JP4727667B2 - 薄膜形成方法および半導体デバイスの製造方法 - Google Patents
薄膜形成方法および半導体デバイスの製造方法 Download PDFInfo
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- 239000010409 thin film Substances 0.000 title claims description 138
- 238000000034 method Methods 0.000 title claims description 89
- 238000004519 manufacturing process Methods 0.000 title claims description 12
- 239000004065 semiconductor Substances 0.000 title claims description 12
- 239000010408 film Substances 0.000 claims description 83
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 60
- 239000000758 substrate Substances 0.000 claims description 52
- 229910052799 carbon Inorganic materials 0.000 claims description 23
- 229910052739 hydrogen Inorganic materials 0.000 claims description 21
- 239000012535 impurity Substances 0.000 claims description 17
- 238000009832 plasma treatment Methods 0.000 claims description 14
- 230000003647 oxidation Effects 0.000 claims description 13
- 238000007254 oxidation reaction Methods 0.000 claims description 13
- 230000015572 biosynthetic process Effects 0.000 claims description 10
- 238000000151 deposition Methods 0.000 claims description 10
- 229910052757 nitrogen Inorganic materials 0.000 claims description 10
- 229910052719 titanium Inorganic materials 0.000 claims description 9
- 230000001590 oxidative effect Effects 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 238000005121 nitriding Methods 0.000 claims description 3
- 239000007789 gas Substances 0.000 description 104
- 230000008569 process Effects 0.000 description 48
- 238000012545 processing Methods 0.000 description 36
- 238000006243 chemical reaction Methods 0.000 description 26
- 239000013078 crystal Substances 0.000 description 18
- 235000012431 wafers Nutrition 0.000 description 18
- 239000010936 titanium Substances 0.000 description 11
- 238000011144 upstream manufacturing Methods 0.000 description 11
- 230000007246 mechanism Effects 0.000 description 10
- 230000008859 change Effects 0.000 description 9
- 239000002994 raw material Substances 0.000 description 9
- 239000011261 inert gas Substances 0.000 description 8
- 238000005229 chemical vapour deposition Methods 0.000 description 7
- 238000004381 surface treatment Methods 0.000 description 7
- 238000000231 atomic layer deposition Methods 0.000 description 6
- 230000004888 barrier function Effects 0.000 description 6
- 230000009467 reduction Effects 0.000 description 6
- 238000010926 purge Methods 0.000 description 5
- 239000010453 quartz Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 238000010301 surface-oxidation reaction Methods 0.000 description 5
- MNWRORMXBIWXCI-UHFFFAOYSA-N tetrakis(dimethylamido)titanium Chemical compound CN(C)[Ti](N(C)C)(N(C)C)N(C)C MNWRORMXBIWXCI-UHFFFAOYSA-N 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 4
- 238000000280 densification Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 230000007423 decrease Effects 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- VJDVOZLYDLHLSM-UHFFFAOYSA-N diethylazanide;titanium(4+) Chemical compound [Ti+4].CC[N-]CC.CC[N-]CC.CC[N-]CC.CC[N-]CC VJDVOZLYDLHLSM-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
