EP2251207A1 - Caractéristique de sécurité et procédé destiné à sa fabrication - Google Patents
Caractéristique de sécurité et procédé destiné à sa fabrication Download PDFInfo
- Publication number
- EP2251207A1 EP2251207A1 EP09006340A EP09006340A EP2251207A1 EP 2251207 A1 EP2251207 A1 EP 2251207A1 EP 09006340 A EP09006340 A EP 09006340A EP 09006340 A EP09006340 A EP 09006340A EP 2251207 A1 EP2251207 A1 EP 2251207A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- layers
- security feature
- oxides
- oxide
- alloys
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 15
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 239000003550 marker Substances 0.000 title abstract 4
- 239000000758 substrate Substances 0.000 claims abstract description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052802 copper Inorganic materials 0.000 claims abstract description 5
- 229910052709 silver Inorganic materials 0.000 claims abstract description 5
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 4
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 4
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 4
- 239000003086 colorant Substances 0.000 claims abstract description 4
- 239000010959 steel Substances 0.000 claims abstract description 4
- 108091005950 Azurite Proteins 0.000 claims abstract description 3
- 229910000640 Fe alloy Inorganic materials 0.000 claims abstract description 3
- 241000907663 Siproeta stelenes Species 0.000 claims abstract description 3
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 3
- 229910052793 cadmium Inorganic materials 0.000 claims abstract description 3
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052737 gold Inorganic materials 0.000 claims abstract description 3
- 229910052742 iron Inorganic materials 0.000 claims abstract description 3
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 3
- 229910052718 tin Inorganic materials 0.000 claims abstract description 3
- GWBUNZLLLLDXMD-UHFFFAOYSA-H tricopper;dicarbonate;dihydroxide Chemical compound [OH-].[OH-].[Cu+2].[Cu+2].[Cu+2].[O-]C([O-])=O.[O-]C([O-])=O GWBUNZLLLLDXMD-UHFFFAOYSA-H 0.000 claims abstract description 3
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 claims description 14
- 229910045601 alloy Inorganic materials 0.000 claims description 7
- 239000000956 alloy Substances 0.000 claims description 7
- 239000000969 carrier Substances 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 5
- 150000002739 metals Chemical class 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- 239000002195 soluble material Substances 0.000 claims description 4
- 230000003287 optical effect Effects 0.000 claims description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 2
- 229910017518 Cu Zn Inorganic materials 0.000 claims description 2
- 229910017752 Cu-Zn Inorganic materials 0.000 claims description 2
- 229910017767 Cu—Al Inorganic materials 0.000 claims description 2
- 229910017943 Cu—Zn Inorganic materials 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000002537 cosmetic Substances 0.000 claims description 2
- 239000003814 drug Substances 0.000 claims description 2
- 239000005022 packaging material Substances 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 239000010949 copper Substances 0.000 abstract description 10
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract description 4
- 239000011651 chromium Substances 0.000 abstract description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract description 2
- UOUJSJZBMCDAEU-UHFFFAOYSA-N chromium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Cr+3].[Cr+3] UOUJSJZBMCDAEU-UHFFFAOYSA-N 0.000 abstract description 2
- 239000010931 gold Substances 0.000 abstract description 2
- 239000004332 silver Substances 0.000 abstract description 2
- 239000011701 zinc Substances 0.000 abstract description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical class [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- 229910000838 Al alloy Inorganic materials 0.000 abstract 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005751 Copper oxide Substances 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 239000005083 Zinc sulfide Substances 0.000 abstract 1
- 229910001297 Zn alloy Inorganic materials 0.000 abstract 1
- JRBRVDCKNXZZGH-UHFFFAOYSA-N alumane;copper Chemical compound [AlH3].[Cu] JRBRVDCKNXZZGH-UHFFFAOYSA-N 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 abstract 1
- 229910000416 bismuth oxide Inorganic materials 0.000 abstract 1
- 229940036359 bismuth oxide Drugs 0.000 abstract 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910000431 copper oxide Inorganic materials 0.000 abstract 1
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 abstract 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 abstract 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 1
- 235000013980 iron oxide Nutrition 0.000 abstract 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 abstract 1
- 239000004973 liquid crystal related substance Substances 0.000 abstract 1
- OTCVAHKKMMUFAY-UHFFFAOYSA-N oxosilver Chemical class [Ag]=O OTCVAHKKMMUFAY-UHFFFAOYSA-N 0.000 abstract 1
- 229910001923 silver oxide Inorganic materials 0.000 abstract 1
- SKRWFPLZQAAQSU-UHFFFAOYSA-N stibanylidynetin;hydrate Chemical compound O.[Sn].[Sb] SKRWFPLZQAAQSU-UHFFFAOYSA-N 0.000 abstract 1
- 239000011135 tin Substances 0.000 abstract 1
- QHGNHLZPVBIIPX-UHFFFAOYSA-N tin(ii) oxide Chemical class [Sn]=O QHGNHLZPVBIIPX-UHFFFAOYSA-N 0.000 abstract 1
- 239000004408 titanium dioxide Substances 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
