3) 3 (4) 2
2 3
36. Calculate velocity of an electron placed in the third orbit of the hydrogen atom
(1) 7.27×105 m sec –1 (2) 7.27×107 m sec –1
(3) 0.27×105 m sec –1 (4) 7.27 ×106 m sec –1
37. The first three radius ratio of Bohr orbits
(1) 1 : 0·5 : 0·5 (2) 1 : 2 : 3
(3) 1 : 4 : 9 (4) 1 : 8 : 27
38. Which is correct for any H like species :-
(1) (E2 – E1) > (E3 – E2) > (E4 – E3)
(2) (E2 – E1) < (E3 – E2) < (E4 – E3)
(3) (E2 – E1) = (E3 – E2) = (E4 – E3)
(4) (E2 – E1) = 1/4 (E3 – E2)=1/9 (E4 – E3)
39. The ratio of the radii of two Bohr orbit's of H-atoms is 4 : 1 what would be their nomenclature :-
(1) K & L
(2) L & K
(3) N & L
(4) 2 & 3 both
40. When an electron jumps from L to K shell
(1) Energy is absorbed
(2) Energy is released
(3) Energy is neither absorbed nor released
(4) Energy is sometimes absorbed and some times released
41. Angular momentum in second Bohr orbit of H-atom is x. Then find out angular momentum in Ist excitetd
state of Li+2 ion :
(1) 3x (2) 9x
x
(3) (4) x
2
42. En = – 313.6/n2.If the value of En = – 34.84 then to which of the following values does 'n' correspond :-
(1) 1 (2) 2
(3) 3 (4) 4
43. The graphical representation of energy of e – and atomic number is :-
(1)
(2)
(3)
(4)
44. The radius of a shell for H-atom is 4.761A°. The value of n is :-
(1) 3 (2) 9 (3) 5 (4) 4
45. The ratio of minimum wavelengths of Lyman & Balmer series will be : –
(1) 1.25 (2) 0.25
(3) 5 (4) 10
46. If 9.9 eV energy is supplied to H atom, the no. of spectral lines emitted is equal to :-
(1) 0 (2) 1
(3) 2 (4) 3
47. If radius of second stationary orbit (in Bohr's atom) is R. Then radius of third orbit will be:-
(1) R/3 (2) 9R
(3) R/9 (4) 2.25 R
48. How much energy must be provided to an electron present in ground state of hydrogen atom, so that
electron excites to 2nd excited state.
(1) 10.2 eV
(2) 13.6 eV
(3) 1.89 eV
(4) 12.09 eV
49. Angular momentum for P – shell electron is : –
(1) 3h (2) Zero
π
(3) √ 2h (4) None
2π
50. Energy of e – in 2nd orbit of H-atom is-
(1) 13.6 eV
(2) – 3.4 eV
(3) – 1.51 eV
(4) – 0.54 eV
51. If the K.E. of e – in first and second orbit of Li+2 ion is x and y respectively then :
(1) x < y
(2) x > y
(3) x = y
(4) None of these
52. According to Bohr's theory, the angular momentum to an electron in 5th orbit is :
(1) 25 (h/ π ) (2) 1.0 (h/ π )
(3) 10 (h/ π ) (4) 2.5 (h/ π )
53. If the velocity of an electron in 1st orbit of H-atom is u, what will be the velocity of electron in 3rd orbit
Li+2 ?
