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KR880011234A - 접착제로서 유용한 열-용융성 중합체, 그것의 제조방법 및 기질재료의 접착을 위한 이용 - Google Patents

접착제로서 유용한 열-용융성 중합체, 그것의 제조방법 및 기질재료의 접착을 위한 이용 Download PDF

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Publication number
KR880011234A
KR880011234A KR1019880002547A KR880002547A KR880011234A KR 880011234 A KR880011234 A KR 880011234A KR 1019880002547 A KR1019880002547 A KR 1019880002547A KR 880002547 A KR880002547 A KR 880002547A KR 880011234 A KR880011234 A KR 880011234A
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KR
South Korea
Prior art keywords
polymer
diisocyanate
group
heat
polycaprolactone
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KR1019880002547A
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KR930007918B1 (ko
Inventor
띠보 쟝-피에르
떼제나스 필립
비띠앙 이앙퀴
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에르베 뷔리에즈
에셈 에스. 아.
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Publication of KR880011234A publication Critical patent/KR880011234A/ko
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Publication of KR930007918B1 publication Critical patent/KR930007918B1/ko
Anticipated expiration legal-status Critical
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
    • C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C09J175/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4202—Two or more polyesters of different physical or chemical nature
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2170/00—Compositions for adhesives
    • C08G2170/20—Compositions for hot melt adhesives

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compounds Of Unknown Constitution (AREA)
  • Ceramic Products (AREA)

Abstract

내용없음

Description

접착제로서 유용한 열-용융성 중합체, 그것의 제조방법 및 기질지료이 접착을 위한 이용
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (18)

  1. 폴리우레탄 및 폴리카프로락톤 서열로 구성된 블록 전중합체를 함유하고 유리 NCO기 비율이 1% 내지 5%인, 접착제로서 유용한 열-용융성 중합체.
  2. 제1항에 있어서, -NH-CO.O-우레탄 서열 및 -(C6H10O2)n-폴리카프로락톤 서열의 중량비가 각각 바람직하게는 1.1% 내지 2.1% 및 10% 내지 40%인 중합체.
  3. 제1항에 있어서, 하기 성분들, 즉 (1)유리 OH기를 포함하는 폴리카로락톤-기재 수지 ; (2)저융점폴리올 ; 및 (3)1.1 내지 4의 작용기 비율을 갖는 디이소시아네이트로 형성된 중합체.
  4. 제1항에 있어서, 유리 OH기를 함유하는 폴리카프로락톤-기재중합체가, 30000 내지 40000의 평균분자량을 갖고, 60℃의 융점 및 -60℃이 유리전이 온도르 갖는 폴리에스테르 수지인 중합체.
  5. 제4항에 있어서, 상기 수지가, 예를 들어 TONE PCL 700R로서 시판되는 유니온 카바이드사 제품과 같이, 폴리에스테르 및 폴리이소시아네이트로부터 유도되는 약간 결정성이 선형 폴리우레탄에 결합되거나 또는 아디프산, 이소프탈산 및 헥산디올의 중측합 반응의 의해 형성된 혼성중합 에스테르에 결합된, 카프로락톤 구조를 갖는 폴리에스테르로 구성된 군으로부터 선정된 중합체.
  6. 제1항에 있어서, 폴리올이 100℃ 미만의 융점을 갖고 또 히드록시 말단기를 포함하며, 분자량이 200 내지 6000이고, 히드록기 지수가 20 내지 100이며 또 바람직하게는 50℃ 내지 90℃범위이 융점을 갖는 지방족 동종 중합에스테르인 중합체.
  7. 제6항에 있어서, 폴리올이 아디프산 및 헥산디올의 축합 중합체이거나 또는 선형 이산(diacid) 및 선형 디올이 중측합 반응으로부터 생성된 결정성 폴리에스테르인 중합체.
  8. 제1항에 있어서, 디이소시아네이트가 순수한 4,4`-디페닐메탄 디이소시아네이트, 디페닐메탄 디이소시아네이트의 2,4` 및 4,4` 이성질체의 혼합물, 디이소시아네이트 부가물, 이소포론 디이소시아네이트 및 헥사메틸렌 디이소시아네이트로 구성된 군으로부터 선정된 중합체.
  9. 제1항에 있어서, 성부들의 중량비가, 각각 카프로락톤 전 중합체에 대하여 10 내지 40, 폴리올에 대해서 40 내지 80, 또 디이소시아네이트에 대해서는 10 내지 30인 중합체.
  10. 제1항에 있어서, (1)히드록시기 백분율이 0.7 내지 1.5인 폴리카프로락톤 ; (2)히드록시기 지수가 20 내지 110인 헥산디올과 아디프산의 동종 중합에스테르 ; 및 (3)4,4`-디페닐메탄 디이소시아네이트로부터 형성된 중합체.
  11. 제10항에 있어서, 성분들의 각 중량비가 25/60/15인 중합체.
  12. 제11항에 있어서, 1.5 내지 2%의 유리 이소시아네이트기를 함유하는 중합체.
  13. 제12항에 있어서, 2%의 유리 이소시아네이트기를 함유하는 중합체.
  14. 제13항에 있어서, 150℃에서의 점도가, 5,000 내지 100,000 mPa.s인 중합체.
  15. 제14항에 있어서, 40℃ 미만의 온도에서 고체 상태인 중합체.
  16. 카프로락톤을 기채로하는 전중합체를 용융상태의 폴리올과 결합시키고, 또 최종 중합체가 1 내지 5중량%이 양으로 유리이소시아네이트기를 함유하도록 충분량의 디이소시아네이트를 부가함으로써, 제1항 내지 제15항중 어느 하나에 따르는 열-용융성 중합체를 제조하는 방법.
  17. 제15항에 있어서, 반응 온도가 80℃ 내지 130℃인 방법.
  18. 동일하거나 상이한 재료의 표면을 상호 접착시키는 접착제로서, 제1항 내지 제14항중 어느 하나에 따르는 열-용융성 중합체의 용도.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880002547A 1987-03-13 1988-03-11 접착제로서 유용한 열-용융성 중합체, 그것의 제조방법 및 기질재료의 접착을 위한 이용 Expired - Fee Related KR930007918B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8703441 1987-03-13
FR8703441A FR2612193B1 (fr) 1987-03-13 1987-03-13 Polymere thermofusible, utile comme agent adhesif, son procede de fabrication et son application au collage de materiaux

