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ES2142581T3 - Procedimiento para la preparacion de polimeros lldpe. - Google Patents

Procedimiento para la preparacion de polimeros lldpe.

Info

Publication number
ES2142581T3
ES2142581T3 ES96912058T ES96912058T ES2142581T3 ES 2142581 T3 ES2142581 T3 ES 2142581T3 ES 96912058 T ES96912058 T ES 96912058T ES 96912058 T ES96912058 T ES 96912058T ES 2142581 T3 ES2142581 T3 ES 2142581T3
Authority
ES
Spain
Prior art keywords
procedure
preparation
lldpe polymers
sub
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96912058T
Other languages
English (en)
Inventor
Harri Hokkanen
Hannu Salminen
Kalle Kallio
Hilkka Knuuttila
Ari Palmroos
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Borealis AS
Original Assignee
Borealis AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis AS filed Critical Borealis AS
Application granted granted Critical
Publication of ES2142581T3 publication Critical patent/ES2142581T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/04Polymerisation in solution
    • C08F2/06Organic solvent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642Component covered by group C08F4/64 with an organo-aluminium compound
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

PROCESO PARA FABRICAR COPOLIMEROS MEDIANTE POLIMERIZACION DE ETILENO Y UNA CANTIDAD PEQUEÑA DE ALFAOLEFINAS C SUB,3} C SUB,6}EN FORMA DE PARTICULAS EN UN REACTOR CON COMBUSTIBLE EN SUSPENSION EN PRESENCIA DE UN CATALIZADOR DE POLIMERIZACION DE ETILENO. CONFORME A LA INVENCION, LA POLIMERIZACION SE REALIZA EN DILUYENTE DE PROPANO UTILIZANDO UN CATALIZADOR METALOCENO ACTIVADO CON UN COMPUESTO ALUMOXANO.
ES96912058T 1995-05-02 1996-04-30 Procedimiento para la preparacion de polimeros lldpe. Expired - Lifetime ES2142581T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FI952098A FI952098L (fi) 1995-05-02 1995-05-02 LLDPE-polymeerien valmistusmenetelmä

Publications (1)

Publication Number Publication Date
ES2142581T3 true ES2142581T3 (es) 2000-04-16

Family

ID=8543332

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96912058T Expired - Lifetime ES2142581T3 (es) 1995-05-02 1996-04-30 Procedimiento para la preparacion de polimeros lldpe.

Country Status (17)

