TW490793B - Semiconductor device and method of formation - Google Patents
Semiconductor device and method of formation Download PDFInfo
- Publication number
- TW490793B TW490793B TW089106143A TW89106143A TW490793B TW 490793 B TW490793 B TW 490793B TW 089106143 A TW089106143 A TW 089106143A TW 89106143 A TW89106143 A TW 89106143A TW 490793 B TW490793 B TW 490793B
- Authority
- TW
- Taiwan
- Prior art keywords
- barrier layer
- layer
- opening
- copper
- interconnect
- Prior art date
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- 239000004065 semiconductor Substances 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title claims description 42
- 230000015572 biosynthetic process Effects 0.000 title claims description 5
- 230000004888 barrier function Effects 0.000 claims abstract description 86
- 239000000758 substrate Substances 0.000 claims abstract description 10
- 239000010410 layer Substances 0.000 claims description 152
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 41
- 229910052802 copper Inorganic materials 0.000 claims description 41
- 239000010949 copper Substances 0.000 claims description 41
- 239000011241 protective layer Substances 0.000 claims description 37
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Classifications
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- H—ELECTRICITY
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
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- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76838—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
- H01L21/76841—Barrier, adhesion or liner layers
- H01L21/76843—Barrier, adhesion or liner layers formed in openings in a dielectric
- H01L21/76849—Barrier, adhesion or liner layers formed in openings in a dielectric the layer being positioned on top of the main fill metal
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- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
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- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
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- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
- H01L21/76802—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing by forming openings in dielectrics
- H01L21/76807—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing by forming openings in dielectrics for dual damascene structures
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- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
- H01L21/76802—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing by forming openings in dielectrics
- H01L21/76807—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing by forming openings in dielectrics for dual damascene structures
- H01L21/76813—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing by forming openings in dielectrics for dual damascene structures involving a partial via etch
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- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76838—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
- H01L21/76841—Barrier, adhesion or liner layers
- H01L21/76843—Barrier, adhesion or liner layers formed in openings in a dielectric
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- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76838—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
- H01L21/76877—Filling of holes, grooves or trenches, e.g. vias, with conductive material
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- H01L23/52—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
- H01L23/522—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
- H01L23/532—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body characterised by the materials
- H01L23/53204—Conductive materials
- H01L23/53209—Conductive materials based on metals, e.g. alloys, metal silicides
- H01L23/53228—Conductive materials based on metals, e.g. alloys, metal silicides the principal metal being copper
- H01L23/53233—Copper alloys
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- H01L23/522—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
- H01L23/532—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body characterised by the materials
- H01L23/53204—Conductive materials
- H01L23/53209—Conductive materials based on metals, e.g. alloys, metal silicides
- H01L23/53228—Conductive materials based on metals, e.g. alloys, metal silicides the principal metal being copper
- H01L23/53238—Additional layers associated with copper layers, e.g. adhesion, barrier, cladding layers
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- H01L24/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L24/02—Bonding areas ; Manufacturing methods related thereto
- H01L24/04—Structure, shape, material or disposition of the bonding areas prior to the connecting process
- H01L24/05—Structure, shape, material or disposition of the bonding areas prior to the connecting process of an individual bonding area
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- H01L2223/544—Marks applied to semiconductor devices or parts
- H01L2223/54473—Marks applied to semiconductor devices or parts for use after dicing
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- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/02—Bonding areas; Manufacturing methods related thereto
- H01L2224/03—Manufacturing methods
- H01L2224/03001—Involving a temporary auxiliary member not forming part of the manufacturing apparatus, e.g. removable or sacrificial coating, film or substrate
- H01L2224/03009—Involving a temporary auxiliary member not forming part of the manufacturing apparatus, e.g. removable or sacrificial coating, film or substrate for protecting parts during manufacture
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- H01L2224/02—Bonding areas; Manufacturing methods related thereto
- H01L2224/04—Structure, shape, material or disposition of the bonding areas prior to the connecting process
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- H01L2224/05001—Internal layers
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- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/02—Bonding areas; Manufacturing methods related thereto
- H01L2224/04—Structure, shape, material or disposition of the bonding areas prior to the connecting process
- H01L2224/05—Structure, shape, material or disposition of the bonding areas prior to the connecting process of an individual bonding area
- H01L2224/05001—Internal layers
- H01L2224/05005—Structure
- H01L2224/05008—Bonding area integrally formed with a redistribution layer on the semiconductor or solid-state body, e.g.
