RU94031156A - Никелевый катализатор на носителе для парового риформинга азотсодержащего углеводородного сырья и способ получения газа, богатого водородом и/или моноокисью углерода - Google Patents
Никелевый катализатор на носителе для парового риформинга азотсодержащего углеводородного сырья и способ получения газа, богатого водородом и/или моноокисью углеродаInfo
- Publication number
- RU94031156A RU94031156A RU94031156/04A RU94031156A RU94031156A RU 94031156 A RU94031156 A RU 94031156A RU 94031156/04 A RU94031156/04 A RU 94031156/04A RU 94031156 A RU94031156 A RU 94031156A RU 94031156 A RU94031156 A RU 94031156A
- Authority
- RU
- Russia
- Prior art keywords
- hydrogen
- carrier
- carbon monoxide
- containing hydrocarbon
- steam reforming
- Prior art date
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract 6
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract 5
- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract 3
- 229910002091 carbon monoxide Inorganic materials 0.000 title claims abstract 3
- 239000007789 gas Substances 0.000 title claims abstract 3
- 239000001257 hydrogen Substances 0.000 title claims abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract 3
- -1 nitrogen containing hydrocarbon Chemical class 0.000 title claims abstract 3
- 238000000629 steam reforming Methods 0.000 title claims abstract 3
- 238000000034 method Methods 0.000 title 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract 4
- 239000003054 catalyst Substances 0.000 claims abstract 4
- 229910052802 copper Inorganic materials 0.000 claims abstract 4
- 239000010949 copper Substances 0.000 claims abstract 4
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract 2
- 239000001569 carbon dioxide Substances 0.000 claims abstract 2
- YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 claims abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract 2
- 238000004519 manufacturing process Methods 0.000 claims abstract 2
- 239000000203 mixture Substances 0.000 claims abstract 2
- 229910052759 nickel Inorganic materials 0.000 claims abstract 2
- 238000002955 isolation Methods 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1005—Arrangement or shape of catalyst
- C01B2203/1011—Packed bed of catalytic structures, e.g. particles, packing elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1005—Arrangement or shape of catalyst
- C01B2203/1011—Packed bed of catalytic structures, e.g. particles, packing elements
- C01B2203/1017—Packed bed of catalytic structures, e.g. particles, packing elements characterised by the form of the structure
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
- C01B2203/1058—Nickel catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1076—Copper or zinc-based catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1082—Composition of support materials
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1247—Higher hydrocarbons
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
Объектом изобретения являются никелевый катализатор на носителе для парового риформинга азотсодержащего углеводородного сырья, который дополнительно содержит медь при следующем соотношении компонентов, мас.%: никель 5 - 50; медь 0,03-0,5; носитель остальное, а также способ получения богатого водородом и/или моноокисью углерода газа путем пропускания смеси углеводородов и пара и/или двуокиси углерода через слой указанного никелево-медного катализатора на носителе при повышенных температурах и под давлением с последующим выделением целевого продукта.
Claims (1)
