JP2003055699A - Liquid detergent composition - Google Patents
Liquid detergent compositionInfo
- Publication number
- JP2003055699A JP2003055699A JP2001248774A JP2001248774A JP2003055699A JP 2003055699 A JP2003055699 A JP 2003055699A JP 2001248774 A JP2001248774 A JP 2001248774A JP 2001248774 A JP2001248774 A JP 2001248774A JP 2003055699 A JP2003055699 A JP 2003055699A
- Authority
- JP
- Japan
- Prior art keywords
- liquid detergent
- detergent composition
- group
- foam
- points
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 57
- 239000003599 detergent Substances 0.000 title claims abstract description 49
- 239000007788 liquid Substances 0.000 title claims abstract description 42
- 150000003839 salts Chemical class 0.000 claims abstract description 12
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 11
- 125000001165 hydrophobic group Chemical group 0.000 claims abstract description 11
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 11
- 239000002253 acid Substances 0.000 claims description 11
- -1 amide carboxylic acid Chemical class 0.000 abstract description 29
- 239000006260 foam Substances 0.000 abstract description 21
- 230000000694 effects Effects 0.000 abstract description 12
- 230000007794 irritation Effects 0.000 abstract description 3
- 238000011156 evaluation Methods 0.000 description 17
- 125000004432 carbon atom Chemical group C* 0.000 description 16
- 235000014113 dietary fatty acids Nutrition 0.000 description 16
- 239000000194 fatty acid Substances 0.000 description 16
- 229930195729 fatty acid Natural products 0.000 description 16
- 150000004665 fatty acids Chemical class 0.000 description 13
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 241000282320 Panthera leo Species 0.000 description 7
- 238000004140 cleaning Methods 0.000 description 7
- 239000000839 emulsion Substances 0.000 description 7
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- 230000001815 facial effect Effects 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 125000001183 hydrocarbyl group Chemical group 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- LQXBZWFNAKZUNM-UHFFFAOYSA-N 16-methyl-1-(16-methylheptadecoxy)heptadecane Chemical compound CC(C)CCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC(C)C LQXBZWFNAKZUNM-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 239000004359 castor oil Substances 0.000 description 3
- 235000019438 castor oil Nutrition 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 239000012847 fine chemical Substances 0.000 description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 230000001953 sensory effect Effects 0.000 description 3
- 239000002453 shampoo Substances 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 150000005846 sugar alcohols Chemical group 0.000 description 3
- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- NGNZTXNWCGRXKL-UHFFFAOYSA-M potassium;16-methylheptadecanoate Chemical compound [K+].CC(C)CCCCCCCCCCCCCCC([O-])=O NGNZTXNWCGRXKL-UHFFFAOYSA-M 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- ODZPKZBBUMBTMG-UHFFFAOYSA-N sodium amide Chemical compound [NH2-].[Na+] ODZPKZBBUMBTMG-UHFFFAOYSA-N 0.000 description 2
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 2
- FRHNXUKHAUWMOQ-UHFFFAOYSA-M sodium;16-methylheptadecanoate Chemical compound [Na+].CC(C)CCCCCCCCCCCCCCC([O-])=O FRHNXUKHAUWMOQ-UHFFFAOYSA-M 0.000 description 2
- OCWPEQFHKVUBTB-HVDRVSQOSA-N 16-methylheptadecanoic acid;(2s)-5-oxopyrrolidine-2-carboxylic acid Chemical compound OC(=O)[C@@H]1CCC(=O)N1.CC(C)CCCCCCCCCCCCCCC(O)=O OCWPEQFHKVUBTB-HVDRVSQOSA-N 0.000 description 1
- ZFFBIQMNKOJDJE-UHFFFAOYSA-N 2-bromo-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(Br)C(=O)C1=CC=CC=C1 ZFFBIQMNKOJDJE-UHFFFAOYSA-N 0.000 description 1
- MHGOKSLTIUHUBF-UHFFFAOYSA-M 2-ethylhexyl sulfate(1-) Chemical compound CCCCC(CC)COS([O-])(=O)=O MHGOKSLTIUHUBF-UHFFFAOYSA-M 0.000 description 1
- ZUGHHBXQIMYNTD-UHFFFAOYSA-N 2-hydroxypropanoyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC(=O)C(C)O ZUGHHBXQIMYNTD-UHFFFAOYSA-N 0.000 description 1
- BHIZVZJETFVJMJ-UHFFFAOYSA-N 2-hydroxypropyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCC(C)O BHIZVZJETFVJMJ-UHFFFAOYSA-N 0.000 description 1
- FSOIWVKMFCDTNT-UHFFFAOYSA-N 4-(decylamino)-2,3-dihydroxy-4-oxobutanoic acid Chemical compound CCCCCCCCCCNC(=O)C(O)C(O)C(O)=O FSOIWVKMFCDTNT-UHFFFAOYSA-N 0.000 description 1
- MHFFNCIDSRYQCS-UHFFFAOYSA-N 4-(dodecylamino)-3-hydroxy-4-oxobutanoic acid Chemical compound CCCCCCCCCCCCNC(=O)C(O)CC(O)=O MHFFNCIDSRYQCS-UHFFFAOYSA-N 0.000 description 1
- CUGWQSJAOHEMKR-UHFFFAOYSA-N C(CCCCCCCCC)NC(C(O)CC(=O)O)=O Chemical compound C(CCCCCCCCC)NC(C(O)CC(=O)O)=O CUGWQSJAOHEMKR-UHFFFAOYSA-N 0.000 description 1
- LFVWLTQHMPLAGI-UHFFFAOYSA-N CCCCCCCCCCCCCCCCNC(=O)C(CC(=O)O)O Chemical compound CCCCCCCCCCCCCCCCNC(=O)C(CC(=O)O)O LFVWLTQHMPLAGI-UHFFFAOYSA-N 0.000 description 1
- TYAGLMTVXHRMPS-UHFFFAOYSA-N CCCCCCCCCCCCCCNC(=O)C(CC(=O)O)O Chemical compound CCCCCCCCCCCCCCNC(=O)C(CC(=O)O)O TYAGLMTVXHRMPS-UHFFFAOYSA-N 0.000 description 1
- 101100061515 Caenorhabditis elegans csk-1 gene Proteins 0.000 description 1
- 101100321669 Fagopyrum esculentum FA02 gene Proteins 0.000 description 1
- 101100321670 Fagopyrum esculentum FA18 gene Proteins 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 101100161928 Solanum tuberosum AC58 gene Proteins 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 1
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000001734 carboxylic acid salts Chemical class 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- DTPCFIHYWYONMD-UHFFFAOYSA-N decaethylene glycol Polymers OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO DTPCFIHYWYONMD-UHFFFAOYSA-N 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 229940074052 glyceryl isostearate Drugs 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229950001046 piroctone Drugs 0.000 description 1
- BTSZTGGZJQFALU-UHFFFAOYSA-N piroctone olamine Chemical compound NCCO.CC(C)(C)CC(C)CC1=CC(C)=CC(=O)N1O BTSZTGGZJQFALU-UHFFFAOYSA-N 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- ZUFQCVZBBNZMKD-UHFFFAOYSA-M potassium 2-ethylhexanoate Chemical compound [K+].CCCCC(CC)C([O-])=O ZUFQCVZBBNZMKD-UHFFFAOYSA-M 0.000 description 1
- HDNUWVXAEZKFPH-UHFFFAOYSA-M potassium 2-octyldodecanoate Chemical compound CCCCCCCCCCC(CCCCCCCC)C(=O)[O-].[K+] HDNUWVXAEZKFPH-UHFFFAOYSA-M 0.000 description 1
- XWJWRUYIKNLZFO-UHFFFAOYSA-M potassium;7-methyloctanoate Chemical compound [K+].CC(C)CCCCCC([O-])=O XWJWRUYIKNLZFO-UHFFFAOYSA-M 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- CAVXVRQDZKMZDB-UHFFFAOYSA-M sodium;2-[dodecanoyl(methyl)amino]ethanesulfonate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CCS([O-])(=O)=O CAVXVRQDZKMZDB-UHFFFAOYSA-M 0.000 description 1
- VYPDUQYOLCLEGS-UHFFFAOYSA-M sodium;2-ethylhexanoate Chemical compound [Na+].CCCCC(CC)C([O-])=O VYPDUQYOLCLEGS-UHFFFAOYSA-M 0.000 description 1
- IWZMRTOJHVIXKV-UHFFFAOYSA-M sodium;2-octyldodecanoate Chemical compound [Na+].CCCCCCCCCCC(C([O-])=O)CCCCCCCC IWZMRTOJHVIXKV-UHFFFAOYSA-M 0.000 description 1
- TVLQCQIKBJXIQX-UHFFFAOYSA-M sodium;7-methyloctanoate Chemical compound [Na+].CC(C)CCCCCC([O-])=O TVLQCQIKBJXIQX-UHFFFAOYSA-M 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
(57)【要約】
【解決手段】 （Ａ）下記一般式（Ｉ）で表されるアミ
ドカルボン酸又はその塩と、
【化１】
（Ｂ）疎水基に分岐鎖を有するアニオン性界面活性剤及
びノニオン性界面活性剤から選ばれる１種又は２種以上
とを含有する液体洗浄剤組成物。
【効果】 皮膚や毛髪に対して低刺激であり、且つすす
ぎ時には、さっぱり感を有し、例えば口紅等のメイクの
汚れを良好に洗浄することができ、フォーマー容器に充
填して用いると、低温下でも均質でクリーミィな泡を形
成できる。(A) An amide carboxylic acid or a salt thereof represented by the following general formula (I): (B) A liquid detergent composition containing one or more selected from anionic surfactants having a branched chain in a hydrophobic group and nonionic surfactants. [Effect] It has low irritation to the skin and hair, and has a refreshing feeling when rinsed. For example, it can well wash makeup stains such as lipstick. Even below, a homogeneous and creamy foam can be formed.