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Description
490793 五、發明說明( 先前申請s耒考 (請先閱讀背面之注意事項再填寫本頁) 本申請案已於1"9年4月5曰以專利申請案號〇9/285,666 申請美國專利。 發明領域 本發明係有關於形成半導體裝置的製程,特別是形成包 士有互連障礙層(interconnect barrier layer)的半導體裝置 的製程。 相關拮藝夕啟沭 經濟部智慧財產局員工消費合作社印製
Ik著半導體裝置的尺寸與封裝持續縮小,在半導體裝置 的打線墊(bond pads )上形成導電緩衝墊(conductive bumps ) 的技術也逐漸普遍化。這些^爰衝墊(bumpS )係用來取代金 屬導線’而電連接打線塾(戈011(1 pads )至個別的封裝腳位 (packaging leads)。緩衝墊的類型包括了控制倒塌晶片連 結型(controlled-collapse chip-connection,C4)緩衝塾。大 體而言,緩衝墊要求在打線墊與緩衝墊之間形成一層由打 線墊所限制大小的金屬層。該打線墊所限制大小的金屬層 包含有鉻化物與鉻合金。然而,含鉻的薄膜通常具有缺陷 (defect ),—例如裂缝(crack )、以及非規則狀的鼓粒邊界 (grain boundary ),其可能會限制含鉻金屬層準確地分離打 線塾與緩衝塾材料之能力。 典型之緩衝墊包括如錫(Sn)與鉛(Pb)等元素。因此, 通常會導致障礙物無法有效分離打線墊與緩衝墊,使得打 線墊的材料與緩衝墊中的錫(S、η )或鉛(P b )起反應,而形 -4 - 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 經濟部智慧財產局員工消費合作社印製 490793 A7 __B7_ 五、發明說明(2 ) 成這些材料的金屬間合金(intermetallic alloy)。如果打線 墊包括有含銅的材料,便會形成易碎的金屬間合金。易碎 的金屬間合金可能因而碎裂並造成緩衝墊的失效。另外, 打線墊與缓衝墊之間合金的過程以及黏著性的退化可能會 導致空洞(void)的形成。較嚴重者,會產生高電阻而對於 半導體裝置的性能有負面的影響並甚至造成半導體裝置的 故障。 . 圖式之簡要説明 , 本發明將籍由下列參照附圖所作之較佳具體實施例的詳 細描述,將會更爲明白但並不爲其所限制,其中相同的參 考數字代表相同的元件,其中: 圖1至圖7係爲本發明第一組具體實施例中,形成具有 銅互連與緩衝墊之半導體裝置的橫截面圖;以及 圖8至圖1 2係爲本發明第二组具體實施例中,形成具有 銅互連與緩衝墊之半導體裝置的橫截面圖。 熟習此項技藝者當可明白以上圖式係以簡化與清楚爲 要,且不必然依實際比例而繪示者。舉例而言,圖式中部 分元件的尺寸較於實際尺寸係被誇大,以助益對於本發明 具體實施例之了解。 本發明之詳細描述 根據本發明之具體實施例,所揭露者係爲一種半導體裝 置及其形成方法。在一具體實施例中,一導通障礙層 (conductive barrier layer)覆蓋於互連(interconnect)之上 方,一保護層(passivation layer)覆蓋於導通障礙層之上 -5- 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) (請先閱讀背面之注意事項再填寫本頁) T裝 1T---------0», 490793 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明(3 ) 方,而该保濩層具有一曝露該導通障礙層之部分的開口 (opening)。在另一具體實施例中,_保護層覆蓋於互連 心上方’孩保護層具有一曝露該互連的開口,而導通障礙 層於開口的範圍内覆蓋於互連之上方。 