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GB933106A - Improved cellulosic fabrics and methods for making them - Google Patents

Improved cellulosic fabrics and methods for making them

Info

Publication number
GB933106A
GB933106A GB2443/60A GB244360A GB933106A GB 933106 A GB933106 A GB 933106A GB 2443/60 A GB2443/60 A GB 2443/60A GB 244360 A GB244360 A GB 244360A GB 933106 A GB933106 A GB 933106A
Authority
GB
United Kingdom
Prior art keywords
cross
formaldehyde
acid
linking agent
urea
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2443/60A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Deering Milliken Research Corp
Milliken Research Corp
Original Assignee
Deering Milliken Research Corp
Milliken Research Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Deering Milliken Research Corp, Milliken Research Corp filed Critical Deering Milliken Research Corp
Publication of GB933106A publication Critical patent/GB933106A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/11—Compounds containing epoxy groups or precursors thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/12—Aldehydes; Ketones
    • D06M13/13—Unsaturated aldehydes, e.g. acrolein; Unsaturated ketones; Ketenes ; Diketenes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/272—Unsaturated compounds containing sulfur atoms
    • D06M13/278—Vinylsulfonium compounds; Vinylsulfone or vinylsulfoxide compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

Fabrics containing at least 10% of alkali insoluble cellulosic fibres having at least 1,8 free hydroxy groups per anhydro glucose unit are creaseproofed by (1) treating them with an aqueous solution containing a textile resin, i.e. a water-soluble, acid or acid salt catalysed material having a molecular weight of less than 1000 which will react with the cellulose molecules and which is thermosetting, and an acid or acid salt catalyst and (2) reacting them with an alkali catalysed cross-linking agent while the cellulosic fibres are in a moist, swollen condition by contact with a basic aqueous solution to produce cellulosic fibres cross-linked with linkages from 3-15 carbon atoms in length, the steps (1) and (2) being carried out in either order. Suitable textile resins are urea-formaldehyde and melamine-formaldehyde resins, methyl ethers of urea-formaldehyde resins, acrolein urea formaldehyde, cyclic ethylene urea formaldehyde, trimethylol acetylene diurea, tetramethylol acetylene diurea, methylated melamine formaldehyde, uran, triazane, tris (1 aziridinyl) phosphine oxide and epoxy resins, e.g. the diglycidyl ether of ethylene glycol, the triglycidyl ether of glycerol, and suitable acid catalysts are monoethanolamine hydrochloride, 2 amino-2 methyl-propanol nitrate, zinc nitrate, magnesium chloride and acid fluoride salts. After application of the resin the fabric may be dried and cured by heating at a temperature of 100 DEG -200 DEG C. for from 10 seconds to 30 minutes. The cross-linking agent may be diepoxybutane, the diglycidyl ethers of ethylene glycol, propylene glycol, diethylene glycol or bisphenol A, the triglycidyl ether of glycerol, epichlorohydrin, 1,2 dichloropropanol-3,1,3 dichloropropanol-2, 1-3 di-bromo-propanol-2, bis(1chloro-2hydroxy-n-propoxy)ethane, 1,4 dichloro-2,3-dihydroxybutane, divinyl sulphane, bis(vinyl sulphonyl)-methane, 1-4-bis(vinyl sulphony)butane, and octadiene-1-2, 7-8-diane-3-6. The basic catalyst employed as catalyst for the cross-linking reaction, e.g. sodium hydroxide, potassium hydroxide, sodium silicate, trimethyl phenyl ammonium hydroxide and tetramethyl ammonium hydroxide, may be applied in the form of an aqueous solution before, after or simultaneously with the cross-linking agent. The reaction of the fabric with the cross-linking agent may be effected at a temperature below 100 DEG C. Fabrics comprising cotton, linen, regenerated cellulose, cellulose acetate or partially methylated cellulose fibres alone or in admixture with glycolterephthalate, nylon or polyacrylic fibres may be treated.
GB2443/60A 1959-01-29 1960-01-22 Improved cellulosic fabrics and methods for making them Expired GB933106A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US789798A US3175874A (en) 1959-01-29 1959-01-29 Method of creaseproofing cellulosic fabrics by wet creaseproofing followed by dry creaseproofing and the resulting product

Publications (1)

Publication Number Publication Date
GB933106A true GB933106A (en) 1963-08-08

Family

ID=25148712

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2443/60A Expired GB933106A (en) 1959-01-29 1960-01-22 Improved cellulosic fabrics and methods for making them

Country Status (9)

Country Link
US (1) US3175874A (en)
BE (1) BE587065A (en)
CH (1) CH369104A (en)
DE (1) DE1212486C2 (en)
DK (1) DK108668C (en)
ES (1) ES255003A1 (en)
FR (1) FR1245982A (en)
GB (1) GB933106A (en)
NL (2) NL113784C (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL286002A (en) * 1961-11-28
CH424703A (en) * 1963-03-08 1967-05-31 Heberlein & Co Ag Process for improving the textile properties, in particular the wet and dry wrinkle resistance, of cellulosic textiles
US3457024A (en) * 1965-07-27 1969-07-22 Council Scient Ind Res Process for treating cellulosic textile material for improving simultaneously its crease recovery and its abrasion and tear resistance properties

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB510511A (en) * 1937-11-02 1939-08-02 Roger Wallach Improvements in the manufacture of textile fibres composed of cellulose ethers
US2288695A (en) * 1939-07-26 1942-07-07 Bell Telephone Labor Inc Electrical insulated conductor
US2412832A (en) * 1943-10-30 1946-12-17 Cluett Peabody & Co Inc Textile material and method of preparing it
US2524399A (en) * 1948-07-07 1950-10-03 Us Rubber Co Cellulose treated with di-vinyl sulfone to shrinkproof
US2680057A (en) * 1948-08-31 1954-06-01 Deering Milliken Res Trust Cyclopropyl quaternary ammonium compounds and process of applying to textiles
BE499068A (en) * 1949-10-31 1900-01-01
GB692258A (en) * 1949-11-22 1953-06-03 Stevensons Dyers Ltd Improvements relating to the anti-shrink and anti-felt treatment of wool
NL81413C (en) * 1950-01-17
FR1036376A (en) * 1950-07-03 1953-09-07 Albert Ag Chem Werke Process for the preparation of urea formaldehyde resins resistant to attack by chemicals
US2730427A (en) * 1952-08-13 1956-01-10 American Cyanamid Co Shrinkage control of cellulosic and wool textiles with diglycidyl ether compounds
US2774691A (en) * 1954-09-21 1956-12-18 Shell Dev Treatment of textile materials and product
GB796815A (en) * 1955-02-22 1958-06-18 Courtaulds Inc Improvements in and relating to the production of an aminoplast precondensate for the treatment of cellulosic textile materials
BE556279A (en) * 1956-04-03
US2794754A (en) * 1956-04-30 1957-06-04 Shell Dev Treatment of textile materials
US2889192A (en) * 1956-12-19 1959-06-02 American Cyanamid Co Method of treating cellulose-containing textile materials, materials so treated and diester composition therefor

Also Published As

Publication number Publication date
BE587065A (en) 1960-07-29
FR1245982A (en) 1960-11-10
NL247847A (en)
ES255003A1 (en) 1960-04-16
CH369104A (en) 1963-01-31
NL113784C (en)
DE1212486C2 (en) 1974-11-07
DE1212486B (en) 1966-03-17
DK108668C (en) 1968-01-29
US3175874A (en) 1965-03-30

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