IT1246614B - Procedimento per la polimerizzazione in fase gas delle olefine - Google Patents
Procedimento per la polimerizzazione in fase gas delle olefineInfo
- Publication number
- IT1246614B IT1246614B ITRM910379A ITRM910379A IT1246614B IT 1246614 B IT1246614 B IT 1246614B IT RM910379 A ITRM910379 A IT RM910379A IT RM910379 A ITRM910379 A IT RM910379A IT 1246614 B IT1246614 B IT 1246614B
- Authority
- IT
- Italy
- Prior art keywords
- olefins
- gas phase
- catalyst
- propylene
- chr
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- 238000012685 gas phase polymerization Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 abstract 5
- 239000007789 gas Substances 0.000 abstract 3
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 2
- -1 titanium halide Chemical class 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- 150000001335 aliphatic alkanes Chemical class 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 150000005840 aryl radicals Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 235000011147 magnesium chloride Nutrition 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 229920001155 polypropylene Polymers 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
- 239000004711 α-olefin Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/34—Polymerisation in gaseous state
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Processo per la polimerizzazione in fase gas di olefine CH2=CHR in cui R è un atomo di idrogeno o un radicale alchilico o arilico contenente da 1 a 8 atomi di carbonio, condotta in uno o più reattori aventi un letto fluidizzato o agitato meccanicamente, usando un catalizzatore ottenuto per reazione di un alogenuro o aloalcolato di titanio ed eventualmente un composto elettron-donatore supportato su un dicloruro di magnesio attivo con un composto di alluminio trialchile ed eventualmente un composto elettron-donatore, comprendente gli stadi di: a) messa in contatto dei componenti del catalizzatore in assenza di olefine; b) prepolimerizzazione del propilene o di miscele di propilene con piccole quantità di etilene o di una alfa olefina per ottenere un polimero di propilene con una insolubilità in xilolo di almeno il 60% in peso, in quantità da 0,5 g per g di componente solido di catalizzatore fino al 10% in peso della resa finale del catalizzatore; c) polimerizzazione di una o più olefine CH2=CHR in fase gas in presenza del sistema prepolimero-catalizzatore ottenuto in b) mantenendo nel contempo in fase gas un alcano in concentrazione molare dal 20 al 90% rispetto al totale dei gas.
Priority Applications (27)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITRM910379A IT1246614B (it) | 1991-06-03 | 1991-06-03 | Procedimento per la polimerizzazione in fase gas delle olefine |
| ZA923985A ZA923985B (en) | 1991-06-03 | 1992-06-01 | Process for the gas-phase polymmerization of olefins |
| MX9202633A MX9202633A (es) | 1991-06-03 | 1992-06-02 | Proceso para la polimerizacion en fase gas, de olefinas y producto obtenido mediante el mismo. |
| AR92322449A AR247408A1 (es) | 1991-06-03 | 1992-06-02 | Un procedimiento continuo para la polimerizacion en fase gaseosa de olefinas y polimeros esferiformes de etileno y propileno obtenidos con dicho procedimiento. |
| IL10207492A IL102074A (en) | 1991-06-03 | 1992-06-02 | Gas-phase polymerization of olefins |
| UA93004428A UA27785C2 (uk) | 1991-06-03 | 1992-06-03 | Спосіб безперервної газофазної полімеризації і сополімеризації олефінів та полімери, одержані в такий спосіб |
| CN92105616A CN1078216C (zh) | 1991-06-03 | 1992-06-03 | 烯烃的气相聚合方法 |
| HU9300265A HU212442B (en) | 1991-06-03 | 1992-06-03 | Continuous process for the gas-phase polymerization of olefins |
| EP19920109376 EP0517183A3 (en) | 1991-06-03 | 1992-06-03 | Process for the gas-phase polymerization of olefins |
