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ES2158486T3 - Oxidacion en fase vapor de propileno a oxido de propileno. - Google Patents

Oxidacion en fase vapor de propileno a oxido de propileno.

Info

Publication number
ES2158486T3
ES2158486T3 ES97901611T ES97901611T ES2158486T3 ES 2158486 T3 ES2158486 T3 ES 2158486T3 ES 97901611 T ES97901611 T ES 97901611T ES 97901611 T ES97901611 T ES 97901611T ES 2158486 T3 ES2158486 T3 ES 2158486T3
Authority
ES
Spain
Prior art keywords
propylene
potassium salt
propylene oxide
molybdenum
oxidation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97901611T
Other languages
English (en)
Inventor
Rangasamy Pitchai
Andrew Kahn
Anne Gaffney
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lyondell Chemical Technology LP
Original Assignee
Arco Chemical Technology LP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arco Chemical Technology LP filed Critical Arco Chemical Technology LP
Application granted granted Critical
Publication of ES2158486T3 publication Critical patent/ES2158486T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
    • B01J23/686—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20—Carbon compounds
    • B01J27/232—Carbonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)

Abstract

EL PROPILENO SE CONVIERTE EN OXIDO DE PROPILENO A TRAVES DE UN PROCESO DE OXIDACION EN FASE DE VAPOR EN QUE SE HACE USO DE UN CATALIZADOR DE PLATA SOPORTADO SOBRE UN CARBONADO DE METALES ALCALINO - TERREOS Y QUE CONTIENE TANTO UNA SAL DE POTASIO COMO NITRATO DE POTASIO Y UN PROMOTOR DE MOLIBDENO. LA SAL DE POTASIO Y EL PROMOTOR DE MOLIBDENO SE PUEDEN SUMINISTRAR SIMULTANEAMENTE MEDIANTE EL USO DE UNA SAL DE POTASIO DE UN OXIANION DE MOLIBDENO. LA EFICIENCIA DEL PROCESO AUMENTA ENORMEMENTE CON LA INCLUSION SIMULTANEA DE DIOXIDO DE CARBONO Y UN HALURO ORGANICO EN LA CORRIENTE DE ALIMENTACION. LA CORRIENTE DE ALIMENTACION NO NECESITA CONTENER UNA ESPECIE DE OXIDO DE NITROGENO TAL COMO NO PARA CONSEGUIR UNA ALTA SELECTIVIDAD AL OXIDO DE PROPILENO.
ES97901611T 1996-01-31 1997-01-28 Oxidacion en fase vapor de propileno a oxido de propileno. Expired - Lifetime ES2158486T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/595,007 US5625084A (en) 1996-01-31 1996-01-31 Vapor phase oxidation of propylene to propylene oxide

Publications (1)

Publication Number Publication Date
ES2158486T3 true ES2158486T3 (es) 2001-09-01

Family

ID=24381317

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97901611T Expired - Lifetime ES2158486T3 (es) 1996-01-31 1997-01-28 Oxidacion en fase vapor de propileno a oxido de propileno.

Country Status (15)

Country Link
US (2) US5625084A (es)
EP (1) EP0880513B1 (es)
JP (1) JPH11510817A (es)
KR (1) KR100476081B1 (es)
CN (1) CN1101388C (es)
AT (1) ATE202565T1 (es)
AU (1) AU721055B2 (es)
BR (1) BR9707465A (es)
CA (1) CA2244859C (es)
DE (1) DE69705391T2 (es)
ES (1) ES2158486T3 (es)
MX (1) MX209226B (es)
RU (1) RU2167872C2 (es)
TW (1) TW448166B (es)
WO (1) WO1997028142A1 (es)

