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KR900003349A - 알릴-유도된 설폰화 말단 캡을 갖는 방오제 - Google Patents

알릴-유도된 설폰화 말단 캡을 갖는 방오제 Download PDF

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KR900003349A
KR900003349A KR1019890012195A KR890012195A KR900003349A KR 900003349 A KR900003349 A KR 900003349A KR 1019890012195 A KR1019890012195 A KR 1019890012195A KR 890012195 A KR890012195 A KR 890012195A KR 900003349 A KR900003349 A KR 900003349A
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sulfonated
sulfonation
atm
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moles
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존 쉐이벨 제프리
폴 고젤링크 유진
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리차드 챨스 위트
더 프록터 앤드 갬블 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/688—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur
    • C08G63/6884—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/6886—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/91—Polymers modified by chemical after-treatment
    • C08G63/914—Polymers modified by chemical after-treatment derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/918—Polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3715—Polyesters or polycarbonates

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Abstract

내용 없음

Description

알릴-유도된 설폰화 말단 캡을 갖는 방오제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (17)

1몰당 알릴알콜 및 메탈릴 알콜중에서 선택된 올레핀계 불포화 성분으로부터 유도된 말단 단위 1몰 내지 2몰 ; 산화에틸렌 50% 내지 100%를 포함하는 에테르 성분으로부터 유도된 비이온성 친수성 단위 1몰 내지 4몰 ; 디메틸테레프탈레이트 50% 내지 100%를 포함하는 아릴디카보닐 성분으로부터 유도된 반복된위 1.1몰 내지 20몰 ; 및 C2-, C3- 및 C4글리콜중에서 선택된 디올 성분으로부터 유도된 반복 단위 0.1몰 내지 19몰을 포함하는 예비형성된, 실질적으로 선형인 에스테르 올리고머의 설폰화된 생성물을 포함하는 설폰화된 올리고머성 에스테르 조성물[여기서, 설폰화된 올리고머성 에스테르 조성물은 말단 단위가 HSO3M(여기서, M은 통상적인 수용성 양이온이다)중에서 선택된 비설파이트 성분으로부터 유도된, 일반식 -SOxM(여기서, x는 2 또는 3이다)의 말단 단위 치환체 그룹 1몰 내지 4몰에 의해 화학적으로 변형되는 정도로 설폰화된다].
제1항에 있어서, 말단 단위가 필수적으로 알릴 알콜을 포함하는 올레핀계 불포화 성분으로부터 유도되고 ; 평균 중합도가 4 내지 30인 비이온성 친수성 단위가 필수적으로 사화 에틸렌을 포함하는 에테르 성분으로부터 유도되며 ; 반복단위가 80% 내지 100% 디메틸-테레프탈레이트를 함유하는 아릴디카보닐 성분 및 필수적으로 에틸렌 글리콜 및 1,2-프로필렌 글리콜의 혼합물(여기서, 에틸렌 글리콜 : 1,2-프로필렌 글리콜 몰비는 0 : 1 내지 0.9 : 0.1의 범위이다)을 포함하는 디올 성분의 혼합물로부터 유도되는 설폰화된 올리고머성 에스테르 조성물.