Publications (2)

Publication Number Publication Date
KR880011234A true KR880011234A (ko) 1988-10-27
KR930007918B1 KR930007918B1 (ko) 1993-08-21

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KR1019880002547A Expired - Fee Related KR930007918B1 (ko) 1987-03-13 1988-03-11 접착제로서 유용한 열-용융성 중합체, 그것의 제조방법 및 기질재료의 접착을 위한 이용

Country Status (17)

Country Link
US (1) US4814413A (ko)
EP (1) EP0283345B1 (ko)
JP (1) JPS63251415A (ko)
KR (1) KR930007918B1 (ko)
AT (1) ATE74946T1 (ko)
CA (1) CA1313718C (ko)
DE (1) DE3870007D1 (ko)
DK (1) DK171575B1 (ko)
ES (1) ES2007311T3 (ko)
FI (1) FI97061C (ko)
FR (1) FR2612193B1 (ko)
GR (2) GR880300175T1 (ko)
IE (1) IE60001B1 (ko)
NO (1) NO170855C (ko)
NZ (1) NZ223760A (ko)
PT (1) PT86915B (ko)
ZA (1) ZA881742B (ko)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NO891754L (no) * 1988-06-02 1989-12-04 Minnesota Mining & Mfg Ikke-traaddannende fuktighets-herdende blandinger.
JPH0622956B2 (ja) * 1989-03-31 1994-03-30 日立化成ポリマー株式会社 ハニカムサンドイッチ構造パネルの製造方法
US5336733A (en) * 1989-04-10 1994-08-09 Rheox, Inc. High performance polyurethane base resins
JP2844474B2 (ja) * 1989-07-19 1999-01-06 ダイセル化学工業株式会社 ポリウレタンの製造方法
JPH0735503B2 (ja) * 1989-07-27 1995-04-19 サンスター技研株式会社 湿気硬化性熱溶融型接着剤
DE3931845A1 (de) * 1989-09-23 1991-04-04 Bayer Ag Schnellkristallisierende polyurethansysteme
JPH0794653B2 (ja) * 1990-03-30 1995-10-11 大日精化工業株式会社 ホットメルト接着剤組成物
CA2055346A1 (en) * 1990-12-21 1992-06-22 John C. Tangen Mixture of isocyanate-terminated polyurethane prepolymers having reduced set time
JPH04300985A (ja) * 1991-03-29 1992-10-23 Sunstar Eng Inc 反応性ホットメルト接着剤
EP0512198A1 (en) * 1991-05-08 1992-11-11 Rheox International, Inc. High performance polyurethane base resins
JPH0525455A (ja) * 1991-07-22 1993-02-02 Sekisui Chem Co Ltd 反応性ホツトメルト型接着剤組成物
US5288359A (en) * 1992-08-07 1994-02-22 Minnestoa Mining And Manufacturing Company Method for adhesively bonding close fitting components
US7984597B2 (en) * 2000-11-20 2011-07-26 Exterior Portfolio, Llc Vinyl siding
USD450138S1 (en) * 2000-11-20 2001-11-06 Crane Plastics Siding Llc Straight face, foam-backed, vinyl siding panel
KR100466226B1 (ko) * 2001-10-06 2005-01-14 호성케멕스 주식회사 에테르 함유 폴리에스테르 폴리올을 포함하는 열가소성폴리우레탄 및 그 제조방법
US6988345B1 (en) 2003-02-03 2006-01-24 Crane Plastics Company Llc Lineal
US20060053948A1 (en) * 2003-05-28 2006-03-16 Akhil Mahendra Variable ratio brake pedal linkage mechanism
DE10334723A1 (de) * 2003-07-30 2005-02-24 Bayer Materialscience Ag Neue Bindemittelkombination für hochbeständige Kunststofflacke
US7726092B1 (en) 2003-10-09 2010-06-01 The Crane Group Companies Limited Window sill and trim corner assembly
US8225568B1 (en) 2003-10-17 2012-07-24 Exterior Portfolio, Llc Backed building structure panel having grooved and ribbed surface
US8336269B1 (en) 2003-10-17 2012-12-25 Exterior Portfolio Llc Siding having facing and backing portion with grooved and ribbed backing portion surface
US8225567B1 (en) 2003-10-17 2012-07-24 Exterior Portfolio, Llc Siding having backer with features for drainage, ventilation, and receiving adhesive
US7934352B1 (en) 2003-10-17 2011-05-03 Exterior Portfolio, Llc Grooved foam backed panels
