JP7036421B2 - Hair cosmetics - Google Patents

Description

The present invention relates to a hair cosmetic, and more specifically, when applied to wet hair after washing, it is easy to spread the hair evenly and evenly over the entire hair, and the hair cosmetic does not immediately drip from the hair after application. It is related to hair cosmetics that cling firmly to the hair, have a soft feel when rinsing, and are easy to pass through with fingers, and give a soft, moist and cohesive finish without giving the hair stickiness after drying.

With the trend of women's hairstyles, the required hair finish and feel are also changing at the same time. Recently, hairstyles such as shaggy and layer cuts that reduce the volume of hair tips are common, but on the other hand, dryness and hardness of hair have become problems due to treatments such as coloring and perm. From such a background, the finish is required to be moist, cohesive, non-greasy, and soft. In addition, hair damaged by treatments such as coloring and perm leads to an unpleasant feeling such as entanglement and catching even when rinsing the hair treatment. This unpleasant feel during rinsing also greatly affects the satisfaction of the finished feeling. Therefore, in order to obtain a highly satisfying finish, it is desired to have a soft, moist and cohesive finish that is not sticky, and that is soft and easy to use even when rinsing a hair treatment. In hair cosmetics such as hair treatments, conventionally, for the purpose of softening the hair and improving combing, a cationic surfactant, silicone, etc. are blended, or in a liquid or solid state to give a moist feel. However, it is difficult to meet the needs of recent hairstyles with these conventional techniques, and the finish is moist, non-greasy, and soft when used. However, it was a problem to achieve both a soft feel when rinsing and a good feeling of finger passage.

Japanese Unexamined Patent Publication No. 2014-043402 Japanese Unexamined Patent Publication No. 2014-0434119 Japanese Unexamined Patent Publication No. 2015-124173 Japanese Unexamined Patent Publication No. 2015-124174

An object of the present invention is that when applied to wet hair after washing, it is easy to spread evenly and evenly over the entire hair, and after application, the hair cosmetic does not immediately drip from the hair and clings firmly to the hair. Furthermore, it is intended to provide hair cosmetics that have a soft feel when rinsing and are easy to pass through with fingers, and give a soft, moist and cohesive finish without giving stickiness to the hair after drying.

As a result of diligent research in view of such circumstances, the present inventor has found that hair cosmetics containing a specific aliphatic amine, a higher alcohol, polyethylene glycol having a molecular weight of a certain level or higher, and a nonionic cellulose derivative have been found. We have found that the above problems can be solved, and have completed the present invention.

The first invention of the present application is a hair cosmetic containing the following components (A) to (C).
(A) Aliphatic amine represented by the following general formula (I)

（式中、Ｒ^１は、直鎖又は分岐した炭素数１２～２４の飽和もしくは不飽和アルキル基、Ｒ^２はＣ_２Ｈ_４Ｏで表されるヒドロキシエチル基、Ｒ^３はＣ_３Ｈ_６Ｏで表されるヒドロキシプロピル基、ａ、ｂは０～３の整数）
（Ｂ）分子量９００００以上のポリエチレングリコール
（Ｃ）ノニオン性セルロース誘導体

(In the formula, R ¹ is a linear or branched saturated or unsaturated alkyl group having 12 to 24 carbon atoms, R ² is a hydroxyethyl group represented by C ₂ H ₄ O, and R ³ is C ₃ H ₆ O. (Hydroxypropyl group represented by, a and b are integers of 0 to 3)
(B) Polyethylene glycol (C) nonionic cellulose derivative having a molecular weight of 90,000 or more

（式中、Ｒ^１は、直鎖又は分岐した炭素数１２～２４の飽和もしくは不飽和アルキル基、
Ｒ^２はＣ_２Ｈ_４Ｏで表されるヒドロキシエチル基、Ｒ^３はＣ_３Ｈ_６Ｏで表されるヒドロキシプロピル基、ａ、ｂは０～３の整数）
（Ｂ）分子量９００００以上のポリエチレングリコール
毛髪化粧料全質量に対し０．００２～０．２質量％
（Ｃ）ノニオン性セルロース誘導体
毛髪化粧料全質量に対し０．０１～１．０質量％ The second invention of the present application is the hair cosmetic according to claim 1, wherein the blending amounts of the components (A) to (C) are as follows.
(A) Aliphatic amine represented by the following general formula (I)
0.5 to 10.0% by mass with respect to the total mass of hair cosmetics

