JP6960743B2 - Small molecule silicone alternative oil - Google Patents

Description

The present invention relates to a cosmetic oil which is a non-silicone compound and can impart a feel similar to that of a small molecule silicone oil.

Conventionally, silicone compounds have been widely used in personal care products because they have the effect of imparting a light feel and smoothness to the skin and hair and improving gloss in cosmetic applications. In particular, low-molecular-weight silicone oils typified by cyclic siloxane and 10-100 cSt polydimethylsiloxane are widely used in a wide range of applications such as skin care, hair care, make-up, and sun care. However, in recent years, there has been a demand for the development of alternatives to such silicone compounds from the viewpoint of consumers' preference for natural materials and environmental load.

Against this background, attempts have been made in Patent Documents 1 to 3 to substitute low-molecular-weight silicone oils with non-silicone compounds, but they have not always been sufficient as substitutes. Further, in Patent Documents 4 and 5, attempts have been made to impart a silicone-like feel by using an oligomer ester or polyester containing one or both of dimer acid and dimer diol as a constituent unit, but the compounds of these patents are expensive. Since it is a viscous substance, it is useful as a substitute for high molecular weight silicone, but it is not suitable as a substitute for low molecular weight silicone oil.

Special table 2000-512285 JP-A-2005-075333 Special Table 2014-533288 Japanese Unexamined Patent Publication No. 2004-262683 Japanese Unexamined Patent Publication No. 2014-009259

An object of the present invention is to provide a cosmetic oil which is a non-silicone compound and gives a feel similar to that of a small molecule silicone oil.

As a result of diligent studies in view of such a situation, the present inventors have made a cosmetic oil containing the following components (A) and (B), or the following components (A), (B) and (C). The present invention has been completed by finding that the cosmetic oil preparation can solve the above-mentioned problems.
(A) Dimeric acid ester, dimer diol ester, and one or more selected from sterols (B) Diester of dicarboxylic acid having 4 to 10 carbon atoms and monovalent alcohol having 2 to 12 carbon atoms. One or more selected from an ester of a monocarboxylic acid having 12 to 18 carbon atoms and a monovalent alcohol having 2 to 8 carbon atoms, and a triester of a monocarboxylic acid having 6 to 12 carbon atoms and glycerin. (C) Volatile hydrocarbon

By using the cosmetic oil of the present invention, an effect similar to that of a small molecule silicone oil can be obtained. Therefore, by substituting the small molecule silicone oil in the cosmetic with the cosmetic oil of the present invention, it is possible to obtain a cosmetic having the same feel.

The cosmetic oil agent of the present invention is a composition comprising the following components (A) and (B), or the following components (A), (B) and (C).
(A) Dimeric acid ester, dimer diol ester, and one or more selected from sterols (B) Diester of dicarboxylic acid having 4 to 10 carbon atoms and monovalent alcohol having 2 to 12 carbon atoms. One or more selected from an ester of a monocarboxylic acid having 12 to 18 carbon atoms and a monovalent alcohol having 2 to 8 carbon atoms, and a triester of a monocarboxylic acid having 6 to 12 carbon atoms and glycerin. (C) Volatile hydrocarbon

The component (A) used in the present invention is not particularly limited as long as it is an ester of dimer acid containing a hydrogen additive, an ester of dimer diol, or sterols, but specifically, as an ester of dimer acid. Diisopropyl dimerginolate, diisostearyl dimerginolate, dimergilinolate di (isostearyl / phytosteryl), dimerginolic acid (phytosteryl / behenyl), dimerginolic acid (phytosteryl / isostearyl / cetyl /) Stearyl / behenyl), dimer dilinoleic acid dimer dilinoleyl, dimer dilinoleic acid dimer dinorail bis (behenyl / isostearyl / phytosteryl), dimer dilinoleic acid hardened castor oil, etc. are dimerdiol esters. Acid dimer dilinoleil, dimer dilinoleil hydrogenated rosin condensate, etc., as sterols, cholesterol, phytosterol, cholesteryl oleate, phytosteryl oleate, cholesteryl isostearate, phytosteryl isostearate, macadamia nut oil fatty acid cholesteryl, macadamia nut oil Examples thereof include fatty acid phytosteryl, sunflower seed oil fatty acid cholesteryl, and sunflower seed oil fatty acid phytosteryl. Of these, dimer dilinoleic acid di (isostearyl / phytosterol), dimer dilinoleate dimer dilinoleyl, and phytosterol are preferable. Further, from the viewpoint of further exerting the effect of the present invention, it is more preferable to use the ester of dimer acid or the ester of dimerdiol in combination with sterols.

Specific examples of the diester of the dicarboxylic acid having 4 to 10 carbon atoms and the monohydric alcohol having 2 to 12 carbon atoms of the component (B) used in the present invention include succinic acid, glutaric acid, methylglutaric acid, and phthalic acid. Dicarboxylic acid selected from acids, adipic acid, pimelli acid, suberic acid, azelaic acid and sebacic acid, and ethanol, propanol, isopropanol, butanol, isobutanol, pentanol, hexanol, octanol, 2-ethylhexanol, isononyl alcohol. , Decanol, Isodecanol, Undecanol and Dodecanol, a compound comprising a diester with a monohydric alcohol selected from. Of these, the diester of succinic acid is preferable, and diheptyl succinate and di2-ethylhexyl succinate are most preferable. The succinic acid of the ester may be derived from petroleum or bio.

Specific examples of the ester of the monocarboxylic acid having 12 to 18 carbon atoms and the monohydric alcohol having 2 to 8 carbon atoms of the component (B) used in the present invention include lauric acid, myristic acid, palmitic acid, and palmitrain. Esters of a monocarboxylic acid selected from acids, stearic acids, oleic acids and isostearic acids and a monohydric alcohol selected from ethanol, propanol, isopropanol, butanol, isobutanol, heptanol, hexanol, octanol and 2-ethylhexanol. It is a compound that includes. Of these, an ester of oleic acid and a monovalent alcohol having 2 to 4 carbon atoms, an ester of isostearic acid and a monovalent alcohol having 2 to 4 carbon atoms, or a monovalent of palmitic acid and a branch of 3 to 8 carbon atoms. Esters with alcohols are preferred, and ethyl oleate, ethyl isostearate, and ethylhexyl palmitate are most preferred. The fatty acid may be a mixture of fatty acids obtained from animal and vegetable oils.

Specific examples of the triester of the monocarboxylic acid having 6 to 12 carbon atoms and glycerin of the component (B) used in the present invention include caproic acid, caproic acid, 2-ethylhexanoic acid, pelargonic acid, and caproic acid. And a compound that includes an ester of a monocarboxylic acid selected from lauric acid and glycerin. Of these, a triester of a monocarboxylic acid having 8 to 10 carbon atoms and glycerin is preferable, and glyceryl tri2-ethylhexanoate, glyceryl tricaprylate, glyceryl tricaprate, and tri (caprylic acid / capric acid) glyceryl are most preferable. The fatty acid may be a mixture of fatty acids obtained from animal and vegetable oils.

The volatile hydrocarbon of the component (C) used in the present invention is a linear or branched hydrocarbon having 6 to 18 carbon atoms, more preferably a linear or branched hydrocarbon having 10 to 16 carbon atoms. , These may be a mixture of a plurality of species, and may be derived from any of petroleum, animals, and plants. More specifically, decane, dodecane, isododecane, isohexadecane, light isoparaffin, light liquid isoparaffin and the like are preferred, with dodecane and isododecane being the most preferred.

The cosmetic oil of the present invention imparts a feel similar to that of low-molecular-weight silicone oil, but can be made closer to the feel of low-molecular-weight silicone oil to be replaced by adjusting the essential components and their blending amounts. Specifically, when it is desired to substitute a non-volatile low molecular weight silicone oil such as dimethicone 5cs to 50cs, a cosmetic oil containing the components (A) and (B) can be used. The content of the component (A) in the cosmetic oil may be 0.1 to 50% by weight, preferably 0.2 to 25% by weight, more preferably 0.3 to 15% by weight, and the component. The content of (B) is 50 to 99.9% by weight, preferably 75 to 99.8% by weight, and more preferably 85 to 99.7% by weight. At this time, since the component (A) is a highly viscous compound as compared with the component (B), it is desired to adjust the viscosity of the cosmetic oil agent of the present invention by changing the content of the component (A). It is possible to match the viscosity with that of low molecular weight silicone oil.

On the other hand, when it is desired to substitute a volatile silicone oil such as cyclopentasiloxane, methyltrimethicone, and dimethicone 1.5cs to 2cs, the component (C) is an essential component in addition to the components (A) and (B). It is advisable to use cosmetic oils. In this case, the content of the component (A) in the cosmetic oil is 0.1 to 5% by weight, the content of the component (B) is 10 to 79.9% by weight, and the content of the component (C) is 20 to 20 to 5% by weight. It may be 85% by weight, more preferably the content of the component (A) is 0.2 to 3% by weight, the content of the component (B) is 17 to 69.8% by weight, and the content of the component (C). The amount is 30-80% by weight. Since the component (C) is a compound having a lower viscosity than the components (A) and (B) and has volatility, the viscosity of the cosmetic oil of the present invention can be increased by changing the content of the component (C). It can be made closer to volatile silicone oil and volatile.

The cosmetic oil agent of the present invention may contain components other than the components (A), (B) and (C) as long as the effects of the present invention are not impaired. , Gelling agent, antioxidant and the like may be contained. As the antioxidant, those usually added to oils can be used, but in particular, d-α-tocopherol, d-δ-tocopherol, d, l-α-tocopherol, d-α-tocopherol acetate, d acetate. , L-α-tocopherol and other vitamin Es are desirable.

The cosmetic oil agent of the present invention can obtain the excellent effect of the present invention by blending it in a cosmetic, but the blending amount in the cosmetic should be within a range that does not impair the effect of the present invention. The above is not particularly limited, and is usually 0.01 to 99% by weight, preferably 0.05 to 50% by weight.

The cosmetics of the present invention include additive components that are added to water and ordinary cosmetics as needed, such as oily bases, surfactants, alcohols, moisturizers, polymers / thickening / gelling agents, and antioxidants. Agents, preservatives, bactericides, chelating agents, pH regulators / acids / alkalis, UV absorbers, whitening agents, solvents, keratin exfoliating / dissolving agents, antipruritic agents, anti-inflammatory agents, antiperspirants, refreshing agents, antihistamines, astringents Agents, stimulants, hair growth agents / blood circulation promoters, reducing agents / oxidizing agents, polymer powders, hydroxy acids, vitamins and their derivatives, sugars and their derivatives, organic acids, enzymes, nucleic acids, hormones , Inorganic powders, fragrances, pigments, etc. can be blended.

Oily bases include cetanol, myristyl alcohol, oleyl alcohol, lauryl alcohol, cetostearyl alcohol, stearyl alcohol, araquil alcohol, behenyl alcohol, jojoba alcohol, chimil alcohol, seraquil alcohol, bacil alcohol, hexyldecanol, isostearyl alcohol, Higher alcohols such as 2-octyldodecanol and dimerdiol; aralkyl alcohols and derivatives such as benzyl alcohol; lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, behenic acid, undecylene acid, 12-hydroxystearic acid, Higher grades such as palmitooleic acid, oleic acid, linoleic acid, linoleic acid, erucic acid, docosahexaenoic acid, eikosapentaenoic acid, isohexadecanoic acid, anteisohenicosanoic acid, long chain branched fatty acids, dimer acid, hydrogenated dimer acid, etc. Fatty acids and their aluminum salts, calcium salts, magnesium salts, zinc salts, potassium salts, sodium salts and other metal soaps, and nitrogen-containing derivatives such as amides; liquid paraffin (mineral oil), heavy liquid isoparaffin, light fluid Hydrocarbons such as isoparaffin, α-olefin oligomer, polyisobutene, hydrogenated polyisobutene, polybutene, squalane, olive-derived squalane, squalane, vaseline, solid paraffin; candelilla wax, carnauba wax, rice wax, wood wax, honey wax, Waxes such as monttan wax, ozokelite, ceresin, paraffin wax, microcrystallin wax, petrolatum, fishertroph wax, polyethylene wax, ethylene / propylene copolymer; palm oil, palm oil, palm kernel oil, safflower oil, olive oil, castor oil , Avocado oil, sesame oil, tea oil, evening primrose oil, wheat germ oil, macadamia nut oil, hazelnut oil, kukui nut oil, rose hip oil, meadowfoam oil, persic oil, tea tree oil, peppermint oil, corn oil, rapeseed oil, sunflower oil , Wheat germ oil, flaxseed oil, cottonseed oil, soybean oil, peanut oil, rice bran oil, cacao butter, shea butter, hydrogenated palm oil, hydrogenated castor oil, jojoba oil, hydrogenated jojoba oil and other vegetable oils; beef fat, Animal oils and fats such as milk fat, horse fat, egg yolk oil, mink oil and turtle oil; animal waxes such as whale wax, lanolin and orange raffy oil; liquid lanolin, reduced lano Lanolins such as phosphorus, adsorption-purified lanolin, lanolin acetate, liquid acetate lanolin, hydroxylanolin, polyoxyethylene lanolin, lanolin fatty acid, hard lanolin fatty acid, lanolin alcohol, lanolin alcohol acetate, acetic acid (cetyl lanolyl) ester; lecithin, phosphatidylcholine , Sphingophosphory lipids such as phosphatidylethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidylinositol, sphingomyelin, phospholipids such as phosphatidic acid, lysolecithin; hydrogenated soybean phospholipids, partially hydrogenated soybean phospholipids, hydrogenated egg yolk phospholipids , Phosphorid derivatives such as partially hydrogenated egg yolk phospholipids; sterols such as cholesterol, dihydrocholesterol, lanosterol, dihydrolanosterol, phytosterol, cholic acid; sapogenins; saponins; cholesteryl acetate, cholesteryl nonanoate, cholesteryl stearate, Cholesteryl isostearate, cholesteryl oleate, di-lauroyl-L-glutamate (cholesteryl / behenyl / octyldodecyl), di-lauroyl-L-glutamate (cholesteryl / octyldodecyl), di-lauroyl-L-glutamate (phytosteryl) / Behenyl / octyldodecyl), di (phytosteryl / octyldodecyl) N-lauroyl-L-glutamate, acylsarcosine alkyl esters such as N-lauroyl sarcosin isopropyl, cholesteryl 12-hydroxystearate, macadamia nut oil fatty acid cholesteryl, macadamia nut oil fatty acid phytosteryl , Phytosteryl isostearate, phytosteryl oleate, soft lanolin fatty acid cholesteryl, hard lanolin fatty acid cholesteryl, long-chain branched fatty acid cholesteryl, long-chain α-hydroxy fatty acid cholesteryl and other sterol esters; Fatty acid complex such as body; octyldodecyl myristate, hexyldecyl myristate, octyldodecyl isostearate, cetyl palmitate, octyldodecyl palmitate, cetyl octanate, hexyldecyl octanoate, isotolideyl isononanoate, isononyl isononanoate, isononanoic acid Octyl, isotridecyl isononanoate, isodecyl neopentanoate, isotridecyl neopentanoate, isopentanoate Stearyl, octyldodecyl neodecanoate, oleyl oleate, octyldodecyl oleate, octyldodecyl ricinoleate, octyldodecyl lanolin, hexyldecyl dimethyloctanoate, octyldodecyl erucate, cured castor oil isostearate, ethyl oleate, avocado oil Ethyl, isopropyl myristate, isopropyl palmitate, octyl palmitate, isopropyl isostearate, isopropyl lanolin fatty acid, methyl heptyl laurate, methyl heptyl myristate, methyl heptyl palmitate, methyl heptyl isostearate, diethyl sebacate, diisopropyl sebacate, Monoalcoholic carboxylic acid esters such as dioctyl sebacate, diisopropyl adipate, dibutyloctyl sebacate, diisobutyl adipate, dioctyl succinate, triethyl citrate; cetyl lactate, diisostearyl malate, hydrogenated monoisostearate castor oil, Oxyacid esters such as γ-ercalactone; glyceryl trioctanoate, glyceryl trioleate, glyceryl triisostearate, glyceryl diisostearate, tri (capric acid / capric acid) glyceryl, tri (capric acid / capric acid / myristic acid /) Steeric acid) glyceryl, hydrogenated rosin triglyceride (hydrogenated ester gum), rosin triglyceride (ester gum), glyceryl beecosanate, trimethylol propane trioctanoate, trimethylol propane triisostearate, neopentyl glycol dioctanoate, dicaprin Neopentyl glycol acid, 2-butyl-2-ethyl-1,3-propanediol dioctanoate, propylene glycol dioleate, pentaerythricyl tetraoctanoate, hydrogenated rosin pentaerythricyl, ditrimethylolpropane triethylhexanoate, (isostea) Acid / sebacic acid) ditrimethylolpropane, pentaerythricyl triethylhexanoate, (hydroxystearic acid / stearic acid / logonic acid) dipentaerythrityl, diglyceryl diisostearate, polyglyceryl tetraisostearate, polyglyceryl-10 nonaisostearate, deca (ercaic acid) / Isostearic acid / ricinoleic acid) polyglyceryl-8, (hexyldecanoic acid / sebacic acid) diglyceryl oligoester, diss Polyhydric alcohol fatty acid esters such as glycol thearate (ethylene glycol distearate), 3-methyl-1,5-pentanediol dineopentanoate, 2,4-diethyl-1,5-pentanediol dineopentanoic acid; Diisopropyl, diisostearyl dimersylinolate, dimerselyl dimerginolate (isostearyl / phytosteryl), dimergylinol acid (phytosteryl / behenyl), dimerserinolic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl), die Dimeric acid or dimerdiol derivatives such as dimerdilinoleyl dimerginoleyl, dimerdilinoleyl diisostearate, hydrogenated rosin condensate, dimerdilinoleic acid hardened castor oil, hydroxyalkyl dimerdilinoleyl ether; Palm oil fatty acid monoethanolamide (cocamide MEA), palm oil fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), Fatty acid alkanolamides such as palmitic acid monoethanolamide (partamide MEA), palmitic acid diethanolamide (partamide DEA), palm oil fatty acid methylethanolamide (cocamidomethyl MEA); dimethicone (dimethylpolysiloxane), highly polymerized dimethicone (highly polymerized dimethyl) Polysiloxane), cyclomethicone (cyclic dimethylsiloxane, decamethylcyclopentasiloxane), phenyltrimethicone, diphenyldimethicone, phenyldimethicone, (aminoethylaminopropylmethicone / dimethicone) copolymer, dimethiconol, dimethiconol crosspolymer, silicone resin, silicone rubber , Amino-modified silicones such as aminopropyl dimethicone and amodimethicone, cationic-modified silicones, polyether-modified silicones such as dimethicone copolyol, polyglycerin-modified silicones, sugar-modified silicones, carboxylic acid-modified silicones, phosphoric acid-modified silicones, sulfate-modified silicones, Alcohol-modified silicone, fatty acid-modified silicone, alkyl ether-modified silicone, amino acid-modified silicone, peptide-modified silicone, fluorine-modified silicone, cationic-modified and polyether-modified Sirico Silicones such as amino-modified and polyether-modified silicones, alkyl-modified and polyether-modified silicones, amidalkyl-modified silicones, aminoglycol-modified silicones, aminophenyl-modified silicones, polysiloxane / oxyalkylene copolymers; Fluoro-based oils such as perfluorooctane and perfluoropolyether are preferred.

Examples of the moisturizing agent / feel improving agent include glycerin, 1,3-butylene glycol, propylene glycol, 3-methyl-1,3-butanediol, 1,3-propanediol, 2-methyl-1,3-propanediol, and the like. Polypolymers such as trimethylolpropane, pentaerythritol, hexylene glycol, diglycerin, polyglycerin, diethylene glycol, polyethylene glycol, dipropylene glycol, polypropylene glycol, ethylene glycol / propylene glycol copolymer and its polymers; diethylene glycol monoethyl ether Glycol alkyl ethers such as (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol dibutyl ether; (eicosanedioic acid / tetradecanedioic acid) polyglyceryl-10, polyglyceryl-10 tetradecanedioate, cyclohexanedicarboxylic acid Water-soluble esters such as bisethoxydiglycol; sugar alcohols such as sorbitol, xylitol, erythritol, mannitol, martitol; glucose, fructose, galactose, mannose, treose, xylose, arabinose, fucose, ribose, deoxyribose, maltose, Trehalose, lactose, raffinose, gluconic acid, glucuronic acid, cyclodextrins (α-, β-, γ-cyclodextrin, and modified cyclodextrins such as maltosylation and hydroxyalkylation), β-glucan, chitin, chitosan, Sugars and derivatives such as heparin and derivatives, pectin, arabinogalactan, dextrin, dextran, glycogen, ethyl glucoside, glucosyl ethyl methacrylate polymer or copolymer; hyaluronic acid, sodium hyaluronate; sodium chondroitin sulfate; mucoitin sulfate , Caronine sulfate, keratosulfate, dermatane sulfate; white jellyfish extract, white jellyfish polysaccharide; fucoidan; tuberose polysaccharide, naturally occurring polysaccharide; organic acids such as citric acid, tartrate acid, lactic acid and salts thereof; urea; 2-pyrrolidone-5 -Dicarboxylic acids and salts such as sodium thereof; betaine (trimethylglycine), proline, hydroxyproline, arginine, lysine, serine, glycine, alanine, phenylalanine, tyrosine, β-alanine, threonine, glutamate, glutamine, asses Amino acids such as paragin, aspartic acid, cysteine, cystine, methionine, leucine, isoleucine, valine, tryptophan, histidine, taurine and their salts; collagen, fish-derived collagen, atelocollagen, gelatin, elastin, collagen-degrading peptide, hydrolyzed collagen, Hydroxypropyl ammonium chloride Hydrolyzed collagen, elastin-degraded peptide, keratin-degraded peptide, hydrolyzed keratin, conchiolin-degraded peptide, hydrolyzed conchiolin, silk proteolytic peptide, hydrolyzed silk, lauroyl hydrolyzed silk sodium, soybean proteolytic peptide, wheat protein Protein peptides such as degrading peptides, hydrolyzed wheat proteins, casein-degrading peptides, acylated peptides and their derivatives; acylated peptides such as palmitoyl oligopeptides, palmitoyl pentapeptides and palmitoyl tetrapeptides; silylated peptides; lactic acid bacteria culture solution , Yeast extract, eggshell membrane protein, submandibular gland mutin, hypotaurine, sesame lignan glycoside, glutathione, albumin, lactate; choline chloride, phosphorylcholine; placenta extract, aerastin, collagen, aloe extract, hamamelis water, hechima Animal / plant extracts such as water, chamomile extract, kanzo extract, comfrey extract, silk extract, Izayoi rose extract, sardine extract, eucalyptus extract, melilot extract, natural ceramide (types 1, 2, 3, 4, 5, 6), hydroxyceramides, pseudo-ceramides, sphingoglycolipids, ceramides and ceramides such as sugar ceramide-containing extracts are preferable.

