WO2023206986A1 - 碳化硅半导体器件及其制作方法 - Google Patents
碳化硅半导体器件及其制作方法 Download PDFInfo
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- H10D30/0291—Manufacture or treatment of FETs having insulated gates [IGFET] of double-diffused metal oxide semiconductor [DMOS] FETs of vertical DMOS [VDMOS] FETs
- H10D30/0297—Manufacture or treatment of FETs having insulated gates [IGFET] of double-diffused metal oxide semiconductor [DMOS] FETs of vertical DMOS [VDMOS] FETs using recessing of the gate electrodes, e.g. to form trench gate electrodes
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- H10D62/106—Constructional design considerations for preventing surface leakage or controlling electric field concentration for increasing or controlling the breakdown voltage of reverse-biased devices by having particular doping profiles, shapes or arrangements of PN junctions; by having supplementary regions, e.g. junction termination extension [JTE] having supplementary regions doped oppositely to or in rectifying contact with regions of the semiconductor bodies, e.g. guard rings with PN or Schottky junctions
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- H10D62/83—Semiconductor bodies, or regions thereof, of devices having potential barriers characterised by the materials being Group IV materials, e.g. B-doped Si or undoped Ge
- H10D62/832—Semiconductor bodies, or regions thereof, of devices having potential barriers characterised by the materials being Group IV materials, e.g. B-doped Si or undoped Ge being Group IV materials comprising two or more elements, e.g. SiGe
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- H10D62/102—Constructional design considerations for preventing surface leakage or controlling electric field concentration
- H10D62/103—Constructional design considerations for preventing surface leakage or controlling electric field concentration for increasing or controlling the breakdown voltage of reverse-biased devices
- H10D62/105—Constructional design considerations for preventing surface leakage or controlling electric field concentration for increasing or controlling the breakdown voltage of reverse-biased devices by having particular doping profiles, shapes or arrangements of PN junctions; by having supplementary regions, e.g. junction termination extension [JTE]
- H10D62/106—Constructional design considerations for preventing surface leakage or controlling electric field concentration for increasing or controlling the breakdown voltage of reverse-biased devices by having particular doping profiles, shapes or arrangements of PN junctions; by having supplementary regions, e.g. junction termination extension [JTE] having supplementary regions doped oppositely to or in rectifying contact with regions of the semiconductor bodies, e.g. guard rings with PN or Schottky junctions
Definitions
- the present application relates to the technical field of semiconductor devices, and more specifically, to a silicon carbide (SiC) semiconductor device and a manufacturing method thereof.
- SiC silicon carbide
- the main structure of electronic equipment to achieve various functions is integrated circuits, and semiconductor devices are important electronic components of integrated circuits.
- Silicon carbide semiconductor devices have become a major development direction in the semiconductor field due to their excellent characteristics in high-power applications.
- silicon carbide semiconductor devices are prone to breakdown problems in areas where the electric field is concentrated due to the existence of higher electric fields.
- this application provides a silicon carbide semiconductor device and a manufacturing method thereof.
- the scheme is as follows:
- a silicon carbide semiconductor device, the silicon carbide semiconductor device includes:
- a silicon carbide epitaxial layer having opposite first and second surfaces, the first surface including a gate region and source regions located on both sides of the gate region;
- a first voltage-resistant shielding structure formed in the silicon carbide epitaxial layer based on the first trench
- the gate structure has a metal gate on its surface
- the source region has a metal source on its surface
- a well region is provided in the first surface, and the well region is located between the first trench and the second voltage-withstanding shielding structure.
- the first voltage-withstanding shielding structure in the depth direction of the first trench, is located on a side of the well region facing the second surface and is connected to the well region. Zone no contact.
- the first trench is a first double-step trench
- the gate structure includes polysilicon filling the first trench, and there is a first insulating dielectric layer between the first trench and the filled polysilicon;
- the first voltage-withstanding shielding structure includes a doped region located in the sidewalls and the bottom surface of the first-level trench of the first double-level step trench facing the second surface.
- the depth of the well region relative to the first surface is less than the depth of the step between two levels of the first two-level step trench, and the first withstand voltage
- the shielding structure is located on a side of the first double-stepped trench where the step between the two-stepped trenches faces the second surface.
- the first trench is a first double-step trench; the first double-step trench is filled with polysilicon, and the first double-step trench is connected to the first double-step trench.
- the thickness of the insulating dielectric layer at the bottom of the first two-stage stepped trench is greater than the thickness of the insulating dielectric layer on the side walls of each stage of the first two-stage stepped trench, and is greater than that of the adjacent two stages.
- the silicon carbide semiconductor device there is a multi-level step trench in the surface of the source region; the multi-level step trench is filled with polysilicon, and the relationship between the multi-level step trench and the filled polysilicon is There is a second insulating dielectric layer between;
- the second voltage-withstanding shielding structure includes a doped region formed in the silicon carbide epitaxial layer based on the multi-level step trench.
- the first trench is a first two-level step trench; the multi-level step trench is a second two-level step trench, and the first two-level step trench is The depth is the same as the second double step trench.
- the first trench is a first double-step trench
- the multi-level step trench is a three-level step trench, and the depth of the three-level step trench is greater than the depth of the first two-level step trench.
- the second voltage-resistant shielding structure includes a doping region located in the silicon carbide epitaxial layer around sidewalls, steps, bottoms and openings of the multi-level step trench.
- the thickness of the second insulating dielectric layer at the bottom of the multi-level stepped trench is greater than the thickness of the second insulating layer on the side walls of each level of the multi-level stepped trench.
- the thickness of the dielectric layer is greater than the thickness of the second insulating dielectric layer on the step between two adjacent trenches.
- the second voltage-withstanding shielding structure is an ion implantation region formed in the source region.
- the implantation depth of the ion implantation region is not less than the depth of the first trench.