| PL92297841A PL170118B1 (pl) | 1991-06-03 | 1992-06-03 | Sposób polimeryzacji i kopolimeryzacji w fazie gazowej olefin PL PL PL PL PL PL PL PL |
| KR1019920703325A KR100218863B1 (ko) | 1991-06-03 | 1992-06-03 | 올레핀의 기체상 중합 방법 |
| DK92911445.2T DK0541760T3 (da) | 1991-06-03 | 1992-06-03 | Fremgangsmåde til gasfasepolymerisering af olefiner |
| AU19177/92A AU653829B2 (en) | 1991-06-03 | 1992-06-03 | Process for the gas-phase polymerization of olefins |
| ES92911445T ES2090646T3 (es) | 1991-06-03 | 1992-06-03 | Procedimiento para la polimerizacion en fase gaseosa de olefinas. |
| DE69212633T DE69212633T2 (de) | 1991-06-03 | 1992-06-03 | Verfahren für die gasphasenpolymerisation von olefinen |
| RU93005275/04A RU2114125C1 (ru) | 1991-06-03 | 1992-06-03 | Способ получения (со)полимеров олефинов и (со)полимеры олефинов |
| CA002088681A CA2088681C (en) | 1991-06-03 | 1992-06-03 | Process for the gas-phase polymerization of olefins |
| EP92911445A EP0541760B1 (en) | 1991-06-03 | 1992-06-03 | Process for the gas-phase polymerization of olefins |
| JP51122892A JP3190041B2 (ja) | 1991-06-03 | 1992-06-03 | オレフィンの気相重合方法 |
| BR9205273A BR9205273A (pt) | 1991-06-03 | 1992-06-03 | Processo continuo para polimerizacao e copolimerizacao de fase de gas de olifinas,o produto do processo,e polimeros esferiformes |
| PCT/EP1992/001231 WO1992021706A1 (en) | 1991-06-03 | 1992-06-03 | Process for the gas-phase polymerization of olefins |
| AT92911445T ATE141094T1 (de) | 1991-06-03 | 1992-06-03 | Verfahren für die gasphasenpolymerisation von olefinen |
| CS19923960A CZ289004B6 (cs) | 1991-06-03 | 1992-12-29 | Kontinuální způsob polymerace olefinů v plynné fázi |
| FI930151A FI106308B (fi) | 1991-06-03 | 1993-01-14 | Menetelmä olefiinien polymeroimiseksi kaasufaasissa |
| NO930363A NO180721C (no) | 1991-06-03 | 1993-02-02 | Fremgangsmåte for gassfasepolymerisasjon av olefiner |
| US08/476,063 US6228956B1 (en) | 1991-06-03 | 1995-06-07 | Process for the gas-phase polymerization of olefins |
| GR960401974T GR3020753T3 (en) | 1991-06-03 | 1996-08-08 | Process for the gas-phase polymerization of olefins |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITRM910379A IT1246614B (it) | 1991-06-03 | 1991-06-03 | Procedimento per la polimerizzazione in fase gas delle olefine |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| ITRM910379A0 ITRM910379A0 (it) | 1991-06-03 |
| ITRM910379A1 ITRM910379A1 (it) | 1992-12-03 |
| IT1246614B true IT1246614B (it) | 1994-11-24 |
Family
ID=11400172
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ITRM910379A IT1246614B (it) | 1991-06-03 | 1991-06-03 | Procedimento per la polimerizzazione in fase gas delle olefine |
Country Status (26)
| Country | Link |
|---|---|
| US (1) | US6228956B1 (it) |
| EP (2) | EP0541760B1 (it) |
| JP (1) | JP3190041B2 (it) |
| KR (1) | KR100218863B1 (it) |
| CN (1) | CN1078216C (it) |
| AR (1) | AR247408A1 (it) |
| AT (1) | ATE141094T1 (it) |
| AU (1) | AU653829B2 (it) |
| BR (1) | BR9205273A (it) |
| CA (1) | CA2088681C (it) |
| CZ (1) | CZ289004B6 (it) |
| DE (1) | DE69212633T2 (it) |
| DK (1) | DK0541760T3 (it) |
| ES (1) | ES2090646T3 (it) |
| FI (1) | FI106308B (it) |
| GR (1) | GR3020753T3 (it) |
| HU (1) | HU212442B (it) |
| IL (1) | IL102074A (it) |
| IT (1) | IT1246614B (it) |
| MX (1) | MX9202633A (it) |
| NO (1) | NO180721C (it) |
| PL (1) | PL170118B1 (it) |
| RU (1) | RU2114125C1 (it) |
| UA (1) | UA27785C2 (it) |
| WO (1) | WO1992021706A1 (it) |
| ZA (1) | ZA923985B (it) |
Families Citing this family (87)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1254279B (it) * | 1992-03-13 | 1995-09-14 | Montecatini Tecnologie Srl | Procedimento per la polimerizzazione in fase gas delle olefine |
| EP0605380A3 (en) * | 1992-12-22 | 1994-10-26 | Fina Technology | Optimal co-catalyst / external electron donor molar ratio in the polymerization of propylene. |
| ES2117803T5 (es) * | 1993-09-16 | 2002-07-16 | Union Carbide Chem Plastic | Produccion de polimeros. |
