[go: up one dir, main page]

RU2220959C1 - 4-аминопиколинаты и их применение в качестве гербицидов - Google Patents

4-аминопиколинаты и их применение в качестве гербицидов Download PDF

Info

Publication number
RU2220959C1
RU2220959C1 RU2002121652/04A RU2002121652A RU2220959C1 RU 2220959 C1 RU2220959 C1 RU 2220959C1 RU 2002121652/04 A RU2002121652/04 A RU 2002121652/04A RU 2002121652 A RU2002121652 A RU 2002121652A RU 2220959 C1 RU2220959 C1 RU 2220959C1
Authority
RU
Russia
Prior art keywords
alkoxy
halogen
trifluoromethyl
group
substituted
Prior art date
Application number
RU2002121652/04A
Other languages
English (en)
Other versions
RU2002121652A (ru
Inventor
Стефен Крэйг ФИЛДЗ (US)
Стефен Крэйг Филдз
Анита Ленора АЛЕКСАНДЕР (US)
Анита Ленора АЛЕКСАНДЕР
Терри Вилль м БАЛКО (US)
Терри Вилльям Балко
Лесли Энни БЬЕЛЬК (US)
Лесли Энни БЬЕЛЬК
Энн Мари БЮИСС (US)
Энн Мари БЮИСС
Рене Джоан КИСЕ (US)
Рене Джоан КИСЕ
Карл Леопольд КРУМЭЛ (US)
Карл Леопольд КРУМЭЛ
Вилль м Чи-Леунг ЛО (US)
Вилльям Чи-Леунг ЛО
Кристиан Томас ЛОУЭ (US)
Кристиан Томас ЛОУЭ
Джон Сандерс РИЧБУРГ (US)
Джон Сандерс РИЧБУРГ
Джеймс Мэлвин РУИЗ (US)
Джеймс Мэлвин РУИЗ
Original Assignee
Дау Агросайенсиз Ллс
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Дау Агросайенсиз Ллс filed Critical Дау Агросайенсиз Ллс
Application granted granted Critical
Publication of RU2002121652A publication Critical patent/RU2002121652A/ru
Publication of RU2220959C1 publication Critical patent/RU2220959C1/ru

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/79—Acids; Esters
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/26—Radicals substituted by halogen atoms or nitro radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/28—Radicals substituted by singly-bound oxygen or sulphur atoms
    • C07D213/30—Oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/28—Radicals substituted by singly-bound oxygen or sulphur atoms
    • C07D213/32—Sulfur atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/61—Halogen atoms or nitro radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/72—Nitrogen atoms
    • C07D213/74—Amino or imino radicals substituted by hydrocarbon or substituted hydrocarbon radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/89—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members with hetero atoms directly attached to the ring nitrogen atom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pyridine Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)

Abstract

Описываются соединения 4-аминопиколиновой кислоты формулы I:
Figure 00000001

где Х обозначает Н, галоген, C1-С6 алкокси, C1-C6 алкилтио, нитро, трифторметил; Y обозначает галоген, C1-С6 алкокси, трифторметил, фенокси, Z обозначает галоген, C1-С6 алкокси; W обозначает -NO2, -Т3, -NR1R2, где R1 и R2 независимо представляют Н, C1-С6 алкил, С3-С6 алкенил, гидрокси, C1-C6 алкокси, C1-С6 ацил или R1 и R2, взятые вместе с N, представляют пирролидин или пиррол; и их сельскохозяйственно-приемлемые соли, сложные C1-C12 эфиры или амиды. Описывается гербицидная композиция и способ борьбы с нежелательной растительностью. Технический результат заключается в подавлении широкого спектра сорняков в посевах риса, пшеницы, кукурузы. 3 с. и 7 з.п. ф-лы, 10 табл.