- 229910052984 zinc sulfide Inorganic materials 0.000 abstract 1
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 abstract 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 49
- 238000000576 coating method Methods 0.000 description 11
- 239000011248 coating agent Substances 0.000 description 10
- 239000004922 lacquer Substances 0.000 description 7
- 239000000049 pigment Substances 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 229910052786 argon Inorganic materials 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 150000002736 metal compounds Chemical class 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 238000004544 sputter deposition Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 239000002318 adhesion promoter Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004920 heat-sealing lacquer Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000005240 physical vapour deposition Methods 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- 235000016299 Canarium odontophyllum Nutrition 0.000 description 1
- 244000001582 Canarium odontophyllum Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004696 Poly ether ether ketone Substances 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- JUPQTSLXMOCDHR-UHFFFAOYSA-N benzene-1,4-diol;bis(4-fluorophenyl)methanone Chemical compound OC1=CC=C(O)C=C1.C1=CC(F)=CC=C1C(=O)C1=CC=C(F)C=C1 JUPQTSLXMOCDHR-UHFFFAOYSA-N 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 238000005566 electron beam evaporation Methods 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 1
- 229920002457 flexible plastic Polymers 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- -1 for example of PI Substances 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000010884 ion-beam technique Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000012939 laminating adhesive Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920001643 poly(ether ketone) Polymers 0.000 description 1
- 229920006260 polyaryletherketone Polymers 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000010944 silver (metal) Substances 0.000 description 1
- 238000002207 thermal evaporation Methods 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/40—Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
- D21H21/42—Ribbons or strips
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/40—Manufacture
- B42D25/405—Marking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/355—Security threads
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/40—Manufacture
- B42D25/405—Marking
- B42D25/43—Marking by removal of material
-
- B42D2033/10—
-
- B42D2035/24—
Definitions
- the invention relates to a security feature for data carriers, such as value documents and the like, which is applied to a data carrier or at least partially embedded in a data carrier or at least partially closes an opening of the data carrier by application to or at least partial embedding in the data carrier, as well as a method for its production.
- Security elements with so-called see-through registers, ie recognizable recesses in transmitted light are known.
- Security elements with visually visible features are for example off EP - A 0 330 733 known.
- security elements in particular security threads consisting of a translucent plastic film, an over the entire security element extending opaque coating having recesses in the form of the coding to be introduced, in particular in the form of characters and patterns described.
- coloring and / or luminescent substances may be present at least in the regions defined by the recesses, by means of which the coding differs from the opaque coating under the corresponding influence of light in contrasting color.
- the object of the invention was a security feature that has different partial optical features on front and back, which are interrupted by recesses, these recesses result in transmitted light a clear sharply defined image. Another object of the invention was to provide a method for producing such a security feature.
- the subject of the invention is therefore a security feature comprising a carrier substrate with at least two partial layers, characterized in that the two layers have different colors or Have color impressions and in each case at least partially transparent recesses, wherein the layers are applied absolutely congruent to each other without tolerances.
- Carrier foils are for example carrier foils, preferably flexible plastic foils, for example of PI, PP, OPP, PE, PPS, PEEK, PEK, PEI, PSU, PAEK, LCP, PEN, PBT, PET, PA, PC, COC, POM, ABS, PVC fluoropolymers such as Teflon and the like in question.
- the carrier films preferably have a thickness of 4 to 700 ⁇ m, preferably 4 to 200 ⁇ m, particularly preferably 4 to 125 ⁇ m.
- the carrier substrate may already have a layer with a structured lacquer layer.
- the lacquer layer can be a radiation-curable lacquer layer or a thermoplastic lacquer layer mixed with stabilizers into which a structure, for example a surface relief, a diffraction structure, a diffraction grating or a hologram, is embossed by means of known methods.
- the structure is then stabilized, for example by electromagnetic radiation, or by curing the thermoplastic lacquer layer, which is influenced by the stabilizers.
- metals, metal compounds or alloys come into question.
- Suitable metals include, for example, Al, Cu, Fe, Ag, Au, Cr, Ni, Zn, Cd, Bi, Sn and the like.
- metal compounds are oxides or sulfides or chromates of metals, in particular TiO 2 , Cr oxides, ZnS, ITO, Bi oxide, ATO, FTO, ZnO, Al 2 O 3 , unstoichiometric aluminum oxide, Zn chromate, Fe oxides.