圖1包括一半導體裝置之部分橫截面圖。該半導體裝置 包括一半導體裝置基板100、以及形成於該半導體裝置基 板1 0 0中之場隔離區i 0 2與摻雜區i 〇 4。一閘極介電層 106覆盍於半導體裝置的部分之上方,而一閘極電極工⑽ 覆蓋於該閘無介電層1 〇 6之上方。 - 一第一層間介電層(ILd)i ίο形成於閘極電極108以及 整個半導體裝置基板100之上方。第一層間介電層11〇被 足義圖案以形成雙重嵌入之開口,其係由黏著/障礙層 112與銅填充材料114所填滿。該黏著/障礙層112通常爲 一種堅硬的金屬、堅硬的金屬氮化物或是堅硬的金屬及其 金屬氮化物的組合。而銅填充材料114則通常爲銅金屬或 銅合金,其中的銅含量必須至少爲九十原子百分比。銅可 以與鎂、硫、碳或類似的元素組成奋金,以增進其黏著 性、電移動性、以及其他金屬互連的特性。在沉積黏著/ 障礙層112與銅填充材料H4之後,該基板被研磨處理, 以除去開口之外的黏著/障礙層1 i 2與銅填充材料丨丨4部 分。 " 在形成第一互連(interconnect)之後,一絕緣障礙層Μ〕 形成於由銅所填滿的互連與第一層間介電層11〇之上方。 此一絕緣障礙層丨22包含有氮化矽(silic0I1 nitride)、氮氧 ^ ^--------t--------- (請先閲讀背面之注意事項再填寫本頁) 冬
本紙張尺度適用中國國家標準(CNS)A4規格(210 297公釐) 490793 A7
化矽(silicon oxynitride )或類似的材料。使用絕緣材料以 形成絕緣障礙層122可以減少形成額外的圖案以及蝕刻製 程的需要,否則如果使用導通障礙層,便需要上述的額外 製程以將互連施以彼此之間的電隔離。一第二層間介電層 (ILD)124形成於絕緣障礙層122之上方。一包括有導; 黏著/障礙層126與銅填充材料128之雙重嵌入的互連形 成於第二層間介電層124中。該雙重嵌入的互連之形成係 藉由使用類似於第一層間介電層1 1 〇中雙重嵌入互連的結 構所使用的翁程與材料。 - 如圖2所示,一保護層22接著形成於第二層間介電層 124與雙重嵌入的互連之上方。該保護層22可包括一或多 層的氮化碎、氮氧化矽、二氧化矽(silic〇n di〇xide)或類似 的材料。靠近銅填充材料丨2 8之保護層2 2的部分通常包括 有氮化碎、或含有相對於原子氧之較高濃度的原子氮之氮 氧化石夕。保護層2 2被定義圖案以形成打線墊的開口 2 *, 其透過保護層22而延伸至銅填充材料128。 如圖3所示,一導通障礙層3 2沉積於保護層2 2與銅填充 材料1 2 8之上,方。導通障礙層3 2之沉積製程係可用化學氣 相沉積、物理氣相沉積、蒸鍍沉積、電鍍、無電極電鍍或 類似的方式而完成。該導通障礙層32之厚度通常介於大 約50至300奈米(nm)的範圍。通常,導通障礙層32包含 有一種堅硬的金屬、堅硬的金屬氮化物或是堅硬的金屬及 其金屬氮化物的組合。在一具體實施例中,導通障礙層 32包含了鈦(Ti)與氮化鈦(TiN )的組成。鈦/氮化欽的堆 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公餐) (請先閱讀背面之注意事項再填寫本頁} 裝-------訂i! Φ 經濟部智慧財產局員工消費合作社印製 490793
