JP2007238457A - Cleansing agent in which cleansing agent composition is packed in pump vessel - Google Patents
Cleansing agent in which cleansing agent composition is packed in pump vessel Download PDFInfo
- Publication number
- JP2007238457A JP2007238457A JP2006058807A JP2006058807A JP2007238457A JP 2007238457 A JP2007238457 A JP 2007238457A JP 2006058807 A JP2006058807 A JP 2006058807A JP 2006058807 A JP2006058807 A JP 2006058807A JP 2007238457 A JP2007238457 A JP 2007238457A
- Authority
- JP
- Japan
- Prior art keywords
- fatty acid
- cleaning
- cleansing agent
- composition
- cleaning composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000000203 mixture Substances 0.000 title claims abstract description 79
- 239000003599 detergent Substances 0.000 title abstract description 22
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 50
- 239000000194 fatty acid Substances 0.000 claims abstract description 50
- 229930195729 fatty acid Natural products 0.000 claims abstract description 50
- -1 polyoxyethylene Polymers 0.000 claims abstract description 42
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 40
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 claims abstract description 33
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 21
- 150000003839 salts Chemical class 0.000 claims abstract description 17
- 239000004359 castor oil Substances 0.000 claims abstract description 15
- 235000019438 castor oil Nutrition 0.000 claims abstract description 15
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 15
- ODHCTXKNWHHXJC-VKHMYHEASA-N 5-oxo-L-proline Chemical compound OC(=O)[C@@H]1CCC(=O)N1 ODHCTXKNWHHXJC-VKHMYHEASA-N 0.000 claims abstract description 9
- 238000007599 discharging Methods 0.000 claims abstract description 5
- 229940043131 pyroglutamate Drugs 0.000 claims abstract description 4
- 238000004140 cleaning Methods 0.000 claims description 67
- 239000011538 cleaning material Substances 0.000 claims description 29
- 239000006260 foam Substances 0.000 claims description 11
- 229910052783 alkali metal Inorganic materials 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 7
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 3
- 159000000000 sodium salts Chemical class 0.000 claims description 3
- 239000000344 soap Substances 0.000 abstract description 12
- 238000007711 solidification Methods 0.000 abstract description 4
- 230000008023 solidification Effects 0.000 abstract description 4
- 230000005764 inhibitory process Effects 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 16
- 230000000694 effects Effects 0.000 description 9
- 239000012459 cleaning agent Substances 0.000 description 8
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 7
- 239000006096 absorbing agent Substances 0.000 description 7
- 229920001296 polysiloxane Polymers 0.000 description 7
- 238000003860 storage Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- ODHCTXKNWHHXJC-GSVOUGTGSA-N Pyroglutamic acid Natural products OC(=O)[C@H]1CCC(=O)N1 ODHCTXKNWHHXJC-GSVOUGTGSA-N 0.000 description 5
- ODHCTXKNWHHXJC-UHFFFAOYSA-N acide pyroglutamique Natural products OC(=O)C1CCC(=O)N1 ODHCTXKNWHHXJC-UHFFFAOYSA-N 0.000 description 5
- 239000002537 cosmetic Substances 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 239000004166 Lanolin Substances 0.000 description 4
- 239000005639 Lauric acid Substances 0.000 description 4
- 230000001771 impaired effect Effects 0.000 description 4
- 229940039717 lanolin Drugs 0.000 description 4
- 235000019388 lanolin Nutrition 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 3
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-Hydroxyoctadecanoic acid Natural products CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 description 3
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 235000021360 Myristic acid Nutrition 0.000 description 3
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002280 amphoteric surfactant Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 229960003237 betaine Drugs 0.000 description 3
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 2
- GHOKWGTUZJEAQD-ZETCQYMHSA-N (D)-(+)-Pantothenic acid Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-ZETCQYMHSA-N 0.000 description 2
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004386 Erythritol Substances 0.000 description 2
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 229920001214 Polysorbate 60 Polymers 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 150000004347 all-trans-retinol derivatives Chemical class 0.000 description 2
- RWZYAGGXGHYGMB-UHFFFAOYSA-N anthranilic acid Chemical compound NC1=CC=CC=C1C(O)=O RWZYAGGXGHYGMB-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 2
- 235000019414 erythritol Nutrition 0.000 description 2
- 229940009714 erythritol Drugs 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 229940119170 jojoba wax Drugs 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- XOJVVFBFDXDTEG-UHFFFAOYSA-N pristane Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 2
- ZUFQODAHGAHPFQ-UHFFFAOYSA-N pyridoxine hydrochloride Chemical compound Cl.CC1=NC=C(CO)C(CO)=C1O ZUFQODAHGAHPFQ-UHFFFAOYSA-N 0.000 description 2
- MMXZSJMASHPLLR-UHFFFAOYSA-N pyrroloquinoline quinone Chemical compound C12=C(C(O)=O)C=C(C(O)=O)N=C2C(=O)C(=O)C2=C1NC(C(=O)O)=C2 MMXZSJMASHPLLR-UHFFFAOYSA-N 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
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- 239000000600 sorbitol Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
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- 150000005846 sugar alcohols Polymers 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 2
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- 235000013343 vitamin Nutrition 0.000 description 2
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- 239000001993 wax Substances 0.000 description 2
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- YBJHBAHKTGYVGT-ZKWXMUAHSA-N (+)-Biotin Chemical compound N1C(=O)N[C@@H]2[C@H](CCCCC(=O)O)SC[C@@H]21 YBJHBAHKTGYVGT-ZKWXMUAHSA-N 0.000 description 1
- CUNWUEBNSZSNRX-RKGWDQTMSA-N (2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol;(z)-octadec-9-enoic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O CUNWUEBNSZSNRX-RKGWDQTMSA-N 0.000 description 1
