KR950005962A - 탄화수소의 증기 개질방법 - Google Patents
탄화수소의 증기 개질방법 Download PDFInfo
- Publication number
- KR950005962A KR950005962A KR1019940021186A KR19940021186A KR950005962A KR 950005962 A KR950005962 A KR 950005962A KR 1019940021186 A KR1019940021186 A KR 1019940021186A KR 19940021186 A KR19940021186 A KR 19940021186A KR 950005962 A KR950005962 A KR 950005962A
- Authority
- KR
- South Korea
- Prior art keywords
- catalyst
- steam reforming
- amount
- nickel
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract 5
- 238000000629 steam reforming Methods 0.000 title claims abstract 4
- 239000004215 Carbon black (E152) Substances 0.000 title 1
- 229930195733 hydrocarbon Natural products 0.000 title 1
- 150000002430 hydrocarbons Chemical class 0.000 title 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract 9
- 239000003054 catalyst Substances 0.000 claims abstract 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract 4
- 229910052802 copper Inorganic materials 0.000 claims abstract 4
- 239000010949 copper Substances 0.000 claims abstract 4
- 229910052759 nickel Inorganic materials 0.000 claims abstract 3
- 229910021529 ammonia Inorganic materials 0.000 claims abstract 2
- 238000004519 manufacturing process Methods 0.000 claims abstract 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000002994 raw material Substances 0.000 abstract 2
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1005—Arrangement or shape of catalyst
- C01B2203/1011—Packed bed of catalytic structures, e.g. particles, packing elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1005—Arrangement or shape of catalyst
- C01B2203/1011—Packed bed of catalytic structures, e.g. particles, packing elements
- C01B2203/1017—Packed bed of catalytic structures, e.g. particles, packing elements characterised by the form of the structure
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
- C01B2203/1058—Nickel catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1076—Copper or zinc-based catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1082—Composition of support materials
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1247—Higher hydrocarbons
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
Description
Claims (4)
- 원료가 촉매에서 니켈의 양에 대하여 산출된 0.01∼10중량%의 양으로 구리를 더 포함하는 지지니켈촉매와 접촉되는 것을 특징으로 하는, 암모니아의 생성이 감소된 질소함유 탄소성 원료의 접촉증기 개질방법.
- 제1항에 있어서, 촉매내 구리의 양은 총 촉매중량에 대하여 산출된 0.03∼0.50중량% 사이인 것을 특징으로 하는 방법.
- 제1항에 있어서, 구리함유니켈 촉매는 통상의 니켈증기개질촉매의 고정베드에 부층으로서 배열되는 것을 특징으로 하는 방법.
- 제3항에 있어서, 부층은 총 촉매베드의 25% 내지 75%를 구성하는 것을 특징으로 하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DK199300974A DK174087B1 (da) | 1993-08-27 | 1993-08-27 | Fremgangsmåde til dampreforming af nitrogenholdige carbonhydrider med reduceret dannelse af ammoniak |
DK0974/93 | 1993-08-27 | ||
DK974/93 | 1993-08-27 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR950005962A true KR950005962A (ko) | 1995-03-20 |
KR0124987B1 KR0124987B1 (ko) | 1997-11-27 |
Family
ID=8099599
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019940021186A Expired - Lifetime KR0124987B1 (ko) | 1993-08-27 | 1994-08-26 | 탄화수소의 증기 개질방법 |
Country Status (13)
Country | Link |
---|---|
US (1) | US5498404A (ko) |
EP (1) | EP0640560B1 (ko) |
JP (1) | JP2958242B2 (ko) |
KR (1) | KR0124987B1 (ko) |
AU (1) | AU673451B2 (ko) |
CA (1) | CA2130953C (ko) |
DE (1) | DE69407692T2 (ko) |
DK (1) | DK174087B1 (ko) |
ES (1) | ES2111811T3 (ko) |
NO (1) | NO311207B1 (ko) |
NZ (1) | NZ264308A (ko) |
RU (1) | RU2132228C1 (ko) |
