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KR930008022A - 말레이미드 조성물, 수지 침투 가공재 및 섬유 강화 플라스틱 - Google Patents

말레이미드 조성물, 수지 침투 가공재 및 섬유 강화 플라스틱 Download PDF

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Publication number
KR930008022A
KR930008022A KR1019920019490A KR920019490A KR930008022A KR 930008022 A KR930008022 A KR 930008022A KR 1019920019490 A KR1019920019490 A KR 1019920019490A KR 920019490 A KR920019490 A KR 920019490A KR 930008022 A KR930008022 A KR 930008022A
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South Korea
Prior art keywords
resin composition
maleimide
maleimide resin
general formula
fiber
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KR1019920019490A
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English (en)
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하지메 키시
마사즈미 토쿠노오
노브유키 오다기리
Original Assignee
니시무라 켄
토오레 카부시키가이샤
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Publication of KR930008022A publication Critical patent/KR930008022A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
    • C08L79/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C08L79/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/12—Unsaturated polyimide precursors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
    • C08J5/042—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with carbon fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/243—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using carbon fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/01—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/06—Elements
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
    • C08L79/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C08L79/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08L79/085—Unsaturated polyimide precursors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2379/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2361/00 - C08J2377/00
    • C08J2379/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C08J2379/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Reinforced Plastic Materials (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

메트릭스수지로서 본 발명의 말레이미드 수지 조성물을 보유하는 수지 침투가공재 및 강화섬유플라스틱과 더불어 고인성, 고탄성률, 고내열성, 고내열분해성, 저흡수성 및 고내용제성을 보유하는 경화플라스틱을 제공하는 말레이미드수지 조성물이 공개되었다.
본 발명의 말레이미드수지 조성물은 말레이미드수지〔A〕및 폴리이미드분자의 말단에 아미노기 및/또는 말레이미드기를 보유하며, 일반식〔Ⅰ〕및/또는〔Ⅱ〕의 순환단위로 구성되는 폴리이미드수지〔B〕로 이루어진다.
(식중 X는 테트라카르복실산 이무수잔유물을 나타낸다.)
(식중 Z는 일반식〔Ⅰ〕과 동일한 의미로 사용된다.)

Description

말레이미드 조성물, 수지 침투 가공재 및 섬유 강화 플라스틱
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도-제3도는 경화수지의 변형에너지해방률을 측정하기 위한 이중 비틀림법을 설명한 것이다.

Claims (12)

  1. 말레이미드수지〔A〕및 폴리이미드분자의 말단에 아미노기 및/또는 말레이미드기를 보유하며, 일반식〔Ⅰ〕및/또는〔Ⅱ〕의 순환단위로 구성되는 폴리이미드수지〔B〕로 이루어지는 것을 특징으로 하는 말레이미드수지조성물.
    (식중 Z는 테트라카르복실산 이무수잔유물을 대표한다.)
    (식중 Z는 일반식〔Ⅰ〕과 동일한 의미로 사용된다.)
  2. 제1항에 있어서, 상기한 폴리이미드수지〔B〕가 일반식〔Ⅲ〕및/또는〔Ⅳ〕로 대표되는 아민단위를 공중합성분으로서 함유하는 것을 특징으로 하는 말레이미드수지조성물.
    (식중 X는 -CO-, -SO2-, -O-, -S- 또는 -C(M)2-, M은 수소원자, C1-C5인 알킬, 알릴 또는 C1-C5인 할로알킬을 나타낸다.)
    (식중 X는 일반식〔Ⅲ〕과 동일한 의미로 사용된다.)
  3. 제1항에 있어서, Z로 대표되는 상기한 테트라카르복실산 이무수잔유물은 일반식〔Ⅴ〕로 대표되는 것을 특징으로 하는 말레이미드수지조성물.
    (식중 Y는 -CO-, -SO2-, -O- 또는 -C(M)2-M은 수소원자, C1-C5인 알킬, 알릴 또는 C1-C5인 할로알킬 및 n은 0 또는 1인 정수를 나타낸다.)
  4. 제1항에 있어서, 상기한 말레이미드수지〔A〕는 디아미노디페닐 메탄비스말레이미드 및/또는 m-페닐렌디말레이미드로 이루어지는 것을 특징으로 하는 말레이미드 수지조성물.
  5. 제1항에 있어서, 상기한 말레이미드수지〔A〕의 반응성 희석제로서 방향족 알릴 화합물을 함유하는 것을 특징으로 하는 말레이미드수지조성물.
  6. 제1항에 있어서, 상기한 폴리이미드수지의 중량이 상기한 말레이미드수지 조성물의 중량에 대하여 5-40중량%인 것을 특징으로 하는 말레이미드수지조성물.
  7. 제6항에 있어서, 상기한 폴리이미드수지〔B〕의 수평균분자량이 2000-20000인 것을 특징으로 하는 말레이미드수지조성물.
  8. 제1항 내지 제7항중 어떠한 항에 있어서, 상기한 말레이미드수지조성물과 강화섬유로 이루어지는 것을 특징으로 하는 섬유 침투가공재.
  9. 제8항에 있어서, 상기한 강화섬유는 탄성섬유 및/또는 흑연섬유인 것을 특징으로 하는 섬유 침투가공재.
  10. 제8항에 있어서, 상기한 섬유 침투가공재를 경화시켜서 제조하는 것을 특징으로 하는 섬유 강화플라스틱.
  11. 제10항에 있어서, 상기한 폴리이미드수지〔B〕는 상기한 경화 말레이미드수지 조성물중에 3차원 연속상으로 구성되는 것을 특징으로 하는 섬유 강화플라스틱.
  12. 제9항에 있어서, 상기한 수지침투가공재를 경화시켜서 제조하는 것을 특징으로 하는 섬유 강화플라스틱.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920019490A 1991-10-22 1992-10-22 말레이미드 조성물, 수지 침투 가공재 및 섬유 강화 플라스틱 KR930008022A (ko)