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- NCLNAHJFXIKYBY-UHFFFAOYSA-N 2-hexyldecyl 16-methylheptadecanoate Chemical compound CCCCCCCCC(CCCCCC)COC(=O)CCCCCCCCCCCCCCC(C)C NCLNAHJFXIKYBY-UHFFFAOYSA-N 0.000 description 1
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- 235000021357 Behenic acid Nutrition 0.000 description 1
- 235000014698 Brassica juncea var multisecta Nutrition 0.000 description 1
- 235000006008 Brassica napus var napus Nutrition 0.000 description 1
- 235000006618 Brassica rapa subsp oleifera Nutrition 0.000 description 1
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- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 229940045920 sodium pyrrolidone carboxylate Drugs 0.000 description 1
- HYRLWUFWDYFEES-UHFFFAOYSA-M sodium;2-oxopyrrolidine-1-carboxylate Chemical compound [Na+].[O-]C(=O)N1CCCC1=O HYRLWUFWDYFEES-UHFFFAOYSA-M 0.000 description 1
- 239000013042 solid detergent Substances 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 229960005078 sorbitan sesquioleate Drugs 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229960003080 taurine Drugs 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 229960000984 tocofersolan Drugs 0.000 description 1
- AOBORMOPSGHCAX-DGHZZKTQSA-N tocofersolan Chemical compound OCCOC(=O)CCC(=O)OC1=C(C)C(C)=C2O[C@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C AOBORMOPSGHCAX-DGHZZKTQSA-N 0.000 description 1
- 229940042585 tocopherol acetate Drugs 0.000 description 1
- 229940118594 trimethylolpropane triisostearate Drugs 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 235000019163 vitamin B12 Nutrition 0.000 description 1
- 239000011715 vitamin B12 Substances 0.000 description 1
- 235000019164 vitamin B2 Nutrition 0.000 description 1
- 239000011716 vitamin B2 Substances 0.000 description 1
- 235000019158 vitamin B6 Nutrition 0.000 description 1
- 239000011726 vitamin B6 Substances 0.000 description 1
- 235000011912 vitamin B7 Nutrition 0.000 description 1
- 239000011735 vitamin B7 Substances 0.000 description 1
- 235000019166 vitamin D Nutrition 0.000 description 1
- 239000011710 vitamin D Substances 0.000 description 1
- 150000003710 vitamin D derivatives Chemical class 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- 229940011671 vitamin b6 Drugs 0.000 description 1
- 229940046008 vitamin d Drugs 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 235000004835 α-tocopherol Nutrition 0.000 description 1
- 239000002076 α-tocopherol Substances 0.000 description 1
- 235000007680 β-tocopherol Nutrition 0.000 description 1
- 239000011590 β-tocopherol Substances 0.000 description 1
- 239000002478 γ-tocopherol Substances 0.000 description 1
- QUEDXNHFTDJVIY-DQCZWYHMSA-N γ-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-DQCZWYHMSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、化粧料に関し、更に詳細には、洗浄料組成物をポンプ容器に充填してなる洗浄料に好適な化粧料に関する。 The present invention relates to a cosmetic material, and more particularly to a cosmetic material suitable for a cleaning material obtained by filling a cleaning agent composition into a pump container.
人体に於いて、付着した異物を洗浄によって除去することは重要なことであり、前記異物が病原微生物であった場合には、洗浄行為は重要な感染予防処置となるし、スギ花粉のようなアレルゲンであった場合には、アレルギー反応の惹起の重要な予防処置となり、何れの場合においても洗浄行為は疾病から人体を守る有用な手段であると言える。この様な洗浄行為を担う洗浄用の化粧料（洗浄料）としては、脂肪酸ナトリウム石鹸やアシルグルタミン酸ナトリウムを固化した固形洗浄料、脂肪酸石鹸の水溶液、アルキル硫酸塩の水溶液、両性界面活性剤の水溶液などを主洗浄成分とした液体洗浄料、脂肪酸カリウム石鹸を水や多価アルコールとともにクリーム状に製剤化したクリーム状洗浄料などが存する。洗浄料の洗浄成分の界面活性剤は皮膚残存すると刺激を発現する場合が存することから、この様な洗浄料においては、洗浄成分が皮膚に残存しないような使用態様が望まれている。この意味に於いて、固形石鹸やクリーム状の洗浄料を使用する場合にも、泡立てネットなどの小道具などを利用して、泡立ててこの泡を用いて洗浄するのが常道となっている。この様な状況から、洗浄剤の製剤としては、液状洗浄料が最も洗浄後に、皮膚に洗浄料が残りにくく好ましい。しかしながら、液体洗浄料には、洗浄料組成物の取り出しが困難であるという欠点が存するため、これを補完する方法としてポンプ容器に充填し、使用量が簡便に吐出されるような形態での使用が主流になってきているが、この様な形態においては、洗浄料組成物の口部への固化と、それによるポンプ機能の障害という新たな問題が生じている（例えば、特許文献１を参照）。この問題は、口部に網目を配し、この網目により空気と洗浄料組成物を混合し、泡沫を形成させながら吐出する、「ポンプフォーマー容器」を用いた場合には特に重大であり、泡沫形成のための口部の網目構造に洗浄料組成物の固化物が詰まると、フォーマー機能が全く損なわれてしまう。この為、脂肪酸石鹸は洗浄性に優れるにもかかわらず、口部の固化物が発生しやすい欠点を有しているが故にポンプフォーマー用の洗浄料組成物への配合はされにくい状況にあった。 In the human body, it is important to remove adhering foreign substances by washing. When the foreign substances are pathogenic microorganisms, the washing action is an important infection prevention measure, such as cedar pollen. When it is an allergen, it is an important preventive measure for inducing an allergic reaction. In any case, it can be said that the cleaning action is a useful means for protecting the human body from diseases. The cleaning cosmetics (cleaning agents) responsible for such a cleaning action include solid detergents obtained by solidifying fatty acid sodium soap and sodium acylglutamate, fatty acid soap aqueous solutions, alkyl sulfate aqueous solutions, and amphoteric surfactant aqueous solutions. There are liquid detergents with the main washing ingredients, and cream detergents in which fatty acid potassium soap is formulated in a cream form with water and polyhydric alcohol. Since the surfactant of the cleaning component of the cleaning agent may cause irritation when it remains on the skin, such a cleaning agent is desired to be used such that the cleaning component does not remain on the skin. In this sense, even when using a soap or creamy detergent, it is usual to use a foaming tool such as a foaming net and wash using the foam. From such a situation, as the preparation of the cleaning agent, the liquid cleaning agent is preferable because the cleaning agent hardly remains on the skin after the cleaning. However, the liquid cleaning material has a drawback that it is difficult to take out the cleaning composition. Therefore, as a method for complementing this, the liquid container is filled in a pump container and used in a form that can be easily discharged. However, in such a form, there is a new problem that the cleaning composition is solidified in the mouth portion and the pump function is thereby impaired (see, for example, Patent Document 1). ). This problem is particularly serious when using a “pump former container” in which a mesh is arranged in the mouth, air and a cleaning composition are mixed through this mesh, and discharged while forming foam. When the solidified product of the cleaning composition is clogged in the network structure of the mouth for foam formation, the former function is completely impaired. For this reason, although fatty acid soap has excellent detergency, it has a defect that solidified products are easily generated in the mouth, so that it is difficult to mix into a detergent composition for pump formers. It was.