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、液体洗浄剤組成物
に関し、より詳しくは、皮膚にマイルドで、且つすすぎ
時のさっぱり感及び洗浄力に優れ、特にフォーマー容器
に充填してフォーマー用液体洗浄剤組成物として使用す
ると、泡形成性に優れるのみならず、低温での目詰まり
などもなく、良好な使用性が得られる液体洗浄剤組成物
に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a liquid detergent composition, and more particularly, it is mild to the skin and has excellent refreshing feeling and detergency at the time of rinsing. The present invention relates to a liquid detergent composition which, when used as an agent composition, not only has excellent foam-forming property but also has no clogging at low temperature and has good usability.
【０００２】[0002]
【従来の技術及び発明が解決しようとする課題】一般
に、身体洗浄剤に求められる機能としては、洗浄性、泡
立ち性（質・量感）、泡切れ性、皮膚に対するマイルド
性、使用後の官能性（しっとり感、すべすべ感等）、洗
浄剤組成物の保存安定性などが挙げられる。これらのう
ち、使用時に求められる性能は、洗浄組成物によって大
きく変わるものであるが、同一の洗浄剤組成物を用いて
も、洗浄剤の量及びその泡立て方によっても大きく変化
する。2. Description of the Related Art Generally, the functions required for a personal cleansing agent include detergency, foamability (quality / quantity), defoaming ability, mildness to the skin, and functionality after use. (Moistness, smoothness, etc.), storage stability of the cleaning composition, and the like. Among these, the performance required at the time of use varies greatly depending on the cleaning composition, but even if the same cleaning composition is used, it also varies greatly depending on the amount of the cleaning agent and the foaming method thereof.
【０００３】皮膚に対してマイルドな界面活性剤として
Ｎ−アシルアミノ酸塩やスルホコハク酸塩を配合した低
刺激性洗浄剤組成物が開示されているが、これらの界面
活性剤では、すすぎ時にぬるつき感があるという課題が
あるものであった。その課題を解決すべく、マイルドで
泡立ちが良く、すすぎのさっぱり感を特徴とするアミド
カルボン酸又はその塩を含有する洗浄剤組成物が提案さ
れている（特開平８−２９１１２３号、特開平１０−１
２１０９０号公報）。しかしながら、この提案の場合、
メイク落ちなどの洗浄力については未だ改良の余地があ
った。A mild detergent composition containing an N-acyl amino acid salt or a sulfosuccinate as a mild surfactant for the skin is disclosed, but these surfactants have a slimy feel during rinsing. There was a problem of feeling. In order to solve the problem, a detergent composition containing an amidocarboxylic acid or a salt thereof, which is mild and has a good foaming property and a refreshing feeling of rinsing, has been proposed (JP-A-8-291123, JP-A-10-123123). -1
No. 21090). However, in the case of this proposal,
There was still room for improvement in detergency such as makeup removal.
【０００４】また、使用性や洗浄力を改善するために、
分岐脂肪酸又はその塩を配合することが提案されている
（特開平１−３０１７９９号、特開平４−５２１２号、
特開平４−５７８９６号、特開平７−１１８６９１号公
報）。しかしながら、これらの公報に開示の組成物で
は、すすぎ時のぬるつき感の改善効果を確保できていな
いという課題があった。Further, in order to improve usability and cleaning power,
It has been proposed to blend a branched fatty acid or a salt thereof (JP-A-1-301799, JP-A-4-5212,
JP-A-4-57896 and JP-A-7-118691). However, the compositions disclosed in these publications have a problem that the effect of improving the slimy feeling during rinsing cannot be secured.
【０００５】一方、従来の身体洗浄剤は、洗浄組成物を
手又はタオルなどに取り、更に、場合によっては適度な
水を加えた状態で、身体又はタオルなどとの摩擦によ
り、適度に泡立てて洗浄を行うものであった。摩擦によ
る泡立て方では、温度、湿度などの使用環境や摩擦を行
う力のかけ具合、更に、泡立てるために使用する水の硬
度及び水分量などにより、泡の質感、量感が大きく左右
され、洗浄剤の諸性能に影響を与える。また、最近、手
を汚すことなく、しかも１回に使用する量を一定にし得
る、簡便性、使用性等に優れたポンプ式の容器に入った
洗浄剤が市販されている。しかしながら、ポンプ式容器
に充填した洗浄剤は、泡質や泡の安定性等が悪く、ま
た、粘性の高い洗浄剤が入った場合は、使用する量を一
定にすることは困難であった。On the other hand, in the conventional body cleansing agent, the cleansing composition is taken on a hand or a towel, and in some cases, a suitable amount of water is added to the body to rub the body or the towel with a proper amount of foam to rub the foam. It was to be washed. In the method of foaming by friction, the texture and volume of the foam are greatly affected by the environment of use such as temperature and humidity, the degree of the force of friction, and the hardness and water content of the water used for foaming. Affect the performance of. Further, recently, a cleaning agent in a pump-type container, which is excellent in convenience and usability, which can keep the amount used at one time constant without soiling the hands, is commercially available. However, the detergent filled in the pump-type container has poor foam quality and foam stability, and when a highly viscous detergent is contained, it is difficult to keep the amount used.
【０００６】そこでフォーマー容器に充填する洗浄剤組
成物が種々提案されている（特開平７−２５２１３４
号、特開平７−１８２９４号、特開平８−１６５２３４
号、特開平１１−３５９７２号公報）。しかしながら、
これら洗浄剤組成物は、その主成分である界面活性剤
が、皮膚への刺激性、安定性等に問題を有していたり、
洗浄力、泡形成性や泡量の均一性等が不十分であるとい
う問題も有していた。また、フォーマー容器の改良のみ
では、洗浄力、泡質、低温下での使用性等の問題を解決
することは困難であった。Therefore, various detergent compositions to be filled in the former container have been proposed (Japanese Patent Laid-Open No. 252134/1995).
No. 7, JP-A-18-18294, and JP-A-8-165234.
No. 11-35972). However,
In these detergent compositions, the main component, the surfactant, has a problem in irritation to the skin, stability, etc.,
There is also a problem that the detergency, the foam-forming property and the uniformity of the foam amount are insufficient. Further, it has been difficult to solve the problems such as detergency, foam quality, and usability at low temperature only by improving the former container.
【０００７】本発明は、上述したような従来技術の課題
を解消しようとするものであり、皮膚に対して低刺激
で、洗浄力に優れ、すすぎ時にさっぱり感を有し、特に
フォーマー容器に充填して使用すると、泡形成性に優れ
るのみならず、低温下でも均質でクリーミィな泡を形成
できる液体洗浄剤組成物を提供することを目的とする。The present invention is intended to solve the above-mentioned problems of the prior art. It has a low irritation to the skin, an excellent cleansing power, and a refreshing feeling at the time of rinsing. It is an object of the present invention to provide a liquid detergent composition which is excellent in foam-forming property and can form a uniform and creamy foam even at a low temperature when used.
【０００８】[0008]
【課題を解決するための手段及び発明の実施の形態】本
発明者らは、上記課題を解決するため、鋭意検討した結
果、特定のアミドカルボン酸又はその塩と、疎水基に分
岐鎖を有することを特徴とするアニオン性界面活性剤、
ノニオン性界面活性剤の１種又は２種以上とを併用する
と、皮膚に対するマイルド性、すすぎ時におけるさっぱ
り感が格段に向上するのみならず、洗浄力も格段に向上
し、特にフォーマー容器に充填してフォーマー用液体洗
浄剤組成物として使用すると、泡形成性に優れ、且つ低
温での目詰まりなどもなく、特に使用性に優れる液体洗
浄剤組成物が得られることを見出し、本発明を完成する
に至った。Means for Solving the Problems and Modes for Carrying Out the Invention As a result of intensive studies to solve the above problems, the present inventors have found that a specific amidocarboxylic acid or a salt thereof and a branched chain in a hydrophobic group are included. An anionic surfactant, characterized in that
When used in combination with one or more nonionic surfactants, not only the mildness to the skin and the refreshing feeling at the time of rinsing are significantly improved, but also the detergency is significantly improved. When used as a liquid detergent composition for a former, it was found that a liquid detergent composition having excellent foam-forming property and no clogging at a low temperature and particularly excellent usability can be obtained, and thus the present invention is completed. I arrived.
【０００９】即ち、本発明は、下記（Ａ）及び（Ｂ）を
含有してなることを特徴とする液体洗浄剤組成物。
（Ａ）下記一般式（Ｉ）で表されるアミドカルボン酸又
はその塩That is, the present invention is a liquid detergent composition containing the following (A) and (B). (A) Amidocarboxylic acid represented by the following general formula (I) or a salt thereof
【００１０】[0010]
【化２】 [Chemical 2]
【００１１】（Ｂ）疎水基に分岐鎖を有するアニオン性
界面活性剤及びノニオン性界面活性剤から選ばれる１種
又は２種以上(B) One or more selected from anionic surfactants and nonionic surfactants having a branched chain in the hydrophobic group.