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- 230000000694 effects Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
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- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
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Description
また、本発明の主な目的は、バリア性の高いTiN膜を形成する薄膜形成方法および半導体デバイスの製造方法を提供することにある。
Ti、N、C、Hを主成分として構成されるアモルファス薄膜を形成する工程と、
該薄膜の表面を酸化する工程と、
プラズマ処理により前記薄膜中の不純物であるCおよびHを除去し、および前記薄膜を緻密化する工程と、
前記薄膜表面のTiO薄膜を除去する工程と、を連続して実施することにより被処理基板上にTiN膜を堆積する薄膜形成方法が提供される。
Ti、N、C、Hを主成分として構成されるアモルファス薄膜を形成する工程と、
該薄膜の表面を酸化する工程と、
プラズマ処理により前記薄膜中の不純物であるCおよびHを除去し、および前記薄膜を緻密化する工程と、
前記薄膜表面のTiO薄膜を除去する工程と、を連続して実施することにより被処理基板上にTiN膜を堆積する工程を備える半導体デバイスの製造方法が提供される。
また、本発明によれば、バリア性の高い半導体デバイスの製造方法が提供される。
ガス供給管335にはバルブ355の下流側にバルブ356が設けられている。
尚、このバルブ351は、弁を開閉して処理室201の真空排気・真空排気停止ができ、更に弁開度を調節して圧力調整可能になっている開閉弁である。
また、ノズル361にはガスを供給する供給孔であるガス供給孔372が複数設けられている。複数のガス供給孔372は、ガス供給孔371の場合と同じ所定の長さにわたってウエハ200の積載方向に沿って配設されている。そして、複数のガス供給孔372と複数のガス供給孔371とをそれぞれ1対1で対応させて配置している。
本発明の好ましい態様は、次のような知見に基づいてなされたものである。膜密度の大きなアモルファスTiN膜を得るには膜を緻密化する必要がある。プラズマ処理により緻密化する際、アモルファスTiN膜が結晶化するおそれがある。アモルファスTiN膜の多結晶化を抑えるには、TiN膜の表面を酸化して化学的に安定なTiO系の酸化膜を形成すればよい。アモルファスTiN膜を容易に酸化させるようにするには、TiN膜にC、Hなどの不純物を混入すればよい。不要なC、Hは、TiN膜を緻密化する際、改質により除去すればよい。薄膜表面の不要なTiO膜を除去すれば、意図する膜密度の大きなTiN膜が得られる。
第1の工程:アモルファスTiNxCyHz(以下、単にTiNCHと称す)薄膜を形成する工程
第2の工程:アモルファスTiNCH薄膜を大気に曝して表面を自然酸化させる工程
第3の工程:プラズマ処理により膜中不純物(C、H)を除去し、および緻密化する工程
第4の工程:該薄膜表面のTiO薄膜を除去する工程
この工程においては、例えば上述した 図1、図2に示される装置を用いる。成膜原料はTDMAT(Tetrakis(Dimethylamino)Titanium:Ti(N(CH3)2)4)やTDEAT(Tetrakis(Diethylamino)Titanium:Ti(N(C2H5)2)4)、改質ガスはNH3、SiH4、H2、N2、Arなどである。本工程における、基板処理フローの一例を図3に示す。
真空ポンプ246により反応管203内の圧力を下げることで、基板表面に付着した不純物を離脱させる。
ノズル361を経由して減圧処理されている反応管203内に不活性ガスを定期的に導入して、基板表面に付着する不純物を、不活性ガス中に溶け込ませて除去する処理である。この処理は、基板を過熱しながら実施すると良い。
この処理は、減圧された反応管203に対してノズル361より表面処理ガスを導入しながら、高周波電源273により、棒状電極269と棒状電極270の間に放電を発生させてプラズマをバッファ室237内に発生させる処理である。この処理により、プラズマ処理された表面処理ガスがバッファ室237に設けられたガス供給孔371を経由して、基板表面上に照射される。本処理は、前記の(1)、(2)の処理を実施後、さらに基板表面に付着する不純物を除去するための処理であり、ボート回転機構267によりウエハ200を回転させながら実施すると良い。なお、プラズマ表面酸化処理時の表面処理ガスは主にO2であり、酸化剤としての作用を有する改質ガスである。これに対して、プラズマ表面還元処理時の表面処理ガスは主にH2であり、還元剤としての作用を有する改質ガスのことである。
ステップB3の改質ガス照射処理で使用する改質ガスは、ノンプラズマであって、H2あるいは、H2を含む改質ガスが良く、またNH3、N2、Arでも良い。
アモルファスTiNCH薄膜の膜厚が処理膜厚になったら、第1の工程の終了処理が行われる。終了処理は、降温処理と搬出処理とからなる。降温処理は、反応管203の温度を所定温度まで降温する処理である。搬出処理は、アモルファス薄膜を形成した被処理基板をボート217とともに処理炉202から搬出する処理である。
つぎに、プラズマ処理により前記薄膜中の不純物であるCおよびHを除去し、および前記薄膜を緻密化する工程と、前記薄膜表面のTiO薄膜を除去する工程とを実施する薄膜形成方法を含んでいる。アモルファス薄膜の表面が酸化されてTiO系の酸化膜で保護されているので、プラズマ処理による緻密化の際、アモルファス薄膜の多結晶化を抑えることができる。また、プラズマ処理により不純物であるCおよびHが除去される。また、不要なTiO薄膜が除去されるので、緻密化されたTiN薄膜が得られる。
そして、上記薄膜形成工程、酸化工程、不純物除去・緻密化工程、およびTiO薄膜除去工程を連続して実施することにより被処理基板上にTiN膜を堆積する薄膜形成方法を含んでいる。上記工程を連続して実施するので、薄膜を低温形成することで剥離しにくくカバレッジに優れ、またアモルファス薄膜の酸化で結晶粒界がなくあるいは結晶粒界が少なく、さらに薄膜の緻密化で経時変化の少ないTiN膜を形成することができる。