- This application also provides a method for manufacturing the silicon carbide semiconductor device described in any one of the above, the manufacturing method includes:
- An epitaxial wafer includes a silicon carbide epitaxial layer, the silicon carbide epitaxial layer has an opposite first surface and a second surface, the first surface includes a gate region and is located on both sides of the gate region The source region;
- a first voltage-withstanding shielding structure is formed in the silicon carbide epitaxial layer
- the first trench is a first double-step trench
- a multi-level step trench is formed in the surface of the source region
- the method of preparing the first voltage-resistant shielding structure and the second voltage-resistant shielding structure includes:
- the first double-level step trench is close to the first-level trench sidewall of the dielectric layer on the second surface. Ions are implanted into the sidewalls and bottom of the first-level trench to form the first voltage-withstanding shielding structure in the silicon carbide epitaxial layer at the sidewalls and bottom of the first-level trench near the second surface of the first double-step trench;
- ions are implanted at the bottom of the multi-level stepped trench, the steps of the trenches at each level, and the side walls.
- the second voltage-withstanding shielding structure is formed in the silicon carbide epitaxial layer of the sidewall.
- the first trench is a first two-level step trench; a multi-level step trench is formed in the surface of the source region; the first two-level step trench and the The multi-level step trenches are filled with polysilicon; the gate structure includes polysilicon filled in the first double-level step trench;
- the gate structure includes the first two-level step polysilicon filled in the trench;
- the metal gate is located on the surface of the polysilicon filled in the first double-level step trench; and the metal source is located on the surface of the polysilicon filled in the multi-level step trench.
- the thickness of the insulating dielectric layer at the bottom of the first double-step stepped trench is greater than the thickness of the insulating dielectric layer on the side walls of each level of the first double-step stepped trench.
- the thickness is greater than the thickness of the insulating dielectric layer on the step between two adjacent trenches;
- the thickness of the insulating dielectric layer at the bottom of the multi-level stepped trench is greater than the thickness of the insulating dielectric layer on the side walls of each level of the multi-level stepped trench, and is greater than the thickness between two adjacent levels of trenches.
- the thickness of the insulating dielectric layer on the step is greater than the thickness of the insulating dielectric layer on the side walls of each level of the multi-level stepped trench, and is greater than the thickness between two adjacent levels of trenches.
- the multi-level stepped trench is a second double-level stepped trench, and the second double-level stepped trench has the same depth as the first double-level stepped trench; or, the second double-level stepped trench has the same depth as the first double-level stepped trench.
- the multi-level step trench is a three-level step trench, and the depth of the three-level step trench is greater than the depth of the first two-level step trench.
- the method of forming the second voltage-resistant shielding structure includes:
- an ion implantation region is formed in the source region as the second withstand voltage shielding structure
- the implantation depth of the ion implantation region is not less than the depth of the first trench.
- the silicon carbide semiconductor device includes: a silicon carbide epitaxial layer, and the silicon carbide epitaxial layer has opposite first and second surfaces.
- the first surface includes a gate region and source regions located on both sides of the gate region; there is a first trench in the surface of the gate region; based on the first trench formed on the carbonization a first voltage-resistant shielding structure in the silicon epitaxial layer; a gate structure located in the first trench; a metal gate on the surface of the gate structure; and a second voltage-resistant shielding structure on the surface of the source region.
- the silicon carbide semiconductor device has a first voltage-resistant shielding structure formed in the silicon carbide epitaxial layer based on the first trench, and a second voltage-resistant shielding structure formed in the surface of the source region, which improves the first voltage-resistant shielding structure.
- the voltage resistance performance of the corner area at the bottom of the trench solves the problem of breakdown that is prone to occur in areas where the electric field is concentrated.
- Figure 1 is a schematic structural diagram of a DMOSFET
- Figure 2 is a schematic structural diagram of a UMOSFET
- Figure 3 is a schematic structural diagram of a silicon carbide semiconductor device provided by an embodiment of the present application.
- Figure 4 is a schematic structural diagram of another silicon carbide semiconductor device provided by an embodiment of the present application.
- Figure 5 is a schematic structural diagram of another silicon carbide semiconductor device provided by an embodiment of the present application.
- Figure 6 is a schematic structural diagram of another silicon carbide semiconductor device provided by an embodiment of the present application.
- FIGS. 7-29 are schematic flow charts of a method for manufacturing a silicon carbide semiconductor device provided by embodiments of the present application.
- SiC vertical power MOSFET devices mainly include lateral double-diffusion DMOSFET and vertical gate trench structure UMOSFET.
- Figure 1 is a schematic structural diagram of a DMOSFET, including: an n+ (n-type heavily doped) substrate 2; an n- (n-type lightly doped) drift region 3 provided on the surface of the substrate 2 ; The p-type well region 4 located in the drift region 3; and the source region 5 located within the p-type well region.
- the source region 5 includes an n+ doped region 51 and a p+ (p-type heavily doped) doped region 52.
- a gate dielectric layer 7 is provided on the surface of the drift region 3
- a gate electrode 8 is provided on the surface of the gate dielectric layer 7 .
- the side surface of the substrate 2 facing away from the drift region 3 has a drain electrode 1 .
- the DMOSFET structure adopts planar diffusion technology, using refractory materials such as polysilicon gates as masks, and uses the edges of the polysilicon gates to define the p base region and n+ source region.
- refractory materials such as polysilicon gates as masks
- the name DMOS comes from this double diffusion process.
- the surface channel region is formed by utilizing the side diffusion difference between the p-type base region and the n+ source region.
- Figure 2 is a schematic structural diagram of a UMOSFET.
- the difference from the structure shown in Figure 1 is that a U-shaped groove is provided in the UMOSFET.
- the surface of the U-shaped groove is covered with a gate dielectric layer 7, and the gate 8 is filled with in the U-shaped groove.
- the vertical gate trench structure UMOSFET is named after the U-shaped trench structure.
- the U-shaped trench structure is formed in the gate region using reactive ion etching.
- the U-shaped trench structure has a high channel density (channel density is defined as the channel width of the active area), which significantly reduces the on-state characteristic resistance of the device.
- SiC UMOSFET still has several problems in actual process manufacturing and application:
- the thickness of the silicon dioxide layer at the bottom of the trench is often thin during the high-temperature furnace tube oxidation process of a single rectangular or U-shaped gate trench, which reduces the voltage withstand capability of the trench bottom and the device. reliability.
- the technical solution of the present application provides a silicon carbide semiconductor device with a first voltage-withstanding shielding structure formed in the silicon carbide epitaxial layer based on the first trench, and in the surface of the source region A second withstand voltage shielding structure is formed, which improves the withstand voltage performance of the corner area at the bottom of the first trench, solves the problem of breakdown that is prone to occur in areas where electric fields are concentrated, and improves the device's ability to withstand static electricity in harsh environments and to withstand high voltages in the circuit. Spike tolerance.