u
(1) u (2)
3
(3) 3u (4) 9u
54. Bohr's theory is not applicable to
(1) He (2) Li2+
(3) He+ (4) H atom
55. The first emission line in the H-atom spectrum in the Balmer series will have wave number :-
5R
(1) cm –1
36
3R
(2) cm –1
4
7R
(3) cm –1
144
9R
(4) cm –1
400
56. Maximum frequency of emission is obtained for the transition : –
(1) n = 2 to n = 1
(2) n = 6 to n = 2
(3) n = 1 to n = 2
(4) n = 2 to n = 6
57. Find out ratio of following for photon
( ν max.)Lyman : ( ν max)Brakett
(1) 1 : 16 (2) 16 : 1
(3) 4 : 1 (4) 1 : 4
58. In spectral series of hydrogen. The series which does not come in infrared region is :-
(1) P fund
(2) Brackett
(3) Paschen
(4) Lyman
59. The first Lyman transition in the hydrogen spectrum has Δ E = 10.2 eV. The same energy change is
observed in the second Balmer transition of :-
(1) Li2+ (2) Li+
(3) He+ (4) Be3+
60. Four lowest energy levels of H – atoms are shown in the figure. The number of emission lines could be :-
(1) 3 (2) 4 (3) 5 (4) 6
61. The radiation of maximum frequency will be emitted in the transition (for H atom):
(1) From n = 1 to n = 3
(2) From n = 2 to n = 5
(3) From n = 3 to n = 1
(4) From n = 5 to n = 2
62. The shortest wave length in H spectrum of Lyman series when RH = 109678 cm –1 is -
(1) 1215.67 Å (2) 911.7 Å
(3) 1002.7 Å (4) 1127.30 Å
63. Wavelength of first line of Lyman series in terms of R of hydrogen atom :-
(1) 3R
4
4
(2)
3R
(3) 5R
36
(4) 36
5R
64. In the hydrogen atoms, the electrons are excited to the 5th energy level. The number of the lines that may
appear in the emission spectrum will be :
(1) 4 (2) 8
(3) 10 (4) 12
65. When electrons are de-exciting from nth orbit of hydrogen atoms to ground state, 15 spectral lines are
formed. The shortest wavelength among these will be :
(1) 11
R
900
(2) 36
35R
(3) 35
R
36
(4) 35
36R
66. The first emission line in H-atom spectrum in balmer series will have wave no. :-
(1) 5R (2) 3R
36 4
(3) 7R (4) 9R
4 400
67. What will be the longest wavelength line in balmer series of the hydrogen spectrum ?
(1) 566 nm (2) 556 nm
(3) 546 nm (4) 656 nm
68. If an electron in a hydrogen atom jumps from 3rd orbit to the 2nd orbit, it emits a photon of wavelength λ .
When it jumps from the 4th orbit to the 3rd orbit, the corresponding wavelength of photon will be :
(1) 16 (2) 9
λ λ
25 16
(3) 20 (4) 20
λ λ
7 13
69. Which hydrogen like species will have same radius as that of Bohr orbit of hydrogen atom ?
(1) n = 2, Li2+ (2) n = 2, Be3+
(3) n = 2, He+ (4) n = 3, Li2+
70. Electromagnetic radiation travel through vaccum at a speed.
(1) 20,000 ms –1 (2) 5,000 ms –1
(3) 3 × 108 ms –1 (4) can't say
71. Correct order of wavelength of the given radiations is
(1) UV > X rays > IR > Microwave
(2) IR > Microwave > UV > X rays
(3) X rays > UV > IR > Microwave
(4) Microwave > IR > UV > X rays
72. Photon of which light has maximum energy?
(1) Red (2) Blue
(3) Violet (4) Green
73. Visible light consists of rays with wavelengths in the approximate range of :
(1) 4000 Å to 7500 Å (2) 4 × 10 –3 cm to 7.5 × 10 –4 cm
(3) 4000 nm to 7500 nm (4) 4 × 10 –5 m to 7.5 × 10 –6 m
74. The wave number which corresponds to electromagnetic radiations of 600 nm is equal to :
(1) 1.6 × 104 cm –1 (2) 0.16 × 104 cm –1
(3) 16 × 104 cm –1 (4) 160 × 104 cm –1
75. True statements are
(a) Electromagnetic waves do not require medium to move.
(b) All types of electromagnetic radiations are same in wavelength.
(c) In vacuum all electromagnetic radiations, travel at the same speed.
(d) The oscillating electric & magnetic fields produced by oscillating charged particles are perpendicular
to each other and both are perpendicular to the direction of propogation of the wave.