Description

Текст описания в факсимильном виде (см. графическую часть)а

Claims (10)

1. Соединения 4-аминопиколиновой кислоты формулы I
Figure 00000078
где Х представляет Н, галоген, C1-С6 алкокси, C1-С6 алкилтио, нитро или трифторметил;
Y представляет галоген, C1-C6 алкокси, трифторметил или феноксинезамещенный или замещенный одним или двумя заместителями, выбранными из хлора, метила или метокси;
Z представляет галоген или C1-C6 алкокси;
W представляет -NO2, -N3 или -NR1R2, где R1 и R2 независимо представляют Н, C1-C6 алкил, С3-С6 алкенил, гидрокси, C1-С6 алкокси или C1-C6 ацил или R1 и R2, взятые вместе с N, представляют пирролидин или пиррол,
и их сельскохозяйственно приемлемые соли, C1-C12 эфиры или амиды карбоновой кислоты, при условии, что когда Х представляет Н или Сl, тогда оба Y и Z не являются Сl, или когда оба Х и Z представляют Сl, тогда Y не является Вr.
2. Соединение по п.1, где Х представляет Н, галоген или трифторметил, Y представляет галоген, трифторметил или фенокси незамещенный или замещенный одним или двумя заместителями выбранными из хлора, метила или метокси, Z представляет галоген и W представляет -NR1R2, где R1 и R2 независимо представляют Н, C1-C6 алкил или С3-С6 алкенил или R1 и R2, взятые вместе с N, представляют пирролидин или пиррол, и их сельскохозяйственно приемлемые соли, C1-C12 эфиры или амиды карбоновой кислоты.
3. Соединение по п.1 или 2, где Х представляет Н или F, Y представляет F, Cl, Вr или фенокси незамещенный или замещенный одним или двумя заместителями выбранными из хлора, метила или метокси, Z представляет Сl и W представляет -NH2.
4. Соединение по любому из пп.1-3, где Y представляет феноксигруппу, замещенную галогеном или метильной группой в 3-положении.
5. Гербицидная композиция, включающая гербицидно эффективное количество 4-аминопиколината формулы I
Figure 00000079
где X представляет Н, галоген, C1-C6 алкокси, C1-С6 алкилтио, арилокси, нитро или трифторметил, Y представляет галоген, C1-C6 алкокси, C1-С6 алкилтио, трифторметил или феноксинезамещенный или замещенный одним или двумя заместителями выбранными из хлора, метила или метокси, Z представляет галоген, или C1-C6 алкокси и W представляет -NO2, -N3, или -NR1R2, где R1 и R2 независимо представляют H, C1-C6 алкил, С3-С6 алкенил, гидрокси, C1-C6 алкокси или C1-C6 ацил или R1 и R2, взятые вместе с N, представляют пирролидин или пиррол, и их сельскохозяйственно приемлемые соли, C1-C12 эфиры или амиды карбоновой кислоты при условии, что когда Х представляет Сl, тогда оба Y и Z не являются Сl, в смеси с сельскохозяйственно приемлемым адъювантом или носителем.
6. Гербицидная композиция по п.5, где Х представляет Н, галоген или трифторметил, Y представляет галоген, трифторметил или феноксинезамещенный или замещенный одним или двумя заместителями выбранными из хлора, метила или метокси, Z представляет галоген и W представляет -NR1R2, где R1 и R2 независимо представляют Н, C1-С6 алкил, С3-С6 алкенил или R1 и R2, взятые вместе с N, представляют пирролидин или пиррол, и их сельскохозяйственно приемлемые соли, C1-C12 эфиры или амиды карбоновой кислоты.
7. Гербицидная композиция по п.5 или 6, где Х представляет Н или F, Y представляет F, Сl, Вr или феноксинезамещенный или замещенный одним или двумя заместителями выбранными из хлора, метила или метокси, Z представляет Сl и W представляет -NH2.
8. Гербицидная композиция по любому из пп.5-7, где Y представляет феноксигруппу, замещенную галогеном или метильной группой в 3-положении.
9. Гербицидная композиция по п.5, включающая 4-амино-3,6-дихлорпиридин-2-карбоновую кислоту или ее сельскохозяйственно приемлемую соль, сложный эфир или амид.
10. Способ борьбы с нежелательной растительностью, который включает контактирование растительности или места ее произрастания либо внесение в почву для предотвращения появления всходов растительности гербицидно-эффективного количества гербицидной композиции по любому из пп.5-9.
RU2002121652/04A 2000-01-14 2001-01-12 4-аминопиколинаты и их применение в качестве гербицидов RU2220959C1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US17672000P 2000-01-14 2000-01-14
US60/176,720 2000-01-14

