HRP20140278T1 - Proizvodnja koloidnih suspenzija sa nanoäśesticama titanijevog dioksida sa oäśuvanom kristaliniäśnosti korištenjem kugliäśnog mlina s mikrometarskom veliäśinom zrnaca - Google Patents
Proizvodnja koloidnih suspenzija sa nanoäśesticama titanijevog dioksida sa oäśuvanom kristaliniäśnosti korištenjem kugliäśnog mlina s mikrometarskom veliäśinom zrnaca Download PDFInfo
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- 239000000725 suspension Substances 0.000 title claims 46
- 239000002105 nanoparticle Substances 0.000 title claims 28
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims 15
- 238000004519 manufacturing process Methods 0.000 title claims 12
- 239000011324 bead Substances 0.000 title 2
- 238000000227 grinding Methods 0.000 claims 20
- 238000000034 method Methods 0.000 claims 19
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims 12
- 239000002904 solvent Substances 0.000 claims 12
- 150000001412 amines Chemical class 0.000 claims 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims 6
- 239000000203 mixture Substances 0.000 claims 5
- 239000002245 particle Substances 0.000 claims 5
- 239000011164 primary particle Substances 0.000 claims 5
- 239000004408 titanium dioxide Substances 0.000 claims 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 4
- 239000002270 dispersing agent Substances 0.000 claims 3
- 230000000717 retained effect Effects 0.000 claims 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 239000008367 deionised water Substances 0.000 claims 2
- 229910021641 deionized water Inorganic materials 0.000 claims 2
- 238000010790 dilution Methods 0.000 claims 2
- 239000012895 dilution Substances 0.000 claims 2
- 239000006185 dispersion Substances 0.000 claims 2
- 230000014759 maintenance of location Effects 0.000 claims 2
- 239000011941 photocatalyst Substances 0.000 claims 2
- 238000000926 separation method Methods 0.000 claims 2
- 229910052693 Europium Inorganic materials 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 1
- 229910052740 iodine Inorganic materials 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 229910052746 lanthanum Inorganic materials 0.000 claims 1
- HPGPEWYJWRWDTP-UHFFFAOYSA-N lithium peroxide Chemical compound [Li+].[Li+].[O-][O-] HPGPEWYJWRWDTP-UHFFFAOYSA-N 0.000 claims 1
- 229910052750 molybdenum Inorganic materials 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 230000002093 peripheral effect Effects 0.000 claims 1
- 230000001699 photocatalysis Effects 0.000 claims 1
- 229910052697 platinum Inorganic materials 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 229910052709 silver Inorganic materials 0.000 claims 1
- 229910052717 sulfur Inorganic materials 0.000 claims 1
- 150000003512 tertiary amines Chemical class 0.000 claims 1
- 229910052721 tungsten Inorganic materials 0.000 claims 1
- 229910052720 vanadium Inorganic materials 0.000 claims 1
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- C09D17/00—Pigment pastes, e.g. for mixing in paints
- C09D17/004—Pigment pastes, e.g. for mixing in paints containing an inorganic pigment
- C09D17/007—Metal oxide
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Claims (17)
1. Postupak za proizvodnju koloidne suspenzije nano-kristaliničnih čestica u otapalu, te se navedeni postupak sastoji od
- pripreme smjese miješanjem navedenih nano-kristaliničnih čestica s otapalom i jednim ili više disperzijskih sredstava,
- proizvodnje koloidne suspenzije navedenih nano-kristaliničnih čestica podvrgavanjem smjese postupku mljevenja u komori za mljevenje (4; 4A: 4B; 4C), pri čemu je navedena smjesa u kontaktu sa zrncima (9) u kugličnom mlinu,
- razdvajanja navedenih zrnaca (9) iz navedene koloidne suspenzije, pri čemu se postupak sastoji od:
- korištenja navedenih zrnaca (9) u kugličnom mlinu u navedenom postupku mljevenja koje imaju prosječni promjer od najviše 70 µm kao što je najviše 50 µm, te poželjno najviše 40 µm kao što je najviše 30 µm, te čak još poželjnije sa prosječnim promjerom od najviše 20 µm kao što je najviše 10 µm
- mljevenja navedenih čestica u navedenoj suspenziji sve dok
- čestice u suspenziji imaju prosječnu veličinu od manje od 60 nm kao što je manje od 50 nm i poželjno manje od 40 nm kao stoje manje od 30 nm, te čak još poželjnije manje od 20 nm,
naznačen time da postupak dodatno sadrži
- kontrolu inducirane energije da bude manja od energije prevođenja u amorfni oblik tako da se poslije navedenog mljevenja zadržava najmanje 50 % od početne kristaliničnosti navedenih primarnih čestica, kao što je zadržavanje najmanje 60 % od početne kristaliničnosti navedenih primarnih čestica poslije navedenog mljevenja, le poželjno da se zadržava najmanje 70 % od početne kristaliničnosti navedenih primarnih čestica poslije navedenog mljevenja kao što je zadržavanje najmanje 80 % od početne kristaliničnosti poslije navedenog mljevenja, te čak još poželjnije da se zadržava najmanje 90 % od početne kristaliničnosti navedenih primarnih čestica poslije navedenog mljevenja.