一方、イソステアリン酸を洗浄料以外の化粧料に含有させる技術は既に知られているが（例えば、特許文献２を参照）、イソステアリン酸等の分岐脂肪酸及び／又はその塩を洗浄料に含有させる技術は全く知られておらず、イソステアリン酸等の分岐脂肪酸及び／又はその塩を配合することにより口部の洗浄料組成物の固化が抑制できることも全く知られていなかった。 On the other hand, although the technique for containing isostearic acid in cosmetics other than the detergent is already known (see, for example, Patent Document 2), the technique for incorporating a branched fatty acid such as isostearic acid and / or a salt thereof into the detergent. Is not known at all, and it has not been known at all that solidification of the mouthwash composition can be suppressed by blending a branched fatty acid such as isostearic acid and / or a salt thereof.
又、ピログルタミン酸イソステアリン酸ポリオキシエチレン硬化ヒマシ油を毛髪化粧料や油性クレンジング料に含有させる技術は知られているが（例えば、特許文献３、特許文献４、特許文献５を参照）洗浄料に含有させることは全く知られていないし、かかる成分を洗浄料に含有させることにより、前記イソステアリン酸等の分岐脂肪酸及び／又はその塩の口部の洗浄料組成物の固化抑制作用を更に高めることができることも全く知られていない。 In addition, techniques for incorporating pyroglutamic acid isostearic acid polyoxyethylene hydrogenated castor oil in hair cosmetics and oil-based cleansing materials are known (see, for example, Patent Document 3, Patent Document 4, and Patent Document 5). It is not known at all to contain it, and by adding such a component to the cleaning agent, it is possible to further enhance the solidification inhibiting action of the cleaning composition of the branched fatty acid such as isostearic acid and / or its salt. There is no known thing that can be done.
本発明は、この様な状況下為されたものであり、脂肪酸石鹸を洗浄料成分として含有する、洗浄料組成物をポンプで吐出する洗浄料に於いて、前記洗浄料組成物が口部に固化し、吐出性を阻害するのを防ぐ手段を提供すること課題とする。 The present invention has been made under such circumstances, and includes a fatty acid soap as a cleaning ingredient, and a cleaning composition in which the cleaning composition is discharged by a pump. It is an object of the present invention to provide means for solidifying and preventing dischargeability from being hindered.
この様な状況に鑑みて、本発明者らは、脂肪酸石鹸を洗浄料成分として含有する、洗浄料組成物をポンプで吐出する洗浄料に於いて、前記洗浄料組成物が口部に固化し、吐出性を阻害するのを防ぐ手段を求めて、鋭意研究努力を重ねた結果、イソステアリン酸などの分岐脂肪酸及び／又はその塩を含有させることにより、この様な口部の固化を防げることを見いだし、発明を完成させるに至った。即ち、本発明は、以下に示すとおりである。
（１）ポンプ容器に洗浄料組成物を充填してなる洗浄料であって、使用時にポンプより洗浄料組成物を吐出させて使用する態様であり、且つ、前記洗浄料組成物に分岐脂肪酸及び／又はその塩を含有することを特徴とする、皮膚洗浄料。
（２）前記分岐脂肪酸は、イソステアリン酸である、（１）に記載の皮膚洗浄料。
（３）更に、洗浄料組成物にピログルタミン酸イソステアリン酸ポリオキシエチレン硬化ヒマシ油を含有することを特徴とする、（１）又は（２）に記載の皮膚洗浄料。
（４）洗浄成分として、脂肪酸のアルカリ金属塩を８〜１６質量％含有することを特徴とする、（１）〜（３）何れか１項に記載の皮膚洗浄料。
（５）前記脂肪酸のアルカリ金属塩として、カリウム塩とナトリウム塩とを１５：１〜５：１の当量比で含有することを特徴とする、（４）に記載の皮膚洗浄料。
（６）洗浄料組成物の吐出の形態が泡沫であることを特徴とする，（１）〜（５）何れか１項に記載の皮膚洗浄料。
In view of such a situation, the present inventors have included a fatty acid soap as a cleaning ingredient, and in the cleaning composition in which the cleaning composition is discharged by a pump, the cleaning composition is solidified in the mouth. As a result of intensive research efforts to find a means to prevent the dischargeability from being hindered, the inclusion of a branched fatty acid such as isostearic acid and / or a salt thereof can prevent such solidification of the mouth. It has been found and the invention has been completed. That is, the present invention is as follows.
(1) A cleaning composition comprising a pump container filled with a cleaning composition, wherein the cleaning composition is used by discharging the cleaning composition from a pump at the time of use, and a branched fatty acid is added to the cleaning composition. A skin cleanser characterized by containing a salt thereof.
(2) The skin cleanser according to (1), wherein the branched fatty acid is isostearic acid.
(3) The skin cleanser according to (1) or (2), further comprising polyoxyethylene hydrogenated castor oil pyroglutamate isostearate in the cleanser composition.
(4) The skin cleansing material according to any one of (1) to (3), wherein the cleaning component contains an alkali metal salt of a fatty acid in an amount of 8 to 16% by mass.
(5) The skin cleansing material according to (4), wherein the alkali metal salt of the fatty acid contains a potassium salt and a sodium salt in an equivalent ratio of 15: 1 to 5: 1.
(6) The skin cleanser according to any one of (1) to (5), wherein the discharge form of the cleanser composition is foam.
本発明によれば、脂肪酸石鹸を洗浄料成分として含有する、洗浄料組成物をポンプで吐出する洗浄料に於いて、前記洗浄料組成物が口部に固化し、吐出性を阻害するのを防ぐ手段を提供することができる。 According to the present invention, in the detergent containing a fatty acid soap as a detergent component and discharging the detergent composition with a pump, the detergent composition solidifies in the mouth and inhibits ejection properties. Means to prevent can be provided.