Publications (2)

Publication Number Publication Date
RU2002121652A RU2002121652A (ru) 2004-01-10
RU2220959C1 true RU2220959C1 (ru) 2004-01-10

Family

ID=22645557

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2002121652/04A RU2220959C1 (ru) 2000-01-14 2001-01-12 4-аминопиколинаты и их применение в качестве гербицидов

Country Status (26)

Country Link
EP (2) EP1498413B1 (ru)
JP (2) JP4388724B2 (ru)
KR (2) KR100560326B1 (ru)
CN (1) CN1281591C (ru)
AR (1) AR026836A1 (ru)
AT (2) ATE356807T1 (ru)
AU (1) AU760286B2 (ru)
BR (2) BRPI0117327B8 (ru)
CA (1) CA2396874C (ru)
CO (1) CO5231161A1 (ru)
CR (2) CR6696A (ru)
DE (1) DE60127233T2 (ru)
DK (2) DK1498413T3 (ru)
ES (2) ES2368326T3 (ru)
HU (1) HU228505B1 (ru)
IL (2) IL150701A0 (ru)
MX (1) MXPA02006933A (ru)
NO (1) NO323777B1 (ru)
NZ (1) NZ520244A (ru)
PL (1) PL212932B1 (ru)
PT (2) PT1246802E (ru)
RU (1) RU2220959C1 (ru)
TW (1) TWI235747B (ru)
UA (1) UA57184C2 (ru)
WO (1) WO2001051468A1 (ru)
ZA (1) ZA200205557B (ru)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2525918C2 (ru) * 2009-06-08 2014-08-20 ДАУ АГРОСЕЙЕНСИЗ ЭлЭлСи Способ получения 6-арил-4-аминопиколинатов
RU2627659C2 (ru) * 2012-07-24 2017-08-09 ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи Фторпиколиноилфториды и способы их получения
RU2653855C2 (ru) * 2012-12-13 2018-05-15 ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи Способ получения 4-амино-5-фтор-3-хлор-6-(замещенных)пиколинатов
RU2658825C2 (ru) * 2012-12-13 2018-06-25 ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи Способы получения 4-амино-3-галоген-6(замещенных)пиколинатов и 4-амино-5-фтор-3-галоген-6-(замещенных)пиколинатов