2. Postupak prema zahtjevu 1. naznačen time da je volumenski udio navedenih zrnaca za mljevenje (9) u navedenoj komori za mljevenje (4; 4A; 4B; 4C) u rasponu od 60-95 % kao što je 70-90 %, te poželjno daje volumenski udio navedenih zrnaca za mljevenje u navedenom postupku mljevenja u rasponu od 75-85 %, kao što je 80-85 %.
3. Postupak za proizvodnju koloidne suspenzije nano-kristaliničnih čestica u otapalu prema bilo kojem prethodnom zahtjevu, naznačen time da dodatno sadrži podešavanje pH navedene koloidne suspenzije na vrijednosti između 9 i 12, kao što je između 9,5 i 11,5 te poželjno između 10,0 i 11,0.
4. Postupak za proizvodnju koloidne suspenzije nano-kristaliničnih čestica u otapalu prema bilo kojem od prethodnih zahtjeva, naznačen time da navedeno jedno ili više disperzijskih sredstava sadrži jedan ili više amina kao što je jedan ili više tercijarnih amina, poželjno trietilamin.
5. Postupak za proizvodnju koloidne suspenzije nano-kristaliničnih čestica u otapalu prema zahtjevu 5, naznačen time da dodatno sadrži podešavanje koncentracije navedenog jednog ili više amina u spomenutoj koloidnoj suspenziji na vrijednosti u rasponu od 0,1-30 težinskih %, kao što je koncentracija navedenog jednog ili više amina u spomenutoj koloidnoj suspenziji u rasponu od 0,5-20 težinskih %, te poželjno koncentraciju navedenog jednog ili više amina u spomenutoj koloidnoj suspenziji u rasponu od 1-10 težinskih %, kao što je koncentracija navedenog jednog ili više amina u spomenutoj koloidnoj suspenziji od 3-6 težinskih %.
6. Postupak za proizvodnju koloidne suspenzije nano-kristaliničnih čestica u otapalu prema bilo kojem od prethodnih zahtjeva, naznačen time da navedeno jedno ili više disperzijskih sredstava sadrži glikol kao šio je monopropilen glikol.
7. Postupak za proizvodnju koloidne suspenzije nano-kristaliničnih čestica u otapalu prema bilo kojem od prethodnih zahtjeva, naznačen time da navedeno otapalo je voda ili sadrži vodu i/ili jedan ili više alkohola.
8. Postupak za proizvodnju koloidne suspenzije nano-kristaliničnih čestica u otapalu prema bilo kojem od prethodnih zahtjeva, naznačen time da navedene nano-kristalinične čestice su fotokatalitičke čestice, koje poželjno sadrže litanijev dioksid ili modificirani oblik titanijevog dioksida.
9. Postupak za proizvodnju koloidne suspenzije nano-kristaliničnih čestica u otapalu prema zahtjevu 8. naznačen time da navedeni modificirani oblik titanijevog dioksida sadrži anatazni oblik titanijevog dioksida dopiran sa jednim ili više elemenata odabranih od N, C, S, I, W, V, Cu, Ag, Au, Pt, Co, Fe, Mo, La, Eu ili od njihovih kombinacija.
10. Postupak za proizvodnju koloidne suspenzije nano-kristaliničnih čestica u otapalu prema zahtjevu 1, naznačen time da postupak dodatno sadrži
- povlačenje najmanje dijela navedene smjese iz komore za miješanje pomoću cirkulacijske pumpe (2), te
- uvođenje navedene smjese u komoru za mljevenje (4; 4A; 4B; 4C) koja sadrži navedena zrnca za mljevenje (9), te
- mljevenje i/ili drobljenje i/ili dispergiranje navedenih nano-kristaliničnih čestica pomoću stvaranja rotacije navedenih zrnaca (9) u navedenoj komori za mljevenje (4) da se dobije koloidna suspenzija i
- razdvajanje navedenih zrnaca (9) iz navedene koloidne suspenzije, te
- povlačenje i re-cirkulaciju najmanje dijela navedene koloidne suspenzije iz navedene komore za mljevenje (4; 4A; 4B; 4C) u navedenu komoru za miješanje.
11. Postupak za proizvodnju koloidne suspenzije u otapalu prema zahtjevu 10, naznačen time da je rotacijska brzina navedenih zrnaca za mljevenje (9) manja od 15 m/s na primjer manja od 10 m/s, te je poželjno u rasponu od 5-10 m/s, pri čemu se rotacijska brzina zrnaca za mljevenje (9) poželjno postiže pomoću miješalice, koja poželjno rotira obodnom brzinom miješalice koja je manja od 15 m/s na primjer manja od 10 m/s, te je poželjno u rasponu od 8-10 m/s.