（１）本発明の洗浄料の必須成分である分岐脂肪酸
本発明の洗浄料は、ポンプ容器に洗浄料組成物を充填してなる洗浄料であって、使用時にポンプより洗浄料組成物を吐出させて使用する態様であり、且つ、前記洗浄料組成物に分岐脂肪酸及び／又はその塩を含有することを特徴とする。前記分岐脂肪酸としては、炭素数１２〜２６のものが好ましく、より好ましくは、炭素数１４〜２２がより好ましい。具体例を例示すれば、例えば、イソパルミチン酸、イソステアリン酸、オクチルドデカン酸等が好ましく例示できる。かかる成分の塩としては、洗浄料組成物で使用されるものであれば、特段の限定無く使用でき、例えば、ナトリウム塩、カリウム塩等のアルカリ金属塩、カルシウム塩、マグネシウム塩等のアルカリ土類金属塩、アンモニウム塩、トリエチルアミン塩、トリエタノールアミン塩、モノエタノールアミン塩等の有機アミン塩、リジン塩、アルギン酸塩等の塩基性アミノ酸塩等が好適に例示できる。本発明の洗浄料の洗浄料組成物において、かかる成分は唯一種を含有することもできるし、二種以上を組み合わせて含有することもできる。かかる成分は、本発明の洗浄料の洗浄料組成物において、吐出し、吐出口に付着し、使用後に残存した洗浄料組成物中の水分が揮散し固化し、口部の吐出口を閉塞するのを抑制する作用を有する。この様な作用を奏するためには、前記分岐脂肪酸及びその塩を、分岐脂肪酸に換算して、総量で洗浄料組成物全量に対して、下限値として、０．１質量％、より好ましくは０．２質量％、上限値として５質量％、より好ましくは１質量％含有することが好ましい。又、かかる分岐脂肪酸含有量に換算した、分岐脂肪酸及びその塩の含有量は、分岐脂肪酸に分類されない脂肪酸及びその塩の含有量を脂肪酸の含有量に換算した値に対して、１〜１０質量％であることが好ましい。これは、絶対的総量と脂肪酸総量に対する相対的総量において、少なすぎると口部に閉塞が起こり、吐出が阻害される場合が存し、多すぎても効果は頭打ちになり、製剤安定性を損なったり、泡沫形成性を損なう場合が存するためである。
(1) Branched fatty acid which is an essential component of the cleaning material of the present invention The cleaning material of the present invention is a cleaning material obtained by filling a pump container with a cleaning material composition, and the cleaning material composition is discharged from the pump during use. In addition, the cleaning composition contains a branched fatty acid and / or a salt thereof. The branched fatty acid preferably has 12 to 26 carbon atoms, more preferably 14 to 22 carbon atoms. For example, isopalmitic acid, isostearic acid, octyldodecanoic acid and the like can be preferably exemplified. As the salt of such a component, any salt used in the cleaning composition can be used without any particular limitation. For example, alkali metal salts such as sodium salt and potassium salt, alkaline earth such as calcium salt and magnesium salt Preferred examples include organic amine salts such as metal salts, ammonium salts, triethylamine salts, triethanolamine salts and monoethanolamine salts, and basic amino acid salts such as lysine salts and alginates. In the cleaning composition of the cleaning composition of the present invention, such a component may contain only one species, or may contain two or more species in combination. Such a component is discharged in the cleaning composition of the cleaning composition of the present invention, adheres to the discharge port, volatilizes and solidifies the moisture in the cleaning composition remaining after use, and closes the discharge port of the mouth. It has the effect | action which suppresses this. In order to exhibit such an effect, the branched fatty acid and its salt are converted into branched fatty acid, and the total amount is 0.1% by mass, more preferably 0, as the lower limit with respect to the total amount of the cleaning composition. It is preferable to contain 2 mass%, 5 mass% as an upper limit, and more preferably 1 mass%. Moreover, the content of the branched fatty acid and the salt thereof converted to the content of the branched fatty acid is 1 to 10 mass with respect to the value obtained by converting the content of the fatty acid not classified into the branched fatty acid and the salt thereof into the content of the fatty acid. % Is preferred. This is because the absolute total amount and the relative total amount with respect to the total fatty acid amount are too small, the mouth may become clogged and the ejection may be hindered. This is because there are cases where the foam-forming property is impaired.
（２）本発明の洗浄料の好ましい成分であるピログルタミン酸イソステアリン酸ポリオキシエチレン硬化ヒマシ油
本発明の洗浄料は、ポンプ容器に洗浄料組成物を充填してなる洗浄料であって、使用時にポンプより洗浄料組成物を吐出させて使用する態様であり、且つ、好ましい態様に於いて、ピログルタミン酸イソステアリン酸ポリオキシエチレン硬化ヒマシ油を含有する。前記ピログルタミン酸イソステアリン酸ポリオキシエチレン硬化ヒマシ油は既に化粧料用の原料として市販されており、本発明の洗浄料の洗浄料組成物においては、この様な市販品を購入して使用することができる。この様な市販品としては、例えば、日本エマルション株式会社製の「ピロテルＣＰＩ−４０」が好ましく例示できる。かかる成分は、本発明の洗浄料の洗浄料組成物において、前記分岐脂肪酸及び／又はその塩の吐出口閉塞抑制効果を更に高める作用を有する。即ち、一旦使用し、その後長時間不使用の後、再び使用した場合、前記ピログルタミン酸イソステアリン酸ポリオキシエチレン硬化ヒマシ油を含有している場合には、含有していない場合に比して有意に容易に吐出させることができる。即ち、前記分岐脂肪酸及び／又はその塩の効果を高めることができる。この様な効果を奏するためには、前記ピログルタミン酸イソステアリン酸ポリオキシエチレン硬化ヒマシ油は、洗浄料組成物全量に対して、下限値で、０．０１質量％含有することが好ましく、より好ましくは０．０５質量％含有することが好ましく、上限値で、５質量％が好ましく、１質量％がより好ましい。
(2) Pyroglutamic acid isostearic acid polyoxyethylene hydrogenated castor oil which is a preferred component of the cleaning material of the present invention The cleaning material of the present invention is a cleaning material obtained by filling a pump container with a cleaning material composition. It is an embodiment in which the cleaning composition is discharged from a pump and used, and in a preferred embodiment, it contains pyroglutamate isostearate polyoxyethylene hydrogenated castor oil. The pyroglutamic acid isostearate polyoxyethylene hydrogenated castor oil is already commercially available as a raw material for cosmetics, and in the cleaning composition of the cleaning material of the present invention, such a commercial product can be purchased and used. it can. As such a commercially available product, for example, “Pyrotel CPI-40” manufactured by Nippon Emulsion Co., Ltd. can be preferably exemplified. Such a component has an action of further enhancing the effect of suppressing the blockage of the branched fatty acid and / or salt thereof in the cleaning composition of the cleaning composition of the present invention. That is, when used once, then not used for a long time, and then used again, when the pyroglutamic acid isostearic acid polyoxyethylene hydrogenated castor oil is contained, it is significantly compared with the case where it is not contained. It can be easily discharged. That is, the effect of the branched fatty acid and / or salt thereof can be enhanced. In order to achieve such an effect, the pyroglutamic acid isostearic acid polyoxyethylene hydrogenated castor oil is preferably contained at a lower limit of 0.01% by mass, more preferably, based on the total amount of the cleaning composition. It is preferable to contain 0.05 mass%, and 5 mass% is preferable at an upper limit, and 1 mass% is more preferable.
