KR100229703B1 - 에틸렌 단일 중합체와 에틸렌 공중합체 및 이것의 제조방법 - Google Patents
에틸렌 단일 중합체와 에틸렌 공중합체 및 이것의 제조방법 Download PDFInfo
- Publication number
- KR100229703B1 KR100229703B1 KR1019920017485A KR920017485A KR100229703B1 KR 100229703 B1 KR100229703 B1 KR 100229703B1 KR 1019920017485 A KR1019920017485 A KR 1019920017485A KR 920017485 A KR920017485 A KR 920017485A KR 100229703 B1 KR100229703 B1 KR 100229703B1
- Authority
- KR
- South Korea
- Prior art keywords
- ethylene
- polymerization
- initiator
- temperature
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims abstract description 67
- 239000005977 Ethylene Substances 0.000 title claims abstract description 67
- 238000000034 method Methods 0.000 title claims abstract description 45
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 8
- 229920001577 copolymer Polymers 0.000 title claims abstract description 6
- 229920000642 polymer Polymers 0.000 title claims description 34
- 238000006243 chemical reaction Methods 0.000 claims abstract description 50
- 239000003999 initiator Substances 0.000 claims abstract description 50
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 46
- 229920001519 homopolymer Polymers 0.000 claims abstract description 40
- 239000000178 monomer Substances 0.000 claims abstract description 22
- 239000000203 mixture Substances 0.000 claims abstract description 20
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000001301 oxygen Substances 0.000 claims abstract description 7
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 7
- 238000010526 radical polymerization reaction Methods 0.000 claims abstract description 5
- 229920001038 ethylene copolymer Polymers 0.000 claims description 18
- 238000001816 cooling Methods 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims 4
- 239000000463 material Substances 0.000 claims 2
- 229920002120 photoresistant polymer Polymers 0.000 claims 2
- 239000011541 reaction mixture Substances 0.000 abstract description 12
- 239000000155 melt Substances 0.000 abstract description 6
- SGVYKUFIHHTIFL-UHFFFAOYSA-N 2-methylnonane Chemical compound CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 description 25
- 239000010408 film Substances 0.000 description 25
- AQIRXGQDSUUKQA-UHFFFAOYSA-N hydrogen peroxide;4-methylpentan-2-one Chemical compound OO.CC(C)CC(C)=O AQIRXGQDSUUKQA-UHFFFAOYSA-N 0.000 description 17
- VSJBBIJIXZVVLQ-UHFFFAOYSA-N tert-butyl 3,5,5-trimethylhexaneperoxoate Chemical compound CC(C)(C)CC(C)CC(=O)OOC(C)(C)C VSJBBIJIXZVVLQ-UHFFFAOYSA-N 0.000 description 17
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 12
- 238000002360 preparation method Methods 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 9
- 238000012545 processing Methods 0.000 description 8
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 8
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 238000000354 decomposition reaction Methods 0.000 description 5
- 230000003287 optical effect Effects 0.000 description 5
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 4
- OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 238000009529 body temperature measurement Methods 0.000 description 3
- 239000002360 explosive Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000003607 modifier Substances 0.000 description 3
- 239000001294 propane Substances 0.000 description 3
- HGTUJZTUQFXBIH-UHFFFAOYSA-N (2,3-dimethyl-3-phenylbutan-2-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(C)C(C)(C)C1=CC=CC=C1 HGTUJZTUQFXBIH-UHFFFAOYSA-N 0.000 description 2