(1) a, c, d (2) b, c, d
(3) a, c (4) a, b, c, d
76. The frequency of the radiation having wave number 10 m –1 is :
(1) 10 s –1 (2) 3 × 107 s –1
(3) 3 × 1011 s –1 (4) 3 × 109 s –1
77. No. of waves in 4th orbit :-
(1) 3 (2) 4
(3) 5 (4) 6
78. The de-Broglie wavelength of a particle with mass 1 g and velocity 100 m/s is:
(1) 6.63 × 10 –33 m (2) 6.63 × 10 –34 m
(3) 6.63 × 10 –35 m (4) 6.65 × 10 –35 m
79. For a valid Bohr orbit, its circumfrence should be
(1) = n λ (2) = (n – 1) λ
(3) > n λ (4) < n λ
80. Which of the following has least de-Broglie wavelength, moving with same speed ?
(1) e – (2) p
(3) CO2 (4) SO2
81. A 0.66 kg ball is moving with a speed of 100 m/s. The associated wavelength will be (h = 6.6 × 10 –34 Js) :-
(1) 6.6 × 10 –34 m (2) 1.0 × 10 –35 m
(3) 1.0 × 10 –32 m (4) 6.6 × 10 –32 m
82. Which of the following has maximum Debroglie λ if they have same velocity. [Atomic
mass: H = 1, C = 12, O = 16, N = 14, S = 32]
(1) H2 (2) CO2
(3) N2 (4) H2S
83. Which of the following pair is isodiaphers ?
(1) 14 C and 23 (2) 24 Mg and 23
6 11 Na 12 11 Na
(3) 15 and 19 (4) 12 and 15
7 N 9 F 6 C 7 N
84. Which is the de-Broglie equation ?
(1) h = p λ
(2) h = p λ –1
(3) h = λ p –1
(4) h = p + λ
85. Which of the following has the largest de-Broglie wavelength (all have equal velocity) ?
(1) CO2 molecule (2) NH3 molecule
(3) Electron (4) Proton
86. If uncertainty in position and momentum are equal, then uncertainty in velocity is :
(1) √
h (2) h
π 2π
(3) 1 √h (4) None of these
2m π
87. According to uncertainty principle :-
(1) E = mc2
(2) Δ x × Δ p ≥ h
4π
h
(3) λ =
p
(4) Δ x × Δ p = h
6π
88. What will be the uncertainty in velocity of an electron if uncertainty in its position is 1Å
(1) 8.76 × 106 m/s (2) 5.76 × 105 m/s
(3) 5 × 10 –24 m/s (4) 1 × 1023 m/s
89. If the uncertainty in the position of electron is zero, the uncertainty in its momentum would be
(1) Zero (2) Greater than h
4π
(3) Less than h (4) Infinite
4π
90. If uncertainty in position and momentum are equal, then uncertainty in velocity is
(1) √
h (2) 1 √h
π 2m π
(3) √
h (4) 1 √h
2π m π
91. The radius of nucleus of 13Al27 will be :-
[R0 = 1.33 × 10 –15 m]
(1) 1.2 × 10 –15m (2) 2.7 × 10 –15m (3) 10.8 × 10 –15m (4) 4 × 10 –15m
92. The volume of nucleus is about :-
(1) 10 –4 times to that of an atom (2) 10 –15 times to that of an atom
(3) 10 –5 times to that of an atom (4) 10 –10 times to that of an atom
93. The ratio of specific charge of a proton and an α – particle is : –
(1) 2 : 1 (2) 1 : 2 (3) 1 : 4 (4) 1 : 1
94. Rutherford’s experiment on scattering of alpha particles showed for the first time that atom has :-
(1) Electrons (2) Protons (3) Nucleus (4) Neutrons
95. Rutherford's experiment on scattering of alpha particles showed for the first time that atom has:
(1) Electrons (2) Protons (3) Nucleus (4) Neutrons
96. Moles of O3 in its 12.044 × 1022 molecules of O3 will be :
(1) 2 mol (2) 0.4 mol (3) 1 mol (4) 0.2 mol
97. An element having mass number 64. Find out value of radius of nucleus of an element ?
(1) 5.32 × 10 –8 m (2) 5.32 × 10 –15 m
(3) 3.99 × 10 –15 m (4) 3.99 × 10 –8 m
98. Rutherford’s experiment which established the nuclear model of the atom used a beam of
(1)
(2)
(3)
(4)
99. Which orbital is represented by the complete wave function ψ 420 :-
(1) 4dz 2 (2) 3dz 2 (3) 4pz (4) 4s
100. The graph representing two nodes is :
(1) (2)
(3) (4)