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JP27426891 1991-10-22
JP91-274268 1991-10-22

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KR930008022A true KR930008022A (ko) 1993-05-20

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US (1) US5438104A (ko)
EP (1) EP0540250B1 (ko)
JP (1) JPH05255564A (ko)
KR (1) KR930008022A (ko)
DE (1) DE69219065D1 (ko)

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Publication number Priority date Publication date Assignee Title
EP2371536B1 (en) * 2008-12-26 2018-10-24 Mitsubishi Gas Chemical Company, Inc. Copper foil with resin
GB201121304D0 (en) * 2011-12-12 2012-01-25 Hexcel Composites Ltd Improved composite materials
US9783631B2 (en) * 2014-12-19 2017-10-10 The University Of Akron Synthesis and characterization of UV-curable maleimide-terminated imide oligomers
WO2019054297A1 (ja) * 2017-09-13 2019-03-21 三菱瓦斯化学株式会社 ポリイミド、ポリイミドワニス、及びポリイミドフィルム
WO2019225435A1 (ja) 2018-05-22 2019-11-28 ダイキン工業株式会社 樹脂組成物
JP6872081B2 (ja) * 2019-03-15 2021-05-19 日本化薬株式会社 ポリアミック酸樹脂、ポリイミド樹脂およびこれらを含む樹脂組成物
JP7387235B2 (ja) * 2020-11-12 2023-11-28 信越化学工業株式会社 熱硬化性マレイミド樹脂組成物、並びにその樹脂組成物からなる未硬化樹脂フィルム及び硬化樹脂フィルム
JP7330648B2 (ja) * 2020-11-12 2023-08-22 信越化学工業株式会社 熱硬化性マレイミド樹脂組成物、並びにその樹脂組成物からなる未硬化樹脂フィルム及び硬化樹脂フィルム

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CH615935A5 (ko) * 1975-06-19 1980-02-29 Ciba Geigy Ag
JPS59191726A (ja) * 1983-04-15 1984-10-30 Mitsubishi Electric Corp 熱硬化性樹脂組成物
US4985509A (en) * 1985-04-18 1991-01-15 Hitachi, Ltd. Heat curable resin composition
JP2625689B2 (ja) * 1985-11-18 1997-07-02 淑夫 今井 単分子又は単分子累積膜の製造方法
US5112924A (en) * 1987-07-15 1992-05-12 Hercules Incorporated Bismaleimide compositions containing high glass transition temperature and soluble reactive oligomers and composites prepared therefrom
US5194518A (en) * 1989-09-01 1993-03-16 Nitto Denko Corporation Thermosetting resin composition comprising perfluoro containing amine terminated oligomer and polymaleimide

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EP0540250A1 (en) 1993-05-05
JPH05255564A (ja) 1993-10-05
DE69219065D1 (de) 1997-05-22
US5438104A (en) 1995-08-01
EP0540250B1 (en) 1997-04-16

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Patent event code: PA01091R01D

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Patent event date: 19921022

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