| FI952098L (fi) * | 1995-05-02 | 1996-11-03 | Borealis As | LLDPE-polymeerien valmistusmenetelmä |
| FI952175A7 (fi) * | 1995-05-05 | 1996-11-06 | Borealis As | Menetelmä ja katalysaattorikomponentti olefiinien homo- tai kopolymeroimiseksi |
| IT1275573B (it) * | 1995-07-20 | 1997-08-07 | Spherilene Spa | Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine |
| DE69723657T2 (de) | 1996-06-24 | 2004-06-09 | Basell Poliolefine Italia S.P.A. | Elastoplastische polyolefinmasse mit hoher durchsichtigkeit und biegsamkeit |
| DE69831819T2 (de) * | 1997-01-30 | 2006-07-06 | Total Petrochemicals Research Feluy, Seneffe | Selektive Wirkung von Metallocen-Katalysatoren für die Herstellung von isotaktischen Polyolefinen |
| EP0986589B1 (en) | 1997-06-05 | 2002-08-28 | POLYPROPYLENE BELGIUM (Naamloze Vennootschap) | Continuous process for obtaining propylene polymers |
| FI111847B (fi) * | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Menetelmä propeenin kopolymeerien valmistamiseksi |
| FI111845B (fi) * | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Menetelmä propeenin homopolymeerien ja iskulujuudeltaan modifioitujen polymeerien valmistamiseksi |
| FI111846B (fi) | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Menetelmä ja laitteisto polypropeeniseosten valmistamiseksi |
| FI111848B (fi) * | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Menetelmä ja laitteisto propeenin homo- ja kopolymeerien valmistamiseksi |
| US6689845B1 (en) * | 1998-07-08 | 2004-02-10 | Basell Poliolefine Italia S.P.A. | Process and apparatus for the gas-phase polymerization |
| FI991015A0 (fi) | 1999-05-04 | 1999-05-04 | Borealis As | Menetelmä alfa-olefiinipolymeerien valmistamiseksi |
| CA2340908A1 (en) | 1999-06-18 | 2000-12-28 | Basell Technology Company B.V. | Catalyst components for the polymerization of olefins and catalysts therefrom obtained |
| HUP0202584A3 (en) | 1999-09-10 | 2003-10-28 | Basell Technology Co Bv | Catalyst for the polymerization of olefins |
| AU7540700A (en) * | 1999-10-02 | 2001-05-10 | Borealis Technology Oy | Modified supported catalysts for the polymerization of olefins |
| AU782724B2 (en) * | 2000-05-12 | 2005-08-25 | Basell Technology Company B.V. | Pre-polymerized catalyst components for the polymerization of olefins |
| RU2176649C1 (ru) * | 2000-12-08 | 2001-12-10 | Институт катализа им. Г.К. Борескова СО РАН | Способ получения сверхвысокомолекулярного полиэтилена |
| JP2004522849A (ja) | 2001-03-15 | 2004-07-29 | バセル ポリオレフィン イタリア エス．ピー．エー． | エチレンの（共）重合方法 |
| DE60232745D1 (de) | 2001-06-26 | 2009-08-06 | Basell Poliolefine Srl | Verfahren zur Herstellung von Katalysator-Komponenten für die Olefinpolymerisation |
| MY136330A (en) | 2001-12-12 | 2008-09-30 | Basell Poliolefine Spa | Process for the polymerization of olefins |
| EP1419183B2 (en) * | 2002-01-15 | 2011-02-02 | Advanced Elastomer Systems, L.P. | Thermoplastic elastomers and process for making the same |
| JP2005529224A (ja) | 2002-06-13 | 2005-09-29 | バセル ポリオレフィン イタリア エス．ピー．エー． | オレフィンの重合のための触媒成分 |
| TR200400209T1 (tr) | 2002-06-13 | 2005-04-21 | Basell Poliolefine Italia S.P.A | Etilen kopolimerlerini hazırlamak için işlem |
| ATE499392T1 (de) * | 2002-06-25 | 2011-03-15 | Borealis Tech Oy | Polyolefin mit verbesserter kratzfestigkeit und verfahren zu seiner herstelung |
| PL374508A1 (en) * | 2002-08-01 | 2005-10-31 | Basell Poliolefine Italia S.P.A. | Highly stereoregular polypropylene with improved properties |
| US8008412B2 (en) | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
| CN100436491C (zh) | 2002-10-09 | 2008-11-26 | 巴塞尔聚烯烃意大利有限公司 | 烯烃的气相催化聚合 |
| KR101102793B1 (ko) * | 2002-12-18 | 2012-01-05 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 올레핀 중합용 촉매 성분 |
| JP5073291B2 (ja) | 2003-05-29 | 2012-11-14 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 触媒成分の製造方法およびそれから得られる成分 |