As the surfactant, anionic surfactants, nonionic surfactants, cationic surfactants, amphoteric surfactants, polymer surfactants and the like are preferable. The HLB of the surfactant is not particularly limited and can be used from a low HLB of about 1 to a high HLB of about 20, and it is also preferable to combine a low HLB and a high HLB. Examples of preferred surfactants include fatty acid salts such as potassium laurate and potassium myristate; alkyl sulphates such as sodium lauryl sulphate, triethanolamine lauryl sulphate and ammonium lauryl sulphate; laureth. Polyoxyethylene alkyl sulfates such as sodium sulphate and triethanolamine laures sulphate; sodium cocoyl methyl taurine, potassium cocoyl methyl taurine, sodium lauroyl methyl taurine, sodium myristyl methyl taurine, sodium lauroyl methyl alanine, sodium lauroyl sarcosin, lauroyl sarcosin triethanol. Acyl N-methyl amino acid salts such as amines and sodium methylalanine lauroyl glutamate; sodium cocoyl glutamate, triethanolamine cocoyl glutamate, sodium lauroyl glutamate, sodium myristyl glutamate, sodium stearoyl glutamate, ditriethanolamine palmitoyl aspartate, cocoylalanine triethanolamine. , Acylamino acid salts such as lysine Na dilauroyl glutamate; Polyoxyethylene alkyl ether acetates such as sodium laureth acetate; Sulfonic acid ester salts such as sodium lauroyl monoethanolamide succinate; Polyoxyethylene fatty amine sulfate; fatty acid alkanolamide sulfate; hardened coconut oil fatty acid fatty acid glyceride sulfate such as sodium glycerin sulfate; alkylbenzene polyoxyethylene sulfate; olefin sulfonate such as α-olefin sulfonate; Alkyl sulfosuccinates such as lauryl disodium acid, sodium dioctyl sulfosuccinate; alkyl ether sulfosuccinates such as laures disodium sulfosuccinate, monoethanolamide polyoxyethylene sulfosuccinate, sodium lauryl polypropylene glycol sulfosuccinate; tetradecyl Alkyl benzene sulfonates such as sodium benzene sulfonate, triethanolamine tetradecyl benzene sulfonic acid; alkyl naphthalene sulfonate; alkane sulfonate; α-sulfo fatty acid methyl ester salt; acyl acetylionate; alkyl glycidyl ether sulfonate Alkyl sulfoacetate; Alkyl phosphate ester salts such as sodium laures phosphate, sodium dilaures phosphate, sodium trilaureth phosphate, sodium monooleth phosphate; Alkyl phosphate ester salts such as potassium lauryl phosphate; Sodium caseinate; Alkyl aryl ether Phosphate; fatty acid amide ether phosphate; phospholipids such as phosphatidylglycerol, phosphatidylinositol, phosphatidic acid; silicone-based anionic surfactants such as carboxylic acid-modified silicone, phosphate-modified silicone, sulfate-modified silicone; Among nonionic surfactants, laureth (polyoxyethylene lauryl ether), ceteth (polyoxyethylene cetyl ether), steares (polyoxyethylene stearyl ether), behenes (polyoxyethylene behenyl ether), isosteares (poly) Polyoxyethylene alkyl ethers with various polyoxyethylene additions such as oxyethylene isostearyl ethers) and octyldodeces (polyoxyethylene octyldodecyl ethers); polyoxyethylene alkylphenyl ethers; polyoxyethylene hydrogenated castor oil, poly Oxyethylene glycol oil, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene hydrogenated castor oil triisostearate, polyoxyethylene hydrogenated castor oil monopyroglutamic acid monoisostearic acid diester, polyoxyethylene hydrogenated castor oil maleic acid, etc. Polyoxyethylene phytosterol; polyoxyethylene cholesterol; polyoxyethylene cholestanol; polyoxyethylene lanolin; polyoxyethylene reduced lanolin; polyoxyethylene / polyoxypropylene cetyl ether, polyoxyethylene / Polyoxyethylene / polyoxypropylene alkyl such as polyoxypropylene 2-decyltetradecyl ether, polyoxyethylene / polyoxypropylene monobutyl ether, polyoxyethylene / polyoxypropylene hydrogenated lanolin, polyoxyethylene / polyoxypropylene glycerin ether, etc. Ether; polyoxyethylene / polyoxypropylene glycol; (poly) glycerin such as PPG-9 diglyceryl Polyoxypropylene glycol; glyceryl stearate, glyceryl isostearate, pa Glyceryl luminate, glyceryl myristate, glyceryl oleate, coconut oil fatty acid glyceryl, monocotton seed oil fatty acid glycerin, monoercaate glycerin, sesquioleate glycerin, α, α'-pyroglutamate oleate glycerin, monostearate glycerin malic acid, etc. Partial esters of glycerin fatty acids; polyglyceryl-2, 3, 4, 5, 5, 6, 8, 10, distearate, polyglyceryl-6, 10, polyglyceryl tristearate-2, polyglyceryl decastarate -10, polyglyceryl isostearate-2, 3, 4, 5, 6, 8, 8, 10, polyglyceryl diisostearate-2 (diglyceryl diisostearate), 3, 10, polyglyceryl triisostearate- 2. Polyglyceryl-2 tetraisostearate, polyglyceryl-10 decaisostearate, polyglyceryl-2 oleate 3, 4, 4, 5, 6, 8, 10, dioleate polyglyceryl-6, polyglyceryl trioleate -2, Polyglycerin fatty acid ester such as polyglyceryl-10 dekaoleate; ethylene glycol monofatty acid ester such as ethylene glycol monostearate; propylene glycol monofatty acid ester such as propylene glycol monostearate; pentaerythritol partial fatty acid ester; sorbitol partial fatty acid Estares; multi-toll partial fatty acid esters; multi-toll ethers; sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitans sesquioleate, sorbitan trioleate, penta-2 -Sorbitan fatty acid esters such as diglycerol sorbitan ethylhexylate and diglycerol sorbitan tetra-2-ethylhexylate; sugar derivative partial esters such as sucrose fatty acid ester, methylglucoside fatty acid ester and trehalose undecylate; alkyl glucosides such as caprylyl glucoside; Alkyl polyglycoside; lanolin alcohol; reduced lanolin; polyoxyethylene distearate, polytylene glycol diisostearate, polyoxyethylene monooleate, polyoxyethylene dioleate and other polyoxyethylene fatty acid monos and diesters; polyoxy Ethylene / propylene Recall fatty acid ester; polyoxyethylene glycerin fatty acid ester such as polyoxyethylene glycerin monostearate, polyoxyethylene glycerin monoisostearate, polyoxyethylene glycerin triisostearate; polyoxyethylene glycerin fatty acid ester; polyoxyethylene sorbitan Polyoxyethylene sorbitan fatty acid esters such as monooleate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan tetraoleate; polyoxyethylene sorbitol monolaurate, polyoxyethylene sorbitol monooleate , Polyoxyethylene sorbitol pentaoleate, polyoxyethylene sorbitol monostearate and the like; polyoxyethylene sorbitol fatty acid ester; polyoxyethylene methyl glucoside fatty acid ester; polyoxyethylene alkyl ether fatty acid ester; Ethylene animal and vegetable oils and fats; alkyl glyceryl ethers such as isostearyl glyceryl ether, chimyl alcohol, ceracyl alcohol, and batyl alcohol; polyhydric alcohol alkyl ether; polyoxyethylene alkylamine; tetrapolyoxyethylene / tetrapolyoxypropylene-ethylenediamine Condensates; Natural surfactants such as saponin and sophorolipid; Polyoxyethylene fatty acid amide; Palm oil fatty acid monoethanolamide (cocamide MEA), palm oil fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (lauramide MEA) ), Laurate diethanolamide (lauramide DEA), laurate monoisopropanolamide (lauramide MIPA), palmitate monoethanolamide (partamide MEA), palmitate diethanolamide (partamide DEA), coconut oil fatty acid methylethanolamide (cocamidomethyl MEA) Such as fatty acid alkanolamides; alkyldimethylamine oxides such as lauramine oxide, cocamine oxide, stearamine oxide, behenamine oxide; alkylethoxydimethylamine oxides; polyoxyethylene alkyl mercaptans; polyether modification of dimethicone copolyethylene and the like. Silicone, polysiloxane / oxyalkylene copolymer, polyglycerin modification Silicone-based nonionic surfactants such as silicones and sugar-modified silicones; among cationic surfactants, alkyltrimethylammonium chlorides such as behentrimonium chloride, stealtrimonium chloride, cetrimonium chloride, and lauryltrimonium chloride; Alkyltrimethylammonium bromide such as stearyltrimonium bromide; Dialkyldimethylammonium chloride such as distearyldimonium chloride and dicocodimonium chloride; fatty acid amidamines such as stearamidepropyldimethylamine and stearamideethyldiethylamine and salts thereof; stearoxypropyldimethyl Alkyl ether amine such as amine and its salt or quaternary salt; fatty acid amide type quaternary ammonium salt such as ethyl sulfate long chain branched fatty acid (12-31) aminopropyl ethyl dimethyl ammonium, ethyl sulfate lanolin fatty acid aminopropyl ethyl dimethyl ammonium; Polyoxyethylene alkylamine and its salt or quaternary salt; alkylamine salt; fatty acid amide guanidium salt; alkyletheraminemonium salt; alkyltrialkylene glycolammonium salt; benzalconium salt; benzethonium salt; cetylpyridinium chloride, etc. Pyridinium salt; imidazolinium salt; alkylisoquinolinium salt; dialkylmoriphonium salt; polyamine fatty acid derivative; amino-modified silicone such as aminopropyl dimethicone and amodimethicone, cationic-modified silicone, cationic-modified and polyether-modified silicone, amino Silicone-based cationic surfactants such as modified and polyether-modified silicones; among amphoteric surfactants, N-alkyl-N, N-dimethylamino acid betaines such as lauryl betaine (lauryl dimethylaminoacetic acid betaine); cocamidopropyl Fataceates such as betaine and lauramidopropyl betaine Amidoalkyl-N, N-dimethylamino acid betaine; imidazoline-type betaine such as sodium cocoamphoacetate and sodium lauroammonium acetate; alkylsulfobetaine such as alkyldimethyltaurin; alkyldimethylaminoethanol sulfate ester and the like Sulfate-type betaine; Phosphate-type betaine such as alkyldimethylaminoethanol phosphate: Phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, sphingolin lipid such as sphingomyelin, lysolecithin , Hydrogenated soybean phospholipids, partially hydrogenated soybean phospholipids, hydrogenated egg yolk phospholipids, partially hydrogenated egg yolk phospholipids, phospholipids such as lecithin hydroxide; , Polyvinyl alcohol, sodium alginate, starch derivative, tragant gum, acrylate / alkyl methacrylic acid copolymer; various silicone-based surfactants are preferable.

Examples of the polymer / thickener / gelling agent include guar gum, locust bean gum, queens seed, carrageenan, galactan, arabic gum, tara gum, tamarind, farcerelan, karaya gum, trolley aoi, cara gum, tragant gum, pectin, pectic acid and sodium. Salts such as salts, salts such as alginic acid and sodium salts, mannan; starches such as rice, corn, potatoes, wheat; xanthan gum, dextran, succinoglucan, curdran, hyaluronic acid and its salts, zansan gum, purulan, gellan gum, chitin , Chitosan, agar, casso extract, chondroitin sulfate, casein, collagen, gelatin, albumin; methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethyl cellulose and salts such as sodium thereof, methyl hydroxypropyl cellulose, sodium cellulose sulfate, dialkyldimethyl Ammonium sulfate cellulose, crystalline cellulose, cellulose powder and other cellulose and derivatives thereof; starch-based polymers such as soluble starch, carboxymethyl starch, methylhydroxypropyl starch, methyl starch, hydroxypropyltrimonium chloride starch, corn starch aluminum octenyl succinate, etc. Alginic acid derivatives such as sodium alginate and propylene glycol alginate; polyvinylpyridone (PVP), polyvinyl alcohol (PVA), vinylpidridone / vinyl alcohol copolymer, polyvinylmethyl ether; polyethylene glycol, polypropylene glycol, polyoxyethylene Polyoxypropylene copolymer; amphoteric methacrylate copolymer such as (methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymer, (acrelites / stearyl acrylate / ethylamine methacrylate) copolymer; (dimethicone / vinyldimethicone) cloth Polymer, (alkyl acrylate / diacetone acrylamide) copolymer, (alkyl acrylate / diacetone acrylamide) copolymer AMP; partially saponified polyvinyl acetate, maleic acid copolymer; vinylpyrrolidone / dialkylaminoalkyl methacrylate copolymer; Acrylic resin alkanolamine; polyester, water-dispersible polyester; polya Crylamide; polyacrylic acid ester copolymer such as ethyl polyacrylic acid, carboxyvinyl polymer, salt such as polyacrylic acid and sodium salt thereof, acrylic acid / methacrylic acid ester copolymer; acrylate / alkyl methacrylic acid Polymers: cationized cellulose such as polyquaternium-10, diallyldimethylammonium chloride / acrylamide copolymer such as polyquaternium-7, acrylic acid / diallyldimethylammonium chloride copolymer such as polyquaternium-22, acrylic acid such as polyquaternium-39. -Diallyldimethylammonium chloride-acrylamide copolymer, acrylic acid-cationized metaacrylic acid ester copolymer, acrylic acid-cationized metaacrylic acid amide copolymer, polyquaterium-47 and other acrylic acid-methyl acrylate-chloride Methacylamide propyltrimethylammonium copolymer, choline chloride methacrylate polymer; cationized oligosaccharide, cationized dextran, cationized polysaccharide such as guarhydroxypropyltrimonium chloride; polyethyleneimine; cationic polymer; polyquaternium-51, etc. 2-Polymer of methacryloyloxyethyl phosphorylcholine, polymer with butyl methacrylate copolymer, etc .; acrylic resin emulsion, ethyl polyacrylate emulsion, polyacrylic alkyl ester emulsion, polyvinyl acetate resin emulsion, natural rubber latex, synthetic Polymer emulsions such as latex; nitrocellulose; polyurethanes and various copolymers; various silicones; various silicone-based copolymers such as acrylic-silicone graft copolymers; various fluoropolymers; 12-hydroxystearic acid and Its salts; dextrin fatty acid esters such as dextrin palmitate, dextrin myristinate; silicic anhydride, fuming silica (ultrafine anhydrous silicic acid), aluminum magnesium silicate, sodium magnesium silicate, metal soap, metal dialkyl phosphate, Bentonite, hectrite, organically modified clay minerals, sucrose fatty acid esters, fructo-oligosaccharide fatty acid esters are preferred.

Examples of solvents and propellants include lower alcohols such as ethanol, 2-propanol (isopropyl alcohol), butanol and isobutyl alcohol; glycols such as propylene glycol, 1,3-butylene glycol, diethylene glycol, dipropylene glycol and isopentyldiol. Kind: Diethylene glycol monoethyl ether (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, triethylene glycol monoethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, propylene glycol monoethyl ether, dipropylene glycol monoethyl ether Glycol ethers such as: ethylene glycol monoethyl ether acetate, diethylene glycol monoethyl ether acetate, glycol ether esters such as propylene glycol monoethyl ether acetate; glycol esters such as diethoxyethyl succinate, ethylene glycol disuccinate; benzyl Propellants such as alcohol, benzyloxyethanol, propylene carbonate, dialkyl carbonate, acetone, ethyl acetate, N-methylpyrrolidone; toluene; fluorocarbon, next-generation freon; LPG, dimethyl ether, carbon dioxide and the like are preferred.

Antioxidants include tocopherol derivatives such as tocopherol (vitamin E) and tocopherol acetate; BHT, BHA; gallic acid derivatives such as propyl bisulfite; vitamin C (ascorbic acid) and / or its derivatives; erythorbic acid and its derivatives; Sulfites such as sodium bisulfite; hydrogen sulfites such as sodium bisulfite; thiosulfates such as sodium bisulfite; metahydrosulfites; thiotaurine, hypotaurine; thioglycerol, thiourea, thioglycolic acid, cysteine hydrochloride are preferred. Is listed as. As the reducing agent, thioglycolic acid, cysteine, cysteamine and the like are preferable. As the oxidizing agent, hydrogen peroxide solution, ammonium persulfate, sodium bromate, percarbonate and the like are preferable.

Examples of antibacterial agents or preservatives include parabens (hydroxybenzoic acid esters) such as methylparaben, ethylparaben, propylparaben, and butylparaben; phenoxyethanol; 1,2-pentanediol, 1,2-hexanediol, 1,2-octane. 1,2-Alcandiols such as diols; Alkylglyceryl ethers such as 2-ethylhexylglyceryl ether (ethylhexylglycerin); Salicylic acid; Sodium benzoate; Isothiazolinone derivatives such as methylchloroisothiazolinone and methylisothiazolinone; Linium urea; Dehydroacetic acid and its salts; Phenols; Halogenized bisphenols such as triclosan, acid amides, quaternary ammonium salts; Chlorhexidine acid, halocarban, hexachlorophenol, hinokithiol; other phenols such as phenol, isopropylphenol, cresol, timol, parachlorophenol, phenylphenol, sodium phenylphenol; phenylethyl alcohol, photosensitizers, antibacterial zeolite, silver ion However, when used as an antibacterial agent or an antiseptic for the purpose of antiseptic, from the viewpoint of safety of cosmetics or external preparations for skin, phenoxyethanol; 1,2-pentanediol, 1,2-hexane It is more preferable to use 1,2-alkanediols such as diols and 1,2-octanediols; and alkylglyceryl ethers such as 2-ethylhexyl glyceryl ethers.

Examples of the chelating agent include edetates (ethylenediamine tetraacetate) such as EDTA, EDTA2Na, EDTA3Na and EDTA4Na; hydroxyethylethylenediamine triacetate such as HEDTA3Na; pentetate (diethylenetriaminepentaacetate); phytic acid; ethidroic acid and the like. Phosphonic acid and salts such as sodium salts thereof; sodium oxalate; polypolyamino acids such as polyaspartic acid and polyglutamic acid; sodium polyphosphate, sodium metaphosphate, phosphoric acid; sodium citrate, citric acid, alanine, dihydroxyethylglycine , Gluconic acid, ascorbic acid, succinic acid, tartrate acid are preferred. pH adjusters / acids / alkalis include citric acid, sodium citrate, lactic acid, sodium lactate, glycolic acid, succinic acid, acetic acid, sodium acetate, malic acid, tartaric acid, fumaric acid, phosphoric acid, hydrochloric acid, sulfuric acid, monoethanol. Amine, diethanolamine, triethanolamine, isopropanolamine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-hydroxymethyl-1,3-propanediol, arginine, hydroxylated Preferred are sodium, potassium hydroxide, aqueous ammonia, guanidine carbonate, and ammonium carbonate.

Powders include mica, talc, kaolin, sericite, montmorillonite, kaolinite, mica, white mica, gold mica, synthetic mica, red mica, black mica, permiculite, magnesium carbonate, calcium carbonate, aluminum silicate, cay. Barium acid, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, zeolite, barium sulfate, calcined calcium sulfate, calcium phosphate, fluoroapatite, hydroxyapatite, ceramic powder, bentonite, smectite, clay, mud, Metal soap (eg zinc myristate, calcium palmitate, aluminum stearate), calcium carbonate, red iron oxide, yellow iron oxide, black iron oxide, ultramarine, dark blue, carbon black, titanium oxide, fine and ultrafine titanium oxide, zinc oxide , Fine and ultrafine zinc oxide, alumina, silica, fumigant silica (ultrafine anhydrous silicic acid), mica titanium, fish scale foil, boron nitride, photochromic pigment, synthetic fluorine gold mica, fine particle composite powder, gold, aluminum, etc. Inorganic powders of various sizes and shapes, and these are treated with silicones such as hydrogen silicone and cyclic hydrogen silicone or other surface treatment agents such as silane or titanium coupling agents to make them hydrophobic or Inorganic powder such as hydrophilized powder; starch, cellulose, nylon powder, polyethylene powder, polymethyl methacrylate powder, polystyrene powder, styrene and acrylic acid copolymer resin powder, polyester powder, benzoguanamine resin powder, polyethylene terephthalate -Polymethylmethacrylate laminated powder, polyethylene terephthalate, aluminum, epoxy laminated powder, etc., urethane powder, silicone powder, Teflon (registered trademark) powder, and other organic powders and surface treatment powders of various sizes and shapes, organic and inorganic Composite powders are preferred. Inorganic salts include sodium chloride-containing salts such as salt, normal salt, rock salt, sea salt, and natural salt; potassium chloride, aluminum chloride, calcium chloride, magnesium chloride, ginger, zinc chloride, ammonium chloride; sodium sulfate, aluminum sulfate, etc. Aluminum / potassium sulfate (myoban), aluminum / ammonium sulfate, barium sulfate, calcium sulfate, potassium sulfate, magnesium sulfate, zinc sulfate, iron sulfate, copper sulfate; sodium phosphates such as 1Na / 2Na / 3Na phosphate, phosphoric acid Potassiums, calcium phosphates and magnesium phosphates are preferred.

Examples of the ultraviolet absorber include paraaminobenzoic acid, paraaminobenzoic acid monoglycerin ester, N, N-dipropoxyparaaminobenzoic acid ethyl ester, N, N-diethoxyparaaminobenzoic acid ethyl ester, and N, N-dimethylparaaminobenzoate ethyl. Anthroic acid-based UV absorbers such as esters, N, N-dimethylparaaminobenzoic acid butyl esters, N, N-dimethylparaaminobenzoic acid ethyl esters; Anthranilic acid-based UV absorbers such as homomentyl-N-acetylanthranilate; salicylic acid And salicylic acid-based ultraviolet absorbers such as sodium salts, amilsalicylate, menthyl salicylate, homomentyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate; octyl cinnamate, ethyl-4-isopropyl cinnamate, methyl. -2,5-Diisopropyl cinnamate, ethyl-2,4-diisopropyl cinnamate, methyl-2,4-diisopropyl cinnamate, propyl-p-methoxy cinnamate, isopropyl-p-methoxy cinnamate, isoamyl-p-methoxy Synnamete, 2-ethylhexyl p-methoxycinnamate (octyl paramethoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate (sinoxate), cyclohexyl-p-methoxycinnamate, ethyl-α-cyano-β-phenyl Cyraxic acid-based UV absorbers such as cinnamate, 2-ethylhexyl α-cyano-β-phenyl cinnamate (octocrine), glycerylmono-2-ethylhexanoyl-diparamethoxycinnamate, ferulic acid and derivatives thereof; 2, 4-Dihydroxybenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, 2,2', 4,4'-tetrahydroxybenzophenone, 2-hydroxy- 4-Methoxybenzophenone (oxybenzone-3), 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4' Benzophenones such as −phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone UV absorbers; 3- (4'-methylbenziliden) -d, l-phenyl, 3-benziliden-d, l-phenyl; 2-phenyl-5-methylbenzoxazole; 2,2'-hydroxy-5 -Methylphenylbenzotriazole; 2- (2'-hydroxy-5'-t-octylphenyl) benzotriazole; 2- (2'-hydroxy-5'-methylphenylbenzotriazole; dibenzalazine; dianisoilmethane; 5-( 3,3-Dimethyl-2-norbornylidene) -3-pentan-2-one; dibenzoylmethane derivatives such as 4-t-butylmethoxydibenzoylmethane; octylriazone; urocanic acid derivatives such as urocanic acid and ethyl urocanate 2- (2'-Hydroxy-5'-methylphenyl) benzotriazole, 1- (3,4-dimethoxyphenyl) -4,4-dimethyl-1,3-pentandione, dimethoxybenzilidendioxoimidazolidine propionic acid Hydantin derivatives such as 2-ethylhexyl, phenylbenzimidazole sulfonic acid, terephthalylidene dicanfursulfonic acid, drometrizole trisiloxane, methyl anthranilate, rutin and its derivatives, oryzanol and its derivatives are preferred.