US8006455B1 (en) 2004-12-29 2011-08-30 Exterior Portfolio, Llc Backed panel and system for connecting backed panels
US7685787B1 (en) 2005-12-28 2010-03-30 Crane Building Products Llc System and method for leveling or alignment of panels
US20100266520A1 (en) * 2007-12-17 2010-10-21 Stephane Arditty Cosmetic composition comprising a semicrystalline polyurethane/polyester copolymer
US8381472B1 (en) 2010-06-17 2013-02-26 Exterior Portfolio, Llc System and method for adjoining siding
US8795813B2 (en) 2011-02-22 2014-08-05 Exterior Portfolio, Llc Ribbed backed panels
PT2944660T (pt) * 2014-05-16 2017-03-29 Henkel Ag & Co Kgaa Poliuretano termoplástico
TWI818046B (zh) * 2018-07-16 2023-10-11 德商科思創德意志股份有限公司 施加含有游離ｎｃｏ基團的可熔性聚合物材料的方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3775354A (en) * 1972-02-29 1973-11-27 Inter Polymer Res Corp Polyurethane elastomers based on poly(epsilon-caprolactone)polyols
DE2344707A1 (de) * 1973-09-05 1975-03-06 Schering Ag Klebstoff zum verkleben von werkstoffen
GB2093853B (en) * 1981-02-27 1984-09-19 Daicel Chem Lactone polymer and polyurethane obtained therefrom
FR2519992B1 (fr) * 1982-01-20 1986-04-04 Lhd Lab Hygiene Dietetique Procede de preparation d'une nouvelle composition thermoplastique a memoire a partir de polycaprolactone et de polyurethane, produit obtenu selon ce procede et son utilisation notamment en orthopedie
US4515933A (en) * 1983-04-11 1985-05-07 American Cyanamid Company One-component polyurethane adhesive compositions
JPS614717A (ja) * 1984-06-20 1986-01-10 Daicel Chem Ind Ltd ポリウレタン
FR2577935B1 (fr) * 1985-02-26 1988-06-17 Saint Gobain Vitrage Couche adhesive a base de polyurethane et son utilisation dans les vitrages feuilletes
FR2577934B1 (fr) * 1985-02-26 1988-01-08 Saint Gobain Vitrage Couche adhesive a base de polyurethane et son utilisation dans les vitrages feuilletes
FR2579612A1 (fr) * 1985-03-29 1986-10-03 Atochem Procede d'assemblage de surfaces par application d'un joint en polyurethanne ou en polyetheramide, fusion superficielle de ce joint et refroidissement
US4748201A (en) * 1986-03-28 1988-05-31 Urylon Development, Inc. Sprayable polyurethane composition and method of preparation

Also Published As

Publication number Publication date
FR2612193A1 (fr) 1988-09-16
NZ223760A (en) 1990-04-26
GR880300175T1 (en) 1989-06-22
ES2007311T3 (es) 1993-02-16
NO881103D0 (no) 1988-03-11
KR930007918B1 (ko) 1993-08-21
AU599205B2 (en) 1990-07-12
GR3004380T3 (ko) 1993-03-31
ES2007311A4 (es) 1989-06-16
DK108188A (da) 1988-09-14
FI97061B (fi) 1996-06-28
DK108188D0 (da) 1988-03-01
ZA881742B (en) 1988-08-31
DK171575B1 (da) 1997-01-20
FI881175A0 (fi) 1988-03-11
IE880405L (en) 1988-09-13
FI881175L (fi) 1988-09-14
EP0283345A2 (fr) 1988-09-21
CA1313718C (en) 1993-02-16
PT86915B (pt) 1992-05-29
IE60001B1 (en) 1994-05-18
AU1193388A (en) 1988-09-15
DE3870007D1 (de) 1992-05-21
US4814413A (en) 1989-03-21
PT86915A (pt) 1988-04-01
NO170855C (no) 1992-12-16
EP0283345B1 (fr) 1992-04-15
JPS63251415A (ja) 1988-10-18
FR2612193B1 (fr) 1989-08-25
NO881103L (no) 1988-09-14
FI97061C (fi) 1996-10-10
EP0283345A3 (en) 1988-10-12
NO170855B (no) 1992-09-07
ATE74946T1 (de) 1992-05-15
JPH0411596B2 (ko) 1992-02-28

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