- Объектом изобретения являются никелевый катализатор на носителе для парового риформинга азотсодержащего углеводородного сырья, который дополнительно содержит медь при следующем соотношении компонентов, мас.%: никель 5 - 50; медь 0,03-0,5; носитель остальное, а также способ получения богатого водородом и/или моноокисью углерода газа путем пропускания смеси углеводородов и пара и/или двуокиси углерода через слой указанного никелево-медного катализатора на носителе при повышенных температурах и под давлением с последующим выделением целевого продукта.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DK0974/93 | 1993-08-27 | ||
DK199300974A DK174087B1 (da) | 1993-08-27 | 1993-08-27 | Fremgangsmåde til dampreforming af nitrogenholdige carbonhydrider med reduceret dannelse af ammoniak |
Publications (2)
Publication Number | Publication Date |
---|---|
RU94031156A true RU94031156A (ru) | 1996-08-20 |
RU2132228C1 RU2132228C1 (ru) | 1999-06-27 |
Family
ID=8099599
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU94031156A RU2132228C1 (ru) | 1993-08-27 | 1994-08-26 | Никелевый катализатор на носителе для получения богатого водородом и/или моноокисью углерода газа и способ получения указанного газа |
Country Status (13)
Country | Link |
---|---|
US (1) | US5498404A (ru) |
EP (1) | EP0640560B1 (ru) |
JP (1) | JP2958242B2 (ru) |
KR (1) | KR0124987B1 (ru) |
AU (1) | AU673451B2 (ru) |
CA (1) | CA2130953C (ru) |
DE (1) | DE69407692T2 (ru) |
DK (1) | DK174087B1 (ru) |
ES (1) | ES2111811T3 (ru) |
NO (1) | NO311207B1 (ru) |
NZ (1) | NZ264308A (ru) |
RU (1) | RU2132228C1 (ru) |
ZA (1) | ZA946517B (ru) |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1013603A1 (en) | 1998-12-22 | 2000-06-28 | Haldor Topsoe A/S | Process for catalytical steam reforming of a hydrocarbon feedstock |
FR2795339B1 (fr) * | 1999-06-24 | 2001-09-21 | Peugeot Citroen Automobiles Sa | Catalyseur et procede de reformage de l'ethanol ainsi que systeme de pile a combustible les utilisant |
US6376114B1 (en) | 2000-05-30 | 2002-04-23 | Utc Fuel Cells, Llc | Reformate fuel treatment system for a fuel cell power plant |
JP4568448B2 (ja) * | 2001-03-30 | 2010-10-27 | 出光興産株式会社 | 水素製造プラントおよび水素製造方法 |
US7179442B2 (en) * | 2002-12-20 | 2007-02-20 | Honda Giken Kogyo Kabushiki Kaisha | Catalyst formulations containing Group 11 metals for hydrogen generation |
JP2006511427A (ja) * | 2002-12-20 | 2006-04-06 | 本田技研工業株式会社 | 白金およびロジウムおよび/または鉄を含有する水素生成用触媒配合物 |
US7270798B2 (en) * | 2002-12-20 | 2007-09-18 | Honda Giken Kogyo Kabushiki Kaisha | Noble metal-free nickel catalyst formulations for hydrogen generation |
CA2511039A1 (en) * | 2002-12-20 | 2004-07-15 | Honda Giken Kogyo Kabashiki Kaisha | Platinum-alkali/alkaline-earth catalyst formulations for hydrogen generation |
EP1581339A2 (en) * | 2002-12-20 | 2005-10-05 | Honda Giken Kogyo Kabushiki Kaisha | Methods for the preparation of catalysts for hydrogen generation |
CN1729140B (zh) * | 2002-12-20 | 2010-04-21 | 本田技研工业株式会社 | 用于氢产生的不含铂的钌-钴催化剂配方 |
CA2511019A1 (en) * | 2002-12-20 | 2004-07-15 | Honda Giken Kogyo Kabushiki Kaisha | Alkali-containing catalyst formulations for low and medium temperature hydrogen generation |
CN1729050A (zh) | 2002-12-20 | 2006-02-01 | 本田技研工业株式会社 | 用于氢产生的含铂-钌催化剂配方 |
EP1454671A1 (en) * | 2003-03-07 | 2004-09-08 | Karsten Pedersen | A catalyst for use in production of hydrogen by conversion of organic matter in water |
JP4607715B2 (ja) * | 2005-09-06 | 2011-01-05 | 株式会社東芝 | 触媒及び触媒の製造方法 |
JP4706857B2 (ja) * | 2006-05-30 | 2011-06-22 | 戸田工業株式会社 | 金属カルボニルを除去する触媒、水素を含む混合改質ガスを製造する方法、金属カルボニルを除去する方法、燃料電池システム |
US7695708B2 (en) * | 2007-03-26 | 2010-04-13 | Air Products And Chemicals, Inc. | Catalytic steam reforming with recycle |
JP4665044B2 (ja) * | 2009-09-14 | 2011-04-06 | 株式会社東芝 | 燃料改質用触媒、改質器及び燃料電池システム |
JP5812253B2 (ja) * | 2011-04-27 | 2015-11-11 | 戸田工業株式会社 | 炭化水素を分解する触媒及び燃料電池システム |
WO2013042314A1 (ja) * | 2011-09-22 | 2013-03-28 | パナソニック株式会社 | 水素含有ガスの生成方法および燃料電池システムの運転方法 |
EP3095760A1 (en) * | 2015-05-21 | 2016-11-23 | Casale SA | A method for increasing the capacity of an ammonia plant |