(In the formula, R ¹ is a linear or branched saturated or unsaturated alkyl group having 12 to 24 carbon atoms.
R ² is a hydroxyethyl group represented by C ₂ H ₄ O, R ³ is a hydroxypropyl group represented by C ₃ H ₆ O, and a and b are integers of 0 to 3).
(B) Polyethylene glycol having a molecular weight of 90,000 or more
0.002-0.2% by mass with respect to the total mass of hair cosmetics
(C) Nonionic cellulose derivative
0.01-1.0% by mass with respect to the total mass of hair cosmetics

The third invention of the present application is claimed 1 or 2, wherein the mass ratio (B) / (C) of the component (B) to the component (C) is 0.01 to 2.0. It is the hair cosmetics described in.

When the hair cosmetic of the present invention is applied to wet hair after washing, it is easy to spread evenly and evenly over the entire hair, and the hair cosmetic does not immediately drip from the hair after application, and is firmly applied to the hair. It clings to the hair, and the feel of the hair when rinsing is soft and easy to pass through the fingers. After drying, the hair does not become sticky and can be given a soft, moist and cohesive finish.

Hereinafter, the hair cosmetic of the present invention will be described in detail.

（式中、Ｒ^１は、直鎖又は分岐した炭素数１２～２４の飽和もしくは不飽和アルキル基、Ｒ^２はＣ_２Ｈ_４Ｏで表されるヒドロキシエチル基、Ｒ^３はＣ_３Ｈ_６Ｏで表されるヒドロキシプロピル基、ａ、ｂは０～３の整数）で表される。 The aliphatic amine of the component (A) in the present invention is, for example, the following general formula (I).

(In the formula, R ¹ is a linear or branched saturated or unsaturated alkyl group having 12 to 24 carbon atoms, R ² is a hydroxyethyl group represented by C ₂ H ₄ O, and R ³ is C ₃ H ₆ O. The hydroxypropyl group represented by (a, b is an integer of 0 to 3).