經濟部智慧財產局員工消費合作社印製 ®增進了其對於下方之保護層22與銅填充材料128的黏著 程度。此外,氮化鈦(TiN)形成了一道阻止銅填充材料與 陸續沉積的導電緩衝墊反應的障礙。就另一種方式而言, 導通障礙層32亦可包含其他材料,如妲(Ta)、氮化鈕 (TaN )、鎢(W)、氮化鈥鎢(Ti WN)、鈥鐫(Ti W)合金、氮 化鶴(WN)、氮化翻(MoN)、氮化姑(c〇N)、以及上述材 料的組成。在其他具體實施例中,亦可使用耐氧材料。這 些材料包括鉑(Pt)、鈀(Pd)、鎳(Ni)、導電的金屬氧化 物、其對應之金屬、或類似之材料。這些導電的金屬氧化 物以及其對應之金屬更可包括銥(Ir)與氧化依(Ir〇2);铷 (Ru)與氧化铷(Ru〇2);鍊(Re)與氧化鍊(Re〇^Re〇3广 或是鐵(Os)與氧化鐵(〇s〇2)。 隨後再鋪上一層光阻34於導通障凝層32之上方。光阻 34曝露出導通障礙層32下方覆蓋有保護層22之部分。光 阻3 4的形成使得打線墊開口 3 4被覆蓋住。此外,其亦可 被定義圖案,以略為延伸至保護層22上方導通障礙層32 之表面部分,如圖3所示。 接著以習用之蝕刻製程對導通障礙層3 2進行蝕刻作用, 以除去保護層2 2上方導通障礙層3 2之曝露部分。在蝕刻 之後,有圖案之光阻層34再藉由電漿蝕刻製程或使用有機 化學藥品的濕化學製程而除去,而這些化學藥品包括ν· 甲基氮五圜-2-酉同(N-methyl-2-pyrrolidone)、丙酉同、4 丁基甲酿1 ( ΜΙΒΚ)、或其他類似的化學藥品。 就另一種方法而言,如果使用鍍金的方'式,例如電鍍或 -8- 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -----------裝--------訂--------- (請先閱讀背面之注意事項再填寫本頁) A7 B7 五、發明說明(6 無電極電鍍’㈣成導通障礙化,上述 程便不需要了。取而代之者,道、^ #,導通障礙層32可以透過直 (請先閱讀背面之注意事項再填寫本頁) 接在銅填充材料128上方的曝露部份於形成開口24之後, 電鍍而得。如果有必要的話,電鍍可以繼續進行到所鍍上 的金屬覆蓋保護層的—部分,以形成導通障礙層32,t 係如圖4所示者。 接著’ 一晶粒塗佈層(die c〇at layer) ”形成於半導體裝 置I上万,並且被定義圖案以在打線墊開口以上方形成 -晶粒塗伟層開口 54,如圖5所示。在本具體實施例中; 導通障礙層32之周圍部分具有曝露於晶粒塗佈層開口 54 的邊緣。晶粒塗佈層52之形成係可用可感光之聚醯亞胺 (polyumde)層或是使用習知的光阻與蝕刻製程所定義圖案 之聚酸亞胺(polyimide )層。 經濟部智慧財產局員工消費合作社印製 在形成打線墊所限制大小的金屬層62之前,如圖6所 示,導通障礙層32之曝露部分係由射頻濺鍍的清潔方式 所處理。射頻濺鍍的清潔方式可除去導通障礙層32之最 上層邵分,其可能包含有例如氧、碳、氟與氯等雜質,以 改善障礙層與打線墊所限制大小的金屬層6 2之間的接觸 電阻。在一具體實施例中,射頻濺鍍的清潔製程係可在沉 積打線蟄所限制大小的金屬層(於緩衝墊下方)之前,作爲 現場(in-Situ)製程的一部分。在一具體實施例中,執行射 頻賤艘α潔的製程參數如下:射頻功率大約介於丨2〇〇瓦 (W)至1500瓦(W)之間的範圍内、直流偏壓大約介於_3〇〇 伏特(V)至_600伏特(V)之間的範圍内、產力大約介於 9- 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 490793 A7 五、發明說明() 帕(Pascal)之間的範圍内、而時間則大約介於15〇秒至25〇 秒之間的範圍内。射頻濺鍍的清潔製程大約從導通障礙層 32的表面移除了 20至40奈米(nm)範圍的障礙材料。 接著,打線塾所限制大小的金屬層62形成於晶粒塗佈層 開口 54中’如圖6所示。電極所限制大小的金屬層通常包 括有黏著層、中等耦合/焊接層、與反氧化障礙層之組 成。在-具體實施例中,電極所限制大小的金屬層62包括 四種不同層膜之組成:-路層622、—路銅合金層似、一 銅層626、與--金層628。鉻層⑵與鉻銅合金層_各有介 於50至500奈米(nm)範圍之厚度,銅層626具有介於7⑻ 至1300奈米(nm)範圍之厚度,而金層㈣則具有介於至 140奈米(nm)範圍之厚度。