- the first voltage-withstanding shielding structure can be formed based on the first trench, which can increase the ion implantation depth when forming the first voltage-withstanding shielding structure, and facilitate the implementation of various trench gate protection structures and anti-surge designs in terms of technology.
- a thicker insulating dielectric layer can be formed at the bottom of the trench, which solves the problem that the conventional high-temperature furnace tube oxidation process cannot form a thicker silicon dioxide layer in the trench, further improving the resistance of the trench bottom. pressure capability and device reliability.
- Figure 3 is a schematic structural diagram of a silicon carbide semiconductor device provided by an embodiment of the present application.
- the silicon carbide semiconductor device includes:
- Silicon carbide epitaxial layer 11 the silicon carbide epitaxial layer 11 has opposite first surfaces and second surfaces, the first surface includes a gate region and source regions located on both sides of the gate region;
- the first voltage-withstanding shielding structure 13 formed in the silicon carbide epitaxial layer 11 based on the first trench 12;
- the gate structure g located in the first trench 12;
- the gate structure has a metal gate G on its surface
- the well region W is located between the first trench 12 and the second voltage-withstanding shielding structure 14 .
- the silicon carbide semiconductor device has a first voltage-resistant shielding structure 13 formed in the silicon carbide epitaxial layer 11 based on the first trench 12, and a second voltage-resistant shielding structure 14 formed in the surface of the source region,
- the voltage resistance performance of the corner area at the bottom of the first trench 12 is improved, the problem of breakdown that is prone to occur in areas where the electric field is concentrated is solved, and the device's ability to withstand static electricity in harsh environments and to withstand high-voltage spikes in the circuit is improved.
- the first voltage-withstanding shielding structure 13 can be formed based on the first trench 12, which can increase the ion implantation depth when forming the first voltage-withstanding shielding structure 13, and facilitate the realization of a variety of trench gate protection structures and wave resistance in the process. Yong design.
- a thicker insulating dielectric layer can be formed at the bottom of the trench, which solves the problem that the conventional high-temperature furnace tube oxidation process cannot form a thicker silicon dioxide layer in the trench, further improving the resistance of the trench bottom. pressure capability and device reliability.
- the silicon carbide epitaxial layer 11 is prepared on the surface of the semiconductor substrate 10 , and the second surface faces the semiconductor substrate 10 .
- a metal drain D is provided on the surface of the semiconductor substrate 10 away from the silicon carbide epitaxial layer 11 .
- the metal source S and the metal drain D can be Ti or Al, etc., and the metal drain D can be one or a composite metal layer of Ni, Ti, Al or Ag.
- the silicon carbide epitaxial layer 11 and the semiconductor substrate 10 have the same doping type
- the well region W, the first voltage-withstanding shielding structure 13 and the second voltage-withstanding shielding structure 14 have the same doping type, and are opposite to the doping type of the epitaxial layer 11 .
- P-type doping and N-type doping are opposite types of doping.
- the silicon carbide epitaxial layer 11 close to the first surface of the well region W has an ion implantation region 17 with a doping type opposite to that of the well region W.
- the ion implantation region 17 can be N+ ion implantation. area.
- the semiconductor substrate 10 can be an N+ (N-type heavily doped) silicon carbide substrate; the epitaxial layer 11 is an N- (N-type lightly doped) silicon carbide epitaxial layer, serving as a drift region of the semiconductor device; the well region W is P Well area.
- the first voltage-withstanding shielding structure 13 and the second voltage-withstanding shielding structure 14 include P+ (P-type heavily doped) ion implantation regions. It should be noted that in the embodiments of the present application, the doping types of each region of the device are not limited to those described in the embodiments. The doping types can be set based on requirements to form a PMOS or NMOS structure.
- the first voltage-withstanding shielding structure 13 is located on the side of the well region W facing the second surface, and has no contact with the well region W. That is to say In the vertical direction of FIG. 3 , the first voltage-withstanding shielding structure 13 is located below the well region W and has no contact with the well region W.
- the first trench 12 is a first double-step trench;
- the gate structure g includes polysilicon filling the first trench 12 , and the first trench 12 and
- the first voltage-withstanding shielding structure 13 includes a sidewall surface of a first-level trench located in the first double-level step trench facing the second surface. and doped regions within the bottom surface.
- the first insulating dielectric layer 151 is a gate oxide layer, which may be silicon dioxide.
- the first two-level stepped trench has two-level trenches and a step structure located between the two-level trenches.
- One level of the first two-level stepped trench is close to the first surface and the other level is close to the second surface.
- the opening of the primary trench close to the first surface is larger than the opening of the primary trench close to the second surface.
- ion implantation is performed into the first double-level step trench to form the first voltage-resistant shielding structure 13, thereby avoiding ion implantation
- ions are implanted into the first-level trench sidewall of the first double-level step trench close to the first surface, so that the first voltage-withstanding shielding structure 13 is located below the well region W to avoid contact between the two, thereby avoiding
- the resulting abnormal channel opening problem of semiconductor devices ensures the normal operation of the device.
- the first insulating dielectric layer 151 extends to the outside of the first trench 12 and covers the first surface.
- the first insulating dielectric layer 151 has an opening on the first surface for disposing the metal ohmic contact layer 18 .
- the source metal S is connected to the silicon carbide epitaxial layer 11 at the opening through the metal ohmic contact layer 18 .
- the depth of the well region W relative to the first surface is less than the depth of the step between the two-level trenches in the first double-level step trench, and the first voltage-withstanding shielding structure 13 is located on the first double-level step trench.
- the step between two stepped grooves faces the side of the second surface.
- the multi-level stepped trench 16 in the surface of the source region; the multi-level stepped trench 16 is filled with polysilicon, and the multi-level stepped trench 16 is in contact with the filled polysilicon.
- the second insulating dielectric layer 152 in between; the second withstand voltage shielding structure 14 includes a doped region formed in the silicon carbide epitaxial layer 11 based on the multi-level step trench.