Specific examples of such aliphatic amines include PPG-1 / PEG-1 lauramine, PPG-1 / PEG-1 myristamine, PPG-1 / PEG-1 setamine, PPG-1 / PEG-1 stearamine, and PPG-. 1 / PEG-1 aracamine, PPG-1 / PEG-1 behenamine, PPG-1 / PEG-1 carnabamine, PPG-1 / PEG-1 oleamine, PPG-1 / PEG-1 elizamin, PPG-1 / PEG-1 Linolamine, PPG-1 / PEG-1 linolenal, PPG-1 / PEG-2 lauramine, PPG-1 / PEG-2 lauramine, PPG-1 / PEG-2 myristamine, PPG-1 / PEG-2 setamine, PPG-1 / PEG
-2 Stealamine, PPG-1 / PEG-2 Aracamine, PPG-1 / PEG-2 Behenamine, PPG-1 / PEG-2 Carnabamine, PPG-1 / PEG-2 Oleamine, PPG-1 / PEG-2 Elizamin, PPG -1 / PEG-2 linolamine, PPG-1 / PEG-2 linolenal, PPG-1 / PEG-3 lauramine, PPG-1 / PEG-3 lauramine, PPG-1 / PEG-3 myristamine, PPG-1 / PEG- 3 Setamine, PPG-1 / PEG-3 stearamine, PPG-1 / PEG-3 aracamine, PPG-1 / PEG-3 behenamine, PPG-1 / PEG-3 carnabamine, PPG-1 / PEG-3 oleamine, PPG- 1 / PEG-3 Elizamin, PPG-1 / PEG-3 Linolamine, PPG-1 / PEG-3 Linolenal, PPG-2 / PEG-1 Lauramine, PPG-2 / PEG-1 Myristamine, PPG-2 / PEG-1 Setamine, PPG-2 / PEG-1 stearamine, PPG-2 / PEG-1 aracamine, PPG-2 / PEG-1 behenamine, PPG-2 / PEG-1 carnabamine, PPG-2 / PEG-1 oleamine, PPG-2 / PEG-1 Elizamin, PPG-2 / PEG-1 Linolamine, PPG-2 / PEG-1 Linolenal, PPG-2 / PEG-2 Lauramine, PPG-2 / PEG-2 Myristamine, PPG-2 / PEG-2 Setamine , PPG-2 / PEG-2 stearamine, PPG-2 / PEG-2 aracamine, PPG-2 / PEG-2 behenamine, PPG-2 / PEG-2 carnabamine, PPG-2 / PEG-2 oleamine, PPG-2 / PEG-2 Elizamin, PPG-2 / PEG-2 Linolamine, PPG-2 / PEG-2 Linolenal, PPG-2 / PEG-3 Lauramine, PPG-2 / PEG-3 Myristamine, PPG-2 / PEG-3 Setamine, PPG-2 / PEG-3 stearamine, PPG-2 / PEG-3 aracamine, PPG-2 / PEG-3 behenamine, PPG-2 / PEG-3 carnabamine, PPG-2 / PEG-3 oleamine, PPG-2 / PEG -3 Elizamin, PPG-2 / PEG-3 linolamine, PPG-2 / PEG-3 linolenal, PPG-3 / PEG-1 lauramine, PPG-3 / PEG-1 myristamine, PPG-3 / PEG-1 setamine, PPG -3 / PEG-1 stearamine, PPG-3 / PEG-1 aracamine, PPG-3 / P EG-1 behenamine, PPG-3 / PEG-1 carnabamine, PPG-3 / PEG-1 oleamine, PPG-3 / PEG-1 elizamin, PPG-3 / PEG-1 linolamine, PPG-3 / PEG-1 linolenal, PPG-3 / PEG-2 lauramine, PPG-3 / PEG-2 myristamine, PPG-3 / PEG-2 setamine, PPG-3 / PEG-2 stearamine, PPG-3 / PEG-2 aracamine, PPG-3 / PEG -2 Behenamine, PPG-3 / PEG-2 Carnabamine, PPG-3 / PEG-2 Oleamine, PPG-3 / PEG-2 Elizamin, PPG-3 / PEG-2 Linolamine, PPG-3 / PEG-2 Linolenal, PPG -3 / PEG-3 lauramine, PPG-3 / PEG-3 myristamine, PPG-3 / PEG-3 setamine, PPG-3 / PEG-3 stearamine, PPG-3 / PEG-3 aracamine, PPG-3 / PEG- 3 Behenamine, PPG-3 / PEG-3 Carnabamine, PPG-3 / PEG-3 Oleamine, PPG-3 / PEG-3 Elizamin, PPG-3 / PEG-3 Linolamine, PPG-3 / PEG-3 Linolenal, PPG- 1 Lauramine, PPG-1 myristamine, PPG-1 setamine, PPG-1 stealamine, PPG-1 aracamine, PPG-1 behenamine, PPG-1 carnabamine, PPG-1 oleamine, PPG-1 elizamin, PPG-1 linolamine, PPG- 1 linolenal, PPG-2 lauramine, PPG-2 myristamine, PPG-2 setamine, PPG-2 stealamine, PPG-2 aracamine, PPG-2 behenamine, PPG-2 carnavamine, PPG-2 oleamine, PPG-2 elizamin, PPG- 2 Linolamine, PPG-2 Linolenal, PPG-3 Lauramine, PPG-3 Myristamine, PPG-3 Setamine, PPG-3 Stealamine, PPG-3 Aracamine, PPG-3 Behenamine, PPG-3 Carnabamine, PPG-3 Oleamine, PPG- 3 Elizamin, PPG-3 linolamine, PPG-3 linolenal, PEG-1 lauramine, PEG-1 myristamine, PEG-1 setamine, PEG-1 stealamine, PEG-1 aracamine, PEG-1 behenamine, PEG-1 carnavamine, PEG- 1 oleamine, PEG-1 elizamin, PEG-1 linolamine, PEG-1 linolenal, PEG-2 lauramine, PEG-2 myristamine, PEG- 2 Setamine, PEG-2 stealamine, PEG-2 aracamine, PEG-2 behenamine, PEG-2 carnabamine, PEG-2 oleamine, PEG-2 elizamin, PEG-2 linolamine, PEG-2 linolenal, PEG-3 lauramine, PEG- 3 myristamine, PEG-3 setamine, PEG-3 stearamine, PEG-3 aracamine, PEG-3 behenamine, PEG-3 carnabamine, PEG-3 oleamine, PEG-3 elizamin, PEG-3 linolamine, PEG-3 linolenal, lauramine, Examples thereof include myristamine, setamine, stealamine, aracamine, behenamine, carnabamine, oleamine, elizamin, linolamine, linolenal and the like. Among these, those with a ≠ 0 and b ≠ 0 are preferable, and in particular, R ¹ is a stearyl group having 18 carbon atoms, a = 1 and b = 1, PPG-1 / PEG-1 stearamine, and R ¹ . PPG-1 / PEG-1 behenamine, which has 22 carbon atoms and has a = 1 and b = 1, is particularly preferable.