ZA (1) | ZA946517B (ko) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1013603A1 (en) * | 1998-12-22 | 2000-06-28 | Haldor Topsoe A/S | Process for catalytical steam reforming of a hydrocarbon feedstock |
RU2161064C1 (ru) * | 1999-04-06 | 2000-12-27 | Институт катализа им. Г.К. Борескова Сибирского отделения РАН | Способ осуществления трехфазных каталитических процессов |
FR2795339B1 (fr) * | 1999-06-24 | 2001-09-21 | Peugeot Citroen Automobiles Sa | Catalyseur et procede de reformage de l'ethanol ainsi que systeme de pile a combustible les utilisant |
US6376114B1 (en) | 2000-05-30 | 2002-04-23 | Utc Fuel Cells, Llc | Reformate fuel treatment system for a fuel cell power plant |
JP4568448B2 (ja) * | 2001-03-30 | 2010-10-27 | 出光興産株式会社 | 水素製造プラントおよび水素製造方法 |
RU2241657C2 (ru) * | 2001-04-16 | 2004-12-10 | Открытое акционерное общество "Концерн Стирол" | Способ конверсии метана |
US7744849B2 (en) * | 2002-12-20 | 2010-06-29 | Honda Giken Kogyo Kabushiki Kaisha | Platinum-alkali/alkaline-earth catalyst formulations for hydrogen generation |
CA2511173A1 (en) * | 2002-12-20 | 2004-07-15 | Honda Giken Kogyo Kabushiki Kaisha | Noble metal-free nickel catalyst formulations for hydrogen generation |
US7160534B2 (en) * | 2002-12-20 | 2007-01-09 | Honda Giken Kogyo Kabushiki Kaisha | Platinum-free ruthenium-cobalt catalyst formulations for hydrogen generation |
WO2004058396A2 (en) * | 2002-12-20 | 2004-07-15 | Honda Giken Kogyo Kabushiki Kaisha | Methods for the preparation of catalysts for hydrogen generation |
CN1729050A (zh) | 2002-12-20 | 2006-02-01 | 本田技研工业株式会社 | 用于氢产生的含铂-钌催化剂配方 |
JP2006511427A (ja) * | 2002-12-20 | 2006-04-06 | 本田技研工業株式会社 | 白金およびロジウムおよび/または鉄を含有する水素生成用触媒配合物 |
WO2004058635A1 (en) * | 2002-12-20 | 2004-07-15 | Honda Giken Kogyo Kabushiki Kaisha | Alkali-containing catalyst formulations for low and medium temperature hydrogen generation |
EP1578688A2 (en) * | 2002-12-20 | 2005-09-28 | Honda Giken Kogyo Kabushiki Kaisha | Catalyst formulations for hydrogen generation |
EP1454671A1 (en) * | 2003-03-07 | 2004-09-08 | Karsten Pedersen | A catalyst for use in production of hydrogen by conversion of organic matter in water |
JP4607715B2 (ja) * | 2005-09-06 | 2011-01-05 | 株式会社東芝 | 触媒及び触媒の製造方法 |
JP4706857B2 (ja) * | 2006-05-30 | 2011-06-22 | 戸田工業株式会社 | 金属カルボニルを除去する触媒、水素を含む混合改質ガスを製造する方法、金属カルボニルを除去する方法、燃料電池システム |
WO2008084785A1 (ja) * | 2007-01-09 | 2008-07-17 | Murata Manufacturing Co., Ltd. | 二酸化炭素改質用触媒およびその製造方法 |
US7695708B2 (en) * | 2007-03-26 | 2010-04-13 | Air Products And Chemicals, Inc. | Catalytic steam reforming with recycle |
JP4665044B2 (ja) * | 2009-09-14 | 2011-04-06 | 株式会社東芝 | 燃料改質用触媒、改質器及び燃料電池システム |
JP5812253B2 (ja) * | 2011-04-27 | 2015-11-11 | 戸田工業株式会社 | 炭化水素を分解する触媒及び燃料電池システム |
WO2013042314A1 (ja) * | 2011-09-22 | 2013-03-28 | パナソニック株式会社 | 水素含有ガスの生成方法および燃料電池システムの運転方法 |
EP3095760A1 (en) * | 2015-05-21 | 2016-11-23 | Casale SA | A method for increasing the capacity of an ammonia plant |
RU2650495C1 (ru) * | 2017-05-22 | 2018-04-16 | Акционерное общество "Ангарский завод катализаторов и органического синтеза" (АО "АЗКиОС") | Катализатор для паровой конверсии углеводородов |
AU2021232523A1 (en) * | 2020-03-03 | 2022-08-18 | Topsoe A/S | Process for the production of synthesis gas |
GB202012613D0 (en) * | 2020-08-13 | 2020-09-30 | Johnson Matthey Plc | Steam reforming |
GB202012614D0 (en) * | 2020-08-13 | 2020-09-30 | Johnson Matthey Plc | Steam reforming |