Country Link
US (1) US5986021A (es)
EP (1) EP0823915B1 (es)
JP (1) JP3920918B2 (es)
KR (1) KR100355402B1 (es)
CN (1) CN1096469C (es)
AT (1) ATE189464T1 (es)
AU (1) AU699035B2 (es)
BR (1) BR9608311A (es)
CA (1) CA2217534A1 (es)
DE (1) DE69606530T2 (es)
EA (1) EA000627B1 (es)
ES (1) ES2142581T3 (es)
FI (1) FI952098L (es)
IN (1) IN188601B (es)
TW (1) TW304962B (es)
WO (1) WO1996034895A1 (es)
ZA (1) ZA963322B (es)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9712663D0 (en) 1997-06-16 1997-08-20 Borealis As Process
US6239235B1 (en) * 1997-07-15 2001-05-29 Phillips Petroleum Company High solids slurry polymerization
US6329476B1 (en) * 1997-10-14 2001-12-11 Phillips Petroleum Company Olefin polymerization processes and products thereof
DE19756368A1 (de) 1997-12-18 1999-07-01 Bayer Ag Vinylcyclohexan basierende Polymere
US6166152A (en) * 1998-02-26 2000-12-26 Phillips Petroleum Company Process to produce low density polymer in a loop reactor
US6281300B1 (en) * 1998-03-20 2001-08-28 Exxon Chemical Patents, Inc. Continuous slurry polymerization volatile removal
US20020111441A1 (en) 1998-03-20 2002-08-15 Kendrick James Austin Continuous slurry polymerization volatile removal
US7268194B2 (en) * 1998-03-20 2007-09-11 Exxonmobil Chemical Patents Inc. Continuous slurry polymerization process and apparatus
KR100531628B1 (ko) * 1998-03-20 2005-11-29 엑손모빌 케미칼 패턴츠 인코포레이티드 연속적인 슬러리 중합반응의 휘발물질 제거
KR100430438B1 (ko) * 1998-10-22 2004-07-19 대림산업 주식회사 담지메탈로센촉매,그제조방법및이를이용한폴리올레핀의중합방법
WO2001005842A1 (en) * 1999-07-15 2001-01-25 Phillips Petroleum Company Slotted slurry take off
EP1083183A1 (en) * 1999-09-10 2001-03-14 Fina Research S.A. Process for producing polyolefins
US20030099837A1 (en) * 1999-12-22 2003-05-29 Dirk Mockel Thermoplastic multi-layered film with a layer of vinylcyclohexane-based polymer
US7612009B2 (en) 2003-02-21 2009-11-03 Dow Global Technologies, Inc. Process for homo-or copolymerization of conjugated olefines
EP2289952B2 (en) * 2004-08-27 2020-03-25 Chevron Phillips Chemical Company LP Energy efficient polyolefin process
WO2006049699A1 (en) 2004-10-29 2006-05-11 Exxonmobil Chemical Patents Inc Catalyst compound containing divalent tridentate ligand
US7629421B2 (en) * 2005-12-21 2009-12-08 Chevron Phillips Chemical Company Lp Monomer recovery by returning column overhead liquid to the reactor
WO2011078923A1 (en) 2009-12-23 2011-06-30 Univation Technologies, Llc Methods for producing catalyst systems
WO2011101438A1 (en) 2010-02-22 2011-08-25 Ineos Europe Limited Improved polyolefin manufacturing process
KR101422976B1 (ko) 2010-03-04 2014-07-23 토탈 리서치 앤드 테크놀로지 펠루이 개질된 촉매 지지체
US8344078B2 (en) 2010-05-21 2013-01-01 Chevron Phillips Chemical Company Lp Continuous take off technique and pressure control of polymerization reactors
US20170151760A1 (en) * 2015-11-30 2017-06-01 Scholle Corporation Coextruded Film For Flexible Bags
US20170152088A1 (en) * 2015-11-30 2017-06-01 Scholle Ipn Corporation Coextruded Film For Flexible Bags
WO2018129339A1 (en) 2017-01-05 2018-07-12 General Cable Technologies Corporation Linear low-density polyethylene polymers suitable for use on cables
US10029230B1 (en) 2017-01-24 2018-07-24 Chevron Phillips Chemical Company Lp Flow in a slurry loop reactor
CN111087509B (zh) * 2018-10-23 2023-03-14 中国石油化工股份有限公司 一种柔性1-丁烯聚合物及其制备方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1256246A (en) * 1984-04-09 1989-06-20 Thomas J. Pullukat Copolymerization of ethylene
US5084534A (en) * 1987-06-04 1992-01-28 Exxon Chemical Patents, Inc. High pressure, high temperature polymerization of ethylene
US5408017A (en) * 1987-01-30 1995-04-18 Exxon Chemical Patents Inc. High temperature polymerization process using ionic catalysts to produce polyolefins
KR930009208B1 (ko) * 1988-12-26 1993-09-24 마쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 올레핀 공중합체 및 그의 제조방법
FI87360C (fi) * 1990-01-18 1992-12-28 Neste Oy Foerfarande foer framstaellning av eten-propen-kopolymerer i partikelform
FI86867C (fi) * 1990-12-28 1992-10-26 Neste Oy Flerstegsprocess foer framstaellning av polyeten
FI89929C (fi) * 1990-12-28 1993-12-10 Neste Oy Foerfarande foer homo- eller sampolymerisering av eten
IT1246614B (it) * 1991-06-03 1994-11-24 Himont Inc Procedimento per la polimerizzazione in fase gas delle olefine
US5594078A (en) * 1991-07-23 1997-01-14 Phillips Petroleum Company Process for producing broad molecular weight polyolefin
ATE150037T1 (de) * 1992-05-26 1997-03-15 Hoechst Ag Verfahren zur herstellung von polyolefinwachsen
CA2110654C (en) * 1992-12-17 2006-03-21 Albert Rossi Dilute process for the polymerization of ethylene/alpha-olefin copolymer using metallocene catalyst systems
ES2139741T5 (es) * 1993-03-25 2005-07-16 Exxonmobil Oil Corporation Procedimiento para formar una resina granular.
BE1007653A3 (fr) * 1993-10-26 1995-09-05 Fina Research Procede de production de polyethylene ayant une distribution large de poids moleculaire.
US5529965A (en) * 1994-10-28 1996-06-25 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US5670589A (en) * 1995-02-08 1997-09-23 Phillips Petroleum Company Organoaluminoxy product, catalyst systems, preparation, and use

Also Published As

Publication number Publication date
TW304962B (es) 1997-05-11
AU5503996A (en) 1996-11-21
ZA963322B (en) 1996-11-06
KR19980703683A (ko) 1998-12-05
CN1096469C (zh) 2002-12-18
IN188601B (es) 2002-10-19
FI952098L (fi) 1996-11-03
KR100355402B1 (ko) 2003-02-11
FI952098A0 (fi) 1995-05-02
CA2217534A1 (en) 1996-11-07
JP3920918B2 (ja) 2007-05-30
EP0823915A1 (en) 1998-02-18
AU699035B2 (en) 1998-11-19
WO1996034895A1 (en) 1996-11-07
US5986021A (en) 1999-11-16
DE69606530T2 (de) 2000-08-10
EP0823915B1 (en) 2000-02-02
DE69606530D1 (de) 2000-03-09
BR9608311A (pt) 1999-11-30
EA000627B1 (ru) 1999-12-29
EA199700214A1 (ru) 1998-02-26
JPH11504956A (ja) 1999-05-11
CN1183105A (zh) 1998-05-27
ATE189464T1 (de) 2000-02-15

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