12. Koloidna suspenzija nanokristaliničnih čestica dobivena postupkom prema bilo kojem od patentnih zahtjeva 1-11, naznačena time da težinski udio navedenih nano-kristaliničnih čestica u spomenutoj koloidnoj suspenziji je najmanje 0,1 kao što je težinski udio navedenih nano-kristaliničnih čestica od najmanje 0,2, te je poželjno težinski udio navedenih nano-kristaliničnih čestica u spomenutoj koloidnoj suspenziji najmanje 0,30, kao što je težinski udio od najmanje 0,4, te pri čemu zamućenje navedene koloidne suspenzije nakon razrjeđivanja s deioniziranom vodom da se dobije da 0.1 težinskih % navedenih čestica ima zamućenje po cm suspenzije od manje od 6 kao što je zamućenje po cm suspenzije od manje od 4, te poželjno zamućenje po cm suspenzije od manje od 3 kao što je zamućenje po cm suspenzije od manje od 2, te čak još poželjnije zamućenje po cm suspenzije od manje od 1.
13. Koloidna suspenzija nanokristaliničnih čestica dobivena postupkom prema bilo kojem od patentnih zahtjeva 1-11, naznačena time da je koncentracija navedenih nano-kristaliničnih čestica u spomenutoj koloidnoj suspenziji u rasponu od 0,05-5,0 težinskih % kao što je koncentracija navedenih nano-kristaliničnih čestica u rasponu od 0.1-3,0 težinskih %, te poželjno koncentracija navedenih nano-kristaliničnih čestica u spomenutoj koloidnoj suspenziji u rasponu od 0,3-2 težinskih %, kao što je koncentracija navedenih nanokristaliničnih čestica u spomenutoj koloidnoj suspenziji u rasponu od 0,4-1 težinskih %, te pri čemu zamućenje navedene koloidne suspenzije nakon razrjeđivanja s deioniziranom vodom da se dobije da 0,1 težinskih % navedenih čestica ima zamućenje po cm suspenzije od manje od 6 kao što je zamućenje po cm suspenzije od manje od 4 i poželjno zamućenje po cm suspenzije od manje od 3 kao što je zamućenje po cm suspenzije od manje od 2, te čak još poželjnije zamućenje po cm suspenzije od manje od 1.
14. Koloidna suspenzija nanokristaliničnih čestica prema bilo kojem od patentnih zahtjeva 12-13, naznačena time da sadrži aglomerat primarnih čestica navedenih nanokristaliničnih čestica koje imaju prosječnu veličinu od manje od 60 nm kao što je manje od 50 nm i poželjno manje od 40 nm kao što je manje od 30 nm i čak još poželjnije manje od 20 nm.
15. Koloidna suspenzija prema bilo kojem od patentnih zahtjeva 12-14, naznačena time da kristaliničnost navedenih nanokristaliničnih čestica je najmanje 30 %, kao što je najmanje 40 %, te poželjno kristaliničnost je najmanje 50 %, kao stoje kristaliničnost od najmanje 60 %, te čak još poželjnije kristaliničnost je najmanje 70 % kao što je najmanje 80 %.
16. Koloidna suspenzija prema bilo kojem od patentnih zahtjeva 12-14, naznačena time da navedene nanokristalinične čestice sadrže fotokatalizator koji sadrži anatazni oblik titanijevog dioksida ili njegov modificiran oblik u koncentraciji od najmanje 10 težinskih %, te navedeno jedno ili više disperzijskih sredstava sadrži amin kao što je trietilamin (TF.A) u koncentraciji u rasponu od 1-10 težinskih % i monopropilen glikol u koncentraciji u rasponu od 10-20 težinskih %.
17. Koloidna suspenzija prema bilo kojem od patentnih zahtjeva 12-14, naznačena time da navedene nanokristalinične čestice sadrže fotokatalizator koji sadrži anatazni oblik titanijevog dioksida ili njegov modificiran oblik u koncentraciji u rasponu od 0,1-2,0 težinskih %, te navedeno jedno ili više disperzijskih sredstava sadrži amin kao što je trietilamin (TEA) u koncentraciji u rasponu od 0,01-0,30 težinskih % i monopropilen glikol u koncentraciji u rasponu od 0,01-1,50 težinskih %.