Examples of the whitening agent include hydroquinone glycosides such as arbutin and α-arbutin and their esters; ascorbic acid, ascorbic acid phosphate ester salts such as ascorbic acid, ascorbic acid phosphate sodium salt and ascorbic acid phosphate ester magnesium salt, and ascorbic acid. Ascorbic acid fatty acid ester such as tetraisopalmitic acid ester, ascorbic acid alkyl ether such as ethyl ether ascorbic acid, ascorbic acid glucoside such as ascorbic acid-2-glucoside and its fatty acid esters, ascorbic acid sulfate ester, tocopheryl ascorbyl phosphate Ascorbic acid derivatives such as ... Ascorbic acid is preferred.

Examples of vitamins and derivatives thereof include vitamin A such as retinol, retinol acetate, and retinol palmitate; thiamine hydrochloride, thiamine sulfate, riboflavin, riboflavin acetate, pyridoxin hydrochloride, pyridoxin dioctanoate, pyridoxin dipalmitate, etc. Flavin adenine dinucleotide, cyanocobalamine, folic acid, nicotinic acids such as nicotinic acid amide and benzyl nicotinate, vitamin B group such as choline; vitamin C such as ascorbic acid and salts such as sodium thereof; vitamin D; α, Vitamin E such as β, γ, δ-tocopherol; other vitamins such as pantothenic acid and biotin; ascorbic acid phosphate ester salt such as ascorbic acid phosphate sodium salt and ascorbic acid phosphate ester magnesium salt, tetra ascorbic acid Ascorbic acid fatty acid ester such as isoparmic acid ester, ascorbic stearate, ascorbic palmitate, ascorbic dipalmitate, alkyl ether ascorbic acid such as ethyl ether ascorbic acid, ascorbic acid glucoside such as -2-glucoside ascorbic acid and its fatty acid ester. , Ascorbic acid derivatives such as tocopheryl ascorbic acid; tocopherol nicotinate, tocopherol acetate, tocopherol linoleate, tocopherol ferulate, tocopherol derivatives such as tocopherol phosphate, and other vitamin derivatives, tocotrienol, and other various vitamin derivatives are preferable. Is listed as.

Anti-inflammatory and anti-inflammatory agents include glycyrrhizic acid and its derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokithiol, guaiazulene, allantoin, indomethacin, zinc oxide, hydrocortisone acetate, prednison, diphedramine hydrochloride, chlorpheniramine maleate; peach leaf extract. , Plant extracts such as Honoha extract are preferred. As hair growth agents, blood circulation promoters and stimulants, plant extracts and tinctures such as senburi extract, capsicum tincture, ginger tincture, ginger tincture, and cantalis tincture; , Borneol, cyclanderate, cinnaridine, trazoline, acetylcholine, verapamil, cepharanthin, γ-orizanol, cepharanthin, vitamin E and derivatives such as tocopherol nicotinate / tocopherol acetate, γ-orizanol, nicotinic acid and nicotinic acid amide / benzyl nicotinate. Derivatives such as ester inositol hexanicotinate and nicotine alcohol, allantin, photosensitizer 301, photosensitizer 401, capronium chloride, pentadecanoic acid monoglyceride, flavanonol derivative, stigmasterol or stigmasterol and its glycosyl, minoxidil are preferable. Is listed as. As the hormones, estradiol, estrone, ethinyl estradiol, cortisone, hydrocortisone, prednisone and the like are preferable. Other medicinal agents such as anti-wrinkle agents, anti-aging agents, tightening agents, cold sensitizers, warming agents, wound healing promoters, stimulant relievers, analgesics, cell activators, etc. include retinols, retinoic acids, retinoins. Tocopheryl acid; derivatives such as lactic acid, glycolic acid, gluconic acid, fruit acid, salicylic acid and glycosides / esterified products thereof, hydroxycapric acid, long-chain α-hydroxy fatty acid, long-chain α-hydroxy fatty acid cholesteryl and other α- or β-Hydroxy acids and their derivatives; γ-aminobutyric acid, γ-amino-β-hydroxybutyric acid; carnitine; carnosin; creatin; ceramides, spingosins; caffeine, xanthin and its derivatives; coenzyme Q10, carotene, lycopene , Astaxanthin, lutein, α-lipoic acid, platinum nanocolloids, fullerene and other antioxidants and active oxygen scavengers; catechins; quercetin and other flavones; isoflavones; Polyphenols such as anthocyanidin, chlorogenic acid, apple polyphenol; derivatives such as rutin and glycosides; derivatives such as hesperidin and glycosides; lignan glycosides; Glycoside, gingerol; fragrances such as menthol, camphor, sedrol and derivatives thereof; capsaicin, vanillin and derivatives; insect repellents such as diethyl toluamide; complexes of physiologically active substances and cyclodextrins are preferred. Can be mentioned.

Plant / animal / microbial extracts include iris extract, acitaba extract, asunaro extract, asparagus extract, avocado extract, flaxseed extract, almond extract, altea extract, arnica extract, aloe extract, apricot extract, apricot kernel extract, ginkgo extract. , Inchikou extract, Uikyo extract, Ukon extract, Woolong tea extract, Uwaurushi extract, Agetsu extract, Echinashi leaf extract, Enmeisou extract, Ogon extract, Oubaku extract, Ouren extract, Omugi extract, Otanenjinjin extract, Otogirisou extract, Odorikousou extract, Ononis extract , Dutch mustard extract, orange extract, dried seawater, seaweed extract, oyster leaf extract, oyster extract, hydrolyzed elastin, hydrolyzed wheat powder, hydrolyzed silk, cucumber extract, chamomile extract, oil-soluble chamomile extract, carrot extract, kawarayomogi Extract, crow wheat extract, karukade extract, kanzo extract, oil-soluble kanzo extract, kiwi extract, kiou extract, kikurage extract, kina extract, cucumber extract, kiri leaf extract, guanosine, guava extract, kujin extract, cutinashi extract, kumazasa extract, clara extract, walnut Extract, chestnut extract, grapefruit extract, clematis extract, black rice extract, brown sugar extract, black vinegar, chlorella extract, quail extract, gentiana extract, gennoshouko extract, tea extract, yeast extract, koboku extract, coffee extract, gobo extract, rice extract, rice Fermented extract, fermented rice bran extract, rice germ oil, comfrey extract, collagen, moss peach extract, saishin extract, psycho extract, saitai extract, saffron extract, salvia extract, sabonsou extract, sasa extract, sanzashi extract, sansha extract, sansho Extract, Shiitake extract, Jio extract, Shikon extract, Shiso extract, Shinanoki extract, Shimotsukesou extract, Jatoba extract, Shakuyaku extract, Shokyu extract, Shobu root extract, Shirakaba extract, White chrysanthemum extract, Sugina extract, Stevia extract, Stevia fermented product, Nishikawayanagi extract, Seiyoukizuta extract, Seiyousanzashi extract, Seiyouniwatoko extract, Seiyounokogirisou extract, Seiyouhakka extract, Sage extract, Zeniaoi extract, Senkyu extract, Senburi extract, Souhakuhi extract, Daiou extract, Dai Zu extract, Taisou extract, Thyme extract, Dandelion extract, Local clothing extract, Tea extract, Chouji extract, Chigaya extract, Chinpi extract, Tea tree oil, Jincha extract, Togarashi extract, Touki extract, Tokinsenka extract, Tounin extract, Tohi extract, Dokudami extract, Tomato Extract, Natto extract, Carrot extract, Carrot extract, Novara extract, Hibiscus extract, Bakumondou extract, Hass extract, Parsley extract, Birch extract, Honey, Hamamelis extract, Paris etalia extract, Hikiokoshi extract, Bisaborol, Hinoki extract, Bifizus bacterium extract, Biwa extract, Fukitanpopo extract, Fukinotou extract, Bukuryo extract, Butcher bloom extract, Grape extract, Grape seed extract, Propolis, Hechima extract, Benibana extract, Peppermint extract, Bodaiju extract, Button extract, Hop extract, Maikaika extract, Pine extract, Maronie extract , Mizubasho extract, Mukuroji extract, Melissa extract, Mozuku extract, Peach extract, Yagurumagiku extract, Eucalyptus extract, Yukinoshita extract, Yuzu extract, Yuri extract, Yokuinin extract, Yomogi extract, Lavender extract, Green tea extract, Eggshell membrane extract, Apple extract, Louis Boss tea extract , Reishi extract, lettuce extract, lemon extract, lotus extract, lotus extract, rose extract, rosemary extract, roman chamomile extract, royal jelly extract, crackle extract and the like are preferable.

Examples of the antipruritic agent include diphenhydramine hydrochloride, chlorpheniramine maleate, camphor, substance-P inhibitor and the like. Examples of the exfoliating / dissolving agent include salicylic acid, sulfur, resorcin, selenium sulfide, pyridoxine and the like. Examples of the antiperspirant include chlorohydroxyaluminum, aluminum chloride, zinc oxide, zinc paraphenol sulfonate and the like. Examples of the refreshing agent include menthol and methyl salicylate. Examples of the astringent include citric acid, tartaric acid, lactic acid, aluminum / potassium sulfate, tannic acid and the like. Examples of the enzymes include superoxide dismutase, catalase, lysozyme chloride, lipase, papain, pancreatin, protease and the like. Preferred examples of nucleic acids include ribonucleic acid and a salt thereof, deoxyribonucleic acid and a salt thereof, and disodium adenosine triphosphate.

As fragrances, acetylsedrene, amylcinnamaldehyde, allylamylglycolate, β-ionone, isoe super, isobutylquinolin, iris oil, iron, indol, ylang ylang oil, undecanal, undecenal, γ-undecalactone, Estragor, Eugenol, Oak Moss, Opoponax Resinoid, Orange Oil, Eugenol, Oranthiol, Galaxolid, Carbachlor, L-Carbon, Kamfer, Cannon, Carrot Seed Oil, Clove Oil, Methyl Silica, Geraniol, Geranyl nitrile , Isobornyl acetate, Geranyl acetate, Dimethylbenzylcarbinate acetate, Styralyl acetate, Cedril acetate, Telepinel acetate, pt-butylcyclohexyl acetate, Vetiberyl acetate, benzyl acetate, Linaryl acetate, Isopentyl salicylate, benzyl salicylate, Sandalwood oil, Santa roll, Cyclamenaldehyde, cyclopentadecanolide, methyl dihydrojasmonate, dihydromilsenol, jasmine absolute, jasmine lactone, cis-jasmon, citral, citronenol, citroneral, cinnamon bark oil, 1,8-cineole, cinnamaldehyde, stylux Reginoid, Cedarwood Oil, Cedren, Sedrol, Celori Seed Oil, Thyme Oil, Damascon, Damasenon, Timor, Tuberose Absolute, Decanal, Decalactone, Terpineol, γ-Terpinen, Triplar, Nerol, Nonanar, 2,6-Nonadienor, Nonalactone, Pachori Alcohol, vanilla absolute, vanillin, basil oil, patcholi oil, hydroxycitronellal, α-pinene, piperitone, phenethyl alcohol, phenylacetaldehyde, petitgrain oil, hexylcinnamaldehyde, cis-3-hexenol, peruvian balsam, vetiver oil, vetiverol , Peppermint oil, pepper oil, heliotropin, bergamot oil, benzylbenzoate, borneol, milresinoid, muskketone, methylnonylacetaldehyde, γ-methylyonone, menthol, L-menthol, L-menton, eucalyptus oil, β-yonone, lime oil , Lavender oil, D-limonen, linalol, liraal, lilial, lemon oil, rose absolute, rose oxide, rose oil, rosemary oil, synthetic fragrances such as various essential oils and natural Fragrances and various blended fragrances are preferred.

Dyes / colorants / dyes / pigments include brown 201, black 401, purple 201, purple 401, blue 1, blue 2, blue 201, blue 202, blue 203, and blue 204. , Blue 205, Blue 403, Blue 404, Green 201, Green 202, Green 204, Green 205, Green 3, Green 401, Green 402, Red 102, Red 104-1 , Red 105-1, Red 106, Red 2, Red 201, Red 202, Red 203, Red 204, Red 205, Red 206, Red 207, Red 208, Red 213 , Red 214, Red 215, Red 218, Red 219, Red 220, Red 221, Red 223, Red 225, Red 226, Red 227, Red 228, Red 230-1 , Red 230-2, Red 231, Red 232, Red 3, Red 401, Red 404, Red 405, Red 501, Red 502, Red 503, Red 504, Red 505 , Red 506, Orange 201, Orange 203, Orange 204, Orange 205, Orange 206, Orange 207, Orange 401, Orange 402, Orange 403, Yellow 201, Yellow 202-1 , Yellow 202-2, Yellow 203, Yellow 204, Yellow 205, Yellow 4, Yellow 401, Yellow 402, Yellow 403-1, Yellow 404, Yellow 405, Yellow 406, Yellow Legal dyes such as No. 407 and Yellow No. 5; Other acidic dyes such as Acid Red 14; Basic dyes such as Arianor Sienna Brown, Arianor Madder Red, Arianor Steel Blue, Arianor Straw Yellow; HC Yellow 2, HC Yellow 5, HC Red 3, 4-hydoxypropylamino-3-nitrophenol, N, N'-bis (2-hydroxyethyl) -2-nitro-p- phenylenediamine, HC Blue 2, Basic Blue 26 and other nitro dyes; Disperse dyes; Titanium dioxide, Zinc oxide Inorganic white pigments such as; Inorganic red pigments such as iron oxide (Bengala) and iron titanate; Inorganic brown pigments such as γ-iron oxide; Inorganic yellow pigments such as yellow iron oxide and ocher; Black iron oxide, low Inorganic black pigments such as next titanium oxide; Inorganic purple pigments such as mango violet and cobalt violet; Inorganic green pigments such as chrome, chromium hydroxide, cobalt titanate; inorganic blue pigments such as ultramarine and dark blue; titanium oxide coated mica, titanium oxide coated oxybismus chloride, titanium oxide coated talc, colored titanium oxide coated mica, oxy Pearl pigments such as bismuth chloride and fish scale foil; metal powder pigments such as aluminum powder, copper powder and gold; surface-treated inorganic and metal powder pigments; red 201, red 202, red 204, red 205, red 220 , Red 226, Red 228, Red 405, Orange 203, Orange 204, Yellow 205, Yellow 401, Blue 404, Red 3, Red 104, Red 106, Red 227, Red Organic pigments such as zirconium, barium or aluminum lake such as 230, red 401, red 505, orange 205, yellow 4, yellow 5, yellow 202, yellow 203, green 3 and blue 1. Surface-treated organic pigments; anthraquinones such as astaxanthin and alizarin, anthocyanidins, β-carotene, catenal, capsantine, chalcone, calsamine, quercetin, crosin, chlorophyll, curcumin, cochineal, ciconin and other naphthoquinones, bixin, flavones, beta Natural pigments and dyes such as cyanidin, henna, hemoglobin, lycopene, riboflavin, rutin; p-phenylenediamine, toluene-2,5-diamine, o-, m-, or p-aminophenol, m-phenylenediamine, 5- Oxidation dye intermediates and couplers such as amino-2-methylphenol, resorcin, 1-naphthol, 2,6-diaminopyridine and salts thereof; auto-oxidation dyes such as indolin; dihydroxyacetones are preferred.

As the water, in addition to normal water and purified water, hard water, soft water, natural water, deep ocean water, electrolytic alkaline ionized water, electrolytically acidic ionized water, ionized water, and cluster water are preferable.

In addition to these, cosmetic raw material standards, compounding ingredient standards by cosmetic type, Japan Cosmetic Industry Association ingredient display name list, INCI dictionary (The International Cosmetic Ingredient Dictionary and Handbook), pharmaceutical non-pharmaceutical raw material standards, Japanese Pharmacy, pharmaceutical additives Ingredients described in standards, food additive official documents, etc., and Japanese and foreign patent gazettes and patent publication gazettes (including publication gazettes and republishing) whose international patent classification IPC belongs to the classification of A61K7 and A61K8 It is possible to contain known cosmetic ingredients, pharmaceutical ingredients, food ingredients, etc., such as the described ingredients, in known combinations, blending ratios, and blending amounts.

Examples of the type of cosmetic containing the polyester of the present invention include hair cosmetics, basic cosmetics, make-up cosmetics, aromatic cosmetics, body cosmetics, skin external preparations such as ointments, and the like. From the viewpoint of exerting the effects of the present invention, it can be particularly preferably used for hair cosmetics and make-up cosmetics. The cosmetic of the present invention can be produced according to a usual method.

Explaining the types of the cosmetics of the present invention in more detail, the hair cosmetics include shampoos such as oil shampoo, cream shampoo, conditioning shampoo, indulgence shampoo, hair coloring shampoo, and rinse-integrated shampoo; rinse, treatment. , Hair pack, hair foam, hair mousse, hair spray, hair mist, hair wax, hair gel, water grease, set lotion, color lotion, hair tonic, hair liquid, pomade, tic, hair cream, hair blow, split hair coat, hair oil, permanent Wave agents, straight perms, oxidative hair dyes, hair bleaches, hair color pretreatments, hair color aftertreatments, perma pretreatments, perma aftertreatments, hair manicures, and hair restorers are preferred.

Basic cosmetics include soft lotion, astringent lotion, cleaning lotion, multi-layer lotion, etc .; emollient lotion, moisture lotion, milky lotion, nourishing lotion, nourishing milk, skin moisturizer, moisturizer. -Emulsion, massage lotion, cleansing lotion, protect emulsion, sun protect, sun protector, UV care milk, sun screen, make-up lotion, horny smoother, elbow lotion, hand lotion, body lotion and other emulsions; emollient cream, nutrition cream, Nourishing cream, vanishing cream, moisture cream, night cream, massage cream, cleansing cream, make-up cream, base cream, pre-makeup cream, sunscreen cream, suntan cream, hair removal cream, deodorant cream, shaving cream, keratin softening Creams such as creams; Gels such as moisture gels; Essences such as moisturizing essences, whitening essences, and UV protection essences; Lipstick cosmetics such as liposome beauty liquids and liposome cosmetics; Packs and masks such as masks; cleansing foam, cleansing cream, cleansing milk, cleansing lotion, cleansing gel, cleansing oil, cleansing mask, washing powder, face washing powder, and other washing pigments; cosmetic soap, transparent soap, medicated soap, liquid soap, Soaps such as shaving soaps and synthetic cosmetic soaps are preferred.

As makeup cosmetics, white powder / dusting powder, foundations, lipsticks, lip gloss, blusher, eyeliner, mascara, eye shadow, eyebrow, eyebrow, nail enamel, enamel remover, and nail treatment are preferable. ..

Preferable aromatic cosmetics include perfume, perfume, parfum, eau de parfum, eau de toilette, cologne, perfume paste, fragrance powder, perfume soap, body lotion, and bath oil.

Body cosmetics include body cleaning agents such as body shampoo; deodorant cosmetics such as deodorant lotion, deodorant powder, deodorant spray, and deodorant sticks; depigmenting agents, depilatory / depilatory agents; bathing agents; insect repellent sprays, etc. Repellers are preferred.

As the skin external preparation, it can be used in a dosage form such as an ointment, a patch, a lotion, a liniment, and a liquid coating agent. It can also be used as an oral cosmetic such as toothpaste and mouthwash.

As the dosage form of the cosmetic or skin external preparation of the present invention, emulsification of oil-in-water (O / W) type, water-in-oil (W / O) type, W / O / W type, O / W / O type and the like. Type cosmetics, oil-based cosmetics, solid cosmetics, liquid cosmetics, paste-like cosmetics, stick-like cosmetics, volatile oil-type cosmetics, powder-like cosmetics, jelly-like cosmetics, gel-like cosmetics, paste-like Pharmaceutical types such as cosmetics, emulsified polymer type cosmetics, sheet-like cosmetics, mist-like cosmetics, and spray-type cosmetics are preferable.

Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited to these Examples.

Preparation / Evaluation of Cosmetic Oil Agent of the Present Invention 1
The cosmetic oil agent of the present invention was prepared by mixing the component (A) and the component (B) with the compositions shown in Table 1 (Examples 1 to 6). For comparison, an oil agent using a mixed ester of caprylic acid / glycerin / sebacic acid instead of the component (A) (Comparative Example 1) and only the component (B) (Comparative Examples 2 to 4) were used, and these oil agents were applied to the skin. The feel when applied was sensory evaluated by five specialized panelists. The evaluation was performed in the following four stages based on dimethicone (10 cSt), and the results were shown by the average score of 5 panelists. The results obtained are also shown in Table 1.

Compared to dimethicone (10cSt) 4 points: better 3 points: same 2 points: slightly not good 1 point: not good

From the results in Table 1, the present invention is compared with Comparative Examples 2 to 4 in which the component (A) is not contained, as well as Comparative Example 1 in which the mixed ester of caprylic acid / glycerin / sebacic acid is used as the component (A). It was found that the cosmetic oils of Examples 1 to 6 exhibited a feel closer to that of dimethicone (10 cSt).

Preparation / Evaluation of Cosmetic Oil Agent of the Present Invention 2
The cosmetic oil agent of the present invention was prepared by mixing the component (A) and the component (B) with the compositions shown in Table 2 (Examples 7 to 9). For comparison, an oil agent (Comparative Example 5) using a mixed ester of caprylic acid / glycerin / sebacic acid instead of the component (A) was used, and the feel of these oil agents when applied to the skin was sensory evaluated by five specialized panelists. Was done. The evaluation was performed in the following four stages based on dimethicone (20 cSt), and the results were shown by the average score of 5 panelists. The results obtained are also shown in Table 2.

Compared to dimethicone (20cSt) 4 points: better 3 points: same 2 points: slightly not good 1 point: not good

From the results in Table 2, the cosmetic oils of Examples 7 to 9 of the present invention are closer to dimethicone (20 cSt) as compared with Comparative Example 5 in which the mixed ester of caprylic acid / glycerin / sebacic acid was used as the component (A). It showed a feeling, and this tendency was more remarkable than the result of Table 1 in which the amount of the component (A) was small.

Preparation / Evaluation of Cosmetic Oil Agent of the Present Invention 3
The cosmetic oil agent of the present invention was prepared by mixing the component (A), the component (B) and the component (C) with the compositions shown in Table 3 (Examples 10 to 14). For comparison, an oil agent (Comparative Examples 6 to 7) using only the components (A) and (C) or only the components (B) and (C) was used, and the feel when these oil agents were applied to the skin. Sensory evaluation was performed by 5 specialized panelists. The evaluation was carried out in the following four stages based on cyclopentasiloxane, which is a volatile silicone oil, and the results were shown by the average score of five panelists. The results obtained are also shown in Table 3.

Compared to cyclopentasiloxane 4 points: better 3 points: same 2 points: slightly not good 1 point: not good

From the results in Table 3, it was found that the cosmetic oil containing the components (A) to (C) of the present invention had a feel similar to that of cyclopentasiloxane, which is a volatile silicone oil.

Feel evaluation in cosmetic prescription 1
A milky lotion containing the cosmetic oil of the present invention (Example 15) having the composition shown in Table 4 and a milky lotion containing dimethicone (10 cSt) as a comparison (Comparative Example 8) were prepared, and the feel when applied to the skin was specialized. Sensory evaluation was performed by 5 panelists. The evaluation was performed in the following four stages based on the emulsion of Comparative Example 8, and the results were shown by the average score of 5 panelists. The results obtained are also shown in Table 4.

Compared with the emulsion of Comparative Example 8 4 points: better 3 points: same 2 points: slightly not good 1 point: not good

Feel evaluation in cosmetic prescription 2
A sunscreen cosmetic (Example 16) containing the cosmetic oil of the present invention having the composition shown in Table 5 and a sunscreen cosmetic containing cyclopentasiloxane (Comparative Example 9) for comparison were prepared and applied to the skin. A sensory evaluation was performed by five specialized panelists on the feeling of the moment. The evaluation was performed in the following four stages based on the sunscreen cosmetics of Comparative Example 9, and the results were shown by the average score of 5 panelists. The results obtained are also shown in Table 5.