In the present invention, one of these aliphatic amines can be used alone or in combination of two or more thereof, and the blending amount thereof is preferably 0.1 to 10% by mass (hereinafter, particularly described above). Other than those, the mass% is simply indicated by "%"), more preferably in the range of 0.5 to 5% by mass. If it is less than 0.1% by mass, the feel of the finished hair is deteriorated, and it is not possible to give a sufficient feeling of cohesiveness and softness, and if it exceeds 10.0% by mass, the feel of the hair at the time of rinsing or finishing is felt. It becomes stiff and hard.

The polyethylene glycol of the component (B) used in the present invention has a molecular weight of 90,000 or more. Commercially available products can be used for such polyethylene glycol, for example, PEG-90M (average molecular weight: 90000), PEG-115M (average molecular weight: 115000), PEG-160M (average molecular weight: 160000), PEG-180M (average). Molecular weight: 180,000) and the like. Further, among these polyethylene glycols, those having a molecular weight of 11,000 or more are more preferable, and PEG-160M (160000) is most preferable.

The polyethylene glycol can be used alone or in admixture of two or more, and the blending amount thereof is 0.002% by mass or more and 0.2% by mass or less with respect to the total amount of the composition of the present invention. (B) If the blending amount of the component is less than 0.002% by mass, the hair cosmetic will immediately drip from the hair after application (the hair cosmetic will not be well organized into the hair), and the hair cosmetic will not be cohesive. The effect cannot be sufficiently imparted to the hair, and if the blending amount of the component (B) exceeds 0.2% by mass, the spinnability increases and it becomes difficult to apply the component (B) evenly and evenly to the hair.

The component (C) nonionic cellulose derivative used in the present invention may be any as long as it is used in a usual skin cleaning agent composition, and specific examples of the preferable nonionic cellulose derivative are methyl cellulose, ethyl cellulose and hydroxyethyl cellulose. , Hydroxypropyl Cellulose, Hydroxypropyl Methyl Cellulose, etc. Among these, particularly preferable nonionic cellulose derivatives are methyl cellulose, hydroxyethyl cellulose, and hydroxypropyl methyl cellulose.

The nonionic cellulose derivative can be used alone or in admixture of two or more, and the blending amount thereof is 0.01 to 1.0% by mass with respect to the total amount of the composition of the present invention. If it is less than 0.01% by mass, the usability of the hair cosmetic is deteriorated, the elongation at the time of application cannot be obtained, it is difficult to apply evenly and uniformly, and if it exceeds 1.0% by mass, the finish after drying is achieved. It feels stiff.