Applications Claiming Priority (2)
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| DKPA200900401 | 2009-03-23 | ||
| PCT/SE2010/050312 WO2010110726A1 (en) | 2009-03-23 | 2010-03-22 | Production of titania nanoparticle colloidal suspensions with maintained crystallinity by using a bead mill with micrometer sized beads |
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Country Status (10)
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| EP (2) | EP2740538A1 (hr) |
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| CA (1) | CA2756075C (hr) |
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| ES (1) | ES2457546T3 (hr) |
| HR (1) | HRP20140278T1 (hr) |
| PL (1) | PL2411141T3 (hr) |
| PT (1) | PT2411141E (hr) |
| WO (1) | WO2010110726A1 (hr) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106046911A (zh) * | 2007-11-16 | 2016-10-26 | 瓦林格光催化股份有限公司 | 光催化板或面板及其制造方法 |
| CA2756075C (en) | 2009-03-23 | 2018-05-15 | Valinge Photocatalytic Ab | Production of titania nanoparticle colloidal suspensions with maintained crystallinity by using a bead mill with micrometer sized beads |
| US9138704B2 (en) * | 2011-02-04 | 2015-09-22 | Tata Consultancy Services Limited | Suspension of nanoparticles |
| ITFI20110038A1 (it) * | 2011-03-03 | 2012-09-04 | Colorobbia Italiana Spa | Cerameri, loro applicazione ed uso. |
| JP5649060B2 (ja) * | 2011-03-28 | 2015-01-07 | 国立大学法人広島大学 | 酸化チタン粒子およびその製造方法 |
| CN103608533B (zh) | 2011-07-05 | 2017-03-22 | 瓦林格光催化股份有限公司 | 涂覆的木制品以及制备涂覆的木制品的方法 |
| DE102011114363A1 (de) | 2011-09-27 | 2013-03-28 | Kronos International, Inc. | Stabile nanopartikuläre Suspension und Verfahren zur Herstellung |
| DE102011056186A1 (de) | 2011-12-08 | 2013-06-13 | SÜDDEKOR GmbH | Verfahren zur Herstellung einer Schichtanordnung, Schichtanordnung sowie deren Verwendung |
| RU2477257C1 (ru) * | 2011-12-26 | 2013-03-10 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Санкт-Петербургский государственный университет" (СПбГУ) | Композиция на основе нанокристаллического диоксида титана, способ ее изготовления и способ применения композиции для получения фотокаталитического покрытия на стекле |
| RU2643148C2 (ru) | 2012-03-20 | 2018-01-31 | Велинге Фотокаталитик Аб | Фотокаталитические композиции, содержащие диоксид титана и добавки против фотообесцвечивания |
| CN102628213B (zh) * | 2012-04-09 | 2013-12-25 | 瑞阜景丰(北京)科技有限公司 | 一种锐钛型纳米二氧化钛在纺织物表面的分散方法 |
| CN103567045B (zh) * | 2012-08-09 | 2016-04-20 | 昆山市密友粉体设备工程有限公司 | 涂料成套装备环保生产线 |
| CN102950058B (zh) * | 2012-12-03 | 2015-09-30 | 陶裕兴 | 水泥湿磨机 |
| WO2014098762A1 (en) | 2012-12-21 | 2014-06-26 | Välinge Photocatalytic Ab | A method for coating a building panel and a building panel |
| US9375750B2 (en) | 2012-12-21 | 2016-06-28 | Valinge Photocatalytic Ab | Method for coating a building panel and a building panel |
| EP2984059B1 (en) | 2013-04-12 | 2020-11-18 | Välinge Photocatalytic AB | A method of applying a nox degrading composition on a concrete element |
| MY180856A (en) | 2013-09-25 | 2020-12-10 | Valinge Photocatalytic Ab | A method of applying a photo catalytic dispersion and a method of manufacturing a panel |
| US20150343453A1 (en) * | 2014-05-28 | 2015-12-03 | NanoCentrix L.L.C. | Fluid energy media mill system and method |
| MX2017010882A (es) * | 2015-02-27 | 2018-05-28 | Photocat As | Un producto de concreto fotocatalitico y un metodo para generar un producto de concreto fotocatalitico. |
| CN104971801B (zh) * | 2015-05-22 | 2018-01-23 | 广西有色金属集团汇元锰业有限公司 | 一种纳米珠磨系统及纳米晶微球的制备方法 |
| CN104894596B (zh) * | 2015-05-27 | 2017-07-28 | 广西有色金属集团汇元锰业有限公司 | 纳米晶微球修饰电极生产电解二氧化锰的电解系统 |
| CN105362230B (zh) * | 2015-11-27 | 2018-08-24 | 中牧南京动物药业有限公司 | 基于固体分散体技术制备盐酸沙拉沙星可溶性粉的工艺方法 |
| US20200061020A1 (en) * | 2017-05-01 | 2020-02-27 | Zhuhai Beihai Biotech Co., Ltd. | Formulations and compositions of docetaxel |