第1のガスと第2のガスとが被処理基板に交互に繰り返して供給されることにより、アモルファス薄膜をより低温で形成することができるので、より剥離しにくくカバレッジに優れるTiN膜を形成することができる。
Siを含む結晶化しにくいアモルファス薄膜が得られやすくなるので、より結晶粒界がなくあるいは結晶粒界が少ないTiN膜を形成することができる。
SiH4を含む結晶化しにくいアモルファス薄膜が得られやすくなるので、より結晶粒界がなくあるいは結晶粒界が少ないTiN膜を形成することができる。
薄膜の平均電気抵抗率は0.01〜1000Ωcmであると、結晶化しにくいアモルファス薄膜が得られやすくなるので、より結晶粒界がなくあるいは結晶粒界が少ないTiN膜を形成することができる。
被処理基板上に堆積されるTiN膜はアモルファスTiN膜であると、より結晶粒界がなくあるいは結晶粒界が少ないTiN膜を形成することができる。
アモルファス薄膜はTi、N、C、Hを主成分として構成されているので、大気雰囲気下において薄膜の表面を容易に自然酸化できるので、より結晶粒界がなくあるいは結晶粒界が少ないTiN膜を形成することができる。
プラズマにて励起されたHを含むガスが酸化された表面に供給されるので、より経時変化の少ないTiN膜を形成することができる。
薄膜の表面を窒化させる工程を更に設けたので、より経時変化の少ないTiN膜を形成することができる。
TiO薄膜がアモルファスTiO薄膜であると、TiO薄膜を酸系の水溶液により容易に除去できる。
薄膜を低温形成することで剥離しにくくカバレッジに優れ、またアモルファス薄膜の酸化で結晶粒界がなくあるいは結晶粒界が少なく、さらに薄膜の緻密化で経時変化の少ないTiN膜を形成することができ、したがってバリア性を向上できる。
201…処理室
202…処理炉
203…反応管
207…ヒータ
217…ボート
218…石英キャップ
219…シールキャップ
220…Oリング
224…プラズマ生成領域
231…ガス排気管
237…バッファ室
246…真空ポンプ
267…ボート回転機構
269…棒状電極
270…棒状電極
272…整合器
273…高周波電源
275…電極保護管
321…コントローラ
331〜337…ガス供給管
361、362…ノズル
341〜346…マスフローコントローラ
351〜356…バルブ
371〜373…ガス供給孔
380…アース
400…プラズマ処理装置
401…高周波電源
402…整合器
403…電極
404…電極
405…プラズマ
Claims (11)
- Ti、N、C、Hを主成分として構成されるアモルファス薄膜を形成する工程と、
該薄膜の表面を酸化する工程と、
プラズマ処理により前記薄膜中の不純物であるCおよびHを除去し、および前記薄膜を緻密化する工程と、
前記薄膜表面のTiO薄膜を除去する工程と、
を連続して実施することにより被処理基板上にTiN膜を堆積する薄膜形成方法。 - 前記アモルファス薄膜を形成する工程では、Tiを含む第1のガスと改質ガスを含む第2のガスとが被処理基板に対し交互に所定回数繰り返して供給される請求項1に記載の薄膜形成方法。
- 前記第2のガスはSiを含むガスである請求項2に記載の薄膜形成方法。
- 前記Siを含むガスはSiH4である請求項3に記載の薄膜形成方法。
- 前記アモルファス薄膜を形成する工程で形成された薄膜の平均電気抵抗率は0.01〜1000Ωcmである請求項1に記載の薄膜形成方法。
- 前記被処理基板上に堆積されるTiN膜はアモルファスTiN膜である請求項1に記載の薄膜形成方法。
- 前記酸化工程では、前記薄膜の表面を大気雰囲気下において自然酸化する請求項1に記載の薄膜形成方法。
- 前記薄膜中の不純物であるCおよびHを除去し、および前記薄膜を緻密化する工程では、前記プラズマにて励起されたHを含むガスが前記酸化された表面に供給される請求項1に記載の薄膜形成方法。
- 前記緻密化する工程の後に、前記薄膜の表面を窒化させる工程を更に設けた請求項8に記載の薄膜形成方法。
- 前記TiO薄膜を除去する工程では、前記TiO薄膜が酸系の水溶液により除去される請求項1に記載の薄膜形成方法。
- Ti、N、C、Hを主成分として構成されるアモルファス薄膜を形成する工程と、
該薄膜の表面を酸化する工程と、
プラズマ処理により前記薄膜中の不純物であるCおよびHを除去し、および前記薄膜を緻密化する工程と、
前記薄膜表面のTiO薄膜を除去する工程と、
を連続して実施することにより被処理基坂上にTiN膜を堆積する工程を備える半導体デバイスの製造方法。
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JPH05109656A (ja) * | 1990-06-29 | 1993-04-30 | Samsung Electron Co Ltd | 非晶質窒化チタン膜を用いた金属配線形成方法 |
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US5641558A (en) * | 1992-05-27 | 1997-06-24 | Asahi Glass Company Ltd. | Window glass for an automobile |
US6596643B2 (en) * | 2001-05-07 | 2003-07-22 | Applied Materials, Inc. | CVD TiSiN barrier for copper integration |
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2006
- 2006-08-10 US US11/920,720 patent/US20090130331A1/en not_active Abandoned
- 2006-08-10 WO PCT/JP2006/315846 patent/WO2007020874A1/ja active Application Filing
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JPH05109656A (ja) * | 1990-06-29 | 1993-04-30 | Samsung Electron Co Ltd | 非晶質窒化チタン膜を用いた金属配線形成方法 |
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US20090130331A1 (en) | 2009-05-21 |
JPWO2007020874A1 (ja) | 2009-02-26 |
WO2007020874A1 (ja) | 2007-02-22 |
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