- the first insulating dielectric layer 151 on the surface of the first trench 12 and the second insulating dielectric layer 152 on the surface of the multi-step trench 16 are made of the same material and are formed at the same time.
- the polysilicon filled in the first trench 12 and the polysilicon filled in the multi-level stepped trench 16 are formed simultaneously.
- the second voltage-withstanding shielding structure 14 includes a doped region in the silicon carbide epitaxial layer 11 located around the sidewalls, steps, bottoms and openings of the multi-level step trench 16. That is to say, the multi-level steps
- the second voltage-withstanding shielding structure 14 is disposed in the sidewalls, steps, and bottom of the trench 16 and in the silicon carbide epitaxial layer around the opening.
- the first trench 12 is a first double-step trench; the multi-step trench 16 is a second double-step trench.
- the first double-step trench The depth of the second double step trench is the same, and both can be prepared in the same process flow.
- the multi-level step trench 16 is not limited to a double-level step trench, but may also be a step trench with more than 2 levels.
- the number of trench steps of the multi-step trench 16 can be set based on device thickness parameters and ion implantation depth requirements.
- the silicon carbide semiconductor device may be a silicon carbide MOSFET device.
- a trench gate is formed in the gate region based on the first trench 12
- a trench source is formed in the source regions on both sides of the gate region based on the multi-step trench 16 .
- Both the first trench 12 and the multi-level stepped trench 16 may be double-level stepped trenches.
- a silicon carbide MOSFET device with a double-level stepped trench structure is formed.
- Figure 4 is a schematic structural diagram of another silicon carbide semiconductor device provided by an embodiment of the present application.
- the first trench 12 is a first Double-level step trench
- the multi-level step trench 16 is a three-level step trench, and the depth of the three-level step trench is greater than the depth of the first two-level step trench.
- FIG. 5 is a schematic structural diagram of another silicon carbide semiconductor device provided by an embodiment of the present application.
- the first trench 12 is a first two-level step trench. groove; the first double-level step trench is filled with polysilicon, the gate structure g includes polysilicon filling the first double-level step trench, the first double-level step trench and the filled polysilicon
- the thickness of the first insulating dielectric layer 151 at the bottom of the first double-step trench is greater than that of the first double-step trench.
- the thickness of the first insulating dielectric layer 151 on the sidewalls of the trenches at each level is greater than the thickness of the first insulating dielectric layer 151 on the steps between the adjacent two levels of trenches.
- the thickness of the second insulating dielectric layer 152 at the bottom 16 of the multi-level stepped trench is greater than the thickness of the second insulating dielectric layer 152 on the sidewalls of each level of the multi-level stepped trench 16 .
- the thickness of the insulating dielectric layer 152 is greater than the thickness of the second insulating dielectric layer 152 on the step between two adjacent trenches.
- the second insulating dielectric layer 152 and the first insulating dielectric layer 151 are the same insulating dielectric layer 15 .
- the thickness of the first insulating dielectric layer 151 and the second insulating dielectric layer 152 at the bottom of the trench can be greater than the thickness of other areas of the trench.
- the silicon carbide semiconductor device described in the embodiment of the present application can form a trench gate based on the first trench 12 in the gate region, and form a trench source based on the multi-step trenches 16 in the source region on both sides of the gate region. , and form a first voltage-resistant shielding structure 13 at the bottom of the first trench 12 through ion implantation, passing through the bottom and side walls of the multi-level stepped trench 16 and the silicon carbide epitaxial layer 11 of the steps between the two-level trenches. Ion implantation forms the second voltage-resistant shielding structure 14 .
- both the first voltage-withstanding shielding structure 13 and the second voltage-withstanding shielding structure 14 may be P+ (P-type heavily doped) regions.
- the first voltage-withstanding shielding structure 13 and the second voltage-withstanding shielding structure 14 are formed by ion implantation in the silicon carbide epitaxial layer 11 respectively, thereby solving the problem of carbonization. It is difficult to form a deep P+ masking layer in silicon material and the damage problem of high-dose and high-energy P+ ion implantation improves the reliability of the device and can better shield and protect the gate trench.
- a silicon dioxide layer is grown on the surface of the first trench 12 and the multi-level step trench 16 as the first insulating dielectric layer 151 and the second insulating layer 151.
- the dielectric layer 152 is then filled with polysilicon in the first trench 12 and the multi-level step trench 16, and then a metal electrode is formed to complete a silicon carbide MOSFET device with a double-level step trench structure.
- the second voltage-withstanding shielding structure 14 is an ion implantation region formed in the source region.
- the implantation depth of the ion implantation region is not less than the depth of the first trench 12 .
- another embodiment of the present application also provides a method for manufacturing a silicon carbide semiconductor device, which is used to manufacture the silicon carbide semiconductor device described in the above embodiment.
- the manufacturing method can be as shown in Figures 7 to 29 Show.
- Figures 7 to 29 are schematic flow diagrams of a method for manufacturing a silicon carbide semiconductor device provided by an embodiment of the present application.
- the manufacturing method includes:
- Step S11 As shown in FIG. 7, an epitaxial wafer is provided.
- the epitaxial wafer includes a silicon carbide epitaxial layer 11.
- the silicon carbide epitaxial layer 11 has an opposite first surface and a second surface.
- the first surface includes a gate. electrode region and source regions located on both sides of the gate region.
- the silicon carbide semiconductor device may be prepared using an N+ silicon carbide semiconductor substrate 10 having an N-silicon carbide epitaxial layer 11 . Wherein, the second surface of the silicon carbide epitaxial layer 11 faces the semiconductor substrate 10 .
- Step S12 As shown in Figures 8 to 16, form a first trench 12 in the gate region.
- the well region W, the ion implantation region 17 and the electric field buffer region 19 are formed in the silicon carbide epitaxial layer 11 by performing ion implantation on the first surface.
- the ion implantation region 17 and the electric field buffer region 19 are located within the surface of the source region and within the well region W.
- the manufacturing method is described by taking the source region having multi-level step trenches 16 as an example.
- the subsequent process forms the second voltage-withstanding shielding structure 14 based on the multi-level step trenches 16 .
- the electric field buffer 19 can solve the leakage and breakdown problems caused by the thin thickness of the second voltage-withstanding shielding structure 14 at the opening position of the multi-level stepped trench 16, thereby enhancing the manufacturability and reliability of the device.