| CN108862273B (zh) * | 2018-09-11 | 2020-05-05 | 河北卫星化工股份有限公司 | 纳米金刚石胶体的制备方法及纳米金刚石二次分散方法 |
| CN111318342A (zh) * | 2020-03-24 | 2020-06-23 | 龙游讴凡纳米材料有限公司 | 一种可反复研磨的纳米砂磨机 |
| CN117088407B (zh) * | 2023-10-20 | 2024-01-02 | 琥崧科技集团股份有限公司 | 一种纳米二氧化钛及其制备方法和应用 |
Family Cites Families (105)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3932342A (en) | 1966-12-14 | 1976-01-13 | Nippon Paint Co., Ltd. | Methyl methacrylate lacquers containing polyisocyanates |
| US3798111A (en) | 1972-03-24 | 1974-03-19 | Mead Corp | Multiple layer decorated paper,laminates prepared therefrom and process |
| US5213702A (en) * | 1988-07-21 | 1993-05-25 | Matsushita Electric Industrial Co., Ltd. | Media agitating mill and method for milling ceramic powder |
| JP2860707B2 (ja) | 1992-11-24 | 1999-02-24 | キャスコ ノーベル アクチェボラーグ | フィルム複合材料 |
| JP3397365B2 (ja) * | 1993-04-01 | 2003-04-14 | キヤノン株式会社 | インク、インクの製造方法、インクジェット記録方法、記録ユニット、インクカートリッジおよびインクジェット記録装置 |
| US6284314B1 (en) | 1993-12-09 | 2001-09-04 | Agency Of Industrial Science & Technology, Ministry Of International Trade & Industry | Porous ceramic thin film and method for production thereof |
| US5500331A (en) * | 1994-05-25 | 1996-03-19 | Eastman Kodak Company | Comminution with small particle milling media |
| WO1996039251A1 (fr) | 1995-06-06 | 1996-12-12 | Kotobuki Eng. & Mfg. Co., Ltd. | Broyeur humide d'agitation a billes et procede |
| ATE391553T1 (de) | 1995-06-19 | 2008-04-15 | Nippon Soda Co | Trägerstruktur mit photokatalysator und photokatalytisches beschichtungsmaterial |
| US5679138A (en) * | 1995-11-30 | 1997-10-21 | Eastman Kodak Company | Ink jet inks containing nanoparticles of organic pigments |
| US6740312B2 (en) | 1996-02-15 | 2004-05-25 | Rhodia Chimie | Titanium dioxide particles |
| FR2744914B1 (fr) | 1996-02-15 | 1998-03-20 | Rhone Poulenc Chimie | Dispersion de dioxyde de titane, poudre a base de dioxyde de titane, leur utilisation dans les formulations cosmetiques |
| JPH09234375A (ja) | 1996-03-01 | 1997-09-09 | Mitsubishi Paper Mills Ltd | 光反応性有害物除去材 |
| JP3862760B2 (ja) * | 1996-06-12 | 2006-12-27 | トレスパファン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | 低い薄膜干渉を示す透明なバリヤコーティング |
| WO1998003607A1 (fr) | 1996-07-19 | 1998-01-29 | Toto Ltd. | Composition de revetement hydrophile photocatalytique |
| US5962343A (en) | 1996-07-30 | 1999-10-05 | Nissan Chemical Industries, Ltd. | Process for producing crystalline ceric oxide particles and abrasive |
| IT1286492B1 (it) | 1996-08-07 | 1998-07-15 | Italcementi Spa | Legante idraulico con migliorate proprieta' di costanza di colore |
| FR2756276B1 (fr) | 1996-11-26 | 1998-12-24 | Saint Gobain Vitrage | Substrat a proprietes hydrophiles ou hydrophobes ameliorees, comportant des irregularites |
| SK286684B6 (sk) | 1999-01-26 | 2009-03-05 | Kronospan Technical Company Ltd. | Spôsob impregnovania dekoratívnych papierov |
| FR2789591B1 (fr) | 1999-02-17 | 2002-10-04 | Rhodia Chimie Sa | Utilisation de dispersions filmogenes de dioxyde de titane pour la desinfection des surfaces dures, dispersions filmogenes de dioxyde de titane et procede de desinfection |
| US6162842A (en) | 1999-05-18 | 2000-12-19 | The Goodyear Tire & Rubber Company | Radiation curable coating composition |
| US6436159B1 (en) | 1999-12-09 | 2002-08-20 | Lilly Industries, Inc. | Abrasion resistant coatings |
| US6653356B2 (en) | 1999-12-13 | 2003-11-25 | Jonathan Sherman | Nanoparticulate titanium dioxide coatings, and processes for the production and use thereof |
| US20020042343A1 (en) | 2000-05-16 | 2002-04-11 | Kansai Paint Co., Ltd. | Coating composition for forming titanium oxide film, process for forming titanium oxide film and photocatalyst |
| US7264678B2 (en) | 2000-06-14 | 2007-09-04 | The Procter & Gamble Company | Process for cleaning a surface |
| JP4667562B2 (ja) | 2000-06-29 | 2011-04-13 | 日新製鋼株式会社 | 加工性，光反射性及び光反射持続性に優れた白色塗装金属板 |