就另—種方法而言,電極所限 制大小的金屬層也可包括有其他層膜,例如欽、銅與金的 的:二鈦•、銅與金心組合。通常,電極所限制大小 =屬層62之形成可藉由使用罩幕(_k)的蒸鐘製程而 而’其他的方法,例如賤鍍亦可用於形成電極所 限制大小的金屬層。 根據-具體實施例,在形成電極所限制大小 大料72之緩衝塾材料,被沉積於電㈣限 制大小的金屬層6 2之上方,茹同7 k 一 ^ ^ ^ . ^ ^ , 圖所777。鉛錫焊接材料72 =係可:由使用罩幕的蒸鍍製程而完成,或就另一種 ΓΓ出係可藉由使用習知方法,如電鐘或焊接 賣出㈣—etung)的方式而完成。接著,再施以 -10- 裝--------訂--------- (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適^ΓΓ_ &鮮(GNS)A4規格⑽· 297公釐) 五、發明說明(8 ) 回流(reflow)的製程步驟以圓化鉛錫焊接材料”之角落, 並形成如圖7所示之緩衝塾。 在此一製程階段,基本的半導體裝置便已完成。此一裝 置隨後可被接著至如覆晶(flip chip )或球型格狀陣列封裝 (ball gnd array package)等封裝基板。儘管未被繪示出 來,其他層間的互連亦可依需要而形成。同理,其他互連 亦可被形成以連接至摻雜區j〇4與閘極電極〗〇8。如果額 外的互連需要形成時,其可使用與用來形成絕緣障礙層 122、第二層間介電層124、黏著/障礙層126與銅填充材料 128相同的製程。 圖8至圖1 2係爲本發明另一具體實施例之半導體裝置的 檢截面圖。煩請參閱圖8,其中有一導通障礙層82形成於 第二層間介電層124與銅填充材料128之上方。導通障礙 層8 2之形成係使用相同於先前對照圖3所述之導通障礙層 32的任一種形成材料方法。導通障礙層82具有介於50至 300奈米(nm)範圍之厚度。在此一具體實施例中,一選用 之抗氧化層(oxidation-resist) 84隨後被形成於導通障礙層 8 2之上方。該抗氧化層可採用能夠避免下方層膜被氧化 或者較下方層膜更易被氧化之任何材料。可以採用的材料 包括氮化矽、多晶矽、非晶矽、或導電之金屬氧化物或其 對應之導電金屬。抗氧化層84具有介於10至50奈米(nm) 範圍之厚度。一光阻層86隨後被形成於導通障礙層82與 抗氧化層84之上方。光阻層86被定義圖案,以覆蓋下方 覆蓋有黏著/障礙層126與銅填充材料128'之導通障礙層8 2 -11 - 本紙張尺度適用中國國家^票準(CNS)A4規格(210 X 297公釐) 9 490793 五、發明說明( 與抗氧化層8 4。 導通障礙層82與抗氧化層84之未被定義圖案的部分隨 後便以g用之蝕刻製程而除去。之後,光阻便被除去,而 一保濩層92形成於包括有導通障礙層82與抗氧化層^之 堆疊結構以及第二層間介電層124部分區域之上方,如圖 9所示。保濩層9 2係類似於先前對照圖2所述之保護層2 2 者。在此一具體實施例中,保護層9 2被定義圖案,以形 成打線墊之開口 94。如圖9所示,並非所有打線·墊之開= 内的保護着均被移除。因此,打線墊之開口只有部分形成 於走義圖案的製程中。保護層之剩餘部分9 6在定義圖案 的製程之後依然保留在抗氧化層8 4之上方。 接著,一晶粒塗佈層1〇〇1形成於半導體裝置之上方,並 且被定義圖案以形成一晶粒塗佈層開口 1〇〇3,如圖i 〇所 示。晶粒塗佈層1001係類似於先前對照圖5所述之晶粒塗 佈層1001者。晶粒塗佈層開口 1〇〇3曝露出保護層92之部 分區域,其包括剩餘部分9 6。在形成晶粒塗佈層開口 1003 <後,以蝕刻方式除去剩餘部分9 6以及其下方之抗 氧化層8 4。藉此形成如圖} i所示之晶粒塗佈層開口 1〇〇3。在此一蝕刻過程中,晶粒塗佈層1〇〇1所曝露出的 保護層9 2部分也被蝕刻。在一具體實施例中,保護層$ 2 包括含碎與氮之成分,例如氮化矽或氮氧化矽,而抗氧化 層8 4則包括有氮化矽。於是,相同或類似的蝕刻化學藥 品可被使用來移去保護層9 2以及抗氧化層8 4的剩餘部分 9 6° , -12- 本紙張尺度適Tfg國家X 297公釐)