- the doping type of the electric field buffer region 19 and the second withstand voltage shielding structure 14 is the same, for example, both can be N+ doped.
- the doping types of the ion implantation region 17 and the second withstand voltage shielding structure 14 are opposite, and the ion implantation region 17 may be an N+ doped region.
- the second double-step trench can be formed while forming the first double-step trench.
- the specific process of forming the first double-step trench and the second double-step trench is as follows:
- Step S121 As shown in FIG. 8 , a well region W, an ion implantation region 17 and an electric field buffer region 19 located in the well region are formed on the first surface through ion implantation.
- ion implantation is generally carried out through high-temperature ion implantation equipment at 500-600°C to reduce damage to the crystal lattice of the silicon carbide material.
- Step S122 As shown in Figure 12, perform first-level trench etching on the first surface.
- a plasma dry etching process such as RIE or ICP etching process, can be used to etch to form the first-level trench.
- the etching principle of silicon carbide materials is shown in Figures 9-11.
- SiO 2 is deposited on the silicon carbide material as a mask layer through a deposition process such as CVD, and the photoresist PR is spin-coated on the surface of the mask layer.
- the photoresist PR with the required pattern is formed through exposure and development, and then as shown in the figure As shown in Figure 10, based on the patterned photoresist PR, the mask layer is etched to form a patterned mask layer.
- the silicon carbide material is etched. Grooves form on its surface. Common semiconductor processes such as photolithography and etching will not be described in detail in subsequent processes.
- a layer of SiO 2 can be deposited by CVD as the mask layer 21, using gases containing F groups such as CF 4 and SF 6 , or gases containing Cl groups such as chlorine.
- Gas, and a mixed gas of Ar and oxygen use plasma etching equipment ICP or RIE to etch the silicon carbide epitaxial layer 11 in the gate region and the source regions on both sides, so that in the gate region and The source regions respectively form first-level trenches.
- the depth of the first-level trench is 10nm-3 ⁇ m. Further, the depth of the first-level trench can be set to 800nm-1um, so that the device has better performance.
- Step S123 As shown in Figure 13, fill the first-level trench with SiO2 dielectric layer 22.
- the SiO 2 dielectric layer 22 may be deposited using a CVD process.
- the SiO 2 dielectric layer 22 fills the first level trench and covers the mask layer 21 .
- Step S124 As shown in Figure 14, the mask 23 of the second-level trench is aligned.
- a photoresist is spin-coated on the surface of the SiO 2 dielectric layer 22 , and the photoresist is exposed and developed based on the mask 23 to pattern the photoresist.
- the photoresist is not shown in FIG. 14 .
- the mask 23 has a first hollow region and a second hollow region, the first hollow region is used to form a second-level trench of the trench gate in the gate region, and the second hollow region is used to form a second-level trench in the source region.
- the opening of the first hollow region is smaller than the opening of the first-level trench in the gate region, and the opening of the second hollow region is larger than the opening of the first-level trench in the source region.
- Step S125 As shown in Figure 15, etching is performed based on the photoresist on the surface of the SiO2 dielectric layer 22, and second-level trenches are formed based on the first-level trenches in the gate region and the source region.
- F-based gases such as CF 4 and SF 6 , or Cl-based gases such as chlorine, and a mixed gas of Ar and oxygen, through plasma etching equipment ICP or RIE, in the gate area and on both sides.
- the silicon carbide epitaxial layer 11 is etched to form second-level trenches in the gate region and the source region respectively.
- the etching depth of the second-level trench is 100nm-3um; further, the etching depth of the second-level trench can be set to 300-500nm, so that the device has better performance.
- a second-level trench with a greater depth can be etched at the bottom of the first-level trench in the gate region, thereby forming a second-level trench.
- a double step trench Based on this method, while forming the first double-level step trench in the gate region, it is also possible to form the first double-level step trench close to the first-level trench on the first surface.
- the SiO 2 dielectric layer 22 is retained on the sidewall as a sacrificial layer to avoid scattering of ions on the first-level trench sidewall of the first double-level step trench close to the first surface when the first voltage-withstanding shielding structure 13 is formed in the subsequent process. problem, solve the abnormal channel opening problem caused by this, ensure the normal operation of the device, and improve the reliability of the device.
- the opening of the second hollow region is larger than the opening of the first-level trench in the source region, when etching downward, the size of the upper part of the first-level trench increases and the depth of the lower part increases, thereby forming a second-level trench.
- Double step trench Based on this method, the SiO 2 dielectric layer 22 on the sidewalls, steps and bottom surface of the second double-level step trench can be removed.
- ions are implanted to facilitate the formation of the second double-level step trench in the source region. Ions are implanted into the sidewalls, steps and bottom of the silicon carbide epitaxial layer 11 of the two-step trench to form a second voltage-withstanding shielding structure 14 .
- Figure 16 is an SEM image of a double step trench formed in the source region and the gate region based on the manufacturing method described in the embodiment of the present application. Based on the SEM image, it can be seen that using the method described in the embodiment of the present application The manufacturing method can form double-step trenches with good morphology in the gate region and the source region respectively.
- Step S13 As shown in FIGS. 17 to 20 , based on the first trench, form a first voltage-withstanding shielding structure 13 in the silicon carbide epitaxial layer.
- second voltage-withstanding shielding structure 14 in the surface of the source region; there is a well region W in the first surface, and the well region W is located between the first trench 12 and the second voltage-withstanding shielding structure. between 14.
- the first trench 12 is a first two-level stepped trench; a multi-level stepped trench 16 is formed in the surface of the source region; the first voltage-resistant shielding structure 13 and the second voltage-resistant shielding structure 13 are prepared.
- the method of masking the structure 14 includes: based on the first double-level step trench and the dielectric layer 22 of the first double-level step trench close to the sidewall of the first-level trench on the first surface, Ion implantation is performed on the sidewalls and bottom of the first-level trench close to the second surface, and the silicon carbide epitaxial layer is formed in the sidewalls and bottom of the first-level trench of the first double-step trench close to the second surface.