Compared with the sunscreen cosmetics of Comparative Example 9 4 points: better 3 points: same 2 points: slightly not good 1 point: not good

From the results in Table 4, it was found that the emulsion containing the cosmetic oil of the present invention and the emulsion containing dimethicone (10 cSt) showed similar feelings. Further, from the results in Table 5, it was found that the sunscreen cosmetics containing the cosmetic oil of the present invention and the sunscreen cosmetics containing cyclopentasiloxane show similar feelings. Therefore, it has been found that the cosmetic oil of the present invention can replace the small molecule silicone oil in the cosmetic formulation and give a similar feel.

Example 17 Whitening Emulsion An emulsion having the following formulation was prepared. This emulsion could be uniformly emulsified without the use of other emulsifiers. In addition, it has a non-greasy and refreshing feel, is excellent in whitening effect and barrier function improving effect, moisturizes the skin, keeps it fresh, and prevents fine wrinkles due to rough skin and dryness.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil Agent of Example 1 5.0
Bisdiglyceryl polyacyl adipate-2
(Plandol-DP: Nippon Fine Chemical Co., Ltd.) 1.0
Cetyl ethylcaproate (NS-CIO: Nippon Fine Chemical Co., Ltd.) 10.0
Cetanol 1.2
Phenyltrimethicone 3.0
Ethylparaben 0.1
Myristyl Alcohol 2.0
Oleyl alcohol 1.0
Part B Stearoxy hydroxypropyl Methyl Cellulose 0.1
Xanthan gum 0.1
Purified water 20.0
Part C Hydrogenated lecithin, phytosterols (Phytocompo-PP: Nippon Fine Chemical Co., Ltd.) 1.0
Pentylene glycol 3.0
Glycerin 8.0
Part D 3-O-ethylascorbic acid (VC ethyl: Nippon Fine Chemical Co., Ltd.) 1.0
Purified water 5.0
Part E Phenoxyethanol 0.2
Methylparaben 0.15
Phytic acid 0.5
Citric acid 0.1
Amount of sodium citrate pH 4.5 Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− −−−−−−
(Preparation method)
Parts A and E were each heated to about 70 ° C. and dissolved uniformly. Part B was stirred to obtain a viscous liquid. Part C was heated to about 70 ° C. and dispersed uniformly. After adding part A while stirring part C with a homodisper, part E was added while stirring. Parts D and B were added at about 50 ° C., and the mixture was stirred and uniformly dissolved.

Example 18 Emulsion An emulsion having the following formulation was prepared. This milky lotion has a non-greasy and refreshing feel, spreads well and moisturizes the skin, keeps it fresh, and prevents fine wrinkles due to rough skin and dryness.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Glycerin 3.0
Diglycerin 1.0
BG 7.0
Hydrogenated lecithin, phytosterols, ceramide 2, ceramide 3,
Ceramide 6II (Phytocompo-C: Nippon Fine Chemical Co., Ltd.) 1.0
Hydrogenated lysolecithin (LP70H: Nippon Fine Chemical Co., Ltd.) 0.1
Part B Oil of Example 2 5.0
Oil of Example 12 5.0
Triethylhexanoin (IOTG: Nippon Fine Chemical Co., Ltd.) 3.0
Dimer dilinoleic acid dimer dilinoleyl,
Tri (caprylic acid / capric acid) glyceryl (LUSPLAN SR-DM4: Nippon Fine Chemical Co., Ltd.) 0.5
Hydrogenated polyisobutene 3.5
Isododecane 1.5
Setostearyl alcohol 1.0
Arachidyl alcohol 0.1
Jojoba Alcohol 3.0
Kimil alcohol 0.3
Ceraquil Alcohol 0.1
Hexildecanol 0.5
Part C Hydroxyethyl Acrylate / Acryloyl Dimethyltaurine Na) Copolymer 0.2
White fungus polysaccharide (Tremost-TP: Nippon Fine Chemical Co., Ltd.) 0.03
Carbomer 0.1
Purified water 20.0
Part D (icosanedioic acid / tetradecanedioic acid) polyglyceryl-10, glycerin (Neosolue-AquaS: Nippon Fine Chemical Co., Ltd.) 0.5
Polyquaternium-51 1.0
Ascorbyl Glucoside 1.0
Potassium hydroxide 0.2
Phenoxyethanol 0.2
Methylparaben 0.15
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Parts A, B, and D were mixed and heated to about 70 ° C. to uniformly dissolve and disperse them. Part C was mixed and stirred to give a viscous liquid. After adding part B while stirring part A with a homodisper, part D was added and emulsified. After cooling, part C was added at about 50 ° C., and the mixture was stirred and cooled to about 40 ° C.

Example 19 Skin care cream A cream having the following formulation was prepared. This cream has an excellent moisturizing sensation, and has the effects of softening the skin and keeping the skin moisturized and moisturized. After use, the skin is non-greasy and silky, and these effects last for a long time.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Glycerin 9.0
DPG 5.0
Phytocompo-PP (Nippon Fine Chemical Co., Ltd.) 1.0
Part B Oil of Example 8 4.0
Oil of Example 12 4.0
Vaseline 10.0
Pentaerythrityl tetraisostearate 5.0
Astaxanthin 0.01
Cetyl PG hydroxyethyl palmitamide 0.05
Cyclic lysophosphatidic acid Na 0.01
Dipentaerythrityl hexahydroxystearate 1.0
Part C carbomer 0.1
Hydroxide K 0.07
Xanthan gum 0.1
Purified water 10.0
Part D Phenoxyethanol 0.4
Ethylhexyl glycerin 0.2
Methylparaben 0.05
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Parts A, B, and D were mixed and heated to about 70 ° C. to uniformly dissolve and disperse them. Part C was mixed and stirred to give a viscous liquid. After adding part B while stirring part A with a homodisper, part D was added and emulsified. After cooling, part C was added at about 50 ° C., and the mixture was stirred and cooled to about 40 ° C.

Example 20 Skin care cream A cream having the following formulation was prepared. This cream has an excellent moisturizing sensation, and has the effects of softening the skin and keeping the skin moisturized and moisturized. After use, the skin is non-greasy and silky, and these effects last for a long time.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil Agent of Example 1 1.0
Oil of Example 12 3.0
Squalene 10.0
Stearic acid 1.0
Phytosteryl isostearate (Plandol-ISS: Nippon Fine Chemical Co., Ltd.) 1.0
Macadamia nut oil 3.0
Hydrogenated rapeseed oil alcohol 2.0
Olive oil fatty acid cetearyl 1.0
Olive oil fatty acid sorbitan 0.8
Polyglyceryl oleate-10 1.0
Part B Acrylic acid / alkyl methacrylate copolymer 0.1
Hydroxide K 0.07
(Acryloyl dimethyl taurine ammonium /
Behenes Methacrylic Acid-25) Cross Polymer 0.2
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 1.0
Purified water 10.0
Hydrolyzed polyγ-glutamic acid K 0.1
Polyglutamic acid Na 0.1
Oligopeptide-24 0.05
Part C Glycerin 9.0
Propane diol 10.0
PEG-8 5.0
Methylparaben 0.1
Phenoxyethanol 0.3
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Parts A and C were mixed and heated to about 70 ° C. to uniformly dissolve and disperse them. Part B was mixed and stirred to give a viscous liquid. Part C was added while stirring with a homomixer to emulsify part A. After cooling, part B was added at about 50 ° C., and the mixture was stirred and cooled to about 40 ° C.

Example 21 Skin care cream A cream having the following formulation was prepared. This cream had an excellent moisturizing sensation, softened the skin and kept the skin moisturized and moisturized, and the skin after use was non-greasy and smooth. Moreover, these effects were long-lasting.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil Agent of Example 1 8.0
Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 2.0
Plandoll-LG1 (Nippon Fine Chemical Co., Ltd.) 1.0
Paraffin wax 3.0
Shea butter 3.0
Squalene 8.0
Cetanol 1.8
Hydrogenated cocoglyceryl 0.8
Glyceryl stearate 1.0
Behenyl alcohol 1.5
Sorbitan stearate 1.0
Methyl Glucose Sesquistearate 1.5
Part B xanthan gum 0.1
Hydroxyethyl cellulose 0.1
Crystalline cellulose powder 0.3
Stearoxy hydroxypropyl methylcellulose 0.1
Purified water 20.0
Part C Glycerin 8.0
DPG 5.0
Sorbitol 2.0
Methylparaben 0.15
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Parts A and C were mixed and heated to about 70 ° C. to uniformly dissolve and disperse them. Part B was mixed and stirred to give a viscous liquid. Part C was added while stirring with a homomixer to emulsify part A. After cooling, part B was added at about 50 ° C., and the mixture was stirred and cooled to about 40 ° C.

Example 22 Skin care cream A cream having the following formulation was prepared. This cream had an excellent moisturizing sensation, softened the skin and kept the skin moisturized and smooth, and the skin after use was non-greasy and smooth. Moreover, these effects were long-lasting.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Glycerin 9.0
Phytocompo-C (Nippon Fine Chemical Co., Ltd.) 1.0
Glucosylrutin 0.001
Part B Oil of Example 6 3.0
Argania spinosa kernel oil 1.0
Theobroma Grange Florum Seed Fat 1.0
Astaxanthin 0.005
Pentaerythrityl tetraethylhexanoate (NS-408: Nippon Fine Chemical Co., Ltd.) 0.1
Ethylhexyl stearate 3.0
Plandoll-ISS (Nippon Fine Chemical Co., Ltd.) 2.0
Carnauba wax 0.5
Stairless-2 2.5
Stairless-21 1.8
Cetanol 3.0
Tocopherol acetate 0.03
Squalene 3.0
Part C carbomer 0.1
Arginine 0.1
Hydroxypropyl chitosan 0.2
Ethanol 3.0
Purified water 10.0
Panthenol 0.5
Retinol palmitate 0.05
Part D Methylparaben 0.15
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Parts A, B, and D were mixed and heated to about 70 ° C. to uniformly dissolve and disperse them. Part C was mixed and stirred to give a viscous liquid. After adding part B while stirring part A with a homodisper, part D was added and emulsified. After cooling, part C was added at about 50 ° C., and the mixture was stirred and cooled to about 40 ° C.

Example 23 Skin care cream A cream having the following formulation was prepared. This cream has an excellent moisturizing sensation, and has the effects of softening the skin and keeping the skin moisturized and moisturized. After use, the skin is non-greasy and silky, and these effects last for a long time.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Glycerin 12.0
BG 6.0
Phytocompo-PP (Nippon Fine Chemical Co., Ltd.) 2.5
Part B Oil of Example 4 3.0
Olive fruit oil 3.0
Olive oil 1.5
Shea butter 1.0
NS-408 (Nippon Fine Chemical Co., Ltd.) 3.0
Sucrose stearate 0.8
Cetearyl glucoside 1.2
Behenyl alcohol 1.5
Ascorbyl Tetrahexyl Decanoate 7.0
Lauroyl sarcosine isopropyl 2.0
Hydrogenated cocoglyceryl 3.0
Cetanol 2.5
Sorbitan stearate 0.8
Part C xanthan gum 0.05
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 1.0
Tuberose polysaccharide 0.01
Water-soluble collagen 0.05
Hydrolyzed collagen 0.5
Sodium metabisulfite 0.03
Arbutin (Nippon Fine Chemical Co., Ltd.) 1.0
Tranexamic acid 1.0
Part D Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 1.0
Propanediol 3.0
Methylparaben 0.1
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Parts A, B, and D were mixed and heated to about 70 ° C. to uniformly dissolve and disperse them. Part C was mixed and stirred to give a viscous liquid. After adding part B while stirring part A with a homodisper, part D was added and emulsified. After cooling, part C was added at about 50 ° C., and the mixture was stirred and cooled to about 40 ° C.

Example 24 Skin care cream A cream having the following formulation was prepared. This cream smoothes the skin, gives it freshness, and prevents fine wrinkles caused by rough skin and dryness.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil Agent of Example 1 7.0
Jojoba oil 2.0
Dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl /
Behenil) (Plandol-H: Nippon Fine Chemical Co., Ltd.) 1.0
Tri (caprylic acid / capric acid) glyceryl (Neosolue-MCT: Nippon Fine Chemical Co., Ltd.) 3.0
Daimage Renorail Hydrogenated Rosin Condensate (LUSPLAN DD-DHR: Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-SUN (Nippon Fine Chemical Co., Ltd.) 1.3
Propylene glycol stearate 0.6
Squalene 3.0
Behenyl alcohol 2.0
Ethylparaben 0.1
Liquid isoparaffin 0.5
Carnauba wax 0.3
Corn oil 0.3
Rapeseed oil 1.0
Sunflower oil 1.0
Wheat germ oil 1.0
Flaxseed oil 0.1
Cottonseed oil 0.1
Soybean oil 0.1
Shea butter 0.5
Stigmasterol 1.0
Stannole 1.0
Dihydrocholesterol 0.1
Lanosterol 0.1
Dihydrolanosterol 0.1
Cholesteryl nonanoate 0.1
Cholesteryl stearate 0.1
Cholesteryl isostearate 1.0
Cholesteryl oleate 0.1
Cholesteryl 12-hydroxystearate 0.1
Long-chain branched fatty acid cholesteryl 0.3
Octyldodecyl myristate 1.0
Octyldodecyl isostearate 1.0
Dimeric linoleic acid hardened castor oil 1.0
Hydroxyalkyl dimer dilinoleyl ether 1.0
Tetra (hydroxystearic acid / isostearic acid) dipentaerythrityl
0.5
Rice bran oil fatty acid phytosteryl 0.5
Phenyltrimethicone 1.0
Diphenyldimethicone 1.0
Methyl Hydrogen Polysiloxane 1.0
Polyglyceryl-3 polydimethylsiloxyethyl dimethicone 0.5
Sugar-modified silicone 0.3
Polyoxyethylene / methylpolysiloxane copolymer 1.0
Tocopherol ferulate 0.1
Tocopherol phosphate 0.1
Tocotrienols 0.1
Tannin 0.01
Sesamin 0.01
Proanthocyanidins 0.01
Gravlysin 0.01
Grablen 0.01
Liquiritin 0.01
Isoliquilithin 0.01
Lactoferrin 0.01
Shogaol 0.01
Gingerol 0.01
Part B (Acryloyl Dimethyl Taurine / Behennes Methacrylate-25) Copolymer
0.2
Crystalline cellulose 0.1
Gellan gum 0.1
Carboxyvinyl polymer 0.1
Hydroxide K 0.08
Purified water 20.0
Part C Phytocompo-PP 1.0
Polyglyceryl stearate-10 0.5
Lysolecithin 0.05
Hydrogenated egg yolk lecithin 0.1
Glycerin 7.0
DPG 7.0
Part D Citric acid 0.07
Appropriate amount of Na citrate EDTA-2Na 0.05
Pentetic acid 5Na 0.03
Methylparaben 0.1
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A was mixed and heated to about 70 ° C. to uniformly dissolve. Part B was mixed and stirred to give a viscous liquid. Part C was mixed and heated to about 70 ° C. to uniformly disperse. Part D was mixed and heated to about 70 ° C. to uniformly dissolve. Part A was added to part C with stirring with a homogenizer, and then part D was added for emulsification. After cooling, part B was added at about 50 ° C., and the mixture was stirred and uniformly dissolved.

Example 25 Skin care cream A cream having the following formulation was prepared. This cream softened the skin and had a moist and smooth feel without stickiness. These effects last for a long time.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil Agent of Example 6 3.0
Dimer dilinoleic acid dimer dilinoleyl bis (behenyl / isostearyl /
Phytosteryl) (Plandol-G: Nippon Fine Chemical Co., Ltd.) 1.0
Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 1.5
Neosolue-EHS (Nippon Fine Chemical Co., Ltd.) 8.0
Diisopropyl sebacate (IPSE: Nippon Fine Chemical Co., Ltd.) 2.0
Theobroma Grange Florum Seed Fat 3.0
Bacil isostearate 2.0
Shea butter 3.0
Isostearyl pivalate 0.1
NS-408 (Nippon Fine Chemical Co., Ltd.) 0.1
Ethylparaben 0.2
Stearyl alcohol 3.5
Cetanol 1.3
Polyglyceryl distearate-3 methyl glucose 0.8
Tocopherol 0.1
Ascorbyl Tetrahexyl Decanoate 8.0
Tocopheryl phosphate ascorbyl 2.0
Placenta extract 1.0
Oryzanol 0.3
Phytosphingosine 0.0001
Ubiquinone 0.03
Carotene 0.05
Lycopene 0.01
Astaxanthin 0.01
Lutein 0.01
Peanut oil 0.1
Rice bran oil 1.0
Hydrogenated castor oil 0.3
Jojoba oil 2.0
Orange roughy oil 1.0
Liquid lanolin (liquid lanolin: Nippon Fine Chemical Co., Ltd.) 1.0
Lanolin (purified lanolin: Nippon Fine Chemical Co., Ltd.) 1.0
Polyoxyethylene lanolin 1.0
Lanolin alcohol (lanolin alcohol A: Nippon Fine Chemical Co., Ltd.) 0.3
Lanolin acetate alcohol 0.1
Cholesteryl acetate 0.1
Octocrylene 0.5
Sorbitan sesquistearate 1.2
Part B Tremoist-TP (Nippon Fine Chemical Co., Ltd.) 0.05
Tuberose polysaccharide 0.01
Water-soluble collagen 0.05
Hydrolyzed collagen 0.5
2-methacryloyloxyethyl phosphorylcholine
Butyl methacrylate copolymer solution 0.05
(HEMA Glucoside / Ethyl Trimonium Methacrylate) Copolymer (20%, Nippon Fine Chemical Co., Ltd.) 0.4
Glutathione 0.3
4- (4-Hydroxyphenyl) -2-butanol 1.5
Butyl resorcinol 1.5
Arbutin (Nippon Fine Chemical Co., Ltd.) 3.0
Ascorbyl Phosphate Mg 1.0
Part C Propanediol 10.0
Glycerin 7.0
Diglycerin 1.0
Sodium metabisulfite 0.1
Imidazolenium urea 0.1
Polyvinylpyrrolidone 0.1
Pullulan 0.1
Polyvinyl alcohol 0.1
Dehydroacetic acid 0.1
PEG-32 1.0
Polyglycerin 1.0
Pentetic acid 5Na 0.05
Appropriate amount of succinic acid and sodium succinate Amount of purified water totaling 100 -------------
(Preparation method)
Part A was heated to about 70 ° C. and dissolved uniformly. Part B was made uniform using a part of purified water. Part C was heated to about 70 ° C. and dispersed. While stirring with a homomixer at about 70 ° C., part A was gradually added to part C to emulsify, and after cooling to about 40 ° C., part B was added and mixed uniformly.

Example 26 Hand cream A hand cream having the following formulation was prepared. This hand cream was a non-greasy, moderately stretchable and familiar hand cream with water repellency.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil Agent of Example 3 4.0
Oil of Example 12 4.0
Lanolin fatty acid cholesteryl (YOFCO CLE-S: Nippon Fine Chemical Co., Ltd.) 5.0
LUSPLAN SR-DM4 (Nippon Fine Chemical Co., Ltd.) 0.1
Squalene 8.0
Macadamia nut oil 0.5
Rosehip oil 1.0
Meadowfoam oil 1.0
Vaseline 15.0
Microcrystalline wax 2.0
Glyceryl stearate 2.0
Cetanol 2.0
Cetyl phosphate 1.0
Beeswax 3.0
Propylparaben 0.1
Tocopherol 0.05
Perfluoropolyether 1.0
Part B Glycerin 8.0
Propanediol 5.0
Methylparaben 0.1
Ethylhexyl glycerin 0.5
Phenoxyethanol 0.3
Na hydroxide 0.5
Amount of water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part B was heated to about 70 ° C. and dissolved. Part A was placed in another container and heated to about 80 ° C. to dissolve it. Part A was added to part B with stirring with a homomixer and emulsified. After emulsification, it was cooled to about 40 ° C.

Example 27 Hand cream A hand cream having the following formulation was prepared. This hand cream was a non-greasy, water-repellent hand cream.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil Agent of Example 6 5.0
Plandoll-G (Nippon Fine Chemical Co., Ltd.) 0.5
(Dimethicone / Vinyl Dimethicone) Cross Polymer 0.3
(Vinyl Dimethicone / Lauryl Dimethicone) Cross Polymer 0.5
(Dimethicone / PEG-10 / 15) Cross Polymer 0.5
(PEG-15 / Lauryl Dimethicone) Cross Polymer 0.2
(Alkyl acrylate / dimethicone) copolymer 0.1
NS-CIO (Nippon Fine Chemical Co., Ltd.) 10.0
Propylparaben 0.1
Squalene 5.0
Part B Diglycerin 5.0
Methylparaben 0.1
Part C xanthan gum (2% aqueous solution) 10.0
(Acrylamide / Ammonium Acrylate) Copolymer 0.5
Amount of water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
After dissolving part B, part A was added and heated to about 70 ° C. (part D). The temperature of part C was about 70 ° C. Part C was added to part D with stirring, and the mixture was stirred and mixed with a homomixer for about 3 minutes. After mixing uniformly, it was cooled to about 40 ° C.

Example 28 Hand cream A hand cream having the following formulation was prepared. This hand cream was a non-greasy, water-repellent hand cream.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Squalene 10.0
Vaseline 20.0
Polyglyceryl pentastearate-10 2.0
Microcrystalline wax 4.0
Stearoyl Lactate Na 1.3
Al 1.5 stearate
Mg stearate 1.0
Ca 0.1 stearate
Part B Oil Agent of Example 1 5.0
Oil of Example 12 5.0
Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-DP (Nippon Fine Chemical Co., Ltd.) 0.8
NS-CIO (Nippon Fine Chemical Co., Ltd.) 5.0
IOTG (Nippon Fine Chemical Co., Ltd.) 6.0
Propylparaben 0.05
Tocopherol 0.05
Cyclopentasiloxane 5.0
Part C methylparaben 0.1
Glycerin 10.0
Amount of water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Each of parts B and C was heated to about 80 ° C. and dissolved. Part A was placed in another container, heated to 100 to 120 ° C., transparent gelled, and cooled to 80 ° C. Part B was added to part A with stirring, and part C was further added for emulsification. After mixing uniformly, it was cooled to about 40 ° C.

Example 29 Emulsion An emulsion having the following formulation was prepared. This milky lotion had an excellent moisturizing feeling and had a smooth feeling of use. After use, the skin is soft, non-greasy and silky, and these effects last for a long time.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Phytocompo-SP (hydrogenated lecithin, phytosterols,
BG, glycerin) (Nippon Fine Chemical Co., Ltd.) 8.0
LP70H (Nippon Fine Chemical Co., Ltd.) 0.1
Part B Oil of Example 3 5.0
Squalene 4.0
Neosolue-MCT (Nippon Fine Chemical Co., Ltd.) 4.0
α-olefin oligomer 2.5
Cyclopentasiloxane 3.5
Cetanol 1.5
Glyceryl stearate 1.0
Part C Hydroxyproline 0.05
Citric acid 0.01
Na citrate 0.09
Arbutin (Nippon Fine Chemical Co., Ltd.) 3.0
Phenoxyethanol 0.3
Methylparaben 0.1
Acrylic acid / alkyl methacrylate copolymer 0.1
Hydroxide K 0.1
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Parts A to C were taken, heated to about 70 ° C., and mixed uniformly. Part B was gradually added to part A while stirring with a homodisper, and then part C was added at about 70 ° C. for emulsification. Then it was cooled to about 40 ° C.