ψ Μ--------t---------φ___ (請先閱讀背面之注意事項再填寫本頁)
經濟部智慧財產局員工消費合作社印製 製程持續被進行以完成如圖12所示之裝置。一電椏所 制大小的金屬層1220以與之前所述者採用相同之方式形 其包括一路層1222、一鉻銅合金層1224、一銅層 、26、與一金層1228。如果需要的話,類似於之前所述 =射頻賤鏡清潔製程可被用來製備形成電極所限制大小的 金屬層1220之前所需要之障礙層表面。在此一具體實施例 :’施以回流步驟,以圓化鉛錫焊接材料1230之角落,並 王現如圖1 2所示之圓頂形貌。 在圖9至郾:1 2所示之具體實施例中,絕緣障礙層1 2 2係 用於除了最上層之互連之外的所有互連。最上層之互連係 爲其上形成有打線墊之互連者。因此,其爲使用導通障礙 層82之唯一互連。 本發明有許多其他可行之具體實施例。煩請參閱圖3, 導通障礙層32亦可包括一類似圖8至圖12中所示之第二組 具體實施例中的抗氧化層8 4之覆蓋(overlying)抗氧化層。 同樣地’第二組具體實施例不一定需要使用抗氧化層 8 4,因爲保護層9 2之剩餘部分9 6允許含氧之電漿的使 用’而不會對導通障礙層8 2造成損害。此項特點在導通-障礙層32或82包括氮化妲(TaN)、氮化鈦(TiN)、或類似 材料時,顯得格外重要,因爲以上這些材料可以與含氧電 漿或其他用來移除或顯影光阻或聚醯亞胺(polyilnide)層的 化學藥品產生不利的化學反應。這些化學藥品可能包括四 甲基氫氧化錢(tetramethyl ammonium hydroxide)、N -甲基-1-氮五圜-2_ 嗣(N-methyl-2-pyrrolidone)、丙嗣、異丁基 -13- 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) —^wi ^--------^--------- (請先閱讀背面之注意事項再填寫本頁) 490793 經濟部智慧財產局員工消費合作社印製 發明說明( 甲酮(MIBK),、以及其他類似的化學藥品。 除了在打線塾之上形成如圖9至圖12所示之導通障礙層 之外’導電障礙材料亦可用來形成半導體裝置導電區域之 間可藉由能量或雷射而調整的連接(energy- 〇r laser_ alterable connection )。這些連接之導電性可藉由雷射來修 正,以程式化或調整裝置之電路。 、 使用導通障礙層來形成藉由雷射而調整的連接具有優於 先如技藝的優點。導通障礙層通常比一般用來形成藉由雷 射而調整的連接之互連具有比較薄、較低熱導度、與較低 反射率之特性。相較於互連,導通障礙層也較具自我保護 (self_passivating)的優點。藉此,使用藉由雷射而調整的 連接可改善穩定度,因爲在雷射調變之後用來短路的電壓 被降低了。此外,藉由雷射而調整的連接可形成於靠近半 導體裝置之上表面處。如此可使雷射使用較低的功率即可 改變藉由雷射而碉整的連接之導電性,其可降低會產生短 路、損壞鄰近互連、以及損壞環繞保護層之電壓。此外, 導通障礙層與藉由雷射而調整的連接可以使用相同材料而 同時形成。藉此,製程整合不需要額外的製程步驟。 儘管特定之材料已依照電極所限制大小的金屬層6 2而 被列舉’其他的材料與變動亦可被使用。舉例而言,導通 障礙層可被作爲部分之電極所限制大小的金屬層。在這種 情形中,可在形成其他的電極所限制大小的金屬層之前, 以蒸嫂或濺鍍至晶圓的方式形成。而在另一具體實施例 中,電極所限制大小的金屬層與焊接材蚪可一起藉由物理 -14- I ^ I------^--------- (請先閱讀背面之注意事項再填寫本頁)