- the first voltage-resistant shielding structure 13 based on the multi-level step trench 16, ions are implanted at the bottom of the multi-level step trench 16, the steps and side walls of each level trench, and in the multi-level step trench 16
- the second voltage-withstanding shielding structure 14 is formed in the silicon carbide epitaxial layer at the bottom of the trench, the steps of the trench at each level, and the sidewalls.
- the multi-level step trench 16 can be set as a second double-level step trench, and the second double-level step trench has the same depth as the first double-level step trench; in other ways, all the steps can be set.
- the multi-step trench 16 is a three-step trench, and the depth of the three-step trench is greater than the depth of the first two-step trench.
- step S13 first, as shown in FIG. 17 , ion implantation is performed based on the patterned mask layer 21 and dielectric layer 22 to form the first voltage-resistant shielding structure 13 and the second voltage-resistant shielding structure 14 .
- High-temperature ion implantation equipment can be used to perform P+ ion implantation on the sidewalls and bottom of the trench at 500-600°C to form the first voltage-resistant shielding structure 13 and the second voltage-resistant shielding structure 14, and then remove them as shown in Figure 18
- the buffered HF wet method can be used to remove the silicon dioxide mask, thereby removing the mask layer 21 and the dielectric layer 22.
- the typical implanted ions are Al ions; the ion implantation energy can be from a few hundred KeV to several MeV, the dose is 1E12cm -2 -1E16cm -2 ; the implantation depth is a few hundred nm to a few microns .
- the first double-level step trench serves as the well region W of the channel region and will not be affected by P+ ion implantation.
- Figure 19 is an SEM image after forming the first voltage-resistant shielding structure 13 and the second voltage-resistant shielding structure 14 using the manufacturing method of the embodiment of the present application. Based on Figure 19, it can be seen that after the P+ ion implantation is completed, as a trench The well region W in the channel region will not be affected by P+ ion implantation, which improves the reliability and stability of the device.
- Figure 20 is an SEM image of the source region before and after P+ ion implantation using the manufacturing method of the embodiment of the present application.
- the picture on the left is an SEM image of the area corresponding to the second double-step trench before P+ ion implantation.
- the picture on the right is an SEM image of the area corresponding to the second double-step trench after P+ ion implantation.
- the smaller gray area in the picture on the right is an SEM slice image formed after Al ion implantation.
- the trench gate adopts a first two-level step trench.
- the first two-level step trench can be formed while retaining the dielectric on the side wall of the first-level trench close to the first surface.
- Layer 22 therefore, when performing ion implantation on the first two-level step trench, P+ ions can be implanted at the bottom and sidewalls of the first-level trench close to the second surface, while avoiding ion implantation at the first-level trench close to the first surface.
- the sidewalls of the first-level trench are doped by P+ ion scattering, which solves the problem of abnormal channel opening of subsequent trench MOSFETs.
- Step S14 As shown in Figures 21 to 23, form a gate structure g in the first trench;
- the first trench 12 is a first double-step trench; a multi-step trench 16 is formed in the surface of the source region; the first double-step trench and the multi-step trench are filled with polysilicon; the gate structure g includes polysilicon filled in the first double-level step trench; between the first double-level step trench and the filled polysilicon, the multi-level step There is an insulating dielectric layer 15 between the trench 16 and the filled polysilicon; the gate structure g includes the polysilicon filled in the first double-step trench.
- the part of the insulating dielectric layer 15 located in the first trench 12 is the first insulating dielectric layer 151 , which serves as the gate dielectric layer of the trench gate.
- the part located in the multi-step trench 16 is the second insulating dielectric layer 152 .
- an insulating dielectric layer 15 is formed covering the first surface and the surface of the first trench 12 and the multi-level stepped trench 16.
- the insulating dielectric layer in the first trench 12 serves as a trench.
- the insulating dielectric layer 15 is a SiO2 layer.
- the insulating dielectric layer 15 can be grown in a high-temperature furnace tube. Oxygen can be introduced into the high-temperature furnace tube at 1100°C-1350°C.
- the first trench 12 and the multi-step trench 16 SiO2 is oxidized and grown to form an insulating dielectric layer 15.
- the thickness of the insulating dielectric layer 15 may be 40-70 nm.
- the first trench 12 and the multi-level stepped trench 16 are filled with polysilicon.
- silane or DCS gas and Ar, and doping gases containing phosphorus or B, phosphane, borane, etc. are passed into the LPCVD furnace tube; polysilicon is generated after the chemical cracking reaction, and the thickness of the polysilicon can be 400nm. to several um thickness.
- a mixed gas of HBr, chlorine and oxygen is used to etch the polysilicon to remove the polysilicon on the first surface.
- Step S15 As shown in Figures 24 and 25, form a metal gate on the surface of the gate structure g, form a metal source on the surface of the source region, and form silicon carbide as shown in Figure 3 Semiconductor device.
- the metal gate G is located on the surface of the polysilicon filled in the first two-level step trench; the metal source S is located on the surface of the polysilicon filled in the multi-level step trench 16 .
- step S15 first, as shown in FIG. 24, the insulating dielectric layer 15 on the first surface is etched to form an opening exposing the first surface.
- F-based gases such as CHF 3 and CF 4 or chlorine-based gases containing Cl can be used to etch the first insulating dielectric layer 15 in the preset area on the surface of the source region to form the required openings.
- a metal ohmic contact layer 18 is formed in the opening area of the first insulating dielectric layer 15 to reduce the contact resistance between the metal source S and the first surface.
- PVD deposition of a single layer of Ni or multi-layer metal PVD deposition of Ti/Ni/Al can be carried out in the source area, and the metal except the source area can be stripped or etched away, and then carried out at 900°C-1100°C Rapid thermal annealing, the annealing time can be 30 seconds to 5 minutes, to form the metal ohmic contact layer 18 .
- a metal gate G is formed on the surface of the trench gate, a metal source S is formed on the surface of the trench source, and a metal drain D is formed on the surface of the semiconductor substrate 10 away from the silicon carbide epitaxial layer 11, as shown in Figure 3 Silicon carbide semiconductor device shown.
- the subsequent metal processes such as gate and source electrodes, the metal processes of the passivation layer and polyimide PI glue, and the back drain electrode are all conventional process methods and will not be described again.
- the first trench 12 is a first double-step trench, and the source region has a second double-step trench.
- the carbonization shown in FIG. 3 can be produced. Silicon semiconductor devices.