【００１２】ここで、上記液体洗浄剤組成物が、フォー
マー容器に充填されたものであると、より好適である。Here, it is more preferable that the liquid detergent composition is filled in a former container.
【００１３】以下、本発明をより詳細に説明すると、本
発明の液体洗浄剤組成物は、（Ａ）下記一般式（Ｉ）で
表されるアミドカルボン酸又はその塩及び（Ｂ）疎水基
に分岐鎖を有するアニオン性界面活性剤及びノニオン性
界面活性剤から選ばれる１種又は２種以上を必須成分と
するものである。The present invention will be described in more detail below. The liquid detergent composition of the present invention comprises (A) an amidocarboxylic acid represented by the following general formula (I) or a salt thereof and (B) a hydrophobic group. One or more selected from anionic surfactants having a branched chain and nonionic surfactants are essential components.
【００１４】[0014]
【化３】 [Chemical 3]
【００１５】ここで、上記一般式（Ｉ）中のＲは、炭素
数８〜２２、好ましくは炭素数８〜１８の直鎖又は分岐
鎖のアルキル基、アルケニル基若しくはヒドロキシアル
キル基であり、具体的には、例えばオクチル基、デシル
基、ラウリル基、ミリスチル基、ヘキサデシル基、オク
タデシル基、ベヘニル基、オレイル基等が挙げられ、デ
シル基、ラウリル基、ミリスチル基が特に好ましい。Ｒ
の炭素数が８未満では本発明が目的とする洗浄力が得ら
れず、また炭素数が２２を超えると溶液の分散性が良く
ない。Here, R in the above general formula (I) is a linear or branched alkyl group, alkenyl group or hydroxyalkyl group having 8 to 22 carbon atoms, preferably 8 to 18 carbon atoms. Specific examples thereof include an octyl group, a decyl group, a lauryl group, a myristyl group, a hexadecyl group, an octadecyl group, a behenyl group and an oleyl group, and a decyl group, a lauryl group and a myristyl group are particularly preferable. R
When the carbon number is less than 8, the detergency desired by the present invention cannot be obtained, and when the carbon number exceeds 22, the dispersibility of the solution is not good.
【００１６】また、Ａは、水素原子又は炭素数１〜６、
好ましくは１〜３の直鎖又は分岐鎖のアルキル基若しく
はヒドロキシアルキル基、或いは炭素数４〜７の糖残基
又は糖アルコール残基である。上記アルキル基、ヒドロ
キシアルキル基として、具体的には、例えばメチル基、
エチル基、ヒドロキシエチル基、ヒドロキシプロピル基
等が挙げられる。炭素数が６を超えると溶液への分散性
が良くない。また、上記糖残基又は糖アルコール残基の
具体例としては、１−デオキシソルビチル基、１−デオ
キシエリスリチル基、１−デオキシキシリチル基、１−
デオキシ−４−グリコシド−ソルビチル基、１−デオキ
シマンニチル基、１−デオキシアラビチル基、１−デオ
キシガラクチル基等が挙げられる。A is a hydrogen atom or has 1 to 6 carbon atoms,
Preferably, it is a linear or branched alkyl group or hydroxyalkyl group having 1 to 3 carbon atoms, or a sugar residue or sugar alcohol residue having 4 to 7 carbon atoms. As the alkyl group and the hydroxyalkyl group, specifically, for example, a methyl group,
Examples thereof include an ethyl group, a hydroxyethyl group and a hydroxypropyl group. When the carbon number exceeds 6, the dispersibility in the solution is not good. In addition, specific examples of the sugar residue or sugar alcohol residue include 1-deoxysorbityl group, 1-deoxyerythrityl group, 1-deoxyxylyl group, 1-
Examples thereof include a deoxy-4-glycoside-sorbityl group, a 1-deoxymannityl group, a 1-deoxyarabityl group, a 1-deoxygalactyl group.
【００１７】更に、Ｘは、−ＣＨ（ＯＨ）ＣＨ2−、−
ＣＨ2ＣＨ（ＯＨ）−、若しくはこれらの混合物、−Ｃ
Ｈ（ＯＨ）ＣＨ（ＯＨ）−又は−ＣＨ2ＣＨ2−である。Further, X is --CH (OH) CH 2 -,-
CH 2 CH (OH)-, or a mixture thereof, -C
H (OH) CH (OH) - or -CH 2 CH 2 -.
【００１８】本発明の上記（Ａ）アミドカルボン酸又は
その塩として、より具体的には、モノ−Ｎ−ラウリルリ
ンゴ酸アミド、モノ−Ｎ−ラウリルリンゴ酸アミドカリ
ウム、モノ−Ｎ−ラウリルリンゴ酸アミドナトリウム、
モノ−Ｎ−ラウリルリンゴ酸アミドジエタノールアミ
ン、モノ−Ｎ−ラウリルリンゴ酸アミドトリエタノール
アミン、Ｎ−メチル−Ｎ−ラウリルリンゴ酸アミドカリ
ウム、モノ−Ｎ−ミリスチルリンゴ酸アミド、モノ−Ｎ
−ミリスチルリンゴ酸アミドカリウム、モノ−Ｎ−ミリ
スチルリンゴ酸アミドナトリウム、モノ−Ｎ−ミリスチ
ルリンゴ酸アミドジエタノールアミン、モノ−Ｎ−ミリ
スチルリンゴ酸アミドトリエタノールアミン、モノ−Ｎ
−パルミチルリンゴ酸アミド、モノ−Ｎ−パルミチルリ
ンゴ酸アミドナトリウム、モノ−Ｎ−デシルリンゴ酸ア
ミド、モノ−Ｎ−デシルリンゴ酸アミドカリウム、モノ
−Ｎ−デシルリンゴ酸アミドナトリウム、モノ−Ｎ−オ
レイルリンゴ酸アミド、モノ−Ｎ−オレイルリンゴ酸ア
ミドナトリウム、モノ−Ｎ−デシル酒石酸アミド、モノ
−Ｎ−デシル酒石酸アミドナトリウム、モノ−Ｎ−デシ
ル酒石酸アミドカリウムなどが挙げられ、これらは１種
単独で又は２種以上を適宜組み合わせて用いることがで
きる。なお、光学異性体は単独でもラセミ体でも良い。More specifically, the above-mentioned (A) amidocarboxylic acid or a salt thereof of the present invention is, more specifically, mono-N-laurylmalic acid amide, mono-N-laurylmalic acid potassium amide, mono-N-laurylmalic acid. Sodium amide,
Mono-N-laurylmalic acid amide diethanolamine, mono-N-laurylmalic acid amide triethanolamine, N-methyl-N-laurylmalic acid amide potassium, mono-N-myristylmalic acid amide, mono-N
-Potassium myristylmalic acid amide, sodium mono-N-myristylmalic acid amide, mono-N-myristylmalic acid amide diethanolamine, mono-N-myristylmalic acid amide triethanolamine, mono-N
-Palmitylmalic acid amide, mono-N-palmitylmalic acid sodium amide, mono-N-decylmalic acid amide, mono-N-decylmalic acid amide potassium, mono-N-decylmalic acid amide sodium, mono-N-oleyl apple Acid amide, sodium mono-N-oleyl malic acid amide, mono-N-decyl tartaric acid amide, sodium mono-N-decyl tartaric acid amide, potassium mono-N-decyl tartaric acid amide, etc. These may be used alone or Two or more kinds can be used in appropriate combination. The optical isomers may be single or racemic.
【００１９】本発明の液体洗浄剤組成物におけるこれら
（Ａ）成分のアミドカルボン酸又はその塩の配合量は、
特に制限されるものではないが、通常、好ましくは組成
物全量に対して、１〜５０％（質量％、以下同様）、よ
り好ましくは１〜３０％が好適である。（Ａ）成分の配
合量が１％未満では、十分な洗浄力が得られ難い場合が
あり、しかもすすぎ時にさっぱり感、使用後につっぱり
感を与える効果が低くなる場合がある。一方、５０％を
超えて配合しても、それ以上の顕著な洗浄力の向上効果
が得られなかったり、すすぎ時のさっぱり感及び使用後
につっぱり感を与える更なる効果がないものとなる場合
がある。The amount of the amidocarboxylic acid or salt thereof as the component (A) in the liquid detergent composition of the present invention is
Although not particularly limited, it is usually preferably 1 to 50% (mass%, the same applies hereinafter), and more preferably 1 to 30% with respect to the total amount of the composition. When the content of the component (A) is less than 1%, it may be difficult to obtain sufficient detergency, and the effect of giving a feeling of freshness during rinsing and a feeling of tightness after use may be reduced. On the other hand, even if it is blended in an amount exceeding 50%, it may not be possible to obtain a further remarkable effect of improving the detergency, or there may be no further effect of giving a feeling of freshness during rinsing and a feeling of tightness after use. is there.