Example 30 Gel lotion A lotion having the following formulation was prepared. This lotion moisturized the skin, kept it fresh, and was able to prevent fine wrinkles caused by rough skin and dryness.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Phytocompo-PP (Nippon Fine Chemical Co., Ltd.) 0.5
Glycerin 5.0
Sorbitol solution (70%) 5.0
Glyceryl behenate 0.8
Oil of Example 3 0.5
Stearic acid 0.3
PEG-20 hydrogenated castor oil 0.1
Polyglyceryl oleate-10 0.1
Part B Phenoxyethanol 0.3
Pullulan 0.2
Ethylhexyl glycerin 0.2
Poly HEMA Glucoside 0.05
Polymethacryloyl lysine 0.05
Crystalline cellulose powder 0.1
Locust bean gum 0.03
Hydroxyethyl cellulose 0.05
Hyaluronic acid Na 0.01
Carbomer 0.06
Hydroxide K 0.05
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A was heated to about 70 ° C. and dispersed uniformly. Part B was mixed, stirred well, made uniform, and then heated to about 70 ° C. Part B was added to part A, stirred at about 70 ° C. using a homomixer, and cooled to about 40 ° C.

Example 31 Cleansing gel A cleansing gel having the following formulation was prepared. This cleansing gel has good removal of foundation, make-up, etc., is moderately thick and non-greasy, and has the effect of giving a refreshing feel.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil Agent of Example 2 10.0
Plandoll-S (Nippon Fine Chemical Co., Ltd.) 1.0
Dihydrocholes-30
(Bellpole DC-30: Nippon Fine Chemical Co., Ltd.) 2.0
Diisostearate dimer dilinoleil (LUSPLAN DD-IS: Nippon Fine Chemical Co., Ltd.) 8.0
PEG-25 hydrogenated castor oil 20.0
Octildo Decess-20 15.0
Glycerin 16.0
BG 5.0
Part B Phenoxyethanol 0.5
Amount of purified water totaling 100 -------------
(Preparation method)
Part A is weighed and heated to about 80 ° C to dissolve. Weigh part B and heat to about 80 ° C. B was gradually added to A with stirring, and after mixing, the mixture was cooled to 40 ° C.

Example 32 Cleansing Cream A cleansing cream having the following formulation was prepared. This cleansing cream was well-adapted to make-up cosmetics and had an excellent cleansing effect.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil Agent of Example 1 5.0
Glycerin 3.0
Plandoll-LG2 (Nippon Fine Chemical Co., Ltd.) 1.0
Neosolue-Aquolio (Nippon Fine Chemical Co., Ltd.) 1.0
Celesin 6.0
Mineral oil 28.0
PEG-12 isostearate 3.0
Sorbitan sesquioleate 1.5
Polyoxyethylene sorbitan oleate 0.3
Microcrystalline wax 2.0
Tocopherol 0.05
Propylparaben 0.05
Part B DPG 5.0
Methylparaben 0.2
Edetonic acid 3Na 0.02
Phenoxyethanol 0.2
Amount of purified water totaling 100 -------------
(Preparation method)
Part A was weighed and heated to about 80 ° C. to dissolve. Weigh part B and heat to about 80 ° C. B was gradually added to A with stirring, and after mixing, the mixture was cooled to 40 ° C.

Example 33 Cleansing balm A cleansing balm having the following formulation was prepared. This cleansing balm was well-adapted to make-up cosmetics and had an excellent cleansing effect.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Ethylhexyl palmitate (Neosolve-IOP: Nippon Fine Chemical Co., Ltd.) A total amount of 100 NS-CIO (Nippon Fine Chemical Co., Ltd.) 10.0
Oil Agent of Example 7 13.0
Di lauroyl glutamate (octyldodecyl / phytosteryl / behenyl)
(Plandol-LG3: Nippon Fine Chemical Co., Ltd.) 0.2
Plandoll-S (Nippon Fine Chemical Co., Ltd.) 0.5
PEG-20 glyceryl triisostearate 14.0
Polyethylene 5.5
Microcrystalline wax 2.0
Phenoxyethanol 0.5
Tocopherol 0.05
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
All components were weighed and mixed at about 90 ° C. with stirring until uniform.

Example 34 Cleansing oil A cleansing oil having the following formulation was prepared. This cleansing oil was well-adapted to make-up cosmetics and had an excellent cleansing effect.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Oil Agent of Example 4 12.0
Neosolue-Aquolio (Nippon Fine Chemical Co., Ltd.) 2.0
NS-CIO (Nippon Fine Chemical Co., Ltd.) 9.0
Mineral oil 14.0
Glycerin 16.0
BG 5.0
PEG-8 glyceryl isostearate 14.0
Coconut oil fatty acid PEG-7 glyceryl 14.0
Polyglyceryl diisostearate-2 1.5
EDTA-2Na 0.1
Citric acid 0.01
Na citrate 0.09
Amount of purified water totaling 100 -------------
(Preparation method)
All components were weighed and stirred and mixed until uniform at room temperature.

Example 35 Facial cleansing foam A facial cleansing foam having the following formulation was prepared. This facial cleansing foam had good foaming, and had a long-lasting moist feel from the time of washing to rinsing and after washing.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A stearic acid K 10.0
Palmitic acid K 10.0
Myristic acid K 10.0
Lauric acid K 4.0
Lauroyl sarcosine isopropyl 0.8
Oil agent of Example 3 0.3
PEG1500 10.0
Glycerin 15.0
Glyceryl monostearate 1.0
POE (20) Sorbitan Monostearate 2.0
Part B Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 1.0
Polyquaternium-7 0.5
Polyquaternium-39 0.5
Methylparaben 0.1
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A was weighed and heated to about 80 ° C. to dissolve. Weigh part B and heat to about 80 ° C. B was gradually added to A with stirring, and after mixing, the mixture was cooled to 40 ° C.

Example 36 Facial cleansing foam A facial cleansing foam having the following formulation was prepared. This facial cleansing foam has good foaming properties, and has effects such as giving the skin a smooth and slippery feel and a refreshing feel.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil agent of Example 7 0.1
(Palm fatty acid / hydrogenated beef tallow fatty acid) Na glutamic acid 30.0
Cocoyl glycine K 5.0
Plandoll-LG2 (Nippon Fine Chemical Co., Ltd.) 0.2
Lauric acid diethanolamide 3.0
Tocopherol 0.1
PEG-8 5.0
PEG-32 10.0
Glycerin 14.0
Propylparaben 0.1
Part B Methylparaben 0.2
Polyquaternium-51 1.0
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 0.5
Crystalline cellulose 0.3
Polyquaternium-7 0.8
Amount of purified water totaling 100 -------------
(Preparation method)
Part A was weighed and heated to about 80 ° C. to dissolve. Weigh part B and heat to about 80 ° C. B was gradually added to A with stirring, and after mixing, the mixture was cooled to 40 ° C.

Example 37 Body shampoo A body shampoo having the following formulation was prepared. This body shampoo foamed well, was moisturized after washing, and gave a soft feeling to the skin.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Oil agent of Example 8 0.05
Cocoyl methyl taurine Na 10.0
Lauroyl hydrolyzed silk Na 6.0
Lauroylmethylalanine Na 10.0
Sodium cocoamphoacetate (30%) 4.0
Cocamidopropyl Betaine (30%) 10.0
Olefin (C14-16) Na Sulfonate 5.0
Polyquaternium-10 1.3
Guar Hydroxypropyltrimonium Chloride 0.8
Acetyl hyaluronic acid Na 0.02
Cocamide DEA 3.0
Glycerin 5.0
Methylparaben 0.2
Amount of purified water totaling 100 -------------
(Preparation method)
All components were heated at about 80 ° C. and uniformly stirred and mixed.

Example 38 Shampoo A shampoo having the following formulation was prepared. This shampoo foamed well, the hair was moisturized, and damage care was possible.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Oil agent of Example 1 0.1
Oil agent of Example 12 0.1
Plandoll-LG2 (Nippon Fine Chemical Co., Ltd.) 0.03
Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 0.1
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 0.5
Laureth-4 Carboxylic Acid Na (28%) 10.0
Laureth-6 Carboxylic Acid 4.0
Cocamidopropyl Betaine (30%) 10.0
Lauroylmethylalanine Na (30%) 5.0
Cocamidomethyl MEA 3.0
Coconut oil fatty acid PEG-7 glyceryl 5.0
Na hydroxide 1% solution 0.5
Polyquaternium-10 0.8
Glycol distearate 0.5
Polyquaternium-7 0.5
EDTA-2Na 0.05
Methylparaben 0.2
Phenoxyethanol 0.4
Amount of purified water totaling 100 -------------
(Preparation method)
All components were heated at about 80 ° C. and uniformly stirred and mixed.

Example 39 Hand soap A hand soap having the following formulation was prepared. This hand soap foamed well, was moisturized after washing, and gave a soft feeling to the skin.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A cocoyl isetionate Na 1.0
Glycerin 50.0
Oil agent of Example 5 0.1
Part B lauroyl sarcosine salt 12.0
Myristoylation Methyl Taurine Sodium 2.0
Polyglyceryl laurate-6 2.0
Coconut oil fatty acid diethanolamide 2.0
PEG-7 coconut oil fatty acid glyceryl 2.0
Synthetic latex 0.1
Nitrocellulose 0.1
Sorbitol 8.0
Conchiolin Degrading Peptide 0.1
1,3-butylene glycol 8.0
Phenoxyethanol 0.8
Amount of purified water totaling 100 -------------
(Preparation method)
Part A was heated to about 80 ° C. and dissolved. Part B was added to part A, heated to about 80 ° C. to uniformly dissolve, and then cooled.

Example 40 Non-rinse hair treatment A non-rinse hair treatment having the following formulation was prepared. This hair treatment improved the damage to the hair and was able to give a moist and smooth feeling without using silicone.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil agent of Example 2 2.5
Polyquaternium-37 2.0
Squalene 2.0
PPG-3 Caprylyl Ether 2.0
Microcrystalline wax 0.1
Lanolin alcohol 0.2
Montan wax 0.1
Polyethylene wax 0.1
Beeswax 0.1
Japan wax 0.2
Celesin 0.1
Dicapric acid PG 1.0
Almond oil 0.5
Ethylhexyl ethylhexanoate 1.0
Candelilla wax extract 0.1
Octyldodecyl erucate 4.5
Tocopherol acetate 0.02
γ-docosalactone, tri (caprylic acid / capric acid) glyceryl (ercalactone MCT: Nippon Fine Chemical Co., Ltd.) 2.0
Dipentaerythrityl tripolyhydroxystearate 1.5
PPG-5 Phytosteryl 0.5
Glycerin 4.0
Sorbitol 2.0
Phenoxyethanol 0.5
Part B Hydrolyzed Conchiolin 0.1
Panthenol 0.1
Hydroxypropyltrimonium hyaluronate 0.01
Polyquaternium-11 0.2
Glycosyl trehalose 0.1
Glyceryl glucoside 0.3
Arginine 0.1
Part C Purified water Amount totaling 100 Hydroxypropyl starch phosphoric acid 1.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part C was uniformly dispersed and heated to about 80 ° C. Next, part A was heated to about 80 ° C. to dissolve it. Part C was added while stirring, and after mixing uniformly, the mixture was cooled to about 40 ° C. Then, each part B was added and mixed uniformly.

Example 41 Non-rinse hair treatment A non-rinse hair treatment having the following formulation was prepared. This hair treatment improved the damage to the hair without using silicone, and improved the smoothness and moistness. In addition, although these feelings lasted for a long time, no residual feeling was felt on the hair after shampoo washing.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil Agent of Example 1 3.0
Neosolue-Aquolio (Nippon Fine Chemical Co., Ltd.) 1.0
Neosolue-EHS (Nippon Fine Chemical Co., Ltd.) 1.0
Setrimonium chloride (25%) 2.8
Ranorin Row 1.0
PPG-3 Caprylyl Ether 1.0
Methyl heptyl myristate 0.5
Cetyl ethylhexanoate 0.3
Isononyl isononanoate 0.3
Tridecyl neopentaneate 0.5
Myristyl isooctanoate 0.3
Neopentyl glycol diethylcaproate 0.3
Isobutyl isostearate 0.3
Glyceryl triisostearate 0.3
Trimethylolpropane triisostearate 0.3
Broccoli seed oil 0.3
Sphinganin 0.01
Glycerin 1.0
Part B Methylparaben 0.1
Amount of purified water totaling 100 Phenoxyethanol 0.5
Part C Ceramide 1, Ceramide 2, Ceramide 3, Ceramide 5, Ceramide 6, Cholesterol,
Quotanium-33, etc. (NanoRepair-CMC5: Nippon Fine Chemical Co., Ltd.)
5.0
γ-docosalactone, soybean sterol, etc. (NanoRepair-EL: Nippon Fine Chemical Co., Ltd.) 1.0
Polyquaternium-6 0.6
Polyquaternium-7 0.4
Polyquaternium-39 0.5
Part D Carrageenan 0.1
Hydroxypropyl chitosan 0.05
Hydroxypropyl Methyl Cellulose 0.1
Tuberose polysaccharide 0.1
Cationized guar gum 0.05
Purified water 20.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part B was heated to about 80 ° C. to dissolve it. Next, part A was heated to about 80 ° C. to dissolve it. Part D was dispersed to prepare a viscous liquid. Part A was added to part B with stirring, mixed uniformly, and then cooled to about 40 ° C. Next, parts C and D were added and mixed uniformly.

Example 42 Non-rinse scalp / hair treatment A non-rinse scalp / hair treatment having the following formulation was prepared. This hair treatment improved the damage to the hair and improved the smoothness, moistness, and firmness. It also improved the scalp environment.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil Agent of Example 4 3.0
Neosolue-Aquolio (Nippon Fine Chemical Co., Ltd.) 1.0
Ethanol 40.0
Glycyrrhetinic acid 0.02
PPG-3 Caprylyl Ether 0.3
γ-docosalactone, diethyl sebacate (Elcalactone DES: Nippon Fine Chemical Co., Ltd.) 1.5
PEG / PPG-20 / 20 Dimethicone 0.2
PEG-12 Dimethicone 0.4
Hydrogenated retinol 0.1
Trishexyldecanoic acid pyridoxine 0.05
Bisglyceryl ascorbic acid 0.3
Hexil 3-glyceryl ascorbic acid 0.3
Part B Triethanolamine 0.1
Amount of purified water totaling 100 (Acrylate / Alkyl acrylate (C10-30)) Crosspolymer 0.4
Carbomer 0.05
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 1.0
(Acryloyl dimethyl taurine ammonium / VP) copolymer 0.05
(Acryloyldimethyltaurine ammonium / Behenez methacrylic acid-25) Crosspolymer 0.1
Hydroxypropyl chitosan 0.1
Methylparaben 0.1
Phenoxyethanol 0.2
Part C VC Ethyl (Nippon Fine Chemical Co., Ltd.) 0.05
Nicotinamide 0.3
Pyridoxine hydrochloride 0.1
Caffeine 0.1
Glucosyl trehalose 0.1
Purified water 10.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part A was heated to about 50 ° C. and dissolved. Next, part B was uniformly dispersed to obtain a viscous liquid. Part A was added to part B with stirring and mixed uniformly. Then part C was added and mixed uniformly.

Example 43 Hair Treatment A treatment with the following formulation was prepared. This treatment was a treatment that could improve hair damage without using silicone and give a moist feeling, smoothness, smooth feeling and its lasting feeling.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil of Example 2 0.5
Dodecane 1.5
Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 0.2
Candelilla wax 0.2
Cetyl Esters 0.3
Stearyl ethyl hexaneate 1.0
Cetearyl alcohol 3.5
PEG-200 0.5
Hydroxyethyl cellulose 0.4
Setrimonium chloride (30%) 1.0
Behentrimonium chloride (80%) 1.0
Trideces-6 0.3
BHT 0.03
Part B Methylparaben 0.2
Citric acid 0.05
Amount of purified water totaling 100 Part C PPG-3 myristyl 0.5
DUB VIC-10 (Nippon Fine Chemical Co., Ltd.) 1.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part B was heated to about 80 ° C. and dissolved. Part A was added to another container and heated to dissolve it. Part B was gradually added to part A and mixed uniformly. Part C was added with stirring at about 50 ° C. to make it uniform.

Example 44 Hair Treatment A treatment with the following formulation was prepared. This treatment was able to improve hair damage and give it a moist, silicone-like slippery feel. In addition, after washing with shampoo, no residual feeling was felt on the hair.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Plandoll-LG2 (Nippon Fine Chemical Co., Ltd.) 0.5
Propanediol 3.0
Behenamide propyl dimethylamine 1.5
Cetanol 2.2
Stearyl alcohol 0.8
Hydrogenated rapeseed oil alcohol 0.5
Neopentyl glycol diethylcaproate 0.8
Jojoba seed oil 1.0
Glyceryl stearate 0.4
Propylparaben 0.1
Cocamide MEA 0.8
Caesarpinia Spinosa Hydroxypropyltrimonium Chloride 0.1
Rice bran wax 0.5
Glycerin 1.0
Part B Methylparaben 0.1
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 1.0
Lactic acid 0.4
Amount of purified water totaling 100 Part C Oil agent of Example 4 1.0
Methyl heptyl caprylate 1.0
Polyquaternium-7 0.15
Myristic acid PPG-3 benzyl ether 0.5
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part A was uniformly mixed at about 80 ° C. Part B, which was set aside separately, was heated to about 60 ° C. to make it uniform. Part B was gradually added to part A with stirring, mixed uniformly, and then cooled to about 50 ° C. Further, part C was added and mixed uniformly.

Example 45 Hair Treatment A treatment with the following formulation was prepared. This treatment was able to improve hair damage and give it a moist, silicone-like slippery feel. In addition, after washing with shampoo, no residual feeling was felt on the hair.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil of Example 1 0.8
Neosolue-MCT (Nippon Fine Chemical Co., Ltd.) 0.6
Stearyl alcohol 2.0
Cetanol 1.2
Stealtrimonium chloride 1.0
PEG-45M 0.8
Plandoll-LG1 (Nippon Fine Chemical Co., Ltd.) 0.3
Totsubaki Seed Oil 0.4
Hydroxyethylurea 0.5
Dicaprilyl Carbonate 2.0
PPG-1 / PEG-1 stearamine 1.0
Squalene 0.1
Isosetes-10 0.5
Sunflower wax 0.8
Cocoyl Arginine Ethyl PCA 0.2
Phenoxyethanol 0.2
Tocopherol 0.05
Part B DPG 2.2
Glycerin 1.3
Sorbitol 3.5
BG 1.0
Hydroxycellulose 0.07
Phenoxyethanol 0.2
Appropriate amount of citric acid EDTA-2Na 0.01
Amount of purified water totaling 100 Part C Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 1.0
Polyquaternium-61 0.3
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part A was uniformly mixed at about 80 ° C. Part B, which was set aside separately, was heated to about 60 ° C. to make it uniform. Part B was gradually added to part A with stirring, mixed uniformly, and then cooled to about 50 ° C. Further, part C was added and mixed uniformly.

Example 46 Hair Treatment A treatment with the following formulation was prepared. This treatment was able to improve hair damage and give it a moist, silicone-like slippery feel. In addition, after washing with shampoo, no residual feeling was felt on the hair.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil agent of Example 1 0.1
Cetearyl alcohol 3.0
PPG-1 / PEG-1 stearamine 0.8
Behenamide propyl dimethylamine 1.0
Ethylhexyl palmitate 1.0
Dextrin palmitate 0.5
Inulin stearate 0.5
Neosolue-DE (Nippon Fine Chemical Co., Ltd.) 1.0
Hybrid sunflower oil 1.0
DPG 1.8
Glycerin 4.0
Mineral oil 0.5
Plandoll-DP (Nippon Fine Chemical Co., Ltd.) 1.0
PEG-160M 0.5
Rice bran wax 1.0
Part B Lecithin Hydroxide 0.2
Lactic acid 0.3
Hydrolyzed starch 0.4
Hyaluronic acid Na 0.05
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 1.0
Hydroxypropyl Methyl Cellulose 0.1
Amount of purified water totaling 100 Part C Polyquaternium-107 0.5
Neopentyl glycol diheptate 2.0
Ethylhexyl isononanoate 1.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was added to another container and heated to dissolve it. Part B was gradually added to part A, mixed uniformly, and cooled. Part C was added at around 50 ° C. and mixed uniformly.

Example 47 Treatment A treatment with the following formulation was prepared. This treatment was able to improve hair damage and give it a moist, silicone-like slippery feel. In addition, after washing with shampoo, no residual feeling was felt on the hair.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil agent of Example 2 0.3
Stearyl alcohol 3.0
Behentrimonium chloride 1.0
Stealtrimonium chloride 0.5
Stearamidopropyl dimethylamine 0.1
Hydrogenated polyisobutene 1.0
Hydrogenated polydecene 0.6
Camellia seed oil 0.5
Dicaprilyl ether 3.0
Dilauroyl lysine Na 0.1
Ascorbyl dipalmitate 0.1
BG 3.0
Tocopherol 0.1
Phenoxyethanol 0.4
Part B Na hydrogen carbonate 0.4
Amount of purified water totaling 100 Locust Bean Hydroxypropyltrimonium Chloride 0.1
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 1.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was added to another container and heated to dissolve it. Part B was gradually added to part A, mixed uniformly, and emulsified. It was cooled to about 40 ° C.

Example 48 Treatment A treatment with the following formulation was prepared. This treatment was able to improve hair damage and give it a moist, silicone-like slippery feel. In addition, after washing with shampoo, no residual feeling was felt on the hair.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil Agent of Example 1 1.0
Plandoll-H (Nippon Fine Chemical Co., Ltd.) 0.5
Behentrimonium methsulfate 1.3
Setrimonium chloride 0.3
Paraffin 1.0
Hydroxypropyltrimonium hyaluronate 0.2
Isostearic acid hydrogenated castor oil 1.0
Squalene 2.0
Tocopherol acetate 0.05
Diethyl sebacate 2.0
Candelilla wax 0.3
Rice bran wax 0.2
Apricot kernel oil 1.0
DPG 2.0
Propanediol 1.0
Benzyl alcohol 0.5
Glycerin 1.0
PEG-7 propyl heptyl ether 0.8
PEG-180M 0.3
Part B Methylisothiazolinone 0.005
EDTA-2Na 0.03
Zinc chloride 0.1
Amount of purified water totaling 100 Polyquaternium-10 0.2
Part C LUSPLAN SR-DM4 (Nippon Fine Chemical Co., Ltd.) 0.2
DUB VCI-10 (Nippon Fine Chemical Co., Ltd.) 0.5
Neosolue-EHS (Nippon Fine Chemical Co., Ltd.) 0.7
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was added to another container and heated to dissolve it. Part B was gradually added to part A, mixed uniformly, and cooled. Part C was added at around 50 ° C. and mixed uniformly.

Example 49 Dandruff shampoo A dandruff shampoo having the following formulation was prepared. This shampoo was a shampoo that suppresses dandruff, gives hair a moist feeling and luster without using silicone, and can give smooth finger passage.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil agent of Example 1 0.05
Lauroylmethylalanine Na (30%) 13.0
Cocamidopropyl Betaine (30%) 20.0
Cocoyl Glutamic Acid TEA (30%) 5.0
Cocamide DEA 1.0
Glycerin 1.0
Glyceryl caprylate 0.4
Glyceryl undecylenic acid 0.1
Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 1.0
Sorbitol 1.6
Miconazole nitrate 0.75
Glycol distearate 1.5
Polyquaternium-7 0.3
Part B Na benzoate 0.4
Na chloride 0.2
Amount of purified water totaling 100 Part C Swertia japonica extract 3.0
Polyquaternium-10 0.2
Guar Hydroxypropyltrimonium Chloride 0.1
Polyquaternium-47 0.1
Piroctone olamine 0.1
Purified water 9.7
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was placed in a separate container and heated to dissolve it. Part B was gradually added to part A, mixed uniformly, and part C was added at about 60 ° C.