JP7695142B2 (ja) * | 2021-07-30 | 2025-06-18 | 三菱化工機株式会社 | 水素製造装置及び水素製造装置の運転方法 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1032754A (en) * | 1962-12-17 | 1966-06-15 | Ici Ltd | Improvements in or relating to the steam reforming of hydrocarbons and catalysts therefor |
GB1045616A (en) * | 1964-07-20 | 1966-10-12 | Gas Council | Improvements in or relating to the production of combustible gases |
FR1433595A (fr) * | 1965-02-17 | 1966-04-01 | Azote Office Nat Ind | Perfectionnements aux catalyseurs de reformage des hydrocarbures pétroliers par la vapeur |
US4000987A (en) * | 1973-02-03 | 1977-01-04 | Japan Gasoline Co., Ltd. | Low-temperature steam reforming process for hydrocarbons |
US4000988A (en) * | 1973-06-20 | 1977-01-04 | Japan Gasoline Co., Ltd. | Low-temperature steam reforming process for hydrocarbons |
US4073750A (en) * | 1976-05-20 | 1978-02-14 | Exxon Research & Engineering Co. | Method for preparing a highly dispersed supported nickel catalyst |
GB8308343D0 (en) * | 1983-03-25 | 1983-05-05 | Ici Plc | Steam reforming |
DK165946C (da) * | 1985-03-21 | 1993-07-05 | Haldor Topsoe As | Reformingproces under varmeudveksling og reaktor dertil |
GB8728882D0 (en) * | 1987-12-10 | 1988-01-27 | Ici Plc | Hydrogen |
US5026536A (en) * | 1988-12-20 | 1991-06-25 | Nippon Oil Co., Ltd. | Hydrogen production from hydrocarbon |
JPH0312301A (ja) * | 1989-06-07 | 1991-01-21 | Mitsubishi Heavy Ind Ltd | メタノールの改質方法 |
JP2659836B2 (ja) * | 1989-12-28 | 1997-09-30 | 三菱重工業株式会社 | メタノールの改質方法 |
JP2851406B2 (ja) * | 1990-10-02 | 1999-01-27 | 三菱重工業株式会社 | メタノール改質用触媒 |
JP2738975B2 (ja) * | 1990-10-02 | 1998-04-08 | 三菱重工業株式会社 | メタノールの改質方法 |
JPH0567336A (ja) * | 1992-02-04 | 1993-03-19 | Brother Ind Ltd | 光記録媒体および光記録装置 |
-
1993
- 1993-08-27 DK DK199300974A patent/DK174087B1/da not_active IP Right Cessation
-
1994
- 1994-07-27 DE DE69407692T patent/DE69407692T2/de not_active Expired - Lifetime
- 1994-07-27 EP EP94111699A patent/EP0640560B1/en not_active Expired - Lifetime
- 1994-07-27 ES ES94111699T patent/ES2111811T3/es not_active Expired - Lifetime
- 1994-08-24 US US08/295,285 patent/US5498404A/en not_active Expired - Lifetime
- 1994-08-25 NO NO19943145A patent/NO311207B1/no not_active IP Right Cessation
- 1994-08-25 AU AU71473/94A patent/AU673451B2/en not_active Expired
- 1994-08-25 NZ NZ264308A patent/NZ264308A/en not_active IP Right Cessation
- 1994-08-26 ZA ZA946517A patent/ZA946517B/xx unknown
- 1994-08-26 JP JP6202443A patent/JP2958242B2/ja not_active Expired - Lifetime
- 1994-08-26 CA CA002130953A patent/CA2130953C/en not_active Expired - Lifetime
- 1994-08-26 KR KR1019940021186A patent/KR0124987B1/ko not_active Expired - Lifetime
- 1994-08-26 RU RU94031156A patent/RU2132228C1/ru active
Also Published As
Publication number | Publication date |
---|---|
EP0640560B1 (en) | 1998-01-07 |
NZ264308A (en) | 1996-03-26 |
NO943145D0 (no) | 1994-08-25 |
AU673451B2 (en) | 1996-11-07 |
EP0640560A1 (en) | 1995-03-01 |
DK97493D0 (da) | 1993-08-27 |
DK174087B1 (da) | 2002-06-03 |
JPH07144902A (ja) | 1995-06-06 |
NO943145L (no) | 1995-02-28 |
KR0124987B1 (ko) | 1997-11-27 |
DK97493A (da) | 1995-02-28 |
RU94031156A (ru) | 1996-08-20 |
ZA946517B (en) | 1995-03-28 |
JP2958242B2 (ja) | 1999-10-06 |
US5498404A (en) | 1996-03-12 |
NO311207B1 (no) | 2001-10-29 |
DE69407692D1 (de) | 1998-02-12 |
ES2111811T3 (es) | 1998-03-16 |
CA2130953C (en) | 2002-07-30 |
DE69407692T2 (de) | 1998-04-16 |
RU2132228C1 (ru) | 1999-06-27 |
CA2130953A1 (en) | 1995-02-28 |
AU7147394A (en) | 1995-03-09 |
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