【００２０】本発明の液体洗浄剤組成物の（Ｂ）成分
は、疎水基に分岐鎖を有するアニオン性界面活性剤、疎
水基に分岐鎖を有するノニオン性界面活性剤から選ばれ
る１種又は２種以上である。ここで、分岐鎖を有する疎
水基としては、例えば炭素数が好ましくは７〜２４、よ
り好ましくは７〜２２の飽和又は不飽和の鎖状炭化水素
基であって、その炭素鎖中に好ましくは１又は２、より
好ましくは１の分岐鎖を有する分岐炭化水素基、炭素数
が好ましくは３〜２２、より好ましくは７〜１８の飽和
又は不飽和の鎖状炭化水素基であって、その炭素鎖中に
好ましくは１又は２、より好ましくは１の分岐鎖を有す
る分岐炭化水素基を側鎖にもつ炭素数が好ましくは３〜
９、より好ましくは５又は６の環状炭化水素基又は芳香
族炭化水素基などを挙げることができる。The component (B) of the liquid detergent composition of the present invention is one or two selected from anionic surfactants having a branched chain in the hydrophobic group and nonionic surfactants having a branched chain in the hydrophobic group. More than a seed. Here, the hydrophobic group having a branched chain is, for example, a saturated or unsaturated chain hydrocarbon group having preferably 7 to 24 carbon atoms, more preferably 7 to 22 carbon atoms, and preferably in the carbon chain. A branched hydrocarbon group having a branched chain of 1 or 2, more preferably 1, a saturated or unsaturated chain hydrocarbon group having a carbon number of preferably 3 to 22, more preferably 7 to 18, The number of carbon atoms having a branched hydrocarbon group having a branched chain of preferably 1 or 2, and more preferably 1 in the chain in the side chain is preferably 3 to
9, more preferably 5 or 6 cyclic hydrocarbon groups or aromatic hydrocarbon groups can be mentioned.
【００２１】このような分岐鎖を有する疎水基をもつア
ニオン性界面活性剤、ノニオン性界面活性剤の具体例と
しては、アニオン性界面活性剤では、イソステアリン酸
カリウム、イソステアリン酸ナトリウム、イソステアリ
ン酸トリエタノールアミン、２−オクチルドデカン酸カ
リウム、２−オクチルドデカン酸ナトリウム、２−エチ
ルヘキサン酸カリウム、２−エチルヘキサン酸ナトリウ
ム、イソノナン酸カリウム、イソノナン酸ナトリウムな
どの脂肪酸の炭素数が８〜２２の分岐脂肪酸塩（カルボ
ン酸塩）、２−エチルヘキシル硫酸ナトリウムなどのア
ルキル基の炭素数が７〜２１の硫酸分岐アルキル塩、イ
ソステアロイル乳酸ナトリウムなどの脂肪酸の炭素数が
８〜２２の分岐脂肪酸の乳酸エステル塩などが挙げられ
る。上記分岐脂肪酸塩は、そのものを配合しても良い
し、又は、液体洗浄剤組成物中に脂肪酸とアルカリをそ
れぞれ別に配合して、中和して用いても良い。Specific examples of the anionic surfactant and nonionic surfactant having a hydrophobic group having such a branched chain include anionic surfactants such as potassium isostearate, sodium isostearate, and triethanol isostearate. A branched fatty acid having 8 to 22 carbon atoms in fatty acid such as amine, potassium 2-octyldodecanoate, sodium 2-octyldodecanoate, potassium 2-ethylhexanoate, sodium 2-ethylhexanoate, potassium isononanoate, sodium isononanoate. Salt (carboxylic acid salt), 2-ethylhexyl sodium sulfate, etc., alkyl sulfate having 7 to 21 carbon atoms, branched alkyl salt, fatty acid, such as sodium isostearoyl lactate, fatty acid, lactic acid ester salt, having 8 to 22 carbon atoms And so on. The branched fatty acid salt may be blended as it is, or may be neutralized by blending a fatty acid and an alkali in the liquid detergent composition separately.
【００２２】一方、ノニオン性界面活性剤では、ポリオ
キシエチレン（５）イソステアリルエーテル，ポリオキ
シエチレン（１５）イソステアリルエーテル等のエチレ
ンオキサイドの平均付加モル数が５〜１５のポリオキシ
エチレンイソステアリルエーテル、ポリオキシエチレン
（１０）オクチルドデシルエーテル，ポリオキシエチレ
ン（５）オクチルドデシルエーテル等のエチレンオキサ
イドの平均付加モル数が３〜２５のポリオキシエチレン
オクチルドデシルエーテルなどのアルキル基の炭素数が
８〜２２の分岐アルキルポリオキシエチレンエーテル、
イソステアリン酸ポリエチレングリコール等のエチレン
オキサイドの平均付加モル数が３〜６０、脂肪酸の炭素
数が８〜２２の分岐脂肪酸ポリエチレングリコール、イ
ソステアリン酸ポリオキシエチレングリセリル，イソパ
ルミチン酸グリセリル等のエチレンオキサイドの平均付
加モル数が３〜６０、脂肪酸の炭素数が８〜２２の分岐
脂肪酸グリセリル、イソステアリン酸ポリオキシエチレ
ン硬化ヒマシ油，ピログルタミン酸イソステアリン酸ポ
リオキシエチレン硬化ヒマシ油等のエチレンオキサイド
の平均付加モル数が３〜６０、脂肪酸の炭素数が８〜２
２の分岐脂肪酸ポリオキシエチレン硬化ヒマシ油、イソ
ステアリン酸モノイソプロパノールアミド等の脂肪酸の
炭素数が８〜２２の分岐脂肪酸アルコールエステルなど
が挙げられ、これらは１種単独で又は２種以上を適宜組
み合わせて用いることができる。On the other hand, as the nonionic surfactant, polyoxyethylene isostearyl having an average addition mole number of ethylene oxide of 5 to 15 such as polyoxyethylene (5) isostearyl ether and polyoxyethylene (15) isostearyl ether is used. The average number of moles of ethylene oxide added such as ether, polyoxyethylene (10) octyldodecyl ether, polyoxyethylene (5) octyldodecyl ether is 3 to 25, and the number of carbon atoms of the alkyl group such as polyoxyethylene octyldodecyl ether is 8 ~ 22 branched alkyl polyoxyethylene ethers,
Average addition of ethylene oxide such as polyethylene glycol isostearate Average number of addition of ethylene oxide such as branched fatty acid polyethylene glycol having 3 to 60 moles of fatty acid and 8 to 22 carbon atoms of fatty acid, polyoxyethylene glyceryl isostearate, glyceryl isopalmitate and the like The average number of moles of ethylene oxide added is 3 to 60, branched fatty acid glyceryl having 8 to 22 carbon atoms in fatty acid, polyoxyethylene hydrogenated castor oil isostearate, and polyoxyethylene hydrogenated castor oil isostearate pyroglutamate. ~ 60, fatty acid has 8 to 2 carbon atoms
2 branched fatty acid polyoxyethylene hydrogenated castor oil, branched fatty acid alcohol ester having 8 to 22 carbon atoms of fatty acid such as isostearic acid monoisopropanolamide, and the like. These may be used alone or in combination of two or more. Can be used.
【００２３】これらの中でも、本発明の（Ｂ）成分とし
ては、特にイソステアリン酸カリウム、イソステアリン
酸ナトリウム、ポリオキシエチレン（５）イソステアリ
ルエーテル、イソステアリン酸ポリエチレングリコール
等が、洗浄力、使用性の点からより好ましい。Among these, as the component (B) of the present invention, potassium isostearate, sodium isostearate, polyoxyethylene (5) isostearyl ether, polyethylene glycol isostearate and the like are used in view of detergency and usability. To more preferred.
【００２４】本発明の液体洗浄剤組成物におけるこれら
（Ｂ）成分の疎水基に分岐鎖を有することを特徴とする
アニオン性界面活性剤、ノニオン性界面活性剤から選ば
れる１種又は２種以上の配合量は、特に制限されるもの
ではないが、通常、組成物全量に対して、好ましくは
０．２〜３０％、より好ましくは０．５〜２０％、更に
好ましくは０．５〜１５％である。（Ｂ）成分の配合量
が０．２％未満では、十分な洗浄力が得られ難くなる場
合があり、しかも低温での使用性を向上させる効果が低
くなる場合がある。一方、３０％を超えて配合しても、
それ以上の顕著な洗浄力の向上効果が得られない場合が
あったり、低温での使用性を与える更なる効果がないも
のとなる場合がある。One or more selected from anionic surfactants and nonionic surfactants characterized in that the hydrophobic group of the component (B) in the liquid detergent composition of the present invention has a branched chain. The compounding amount of is not particularly limited, but is usually preferably 0.2 to 30%, more preferably 0.5 to 20%, further preferably 0.5 to 15% with respect to the total amount of the composition. %. If the content of the component (B) is less than 0.2%, it may be difficult to obtain sufficient detergency, and the effect of improving usability at low temperatures may be reduced. On the other hand, even if it exceeds 30%,
In some cases, a more remarkable effect of improving the detergency may not be obtained, or there may be no further effect of providing usability at low temperatures.
【００２５】本発明の液体洗浄剤組成物には、本発明の
効果を損なわない限り、上記必須成分以外にも、通常洗
浄剤に配合される各種添加剤を用いることができる。こ
れら添加剤としては、例えば（Ｂ）成分以外のアニオン
性界面活性剤，ノニオン性界面活性剤、両性界面活性
剤、半極性界面活性剤、アルコール類、水溶性高分子化
合物、油剤、薬剤、殺菌剤、酸化防止剤、金属イオン封
鎖剤、香料、色素類などが挙げられる。In the liquid detergent composition of the present invention, various additives usually added to detergents can be used in addition to the above essential components, as long as the effects of the present invention are not impaired. Examples of these additives include anionic surfactants other than component (B), nonionic surfactants, amphoteric surfactants, semipolar surfactants, alcohols, water-soluble polymer compounds, oil agents, drugs, sterilizers. Agents, antioxidants, sequestering agents, perfumes, dyes and the like.