（３）本発明の洗浄料の洗浄料組成物
本発明の洗浄料の洗浄料組成物は、前記必須成分及び好ましい形態に於いて、前記好ましい成分を含有することを特徴とする。本発明の洗浄料組成物は、ポンプ機構によって吐出されることを条件としており、この様な条件からその粘度はＢ型粘度計４号ローター（６０ｒｐｍ）を用いた測定に於いて、粘度が１０００ｍＰａ・ｓ以下であることが好ましい。これ以上の粘度であると吐出しにくいことが存するためである。
(3) The cleaning composition of the cleaning composition of the present invention The cleaning composition of the cleaning composition of the present invention is characterized by containing the preferable component in the essential component and the preferable form. The cleaning composition of the present invention is provided under the condition that it is discharged by a pump mechanism. From such conditions, the viscosity is 1000 mPa in the measurement using a B-type viscometer No. 4 rotor (60 rpm). -It is preferable that it is below s. This is because it is difficult to discharge when the viscosity is higher than this.
本発明の洗浄料においては、脂肪酸のアルカリ金属塩を洗浄成分として含有することが好ましい。これは、脂肪酸のアルカリ金属石鹸に洗浄性が優れるが、口部に吐出残物の固化物を生じやすい特性が存し、本発明の効果が該口部の吐出残物の固化物による、口部閉塞を抑制することであるため、ポンプアップ容器形態の洗浄料に於いて、脂肪酸アルカリ金属石鹸の洗浄効果を最大に利用できるためである。前記脂肪酸のアルカリ金属石鹸を構成する脂肪酸としては、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘン酸、オレイン酸、リノール酸、リノレイン酸、ヒドロキシステアリン酸などが好ましく例示でき、アルカリ金属としては、ナトリウム或いはカリウムが特に好ましく例示できる。勿論、動植物油を水酸化カリウムや水酸化ナトリウムで鹸化して、該鹸化物を配合する形態で含有させることもできる。特に好ましい形態としては、ヒドロキシステアリン酸、ミリスチン酸及びラウリン酸を組み合わせて、ナトリウムとカリウムの混合塩とした形態である。かかる脂肪酸の質量比としては、ミリスチン酸とラウリン酸の質量比が、１：３〜１：１が好ましく、ミリスチン酸の質量とラウリン酸の質量を加した質量とヒドロキシステアリン酸の質量との質量比が１５：１〜９：１であることが好ましい。又、かかる脂肪酸のアルカリ金属塩の総量としては、１０〜２０質量％が好ましく、１２〜１８質量％がより好ましい。 The cleaning material of the present invention preferably contains an alkali metal salt of a fatty acid as a cleaning component. This is because the fatty acid alkali metal soap has excellent detergency, but there is a characteristic that a discharge residue solidified easily occurs in the mouth, and the effect of the present invention is due to the solidified discharge residue in the mouth. This is because the cleaning effect of the fatty acid alkali metal soap can be utilized to the maximum in the cleaning material in the form of a pump-up container. Examples of the fatty acid constituting the alkali metal soap of the fatty acid include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, linoleic acid, linolenic acid, and hydroxystearic acid. Sodium or potassium is particularly preferable. Of course, animal and vegetable oils may be saponified with potassium hydroxide or sodium hydroxide and contained in a form in which the saponified product is blended. A particularly preferred form is a form in which hydroxystearic acid, myristic acid and lauric acid are combined to form a mixed salt of sodium and potassium. As the mass ratio of such fatty acids, the mass ratio of myristic acid and lauric acid is preferably 1: 3 to 1: 1, and the mass of the mass of myristic acid and the mass of lauric acid and the mass of hydroxystearic acid is preferred. The ratio is preferably 15: 1 to 9: 1. Moreover, as a total amount of the alkali metal salt of this fatty acid, 10-20 mass% is preferable, and 12-18 mass% is more preferable.
前記の成分以外に、本発明の洗浄料の洗浄料組成物においては、本発明の効果を損なわない限度に於いて、通常洗浄料で使用される任意成分を含有することができる。この様な任意成分としては、例えば、マカデミアナッツ油、アボガド油、トウモロコシ油、オリーブ油、ナタネ油、ゴマ油、ヒマシ油、サフラワー油、綿実油、ホホバ油、ヤシ油、パーム油、液状ラノリン、硬化ヤシ油、硬化油、モクロウ、硬化ヒマシ油、ミツロウ、キャンデリラロウ、カルナウバロウ、イボタロウ、ラノリン、還元ラノリン、硬質ラノリン、ホホバロウ等のオイル、ワックス類；流動パラフィン、スクワラン、プリスタン、オゾケライト、パラフィン、セレシン、ワセリン、マイクロクリスタリンワックス等の炭化水素類；セチルアルコール、ステアリルアルコール、イソステアリルアルコール、ベヘニルアルコール、オクチルドデカノール、ミリスチルアルコール、セトステアリルアルコール等の高級アルコール等；イソオクタン酸セチル、ミリスチン酸イソプロピル、イソステアリン酸ヘキシルデシル、アジピン酸ジイソプロピル、セバチン酸ジ−２−エチルヘキシル、乳酸セチル、リンゴ酸ジイソステアリル、ジ−２−エチルヘキサン酸エチレングリコール、ジカプリン酸ネオペンチルグリコール、ジ−２−ヘプチルウンデカン酸グリセリン、トリ−２−エチルヘキサン酸グリセリン、トリ−２−エチルヘキサン酸トリメチロールプロパン、トリイソステアリン酸トリメチロールプロパン、テトラ−２−エチルヘキサン酸ペンタンエリトリット等の合成エステル油類；ジメチルポリシロキサン、メチルフェニルポリシロキサン、ジフェニルポリシロキサン等の鎖状ポリシロキサン；オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサンシロキサン等の環状ポリシロキサン；アミノ変性ポリシロキサン、ポリエーテル変性ポリシロキサン、アルキル変性ポリシロキサン、フッ素変性ポリシロキサン等の変性ポリシロキサン等のシリコーン油等の油剤類；ラウリル硫酸カリウム、アルキル硫酸トリエタノールアミンエーテル等のアニオン界面活性剤類；塩化ステアリルトリメチルアンモニウム、塩化ベンザルコニウム、ラウリルアミンオキサイド等のカチオン界面活性剤類；イミダゾリン系両性界面活性剤（２−ココイル−２−イミダゾリニウムヒドロキサイド−１−カルボキシエチロキシ２ナトリウム塩等）、ベタイン系界面活性剤（アルキルベタイン、アミドベタイン、スルホベタイン等）、アシルメチルタウリン等の両性界面活性剤類；ソルビタン脂肪酸エステル類（ソルビタンモノステアレート、セスキオレイン酸ソルビタン等）、グリセリン脂肪酸類（モノステアリン酸グリセリン等）、プロピレングリコール脂肪酸エステル類（モノステアリン酸プロピレングリコール等）、硬化ヒマシ油誘導体、グリセリンアルキルエーテル、ＰＯＥソルビタン脂肪酸エステル類（ＰＯＥソルビタンモノオレエート、モノステアリン酸ポリオキエチレンソルビタン等）、ＰＯＥソルビット脂肪酸エステル類（ＰＯＥ−ソルビットモノラウレート等）、ＰＯＥグリセリン脂肪酸エステル類（ＰＯＥ−グリセリンモノイソステアレート等）、ＰＯＥ脂肪酸エステル類（ポリエチレングリコールモノオレート、ＰＯＥジステアレート等）、ＰＯＥアルキルエーテル類（ＰＯＥ２−オクチルドデシルエーテル等）、ＰＯＥアルキルフェニルエーテル類（ＰＯＥノニルフェニルエーテル等）、プルロニック型類、ＰＯＥ・ＰＯＰアルキルエーテル類（ＰＯＥ・ＰＯＰ２−デシルテトラデシルエーテル等）、テトロニック類、ＰＯＥヒマシ油・硬化ヒマシ油誘導体（ＰＯＥヒマシ油、ＰＯＥ硬化ヒマシ油等）、ショ糖脂肪酸エステル、アルキルグルコシド等の非イオン界面活性剤類；ポリエチレングリコール、グリセリン、１，３−ブチレングリコール、エリスリトール、ソルビトール、キシリトール、マルチトール、プロピレングリコール、ジプロピレングリコール、ジグリセリン、イソプレングリコール、１，２−ペンタンジオール、２，４−ヘキサンジオール、１，２−ヘキサンジオール、１，２−オクタンジオール等の多価アルコール類；ピロリドンカルボン酸ナトリウム、乳酸、乳酸ナトリウム等の保湿成分類；表面を処理されていても良い、マイカ、タルク、カオリン、合成雲母、炭酸カルシウム、炭酸マグネシウム、無水ケイ酸（シリカ）、酸化アルミニウム、硫酸バリウム等の粉体類、；表面を処理されていても良い、ベンガラ、黄酸化鉄、黒酸化鉄、酸化コバルト、群青、紺青、酸化チタン、酸化亜鉛の無機顔料類；表面を処理されていても良い、雲母チタン、魚燐箔、オキシ塩化ビスマス等のパール剤類；レーキ化されていても良い赤色２０２号、赤色２２８号、赤色２２６号、黄色４号、青色４０４号、黄色５号、赤色５０５号、赤色２３０号、赤色２２３号、橙色２０１号、赤色２１３号、黄色２０４号、黄色２０３号、青色１号、緑色２０１号、紫色２０１号、赤色２０４号等の有機色素類；ポリエチレン末、ポリメタクリル酸メチル、ナイロン粉末、オルガノポリシロキサンエラストマー等の有機粉体類；パラアミノ安息香酸系紫外線吸収剤；アントラニル酸系紫外線吸収剤；サリチル酸系紫外線吸収剤、；桂皮酸系紫外線吸収剤、；ベンゾフェノン系紫外線吸収剤；糖系紫外線吸収剤；２−（２’−ヒドロキシ−５’−ｔ−オクチルフェニル)ベンゾトリアゾール、４−メトキシ−４’−ｔ−ブチルジベンゾイルメタン等の紫外線吸収剤類；エタノール、イソプロパノール等の低級アルコール類；ビタミンＡ又はその誘導体、ビタミンＢ6塩酸塩、ビタミンＢ6トリパルミテート、ビタミンＢ6ジオクタノエート、ビタミンＢ2又はその誘導体、ビタミンＢ12、ビタミンＢ15又はその誘導体等のビタミンＢ類；α−トコフェロール、β−トコフェロール、γ−トコフェロール、ビタミンＥアセテート等のビタミンＥ類、ビタミンＤ類、ビタミンＨ、パントテン酸、パンテチン、ピロロキノリンキノン等のビタミン類等；フェノキシエタノール等の抗菌剤などが好ましく例示できる。本発明の洗浄料の洗浄料組成物はこれらの成分を常法に従って処理することにより、製造することができる。 In addition to the components described above, the cleaning composition of the cleaning composition of the present invention can contain optional components that are usually used in cleaning compositions as long as the effects of the present invention are not impaired. Examples of such optional ingredients include macadamia nut oil, avocado oil, corn oil, olive oil, rapeseed oil, sesame oil, castor oil, safflower oil, cottonseed oil, jojoba oil, coconut oil, palm oil, liquid lanolin, and hardened coconut oil. Oil, wax, oil such as beeswax, canola wax, carnauba wax, ibotarou, lanolin, reduced lanolin, hard lanolin, jojoba wax, liquid paraffin, squalane, pristane, ozokerite, paraffin, ceresin, petrolatum Hydrocarbons such as microcrystalline wax; higher alcohols such as cetyl alcohol, stearyl alcohol, isostearyl alcohol, behenyl alcohol, octyldodecanol, myristyl alcohol, cetostearyl alcohol; Cetyl octoate, isopropyl myristate, hexyl decyl isostearate, diisopropyl adipate, di-2-ethylhexyl sebacate, cetyl lactate, diisostearyl malate, ethylene glycol di-2-ethylhexanoate, neopentyl glycol dicaprate, Synthetic esters such as glycerin di-2-heptylundecanoate, glyceryl tri-2-ethylhexanoate, trimethylolpropane tri-2-ethylhexanoate, trimethylolpropane triisostearate, pentane erythritol tetra-2-ethylhexanoate Oils: Chain polysiloxanes such as dimethylpolysiloxane, methylphenylpolysiloxane, diphenylpolysiloxane; octamethylcyclotetrasiloxane, decamethylcyclopentasiloxa , Cyclic polysiloxanes such as dodecamethylcyclohexanesiloxane; oil agents such as silicone oils such as amino-modified polysiloxanes, polyether-modified polysiloxanes, alkyl-modified polysiloxanes, and fluorine-modified polysiloxanes; silicone oils; potassium lauryl sulfate, alkyls Anionic surfactants such as triethanolamine ether sulfate; Cationic surfactants such as stearyltrimethylammonium chloride, benzalkonium chloride and laurylamine oxide; Imidazoline-based amphoteric surfactants (2-cocoyl-2-imidazolinium) Hydroxide-1-carboxyethyloxy disodium salt, etc.), betaine surfactants (alkyl betaine, amide betaine, sulfobetaine, etc.), amphoteric surfactants such as acylmethyl taurine; Vitan fatty acid esters (such as sorbitan monostearate, sorbitan sesquioleate), glycerin fatty acids (such as glyceryl monostearate), propylene glycol fatty acid esters (such as propylene glycol monostearate), hydrogenated castor oil derivatives, glycerin alkyl ether POE sorbitan fatty acid esters (POE sorbitan monooleate, polyoxyethylene sorbitan monostearate, etc.), POE sorbite fatty acid esters (POE-sorbitol monolaurate, etc.), POE glycerin fatty acid esters (POE-glycerin monoisosteare) Rate), POE fatty acid esters (polyethylene glycol monooleate, POE distearate, etc.), POE alkyl ethers (POE2-octyldodecyl) Ether, etc.), POE alkylphenyl ethers (POE nonylphenyl ether, etc.), Pluronic types, POE / POP alkyl ethers (POE / POP2-decyltetradecyl ether, etc.), Tetronics, POE castor oil / hardened castor oil Nonionic surfactants such as derivatives (POE castor oil, POE hydrogenated castor oil, etc.), sucrose fatty acid esters, alkyl glucosides; polyethylene glycol, glycerin, 1,3-butylene glycol, erythritol, sorbitol, xylitol, maltitol, Polyhydric alcohols such as propylene glycol, dipropylene