Families Citing this family (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AR037228A1 (es) * 2001-07-30 2004-11-03 Dow Agrosciences Llc Compuestos del acido 6-(aril o heteroaril)-4-aminopicolinico, composicion herbicida que los comprende y metodo para controlar vegetacion no deseada
UA82358C2 (ru) * 2003-04-02 2008-04-10 Дау Агросайенсиз Ллс 6-алкил или фенил-4-аминопиколинаты, гербицидная композиция, способ борьбы с нежелательной растительностью
UA81177C2 (ru) * 2003-08-04 2007-12-10 Дау Агросайєнсіз Ллс 6-(1,1-дифторалкил)- 4-аминопиколинаты и их использование в качестве гербицидов
TWI355894B (en) 2003-12-19 2012-01-11 Du Pont Herbicidal pyrimidines
TWI406849B (zh) * 2006-10-04 2013-09-01 Dow Agrosciences Llc 鹵化４-胺基吡啶甲酸之經改良的電化學還原反應
CA2693519C (en) 2007-08-27 2015-02-17 Dow Agrosciences Llc Synergistic herbicidal composition containing certain pyridine or pyrimidine carboxylic acids and certain cereal and rice herbicides
EP2052612A1 (de) 2007-10-24 2009-04-29 Bayer CropScience AG Herbizid-Kombination
EP2742802A1 (en) 2008-06-18 2014-06-18 Basf Se Ternary herbicidal compositions comprising aminopyralid and imazamox
EP2745695A1 (en) 2008-06-18 2014-06-25 Basf Se Herbicidal compositions comprising 4-amino-3,6-dichloropyridine-2-carboxylic acid
DE102008037629A1 (de) 2008-08-14 2010-02-18 Bayer Cropscience Ag Herbizid-Kombination mit Dimethoxytriazinyl-substituierten Difluormethansulfonylaniliden
CA2750539A1 (en) 2009-02-27 2010-09-02 Dow Agrosciences Llc N-alkoxyamides of 6-(substituted phenyl)-4-aminopicolinates and 2-(substituted phenyl)-6-amino-4-pyrimidinecarboxylates and their use as selective herbicides for crops
GB0910766D0 (en) * 2009-06-22 2009-08-05 Syngenta Ltd Chemical compounds
GB0917934D0 (en) 2009-10-13 2009-11-25 Syngenta Ltd Herbicidal compounds
EA020273B1 (ru) * 2010-03-22 2014-09-30 ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи Сильный гербицидный концентрат диметиламинной соли клопиралида низкой вязкости
GB201008290D0 (en) * 2010-05-18 2010-06-30 Syngenta Ltd Chemical compounds
BR112013009703A2 (pt) 2010-10-22 2018-05-22 Bayer Ip Gmbh ácidos picolínicos substituídos, seus sais e derivados de ácidos, bem como seu uso como herbicidas.
KR20140037804A (ko) * 2010-12-16 2014-03-27 바이엘 인텔렉쳐 프로퍼티 게엠베하 6-(2-아미노페닐)피콜리네이트 및 제초제로서의 그의 용도
EP2471776A1 (de) 2010-12-28 2012-07-04 Bayer CropScience AG Pyridin-2-ylpropandinitrile und deren Verwendung als Herbizide
TWI592401B (zh) * 2011-01-25 2017-07-21 陶氏農業科學公司 用於製備４－胺基－３－氯－５－氟－６－（經取代的）吡啶甲酸酯的方法（一）
TWI520943B (zh) 2011-01-25 2016-02-11 陶氏農業科學公司 用於製備４－胺基－３－氯－５－氟－６－（經取代的）吡啶甲酸酯的方法（二）
TWI529163B (zh) * 2011-01-25 2016-04-11 陶氏農業科學公司 用於製備４－胺基－５－氟－３－鹵素－６－（經取代之）吡啶甲酸酯的方法