- HQOVXPHOJANJBR-UHFFFAOYSA-N 2,2-bis(tert-butylperoxy)butane Chemical compound CC(C)(C)OOC(C)(CC)OOC(C)(C)C HQOVXPHOJANJBR-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- YQHLDYVWEZKEOX-UHFFFAOYSA-N cumene hydroperoxide Chemical compound OOC(C)(C)C1=CC=CC=C1 YQHLDYVWEZKEOX-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 150000003384 small molecules Chemical class 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- HGXJDMCMYLEZMJ-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOOC(=O)C(C)(C)C HGXJDMCMYLEZMJ-UHFFFAOYSA-N 0.000 description 1
- SWPHKGWMJWHRQR-UHFFFAOYSA-N (3-hydroperoxy-2,4-dimethylpentan-3-yl)benzene Chemical compound CC(C)C(OO)(C(C)C)C1=CC=CC=C1 SWPHKGWMJWHRQR-UHFFFAOYSA-N 0.000 description 1
- RQHGZNBWBKINOY-PLNGDYQASA-N (z)-4-tert-butylperoxy-4-oxobut-2-enoic acid Chemical compound CC(C)(C)OOC(=O)\C=C/C(O)=O RQHGZNBWBKINOY-PLNGDYQASA-N 0.000 description 1
- OKIRBHVFJGXOIS-UHFFFAOYSA-N 1,2-di(propan-2-yl)benzene Chemical compound CC(C)C1=CC=CC=C1C(C)C OKIRBHVFJGXOIS-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 description 1
- NGCFVIRRWORSML-UHFFFAOYSA-N 3-phenylbutan-2-ylbenzene Chemical class C=1C=CC=CC=1C(C)C(C)C1=CC=CC=C1 NGCFVIRRWORSML-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- JEAIVVDKUUARLF-UHFFFAOYSA-N acetyloxycarbonylperoxycarbonyl acetate Chemical compound CC(=O)OC(=O)OOC(=O)OC(C)=O JEAIVVDKUUARLF-UHFFFAOYSA-N 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- BLCKNMAZFRMCJJ-UHFFFAOYSA-N cyclohexyl cyclohexyloxycarbonyloxy carbonate Chemical compound C1CCCCC1OC(=O)OOC(=O)OC1CCCCC1 BLCKNMAZFRMCJJ-UHFFFAOYSA-N 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000010096 film blowing Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- AVCZKSDZZCSKIX-UHFFFAOYSA-N furan-2,5-dione 2-methylprop-2-enoyl 2-methylprop-2-enoate Chemical compound CC(C(=O)OC(C(=C)C)=O)=C.C1(C=C/C(=O)O1)=O AVCZKSDZZCSKIX-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000010327 methods by industry Methods 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000004978 peroxycarbonates Chemical class 0.000 description 1
- -1 peroxyesters Chemical class 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- KQYLUTYUZIVHND-UHFFFAOYSA-N tert-butyl 2,2-dimethyloctaneperoxoate Chemical compound CCCCCCC(C)(C)C(=O)OOC(C)(C)C KQYLUTYUZIVHND-UHFFFAOYSA-N 0.000 description 1
- VXHFNALHLRWIIU-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropanoate Chemical compound CC(C)(C)OC(=O)C(C)(C)C VXHFNALHLRWIIU-UHFFFAOYSA-N 0.000 description 1
- ZUSDEBDNDIJDMZ-UHFFFAOYSA-N tert-butyl 7-methyloctaneperoxoate Chemical compound CC(C)CCCCCC(=O)OOC(C)(C)C ZUSDEBDNDIJDMZ-UHFFFAOYSA-N 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- LYDRKKWPKKEMNZ-UHFFFAOYSA-N tert-butyl benzoate Chemical compound CC(C)(C)OC(=O)C1=CC=CC=C1 LYDRKKWPKKEMNZ-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4132012A DE4132012A1 (de) | 1991-09-26 | 1991-09-26 | Ethylenhomopolymerisate und -copolymerisate sowie ein verfahren zu ihrer herstellung |
| DEP4132012.3 | 1991-09-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR930006062A KR930006062A (ko) | 1993-04-20 |
| KR100229703B1 true KR100229703B1 (ko) | 1999-11-15 |
Family
ID=6441518
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019920017485A Expired - Fee Related KR100229703B1 (ko) | 1991-09-26 | 1992-09-25 | 에틸렌 단일 중합체와 에틸렌 공중합체 및 이것의 제조방법 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5306791A (fi) |
| EP (1) | EP0534237B1 (fi) |
| JP (1) | JP3370353B2 (fi) |
| KR (1) | KR100229703B1 (fi) |
| AT (1) | ATE145652T1 (fi) |
| DE (2) | DE4132012A1 (fi) |
| ES (1) | ES2094261T3 (fi) |