glycol, diglycerin, isoprene glycol, 1,2-pentanediol, 2,4-hexanediol, 1,2-hexanediol, 1,2-octanediol Moisturizing ingredients such as sodium pyrrolidonecarboxylate, lactic acid, sodium lactate; mica, talc, kaolin, synthetic mica, calcium carbonate, magnesium carbonate, anhydrous silicic acid (silica), aluminum oxide, which may be surface-treated; Powders such as barium sulfate; surface treated, bengara, yellow iron oxide, black iron oxide, cobalt oxide, ultramarine, bitumen, titanium oxide, zinc oxide inorganic pigments; surface treated Pearl agents such as mica titanium, fish phosphorus foil, bismuth oxychloride; red 202, red 228, red 226, yellow 4, blue 404, yellow 5 which may be raked , Red 505, Red 230, Red 223, Orange 201, Red 213, Yellow 204, Yellow 203, Blue 1, Green 201, Purple 201 No., organic dyes such as red No. 204; organic powders such as polyethylene powder, polymethyl methacrylate, nylon powder, organopolysiloxane elastomer; paraaminobenzoic acid UV absorber; anthranilic acid UV absorber; salicylic acid UV absorbers; cinnamic acid UV absorbers; benzophenone UV absorbers; sugar UV absorbers; 2- (2′-hydroxy-5′-t-octylphenyl) benzotriazole, 4-methoxy-4 ′ UV absorbers such as t-butyldibenzoylmethane; lower alcohols such as ethanol and isopropanol; vitamin A or a derivative thereof, vitamin B6 hydrochloride, vitamin B6 tripalmitate, vitamin B6 dioctanoate, vitamin B2 or a derivative thereof, Vitamins such as vitamin B12, vitamin B15 or their derivatives B: α-tocopherol, β-tocopherol, γ-tocopherol, vitamin E such as vitamin E acetate, vitamin D, vitamin H, pantothenic acid, panthetin, vitamins such as pyrroloquinoline quinone, etc .; antibacterial agent such as phenoxyethanol Etc. can be preferably exemplified. The cleaning composition of the cleaning composition of the present invention can be produced by treating these components according to a conventional method.
本発明の洗浄料は、前記洗浄料組成物をポンプ容器に充填してなることを特徴とする。ポンプ容器は通常流布されているものであれば特段の限定なく適用することができる。ポンプ容器としては、吐出口の最小のものが直径１ｍｍφ以下のものであれば、本発明の効果は顕著であり、好ましい。特に吐出口に複数の細口が集合的に配され、一定量の洗浄剤組成物を一定量の空気と混合して発泡させ、泡状態として吐出する構造のポンプフォーマーを装備したポンプフォーマー容器に充填してなることが好ましい。この様なフォーマー構造としては、特公昭５２−１６５６７号公報、実開平７−２２９５６号公報、特開平９−１９３９５３号公報、２０００−１２８２１５号公報などの特許文献に詳細が記載されている。本発明の洗浄料の洗浄料組成物は、この様な構造の吐出口を洗浄料組成物の固化体などで閉塞し、吐出を阻害しない。 The cleaning material of the present invention is characterized in that the cleaning material composition is filled in a pump container. The pump container can be applied without particular limitation as long as it is normally distributed. As the pump container, if the smallest outlet is one having a diameter of 1 mmφ or less, the effect of the present invention is remarkable and preferable. In particular, a pump former container equipped with a pump former having a structure in which a plurality of narrow ports are collectively arranged at the discharge port, a fixed amount of a cleaning composition is mixed with a fixed amount of air, foamed, and discharged as a foam state. It is preferable to fill it. Details of such a former structure are described in patent documents such as Japanese Patent Publication No. 52-16567, Japanese Utility Model Laid-Open No. 7-22756, Japanese Patent Application Laid-Open No. 9-193953 and 2000-128215. The cleaning composition of the cleaning composition of the present invention blocks the discharge port having such a structure with a solidified body of the cleaning composition, and does not hinder the discharge.
以下に、実施例をあげて、本発明について、更に詳細に説明を加えるが、本発明が、かかる実施例にのみ、限定されないことは言うまでもない。 Hereinafter, the present invention will be described in more detail with reference to examples, but it goes without saying that the present invention is not limited to such examples.
以下に示す処方に従って、本発明の洗浄料用の洗浄組成物を製造した。即ち、イ、ロの成分を８０℃に加熱し、攪拌下イにロを徐々に加え、均一にし、攪拌冷却し、洗浄料組成物１を得た。このものの粘度は４５０ｍＰａ・ｓであった。同様に操作して、イソステアリン酸を水に置換した比較例１（４００ｍＰａ・ｓ）、ステアリン酸に置換した比較例２（４５０ｍＰａ・ｓ）も製造した。 A cleaning composition for a cleaning material of the present invention was produced according to the formulation shown below. That is, components (a) and (b) were heated to 80 ° C., and (b) was gradually added to the mixture under stirring to make it uniform, and stirred and cooled to obtain a cleaning composition 1. The viscosity of this product was 450 mPa · s. In the same manner, Comparative Example 1 (400 mPa · s) in which isostearic acid was substituted with water and Comparative Example 2 (450 mPa · s) in which stearic acid was substituted were also produced.