TWI537252B (zh) * 2011-01-25 2016-06-11 陶氏農業科學公司 用於製備４－胺基－５－氟－３－鹵素－６－（經取代之）吡啶甲酸酯的方法（一）
US8754229B2 (en) * 2011-06-30 2014-06-17 Dow Agrosciences, Llc. 3-alkoxy, thioalkyl and amino-4-amino-6-(substituted)picolinates and their use as herbicides
CN103827102B (zh) 2011-07-27 2016-04-27 拜耳知识产权有限责任公司 取代的吡啶甲酸和嘧啶-4-羧酸、其制备方法及其作为除草剂和植物生长调节剂的用途
EP2894988A4 (en) * 2012-09-13 2016-06-08 Dow Agrosciences Llc HERBICIDAL COMPOSITIONS WITH AMINO-PYRALID AND PROPANIL
WO2014043156A1 (en) * 2012-09-13 2014-03-20 Dow Agrosciences Llc Herbicidal compositions comprising aminopyralid and bentazon
CN104994734B (zh) * 2012-12-14 2018-06-29 美国陶氏益农公司 由施用氯氨基吡啶酸和二氯吡啶酸进行协同杂草防治
ES2959637T3 (es) 2013-03-15 2024-02-27 Corteva Agriscience Llc 4-Amino-6-(heterocíclico)picolinatos y 6-amino-2-(heterocíclico)pirimidin-4-carboxilatos y su uso como herbicidas
US9637505B2 (en) 2013-03-15 2017-05-02 Dow Agrosciences Llc 4-amino-6-(heterocyclic)picolinates and 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their use as herbicides
PL2967057T3 (pl) 2013-03-15 2019-05-31 Dow Agrosciences Llc Nowe karboksylany 4-aminopirydyny i 6-aminopirymidyny jako herbicydy
US9113629B2 (en) 2013-03-15 2015-08-25 Dow Agrosciences Llc 4-amino-6-(4-substituted-phenyl)-picolinates and 6-amino-2-(4-substituted-phenyl)-pyrimidine-4-carboxylates and their use as herbicides
CN104621141A (zh) * 2013-11-15 2015-05-20 南京华洲药业有限公司 一种含氯氨吡啶酸与恶唑酰草胺的混合除草剂
CN104621112A (zh) * 2013-11-15 2015-05-20 南京华洲药业有限公司 一种含氯氨吡啶酸与毒莠定的混合除草剂
CN104621107A (zh) * 2013-11-15 2015-05-20 南京华洲药业有限公司 一种含氯氨吡啶酸与高效氟吡甲禾灵的混合除草剂
CN104621109A (zh) * 2013-11-15 2015-05-20 南京华洲药业有限公司 一种含氯氨吡啶酸与烯草酮的混合除草剂
CN104621116A (zh) * 2013-11-15 2015-05-20 南京华洲药业有限公司 一种含氯氨吡啶酸与氰氟草酯的混合除草剂
CN104686534A (zh) * 2013-12-06 2015-06-10 南京华洲药业有限公司 一种含氯氨吡啶酸和异恶草酮的混合除草剂
JP2017504582A (ja) * 2013-12-12 2017-02-09 ダウ アグロサイエンシィズ エルエルシー ４−アミノ−６−（ハロ置換−アルキル）−ピコリネートおよび除草剤としてのその使用
CN106146393A (zh) * 2015-04-14 2016-11-23 利尔化学股份有限公司 制备3,4,6-三氯吡啶-2-甲酸及其相应酯的方法
CN106279012B (zh) * 2015-06-09 2019-04-09 利尔化学股份有限公司 一种3,4,6-三氯吡啶-2-甲酸及其酯的制备方法
CN105820115A (zh) * 2016-06-01 2016-08-03 山东润博生物科技有限公司 一种环境友好型氨氯吡啶酸盐的制备方法
CN107778226B (zh) * 2016-08-26 2019-07-02 利尔化学股份有限公司 一种4-氨基-3，6-二氯吡啶-2-甲酸的纯化方法
US20190110473A1 (en) * 2017-09-19 2019-04-18 Dow Agrosciences Llc Synergistic weed control from applications of pyridine carboxylic acid herbicides and photosystem ii inhibitors
EP3897140A1 (en) 2018-12-18 2021-10-27 BASF Agrochemical Products B.V. Herbicidal combinations
CN109553574B (zh) * 2018-12-27 2020-07-24 北京颖泰嘉和生物科技股份有限公司 吡啶酸类化合物及其制备方法、除草剂组合物及其应用
CN110514766B (zh) * 2019-09-11 2022-03-01 中国检验检疫科学研究院 一种食品中三氯甲基吡啶的测定方法
EP4027790A1 (en) 2019-09-13 2022-07-20 Adama Agan Ltd. Herbicidal mixtures comprising aminopyralid and quinmerac