| DE10035924B4 (de) | 2000-07-21 | 2006-04-27 | Fritz Egger Gmbh & Co | Imprägnat und Verfahren zur Herstellung und Verwendung des Imprägnats |
| US6666913B2 (en) * | 2000-09-05 | 2003-12-23 | Sakura Color Products Corporation | Aqueous ink composition |
| US7183023B2 (en) | 2003-04-07 | 2007-02-27 | Dai Nippon Printing Co., Ltd. | Method for manufacturing color filter |
| JP4846088B2 (ja) | 2000-11-07 | 2011-12-28 | 多木化学株式会社 | 酸化チタン含有光触媒塗布液およびその製造方法ならびに酸化チタン光触媒構造体 |
| JP2002177792A (ja) | 2000-12-15 | 2002-06-25 | Sosho:Kk | 流体浄化用光触媒とその製造方法 |
| DE10106213A1 (de) | 2001-02-10 | 2002-08-22 | Dmc2 Degussa Metals Catalysts Cerdec Ag | Selbstreinigende Lackbeschichtungen und Verfahren und Mittel zur Herstellung derselben |
| JP3474546B2 (ja) * | 2001-02-22 | 2003-12-08 | 日新製鋼株式会社 | 光触媒性塗料組成物 |
| KR100434883B1 (ko) * | 2001-08-14 | 2004-06-07 | 삼성전기주식회사 | 티탄산바륨계 파우더의 제조방법 |
| JP2003071967A (ja) | 2001-08-31 | 2003-03-12 | Takiron Co Ltd | 光触媒層を最外層に形成した化粧板 |
| GB0127325D0 (en) | 2001-11-14 | 2002-01-02 | Acma | Metal oxide composition |
| GB0130658D0 (en) | 2001-12-21 | 2002-02-06 | Acma | Particulate metal oxide |
| JP4048775B2 (ja) * | 2001-12-26 | 2008-02-20 | 住友化学株式会社 | 酸化チタン、それを用いてなる光触媒体及び光触媒体コーティング剤 |
| CN1216951C (zh) | 2002-03-20 | 2005-08-31 | 中国科学技术大学 | 具有自洁、抗霉、灭菌及净化空气作用的水性功能涂料 |
| FR2838734B1 (fr) | 2002-04-17 | 2005-04-15 | Saint Gobain | Substrat a revetement auto-nettoyant |
| EP1371693A3 (en) | 2002-06-14 | 2004-01-07 | Rohm And Haas Company | Damage resistant coatings, films and articles of manufacture containing crosslinked nanoparticles |
| JP2004026553A (ja) * | 2002-06-25 | 2004-01-29 | Sumitomo Chem Co Ltd | 酸化チタン分散液およびその保存容器 |
| US7449245B2 (en) | 2002-07-09 | 2008-11-11 | Leibniz-Institut Fuer Neue Materialien Gemeinnuetzige Gmbh | Substrates comprising a photocatalytic TiO2 layer |
| CN101240418B (zh) | 2002-07-09 | 2012-07-04 | 新材料公共服务公司研究所 | 包含光催化TiO2层的基片 |
| EP1541638A4 (en) | 2002-08-07 | 2010-06-16 | Ishihara Sangyo Kaisha | Titanium dioxide pigment, its preparation and its use as an adjunct to a resin composition |
| EP1541231B1 (en) | 2002-09-17 | 2011-08-31 | Fujitsu Limited | Photocatalyst apatite-containing film, method of form ing the same, coating fluid, and electronic apparatus having member covered with photocatalyst apatite-containin g film |
| CA2500244A1 (en) | 2002-10-03 | 2004-04-15 | Metss Corporation | Electrostatic charge dissipating hard laminate surfaces |
| EP1577009B1 (en) | 2002-12-27 | 2013-07-10 | Fujitsu Limited | Method for forming photocatalyst apatite film |
| TW576868B (en) * | 2002-12-30 | 2004-02-21 | Ind Tech Res Inst | Method for dispersion and grinding of ultrafine particles |
| DE10304849A1 (de) | 2003-02-06 | 2004-08-19 | Institut für Neue Materialien gemeinnützige Gesellschaft mit beschränkter Haftung | Chemomechanische Herstellung von Funktionskolloiden |
| US20060003013A1 (en) | 2003-03-11 | 2006-01-05 | Dobbs Robert J | Grinding media and methods associated with the same |
| EP1522629A1 (de) | 2003-10-08 | 2005-04-13 | M-real Oyj | Beschichtetes Papier als Druckstoff |
| EP1536036B1 (en) | 2003-11-14 | 2007-06-20 | Sharp Kabushiki Kaisha | Thin film forming apparatus |
| WO2005060610A2 (en) * | 2003-12-11 | 2005-07-07 | The Trustees Of Columbia University In The City Ofnew York | Nano-sized particles, processes of making, compositions and uses thereof |
| FI116297B (fi) | 2004-01-07 | 2005-10-31 | Kemira Pigments Oy | Menetelmä pintojen käsittelemiseksi |
| BE1015862A6 (nl) | 2004-01-15 | 2005-10-04 | Flooring Ind Ltd | Vloerpaneel en werkwijze voor het vervaardigen ervan. |
| WO2005068181A1 (en) | 2004-01-16 | 2005-07-28 | Domo Oudenaarde Nv | Photocatalytic particles in floor laminates |
| JP4393963B2 (ja) * | 2004-03-17 | 2010-01-06 | 住友化学株式会社 | 光触媒体コーティング液 |
| JP2005281017A (ja) | 2004-03-29 | 2005-10-13 | Moyo Kobayashi | 漆陶磁器及びその製造方法 |