| FI (1) | FI108354B (fi) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4317979A1 (de) * | 1993-05-28 | 1994-12-01 | Minnesota Mining & Mfg | Kunststoffband, dessen Verwendung sowie Verfahren zur Herstellung eines mit einem Kunststoffband umwickelten Körpers |
| AU9186698A (en) | 1997-09-30 | 1999-04-23 | Japan Polyolefins Co., Ltd. | Low-density polyethylene resin for laminating, composition thereof, laminate produced therefrom and process for producing the same |
| DE10128221A1 (de) * | 2001-06-11 | 2002-12-19 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von Ethylenhomo-und -copolymeren durch radikalische Hochdruckpolymerisation |
| ES2765649T3 (es) * | 2009-08-10 | 2020-06-10 | Dow Global Technologies Llc | LDPE para uso como un componente de mezcla en aplicaciones de películas retráctiles |
| US9234055B2 (en) | 2010-09-30 | 2016-01-12 | Dow Global Technologies Llc | Polymerization process to make low density polyethylene |
| US10647789B2 (en) * | 2015-06-22 | 2020-05-12 | Dow Global Technologies Llc | Process for making ethylene-based polymers using carbon-carbon free radical initiators |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3806499A (en) * | 1970-12-23 | 1974-04-23 | It Resine Spa Soc | Process for polymerizing ethylene |
| DE3308804A1 (de) * | 1983-03-12 | 1984-09-13 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von ethylenpolymerisaten bei druecken oberhalb von 500 bar in einem zweizonen-rohrreaktor |
| DE3844047A1 (de) * | 1988-12-28 | 1990-07-05 | Basf Ag | Copolymerisate aus ethylen mit alkencarbonsaeuren und/oder alkencarbonsaeurederivaten |
| DE3912975A1 (de) * | 1989-04-20 | 1990-11-08 | Basf Ag | Polyethylen sowie copolymerisate aus ueberwiegenden anteilen von ethylen |
-
1991
- 1991-09-26 DE DE4132012A patent/DE4132012A1/de not_active Withdrawn
-
1992
- 1992-08-28 JP JP22981792A patent/JP3370353B2/ja not_active Expired - Fee Related
- 1992-09-10 EP EP92115460A patent/EP0534237B1/de not_active Expired - Lifetime
- 1992-09-10 AT AT92115460T patent/ATE145652T1/de not_active IP Right Cessation
- 1992-09-10 DE DE59207584T patent/DE59207584D1/de not_active Expired - Lifetime
- 1992-09-10 ES ES92115460T patent/ES2094261T3/es not_active Expired - Lifetime
- 1992-09-11 FI FI924074A patent/FI108354B/fi active
- 1992-09-25 KR KR1019920017485A patent/KR100229703B1/ko not_active Expired - Fee Related
-
1993
- 1993-05-06 US US08/057,554 patent/US5306791A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| FI108354B (fi) | 2002-01-15 |
| FI924074L (fi) | 1993-03-27 |
| DE59207584D1 (de) | 1997-01-09 |
| JP3370353B2 (ja) | 2003-01-27 |
| JPH05202131A (ja) | 1993-08-10 |
| ATE145652T1 (de) | 1996-12-15 |
| ES2094261T3 (es) | 1997-01-16 |
| DE4132012A1 (de) | 1993-04-01 |
| FI924074A0 (fi) | 1992-09-11 |
| EP0534237A1 (de) | 1993-03-31 |
| US5306791A (en) | 1994-04-26 |
| EP0534237B1 (de) | 1996-11-27 |
| KR930006062A (ko) | 1993-04-20 |
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Patent event code: PA01091R01D Comment text: Patent Application Patent event date: 19920925 |
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| PA0201 | Request for examination |
Patent event code: PA02012R01D Patent event date: 19970724 Comment text: Request for Examination of Application Patent event code: PA02011R01I Patent event date: 19920925 Comment text: Patent Application |
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Patent event code: PE07011S01D Comment text: Decision to Grant Registration Patent event date: 19990529 |
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| GRNT | Written decision to grant | ||
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