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3285925A (en) * 1962-03-06 1966-11-15 Dow Chemical Co Amino-trichloropicolinic acid compounds
FR1426923A (fr) * 1964-07-20 1966-02-04 Prod Chim Ind Et Agricoles Pro Nouveaux mélanges herbicides
US3325272A (en) * 1965-06-23 1967-06-13 Dow Chemical Co Plant growth control methods and compositions
US3607877A (en) * 1968-10-31 1971-09-21 Dow Chemical Co Process for converting aromatic thiols to nitroso and nitro compounds
GB1363415A (en) * 1970-08-04 1974-08-14 Ici Ltd Bis-pyridyl amine compounds
US3755338A (en) * 1970-12-17 1973-08-28 Dow Chemical Co 4-amino-6-bromo-3,5-dichloropicolinic acid compounds
BE788756A (en) * 1971-08-02 1973-03-13 Dow Chemical Co 4-amino-3,5dihalo- 6-alkyl picolinic acid derivs - selective herbicides
IL91083A (en) * 1988-07-25 1993-04-04 Ciba Geigy Cyclohexanedione derivatives, their preparation and their use as herbicides
US6204221B1 (en) * 1996-11-12 2001-03-20 Syngenta Crop Protection, Inc. Herbicides

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2525918C2 (ru) * 2009-06-08 2014-08-20 ДАУ АГРОСЕЙЕНСИЗ ЭлЭлСи Способ получения 6-арил-4-аминопиколинатов
RU2627659C2 (ru) * 2012-07-24 2017-08-09 ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи Фторпиколиноилфториды и способы их получения
RU2653855C2 (ru) * 2012-12-13 2018-05-15 ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи Способ получения 4-амино-5-фтор-3-хлор-6-(замещенных)пиколинатов
RU2658825C2 (ru) * 2012-12-13 2018-06-25 ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи Способы получения 4-амино-3-галоген-6(замещенных)пиколинатов и 4-амино-5-фтор-3-галоген-6-(замещенных)пиколинатов

Also Published As

Publication number Publication date
NZ520244A (en) 2003-07-25
ES2368326T3 (es) 2011-11-16
KR20050053748A (ko) 2005-06-08
HUP0204118A2 (hu) 2003-03-28
CN1281591C (zh) 2006-10-25
UA57184C2 (ru) 2003-06-16
NO20023370D0 (no) 2002-07-12
BRPI0107649B8 (pt) 2022-06-28
BR0107649B1 (pt) 2013-11-12
RU2002121652A (ru) 2004-01-10
WO2001051468A1 (en) 2001-07-19
BRPI0117327B8 (pt) 2022-06-28
HU228505B1 (en) 2013-03-28
CO5231161A1 (es) 2002-12-27
JP2003519685A (ja) 2003-06-24
EP1498413A1 (en) 2005-01-19
EP1498413B1 (en) 2011-08-31
EP1246802A1 (en) 2002-10-09
JP4388724B2 (ja) 2009-12-24
EP1246802B1 (en) 2007-03-14
AU2945301A (en) 2001-07-24
JP2009149611A (ja) 2009-07-09
JP4986977B2 (ja) 2012-07-25
ATE356807T1 (de) 2007-04-15
PL212932B1 (pl) 2012-12-31
HUP0204118A3 (en) 2003-04-28
AU760286B2 (en) 2003-05-08
PT1498413E (pt) 2011-11-02
AR026836A1 (es) 2003-02-26
CR6696A (es) 2008-09-22
TWI235747B (en) 2005-07-11
CA2396874C (en) 2007-03-27
ATE522506T1 (de) 2011-09-15
NO20023370L (no) 2002-08-19
IL150701A (en) 2008-11-03
KR100560326B1 (ko) 2006-03-14
CR20130237A (es) 2013-09-03
CN1416419A (zh) 2003-05-07
DE60127233D1 (de) 2007-04-26
BR0107649A (pt) 2002-10-08
MXPA02006933A (es) 2003-01-28
DK1498413T3 (da) 2011-12-05
IL150701A0 (en) 2003-02-12
CA2396874A1 (en) 2001-07-19
ZA200205557B (en) 2003-07-11
KR20020069513A (ko) 2002-09-04
BR0117327B1 (pt) 2014-11-04
DK1246802T3 (da) 2007-07-16
PL356588A1 (en) 2004-06-28
PT1246802E (pt) 2007-06-18
KR100560324B1 (ko) 2006-03-14
ES2279817T3 (es) 2007-09-01
DE60127233T2 (de) 2008-01-03
NO323777B1 (no) 2007-07-02