제2항에 있어서, 비이온성 친수성 단위의 평균 중합도가 8 내지 20이고, 에틸렌 글리콜 : 1,2-프로필렌 글리콜 몰비가 0:1 내지 0.4:0.6의 범위인 설폰화된 올리고머성 에스테르 조성물.
제2항에 있어서, 평균중합도 8 내지 20으로 에톡실화된 알릴알콜 약 2몰 ; 디메틸 테레프탈레이트 2내지 7몰 ; 및 1,2-프로필렌 글리콜 또는 이의 에틸렌 글리콜과의 혼합물 2 내지 14몰의 혼합물을 반응시킴을 포함하는 트랜스에스테르화 단계(여기서, 트랜스에스테르화 단계는 통상적인 트랜스에스테르화 촉매의 존재하에서, 0.75atm, 내지 3atm. 범위의 트랜스에스테르화 압력 및 120℃ 내지 250℃의 트랜스에스테르화 온도에서, 2시간 내지 60시간의 트랜스에스테르화 시간동안 수행된다) ; 및 이어서 언급된 혼합물을 170℃ 내지 250℃ 범위의 올리고머화 온도에서, 1×10-6atm 내지 0.5atm 범위의 올리고머화 압력하에서, 2시간 내지 60시간의 올리고머화 시간동안 추가로 반응시켜 알릴 말단-캐핑(capping)된 코-올리고머성 에스테르 전구체를 형성시킴을 포함하는 올리고머화 단계를 포함하는 에스테르-결합 형성 공정 ; 및 이어서 라디칼-개시된 올레핀 설폰화 공정을 포함하는 방법의 생성물을 포함함을 추가의 특징으로 하는 설폰화된 올리고머성 에스테르 조성물.
제4항에 있어서, 라디칼-개시된 올레핀 설폰화 공정이 물의 존재하에서, 알릴 말단-캐핑된 코-올리고머성 에스테르 전구체를 저온, 유리-라디칼 설폰화 개시제 및 통상적인 비닐설파이트 설폰화제로 설폰화시키는 적어도 하나의 단계(여기서, 반응물은 수성 반응 혼합물중에서 효과적으로 접촉되고, 통상적인 비설파이트 설폰화제의 수준은 알릴 말단-캐핑된 코-올리고머성 에스테르 전구체의 몰당 1몰 내지 4몰이며, 설폰화 온도는 0℃ 내지 100℃이고, 설폰화 압력은 0.5atm. 내지 3atm. 이며, 설폰화 시간은 0.1시간 내지 90시간이다)를 포함하는 설폰호된 올리고머성 에스테르 조성물.
제5항에 있어서, 트랜스에스테르화 온도가 160℃, 내지 230℃의 범위이고 ; 트랜스에스테르화 압력이 1atm. 내지 2atm.의 범위이며 ; 트랜스에스테르화 시간이 5시간 내지 25시간의 범위이고 ; 올리고머화 온도가 180℃ 내지 220℃의 범위이며 ; 올리고머화 압력이 1×10-4atm.의 범위이고 ; 올리고머화 시간이 5시간 내지 25시간의 범위인 설폰화된 올리고머성 에스테르 조성물.
제6항에 있어서, 저온 유리-라디칼 설폰화 개시제가 아조 개시제 및 레독스 개시제로부터 선태되고, 아조 개시제를 사용하는 경우에 설폰화 온도가 40℃ 내지 65℃이고 ; 설폰화 압력이 1atm. 내지 3atm.이며; 설폰화 시간이 10시간 내지 30시간이고 ; 레독스 개시제를 사용하는 경우에 설폰화 온도가 0℃ 내지 40℃이고 ; 설폰화 압력이 0.5atm. 내지 3atm. 이며 ; 설폰화 시간이 0.1 내지 24시간인 설폰화된 올리고머성 에스테르 조성물.
제6항에 있어서, 방법이 설폰화 생성물을 과산화수소롤 처리하는 추가의 단계를 포함하는 설폰화된 올리고머성 에스테르 조성물.
a) 평균 중합도 8 내지 20으로 에톡실화된 알릴알콜 약 2몰, 디메틸 테레프탈레이트 2 내지 7몰 및 C2-C4글리콜 2 내지 14몰의 혼합물을 120℃ 내지 250℃ 범위의 트랜스에스테르화 온도에서, 0.75atm. 내지 3atm. 범위의 트랜스에스테르화 압력에서 2시간 내지 60시간의 트랜스에스테르화 시간 동안 반응시킴을 특징으로 하는 트랜스에스테르화 단계 및 ; 이어서 상기 혼합물을 170℃ 내지 250℃ 범위의 오릴고머화 온도에서, 1×10-(atm. 내지 0.5atm. 범위의 올리고머화 압력에서 2시간 내지 60시간의 올리고머화 시간 동안 추가로 반응시켜 알릴 말단-캐핑된 코-올리고머성 에스테르 전구체를 형성시킴을 특징으로 하는 올리고머화 단계를 포함하는 에스테르-결합 형성 공정 ; 및 b) 적어도 한 단계에서 생성된 알릴 말단-캐핑된 코-올리고머성 에스테르 전구체를 물의 존재하에서, 저온, 유리-라디칼 설폰화 개시제 및 통상적인 비설파이트 설폰화제로 설폰화시킴을 특징으로 하는 라디칼-개시된 올레핀 설폰화 공정(여기서, 반응물은 수성 반응 혼합물중에서 효과적으로 동시접촉시키고, 통상적인 비설파이트 설폰화제의 수준은 언급한 알릴 말단-캐핑된 코-올리고머성 에스테르 전구체의 몰당 1몰 내지 4몰이며, 설폰화 온도는 0℃ 내지 100℃ 범위이고, 설폰화 압력은 0.5atm. 내지 3atm. 범위이며 설폰화 시간은 0.1시간 내지 90시간이다)을 포함함을 특징으로 하여, 특정한 말단적으로 설폰화된, 실질적으로 선형인 코-올리고머성 에스테르 조성물이 염소화 화합물 및 설폰화 단계에 이어 에톡실화 단계를 포함하는 공정에 관계없이 보전되는, 세정제 조성물중에 작용성 물질로서 유용한 설폰화된 에스테르 조성물을 제조하는 방법.