| ES2771455T3 (es) | 2004-05-28 | 2020-07-06 | SWISS KRONO Tec AG | Panel de material de madera con revestimiento superficial |
| US7824757B2 (en) | 2004-05-28 | 2010-11-02 | Kronotec Ag | Panel made of a wooden material with a surface coating |
| AU2005257315A1 (en) | 2004-06-24 | 2006-01-05 | Ishihara Sangyo Kaisha, Ltd | Titanium dioxide pigments, process for the production thereof, and resin compositions containing the pigments |
| DE102004032013B4 (de) | 2004-07-02 | 2007-05-16 | Rehau Ag & Co | Multilagenschichtaufbau für Polymere, Verfahren zu dessen Herstellung und die Verwendung von Kunststoffformteilen mit dem Multilagenschichtaufbau |
| ITMO20050157A1 (it) * | 2005-06-22 | 2006-12-23 | New Photocatalyst Solution Ltd | Sospensioni di biossido di titanio e metodo per ottenerle. |
| GB0519444D0 (en) | 2005-09-23 | 2005-11-02 | Ici Plc | Metal oxide dispersion |
| JP2009518167A (ja) * | 2005-12-11 | 2009-05-07 | エスセーエフ テクノロジーズ アクティーゼルスカブ | ナノサイズ材料の製造 |
| EP2816087B1 (en) | 2005-12-13 | 2016-11-09 | Asahi Kasei Kabushiki Kaisha | Aqueous organic-inorganic hybrid composition |
| GB0526328D0 (en) | 2005-12-23 | 2006-02-01 | Ici Plc | Particulate metal oxide |
| JP4676877B2 (ja) * | 2005-12-28 | 2011-04-27 | 住友大阪セメント株式会社 | 粒子形状の制御された高結晶性アナターゼ型酸化チタン超微粒子、及びその製造方法 |
| US20090317624A1 (en) | 2006-02-20 | 2009-12-24 | Ken Yoshioka | Uniformly dispersed photocatalyst coating liquid, method for producing same, and photocatalytically active composite material obtained by using same |
| TW200809437A (en) * | 2006-05-18 | 2008-02-16 | Mitsubishi Chem Corp | Electrographic photoreceptor, image forming apparatus, and electrographic cartridge |
| EP2026968A2 (en) | 2006-06-13 | 2009-02-25 | Flooring Industries Limited, SARL | Method for manufacturing coated panels and coated panel |
| BE1017168A5 (nl) | 2006-06-13 | 2008-03-04 | Flooring Ind Ltd | Werkwijze voor het vervaardigen van vloerpanelen en vloerpaneel. |
| SE533410C2 (sv) | 2006-07-11 | 2010-09-14 | Vaelinge Innovation Ab | Golvpaneler med mekaniska låssystem med en flexibel och förskjutbar tunga samt tunga därför |
| US7927664B2 (en) | 2006-08-28 | 2011-04-19 | International Business Machines Corporation | Method of step-and-flash imprint lithography |
| DE102006046961A1 (de) | 2006-10-04 | 2008-04-10 | Leibniz-Institut Für Neue Materialien Gemeinnützige Gmbh | Herstellung einer flexiblen, gasdichten und transparenten Verbundfolie |
| WO2008117655A1 (ja) | 2007-03-23 | 2008-10-02 | Kabushiki Kaisha Toshiba | 光触媒用三酸化タングステン粉末の製造方法、光触媒用三酸化タングステン粉末および光触媒製品 |
| JP2008261093A (ja) | 2007-04-10 | 2008-10-30 | Matsushita Electric Works Ltd | 機能性床材およびその製造方法 |
| DE102007019040A1 (de) | 2007-04-20 | 2008-10-23 | Kronos International, Inc. | Verbesserte Photokatalysatoren auf Basis Titandioxid |
| DE102007019373A1 (de) | 2007-04-23 | 2008-10-30 | Henkel Ag & Co. Kgaa | Flüssiges Wasch- oder Reinigungsmittel mit Fließgrenze |
| TWI349701B (en) | 2007-07-26 | 2011-10-01 | Ind Tech Res Inst | Superhydrophobic self-cleaning powders and fabrication method thereof |
| WO2009021524A1 (en) * | 2007-08-14 | 2009-02-19 | Scf Technologies A/S | Method and compositions for producing optically clear photocatalytic coatings |
| ATE501848T1 (de) | 2007-08-22 | 2011-04-15 | Renolit Ag | Folie mit photokatalytisch aktiver oberfläche |
| CN106046911A (zh) | 2007-11-16 | 2016-10-26 | 瓦林格光催化股份有限公司 | 光催化板或面板及其制造方法 |
| DE102007054848B4 (de) | 2007-11-16 | 2018-09-27 | Erlus Aktiengesellschaft | Keramischer Formkörper mit einer photokatalytisch aktiven, luftreinigenden, transparenten Oberflächenbeschichtung, Verfahren zur Herstellung desselben und dessen Verwendung |
| CA3047796C (en) | 2007-11-19 | 2021-05-04 | Valinge Innovation Ab | A method of producing a panel including a wood veneer layer, and such a panel |
| JP5164542B2 (ja) | 2007-12-04 | 2013-03-21 | ニチハ株式会社 | 建材の塗装方法 |