Further, in the hair cosmetic of the present invention, in order to feel a rich feeling when applied to hair, not only the blending mass of the component (B) and the component (C) but also the blending amount of the component (B) is a component. It is important that the ratio (B) / (C) of the compounding mass of the component (B) and the component (C), which is how much (C) is compounded, is in an appropriate range. At this time, the ratio of the compounding mass of the component (B) and the component (C) (
The appropriate range of B) / (C) is 0.01 to 1.0, and if it is less than 0.01, the hair cosmetics will immediately drip from the hair after application (to the hair of the hair cosmetics). The effect of the hair cosmetic cannot be sufficiently imparted to the hair, and if it is larger than 1.0, the hair cosmetic of the present invention cannot be stretched at the time of application, and the hair cosmetic of the present invention can be applied to the entire hair. It becomes difficult to spread evenly.

The hair cosmetic of the present invention contains an aliphatic amine as represented by the general formula (I), polyethylene glycol having a molecular weight of a certain level or more, and a nonionic cellulose derivative as essential components, and these are appropriately added to water or water. It is prepared by containing it in a liquid containing a various solvents, etc., but for the purpose of other ingredients generally blended in hair cosmetics as long as the effects of the present invention are not impaired, in addition to these essential ingredients. Can be blended according to the above.

Such components include, for example, anionic surfactants such as lauryl sulfate, polyoxyethylene lauryllutel sulfate, laurylbenzene sulfonate, lauroylmethy-β-alanine sodium; 2-alkyl-N-carboxymethyl. Amphoteric surfactants such as -N-hydroxyethyl imidazolium betaine, coconut oil fatty acid amide propyl betaine, coconut oil alkyl N-carboxyethyl-N-hydroxyethyl imidazolinium betaine sodium: cationized cellulose, polyacrylic acid, steer Loxypropyl starch phosphate, poly (diallyldimethylammonium chloride) ;; wetting agents such as sorbitol, inositol, glycerin, propylene glycol, butylene glycol, dipropylene glycol, isoprene glycol; anti-fuke components such as zincpyrythion and benzalconium chloride; Lower alcohols such as ethanol, methanol, propyl alcohol, isopropyl alcohol; higher alcohols such as cetyl alcohol, stearyl alcohol, behenyl alcohol, etc. Amino acids such as acids, sodium L-aspartate, DL-alanine, L-arginine, glycine, L-glutamic acid, L-cysteine, L-threonine; other UV absorbers, preservatives, sugars, fragrances, coloring agents, metal ions Examples include sequestering agents, antioxidants, and various chemicals.

The hair cosmetic of the present invention can be used for hair rinses, hair conditioners, hair treatments, hair packs, hair lotions, hair liquids, hair creams, hair foams, perms, hair colors and the like. Further, the hair cosmetic of the present invention can be produced by a conventional method.

Next, the present invention will be described in detail with reference to examples, but the present invention is not limited thereto. Prior to the examples, the evaluation method adopted in each example will be described.

Examples 1 to 13 and Comparative Examples 1 to 14
The hair cosmetics having the compositions shown in Tables 1 and 2 were prepared according to a conventional method, and the hair cosmetics described in Examples 1 to 13 and Comparative Examples 1 to 14 were obtained. The obtained hair cosmetics were evaluated as follows, and the results are shown in Tables 1 and 2.

(1) Evaluation of usability at the time of application As the usability of the hair cosmetic at the time of application, "elongation of the hair cosmetic" at the time of application to wet hair after washing, "uniform hair without unevenness on the entire hair". "Adhesion of cosmetics" was evaluated. A panel of 20 people used the hair cosmetics of the examples and comparative examples, and judged the items of elongation at the time of application and uniform adhesion without unevenness in three stages of "good", "normal", and "bad". The judgment result was judged by the number of people who answered "good". The judgment criteria are as follows.
◎: Very good ・ ・ ・ The number of test subjects who answered “good” is 16 or more ○: Excellent ・ ・ ・ The number of test subjects who answered “good” is 11 to 15 △ : Slightly inferior ... The number of test subjects who answered "good" is 6 to 10 ×: Inferior ... The number of test subjects who answered "good" is 5 or less