- P+ ions are implanted into the bottom of the first double-stage step trench, it is avoided that the conventional single-stage trench design is used to implant P+ ions due to the scattering of the mask and the trench sidewalls, causing the upper sidewalls of the trench to be implanted.
- a silicon carbide MOSFTE device with a double-step trench structure can be formed, and a double-step trench can be formed in the gate region and the source regions on both sides.
- the gate region has a first two-level step trench for forming a trench gate
- the source region has a second two-level step trench for forming a trench source.
- a first voltage-resistant shielding structure 13 is formed at the bottom of the first-level trench near the second surface of the first double-level step trench and in the silicon carbide epitaxial layer 11 in the sidewall.
- the sidewalls of the trenches at each level, and the second voltage-resistant shielding structure 14 is formed in the silicon carbide epitaxial layer 11 of each step.
- the shielding layer problem solves the damage caused by high-dose and high-energy P+ ion implantation and the resulting reliability problems, and can achieve better shielding and protection of the trench gate.
- a trench source structure is formed based on the double-step trench in the source area, which can easily realize the injection of a P+ electric field shielding structure with a depth of 1-2um or more in the source area, which can provide good shielding and Protect the sidewalls and bottom of the trench gate and enhance the gate reliability of silicon carbide MOSFET devices.
- the silicon carbide semiconductor device and the manufacturing process of the double-level step trench structure can also be extended to the solution of the multi-level step trench structure to achieve a deeper P+ ion implantation distribution depth and better control of the gate area.
- electric field shielding protection and can form a semi-superjunction structure. Therefore, in order to form newer P+ ion implantation in the source region and form a deeper second withstand voltage shielding structure 14 in the source region, a three-level step trench can be formed in the source region to form a deeper P+ shield in the source region.
- the method of forming the second voltage-resistant shielding structure 14 includes: using an ion implantation method to form an ion implantation region in the source region as the second voltage-resistant shielding structure 14; the ion implantation region The implantation depth is not less than the depth of the first trench.
- This method can form a silicon carbide semiconductor device as shown in Figure 6.
- a double-step trench structure is formed only in the gate region, and high-energy and high-dose P+ ion implantation is directly used in the source region to form the second voltage-withstanding shielding structure 14, which forms the electric field shielding and shielding of the trench gate.
- protection and process methods please refer to the process flow of the device structure shown in Figure 3, which will not be described again in the embodiments of this application.
- the thickness of the insulating dielectric layer 15 at the bottom of the first double-step trench can be set to be greater than the thickness of the insulating dielectric layer 15 on the side walls of each level of the first double-step trench.
- the thickness is greater than the thickness of the insulating dielectric layer 15 on the step between adjacent two-level trenches; the thickness of the insulating dielectric layer 15 at the bottom of the multi-level stepped trench 16 is greater than the thickness of the multi-level stepped trench.
- the thickness of the insulating dielectric layer 15 on the sidewalls of the trenches at each level in 16 is greater than the thickness of the insulating dielectric layer 15 on the steps between the adjacent two levels of trenches, thereby forming silicon carbide as shown in Figure 5 Semiconductor device.
- the process and structure can be further selectively optimized.
- first use The CVD process of forming SiO 2 fills the trenches in the gate region and the source region, and then uses a gas ICP or RIE plasma etching process with a high selectivity for SiO 2 :SiC to etch back the trenches and the SiO 2 on the first surface.
- the SiO 2 layer 31 is filled in both the gate region and the double step trench in the source region.
- a relatively dense furnace tube thermal oxidation layer process can be used, such as TEOS or HTO thermal oxidation silicon dioxide process.
- SiH 4 or DCS gas reacts with NO or O2 to deposit a relatively dense layer on the surface of the double-step trench.
- SiO 2 layer 31 is filled in both the gate region and the double step trench in the source region.
- the SiO 2 layer 31 on the first surface and the SiO 2 layer 31 in the double-step trench are etched away, leaving the preset thickness of SiO 2 in the first-level trench close to the second surface side.
- Plasma etching process can be used to select a gas with a high etching selectivity ratio for SiO 2 : SiC, such as C 4 F 8 , etc., to etch back, retaining the preset thickness at the bottom of the first-level trench close to the second surface side SiO 2 layer 31.
- a SiO2 layer is grown on the first surface and the surface of the two double-step trenches.
- oxygen is introduced into the high-temperature furnace tube to grow SiO2 with a thickness of 40-70nm. .
- This SiO 2 layer forms the insulating dielectric layer 15 together with the SiO 2 layer 31 remaining at the bottom of the previous trench.
- a thicker insulating dielectric layer 15 can be formed at the bottom of the trench, which can further increase the voltage resistance of the bottom of the trench gate of the device and further improve the reliability of the device.