＜試験例１＞
洗浄料組成物１を吐出口の口径が２．５ｍｍのポンプを装着した容器に充填し、本発明の洗浄料１とした。同様に、同型の容器に比較例１を充填し、比較例３とし、比較例２を充填し、比較例４とした。洗浄料１、比較例３及び比較例４を４０℃に保存し、保存後１日に、ポンプの押しボタンの上部に１５０ｇのおもりを置き、洗浄料組成物が吐出するのを確認した後、３０日間４０℃で保存し、再度１５０ｇのおもりを乗せて洗浄料組成物の吐出を観察した。結果は洗浄料１のみが吐出を観察し、比較例３及び比較例４は固化物で吐出口が閉塞され吐出されなかった。
<Test Example 1>
The cleaning composition 1 was filled in a container equipped with a pump having a discharge port diameter of 2.5 mm to obtain the cleaning composition 1 of the present invention. Similarly, Comparative Example 1 was filled in a container of the same type to make Comparative Example 3, and Comparative Example 2 was filled to make Comparative Example 4. The cleaning material 1, Comparative Example 3 and Comparative Example 4 were stored at 40 ° C., and after 1 day of storage, a 150 g weight was placed on the top of the push button of the pump, and after confirming that the cleaning material composition was discharged, It was stored at 40 ° C. for 30 days, and a 150 g weight was placed on it again and the discharge of the cleaning composition was observed. As a result, only the cleaning material 1 was observed to be discharged, and Comparative Example 3 and Comparative Example 4 were not discharged because the discharge port was closed with a solidified product.
＜試験例２＞
洗浄料組成物１をポンプフォーマーを装着した容器に充填し、本発明の洗浄料２とした。同様に、同型の容器に比較例１を充填し、比較例５とし、比較例２を充填し、比較例６とした。洗浄料２、比較例５及び比較例６を各２個４０℃に保存し、保存後１日に、ポンプの押しボタンの上部に１５０ｇのおもりを置き、洗浄料組成物が吐出するのを確認した後、１個は１週間の保存後、残る１個は３週間の保存後再度吐出試験を行った。吐出試験では、吐出の可否と、泡形成の可否（吐出形状）とを観察した。結果を表２に示す。これより、本発明の洗浄料は泡沫吐出維持性に優れることがわかる。
<Test Example 2>
The cleaning composition 1 was filled in a container equipped with a pump former to obtain the cleaning composition 2 of the present invention. Similarly, Comparative Example 1 was filled in a container of the same type to make Comparative Example 5, and Comparative Example 2 was filled to make Comparative Example 6. Store 2 each of Cleaning Material 2, Comparative Example 5 and Comparative Example 6 at 40 ° C, and place 150g weight on top of the pump push button one day after storage and confirm that the cleaning material composition is discharged Then, one of them was subjected to a discharge test after storage for one week, and the other one was stored for three weeks after storage. In the discharge test, whether discharge was possible and whether foam was formed (discharge shape) were observed. The results are shown in Table 2. From this, it can be seen that the cleaning material of the present invention is excellent in foam discharge maintenance.
実施例１と同様に洗浄料組成物２を製造した。これをポンプフォーマー容器に充填し洗浄料３として、試験例２の方法で評価した。洗浄料３は保存１週間ではきれいな泡沫を吐出したものの、保存３週間では極めて肌理の粗い泡沫しか吐出できなかった。「ピロテルＣＰＩ４０」を含有する形態が好ましいことがわかる。 A cleaning composition 2 was produced in the same manner as in Example 1. This was filled in a pump former container and evaluated as the cleaning material 3 by the method of Test Example 2. The cleaning material 3 ejected clean foam in one week of storage, but was able to eject only extremely rough foam in three weeks of storage. It turns out that the form containing "Pirotel CPI40" is preferable.
実施例１と同様に洗浄料組成物３を製造した。これをポンプフォーマー容器に充填し洗浄料４として、試験例２の方法で評価した。洗浄料４は保存１週間及び３週間に於いて、きれいな泡沫を吐出した。 A cleaning composition 3 was produced in the same manner as in Example 1. This was filled in a pump former container and evaluated as the cleaning material 4 by the method of Test Example 2. Cleaning material 4 discharged clean foams during storage for 1 week and 3 weeks.
本発明は、ポンプ容器に充填されてなる洗浄料に応用できる。 The present invention can be applied to a cleaning material filled in a pump container.
Claims (6)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| JP2006058807A JP2007238457A (en) | 2006-03-06 | 2006-03-06 | Cleansing agent in which cleansing agent composition is packed in pump vessel |
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| Application Number | Priority Date | Filing Date | Title |
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| JP2006058807A JP2007238457A (en) | 2006-03-06 | 2006-03-06 | Cleansing agent in which cleansing agent composition is packed in pump vessel |
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| Publication Number | Publication Date |
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| JP2007238457A true JP2007238457A (en) | 2007-09-20 |
| JP2007238457A5 JP2007238457A5 (en) | 2009-04-16 |
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| Application Number | Title | Priority Date | Filing Date |
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| JP2006058807A Pending JP2007238457A (en) | 2006-03-06 | 2006-03-06 | Cleansing agent in which cleansing agent composition is packed in pump vessel |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011213682A (en) * | 2010-03-31 | 2011-10-27 | Naris Cosmetics Co Ltd | Foaming cleansing cosmetic |
| JP2020200271A (en) * | 2019-06-10 | 2020-12-17 | 花王株式会社 | Foamer container-contained skin cleaning agent |
| US12053539B2 (en) | 2021-06-15 | 2024-08-06 | The Procter & Gamble Company | Hair care compositions comprising hydroxylated triglyceride oligomers |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0948962A (en) * | 1995-08-04 | 1997-02-18 | Pola Chem Ind Inc | Agent that inhibits solidification of liquid |
| JPH0948714A (en) * | 1995-08-04 | 1997-02-18 | Pola Chem Ind Inc | Nongas shaving cosmetic |
| JP2003055699A (en) * | 2001-08-20 | 2003-02-26 | Lion Corp | Liquid detergent composition |
| JP2004277294A (en) * | 2003-03-13 | 2004-10-07 | Pola Chem Ind Inc | Detergent for promoting old keratin peeling containing granulated material |
-
2006
- 2006-03-06 JP JP2006058807A patent/JP2007238457A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0948962A (en) * | 1995-08-04 | 1997-02-18 | Pola Chem Ind Inc | Agent that inhibits solidification of liquid |
| JPH0948714A (en) * | 1995-08-04 | 1997-02-18 | Pola Chem Ind Inc | Nongas shaving cosmetic |
| JP2003055699A (en) * | 2001-08-20 | 2003-02-26 | Lion Corp | Liquid detergent composition |
| JP2004277294A (en) * | 2003-03-13 | 2004-10-07 | Pola Chem Ind Inc | Detergent for promoting old keratin peeling containing granulated material |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011213682A (en) * | 2010-03-31 | 2011-10-27 | Naris Cosmetics Co Ltd | Foaming cleansing cosmetic |
| JP2020200271A (en) * | 2019-06-10 | 2020-12-17 | 花王株式会社 | Foamer container-contained skin cleaning agent |
| JP7329368B2 (en) | 2019-06-10 | 2023-08-18 | 花王株式会社 | Skin cleanser in foamer container |
| US12053539B2 (en) | 2021-06-15 | 2024-08-06 | The Procter & Gamble Company | Hair care compositions comprising hydroxylated triglyceride oligomers |
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