(2) Evaluation of Adhesion State of Hair Cosmetics after Application It was evaluated whether the hair cosmetics "cling to the hair without dripping immediately" after application. A panel of 20 people used the hair cosmetics of the examples and comparative examples, and "good", "normal", "good", "normal", as to whether the hair cosmetics cling to the hair without dripping immediately after applying the hair cosmetics. Judgment was made in three stages of "bad", and the judgment result was judged by the number of people who answered "good". The judgment criteria are as follows.
◎: Very good ・ ・ ・ The number of test subjects who answered “good” is 16 or more ○: Excellent ・ ・ ・ The number of test subjects who answered “good” is 11 to 15 △ : Slightly inferior ... The number of test subjects who answered "good" is 6 to 10 ×: Inferior ... The number of test subjects who answered "good" is 5 or less

(3) Evaluation of feel during rinsing As the feel during rinsing, "finger passage during rinsing" and "softness of hair during rinsing" were evaluated. A panel of 20 people used the hair cosmetics of the examples and comparative examples, and judged the items of finger passage and softness during rinsing in three stages of "good", "normal", and "bad", and judged the judgment result. Judgment was made based on the number of people who answered "good". The judgment criteria are as follows. ◎: Very good ・ ・ ・ The number of test subjects who answered “good” is 16 or more ○: Excellent ・ ・ ・ The number of test subjects who answered “good” is 11 to 15 △ : Slightly inferior ... The number of test subjects who answered "good" is 6 to 10 ×: Inferior ... The number of test subjects who answered "good" is 5 or less

(4) Evaluation of finished feel As the finished feel after moisture drying, the finished "moist feeling", "cohesiveness", and "softness" were evaluated. A panel of 20 people used the hair cosmetics of the examples and comparative examples, and judged the items of moist feeling, cohesiveness, and softness of the finish in three stages of "good", "normal", and "bad", and the judgment result. Was judged by the number of people who answered "good". The judgment criteria are as follows.
◎: Very good ・ ・ ・ The number of test subjects who answered “good” is 16 or more ○: Excellent ・ ・ ・ The number of test subjects who answered “good” is 11 to 15 △ : Slightly inferior ... The number of test subjects who answered "good" is 6 to 10 ×: Inferior ... The number of test subjects who answered "good" is 5 or less

As is clear from Tables 1 and 2, the hair cosmetics of Examples 1 to 13 using the ingredients of the present invention all showed excellent performance as compared with the hair cosmetics of Comparative Examples 1 to 14.

Hereinafter, other prescription examples of the hair cosmetic of the present invention will be given as examples. The hair cosmetics of these examples also have excellent characteristics in terms of usability at the time of application, the state of hair cosmetic adhesion after application, the feel at the time of rinsing, and the evaluation of the finished feel. It was good.

Example 14 (Hair conditioner) Blending amount (% by mass)
(1) PPG-1 / PEG-1 stealamine 1.0
(2) Behenyltrimethylammonium chloride 1.0
(3) Setostearyl alcohol 6.5
(4) Dilinolate di (phytostearyl / isostearyl /
Cetyl / stearyl / behenyl) 1.0
(5) Behenyl alcohol 0.5
(6) Behenil PG Trimonium Chloride 1.0
(7) Stearyl PG Trimonium Chloride 1.0
(8) Diethylhexyl succinate 2.0
(9) Rice bran oil fatty acid phytosteryl 2.0
(10) Lactic acid 1.0
(11) Paraffin 1.0
(12) Propylene glycol 0.5
(13) Sorbitol 3.0
(14) Glycerin 0.5
(15) Hydroxypropyl cellulose 0.4
(16) PEG-180M 0.4
(17) Sunflower seed oil 0.1
(18) Ceramide 2 0.1
(19) Corn-derived sphingolipid 0.1
(20) Polyglutamic acid 0.1
(21) Sunflower seed extract 0.1
(22) Royal jelly extract 0.1
(23) Sunflower flower extract 0.1
(24) Rice bran extract 0.1
(25) Phenoxyethanol 0.2
(26) Salicylic acid 0.1
(27) Fragrance 0.5
(28) Residual of purified water