490793 A7 __________B7 ___ 12 ---------- 五、發明說明() 氣相沉積或喷射印刷的方式而形成,其中饺㈤ 六r塔化夂焊接滴點 可被沉積於孔洞旁邊的地方。 本發明所述之具體實施例可被整合成一製程流程,而、 需使用有毒材料、開發新的製程或是添購新的製^設備^ 導通障礙層3 2及8 2係足以阻隔互連中的銅與緩衝塾中的 錯錫焊接劑彼此產生反應。因此,可在互連與缓衝塾之間 的介面維持製程的整合性。如此可提昇緩衝塾之機械整人 度,並且降低互連與緩衝墊之間的接面電阻。 口 本發明之·圖式與描述以較佳實施例說明如上,僅用於藉_ 以幫助了解本發明之實施,非用以限定本發明之精神,而 熟悉此領域技藝者於領悟本發明之精神後,在不脫離本發 明之精神範圍内,當可作些許更動潤飾及同等之變化替 換,其專利保護範圍當視後附之申請專利範圍及其等同領 域而定。 ·裝--------訂--------- Φ (請先閱讀背面之注意事項再填寫本頁} 經濟部智慧財產局員工消費合作社印製 適 度 i尺 張 5 格 規 A4 S)A N (C 準 標 家 釐 公 97
Claims (1)
- 490793 經濟部智慧財產局員工消費合作社印製 A8 B8 C8 D8 六、申請專利範圍 1· 一種半導體裝置,包括: 一第一互連(114),其覆蓋於半導體裝置基板(100)之 上方; 一絕緣障礙層(122),其覆蓋於該第一互連(114)之上 方; 一大部分含銅之互連(128),其覆蓋於該第一互連 (114)與絕緣障礙層(122)之部分的上方; 一導通障礙層(82),其覆蓋於該大部分含銅之互連 (128)之部'分的上方,而該導通障礙層(82)延伸於該大-部分含銅之互連(128)之部分的邊緣區域的下方;以及 一保護層(92),其覆蓋於該導通障礙層(82)之上 方,而該保護層(92)具有一曝露該導通障礙層(82)之 部分的開口。 2·如申請專利範圍第1項之半導體裝置,其中該導通障礙 層(8 2 )之一部份為至少兩導電區域之間的可藉由雷射而 調整的連接。 3. —種半導體裝置,其包括: 一大部分含銅之互連(128),其覆蓋於半導體裝置基 板(100)之上方; i 一保護層(22),其覆蓋於該大部分含鋼之互連(128) 之上方,而該保護層(22)具有一曝露該大部分含銅之互 連(128)之部分的開口(24);以及 一導通障礙層(3 2),其位於開口(24)之内且覆蓋於 該大部分含銅之互連(128)之部分的上方。 |、 (請先閱讀背面之注意事項再填寫本頁) T. n I— tame l . I ϋ ΒΒϋ n I— n 11 ·1 I , -16-490793 A8 B8 C8 D8 六、申請專利範圍 4. 一種形成半導體裝置的方法,其包括以下之步驟: 形成一第一互連(114),其覆蓋於半導體裝置基板 (100)之上方; 形成一絕緣障礙層(122),其覆蓋於該第一互連(114) 之上方; 形成一大部分含銅之互連(128),其覆蓋於該第一互 連(114)與絕緣障礙層(122)之部分的上方; 开>成一導通障礙層(82),其覆蓋於該大部分含銅之 互連(12_8>·之部分的上方,而該導通障礙層(82)延伸於 該大部分含銅之互連(丨28 )之部分的邊緣區域的下方; 形成一保護層(92),其覆蓋於該導通障礙層(82)之 上方;以及 开> 成一開口於該保護層(9 2 )内,其中該開口曝露該 導通障礙層(82)之部分。 