【００２６】本発明の液体洗浄剤組成物は、洗顔剤，身
体用洗浄剤（ボディソープ等）等の皮膚用洗浄剤、毛髪
用洗浄剤（シャンプー等）などとして使用することがで
き、その剤型も液体であれば、特に制限されるものでは
なく、例えばクリーム状、エマルション状、ジェル状等
とすることができるが、特にフォーマー容器に充填して
使用すると、低温下でも均質でクリーミィな泡が得ら
れ、しかもクラフト点が高く、溶解性が良いため、目詰
まりが生じることもないので、より効果的である。The liquid detergent composition of the present invention can be used as a facial cleanser, a detergent for the skin such as a detergent for the body (body soap etc.), a detergent for the hair (shampoo etc.) and the like. The mold is not particularly limited as long as it is a liquid, and may be cream-like, emulsion-like, gel-like, or the like, but when it is used by filling it in a former container, it is a homogeneous and creamy foam even at low temperature. It is more effective because it has a high Kraft point and a good solubility, and thus does not cause clogging.
【００２７】ここで、フォーマー容器とは、単数又は複
数の一定の孔径を有する多孔体を用い、所定の割合で液
体洗浄剤組成物と空気とを混合し、該液体洗浄剤組成物
を泡状態として吐出させるものである。これによりクリ
ーミィな泡を形成することができ、洗浄時に良好な使用
感を得ることができる。多孔体としては、ネット、スポ
ンジなどが挙げられるが、目詰まり解消の点からネット
を用いることが好ましい。ネットのメッシュとしては、
好ましくは５０〜５００メッシュ、更に好ましくは１０
０〜４００メッシュである。さらにこのネットを複数枚
用いることが好ましく、特に泡形成性や使用性の点から
２枚又は３枚使用することが好ましい。Here, the former container is a porous body having a single or plural constant pore size, and the liquid detergent composition and air are mixed at a predetermined ratio to foam the liquid detergent composition. Is discharged. As a result, creamy foam can be formed and a good feeling of use can be obtained during washing. Examples of the porous body include nets and sponges, but it is preferable to use nets from the viewpoint of eliminating clogging. As a net mesh,
Preferably 50-500 mesh, more preferably 10
It is 0 to 400 mesh. Further, it is preferable to use a plurality of the nets, and it is particularly preferable to use two or three nets from the viewpoint of foam forming property and usability.
【００２８】本発明の液体洗浄剤組成物をフォーマー容
器に充填する場合、上記のように泡を形成することがで
きる容器であれば、その種類は特に制限されるものでは
なく、公知の各種フォーマー容器を好適に使用すること
ができるが、これらの中でも、使用性の点を考慮すれ
ば、キャップの頭部を手指で押圧することにより使用す
るポンプ式フォーマーがより好ましい。When the liquid detergent composition of the present invention is filled in a former container, the kind thereof is not particularly limited as long as it is a container capable of forming bubbles as described above, and various known formers. Although a container can be preferably used, among these, a pump former that is used by pressing the head of the cap with fingers is more preferable in consideration of usability.
【００２９】また、本発明の液体洗浄剤組成物をフォー
マー容器に充填して使用する場合、低粘度であることが
望ましい。従って、本発明の液体洗浄組成物をフォーマ
ー容器に充填したフォーマー用液体洗浄剤組成物として
使用する場合、液体洗浄剤組成物の粘度は、好ましくは
１〜５０ｃＰ（２５℃）であり、より好ましくは１〜１
０ｃＰ（２５℃）である。この範囲を超えると常温時と
低温時とで異なった泡が形成される場合がある。なお、
本発明の液体洗浄剤組成物の粘度を上記の好適な範囲に
調整する手段は、特に制限されるものではなく、例えば
一価及び／又は多価アルコール類を添加するなどの手段
によって調整すると、好適である。When the liquid detergent composition of the present invention is used by filling it in a former container, it is desirable that it has a low viscosity. Therefore, when the liquid cleaning composition of the present invention is used as a liquid cleaning composition for a former filled in a former container, the viscosity of the liquid cleaning composition is preferably 1 to 50 cP (25 ° C), and more preferably Is 1 to 1
It is 0 cP (25 ° C.). If it exceeds this range, different bubbles may be formed at room temperature and at low temperature. In addition,
Means for adjusting the viscosity of the liquid detergent composition of the present invention to the above-mentioned preferred range is not particularly limited, and for example, when adjusted by means such as adding monohydric and / or polyhydric alcohols, It is suitable.
【００３０】本発明の液体洗浄剤組成物の調製方法は、
特に制限されるものではなく、各剤型の常法に準じて調
製することができる。また、使用方法も特に制限される
ものではなく、通常の洗顔剤、身体用洗浄剤、毛髪用洗
浄剤などの使用方法と同様に使用することができる。The method for preparing the liquid detergent composition of the present invention is as follows:
It is not particularly limited, and it can be prepared according to a conventional method for each dosage form. Further, the method of use is not particularly limited, and it can be used in the same manner as a usual facial cleanser, body cleanser, hair cleanser and the like.
【００３１】[0031]
【発明の効果】本発明の液体洗浄剤組成物によれば、皮
膚や毛髪に対して低刺激であり、且つすすぎ時には、さ
っぱり感を有し、例えば口紅等のメイクの汚れを良好に
洗浄することができる。特に本発明の液体洗浄剤組成物
をフォーマー容器に充填して用いた場合、泡質等の泡形
成性に優れ、低温下でも均質でクリーミィな泡を形成で
きるのみならず、目詰まりも生じないので、さらに良好
な使用感を得ることができる。EFFECTS OF THE INVENTION According to the liquid detergent composition of the present invention, it is a mild stimulant to the skin and hair, and has a refreshing feeling at the time of rinsing, and cleans makeup stains such as lipstick. be able to. In particular, when the liquid detergent composition of the present invention is used by filling it in a former container, it is excellent in foam-forming property such as foam quality, can form a homogeneous and creamy foam even at low temperature, and does not cause clogging. Therefore, a better usability can be obtained.
【００３２】[0032]
【実施例】以下、実施例及び比較例を示し、本発明をよ
り具体的に説明するが、本発明は、下記実施例に制限さ
れるものではない。なお、下記表中の％は、いずれも質
量％である。EXAMPLES The present invention will be described in more detail below by showing Examples and Comparative Examples, but the present invention is not limited to the following Examples. In addition, all% in the following table are mass%.
【００３３】［実施例１〜１５及び比較例１〜６］表１
〜３に示す組成に従って実施例１〜１５及び比較例１〜
６の洗顔剤（液体洗浄剤組成物）を常法に準じて調製し
た。各液体洗浄剤組成物について、それぞれポンプ式フ
ォーマー容器に充填し、次いで、以下の性能評価を行っ
た。結果を表１〜３に併記する。なお、表中のポンプ式
フォーマー容器ａとしては、吉野工業（株）製フォーマ
ー容器（特開平７−３１５４６３号公報記載の泡放出用
ポンプ容器に準じる）（ネット：２００メッシュ、１
枚）を、また、同じく容器ｂとしては、吉野工業（株）
製フォーマー容器（特開平８−２３０９６１号公報記載
の泡放出用ポンプ容器に準じる）（ネット：２００メッ
シュ、２枚）を用いた。[Examples 1 to 15 and Comparative Examples 1 to 6] Table 1
Examples 1 to 15 and Comparative Examples 1 to 3 according to the compositions shown in FIGS.
The facial cleanser (liquid detergent composition) of 6 was prepared according to a conventional method. Each liquid detergent composition was filled in a pump type former container, and then the following performance evaluation was performed. The results are also shown in Tables 1 to 3. In addition, as the pump type former container a in the table, a former container manufactured by Yoshino Industry Co., Ltd. (according to the foam discharging pump container described in JP-A-7-315463) (net: 200 mesh, 1
Sheet) and also as the container b, Yoshino Industry Co., Ltd.
A former container (according to the foam discharging pump container described in JP-A-8-230961) (net: 200 mesh, 2 sheets) was used.
【００３４】＜性能評価＞
〈洗浄力〉女性２０名（専門パネラー）が、前記ａ又は
ｂのポンプ式フォーマー容器に充填した上記実施例、比
較例の洗顔剤（液体洗浄剤組成物）を使用して、通常行
っているように洗顔した後、下記判断基準に従ってメイ
ク落とし効果を官能的に比較し、５点満点で採点を行っ
た。また、その評価点の合計により下記判定基準で評価
を行った。<Performance Evaluation><Detergency> Twenty women (specialist panelists) used the facial cleanser (liquid detergent composition) of the above-mentioned Examples and Comparative Examples filled in the pump former container of a or b. Then, after washing the face as usual, the sensory comparison of the makeup removing effect was carried out according to the following criteria, and a score was given on a scale of 5 points. In addition, evaluation was performed according to the following criteria based on the total of the evaluation points.
【００３５】＜判断基準＞ ５点：非常に良く落ちる ４点：良く落ちる ３点：落ちる ２点：やや落ちにくい １点：水洗いと同様<Judgment criteria> 5 points: Fall very well 4 points: falls well 3 points: fall 2 points: Somewhat hard to fall off 1 point: similar to washing with water
【００３６】＜判定基準＞ ◎：評価点の合計が７５点以上 ○：評価点の合計が５０点以上７４点以下 △：評価点の合計が３０点以上４９点以下 ×：評価点の合計が２９点以下<Judgment criteria> ⊚: Total score of 75 or more ○: The total of evaluation points is 50 points or more and 74 points or less △: Total of evaluation points is 30 points or more and 49 points or less X: Total score of 29 or less
【００３７】〈泡形成性〉各液体洗浄剤組成物をａ又は
ｂのポンプ式フォーマー容器に入れ、数回押し出したと
きの泡の質を下記評価基準に従って目視で判定した。<Foam Formability> Each liquid detergent composition was placed in a pump former container a or b, and the quality of the foam when extruded several times was visually evaluated according to the following evaluation criteria.