Example 50 Shampoo A hair shampoo having the following formulation was prepared. This shampoo has excellent foaming properties, and can give a moist finish and a smooth feel without using silicone.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil agent of Example 3 0.2
PPG-3 Caprylyl Ether 0.2
Ammonium Laureth Sulfate 5.0
Sodium Laureth Sulfate (25%) 10.0
Lauryl hydroxysultaine (30%) 10.0
Lauric acid K 1.0
Glycol distearate 0.5
Toluenesulfonic acid 0.3
Stearoxypropyl dimethylamine 0.5
PPG-17 0.3
Neosolue-EHS (Nippon Fine Chemical Co., Ltd.) 1.0
Neopentyl glycol diethylcaproate 0.4
Lanolin fatty acid 0.3
Isodecyl glyceryl ether 0.4
Miconazole nitrate 0.75
Cocamide MEA 1.0
Laureth-4 0.3
Laureth-16 0.2
Stairless-6 0.2
Phenoxyethanol 0.3
Part B malic acid 0.1
Methylparaben 0.2
Phosphoric acid 0.03
Na benzoate 0.3
Amount of purified water totaling 100 Part C Polyquaternium-10 0.2
Guar Hydroxypropyltrimonium Chloride 0.1
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 3.0
Purified water 6.7
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part A was uniformly mixed at about 80 ° C. Part B, which was set aside separately, was heated to about 60 ° C. to make it uniform. Part B was gradually added to part A with stirring, mixed uniformly, and then cooled to about 50 ° C. Further, part C was added and mixed uniformly.

Example 51 Hair Treatment A treatment with the following formulation was prepared. This treatment was a treatment that could improve the feeling of damage to the hair without using silicone, and could give a moist feeling, smoothness and a feeling of persistence. In addition, after washing with shampoo, no residual feeling was felt on the hair.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil Agent of Example 8 5.0
Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 0.5
Glyceryl stearate (SE) 4.5
Stairless-10 4.0
Cetanol 4.0
Stealtrimonium chloride (63%) 1.8
Behentrimonium chloride (80%) 1.0
Part B Methylparaben 0.2
Glycerin 3.0
Amount of purified water totaling 100 -------------
(Preparation method)
Part B was heated to about 80 ° C. and dissolved. Part A was added to another container and heated to dissolve it. Part B was gradually added to part A and mixed uniformly.

Example 52 Hair Treatment A treatment with the following formulation was prepared. This treatment was able to improve the feeling of damage to the hair and give it a moist feeling and smoothness.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil Agent of Example 7 3.0
Behentrimonium chloride (80%) 2.4
Cetanol 5.2
Glyceryl stearate 1.2
Neosolue-EHS (Nippon Fine Chemical Co., Ltd.) 0.4
Cyclopentasiloxane 0.8
Dimethiconol 0.1
Part B Methylparaben 0.1
Propylparaben 0.1
Amount of purified water totaling 100 Part C Aminoethylaminopropylsiloxane ・
Dimethylsiloxane copolymer emulsion 2.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Parts A and B were taken, heated to about 80 ° C., and mixed uniformly. Part B was gradually added to part A with stirring, mixed uniformly, and then cooled (part D). Part C was added to part D and mixed uniformly.

Example 53 Hair Treatment A treatment with the following formulation was prepared. This treatment was able to improve the feeling of damage to the hair and give it a moist feeling and smoothness.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil Agent of Example 7 3.0
Behentrimonium chloride (80%) 2.4
Cetanol 5.2
Glyceryl stearate 1.2
Neosolue-EHS (Nippon Fine Chemical Co., Ltd.) 0.4
Oil of Example 12 0.8
Dimethiconol 0.1
Part B Methylparaben 0.1
Propylparaben 0.1
Amount of purified water totaling 100 Part C Aminoethylaminopropylsiloxane ・
Dimethylsiloxane copolymer emulsion 2.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Parts A and B were taken, heated to about 80 ° C., and mixed uniformly. Part B was gradually added to part A with stirring, mixed uniformly, and then cooled (part D). Part C was added to part D and mixed uniformly.

Example 54 Hair Treatment A treatment with the following formulation was prepared. This treatment was able to improve the feeling of damage to the hair and give it a moist feeling and smoothness.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil Agent of Example 6 10.0
Cetanol 6.0
Dimethicone (1000cs) 2.0
Aminopropyl Dimethicone 0.4
Behentrimonium chloride (80%) 2.4
Distearyldimonium chloride (75%) 0.8
Glyceryl stearate 0.8
Part B Phenoxyethanol 0.5
Amount of purified water totaling 100 Part C Hydrolyzed keratin (20%) 1.5
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was added to another container and heated to dissolve it. Part B was gradually added to part A, mixed uniformly, and cooled. Part C was added at around 40 ° C. and mixed uniformly.

Example 55 Hair Treatment A treatment with the following formulation was prepared. This treatment had an excellent feel when rinsed, kept the hair moisturized, and was able to give the hair a glossy, moist and smooth feel.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil of Example 5 0.5
Dodecane 3.0
Behenyl alcohol 4.0
Cetanol 2.0
Behentrimonium chloride 2.0
Stearamidopropyl dimethylamine 1.0
Glyceryl stearate 0.4
PPG-9 diglyceryl 0.2
Polyglyceryl diisostearate-2 0.1
Hydrogenated lecithin 0.1
Adsorption purified lanolin 0.2
Neopentyl glycol dioctanoate 0.5
Neosolue-EHS (Nippon Fine Chemical Co., Ltd.) 0.5
Tocopherol 0.05
Part B glycerin 0.2
DPG 0.2
Hydrolyzed collagen 0.1
Panthenol 0.1
Hydroxycellulose 0.02
Polyquaternium-10 0.05
Phenoxyethanol 0.2
Citric acid Appropriate amount Edetonic acid 3Na 0.01
Pentetic acid 0.02
Amount of purified water totaling 100 Part C Arginine 0.10
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part A was heated to about 80 ° C. and dissolved uniformly. B was placed in another container and heated to about 80 ° C. to uniformly dissolve it. Part C was placed in another container, a part of purified water was added to dissolve it, and then part A was added and stirred. Further, part B was gradually added, mixed uniformly, and cooled.

Example 56 Leave on Hair Treatment A non-rinse hair treatment with the following formulation was prepared. This hair treatment improved the feeling of damage to the hair without using silicone, and improved the feeling of slipperiness and moistness. In addition, after washing with shampoo, no residual feeling was felt on the hair.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil agent of Example 7 0.1
Neosolue-Aquolio (Nippon Fine Chemical Co., Ltd.) 2.0
Setrimonium chloride (25%) 3.8
Caprylyl glucoside (50%) 0.8
Glycerin 4.0
Phenoxyethanol 0.5
Part B Ethanol 5.0
Part C Polyquaternium-6 0.6
Polyquaternium-7 0.4
Polyquaternium-39 0.5
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part C was heated to about 80 ° C. to dissolve it. Next, part A was heated to about 80 ° C. to dissolve it. Part C was added while stirring, and after mixing uniformly, the mixture was cooled to about 40 ° C. Then, part B was added and mixed uniformly.

Example 57 Mousse A mousse having the following formulation was prepared. This mousse suppressed the feeling of damage to the hair, was not sticky, and had excellent hair style retention.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Oil agent of Example 3 0.2
Ethanol 5.0
Polyethylene glycol oleyl ether (20) 1.0
Acrylic resin alkanolamine solution 3.0
Diethylaminopropylamide stearate 0.5
Pyrrolidone carboxylic acid 0.2
Preservatives, fragrances 1.0
Amount of purified water totaling 100 -------------
(Preparation method)
The above components were mixed, and the obtained base and LPG were mixed at a ratio of base: LPG = 92: 8 to obtain an injection type mousse.

Example 58 Hair Cream A hair cream having the following formulation was prepared. This hair cream suppressed the feeling of damage to the hair, was not sticky, and had an excellent feel.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A stearic acid 2.0
Lanolin 3.0
Paraffin wax 2.0
Liquid paraffin 38.0
Oil of Example 5 0.2
Glycerin monostearate (SE) 1.0
Sorbitan monostearate 1.0
Polyoxyethylene cetyl ether 1.5
Preservative Appropriate amount B part Triethanolamine 1.0
Part C 1,3-butylene glycol 3.0
(HEMA Glucoside / Ethyl Trimonium Methacrylate) Copolymer (20%, Nippon Fine Chemical Co., Ltd.) 2.5
Appropriate amount of fragrance Amount of purified water totaling 100 -------------
(Preparation method)
Part A was mixed at 80 ° C. Part B was diluted with a part of purified water, heated to 80 ° C., and added to part A (part D). Part C excluding the fragrance was mixed, heated to 80 ° C. and mixed with part A to make it uniform. After cooling to 50 ° C., a fragrance was added.

Example 59 Hair Color Treatment A non-rinse hair color treatment having the following formulation was prepared. This hair color treatment had good dyeability, had an effect of preventing fading, and was excellent in moist and smooth feeling.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil of Example 1 1.5
Neosolue-Aquolio (Nippon Fine Chemical Co., Ltd.) 1.0
Stealtrimonium chloride (70%) 2.5
Cation NH (Nippon Fine Chemical Co., Ltd.) 0.3
Cocamide DEA 1.0
Inulin stearate 0.5
Lanolin alcohol 0.2
Montan wax 0.1
Polyethylene wax 0.1
Beeswax 0.1
Dextrin palmitate 0.3
Celesin 0.1
Decanoate PPG-3 1.0
Dicapric acid PG 1.0
Ethylhexyl ethylhexanoate 1.0
Dicaprilyl Carbonate 1.5
Glycerin 4.0
Setes-7 1.0
Isostearyl alcohol 0.3
Rice bran oil 0.5
Glyceryl stearate 0.5
γ-docosalactone, diethyl sebacate (Elcalactone DES: Nippon Fine Chemical Co., Ltd.) 1.5
Hydrogenated polydecene 0.1
Macadamia nut fatty acid ethyl 1.0
Lysine dilauroyl glutamate Na 0.1
Behendimonium stearyl ethyl phosphate 0.1
Tocopherol 0.05
Phenoxyethanol 0.3
Part C purified water 10.0
BG 2.0
Acylated hydrolyzed collagen 0.1
Panthenol 0.1
Hydroxyethyl cellulose 0.1
Polyquaternium-64 0.1
Polyquaternium-51 0.01
Polyquaternium-49 0.2
Phenoxyethanol 0.4
PCA-Na 0.1
Part D Purified water Amount totaling 100 Basic blue 99 0.1
Basic tea 16 0.13
HC Blue 2 0.05
HC Yellow 2 0.03
HC Red 3 0.1
Hydroxyethylurea 0.5
Arginine 0.2
Ammonium bicarbonate 1.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part A, which had been uniformly mixed in advance, was added to part B and heated to about 80 ° C. to dissolve it (part E). Part D was heated to about 80 ° C. in another container to dissolve it. While stirring the D part in the E part, the mixture was gradually added and uniformly mixed, and then rapidly cooled (F part). Part C was added to part F at about 40 ° C. to make it uniform.

Example 60 Hair Manicure A hair manicure having the following formulation was prepared. This hair manicure has excellent dyeability and anti-fading effect, gives the hair a moist feeling and a slippery feeling, and suppresses swelling and entanglement. In addition, the effect was sustained by blowing with a dryer after washing.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil of Example 4 0.8
Ethanol 10.0
Carnauba wax 0.01
Setes-10 1.0
γ-docosalactone, diethyl sebacate (Elcalactone DES: Nippon Fine Chemical Co., Ltd.) 2.5
PPG-3 Caprylyl Ether 1.0
DUB VCI-10 (Nippon Fine Chemical Co., Ltd.) 1.0
Decanoate PPG-3 0.5
Dicapric acid PG 0.5
Dicaprilyl Carbonate 0.5
Part B Purple 401 0.2
Black 401 0.1
Orange 205 0.1
Red 102 0.1
Citric acid 2.0
Benzyl alcohol 8.0
Ethanol 10.0
Part C Purified water Amount totaling 100 (Acryloyldimethyltaurine ammonium / VP) Copolymer 3.0
Glycolic acid 2.0
Hydroxypropyl xanthan gum 0.2
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Parts A and C were mixed and made uniform. Part B was added to part C with stirring and mixed uniformly, and then part A was added at about 60 ° C. and mixed uniformly.

Example 61 Hair oil A hair oil having the following formulation was prepared. This hair oil was glossy, non-greasy, and smooth when applied to hair.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Oil Agent of Example 1 10.0
Neosolue-DE (Nippon Fine Chemical Co., Ltd.) 10.0
Neosolue-EHS (Nippon Fine Chemical Co., Ltd.) 10.0
Neosolue-MCT (Nippon Fine Chemical Co., Ltd.) 20.0
Tocopherol 0.1
Propylparaben 0.1
Cyclopentasiloxane Amount totaling 100 -------------
(Preparation method)
All components were heated and dissolved and mixed.

Example 62 Hair oil A hair oil having the following formulation was prepared. This hair oil was glossy, non-greasy, and smooth when applied to hair.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Oil Agent of Example 1 10.0
Neosolue-DE (Nippon Fine Chemical Co., Ltd.) 10.0
Neosolue-EHS (Nippon Fine Chemical Co., Ltd.) 10.0
Neosolue-MCT (Nippon Fine Chemical Co., Ltd.) 20.0
Tocopherol 0.1
Propylparaben 0.1
The total amount of the oils of Example 12 is 100.
(Preparation method)
All components were heated and dissolved and mixed.

Example 63 Nail care oil A hair oil having the following formulation was prepared. This nail care oil was glossy, non-greasy, and smooth when applied to nails.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Oil of Example 3 10.0
Neosolue-DE (Nippon Fine Chemical Co., Ltd.) 10.0
Neosolue-EHS (Nippon Fine Chemical Co., Ltd.) 10.0
Neosolue-MCT (Nippon Fine Chemical Co., Ltd.) 20.0
LUSPLAN DD-DA7 (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-H (Nippon Fine Chemical Co., Ltd.) 0.1
Tocopherol 0.1
Propylparaben 0.1
Amount of isododecane totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
All components were heated and dissolved and mixed.

Example 64 Nail care oil A hair oil having the following formulation was prepared. This nail care oil was glossy, non-greasy, and smooth when applied to nails.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Oil of Example 2 10.0
Neosolue-DES (Nippon Fine Chemical Co., Ltd.) 10.0
NS-408 (Nippon Fine Chemical Co., Ltd.) 10.0
NS-CIO (Nippon Fine Chemical Co., Ltd.) 20.0
LUSPLAN DD-DA5 (Nippon Fine Chemical Co., Ltd.) 0.5
LUSPLAN SR-DM4 (Nippon Fine Chemical Co., Ltd.) 0.5
Tocopherol 0.1
Propylparaben 0.1
Amount of oil agent of Example 14 totaling 100 -------------
(Preparation method)
All components were heated and dissolved and mixed.

Example 65 Lipstick A lipstick having the following formulation was prepared. This lipstick was glossy, fresh and highly adherent.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Oil agent of Example 1 27.2
Dimer dilinoleic acid dimer dilinoleyl,
Pentaerythrityl tetraisostearate (LUSPLAN SR-DP4: Nippon Fine Chemical Co., Ltd.) 7.0
Hydrogenated polyisobutene 5.0
Trioctanoin 10.0
Neosolue-MCT (Nippon Fine Chemical Co., Ltd.) A total amount of 100 Dialkyl carbonate (C14, 15) 3.0
Dextrin palmitate 0.9
Stearoyl Lactate Na 0.9
Cetyl octanoate 24.0
Dimethicone 5.0
Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 2.0
Celesin 8.5
Candelilla Row 4.0
Sorbitan sesquioleate 0.15
Hydrogen Dimethicone 2.0
Ethanol 0.1
Tocopherol 0.5
Nylon-12 2.0
(Ethylene / Propylene) Copolymer 0.5
Sulfate Ba 1.0
Iron oxide 2.0
Mica 2.0
Titanium oxide 1.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
After uniformly heating, stirring and mixing all the components, the mixture was filled in a mold and rapidly cooled.

Example 66 Lipstick A lipstick having the following formulation was prepared. This lipstick spreads well, has a moisturizing effect, has excellent gloss, and has adhesiveness. The stability was also good.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Plandoll-S (Nippon Fine Chemical Co., Ltd.) 10.0
Oil of Example 7 10.0
Pentaerythrityl tetraisostearate A total amount of 100 Plandol-MAS (Nippon Fine Chemical Co., Ltd.) 3.0
Cyclomethicone 10.0
LUSPLAN DD-DA5 (Nippon Fine Chemical Co., Ltd.) 7.0
Dimethylsilylated silica 5.0
Synthetic wax 10.0
Candelilla Row 5.0
Sorbitan sesquiisostearate 4.0
Tocopherol 0.5
Iron oxide 2.0
Titanium oxide 2.0
Mica 1.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
After uniformly heating, stirring and mixing all the components, the mixture was filled in a mold and rapidly cooled.

Example 67 Lipstick A lipstick having the following formulation was prepared. This lipstick was glossy, fresh and highly adherent.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Oil Agent of Example 5 15.0
Plandoll-G (Nippon Fine Chemical Co., Ltd.) 15.0
Plandoll-DP (Nippon Fine Chemical Co., Ltd.) 10.0
IOTG (Nippon Fine Chemical Co., Ltd.) A total amount of 100 Vaseline 1.5
Isododecane 10.0
Cyclomethicone 6.0
Polyethylene wax 9.0
Microcrystalline wax 5.0
LUSPLAN PI-DA (Nippon Fine Chemical Co., Ltd.) 5.0
Sorbitan sesquiisostearate 4.0
Macadamia nut oil 1.0
Tocopherol 0.5
Iron oxide 2.25
Titanium oxide 2.25
Mica 1.5
Red 202 1.5
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
After uniformly heating, stirring and mixing all the components, the mixture was filled in a mold and rapidly cooled.

Example 68 Lipstick A lipstick having the following formulation was prepared. This lipstick was glossy, fresh and highly adherent.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Oil Agent of Example 5 15.0
Oil Agent of Example 12 15.0
Plandoll-G (Nippon Fine Chemical Co., Ltd.) 15.0
Plandoll-DP (Nippon Fine Chemical Co., Ltd.) 10.0
IOTG (Nippon Fine Chemical Co., Ltd.) A total amount of 100 Vaseline 1.5
Polyethylene wax 9.0
Microcrystalline wax 5.0
LUSPLAN PI-DA (Nippon Fine Chemical Co., Ltd.) 5.0
Sorbitan sesquiisostearate 4.0
Macadamia nut oil 1.0
Tocopherol 0.5
Iron oxide 2.25
Titanium oxide 2.25
Mica 1.5
Red 202 1.5
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
After uniformly heating, stirring and mixing all the components, the mixture was filled in a mold and rapidly cooled.

Example 69 Lipstick A hydrous lipstick having the following formulation was prepared. This lipstick was a lipstick that made your lips moist and shiny.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Plandoll-ISS (Nippon Fine Chemical Co., Ltd.) 15.0
Plandoll-SUN (Nippon Fine Chemical Co., Ltd.) 15.0
Amount of oil agent of Example 7 totaling 100 LUSPLAN DD-DA7 (Nippon Fine Chemical Co., Ltd.) 3.0
Dihydrocholesteryl oleate, cholesteryl nonanoate,
Dihydrocholesteryl butyrate, cholesteryl butyrate, phytosteryl oleate (YOFCO CLC-678: Nippon Fine Chemical Co., Ltd.) 1.5
YOFCO MAC (Nippon Fine Chemical Co., Ltd.) 3.0
Shea butter 1.0
Diisostearyl malate 10.0
Candelilla Row 5.5
Celesin 9.0
Dimethicone Copolyol 0.5
Sorbitan sesquiisostearate 2.0
Tocopherol 0.1
Iron oxide 1.2
Titanium oxide 1.2
Mica 1.5
Red 202 0.3
Purified water 6.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
After uniformly heating, stirring and mixing all the components, the mixture was filled in a mold and rapidly cooled.

Example 70 Lipstick A lipstick having the following formulation was prepared. This lipstick was glossy, had an excellent usability, and was less sweaty.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Plandoll-H (Nippon Fine Chemical Co., Ltd.) 15.0
Dimeric linoleic acid hydrogenated castor oil 10.0
Purified lanolin (Nippon Fine Chemical Co., Ltd.) 10.0
Hexa (behenic acid / benzoic acid / ethyl caproic acid) dipentaerythrityl
5.0
Benzyldimethylstearylammonium bentonite 0.36
POE (20) Hydrogenated castor oil 0.12
Amount of oil agent of Example 1 totaling 100 Neosolue-EHS (Nippon Fine Chemical Co., Ltd.) 10.0
Neosolue-CIO (Nippon Fine Chemical Co., Ltd.) 10.0
Phytosteryl oleate 5.0
Sunflower oil 1.0
Cellulose 1.0
Polyethylene wax 5.0
Microcrystalline wax 4.0
Candelilla wax 1.0
Hydrogenated jojoba oil 1.0
Beeswax 1.0
Olive oil-derived squalane 1.0
Sorbitan isostearate 0.1
Ascorbyl dipalmitate 0.1
N-stearoyl-L-glutamic acid 2Na 0.15
d-δ-tocopherol 0.1
Red No. 201 2.4
Red No. 202 0.8
Black iron oxide 0.3
Synthetic mica 0.47
Bengala Coated Mica Titanium 3.0
Acyl Peptide Mixture (Zederma Maxi Lip) 0.5
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
After uniformly heating, stirring and mixing all the components, the mixture was filled in a mold and rapidly cooled.

Example 71 Lipstick A hydrous lipstick having the following formulation was prepared. This lipstick was a lipstick that made your lips moist and shiny.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Plandoll-G (Nippon Fine Chemical Co., Ltd.) 20.0
Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 10.0
YOFCO MAC (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-LG1 (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-LG2 (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-LG3 (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-LG4 (Nippon Fine Chemical Co., Ltd.) 1.0
Amount of oil agent of Example 6 totaling 100 LUSPLAN DD-DHR (Nippon Fine Chemical Co., Ltd.) 3.0
IPSE (Nippon Fine Chemical Co., Ltd.) 19.0
Candelilla Row 4.0
Celesin 5.0
Paraffin 3.0
Dimethicone Copolyol 0.5
Sorbitan sesquiisostearate 2.0
Tocopherol 0.1
Iron oxide 1.2
Titanium oxide 1.2
Mica 1.5
Red No. 218 0.1
Red No. 223 0.1
Orange 201 0.1
Glycerin 1.0
BG 1.0
Purified water 2.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
After uniformly heating, stirring and mixing all the components, the mixture was filled in a mold and rapidly cooled.