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Abstract
Description
Claims (18)
- 一种碳化硅半导体器件,其特征在于,所述碳化硅半导体器件包括:碳化硅外延层,所述碳化硅外延层具有相对的第一表面和第二表面,所述第一表面包括栅极区域以及位于所述栅极区域两侧的源极区域;所述栅极区域的表面内具有第一沟槽;基于所述第一沟槽形成在所述碳化硅外延层内的第一耐压掩蔽结构;位于所述第一沟槽内的栅极结构;所述栅极结构的表面上具有金属栅极;所述源极区域的表面内具有第二耐压掩蔽结构;所述源极区域的表面上具有金属源极;所述第一表面内具有阱区,所述阱区位于所述第一沟槽与所述第二耐压掩蔽结构之间。
- 根据权利要求1所述的碳化硅半导体器件,其特征在于,在所述第一沟槽的深度方向上,所述第一耐压掩蔽结构位于所述阱区朝向所述第二表面的一侧,且与所述阱区无接触。
- 根据权利要求1所述的碳化硅半导体器件,其特征在于,所述第一沟槽为第一双级台阶沟槽;所述栅极结构包括填充所述第一沟槽的多晶硅,所述第一沟槽与所填充的多晶硅之间具有第一绝缘介质层;所述第一耐压掩蔽结构包括位于所述第一双级台阶沟槽朝向所述第二表面的一级沟槽侧壁表面内以及底部表面内的掺杂区域。
- 根据权利要求3所述的碳化硅半导体器件,其特征在于,所述阱区相对于所述第一表面的深度小于所述第一双级台阶沟槽中两级沟槽之间台阶的深度,所述第一耐压掩蔽结构位于所述第一双级台阶沟槽中两级沟槽之间台阶朝向所述第二表面的一侧。
- 根据权利要求1所述的碳化硅半导体器件,其特征在于,所述第一沟槽为第一双级台阶沟槽;所述第一双级台阶沟槽内填充有多晶硅,所述第一双级台阶沟槽与所填充的多晶硅之间具有第一绝缘介质层;所述第一双级台阶沟槽底部的所述绝缘介质层的厚度大于所述第一双级台阶沟槽中各级沟槽侧壁上的所述绝缘介质层的厚度,大于相邻两级沟槽之间台阶上的所述绝缘介质层的厚度。
- 根据权利要求1所述的碳化硅半导体器件,其特征在于,所述源极区域的表面内具有多级台阶沟槽;所述多级台阶沟槽内填充有多晶硅,所述多级台阶沟槽与所填充的多晶硅之间具有第二绝缘介质层;所述第二耐压掩蔽结构包括基于所述多级台阶沟槽形成在所述碳化硅外延层内的掺杂区域。
- 根据权利要求6所述的碳化硅半导体器件,其特征在于,所述第一沟槽为第一双级台阶沟槽;所述多级台阶沟槽为第二双级台阶沟槽,所述第一双级台阶沟槽与所述第二双级台阶沟槽的深度相同。
- 根据权利要求6所述的碳化硅半导体器件,其特征在于,所述第一沟槽为第一双级台阶沟槽;所述多级台阶沟槽为三级台阶沟槽,所述三级台阶沟槽的深度大于所述第一双级台阶沟槽的深度。
- 根据权利要求6所述的碳化硅半导体器件,其特征在于,所述第二耐压掩蔽结构包括位于所述多级台阶沟槽的侧壁、台阶、底部以及开口四周的碳化硅外延层内的掺杂区域。
- 根据权利要求6所述的碳化硅半导体器件,其特征在于,所述多级台阶沟槽底部的所述第二绝缘介质层的厚度大于所述多级台阶沟槽中各级沟槽侧壁上的所述第二绝缘介质层的厚度,大于相邻两级沟槽之间台阶上的所述第二绝缘介质层的厚度。
- 根据权利要求1所述的碳化硅半导体器件,其特征在于,所述第二耐压掩蔽结构为形成在所述源极区域内的离子注入区域。
- 根据权利要求11所述碳化硅半导体器件,其特征在于,所述离子注入区域的注入深度不小于所述第一沟槽的深度。
- 一种如权利要求1-12任一项所述碳化硅半导体器件的制作方法,其特征在于,所述制作方法包括:提供一外延片,所述外延片包括碳化硅外延层,所述碳化硅外延层具有相对的第一表面和第二表面,所述第一表面包括栅极区域以及位于所述栅极区域两侧的源极区域;在所述栅极区域形成第一沟槽;基于所述第一沟槽,在所述碳化硅外延层内形成第一耐压掩蔽结构;在所述第一沟槽内形成栅极结构;在所述栅极结构的表面上形成金属栅极,在所述源极区域的表面上形成金属源极;其中,所述源极区域的表面内具有第二耐压掩蔽结构;所述第一表面内具有阱区,所述阱区位于所述第一沟槽与所述第二耐压掩蔽结构之间。
- 根据权利要求13所述的制作方法,其特征在于,所述第一沟槽为第一双级台阶沟槽;在所述源极区域表面内形成有多级台阶沟槽;制备所述第一耐压掩蔽结构和所述第二耐压掩蔽结构的方法包括:基于所述第一双级台阶沟槽以及第一双级台阶沟槽靠近第一表面一级沟槽侧壁的介质层,对所述第一双级台阶沟槽靠近所述第二表面的一级沟槽的侧壁以及底部进行离子注入,在第一双级台阶沟槽靠近第二表面的一级沟槽侧壁和底部的碳化硅外延层内形成所述第一耐压掩蔽结构;基于所述多级台阶沟槽,在所述多级台阶沟槽的底部、各级沟槽的台阶以及侧壁进行离子注入,在所述多级台阶沟槽的底部、各级沟槽的台阶以及侧壁的碳化硅外延层内形成所述第二耐压掩蔽结构。
- 根据权利要求13所述的制作方法,其特征在于,所述第一沟槽为第一双级台阶沟槽;所述源极区域的表面内形成有多级台阶沟槽;所述第一双级台阶沟槽以及所述多级台阶沟槽内均填充有多晶硅;所述栅极结构包括所述第一双级台沟槽内所填充的多晶硅;所述第一双级台阶沟槽与所填充的多晶硅之间、所述多级台阶沟槽与所填充的多晶硅之间均具有绝缘介质层;所述栅极结构包括所述第一双级台阶沟槽 内填充的多晶硅;其中,所述金属栅极位于所述第一双级台阶沟槽所填充的多晶硅的表面上;所述金属源极位于所述多级台阶沟槽所填充的多晶硅的表面上。
- 根据权利要求15所述的制作方法,其特征在于,所述第一双级台阶沟槽底部的所述绝缘介质层的厚度大于所述第一双级台阶沟槽中各级沟槽侧壁上的所述绝缘介质层的厚度,大于相邻两级沟槽之间台阶上的所述绝缘介质层的厚度;所述多级台阶沟槽底部的所述绝缘介质层的厚度大于所述多级台阶沟槽中各级沟槽侧壁上的所述绝缘介质层的厚度,大于相邻两级沟槽之间台阶上的所述绝缘介质层的厚度。
- 根据权利要求16所述的制作方法,其特征在于,所述多级台阶沟槽为第二双级台阶沟槽,所述第二双级台阶沟槽与所述第一双级台阶沟槽的深度相同;或,所述多级台阶沟槽为三级台阶沟槽,所述三级台阶沟槽的深度大于所述第一双级台阶沟槽的深度。
- 根据权利要求13所述的制作方法,其特征在于,形成所述第二耐压掩蔽结构的方法包括:通过离子注入方法,在所述源极区域形成离子注入区域,作为所述第二耐压掩蔽结构;所述离子注入区域的注入深度不小于所述第一沟槽的深度。
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