| CN100582125C (zh) | 2003-08-20 | 2010-01-20 | 巴塞尔聚烯烃意大利有限责任公司 | 用于乙烯聚合的方法和装置 |
| JP4988568B2 (ja) | 2004-07-08 | 2012-08-01 | エクソンモービル・ケミカル・パテンツ・インク | オレフィン重合触媒系およびその使用方法 |
| WO2006040240A1 (en) * | 2004-10-14 | 2006-04-20 | Basell Poliolefine Italia S.R.L. | Process for the gas-phase polymerization of olefins |
| DE602004015128D1 (de) | 2004-12-17 | 2008-08-28 | Borealis Tech Oy | Verfahren zur Polymerisation von Olefinen in Gegenwart eines Olefin Polymerisationskatalysators |
| DE102005005506A1 (de) * | 2005-02-04 | 2006-08-10 | Basell Polyolefine Gmbh | Verfahren und Vorrichtung zur Polymerisation von Ethylen |
| WO2006103171A1 (en) | 2005-03-30 | 2006-10-05 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins |
| US7834117B2 (en) | 2005-03-30 | 2010-11-16 | Basell Poliolefine Italia S.R.L. | Process for preparing crystalline ethylene (co)polymers |
| BRPI0611460A2 (pt) * | 2005-03-30 | 2010-09-08 | Basell Poliolefine Srl | componentes catalìticos para a polimerização de olefinas |
| EP1896513B1 (en) | 2005-05-13 | 2010-01-20 | Basell Poliolefine Italia S.r.l. | Process for the gas-phase polymerization of olefins |
| JP2009509017A (ja) * | 2005-09-19 | 2009-03-05 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | オレフィン類の気相重合方法 |
| JP5092260B2 (ja) * | 2005-09-21 | 2012-12-05 | 住友化学株式会社 | オレフィン重合体の製造方法 |
| RU2444547C2 (ru) * | 2006-08-04 | 2012-03-10 | Базелль Полиолефин Италия С.Р.Л. | Газофазный способ получения гетерофазных сополимеров пропилена |
| WO2008061662A1 (en) * | 2006-11-21 | 2008-05-29 | Basell Poliolefine Italia S.R.L. | Catalyst component for the polymerization of olefins |
| CN101568560B (zh) * | 2006-12-20 | 2011-09-14 | 巴塞尔聚烯烃意大利有限责任公司 | 用于烯烃聚合的催化剂组分及由此得到的催化剂 |
| US8242237B2 (en) | 2006-12-20 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Phase separator and monomer recycle for supercritical polymerization process |
| WO2008077770A1 (en) | 2006-12-22 | 2008-07-03 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins and catalysts therefrom obtained |
| ES2446294T3 (es) | 2007-06-04 | 2014-03-07 | Exxonmobil Chemical Patents Inc. | Polimerización de propileno en un sistema homogéneo en condiciones de superdisolución |
| CN101168576B (zh) * | 2007-11-30 | 2011-04-20 | 北京三聚环保新材料股份有限公司 | 一种聚烯烃催化剂制备工艺 |
| US8084557B2 (en) | 2007-12-18 | 2011-12-27 | Basell Polyolefine Gmbh | Gas-phase process for the polymerization of alpha-olefins |
| JP2011506718A (ja) * | 2007-12-20 | 2011-03-03 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 改良された特性を有する高立体規則性ポリプロピレン |
| CN101910208B (zh) * | 2007-12-28 | 2012-09-19 | 巴塞尔聚烯烃意大利有限责任公司 | 用于烯烃聚合的催化剂组分 |
| US8318875B2 (en) | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
| EP2315786A1 (en) | 2008-08-20 | 2011-05-04 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins and catalysts therefrom obtained |
| US10125200B2 (en) | 2008-09-26 | 2018-11-13 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins |
| CN102459362B (zh) | 2009-06-18 | 2015-04-29 | 巴塞尔聚烯烃意大利有限责任公司 | 用于烯烃聚合的催化剂组分以及由其所获得的催化剂 |
| CN102030841B (zh) * | 2009-09-29 | 2012-07-04 | 中国石油化工股份有限公司 | 一种丙烯气相聚合方法 |
| EP2330135B1 (en) | 2009-12-02 | 2012-11-07 | Borealis AG | Process for producing polyolefins |
| BR112013004167B1 (pt) | 2010-08-24 | 2020-02-04 | Basell Poliolefine Italia Srl | componente catalisador sólido, processo para sua preparação e catalisador para a polimerização de olefinas |
| US10138310B2 (en) | 2010-08-24 | 2018-11-27 | Equistar Chemicals, Lp | Preparation of LLDPE resins and films having low gels |
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| EP2518090A1 (en) | 2011-04-28 | 2012-10-31 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins and catalysts therefrom obtained |
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- 1992-06-03 KR KR1019920703325A patent/KR100218863B1/ko not_active Expired - Lifetime
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