Example 72 Lipstick A lipstick having the following formulation was prepared. This lipstick was a lipstick that moisturized and made the lips glossy.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Plandoll-G (Nippon Fine Chemical Co., Ltd.) 10.0
Plandoll-LG2 (Nippon Fine Chemical Co., Ltd.) 10.0
Mineral oil 10.0
IOTG (Nippon Fine Chemical Co., Ltd.) 10.0
Octyldodecanol 5.0
Amount of oil agent of Example 5 totaling 100 Phytocompo-PP (Nippon Fine Chemical Co., Ltd.) 5.0
Hydrogenated lecithin, soybean sterol, ceramide 2, ceramide 3, ceramide 6II
(Phytopresom Cera-236: Nippon Fine Chemical Co., Ltd.) 0.5
2-Ethylhexyl hydroxystearate 3.0
(Polyglyceryl-2 isostearate / dimer dilinoleic acid) copolymer
1.0
Neopentyl glycol dicaprate 1.0
Candelilla Row 4.0
Rice wax 8.0
Polyethylene wax 2.0
Tribehenin 1.0
Sorbitan sesquiisostearate 2.0
Rosehip oil 0.1
VC Ethyl (Nippon Fine Chemical Co., Ltd.) 0.01
Tocopherol 0.1
Iron oxide 2.0
Titanium oxide 1.2
Mica 1.5
Red No. 202 0.1
Purified water 2.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
After uniformly heating, stirring and mixing all the components, the mixture was filled in a mold and rapidly cooled.

Example 73 Lipstick A lip cosmetic having the following formulation was prepared. After coating, the volatile oil volatilizes to separate into two layers, a silicone phase and an oil phase.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Diphenylmethylsiloxyphenylmethicone /
Phenylsilsesquioxane) Crosspolymer 15.0
Neosolue-MCT 10.0
Oil Agent of Example 1 5.0
IOTG (Nippon Fine Chemical Co., Ltd.) A total amount of 100 Trimethylolpropane triethylhexanoate (NS-308: Nippon Fine Chemical Co., Ltd.) 3.0
Neosolue-DE (Nippon Fine Chemical Co., Ltd.) 0.2
Methylpentanediol dineopentane (Neosolue-MP: Nippon Fine Chemical Co., Ltd.) 0.2
Isohexadecane 8.0
Isotridecyl isononanoate 8.0
Microcrystalline wax 8.0
Polyethylene 4.0
Candelilla Row 2.0
Carnauba wax 2.0
Plandoll-G (Nippon Fine Chemical Co., Ltd.) 5.0
LUSPLAN DD-DHR (Nippon Fine Chemical Co., Ltd.) 7.5
Plandoll-LG2 (Nippon Fine Chemical Co., Ltd.) 6.0
Diisostearyl malate 5.0
Squalene 5.0
Ascorbyl tetrahexyl decanoate 0.01
Hyaluronic acid Na 0.05
Sorbitan isostearate 0.1
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 0.05
Plandoll-DP (Nippon Fine Chemical Co., Ltd.) 0.01
Plandoll-LG1 (Nippon Fine Chemical Co., Ltd.) 0.01
Plandoll-LG3 (Nippon Fine Chemical Co., Ltd.) 0.01
Plandoll-LG4 (Nippon Fine Chemical Co., Ltd.) 0.01
Plandoll-S (Nippon Fine Chemical Co., Ltd.) 0.01
Tocopherol 0.1
BHT 0.01
Methylparaben 0.1
Titanium oxide Appropriate amount Zinc oxide Appropriate amount Red 202 Appropriate amount Iron oxide Appropriate amount Yellow 4 Appropriate amount Borosilicate (Ca / Al) Appropriate amount Silica Appropriate amount Tin oxide Appropriate amount −−−−−−−−−−−−−
(Preparation method)
After uniformly heating, stirring and mixing all the components, the mixture was filled in a mold and rapidly cooled.

Example 74 Lipstick A lipstick having the following formulation was prepared. This lipstick was a lipstick with excellent smoothness, luster, and color development.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Plandoll-G (Nippon Fine Chemical Co., Ltd.) 15.0
Plandoll-LG2 (Nippon Fine Chemical Co., Ltd.) 12.0
Oil of Example 9 10.0
NS-408 5.0
Diisostearyl malate Amount totaling 100 Neosolue-MCT (Nippon Fine Chemical Co., Ltd.) 10.0
Squalene 10.0
Isotridecyl isononanoate 8.0
Microcrystalline wax 4.0
Polyethylene 4.0
Sorbitan isostearate 0.1
BHT Appropriate amount Methylparaben Appropriate amount Titanium oxide Appropriate amount Zinc oxide Appropriate amount Red 202 Appropriate amount Iron oxide Appropriate amount Yellow 4 Appropriate amount Borosilicate (Ca / Al) Appropriate amount Silica Appropriate amount Tin oxide Appropriate amount −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
After uniformly heating, stirring and mixing all the components, the mixture was filled in a mold and rapidly cooled.

Example 75 Lip balm A lip balm having the following formulation was prepared. This lip balm was glossy, had excellent transparency and usability, and had high adhesion.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Plandoll-H (Nippon Fine Chemical Co., Ltd.) 15.0
Polyglyceryl diisostearate-2 15.0
Oil of Example 2 10.0
Squalane Total amount of 100 12-Hydroxystearic acid 5.0
Cyrilized silica 3.0
Menthol 0.5
Perfume Appropriate amount Antioxidant Appropriate amount －－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
All components were heated and melted and mixed uniformly.

Example 76 Transparent Lipstick A transparent lipstick having the following formulation was prepared. This transparent lipstick was glossy, fresh and highly adherent.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil Agent of Example 5 10.0
Polyglyceryl triisostearate-2 10.0
Plandoll-H (Nippon Fine Chemical Co., Ltd.) 10.0
LUSPLAN DD-DA5 (Nippon Fine Chemical Co., Ltd.) 10.0
12-Hydroxystearic acid 10.0
Mineral oil 10.0
LUSPLAN PI-DA (Nippon Fine Chemical Co., Ltd.) A total amount of 100 castor oil 1.0
2-Ethylhexyl hydroxystearate 5.0
α-olefin oligomer 5.0
Polybutene 5.0
Refined jojoba oil 5.0
Olive oil 5.0
Dipropylene glycol 0.1
Menthol 0.1
Tocopherol 0.1
Part B Perfume Appropriate amount −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A is heated to 90 to 110 ° C. and mixed and melted uniformly, and then part B is added to uniformly mix and disperse.

Example 77 Paste-like lipstick A paste-like lipstick having the following formulation was prepared. This lipstick was excellent in terms of luster and odor, and had a smooth and adherent feeling when applied.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
LUSPLAN DD-DA5 (manufactured by Nippon Fine Chemical Co., Ltd.) 40.0
Plandoll-H (manufactured by Nippon Fine Chemical Co., Ltd.) 30.0
Organic modified clay mineral (Benton 38 manufactured by National Head) 2.0
Appropriate amount of pigment Amount of oil agent of Example 3 totaling 100 -------------
(Preparation method)
All components were heated and melted and mixed uniformly.

Example 78 Paste-like lipstick A paste-like lipstick having the following formulation was prepared. This lipstick was excellent in terms of luster and odor, and had a smooth and adherent feeling when applied.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
LUSPLAN PI-DA (manufactured by Nippon Fine Chemical Co., Ltd.) 40.0
Plandoll-S (manufactured by Nippon Fine Chemical Co., Ltd.) 30.0
Dimethylsilylated silica 5.0
Dextrin palmitate 1.0
Appropriate amount of pigment Amount of oil agent of Example 6 totaling 100 -------------
(Preparation method)
All components were heated and melted and mixed uniformly.

Example 79 Paste-like lipstick A paste-like lipstick having the following formulation was prepared. This lipstick was excellent in terms of luster and odor, and had a smooth and adherent feeling when applied.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Plandoll-H (manufactured by Nippon Fine Chemical Co., Ltd.) 40.0
12-Hydroxystearic acid 8.0
Mineral oil Total amount of 100 isododecane 8.0
Trioctanoin 8.0
Oil Agent of Example 3 15.0
Dimethylsilylated silica 0.3
Red No. 202 Appropriate amount Yellow No. 4 Appropriate amount
(Preparation method)
All components were heated and melted and mixed uniformly.

Example 80 Paste-like lipstick A paste-like lipstick having the following formulation was prepared. This paste-like lipstick was excellent in terms of luster and odor, and had a smooth and adherent feeling when applied.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Plandoll-G (Nippon Fine Chemical Co., Ltd.) 50.0
LUSPLAN DD-DA5 (Nippon Fine Chemical Co., Ltd.) 20.0
Diisostearyl malate 10.0
Dimethylsilylated silica 5.0
Dextrin myristate 2.0
Pigment Appropriate amount Oil agent of Example 7 10.0
Amount of liquid paraffin totaling 100 -------------
(Preparation method)
All components were heated and melted and mixed uniformly.

Example 81 Lip Gloss Using the oily base of the present invention, a lip gloss having the following formulation was prepared. This lip gloss was glossy, had a long-lasting makeup, and had high adhesion.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Oil agent of Example 6 55.00
LUSPLAN DD-DA7 (Nippon Fine Chemical Co., Ltd.) 7.00
LUSPLAN SR-DP4 (Nippon Fine Chemical Co., Ltd.) 7.00
Cyclopentasiloxane 10.0
Phenyltrimethicone 5.0
Polyethylene wax 0.20
12-Hydroxystearic acid 1.50
Neosolue-IOP Amount totaling 100 Tocopherol Appropriate amount Dimethylsilylated silica 5.00
Mica Titanium 12.00
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
All components were heated and melted and mixed uniformly.

Example 82 Lip Gloss A lip gloss having the following formulation was prepared. This lip gloss was glossy, fresh and highly adherent.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Plandoll-H (Nippon Fine Chemical Co., Ltd.) 5.0
Plandoll-G (Nippon Fine Chemical Co., Ltd.) 5.0
Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 5.0
LUSPLAN PI-DA (manufactured by Nippon Fine Chemical Co., Ltd.) 10.0
Hydrogenated polyisobutene 10.0
Trioctanoin 5.0
Amount of oil agent of Example 4 totaling 100 Dextrin palmitate 4.0
Dimethylsilylated silica 2.0
Dimethicone 5.0
Mica 9.0
Sulfate Ba 25.0
Red 104 (1) 0.5
Yellow 203 0.8
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
All components were heated and melted and mixed uniformly.

Example 83 Lip Gloss A lip gloss having the following formulation was prepared. This lip gloss was easy to apply, had a good luster, and was able to give a light feeling of use.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Plandoll-G (Nippon Fine Chemical Co., Ltd.) 20.0
Plandoll-SUN (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-ISS (Nippon Fine Chemical Co., Ltd.) 1.0
YOFCO MAC (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-LG1 (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-LG2 (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-LG3 (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-LG4 (Nippon Fine Chemical Co., Ltd.) 1.0
LUSPLAN PI-DA (Nippon Fine Chemical Co., Ltd.) 18.0
Oil of Example 7 A total amount of 100 Dextrin palmitate 3.0
Quotanium-18 hectorite 0.5
Quotanium-18 Bentonite 1.0
Tocopherol 0.5
Titanium oxide 1.1
Iron oxide, mica 0.5
(Timiron MP-24 manufactured by Merck & Co., Ltd.)
Iron oxide 0.1
Red 104 (1) 0.1
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
All components were heated and melted and mixed uniformly. After uniformly dissolving, cool to about 40 ° C.

Example 84 Lip Gloss A lip gloss having the following formulation was prepared. This lip gloss was a lip gloss having good gloss and high adhesion.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Hydrogenated polyisobutene Amount totaling 100 LUSPLAN DD-DA7 (Nippon Fine Chemical Co., Ltd.) 15.0
LUSPLAN SR-DM4 (Nippon Fine Chemical Co., Ltd.) 3.0
Diisostearyl malate 1.0
Plandoll-G (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-SUN (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-ISS (Nippon Fine Chemical Co., Ltd.) 0.1
YOFCO MAC (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-LG1 (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-LG2 (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-LG3 (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-LG4 (Nippon Fine Chemical Co., Ltd.) 0.1
LUSPLAN PI-DA (Nippon Fine Chemical Co., Ltd.) 0.1
Pentaerythrityl tetraisostearate 32.0
Oil Agent of Example 2 5.0
Dimethylsilylated silica 6.0
Methylparaben 0.1
BHT 0.01
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
All components were heated and melted and mixed uniformly.

Example 85 Lip Gloss A lip gloss having the following formulation was prepared. This lip gloss was a lip gloss having good gloss and high adhesion.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Diisostearyl malate Amount totaling 100 LUSPLAN DD-DA7 (Nippon Fine Chemical Co., Ltd.) 25.0
Oil Agent of Example 4 10.0
Triethylhexyl trimeritate 10.6
IOTG (Nippon Fine Chemical Co., Ltd.) 10.0
Plandoll-G (Nippon Fine Chemical Co., Ltd.) 3.2
Dimethylsilylated silica 3.2
Dextrin palmitate 1.0
Neosolue-IOP (Nippon Fine Chemical Co., Ltd.) 1.6
BHT Appropriate amount Methylparaben Appropriate amount Titanium oxide Appropriate amount Zinc oxide Appropriate amount Red 202 Appropriate amount Iron oxide Appropriate amount Yellow 4 Appropriate amount Borosilicate (Ca / Al) Appropriate amount Silica Appropriate amount Tin oxide Appropriate amount −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
All components were heated and melted and mixed uniformly.

Example 86 Water-containing gloss A lip gloss having the following formulation was prepared. This lip gloss was a fresh, light and highly moisturizing lip gloss.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Octyldodecanol 27.0
Ethyl cellulose 2.5
Oil Agent of Example 1 10.0
IOTG (Nippon Fine Chemical Co., Ltd.) 3.0
LUSPLAN PI-DA (Nippon Fine Chemical Co., Ltd.) 2.0
LUSPLAN DD-DHR (Nippon Fine Chemical Co., Ltd.) 2.0
Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-H (Nippon Fine Chemical Co., Ltd.) 0.1
Diisostearyl malate 0.1
Dimethylsilylated silica 0.2
Inulin stearate 0.3
PEG-60 hydrogenated castor oil 1.0
Red No. 202 Appropriate amount Yellow No. 4 Appropriate amount Titanium oxide Appropriate amount Sorbitan stearate, coconut fatty acid sucrose mixture (ALACEL2121 manufactured by Croda Co., Ltd.) 3.0
Part B Glycerin 7.0
Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 0.4
Maltose 2.0
Phenoxyethanol 0.2
Amount of water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
A part and B part were each heated and melted to make them uniform, and B part was mixed with A part.

Example 87 Water-Containing Gloss A lip gloss having the following formulation was prepared. This lip gloss was a fresh, light and highly moisturizing lip gloss.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Octyldodecanol 27.0
Ethyl cellulose 2.5
Oil of Example 3 10.0
IPSE (Nippon Fine Chemical Co., Ltd.) 3.0
LUSPLAN PI-DA (Nippon Fine Chemical Co., Ltd.) 2.0
LUSPLAN SR-DP4 (Nippon Fine Chemical Co., Ltd.) 2.0
Plandoll-G (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-SUN (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-ISS (Nippon Fine Chemical Co., Ltd.) 0.1
YOFCO MAC (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-LG1 (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-LG2 (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-LG3 (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-LG4 (Nippon Fine Chemical Co., Ltd.) 0.1
Dimethylsilylated silica 0.5
Dextrin palmitate 0.1
PEG-60 hydrogenated castor oil 1.0
Red No. 202 Appropriate amount Red No. 218 Appropriate amount Red No. 223 Appropriate amount Orange No. 201 Appropriate amount Solbitan stearate, coconut fatty acid sucrose mixture (ALACEL2121 manufactured by Croda Co., Ltd.) 3.0
Part B Glycerin 7.0
Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 0.4
Maltose 2.0
Phenoxyethanol 0.2
Amount of water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
A part and B part were each heated and melted to make them uniform, and B part was mixed with A part.

Example 88 Mascara Using the oily base of the present invention, a mascara having the following formulation was produced. This mascara had good adhesion, had a good feeling of use, and had good stability.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Iron Oxide (Black) 10.0
Amount of purified water totaling 100 Part B Polyacrylic acid ester emulsion 30.0
Part C Light Isoparaffin 30.0
Solid paraffin 8.0
Oil of Example 8 1.2
Oil of Example 12 1.0
Plandoll-G (Nippon Fine Chemical Co., Ltd.) 0.5
Sorbitan sesquioleate 4.0
Preservatives Appropriate amount Fragrance Appropriate amount -------------
(Preparation method)
After dispersing part A with a homomixer, part B was heated and mixed (aqueous phase). The components of part B were heated and mixed, an aqueous phase was added to part B, and the mixture was uniformly emulsified and dispersed with a homomixer.

Example 89 Eyeshadow An eyeshadow having the following formulation was produced. This emulsified eye shadow had good adhesion, had a good usability, and had good emulsification stability.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A talc 10.0
Kaolin 2.0
Facial department 5.0
Part B Plandoll-H (Nippon Fine Chemical Co., Ltd.) 3.0
Stearic acid 3.0
Isopropyl myristate 5.0
Oil Agent of Example 1 5.0
Propylene glycol monolaurate 3.0
Tocopherol Appropriate amount Incense family Appropriate amount C part BG 5.0
Glycerin 1.0
Preservatives Appropriate amount Triethanolamine 1.2
Sequestrant Appropriate amount Purified water Amount totaling 100 -------------
(Preparation method)
Part A was mixed with a blender and then treated with a crusher (powder part). Parts B and C were mixed and dissolved by heating. Part A was added to part C, and the mixture was stirred and mixed. Part B was added to this with stirring, dispersed by a homomixer, and stirred and cooled to room temperature to obtain the desired eye shadow.

Example 90 Eyeshadow A foundation with the following formulation was prepared. This foundation was glossy, had excellent color development, and had a moist feel.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Oil of Example 5 3.0
Oil of Example 12 2.0
Plandoll-H (Nippon Fine Chemical Co., Ltd.) 0.6
Amount of mica totaling 100 talc 24.0
Silicone treated titanium oxide 20.0
Silicone treated iron oxide 1.9
Cyclomethicone 3.5
Trimethylsiloxysilicic acid 1.5
Octyl methoxycinnamate 1.0
Dimethicone (10cs) 0.5
Tocopherol 0.1
BHT 0.1
Phenoxyethanol 0.4
Appropriate amount of dye Perfume Appropriate amount -------------
(Preparation method)
All ingredients were mixed uniformly.

Example 91 Foundation A foundation having the following formulation was prepared. This foundation had good adhesion, gloss, excellent color development, and a moist feel.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Oil agent of Example 3 6.0
Cyclomethicone 3.5
Dimethicone (5cs) 2.0
Trimethylsiloxysilicic acid 1.5
Octyl methoxycinnamate 1.0
Octocrylene 1.0
t-Butylmethoxybenzoylmethane 0.5
Phenoxyethanol 0.4
Tocopherol 0.1
Mica 39.6
Talc 24.0
Titanium oxide 20.0
Iron oxide 1.9
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Each component was stirred at high speed and mixed uniformly.

Example 92 Foundation A foundation having the following formulation was prepared. This foundation had good spreadability, excellent color development, and a moist feeling.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Plandoll-S (manufactured by Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-G (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-SUN (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-ISS (Nippon Fine Chemical Co., Ltd.) 0.1
Oil Agent of Example 1 5.0
Oil agent of Example 12 3.5
Trimethylsiloxysilicic acid 1.5
Talc 24.0
Iron oxide 1.9
Titanium oxide 20.0
Tocopherol 0.1
Ethylhexyl methoxycinnamate 1.0
Phenoxyethanol 0.4
Amount of mica totaling 100 －－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
All components are stirred at high speed and mixed uniformly.

Example 93 Solid powder foundation A solid powder foundation having the following formulation was prepared. This solid powder foundation was excellent in usability, adhesion to the skin, long-lasting makeup, odor, and the like.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil Agent of Example 7 10.0
Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 2.0
Plandoll-G (Nippon Fine Chemical Co., Ltd.) 1.0
Perfluoropolyether 5.0
Part B Silicone treated sericite 60.0
Titanium oxide 10.0
Powdered synthetic hydrocarbon wax 1.0
Yellow iron oxide 1.0
Bengala 0.5
Methylparaben 0.5
Black iron oxide 0.05
Amount of talc totaling 100 －－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Heat and mix part A. Take part B in a separate container and mix and disperse (part B). Add part A to part B and mix uniformly.

Example 94 Solid powder foundation A solid powder foundation having the following formulation was prepared. This solid powder foundation was excellent in usability, adhesion to the skin, long-lasting makeup, odor, and the like.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Plandoll-H (Nippon Fine Chemical Co., Ltd.) 2.0
YOFCO MAC (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-LG1 (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-LG2 (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-LG3 (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-LG4 (Nippon Fine Chemical Co., Ltd.) 0.1
LUSPLAN PI-DA (Nippon Fine Chemical Co., Ltd.) 3.0
NS-CIO (Nippon Fine Chemical Co., Ltd.) 3.0
Oil of Example 9 2.0
Mineral oil 1.6
Part B Lecithin-treated sericite 20.0
Boron nitride 10.0
Mica 3.0
Silica 2.0
Dimethicone 3.0
Nylon-12 3.0
Talc 10.0
Titanium oxide 10.0
Amount of iron oxide totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Heat and mix part A. Take part B in a separate container and mix and disperse. Add part A to part B and mix uniformly.

Example 95 Liquid foundation A liquid foundation having the following formulation was prepared. This liquid foundation had good luster, excellent usability, and adhesion to the skin.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Plandoll-G (Nippon Fine Chemical Co., Ltd.) 5.0
Glyceryl stearate (SE) 1.0
Stearic acid PG (SE) 1.0
Oil agent of Example 6 Amount of total to 100 Tocopherol 0.1
Propylparaben 1.0
Part B Titanium oxide / iron oxide mixture (FDP-W-007 manufactured by Toiro Pigment Co., Ltd.) 18.0
Mica 7.0
BG 5.0
Methylparaben 0.2
Purified water 40.0
Part C Cellulose gum (2% aqueous dispersion) 5.0
Xanthan gum (2% aqueous dispersion) 5.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
A part, B part, and C part are heated and mixed. Part B was added to part A, emulsified, cooled to about 50 ° C., part C was added, and the mixture was stirred until uniform.

Example 96 Liquid foundation An emulsified foundation having the following formulation was prepared. This emulsified foundation spreads well, has a silky feel, and has high adhesiveness.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Purified water Amount totaling 100 Carboxyvinyl polymer 0.1
Potassium hydroxide Appropriate amount DPG 5.0
Preservative Appropriate amount B part Polyoxyethylene modified dimethylpolysiloxane 1.0
Trimethylsiloxysilicic acid 3.0
Phenylmethicone 1.0
Cyclomethicone 9.0
Oil Agent of Example 2 5.0
Part C Zinc Oxide 10.0
Sericite 0.36
Titanium oxide 8.32
Iron Oxide Yellow 0.8
Iron oxide red 0.36
Iron oxide black 0.16
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
After heating and stirring Part A at 70 ° C., Part C was added for dispersion treatment. This was preheated to 70 ° C. and added to part B for emulsification and dispersion. Then it was cooled to room temperature.

Example 97 Liquid Foundation A W / O emulsion type liquid foundation having the following formulation was prepared. This liquid foundation had good elongation and adhesiveness, and was able to give a light feeling of use.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil Agent of Example 1 7.0
Octilt Azone 1.5
Ethylhexyl methoxycinnamate 1.0
Quotanium-18 hectorite 0.5
Part B Cyclomethicone 25.0
Polyether modified silicone mixture 5.0
(BY22-008M manufactured by Toray Dow Corning Silicone Co., Ltd.)
Polyglyceryl isostearate-2 1.0
Titanium oxide / iron oxide mixture 12.5
(FDP-C111S manufactured by Toiro Pigment Co., Ltd.)
Mica 6.0
Part C Glycerin 5.0
Methylparaben 0.2
Amount of purified water totaling 100 -------------
(Preparation method)
Part A was heated and dissolved, and part B was heated and uniformly dispersed in part A (part D). Part C is heated and dissolved, part C is added to part D with stirring, emulsified, and then cooled to about 40 ° C.