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US5763630A (en) * 1996-03-18 1998-06-09 Arco Chemical Technology, L.P. Propylene oxide process using alkaline earth metal compound-supported silver catalysts
US5864047A (en) * 1997-04-10 1999-01-26 Arco Chemical Technology, L.P. Propylene oxide process using alkaline earth metal compound-supported silver catalysts containing rhenium and potassium promoters
US5861519A (en) * 1997-05-23 1999-01-19 Arco Chemical Technology, L.P. Propylene oxide process using alkaline earth metal compound-supported silver catalysts containing tungsten and potassium promoters
US5770746A (en) * 1997-06-23 1998-06-23 Arco Chemical Technology, L.P. Epoxidation process using supported silver catalysts pretreated with organic chloride
US5780657A (en) * 1997-06-23 1998-07-14 Arco Chemical Technology, L.P. Propylene epoxidation using chloride-containing silver catalysts
AU8541298A (en) * 1997-07-30 1999-02-22 Arco Chemical Technology L.P. Propylene oxide process using calcium carbonate-supported silver catalysts containing potassium and magnesium promoters
US5856534A (en) * 1997-12-18 1999-01-05 Arco Chemical Technology, L.P. Epoxidation process using supported silver catalysts treated with carbon dioxide
DE19803890A1 (de) * 1998-01-31 1999-08-05 Erdoelchemie Gmbh Silberhaltige Trägerkatalysatoren und Katalysator-Zwischenprodukte, Verfahren zu ihrer Herstellung und ihre Verwendung
GB9807142D0 (en) 1998-04-02 1998-06-03 Bp Chem Int Ltd Catalyst and process utilising the catalyst
US6008388A (en) * 1998-04-16 1999-12-28 Arco Chemical Technology, L.P. Epoxidation process
DE19847629A1 (de) * 1998-10-15 2000-04-20 Basf Ag Verfahren zur Oxidation einer mindestens eine C-C-Doppelbindung aufweisenden organischen Verbindung
US20020009414A1 (en) * 1999-10-25 2002-01-24 Moser William R. Method of preparing compounds using cavitation and compounds formed therefrom
US20070066480A1 (en) * 1999-10-25 2007-03-22 Moser William R Method of preparing compounds using cavitation and compounds formed therefrom
DE10044538A1 (de) * 2000-09-05 2002-04-04 Ift Inst Fuer Troposphaerenfor Verfahren zur Herstellung von Epoxiden durch Oxidation von Olefinen
DE10064301A1 (de) * 2000-12-22 2002-07-04 Basf Ag Silberkatalysator für die Epoxidation von Alkenen
CA2434162C (en) 2001-01-05 2010-02-02 National Institute Of Advanced Industrial Science And Technology Reaction method utilizing diaphram type catalyst and apparatus therefor
US6392066B1 (en) 2001-02-22 2002-05-21 Sri International Epoxidation of olefins using lanthanide-promoted silver catalysts
US6509485B2 (en) 2001-02-22 2003-01-21 Sri International Preparation of epoxides from alkanes using lanthanide-promoted silver catalysts
US7193094B2 (en) 2001-11-20 2007-03-20 Shell Oil Company Process and systems for the epoxidation of an olefin
BR0214251A (pt) * 2001-11-20 2004-09-21 Shell Int Research Processo e sistemas para a epoxidação de uma olefina
DE60225189T2 (de) * 2002-04-08 2009-06-18 Süd-Chemie Catalysts Japan, Inc. Behandlungsmittel für eine metallhydridverbindung enthaltendes abgas und verfahren zur behandlung von eine metallhydridverbindung enthaltendem abgas
DE10240128A1 (de) * 2002-08-30 2004-03-11 Basf Ag Silberkatalysator für die Epoxidation von Propylen
AU2003278999A1 (en) 2002-09-30 2004-04-23 Shell Oil Company Calcium carbonate carrier for making silver based epoxidation catalysts
AU2003284195A1 (en) * 2002-10-28 2004-05-25 Shell Internationale Research Maatschappij B.V. Olefin oxide catalysts
WO2004039497A2 (en) * 2002-10-28 2004-05-13 Shell Internationale Research Maatschappij B.V. Silver-based olefin oxide catalysts
EP2255876A3 (en) * 2002-10-28 2011-06-29 Shell Internationale Research Maatschappij B.V. A process for preparing an olefin oxide, a method of using the olefin oxide and a catalyst composition
US7319156B2 (en) * 2003-03-25 2008-01-15 Sumitomo Chemical Company, Limited Process for producing olefin oxide
CN100361984C (zh) 2003-04-01 2008-01-16 国际壳牌研究有限公司 烯烃环氧化方法及用于该方法的催化剂
US20050027133A1 (en) * 2003-07-29 2005-02-03 Saudi Basic Industries Corporation Method of making a catalyst for direct oxidation of an alkene to an alkene oxide
US20050027134A1 (en) * 2003-07-29 2005-02-03 Saudi Basic Industries Corporation Support for a catalyst for direct oxidation of propylene to propylene oxide, method of making and method of using catalyst
CN101160298B (zh) * 2005-02-25 2011-06-22 住友化学株式会社 环氧烷烃的制备方法
US7759284B2 (en) * 2005-05-09 2010-07-20 Scientific Design Company, Inc. Calcination in an inert gas in the presence of a small concentration of an oxidizing component
WO2007096986A1 (ja) * 2006-02-24 2007-08-30 Ibiden Co., Ltd. 端面加熱装置、ハニカム集合体の端面乾燥方法、及び、ハニカム構造体の製造方法
EP2121916A1 (en) * 2006-12-20 2009-11-25 Danisco US, INC., Genencor Division Assays for improved fungal strains
JP2008184456A (ja) * 2007-01-31 2008-08-14 Sumitomo Chemical Co Ltd 酸化プロピレンの製造法
EP3325455B1 (en) * 2015-07-24 2021-04-07 Lyondell Chemical Technology, L.P. Post treated silver catalysts for epoxidation
WO2017040121A1 (en) 2015-08-28 2017-03-09 Lyondell Chemical Technology, L.P. Epoxidation processes and catalysts for use therein
EP3275537A1 (en) * 2016-07-25 2018-01-31 Omya International AG Surface-modified calcium carbonate as carrier for transition metal-based catalysts
US11123712B2 (en) 2016-07-26 2021-09-21 Research Triangle Institute Catalysts utilizing carbon dioxide for the epoxidation of olefins
KR101810328B1 (ko) * 2016-08-22 2017-12-19 롯데케미칼 주식회사 프로필렌 직접산화 반응용 촉매, 이의 제조방법 및 이를 이용한 프로필렌 직접산화 반응에 의한 프로필렌 옥사이드 제조방법
US10308622B2 (en) 2017-01-24 2019-06-04 Lyondell Chemical Technology, L.P. Liquid phase selective oxidation to epoxides with molecular oxygen
CN113912574B (zh) * 2020-07-10 2024-01-23 中国石油化工股份有限公司 碱性条件下进行丙烯直接环氧化制备环氧丙烷的方法
CN113956216B (zh) * 2021-11-09 2024-01-23 万华化学集团股份有限公司 一种环氧苯乙烷及其制备方法