5·如申請專利範圍第4項之方法,其中形成一開口於該保 護層(92)内更包括以下的步驟: 形成一部分的開口( 9 4 )於該保護層(9 2 )内,其中該 部分的開口之深度小於該保護層在部分開口形成之處的 厚度; 形成一晶粒塗佈層(1001 )於該保護層(9 2 )之上方; 形成一開口(1003)於該晶粒塗佈層(1〇〇1)内,其中該 晶粒塗佈層開口( 1〇〇3)曝露出保護層(92)内之部分的開 口( 9 4 );以及 蝕刻保護層(9 2 )内之部分的開口,’以在形成晶粒塗 -17 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) (請先閱讀背面之注意事項再填寫本頁) 裝 經濟部智慧財產局員工消費合作社印製 490793 A8 B8 C8 D8 ' — —— 六、申請專利範圍 佈層(1001)中之開口( 1003 )之後,曝露其下方之層膜。 6.如申請專利範圍第5項之方法,其更包括以下的步驟: 在形成保護層(9 2 )内的開口之後,移去導通障礙層 (82)之一部分,其中該導通障礙層(82)之部分具有一 深度;以及 在移去導通障礙層(82)之一部分之後,形成一導電 缓衝墊(123〇)於該導通障礙層(82)之上方。 7· —種形成半導體裝置的方法,其包括以下之步驟: 形成一大部分含銅之互連(128),其覆蓋於半導體裝 置基板(100)之上方; 形成一保護層(22),其覆蓋於該大部分含銅之互連 (128)之上方; 形成一開口( 2 4 )於該保護層(2 2 )内,而該開口( 2 4 ) 曝露該大部分含銅之互連(128 )之部分;以及 形成一導通障礙層(32),於開口(24)之内,該導通 障礙層(32)覆蓋於該夫部分含銅之互連(ία)之部分的 上方。 (請先閱讀背面之注意事項再填寫本頁) ▼裝--------訂---------' 經濟部智慧財產局員工消費合作社印製 -18- 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐)
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-
1999
- 1999-04-05 US US09/285,666 patent/US20020000665A1/en not_active Abandoned
-
2000
- 2000-03-27 JP JP2000086214A patent/JP4566325B2/ja not_active Expired - Fee Related
- 2000-04-01 TW TW089106143A patent/TW490793B/zh not_active IP Right Cessation
- 2000-04-04 SG SG200001904A patent/SG84587A1/en unknown
- 2000-04-04 CN CNB001049275A patent/CN1192430C/zh not_active Expired - Fee Related
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2002
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JP4566325B2 (ja) | 2010-10-20 |
US20020000665A1 (en) | 2002-01-03 |
US20020093098A1 (en) | 2002-07-18 |
SG84587A1 (en) | 2001-11-20 |
US6713381B2 (en) | 2004-03-30 |
CN1269607A (zh) | 2000-10-11 |
JP2000306914A (ja) | 2000-11-02 |
CN1192430C (zh) | 2005-03-09 |
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