【００３８】＜評価基準＞ ◎：泡が均質でクリーミィ ○：大きな泡が少し混じる △：大きな泡がやや混じる ×：大きな泡が非常に多い<Evaluation criteria> ◎: The foam is homogeneous and creamy ○: A large bubble is mixed a little △: Large bubbles are mixed a little ×: Very large bubbles
【００３９】〈低温使用性〉各液体洗浄剤組成物をａ又
はｂのポンプ式フォーマー容器に入れ、５℃で２４時間
保存した後、ポンプを１０回押し、その時のポンプ詰ま
りの有無等を下記評価基準に従って評価した。<Low Temperature Usability> Each liquid detergent composition was placed in a pump former container of a or b and stored at 5 ° C. for 24 hours, and then the pump was pushed 10 times. It evaluated according to the evaluation criteria.
【００４０】＜評価基準＞ ◎：ポンプ詰まりがなく、軽い力で押すことができる ○：ポンプ詰まりはないが、若干力を要する △：若干ひっかかりがある ×：詰まる<Evaluation criteria> ◎: Can be pushed with light force without pump clogging ○: Pump is not clogged, but requires some force △: There is some catch ×: clogged
【００４１】〈肌へのマイルド性〉女性２０名（専門パ
ネラー）が、ａ又はｂのポンプ式フォーマー容器に充填
した上記実施例、比較例の洗顔剤（液体洗浄剤組成物）
を使用して通常の方法で洗顔した後、肌へのマイルド性
を官能的に比較した。また、その結果を下記評価基準に
より評価した。<Mildness to Skin> Facial cleanser (liquid detergent composition) of the above-mentioned Examples and Comparative Examples in which 20 females (specialized panelists) filled the pump former container of a or b
After washing the face in the usual manner using the, the sensory comparison of mildness to the skin was performed. Moreover, the result was evaluated according to the following evaluation criteria.
【００４２】＜評価基準＞ ◎：マイルドであると答えた人が１５人以上 ○：マイルドであると答えた人が１０人以上１４人以下 △：マイルドであると答えた人が６人以上９人以下 ×：マイルドであると答えた人が５人以下<Evaluation criteria> ◎: More than 15 people answered that they are mild ○: 10 to 14 people who answered mild △: 6 to 9 people who answered mild ×: 5 or less people answered mild
【００４３】〈すすぎ時のさっぱり感〉女性２０名（専
門パネラー）が、前記ａ又はｂのポンプ式フォーマー容
器に充填した上記実施例、比較例の洗顔剤（液体洗浄剤
組成物）を使用して通常の方法で洗顔した後、下記判断
基準ですすぎ時のさっぱり感を官能的に比較し、５点満
点で採点を行った。また、その評価点の合計により下記
判定基準で評価を行った。<Refreshing sensation during rinsing> Twenty women (specialist panelists) used the facial cleansers (liquid detergent compositions) of the above-mentioned Examples and Comparative Examples filled in the pump former containers a or b. After washing the face in the usual manner, the sensory comparison of the refreshing feeling when rinsing was performed based on the following criteria, and a score was given on a scale of 5 points. In addition, evaluation was performed according to the following criteria based on the total of the evaluation points.
【００４４】＜判断基準＞ ５点：非常にさっぱり感がある ４点：かなりさっぱり感がある ３点：ややさっぱり感がある ２点：ほとんどさっぱり感がない １点：全くさっぱり感がない<Judgment criteria> 5 points: Very refreshing 4 points: There is a refreshing feeling 3 points: Somewhat refreshing 2 points: Almost no feeling 1 point: No feeling at all
【００４５】＜判定基準＞ ◎：評価点の合計が７５点以上 ○：評価点の合計が５０点以上７４点以下 △：評価点の合計が３０点以上４９点以下 ×：評価点の合計が２９点以下<Criteria> ⊚: Total score of 75 or more ○: The total of evaluation points is 50 points or more and 74 points or less △: Total of evaluation points is 30 points or more and 49 points or less X: Total score of 29 or less
【００４６】[0046]
【表１】 [Table 1]
【００４７】[0047]
【表２】 [Table 2]
【００４８】[0048]
【表３】 [Table 3]
【００４９】表１〜３の結果から明らかなように、本発
明の実施例１〜１５の液体洗浄剤組成物は、本発明の
（Ａ）成分であるアミドカルボン酸又はその塩と、
（Ｂ）成分の疎水基に分岐鎖を有することを特徴とする
アニオン性界面活性剤、ノニオン性界面活性剤から選ば
れる１種又は２種以上とを併用しない比較例１〜６の液
体洗浄剤組成物に比べて、皮膚にマイルドで、且つすす
ぎ時のさっぱり感及び洗浄力に優れ、しかも低温での使
用性が良好であることが認められる。これに対して、比
較例１〜６では、本発明の目的とする効果を達成できな
いことが認められる。As is clear from the results shown in Tables 1 to 3, the liquid detergent compositions of Examples 1 to 15 of the present invention were prepared by using the amidocarboxylic acid or salt thereof as the component (A) of the present invention.
Liquid detergents of Comparative Examples 1 to 6 which do not use in combination with one or more selected from anionic surfactants and nonionic surfactants characterized in that the hydrophobic group of the component (B) has a branched chain. It is recognized that the composition is mild to the skin, has a refreshing feeling at the time of rinsing, and has excellent detergency as compared with the composition, and has good usability at low temperatures. On the other hand, it is recognized that Comparative Examples 1 to 6 cannot achieve the intended effect of the present invention.
【００５０】［実施例１６〜２５］下記表４〜１３に示
す組成に従って実施例１６〜２５の液体洗浄剤組成物
（ボディソープ、クレンジングジェル、クリーム状洗顔
剤、液体洗顔剤、シャンプー、フォーマー容器用洗顔
剤、フォーマー容器用ボディソープ、フォーマー容器用
シャンプー、クレンジングミルク）を常法に準じて調製
し、より具体的な組成からなる実施例を得た。[Examples 16 to 25] Liquid detergent compositions of Examples 16 to 25 (body soap, cleansing gel, creamy face wash, liquid face wash, shampoo, foamer container) according to the compositions shown in Tables 4 to 13 below. A face cleanser, a body soap for a foamer container, a shampoo for a foamer container, and a cleansing milk) were prepared according to a conventional method, and Examples having more specific compositions were obtained.
【００５１】これらの液体洗浄剤組成物は、上記と同様
の評価法で評価したところ、いずれも洗浄力（◎）、泡
形成性（実施例２１〜２４のみ）（◎）、低温使用性
（実施例２１〜２４のみ）（◎）、肌へのマイルド性
（◎）及びすすぎ時のさっぱり感（◎）に優れているこ
とがわかった。When these liquid detergent compositions were evaluated by the same evaluation method as described above, they were all found to have detergency (⊚), foam forming property (Examples 21 to 24 only) (⊚), and low temperature usability (∘). It was found that Examples 21 to 24 only) (⊚), mildness to the skin (⊚), and a refreshing feeling at the time of rinsing (⊚) were excellent.