(Manufacturing method) A mixture of (1) to (11) uniformly mixed and dissolved at 80 ° C., and (12) to (16) and (28) dispersed at 80 ° C. is stirred with a propeller. In addition, emulsify. After gradual cooling, (17) to (27) were added at 60 ° C. and cooled to room temperature to prepare a hair conditioner.

Example 15 Hair Treatment Blending Amount (% by Mass) (1) PPG-1 / PEG-1 Stealamine 2.0
(2) Stearyltrimethylammonium chloride 1.0
(3) Setostearyl alcohol 7.5
(4) Behenyl alcohol 0.5
(5) Diglyceryl adipate mixed fatty acid ester 1.0
(6) Amodimethicone 2.0
(7) Methylpolysiloxane (300cs) 5.0
(8) Highly polymerized methylpolysiloxane (500,000 cs) 2.0
(9) Behenil PG Trimonium Chloride 1.0
(10) Stearyl PG Trimonium Chloride 1.0
(11) Rice bran oil fatty acid phytosteryl 3.0
(12) Lactic acid 1.0
(13) Paraffin 1.0
(14) White petrolatum 1.0
(15) 1,3-butylene glycol 3.0
(16) Cholesteryl hydroxystearate 0.5
(17) Cerebroside 0.1
(18) Ginger rhizome extract 0.5
(19) Saccharomyces / sunflower bud fermented extract 1.0
(20) LIPIDURE-C (manufactured by NOF CORPORATION) 1.0
(21) Propylene glycol 0.5
(22) Sorbitol 3.0
(23) Glycerin 0.5
(24) PEG-90M 0.1
(25) Methyl cellulose 1.0
(26) Sunflower seed oil 0.1
(27) Acetylglucosamine 0.1
(28) Sunflower seed oil fatty acid phytostearyl 0.1
(29) Phenoxyethanol 0.2
(30) Salicylic acid 0.1
(31) Preservative 0.1
(32) Fragrance 0.5
(33) Residual of purified water

(Production method) (1) to (16) and (24) to (26) are uniformly mixed and dissolved at 80 ° C. to prepare an oil phase. In (33), (21) to (23) and (27) are uniformly mixed and stirred at 60 ° C. to prepare an aqueous phase. After adding the oil phase to the aqueous phase and emulsifying, (28) and (29) are added and mixed uniformly using a homomixer. The hair treatment was prepared by gradually cooling while mixing, adding (17) to (20) and (30) to (32) at 40 ° C., and cooling to room temperature.

Example 16 Hair cream blending amount (mass%)
(1) PPG-1 / PEG-1 stealamine 0.5
(2) Behenyltrimethylammonium chloride 0.5
(3) Setostearyl alcohol 4.0
(4) Behenyl alcohol 0.5
(5) Vaseline 2.0
(6) Amodimethicone 1.0
(7) Aminopolyether silicon 0.5
(8) Behenil PG Trimonium Chloride 0.5
(9) Stearyl PG Trimonium Chloride 0.5
(10) Silicone aqueous emulsion (XS65-B7116, manufactured by GE Toshiba Silicon Co., Ltd.) 2.0
(11) Sunflower seed oil fatty acid phytosteryl 3.0
(12) Cholesteryl oleate 1.0
(13) 1,3-butylene glycol 2.0
(14) Diethyl sebacate 3.0
(15) PEG-115M 0.005
(16) Ethyl cellulose 0.01
(17) Sunflower leaf / stem extract 0.1
(18) Glycolic acid 0.2
(19) Phenoxyethanol 0.2
(20) Fragrance trace amount (21) Purified water residue

(Manufacturing method) (1) to (9) and (11) to (14) are uniformly mixed and dissolved at 80 ° C., and (15) to (17) and (19) to (21) are uniformly mixed and dissolved at 70 ° C. The mixture was added and emulsified, and (10) and (18) were added at 60 ° C. while mixing and dispersing with a homomixer, and the mixture was cooled to room temperature to prepare a hair cream.

