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KR930019750A - 코모노머서 α-올레핀을 함유하는 프로펜의 랜덤 공중합체 조성물 - Google Patents

코모노머서 α-올레핀을 함유하는 프로펜의 랜덤 공중합체 조성물 Download PDF

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KR930019750A
KR930019750A KR1019930003573A KR930003573A KR930019750A KR 930019750 A KR930019750 A KR 930019750A KR 1019930003573 A KR1019930003573 A KR 1019930003573A KR 930003573 A KR930003573 A KR 930003573A KR 930019750 A KR930019750 A KR 930019750A
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weight
fraction
olefin
polyolefin composition
composition according
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KR1019930003573A
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KR100253015B1 (ko
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세킨 기울리아노
구글리엘미 플로리아노
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케빈 이. 왈쉬
히몬트 인코포레이티드
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/14Copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/14Copolymers of propene
    • C08L23/142Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00Chemical blending or stepwise polymerisation process with the same catalyst

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
  • Medicinal Preparation (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

A) 1∼10중량%의 C4∼C10α-올레핀을 함유하는, 20∼60중량%의 프로펜/C4∼C10α-올레핀 랜덤 공중합체(분획 A), 분획 A에 존재하는 것과 동일하거나 상이한 15∼40중량%의 C4∼C10α-올레핀을 함유하는, 40∼80중량%의 프로펜/C4∼C10α-올레핀 랜덤 공중합체(분획B)를 함유함을 특징으로 하는 반결정질 폴리올레핀 조성물.
(상기에서, 총 조성물에 대한 분획 B의 중량%(%B) 및 분획 B중이 C4∼C10α-올레핀의 중량%(C4 b≥1200을 만족한다.)

Description

코모노머서 α-올레핀을 함유하는 프로펜의 랜덤 공중합체 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

1∼10중량%의 C4∼C10α-올레핀을 함유하는, 20∼60중량%의 프로펜/C4∼C10α-올레핀 랜덤 공중합체(분획 A), 분획 A에 존재하는 것과 동일하거나 상이한 15∼40중량%의 C4∼C10α-올레핀을 함유하는, 40∼80중량%의 프로펜/C4∼C10α-올레핀 랜덤 공중합체(분획B)를 함유함을 특징으로 하는 반결정질 폴리올레핀 조성물.(상기에서, 총 조성물에 대한 분획 B의 중량%(%B) 및 분획 B중이 C4∼C10α-올레핀의 중량%(C4 b≥1200을 만족한다.)
제1항에 있어서, 분획 A와 B의 C4∼C10α-올레핀이 동일한 반결정질 폴리올레핀 조성물.
제1항에 있어서, 분획 A가 25∼50중량%이고 분휙 B가 50∼70중량%인 반결정질 폴리올레핀 조성물.
제1항에 있어서, C4∼C10α-올레핀이 1-부텐, 1-펜텐, 1-헥센, 1-옥텐 및 4-메틸-1-펜텐으로 구성된 군으로 부터 선택된 반경정질 폴리올레핀 조성물.
제1항에 있어서, 분휙 A중의 C4∼C10α-올레핀이 3∼8중량%인 반결정질 폴리올레핀 조성물.
제1항에 있어서, 분휙 B중의 C4∼C10α-올레핀이 20∼30중량%인 반결정질 폴리올레핀 조성물
제1항에 있어서, 25∼에서 크실렌에 가용성인 분획이 20중량%미만인 반결정질 폴리올레핀 조성물.
활성 형태의 활성 마그네슘 디할라이드 상에 지지된 입체 특이서 촉매 존재하에, 분휙 A와 B가 형성되는 2이사으이 별도 및 연속단계로 단량체를 중합시키고, 각 단계를 중합체와 바로 전단계에 사용된 촉매의 존재하에 수행함을 특징으로 하는 반결정질 폴리올레핀 조성물의 제조방법.
제8항에 있어서, 모든 중합 단계가 기체상에서 수행되는 제조방법.
제8항에 있어서, 제1단계가 액체 단량체로, 제2단계가 기체상으로 수행되는 제조방법.
※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930003573A 1992-03-10 1993-03-10 코모노머로서알파-올레핀을 함유하는 프로펜의 랜덤 공중합체 조성물 Expired - Fee Related KR100253015B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ITMI92A000545 1992-03-10
ITMI92A00054 1992-03-10
ITMI920545A IT1254244B (it) 1992-03-10 1992-03-10 Composizioni di copolimeri random del propene contenenti una alfa- olefina come comonomero

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KR930019750A true KR930019750A (ko) 1993-10-18
KR100253015B1 KR100253015B1 (ko) 2000-04-15

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EP (1) EP0560326B1 (ko)
JP (1) JP3452601B2 (ko)
KR (1) KR100253015B1 (ko)
CN (1) CN1082979C (ko)
AT (1) ATE153683T1 (ko)
AU (1) AU664598B2 (ko)
BR (1) BR9301113A (ko)
CA (1) CA2091299C (ko)
DE (1) DE69310961T2 (ko)
ES (1) ES2103990T3 (ko)
FI (1) FI112245B (ko)
IT (1) IT1254244B (ko)
MX (1) MX9301317A (ko)
NO (1) NO301771B1 (ko)
RU (1) RU2104289C1 (ko)
TW (1) TW281681B (ko)

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NO930863D0 (no) 1993-03-09
ATE153683T1 (de) 1997-06-15
ES2103990T3 (es) 1997-10-01
KR100253015B1 (ko) 2000-04-15
RU2104289C1 (ru) 1998-02-10
CN1082979C (zh) 2002-04-17
AU3513893A (en) 1993-09-16
ITMI920545A1 (it) 1993-09-10
FI931040A0 (fi) 1993-03-09
EP0560326A1 (en) 1993-09-15
CN1076937A (zh) 1993-10-06
MX9301317A (es) 1993-09-01
CA2091299A1 (en) 1993-09-11
DE69310961T2 (de) 1997-11-27
BR9301113A (pt) 1993-09-14
EP0560326B1 (en) 1997-05-28
NO301771B1 (no) 1997-12-08
JPH0693146A (ja) 1994-04-05
DE69310961D1 (de) 1997-07-03
ITMI920545A0 (it) 1992-03-10
FI931040L (fi) 1993-09-11
CA2091299C (en) 2001-06-12
AU664598B2 (en) 1995-11-23
NO930863L (no) 1993-09-13
IT1254244B (it) 1995-09-14
TW281681B (ko) 1996-07-21
FI112245B (fi) 2003-11-14

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