RU2650495C1 (ru) * | 2017-05-22 | 2018-04-16 | Акционерное общество "Ангарский завод катализаторов и органического синтеза" (АО "АЗКиОС") | Катализатор для паровой конверсии углеводородов |
GB202012614D0 (en) | 2020-08-13 | 2020-09-30 | Johnson Matthey Plc | Steam reforming |
GB202012613D0 (en) | 2020-08-13 | 2020-09-30 | Johnson Matthey Plc | Steam reforming |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1032754A (en) * | 1962-12-17 | 1966-06-15 | Ici Ltd | Improvements in or relating to the steam reforming of hydrocarbons and catalysts therefor |
GB1045616A (en) * | 1964-07-20 | 1966-10-12 | Gas Council | Improvements in or relating to the production of combustible gases |
FR1433595A (fr) * | 1965-02-17 | 1966-04-01 | Azote Office Nat Ind | Perfectionnements aux catalyseurs de reformage des hydrocarbures pétroliers par la vapeur |
US4000987A (en) * | 1973-02-03 | 1977-01-04 | Japan Gasoline Co., Ltd. | Low-temperature steam reforming process for hydrocarbons |
US4000988A (en) * | 1973-06-20 | 1977-01-04 | Japan Gasoline Co., Ltd. | Low-temperature steam reforming process for hydrocarbons |
US4073750A (en) * | 1976-05-20 | 1978-02-14 | Exxon Research & Engineering Co. | Method for preparing a highly dispersed supported nickel catalyst |
GB8308343D0 (en) * | 1983-03-25 | 1983-05-05 | Ici Plc | Steam reforming |
GB8728882D0 (en) * | 1987-12-10 | 1988-01-27 | Ici Plc | Hydrogen |
US5026536A (en) * | 1988-12-20 | 1991-06-25 | Nippon Oil Co., Ltd. | Hydrogen production from hydrocarbon |
JPH0312301A (ja) * | 1989-06-07 | 1991-01-21 | Mitsubishi Heavy Ind Ltd | メタノールの改質方法 |
JP2659836B2 (ja) * | 1989-12-28 | 1997-09-30 | 三菱重工業株式会社 | メタノールの改質方法 |
JP2738975B2 (ja) * | 1990-10-02 | 1998-04-08 | 三菱重工業株式会社 | メタノールの改質方法 |
JP2851406B2 (ja) * | 1990-10-02 | 1999-01-27 | 三菱重工業株式会社 | メタノール改質用触媒 |
JPH0567336A (ja) * | 1992-02-04 | 1993-03-19 | Brother Ind Ltd | 光記録媒体および光記録装置 |
-
1993
- 1993-08-27 DK DK199300974A patent/DK174087B1/da not_active IP Right Cessation
-
1994
- 1994-07-27 ES ES94111699T patent/ES2111811T3/es not_active Expired - Lifetime
- 1994-07-27 EP EP94111699A patent/EP0640560B1/en not_active Expired - Lifetime
- 1994-07-27 DE DE69407692T patent/DE69407692T2/de not_active Expired - Lifetime
- 1994-08-24 US US08/295,285 patent/US5498404A/en not_active Expired - Lifetime
- 1994-08-25 NZ NZ264308A patent/NZ264308A/en not_active IP Right Cessation
- 1994-08-25 NO NO19943145A patent/NO311207B1/no not_active IP Right Cessation
- 1994-08-25 AU AU71473/94A patent/AU673451B2/en not_active Expired
- 1994-08-26 CA CA002130953A patent/CA2130953C/en not_active Expired - Lifetime
- 1994-08-26 ZA ZA946517A patent/ZA946517B/xx unknown
- 1994-08-26 KR KR1019940021186A patent/KR0124987B1/ko not_active IP Right Cessation
- 1994-08-26 JP JP6202443A patent/JP2958242B2/ja not_active Expired - Lifetime
- 1994-08-26 RU RU94031156A patent/RU2132228C1/ru active
Also Published As
Publication number | Publication date |
---|---|
DE69407692D1 (de) | 1998-02-12 |
JP2958242B2 (ja) | 1999-10-06 |
ES2111811T3 (es) | 1998-03-16 |
CA2130953C (en) | 2002-07-30 |
DK174087B1 (da) | 2002-06-03 |
RU2132228C1 (ru) | 1999-06-27 |
AU673451B2 (en) | 1996-11-07 |
AU7147394A (en) | 1995-03-09 |
KR950005962A (ko) | 1995-03-20 |
EP0640560A1 (en) | 1995-03-01 |
DE69407692T2 (de) | 1998-04-16 |
NO311207B1 (no) | 2001-10-29 |
CA2130953A1 (en) | 1995-02-28 |
KR0124987B1 (ko) | 1997-11-27 |
NO943145D0 (no) | 1994-08-25 |
ZA946517B (en) | 1995-03-28 |
JPH07144902A (ja) | 1995-06-06 |
EP0640560B1 (en) | 1998-01-07 |
US5498404A (en) | 1996-03-12 |
DK97493A (da) | 1995-02-28 |
DK97493D0 (da) | 1993-08-27 |
NO943145L (no) | 1995-02-28 |
NZ264308A (en) | 1996-03-26 |
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