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FR1110846A (fr) * 1953-08-08 1956-02-17 Montedison Spa Catalyseur pour la production intensive d'oxyde d'éthylène
US3560530A (en) * 1969-06-19 1971-02-02 Du Pont Process for the oxidation of alkenes to alkene oxides
US3962285A (en) * 1972-06-05 1976-06-08 Exxon Research And Engineering Company Olefin oxidation process
GB1365745A (en) * 1972-06-27 1974-09-04 Bp Chem Int Ltd Propylene oxide
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US5387751A (en) * 1978-02-10 1995-02-07 Imperial Chemical Industries Plc Production of olefine oxides
DE3669668D1 (de) * 1985-07-31 1990-04-26 Ici Plc Verfahren zur aktivierung der katalysatoren zur herstellung von alkylenoxiden.
US4820675A (en) * 1986-10-31 1989-04-11 Shell Oil Company Ethylene oxide catalyst & process for preparing the catalyst
US4808738A (en) * 1986-10-31 1989-02-28 Shell Oil Company Ethylene oxide process
US4845253A (en) * 1987-11-23 1989-07-04 The Dow Chemical Company Silver-based catalyst for vapor phase oxidation of olefins to epoxides
US5447897A (en) * 1993-05-17 1995-09-05 Shell Oil Company Ethylene oxide catalyst and process
US5364826A (en) * 1993-09-13 1994-11-15 Shell Oil Company Process for preparing ethylene oxide catalysts

Also Published As

Publication number Publication date
DE69705391D1 (de) 2001-08-02
DE69705391T2 (de) 2002-05-02
CA2244859A1 (en) 1997-08-07
EP0880513B1 (en) 2001-06-27
TW448166B (en) 2001-08-01
RU2167872C2 (ru) 2001-05-27
JPH11510817A (ja) 1999-09-21
EP0880513A1 (en) 1998-12-02
MX9805984A (es) 1999-01-31
KR19990076994A (ko) 1999-10-25
BR9707465A (pt) 1999-07-20
US5625084A (en) 1997-04-29
MX209226B (es) 2002-07-25
CA2244859C (en) 2005-08-09
US5686380A (en) 1997-11-11
AU1545897A (en) 1997-08-22
ATE202565T1 (de) 2001-07-15
AU721055B2 (en) 2000-06-22
CN1101388C (zh) 2003-02-12
CN1210524A (zh) 1999-03-10
KR100476081B1 (ko) 2005-12-21
WO1997028142A1 (en) 1997-08-07

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