【００５２】[0052]
【表４】 [Table 4]
【００５３】[0053]
【表５】 [Table 5]
【００５４】[0054]
【表６】 [Table 6]
【００５５】[0055]
【表７】 [Table 7]
【００５６】[0056]
【表８】 [Table 8]
【００５７】[0057]
【表９】 [Table 9]
【００５８】[0058]
【表１０】 [Table 10]
【００５９】[0059]
【表１１】 [Table 11]
【００６０】[0060]
【表１２】 [Table 12]
【００６１】[0061]
【表１３】 [Table 13]
【００６２】上記表中の＊１〜４３は、下記の通りであ
る。
＊１ エマレックスＯＤ−５（日本エマルジョン製）
＊２ アミノソープＡＲ−１１（味の素製）
＊３ アミソフトＬＫ−１２（味の素製）
＊４ サンノールＬＭＴ−１４３０（ライオン化学製）
＊５ アミライトＣＧＫ−１２（味の素製）
＊６ エナジコールＤＰ−３０（ライオン化学製）
＊７ ＮＩＫＫＯＬ ＡＭ−３０１（日光ケミカルズ
製）
＊８ エナジコールＬ−３０Ｂ（ライオン化学製）
＊９ アロモックスＤＭ１２ＤＷ（Ｃ）（ライオン化学
製）
＊１０ ソフタミン ＬＤ（東邦化学工業製）
＊１１ エマレックス７０３（日本エマルジョン製）
＊１２ エマレックス７０９（日本エマルジョン製）
＊１３ エマレックス１０２（日本エマルジョン製）
＊１４ エマレックスＰＧＭＬ（日本エマルジョン製）
＊１５ エマレックスＨＣ−３０（日本エマルジョン
製）
＊１６ メトローズＳＭ１５００（信越化学工業製）
＊１７ メトロ−ズＳＥＢ０４Ｔ（信越化学工業製）
＊１８ メトロ−ズ６０ＳＨ５０（信越化学工業製）
＊１９ カラギニン ＣＳＫ−１（三栄源エフ・エフ・
アイ社製）
＊２０ ネオソフトＧ−１１（太陽化学社製）
＊２１ レオアールＭＳ２００（ライオン化学製）
＊２２ カーボポール１３４２（ＢＦグッドリッチ製）
＊２３ アキュリン２２（ローム・アンド・ハース製）
＊２４ レオガードＧＰ（ライオン化学製）
＊２５ ルビカットＦＣ３７０（ＢＡＳＦ製）
＊２６ マーコート５５０（カルゴン製）
＊２７ マーコートプラス３３３０（カルゴン製）
＊２８ ＳＨ２００−１０，０００ｃｓ（東レ・ダウコ
ーニング・シリコーン製）
＊２９ クニピアＧ（クニミネ工業社製）
＊３０ メトロ−ズ６５ＳＨ１５００（信越化学工業
製）＊３１ ペミュレンＴＲ−２（ＢＦグッドリッチ
製）
＊３２ ソイポンＳＬＥ（川研ファインケミカル製）
＊３３ ポリオックスＷＳＲ−７５０（ユニオンカーバ
イド製）
＊３４ ＳＨ５５６（東レ・ダウコーニング・シリコー
ン製）
＊３５ レオアールＭＳ１００（ライオン化学製）
＊３６ ソフタゾリン ＨＬ−Ｒ（川研ファインケミカ
ル製）
＊３７ オクトピロックス（クラリアント・ジャパン社
製）
＊３８ ＮＩＫＫＯＬ ＬＭＴ（日光ケミカルズ製）
＊３９ ソフダゾリンＬＳＢ（川研ファインケミカル
製）
＊４０ ＳＭ８７０２Ｃ（東レ・ダウコーニング・シリ
コーン製）
＊４１ ＢＹ２２−００９（東レ・ダウコーニング・シ
リコーン製）
＊４２ ソフタミン Ｃ−３（東邦化学工業製）
＊４３ エマレックス６１１（日本エマルジョン製）* 1 to 43 in the above table are as follows. * 1 Emalex OD-5 (manufactured by Nippon Emulsion) * 2 Aminosoap AR-11 (manufactured by Ajinomoto) * 3 Amisoft LK-12 (manufactured by Ajinomoto) * 4 Sannor LMT-1430 (manufactured by Lion Kagaku) * 5 Amylite CGK-12 (Ajinomoto) * 6 Enajikol DP-30 (Lion Kagaku) * 7 NIKKOL AM-301 (Nikko Chemicals) * 8 Enajikol L-30B (Lion Kagaku) * 9 Aromox DM12DW (C) (Lion Kagaku) * 10 Softan LD (Toho Chemical Industry) * 11 Emarex 703 (Nippon Emulsion) * 12 Emarex 709 (Nippon Emulsion) * 13 Emalex 102 (Nippon Emulsion) * 14 Emalex PGML (Nippon Emulsion) * 15 Emalex HC-30 (Nippon Emulsion) * 16 Metrose SM1500 (Shin-Etsu Chemical Co., Ltd.) * 17 Metro-SE SEB04T (Shin-Etsu Chemical Co., Ltd.) * 18 Metro-S 60SH50 (Shin-Etsu Chemical Co., Ltd.) * 19 Carrageenin CSK-1 (San-ei Gen F. F
Ai) * 20 Neosoft G-11 (Taiyo Kagaku) * 21 Leoard MS200 (Lion Kagaku) * 22 Carbopol 1342 (BF Goodrich) * 23 Akyrin 22 (Rohm and Haas) * 24 Leoguard GP (manufactured by Lion Chemical) * 25 Rubicat FC370 (manufactured by BASF) * 26 Marcoat 550 (manufactured by Calgon) * 27 Marcoat Plus 3330 (manufactured by Calgon) * 28 SH200-10,000cs (manufactured by Toray Dow Corning Silicone) * 29 Kunipia G (manufactured by Kunimine Industry Co., Ltd.) * 30 Metro-S 65SH1500 (manufactured by Shin-Etsu Chemical Co., Ltd.) * 31 Pemulen TR-2 (manufactured by BF Goodrich) * 32 Soypon SLE (manufactured by Kawaken Fine Chemicals) * 33 Polyox WSR-750 (Union Carby * 34 SH556 (Toray Dow Corning Silicone) * 35 Leoard MS100 (Lion Chemical) * 36 Sofazoline HL-R (Kawaken Fine Chemicals) * 37 Octopirox (Clariant Japan) * 38 NIKKOL LMT (manufactured by Nikko Chemicals) * 39 Sofdazoline LSB (manufactured by Kawaken Fine Chemicals) * 40 SM8702C (manufactured by Toray Dow Corning Silicone) * 41 BY22-009 (manufactured by Toray Dow Corning Silicone) * 42 Softamine C-3 (Toho) Chemical Industry) * 43 Emarex 611 (Nippon Emulsion)
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ テーマコート゛(参考） Ｃ１１Ｄ 1/10 Ｃ１１Ｄ 1/10 1/72 1/72 17/04 17/04 Ｆターム(参考） 4C083 AA11 AA122 AB33 AB35 AB432 AC022 AC102 AC122 AC132 AC182 AC262 AC30 AC31 AC312 AC342 AC39 AC392 AC402 AC422 AC432 AC48 AC532 AC552 AC58 AC641 AC642 AC662 AC69 AC712 AC782 AC812 AC85 AC892 AD042 AD092 AD132 AD152 AD262 AD282 AD352 AD41 AD532 BB04 BB05 BB21 BB41 CC23 DD23 DD31 DD41 DD47 EE06 EE10 4H003 AB03 AB06 AB09 AB10 AB31 AC08 AC15 AC16 AD02 AD04 BA12 BA21 DA02 EA27 EB05 EB06 EB07 EB16 EB24 EB25 EB37 EB41 EB42 EB43 EB46 ED02 ED28 ED29 FA02 FA16 FA18 FA21 FA26 FA34 ─────────────────────────────────────────────────── ─── Continued Front Page (51) Int.Cl. 7 Identification Code FI Theme Coat (Reference) C11D 1/10 C11D 1/10 1/72 1/72 17/04 17/04 F Term (Reference) 4C083 AA11 AA122 AB33 AB35 AB432 AC022 AC102 AC122 AC132 AC182 AC262 AC30 AC31 AC312 AC342 AC39 AC392 AC402 AC422 AC432 AC48 AC532 AC552 AC58 AC641 AC642 AC662 AC69 AC712 AC782 AC812 AC85 AC892 AD042 AD092 AD132 AD152 AD262 AD282 AD352 AD41 AD532 BB04 BB31 BB05 BB05 BB05 BB05 BB05 EE06 EE10 4H003 AB03 AB06 AB09 AB10 AB31 AC08 AC15 AC16 AD02 AD04 BA12 BA21 DA02 EA27 EB05 EB06 EB07 EB16 EB24 EB25 EB37 EB41 EB42 EB43 EB46 ED02 ED28 ED29 FA02 FA16 FA18 FA21 FA26 FA34
Claims (2)
とを特徴とする液体洗浄剤組成物。 （Ａ）下記一般式（Ｉ）で表されるアミドカルボン酸又
はその塩 【化１】 （Ｂ）疎水基に分岐鎖を有するアニオン性界面活性剤及
びノニオン性界面活性剤から選ばれる１種又は２種以上1. A liquid detergent composition comprising the following (A) and (B): (A) Amidocarboxylic acid represented by the following general formula (I) or a salt thereof: (B) One or more selected from anionic surfactants and nonionic surfactants having a branched chain in the hydrophobic group
載の液体洗浄剤組成物。2. The liquid detergent composition according to claim 1, which is filled in a former container.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001248774A JP5041113B2 (en) | 2001-08-20 | 2001-08-20 | Liquid detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001248774A JP5041113B2 (en) | 2001-08-20 | 2001-08-20 | Liquid detergent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2003055699A true JP2003055699A (en) | 2003-02-26 |
| JP5041113B2 JP5041113B2 (en) | 2012-10-03 |
Family
ID=19077878
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001248774A Expired - Fee Related JP5041113B2 (en) | 2001-08-20 | 2001-08-20 | Liquid detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP5041113B2 (en) |
Cited By (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005171129A (en) * | 2003-12-12 | 2005-06-30 | Kao Corp | Liquid detergent composition |
| JP2007051168A (en) * | 2005-08-12 | 2007-03-01 | Kanebo Cosmetics Inc | Transparent gel detergent composition |
| JP2007051167A (en) * | 2005-08-12 | 2007-03-01 | Kanebo Cosmetics Inc | Transparent gel detergent composition |
| JP2007238457A (en) * | 2006-03-06 | 2007-09-20 | Pola Chem Ind Inc | Cleansing agent in which cleansing agent composition is packed in pump vessel |
| WO2009075142A1 (en) * | 2007-12-12 | 2009-06-18 | Lion Corporation | Bactericidal cleanser composition |
| JP2013532736A (en) * | 2010-07-15 | 2013-08-19 | ザ プロクター アンド ギャンブル カンパニー | Composition containing near-chain-end branching compound (NEARTERMINAL-BRANCHEDCOMPOUND) and method for producing the same |
| JP2015199711A (en) * | 2014-03-31 | 2015-11-12 | 株式会社コーセー | cleansing composition |
| JP2018193461A (en) * | 2017-05-16 | 2018-12-06 | 小林製薬株式会社 | Detergent composition |
| WO2019031572A1 (en) * | 2017-08-10 | 2019-02-14 | 株式会社資生堂 | Oily cleanser |
| JP2019529510A (en) * | 2016-10-21 | 2019-10-17 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | Stable compact shampoo product with low viscosity and viscosity reducer |
| US11116705B2 (en) | 2017-10-10 | 2021-09-14 | The Procter And Gamble Company | Compact shampoo composition containing sulfate-free surfactants |
| US11116703B2 (en) | 2017-10-10 | 2021-09-14 | The Procter And Gamble Company | Compact shampoo composition containing sulfate-free surfactants |
| US11116704B2 (en) | 2017-10-10 | 2021-09-14 | The Procter And Gamble Company | Compact shampoo composition |
| US11129775B2 (en) | 2017-10-10 | 2021-09-28 | The Procter And Gamble Company | Method of treating hair or skin with a personal care composition in a foam form |
| US11141370B2 (en) | 2017-06-06 | 2021-10-12 | The Procter And Gamble Company | Hair compositions comprising a cationic polymer mixture and providing improved in-use wet feel |