Example 17 Hair pack compounding amount (mass%)
(1) PPG-1 / PEG-1 stealamine 2.0
(2) Behenyltrimethylammonium chloride 0.5
(3) Setostearyl alcohol 5.0
(4) Behenyl alcohol 1.0
(5) Lanolin 1.0
(6) Amodimethicone 1.0
(7) Aminopolyether silicon 0.5
(8) Behenil PG Trimonium Chloride 0.5
(9) Stearyl PG Trimonium Chloride 0.5
(10) Silicone aqueous emulsion
(XS65-B7116, manufactured by GE Toshiba Silicon Co., Ltd.) 5.0
(11) Sunflower bud extract 0.5
(12) PG 3.0
(13) Hydroxypropyl cellulose 0.05
(14) PEG-115M 0.02
(15) Diethyl sebacate 1.0
(16) Lactic acid 0.5
(17) Phenoxyethanol 0.2
(18) Fragrance 0.6
(19) Residual of purified water

(Manufacturing method) (1) to (9), (15) and (16) are uniformly mixed and dissolved at 80 ° C., and (12) to (14) and (19) are mixed at 50 ° C. and added. (10), (11), (17) and (18) were added at 50 ° C. and cooled to room temperature to prepare a hair pack.

Example 18 Treatment foam compounding amount (mass%)
(1) PPG-1 / PEG-1 stealamine 0.3
(2) Stearyltrimethylammonium chloride 1.0
(3) Setostearyl alcohol 1.0
(4) Behenyl alcohol 0.1
(5) Diglyceryl adipate mixed fatty acid ester 1.0
(6) Aminopolyether silicon 0.1
(7) Behenil PG Trimonium Chloride 0.2
(8) Methylpolysiloxane (300cs) 0.5
(9) Sunflower seed oil fatty acid phytosteryl 1.0
(10) Macadamia nut oil fatty acid cholesteryl 0.2
(11) Ceramide 1 / ceramide 5 mixture (1: 1) 0.1
(12) Lactic acid 0.2
(13) Polyoxyethylene (20) cetyl ether 1.0
(14) Polyoxyethylene (60) Hardened castor oil 0.5
(15) 1,3-butylene glycol 0.5
(16) PEG-90M 0.05
(17) Hydroxypropyl Methyl Cellulose 0.1
(18) Phenoxyethanol 0.5
(19) Residual of purified water

(Manufacturing method) (1) to (14) are uniformly mixed and dissolved at 80 ° C., and a mixture of (16), (17) and (19) heated to 80 ° C. is added while stirring with a propeller. To emulsify. The mixture was gradually cooled, (15) and (18) were added at 60 ° C., and the mixture was cooled to room temperature to prepare a stock solution. Next, the aerosol pressure-resistant container was filled with the undiluted solution: LPG gas at a ratio of 92: 8, and a treatment foam was prepared.

Claims (2)

A hair cosmetic containing the following components (A) to (C).
(A) 0.5 to 10.0% by mass of the aliphatic amine represented by the following general formula (I) with respect to the total mass of hair cosmetics.

(In the formula, R1 is a linear or branched saturated or unsaturated alkyl group having 12 to 24 carbon atoms, R2 is a hydroxyethyl group represented by C2H4O, and R3 is a hydroxypropyl group represented by C3H6O, m, n. Is an integer from 0 to 3)
(B) Polyethylene glycol having a molecular weight of 90,000 or more is 0.002 to 0.2% by mass based on the total mass of hair cosmetics.
(C) 0.01-1.0 % by mass of nonionic cellulose derivative with respect to the total mass of hair cosmetics
The hair cosmetic according to claim 1, wherein the mass ratio (B) / (C) of the component (B) to the component (C) is 0.01 to 2.0.