Similar Documents

Publication Publication Date Title
RU2220959C1 (ru) 4-аминопиколинаты и их применение в качестве гербицидов
RU2221787C2 (ru) Производные 3-гидрокси-4-арил-5-оксопиразолина, обладающие гербицидным действием, композиция и способ борьбы с нежелательной растительностью
JP2793956B2 (ja) トリアジン誘導体およびそれを有効成分とする除草剤
EA200600606A1 (ru) 2-цианобензолсульфонамиды для борьбы с вредителями
TR200200210T2 (tr) Ftalamid türevleri, bunların üretimindeki ara maddeler.
EA200600631A1 (ru) 2-галоид-6-алкилфенилзамещённые производные тетрамовой кислоты
JPS6310749A (ja) Ｎ−ベンジル２−（４−フルオル−３−トリフルオルメチルフエノキシ）ブタン酸アミド及びそれを含有する除草剤
MD20090049A (ro) Compusi benzoilpirazolici, procedeu de preparare a lor si erbicide care le contin
EA200601077A1 (ru) Производные n-арилгидразина для обработки семян
SU1271371A3 (ru) Способ получени производных простого дифенилового эфира
DK1209975T3 (da) Herbicid sammensætning
RU2007147418A (ru) Соединения 1-(1,2-дифенил-этил)-3-(2-гидроксиэтил)-тиомочевины, предназначенные для борьбы с животными-вредителями
RU95113207A (ru) Способ подавления нежелательных видов растительности, способ селективного подавления однодольных сорняков в присутствии культурных растений, производные 4-(2,6-дизамещенных фенокси)-кумаринов, способ их получения, гербицидная композиция
RU2223271C2 (ru) Бензоилпроизводные соединения и гербицидное средство на их основе
RU94046293A (ru) Производные сульфониламино(тио)карбонила и их соли, способ их получения, гербицидное средство и способ его получения, способ борьбы с сорной растительностью
RU97110291A (ru) Новые синергитические гербицидные композиции, содержащие 4-бензоилизоксазолы и 2,6-динитроанилиновые гербициды
DE60002869D1 (de) Pestizide zusammensetzung und verfahren zur bekämpfung von schädlingen
RU2220973C2 (ru) Замещенное пятичленное гетероциклическое соединение, фунгицидная композиция, содержащая его, способ его получения, способ борьбы с заболеваниями растений
AU3452795A (en) N-arylthiohydrazone derivatives as insecticidal and acaricidal agents
JPS5948403A (ja) 水田用除草剤
EA200400989A1 (ru) Гербицидная композиция
EA200601550A1 (ru) Способ борьбы с сорняками
KR970707119A (ko) 트리아졸 유도체, 그를 함유하는 제초제 조성물, 및 그의 사용방법(triazole derivatives, herbicide composition containing the same, and method for using the same)
CA2302839A1 (en) Process for the preparation of 1-phenylpyrazoline-3-carboxylic acid derivatives
JPS5976045A (ja) α，α−ジメチルフエニル酢酸アニリド誘導体、その製造法及びそれを含有する除草剤