| US11141361B2 (en) | 2016-10-21 | 2021-10-12 | The Procter And Gamble Plaza | Concentrated shampoo dosage of foam designating hair volume benefits |
| US11154467B2 (en) | 2016-10-21 | 2021-10-26 | The Procter And Gamble Plaza | Concentrated shampoo dosage of foam designating hair conditioning benefits |
| US11202740B2 (en) | 2016-10-21 | 2021-12-21 | The Procter And Gamble Company | Concentrated shampoo dosage of foam for providing hair care benefits |
| US11224567B2 (en) | 2017-06-06 | 2022-01-18 | The Procter And Gamble Company | Hair compositions comprising a cationic polymer/silicone mixture providing improved in-use wet feel |
| US11291616B2 (en) | 2015-04-23 | 2022-04-05 | The Procter And Gamble Company | Delivery of surfactant soluble anti-dandruff agent |
| US11318073B2 (en) | 2018-06-29 | 2022-05-03 | The Procter And Gamble Company | Low surfactant aerosol antidandruff composition |
| US11446217B2 (en) | 2016-03-03 | 2022-09-20 | The Procter & Gamble Company | Aerosol antidandruff composition |
| US11679065B2 (en) | 2020-02-27 | 2023-06-20 | The Procter & Gamble Company | Compositions with sulfur having enhanced efficacy and aesthetics |
| US11679073B2 (en) | 2017-06-06 | 2023-06-20 | The Procter & Gamble Company | Hair compositions providing improved in-use wet feel |
| US11771635B2 (en) | 2021-05-14 | 2023-10-03 | The Procter & Gamble Company | Shampoo composition |
| US11819474B2 (en) | 2020-12-04 | 2023-11-21 | The Procter & Gamble Company | Hair care compositions comprising malodor reduction materials |
| US11980679B2 (en) | 2019-12-06 | 2024-05-14 | The Procter & Gamble Company | Sulfate free composition with enhanced deposition of scalp active |
| US11986543B2 (en) | 2021-06-01 | 2024-05-21 | The Procter & Gamble Company | Rinse-off compositions with a surfactant system that is substantially free of sulfate-based surfactants |
| US12226505B2 (en) | 2018-10-25 | 2025-02-18 | The Procter & Gamble Company | Compositions having enhanced deposition of surfactant-soluble anti-dandruff agents |
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| EP3528897A1 (en) | 2016-10-21 | 2019-08-28 | The Procter & Gamble Company | Dosage of foam for delivering consumer desired dosage volume, surfactant amount, and scalp health agent amount in an optimal formulation space |
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| WO2018075836A1 (en) | 2016-10-21 | 2018-04-26 | The Procter & Gamble Company | Concentrated shampoo dosage of foam for providing hair care benefits |
| JP7280265B2 (en) | 2017-12-20 | 2023-05-23 | ザ プロクター アンド ギャンブル カンパニー | Transparent shampoo composition containing silicone polymer |
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|---|---|---|---|---|
| JP2005171129A (en) * | 2003-12-12 | 2005-06-30 | Kao Corp | Liquid detergent composition |
| JP2007051168A (en) * | 2005-08-12 | 2007-03-01 | Kanebo Cosmetics Inc | Transparent gel detergent composition |
| JP2007051167A (en) * | 2005-08-12 | 2007-03-01 | Kanebo Cosmetics Inc | Transparent gel detergent composition |
| JP2007238457A (en) * | 2006-03-06 | 2007-09-20 | Pola Chem Ind Inc | Cleansing agent in which cleansing agent composition is packed in pump vessel |
| WO2009075142A1 (en) * | 2007-12-12 | 2009-06-18 | Lion Corporation | Bactericidal cleanser composition |
| CN101896595B (en) * | 2007-12-12 | 2012-04-25 | 狮王株式会社 | Bactericidal cleanser composition |
| JP5343857B2 (en) * | 2007-12-12 | 2013-11-13 | ライオン株式会社 | Bactericidal detergent composition |
| JP2013532736A (en) * | 2010-07-15 | 2013-08-19 | ザ プロクター アンド ギャンブル カンパニー | Composition containing near-chain-end branching compound (NEARTERMINAL-BRANCHEDCOMPOUND) and method for producing the same |
| US8765651B2 (en) | 2010-07-15 | 2014-07-01 | The Procter & Gamble Company | Method of cleansing hair |
| US8883698B2 (en) | 2010-07-15 | 2014-11-11 | The Procter & Gamble Co | Compositions comprising a near terminal-branched compound and methods of making the same |
| JP2015199711A (en) * | 2014-03-31 | 2015-11-12 | 株式会社コーセー | cleansing composition |
| US11291616B2 (en) | 2015-04-23 | 2022-04-05 | The Procter And Gamble Company | Delivery of surfactant soluble anti-dandruff agent |
| US11446217B2 (en) | 2016-03-03 | 2022-09-20 | The Procter & Gamble Company | Aerosol antidandruff composition |
| JP2019529510A (en) * | 2016-10-21 | 2019-10-17 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | Stable compact shampoo product with low viscosity and viscosity reducer |
| US11202740B2 (en) | 2016-10-21 | 2021-12-21 | The Procter And Gamble Company | Concentrated shampoo dosage of foam for providing hair care benefits |
| US11154467B2 (en) | 2016-10-21 | 2021-10-26 | The Procter And Gamble Plaza | Concentrated shampoo dosage of foam designating hair conditioning benefits |
| US11141361B2 (en) | 2016-10-21 | 2021-10-12 | The Procter And Gamble Plaza | Concentrated shampoo dosage of foam designating hair volume benefits |
| US11129783B2 (en) | 2016-10-21 | 2021-09-28 | The Procter And Gamble Plaza | Stable compact shampoo products with low viscosity and viscosity reducing agent |
| JP7105037B2 (en) | 2017-05-16 | 2022-07-22 | 小林製薬株式会社 | detergent composition |
| JP2018193461A (en) * | 2017-05-16 | 2018-12-06 | 小林製薬株式会社 | Detergent composition |
| US11141370B2 (en) | 2017-06-06 | 2021-10-12 | The Procter And Gamble Company | Hair compositions comprising a cationic polymer mixture and providing improved in-use wet feel |
| US11224567B2 (en) | 2017-06-06 | 2022-01-18 | The Procter And Gamble Company | Hair compositions comprising a cationic polymer/silicone mixture providing improved in-use wet feel |
| US11679073B2 (en) | 2017-06-06 | 2023-06-20 | The Procter & Gamble Company | Hair compositions providing improved in-use wet feel |
| WO2019031572A1 (en) * | 2017-08-10 | 2019-02-14 | 株式会社資生堂 | Oily cleanser |
| US11129775B2 (en) | 2017-10-10 | 2021-09-28 | The Procter And Gamble Company | Method of treating hair or skin with a personal care composition in a foam form |
| US11116704B2 (en) | 2017-10-10 | 2021-09-14 | The Procter And Gamble Company | Compact shampoo composition |
| US11116705B2 (en) | 2017-10-10 | 2021-09-14 | The Procter And Gamble Company | Compact shampoo composition containing sulfate-free surfactants |
| US11116703B2 (en) | 2017-10-10 | 2021-09-14 | The Procter And Gamble Company | Compact shampoo composition containing sulfate-free surfactants |
| US11904036B2 (en) | 2017-10-10 | 2024-02-20 | The Procter & Gamble Company | Sulfate free clear personal cleansing composition comprising low inorganic salt |
| US11992540B2 (en) | 2017-10-10 | 2024-05-28 | The Procter & Gamble Company | Sulfate free personal cleansing composition comprising low inorganic salt |
| US11318073B2 (en) | 2018-06-29 | 2022-05-03 | The Procter And Gamble Company | Low surfactant aerosol antidandruff composition |
| US12226505B2 (en) | 2018-10-25 | 2025-02-18 | The Procter & Gamble Company | Compositions having enhanced deposition of surfactant-soluble anti-dandruff agents |
| US11980679B2 (en) | 2019-12-06 | 2024-05-14 | The Procter & Gamble Company | Sulfate free composition with enhanced deposition of scalp active |
| US11679065B2 (en) | 2020-02-27 | 2023-06-20 | The Procter & Gamble Company | Compositions with sulfur having enhanced efficacy and aesthetics |
| US11819474B2 (en) | 2020-12-04 | 2023-11-21 | The Procter & Gamble Company | Hair care compositions comprising malodor reduction materials |
| US11771635B2 (en) | 2021-05-14 | 2023-10-03 | The Procter & Gamble Company | Shampoo composition |
| US11986543B2 (en) | 2021-06-01 | 2024-05-21 | The Procter & Gamble Company | Rinse-off compositions with a surfactant system that is substantially free of sulfate-based surfactants |
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