| US8357426B2 (en) | 2008-01-11 | 2013-01-22 | Nanomateriales S.A. De C.V. | Single step milling and surface coating process for preparing stable nanodispersions |
| DE102008008808A1 (de) | 2008-02-12 | 2009-08-13 | Dekor-Kunststoffe Gmbh | Verfahren zur Herstellung eines scheuerfesten Overlays |
| EP2344311B1 (en) | 2008-04-07 | 2018-08-22 | Välinge Innovation AB | Method of manufacturing a wood fibre based floor board |
| TWI440505B (zh) | 2008-05-27 | 2014-06-11 | Toto Ltd | Photocatalyst coating |
| WO2009157449A1 (ja) | 2008-06-23 | 2009-12-30 | 旭硝子株式会社 | 太陽電池モジュール用バックシートおよび太陽電池モジュール |
| JP5476581B2 (ja) | 2008-06-30 | 2014-04-23 | 独立行政法人産業技術総合研究所 | サーモクロミック微粒子、その分散液、その製造方法、ならびに調光性塗料、調光性フィルムおよび調光性インク |
| DE102008046391A1 (de) | 2008-09-09 | 2010-03-11 | Kronos International, Inc. | Verfahren zur Herstellung kohlenstoffmodifizierter Photokatalysatorschichten |
| DE102008049963A1 (de) | 2008-10-02 | 2010-04-08 | Treffert Coatings Gmbh | Wässriger Lack zur Reduktion der Formaldehydemission aus Holzwerkstoffen |
| US20100112359A1 (en) | 2008-11-03 | 2010-05-06 | Sharma Pramod K | Titanium dioxide coatings having barrier layers and methods of forming titanium dioxide coatings having barrier layers |
| CA2756075C (en) | 2009-03-23 | 2018-05-15 | Valinge Photocatalytic Ab | Production of titania nanoparticle colloidal suspensions with maintained crystallinity by using a bead mill with micrometer sized beads |
| CA2784857C (en) | 2009-12-21 | 2015-08-04 | Fpinnovations | Coatings containing nanocrystalline cellulose, processes for preparation and use thereof |
| SG182270A1 (en) | 2010-01-29 | 2012-08-30 | Vaelinge Photocatalytic Ab | Method for applying nanoparticles |
| US20110189471A1 (en) | 2010-01-29 | 2011-08-04 | Valinge Innovation Ab | Method for applying nanoparticles |
| CN103608533B (zh) | 2011-07-05 | 2017-03-22 | 瓦林格光催化股份有限公司 | 涂覆的木制品以及制备涂覆的木制品的方法 |
| RU2643148C2 (ru) | 2012-03-20 | 2018-01-31 | Велинге Фотокаталитик Аб | Фотокаталитические композиции, содержащие диоксид титана и добавки против фотообесцвечивания |
| US9375750B2 (en) | 2012-12-21 | 2016-06-28 | Valinge Photocatalytic Ab | Method for coating a building panel and a building panel |
| EP2984059B1 (en) | 2013-04-12 | 2020-11-18 | Välinge Photocatalytic AB | A method of applying a nox degrading composition on a concrete element |
| MY180856A (en) * | 2013-09-25 | 2020-12-10 | Valinge Photocatalytic Ab | A method of applying a photo catalytic dispersion and a method of manufacturing a panel |
-
2010
- 2010-03-22 CA CA2756075A patent/CA2756075C/en active Active
- 2010-03-22 PL PL10756423T patent/PL2411141T3/pl unknown
- 2010-03-22 CN CN201080013268.9A patent/CN102361686B/zh active Active
- 2010-03-22 WO PCT/SE2010/050312 patent/WO2010110726A1/en active Application Filing
- 2010-03-22 PT PT10756423T patent/PT2411141E/pt unknown
- 2010-03-22 ES ES10756423T patent/ES2457546T3/es active Active
- 2010-03-22 EP EP20140157659 patent/EP2740538A1/en not_active Withdrawn
- 2010-03-22 EP EP20100756423 patent/EP2411141B1/en active Active
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- 2010-03-22 DK DK10756423T patent/DK2411141T3/da active
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2014
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| US20120064787A1 (en) | 2012-03-15 |
| PL2411141T3 (pl) | 2014-06-30 |
| CN102361686B (zh) | 2014-10-15 |
| EP2740538A1 (en) | 2014-06-11 |
| PT2411141E (pt) | 2014-04-10 |
| EP2411141A4 (en) | 2012-08-22 |
| EP2411141A1 (en) | 2012-02-01 |
| CN102361686A (zh) | 2012-02-22 |
| DK2411141T3 (da) | 2014-03-31 |
| EP2411141B1 (en) | 2014-03-05 |
| ES2457546T3 (es) | 2014-04-28 |
| US9963609B2 (en) | 2018-05-08 |
| CA2756075C (en) | 2018-05-15 |
| WO2010110726A1 (en) | 2010-09-30 |
| CA2756075A1 (en) | 2010-09-30 |
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