Example 98 Foundation A foundation having the following formulation was prepared. This foundation had good adhesion to the skin and good color development, and gave the skin a moisturizing effect. Further, by blending Neosolue-AquaS, the color development property was improved.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil Agent of Example 2 5.0
Cyclopentasiloxane 4.0
Mineral oil 4.0
Ethylhexyl methoxycinnamate 3.0
Plandoll-H (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-G (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 1.0
Vaseline 1.0
Phenyltrimethicone 2.0
Sorbitan isostearate 1.5
Tribehenin 0.5
(Butyl acrylate / glycol dimethacrylate) Crosspolymer,
Silica, (Methyl Methacrylate / Glycol Dimethacrylate)
Crosspolymer mixture 2.0
Boron Nitride 1.0
PEG / PPG-19 / 19 Dimethicone,
Cyclopentasiloxane mixture 4.0
Gistear dimonium hectorite (20%) 2.5
Polypropyl sesquioxane,
Cyclopentasiloxane mixture 1.0
Mica 15.0
Talc 4.0
Zinc oxide 5.0
Titanium oxide 10.0
Iron oxide 1.5
Part B Water Total amount of 100 DPG 4.0
Maltitol (75% solution) 1.0
Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 0.4
Na chloride 1.0
BG 1.0
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 1.0
Hyaluronic acid (1% solution) 0.1
Phenoxyethanol 0.3
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part A was heated to about 70 ° C., stirred well and dispersed uniformly. Part B was heated to about 70 ° C. to make it uniform, and then part B was added to part A, stirred and emulsified at about 70 ° C., and cooled to about 40 ° C.

Example 99 Foundation A foundation having the following formulation was prepared. This foundation had good adhesion to the skin and good color development, and gave the skin a moisturizing effect. Further, by blending Neosolue-AquaS, the color development property was improved.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Oil agent of Example 6 20.0
Isododecane 10.0
Neosolue-MCT (Nippon Fine Chemical Co., Ltd.) 4.0
Ethylhexyl methoxycinnamate 3.0
Plandoll-SUN (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-LG2 (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-LG4 (Nippon Fine Chemical Co., Ltd.) 1.0
Vaseline 1.0
Isotridecyl isononanoate 2.0
Ascorbyl tetrahexyl decanoate 0.1
Dextrin palmitate 0.3
Sorbitan isostearate 1.5
Tribehenin 0.5
(Butyl acrylate / glycol dimethacrylate) Crosspolymer,
Silica, (Methyl Methacrylate / Glycol Dimethacrylate)
Crosspolymer mixture 2.0
Boron Nitride 1.0
Polysorbate 20 2.0
PEG-60 hydrogenated castor oil 1.0
Gistear dimonium hectorite (20%) 2.5
Polypropyl sesquioxane cyclopentasiloxane mixture 1.0
Mica 15.0
Talc 4.0
Zinc oxide 5.0
Titanium oxide 10.0
Iron oxide 1.5
Part B Water Total amount of 100 DPG 4.0
Maltitol (75% solution) 1.0
Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 0.4
Na chloride 1.0
BG 1.0
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 1.0
Ethanol 0.5
Phenoxyethanol 0.3
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part A was heated to about 70 ° C., stirred well and dispersed uniformly. Part B was heated to about 70 ° C. to make it uniform, and then part B was added to part A, stirred and emulsified at about 70 ° C., and cooled to about 40 ° C.

Example 100 Dual-use foundation A dual-purpose foundation having the following formulation was prepared. This dual-purpose foundation had good spreadability, a silky feel, and high adhesiveness.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Metal soap treatment talc 19.0
Metal soap treatment mica Amount totaling 100 Metal soap treatment Titanium oxide 5.0
Zinc oxide 15.0
Metal soap treatment Bengala 1.0
Metal soap treatment Yellow iron oxide 3.0
Metal soap treatment Black iron oxide 0.2
Zinc stearate 0.1
Nylon powder 2.0
Boron Nitride 5.0
Tremoist-TP (Nippon Fine Chemical Co., Ltd.) 0.01
Part B Oil of Example 4 4.0
YOFCO MAC (Nippon Fine Chemical Co., Ltd.) 0.2
Plandoll-LG2 (Nippon Fine Chemical Co., Ltd.) 4.0
Dextrin palmitate 0.1
Tetradecene 0.5
Oil Agent of Example 1 5.0
Octyl methoxycinnamate 1.0
Preservatives Appropriate amount Antioxidants Appropriate amount Fragrance Appropriate amount
(Preparation method)
Part A was mixed with a Henschel mixer, and then part B was added and mixed and pulverized by heating and dissolving, and this was molded into a middle plate.

Example 101 Base cream A base cream having the following formulation was prepared. This foundation cream was a foundation cream having the characteristics that it spreads well, has a foundation, has a good stickiness, can give a silky feel, and further improves familiarity with the foundation.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A LUSPLAN DD-DA7 (manufactured by Nippon Fine Chemical Co., Ltd.) 5.0
Oil agent of Example 2 2.5
Argania spinosa kernel oil 0.1
Cyclomethicone 14.0
Trimethylsiloxysilicic acid 3.0
Glyceryl stearate (SE) 2.0
Stearic acid PG (SE) 2.0
Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 0.5
Stearic acid 0.5
Palmitic acid 0.5
Ethylhexyl methoxycinnamate 0.5
Tocopherol 0.2
Part B BG 10.0
Ethanol 1.0
Mica 8.0
Talc 7.0
Phenoxyethanol 0.8
Titanate (Li / cobalt) 0.2
Amount of purified water totaling 100 Part C Dextrin (1%) 1.0
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 1.0
Xanthan gum (10%) 1.0
Cellulose gum (10%) 1.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Parts A and B were heated and dissolved in separate containers. Part B was added to part A and emulsified, then part C was added and mixed uniformly. After stirring, the mixture was cooled to 40 ° C.

Example 102 Sunscreen cosmetics A sunscreen cosmetics having the following formulation was prepared. This sunscreen cosmetic had good pigment dispersibility, did not cause whitening, and had a high UV protection effect.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Quotanium-18 Hectorite 1.0
Part B Cyclomethicone 13.7
Diphenyldimethicone 2.0
Oil Agent of Example 1 10.0
Plandoll-H (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-G (Nippon Fine Chemical Co., Ltd.) 0.5
Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 2.0
Dicaprilyl Carbonate 1.0
Dimethicone Copolyol 5.5
Part C Silicone treated fine particles Titanium oxide 3.9
Silicone treated zinc oxide 2.1
Part D Stearic acid Al 0.7
Al 0.5 hydroxide
Isononyl isononanoate 2.5
DUB VCI-10 (Nippon Fine Chemical Co., Ltd.) 1.5
Neosolue-MP (Nippon Fine Chemical Co., Ltd.) 1.0
Neosolue-DE (Nippon Fine Chemical Co., Ltd.) 1.0
Part E trimethylsiloxysilicic acid 1.2
Stearyl glycyrrhetinate 0.02
Sorbitan sesquioleate 2.0
Tocopherol 0.02
Part F Na chloride 1.0
Methylparaben 0.15
Amount of purified water totaling 100 -------------
(Preparation method)
Add part A to part B and stir. Further C is added and dispersed using a roller mill. The D part is heated and melted, added to the mixture of A, B, and C parts, and the E part is further added to bring the temperature to about 70 ° C. Part F is warmed and gradually emulsified with stirring in the mixture of parts A to E. Cool with stirring, stop stirring at 40-35 ° C, and leave.

Example 103 Sunscreen Cosmetics A sunscreen having the following formulation was prepared. This sunscreen spread well and had a high UV protection effect. The stability was also good.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Ultrafine Titanium Oxide 5.0
Amount of purified water totaling 100 BG 7.0
Disodium edetate 0.05
Triethanolamine 1.0
Part B Oxybenzone 3.0
Octyl paramethoxycinnamate 5.0
t-Butylmethoxybenzoylmethane 3.0
Oil of Example 3 10.0
Neosolue-EHS (Nippon Fine Chemical Co., Ltd.) 8.0
Plandoll-H (Nippon Fine Chemical Co., Ltd.) 2.0
Plandoll-SUN (Nippon Fine Chemical Co., Ltd.) 2.0
YOFCO MAS (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-LG1 (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-LG2 (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-LG3 (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-LG4 (Nippon Fine Chemical Co., Ltd.) 0.1
LUSPLAN PI-DA (Nippon Fine Chemical Co., Ltd.) 3.0
NS-CIO (Nippon Fine Chemical Co., Ltd.) 3.0
IPSE (Nippon Fine Chemical Co., Ltd.) 5.0
Stearyl alcohol 3.0
Bacil alcohol 1.0
Stearic acid 3.0
Glyceryl monostearate 3.0
Ethyl acrylate 1.0
Antioxidants, preservatives, fragrances Appropriate amount -------------
(Preparation method)
Part A is heated and dissolved to sufficiently disperse it. A portion B to be heated and dissolved was added thereto, and the mixture was emulsified and dispersed using a homogenizer, and the mixture was stirred and cooled to room temperature.

Example 104 Sunscreen Cosmetics A sunscreen cosmetic having the following formulation was prepared. This sunscreen cosmetic was a sunscreen cosmetic having the characteristics of suppressing collapse due to sweat and the like and having good familiarity.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Phytocompo-PP (Nippon Fine Chemical Co., Ltd.) 1.0
BG 10.0
Glycerin 9.0
Part B Octocrylene 4.0
Octyl salicylate 4.0
Diethylaminohydroxybenzoyl hexyl benzoate 2.25
t-Butylmethoxydibenzoylmethane 1.0
Neosolue-EHS (Nippon Fine Chemical Co., Ltd.) 3.0
NS-408 (Nippon Fine Chemical Co., Ltd.) 2.0
IPSE (Nippon Fine Chemical Co., Ltd.) 1.0
Oil Agent of Example 5 5.0
Behenyl alcohol 2.0
Cetearyl alcohol 2.0
Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 1.0
Tocopherol 0.05
Part C Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 1.0
Methylparaben Appropriate amount Water Amount that totals 100 Part D Carbomer (2%) 5.0
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 10.0
Water-dispersed titanium oxide 5.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Disperse part A evenly. Parts B and C are each heated and dissolved at about 70 ° C. After gradually adding the B part to the A part, the C part is gradually added and emulsified. Cool while stirring, add part D at 45 ° C. and stir.

Example 105 Sunscreen Cosmetics A sunscreen cosmetic having the following formulation was prepared. This sunscreen cosmetic had good pigment dispersibility, did not cause whitening, and had a high UV protection effect.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Phytocompo-PP (Nippon Fine Chemical Co., Ltd.) 1.0
BG 10.0
Glycerin 9.0
Part B Ethylhexyl methoxycinnamate 7.0
Diethylaminohydroxybenzoyl hexyl benzoate 7.0
Oil Agent of Example 8 5.0
Behenyl alcohol 4.0
Plandoll-LG1 (Nippon Fine Chemical Co., Ltd.) 0.5
Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 1.0
Part C Methylparaben 0.15
Amount of purified water totaling 100 Part D Xanthan gum (2%) 10.0
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 10.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Disperse part A evenly. Parts B and C are each heated and dissolved at about 70 ° C. After gradually adding the B part to the A part, the C part is gradually added and emulsified. Cool while stirring, add part D at 45 ° C, and stir.

Example 106 Sunscreen Cosmetics A sunscreen cosmetic having the following formulation was prepared. This sunscreen cosmetic had good pigment dispersibility, did not cause whitening, and had a high UV protection effect.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Silicone treated zinc oxide 5.0
Neosolue-EHS (Nippon Fine Chemical Co., Ltd.) 2.0
Diethylaminohydroxybenzoyl hexyl benzoate 3.0
Ethylhexyl methoxycinnamate 3.0
Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 1.0
Oil of Example 3 1.0
Cyclopentasiloxane 12.0
PEG-10 Dimethicone 2.0
Lauryl PEG-10 Tris (trimethylsiloxy)
Cyril ethyl dimethicone 2.0
NS-408 (Nippon Fine Chemical Co., Ltd.) 2.0
Neosolue-MP (Nippon Fine Chemical Co., Ltd.) 0.5
PEG / PPG-19 / 19 dimethicone, cyclopentasiloxane
1.0
Part B Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 5.0
Glycerin 3.0
BG 9.0
Phenoxyethanol 0.3
NaCl 0.04
VC Ethyl (Nippon Fine Chemical Co., Ltd.) 0.1
Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 1.0
Amount of water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Parts A and B are heated and dissolved to uniformly disperse. Part B is gradually added to part A to emulsify. Cool with stirring.

Example 107 Sunscreen Cosmetics A sunscreen cosmetic having the following formulation was prepared. This sunscreen cosmetic had good pigment dispersibility, did not cause whitening, and had a high UV protection effect.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Silicone treated zinc oxide 5.0
Neosolue-EHS (Nippon Fine Chemical Co., Ltd.) 2.0
Diethylaminohydroxybenzoyl hexyl benzoate 3.0
Ethylhexyl methoxycinnamate 3.0
Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 1.0
Oil of Example 3 1.0
Oil Agent of Example 12 12.0
PEG-10 Dimethicone 2.0
Lauryl PEG-10 Tris (trimethylsiloxy)
Cyril ethyl dimethicone 2.0
NS-408 (Nippon Fine Chemical Co., Ltd.) 2.0
Neosolue-MP (Nippon Fine Chemical Co., Ltd.) 0.5
PEG / PPG-19 / 19 dimethicone, cyclopentasiloxane
1.0
Part B Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 5.0
Glycerin 3.0
BG 9.0
Phenoxyethanol 0.3
NaCl 0.04
VC Ethyl (Nippon Fine Chemical Co., Ltd.) 0.1
Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 1.0
Amount of water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Parts A and B are heated and dissolved to uniformly disperse. Part B is gradually added to part A to emulsify. Cool with stirring.

Example 108 Sunscreen cosmetics A sunscreen cosmetics having the following formulation was prepared. This sunscreen cosmetic had good pigment dispersibility, did not cause whitening, and had a high UV protection effect.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Silicone treated zinc oxide 8.0
Neosolue-EHS (Nippon Fine Chemical Co., Ltd.) 3.0
Diethylaminohydroxybenzoyl hexyl benzoate 5.0
Ethylhexyl methoxycinnamate 5.0
Oil of Example 7 1.0
Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-H (Nippon Fine Chemical Co., Ltd.) 0.1
YOFCO MAC (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-LG1 (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-LG2 (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-LG3 (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-LG4 (Nippon Fine Chemical Co., Ltd.) 0.1
LUSPLAN PI-DA (Nippon Fine Chemical Co., Ltd.) 0.1
NS-CIO (Nippon Fine Chemical Co., Ltd.) 0.1
Cyclopentasiloxane 5.0
Cetyl PEG / PPG-10 / 1 Dimethicone 2.0
PEG-9 Polydimethylsiloxyethyl Dimethicone 1.0
NS-408 (Nippon Fine Chemical Co., Ltd.) 2.0
Neosolue-DE (Nippon Fine Chemical Co., Ltd.) 0.5
Organic modified clay mineral 2.0
(Benton 38 manufactured by National Head)
Part B Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 5.0
Glycerin 3.0
BG 9.0
Phenoxyethanol 0.3
NaCl 0.04
VC Ethyl (Nippon Fine Chemical Co., Ltd.) 0.1
Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 1.0
Amount of water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Parts A and B are heated and dissolved to uniformly disperse. Part B is gradually added to part A to emulsify. Cool with stirring.

Example 109 Cream A cream having the following formulation was prepared. This cream softened the skin and had a moist and smooth feel. These effects last for a long time and are water repellent.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Mineral oil 7.8
Vaseline 7.0
Squalene 0.2
Jojoba oil 0.15
Microcrystalline wax 2.4
Paraffin wax 2.0
Al 0.9 distearate
Hydrogenated polyisobutene 2.8
Lanolin alcohol (Ecolano AL-E: Nippon Fine Chemical Co., Ltd.) 2.3
Octyldodecanol 3.0
Oil of Example 5 1.0
Part B Magnesium Sulfate 0.5
Na benzoate 0.1
Concentrated glycerin 3.5
Amount of purified water totaling 100 Part C Mg stearate 0.9
Cyclomethicone 2.5
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Parts A and B are heated and dissolved to uniformly disperse. Part B is gradually added to part A to emulsify. The dispersed part C is blended and cooled with stirring.

Example 110 Lip balm A lip balm having the following formulation was prepared. This lip balm softened the skin and gave a moist and smooth feel. These effects lasted for a long time.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Liquid lanolin (Nippon Fine Chemical Co., Ltd.) A total amount of 100 Neosolue-MCT (Nippon Fine Chemical Co., Ltd.) 20.0
Candelilla Row 10.0
Oil Agent of Example 1 5.0
Purified lanolin (Nippon Fine Chemical Co., Ltd.) 5.0
Beeswax 3.0
Stearic acid 1.0
Olive oil 1.0
Squalene 1.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
All components were heated and melted and mixed uniformly.

Example 111 Antiperspirant An antiperspirant having the following formulation was prepared. This antiperspirant suppressed perspiration and was smooth to apply. These effects lasted for a long time.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Alum 5.0
Zinc oxide (zinc oxide) 1.0
Silica 8.0
(Dimethicone / Vinyl Dimethicone) Cross Polymer 3.0
Paraffin 10.0
Stearyl alcohol 10.0
Oil Agent of Example 4 10.0
Cyclomethicone Amount totaling 100 Methylphenylpolysiloxane 8.0
PEG-9 Dimethicone 2.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
All components were heated and melted and mixed uniformly.

Example 112 Antiperspirant An antiperspirant having the following formulation was prepared. This antiperspirant suppressed perspiration and was smooth to apply. These effects lasted for a long time.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Alum 10.0
Isopropylmethylphenol 0.1
Menthol 0.2
Amount of oil agent of Example 2 totaling 100 Plandol-MAS (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-H (Nippon Fine Chemical Co., Ltd.) 0.1
YOFCO MAC (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-LG1 (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-LG2 (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-LG3 (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-LG4 (Nippon Fine Chemical Co., Ltd.) 0.1
LUSPLAN PI-DA (Nippon Fine Chemical Co., Ltd.) 0.1
NS-CIO (Nippon Fine Chemical Co., Ltd.) 0.1
Sorbitan sesquiisostearate 3.0
Stearyl alcohol 50.0
BHT 0.005
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
All components were heated and melted and mixed uniformly.

Example 113 Antiperspirant An antiperspirant having the following formulation was prepared. This antiperspirant suppressed perspiration and was smooth to apply. These effects lasted for a long time.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Chlorhydroxy Al 20.0
Talc 7.0
Stearyl alcohol 9.0
NS-408 (Nippon Fine Chemical Co., Ltd.) 2.0
NS-308 (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-S (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-G (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-SUN (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-ISS (Nippon Fine Chemical Co., Ltd.) 0.1
Microcrystalline wax 2.0
PPG-17 Butyl 3.0
BHT 0.01
Stearyl glycyrrhetinate 0.02
Titanium oxide 0.2
Appropriate amount of fragrance Amount of oil agent of Example 1 totaling 100 -------------
(Preparation method)
All components were heated and melted and mixed uniformly.

Example 114 Antiperspirant An antiperspirant having the following formulation was prepared. This antiperspirant suppressed perspiration and was smooth to apply. These effects lasted for a long time.

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Grilled alum 5.0
Isopropylmethylphenol 0.1
Menthol 0.1
Tocopherol 0.03
Cellulose 1.0
Octyldodecanol 10.0
IOP (Nippon Fine Chemical Co., Ltd.) 10.0
IOTG (Nippon Fine Chemical Co., Ltd.) 10.0
NS-CIO (Nippon Fine Chemical Co., Ltd.) 5.0
Neosolue-EHS (Nippon Fine Chemical Co., Ltd.) 5.0
Neosolue-MCT (Nippon Fine Chemical Co., Ltd.) 10.0
Silica 2.0
Microcrystalline wax 3.0
Polymethylsilsesquioxane 1.0
Methyl Methacrylate Cross Polymer 1.0
Methylphenyl polysiloxane 10.0
Distearyldimethylammonium hectorite 3.0
Dextrin palmitate 1.0
Trilaureth-4 Phosphate 1.0
Ethanol 5.0
The total amount of the oils of Example 1 is 100.
(Preparation method)
All components were heated and melted and mixed uniformly.

Claims (5)

It is composed of the following components (A) and (B), and is characterized in that the content of the component (A) is 0.1 to 50% by weight and the content of the component (B) is 50 to 99.9% by weight. Cosmetic oil to be used.
(A) Diisopropyl dimerginolate, diisostearyl dimerginoleate, dimersielyl dimerginolate (isostearyl / phytosteryl), dimerdilinoleic acid (phytosteryl / behenyl), dimerserylinolic acid (phytosteryl / isostearyl / cetyl) / Stearyl / Behenyl), Dymelylinoleyl bis (Behenyl / Isostearyl / Phytosteryl), Dymaly linoleic acid-hardened castor oil, Dymaly linoleyl diisostearate, Dymaly linoleyl hydrogenated rosin condensate, Cholesterol , Phytosterol, cholesteryl oleate, phytosteryl oleate, cholesteryl isostearate, phytosteryl isostearate, macademia nut oil fatty acid cholesteryl, macadamia nut oil fatty acid phytosteryl, sunflower seed oil fatty acid cholesteryl, and sunflower seed oil fatty acid phytosteryl (B) One or more selected from a diester of succinic acid and a monovalent alcohol having 2 to 12 carbon atoms and an ester of isostearic acid and a monovalent alcohol having 2 to 4 carbon atoms. It consists of the following components (A), (B) and (C), the content of the component (A) is 0.1 to 5% by weight, the content of the component (B) is 10 to 79.9% by weight, and the component. A cosmetic oil having a content of (C) of 20 to 85% by weight.
(A) Diisopropyl dimerginolate, diisostearyl dimerginolate, dimersielyl dimerginolate (isostearyl / phytosteryl), dimerginolic acid (phytosteryl / behenyl), dimerserylinolic acid (phytosteryl / isostearyl / cetyl) / Stearyl / behenyl), dimer dilinoleyl bis (behenyl / isostearyl / phytosteryl), dimer dilinoleic acid-hardened castor oil, diisostearate dimer dinorail, dimer dinorail hydrogenated rosin condensate, cholesterol , Phytosterol, cholesteryl oleate, phytosteryl oleate, cholesteryl isostearate, phytosteryl isostearate, macademia nut oil fatty acid cholesteryl, macadamia nut oil fatty acid phytosteryl, sunflower seed oil fatty acid cholesteryl, and sunflower seed oil fatty acid phytosteryl (B) Diester of succinic acid and monovalent alcohol having 2 to 12 carbon atoms, ester of oleic acid and monovalent alcohol having 2 to 4 carbon atoms, and isostearic acid and monovalent alcohol having 2 to 4 carbon atoms. One or more selected from the esters of (C) Volatile fatty acids The cosmetic oil according to claim 1 or 2, wherein the component (A) is selected from dimer dilinoleate di (isostearyl / phytosterol) and phytosterol. A cosmetic containing 0.01 to 99% by weight of the cosmetic oil according to any one of claims 1 to 3. A cosmetic containing 0.01 to 99% by weight of the cosmetic oil according to any one of claims 1 to 3 and not containing a silicone compound.