필수적으로 (i) 테레프탈로일(단위(c)) 및 옥시-1,2-프로필렌옥시(단위(d)) 반복단위의 주쇄 85 내지 100중량%로 이루어진, 실질적으로 선형인 올리고머성 에스테르 주쇄 ; 및 (ⅱ) 상기 주쇄에 공유결합된 말단잔기[여기서, 말단 잔기는 -(En)-(CH2-CH{SO3Na}-CH2{SO3Na}), -(En)-(CH2-CH{S03Na}-CH2{SO3Na}), 및 -(En)-(CH2-CH2-CH2-CH2{S03Na})(여기서, (En)은 단위 (b)로부터 유도된 옥시(폴리옥시에틸렌)옥시이고, n은 8 내지 20의 범위이며, 조성물중의 말단-캡 잔기-(CH2-CH{SO3Na}), -(CH2-CH{SO2Na}-CH2{SO2Na}) 및 -(CH2-CH2-CH2{SO2Na})는 5 내지 40중량%이다)중에서 선택된 잔기의 70 내지 100중량%를 포함한다]로 이루어진 나트륨염 형태의 설폰화된 올리고머성 에스테르.
제10항에 있어서, 말단-캡 잔기 -(CH2-CH{S03Na}-CH2{SO3Na})-, -(CH2-CH{SO2Na}-CH2(SO3Na} 및 -(CH2-CH2-CH2(SO3Na})의 중량%가 10% 내지 30%의 범위인 나트륨염 형태의 설폰화된 올리고머성 에스테르.
제10항에 있어서, 단일 설폰화된 말단-캡 잔기, -(CH2-CH2-CH{S03Na})에 대한 이중 설폰화된 말단-캡 잔기(-(CH2-CH{SO3Na}) 및 -(CH2-CH{SO3Na}-CH2{SO3Na}의 몰비가 1 : 5 내지 1 : 0의 범위의 나트륨 형태의 설폰화된 올리고머성 에스테르.
제10항에 있어서, 단일 설폰화된 말단-캡 잔기, -(CH2-CH2-CH{S03Na})에 대한 이중 설폰화된 말단-캡 잔기(-(CH2-CH{SO3Na}-CH2{SO3Na}) 및 -(CH2-CH{SO3Na}-CH2{SO3Na}의 몰비가 2 : 1 내지 1 : 0의 범위의 나트륨 형태의 설폰화된 올리고머성 에스테르.
제1항의 조성물을 적어도 0.05중량% 포함하는 세정제 조성물.
제14항에 있어서, 세정성 계면활성제 5 내지 50중량% 및 세정력 증강제 5 내지 60중량%를 포함하는 빌트 세탁용 세정제.
제15항에 있어서, 증강제가 폴리카복실레이트 증강제, 지올라이트 증강제, 인산염 증강제, 및 이의 혼합물중에서 선택된느 성분인 조성물.
제16항에 있어서, 증강제가 옥시디숙시네이트 염, 타르트레이트 모노숙시네이트 염, 타르트레이트 디숙시네이트 염, 및 이의 혼합물주에서 선택되는 조성물.
※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890012195A 1988-08-26 1989-08-26 알릴 유도된 설폰화 말단 캡을 갖는 방오제 KR960015371B1 (ko)

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AR242631A1 (es) 1993-04-30
BR8904317A (pt) 1990-04-17
ATE134669T1 (de) 1996-03-15
EP0357280A2 (en) 1990-03-07
EP0357280B1 (en) 1996-02-28
JP3105220B2 (ja) 2000-10-30
AU4028989A (en) 1990-03-01
JPH02163118A (ja) 1990-06-22
SG76454A1 (en) 2000-11-21
AU625762B2 (en) 1992-07-16
KR960015371B1 (ko) 1996-11-11
DE68925765D1 (de) 1996-04-04
CA1332953C (en) 1994-11-08
EP0357280A3 (en) 1991-08-07
HK1006175A1 (en) 1999-02-12
DE68925765T2 (de) 1996-10-02

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