- Cu oxides, unstoichiometric Cu oxide, Ag oxides and the like or silicon oxides are suitable.
- Suitable alloys are, for example, Cu-Al alloys, Cu-Zn alloys, iron alloys, steel, for example Cr-Ni steel and the like.
- the deposited metal compounds may also be doped with rare earth metals. This gives in addition to the desired color in addition a luminescent effect.
- copper color pigments such as azurite or malachite can be vapor-deposited.
- the layer thickness of the vapor-deposited layer essentially depends on the desired color.
- a Bi oxide layer approximately at least 160-230 nm thick, as well as a TiO 2 layer blue transparent, a ZnS layer green, a Cd layer yellow, an Al layer in conjunction with Fe 2 O 3 orange to purple , where the hue is controlled by the energy input. If Cu is vapor-deposited under an excess of oxygen, the coating appears blue. Evaporated ZnO appears reddish transparent.
- the resulting color is dabai from the interaction of layer thickness and absorption behavior.
- a solvent-soluble material application is applied in a first step on one side of the carrier substrate, in a second step optionally this layer is optionally treated by means of an in-line plasma, corona or flame process and in a third step the layers are applied successively, whereupon, in a fourth step, the material application with the layers located in the region of the material application is simultaneously removed by means of a solvent, optionally combined with a mechanical action.
- the application of the material application can by any method, for example by gravure, flexographic printing, screen printing, digital printing and the like.
- the material used for this purpose or the lacquer used or the ink used is soluble in a solvent, preferably in water, but it is also possible to use a dye which is soluble in any desired solvent, for example in alcohol, esters and the like.
- the material or the paint or the color may be conventional compositions based on natural or artificial macromolecules.
- the soluble material may be pigmented or unpigmented. As pigments, all known pigments can be used. Particularly suitable are TiO 2 , ZnS, kaolin and the like.
- the treatment is carried out by means of an in-line plasma (low pressure or atmospheric plasma), corona or flame process.
- High-energy plasma for example Ar or Ar / O 2 plasma, cleans the surface of possibly existing toning residues. In this case, the necessary sharp delimitation of the contours of the recesses is achieved for a partial application.
- the surface is activated. In this case, terminal polar groups are generated on the surface. This improves the adhesion of metals and the like to the surface.
- a thin metal or metal oxide layer can be applied as adhesion promoter, for example by sputtering or vapor deposition.
- adhesion promoter particularly suitable are Cr, Al, Ag, Ti, Cu, TiO 2 , Si oxides or chromium oxides.
- This adhesion promoter layer generally has a thickness of 0.1 nm to 5 nm, preferably 0.2 nm to 2 nm, particularly preferably 0.2 to 1 nm.
- the coating can be done in the usual way, by deposition in a PVD or CVD process, by sputtering or the like.
- the coating is applied under vacuum (to 10 -12 mbar, preferably 10 -2 to 10 -6 mbar) at a temperature dependent on the vapor pressure and the thickness of the applied coating on the carrier substrate, for example by thermal evaporation, arc or Electron beam evaporation deposited.
- vacuum to 10 -12 mbar, preferably 10 -2 to 10 -6 mbar
- the coating is applied by AC or DC sputtering, wherein the appropriate method is selected depending on the thickness of the layer to be applied and the material used.
- separating layers for example insulators, polymer layers and the like, may optionally be applied in-line or in a separate process step between the individual layers.
- gaseous precursor compounds eg organometallic precursor compounds
- precursors gaseous precursor compounds
- an inert carrier gas eg N 2 , argon
- gaseous precursors can be, for example, CO, CO 2 , oxygen, silanes, methane, ammonia, ferrocene, trimethylaluminum, or the like.
- the introduction of energy can be done for example by means of an ion or electron beam, a plasma or at elevated temperature. In this way, several reactive layers can be applied simultaneously or in succession, on the carrier substrate creates a color effect.
- the material application is removed by a suitable solvent, which is tailored to the composition of the material application.
- the material application is preferably water-soluble.
- the separation can be supported by mechanical action.
- a thin pigmented color layer or a pure pigment layer can also be applied with registration accuracy, the thickness of this layer being approximately 0.01-5 ⁇ m.
- the method described can also be carried out several times in succession, if necessary with different layer combinations.
- a protective layer can be applied between the different layer combinations.
- the security feature may optionally have further layers, for example the already mentioned diffractive structures, but also preferably partial liquid-crystalline layers, layers with optical features, for example colored layers, luminescent layers and / or layers with electrically conductive and / or magnetic features.
- the security feature according to the invention may optionally have further auxiliary layers, such as laminating adhesive layers, hot-cold-sealing or self-adhesive layers, release layers and the like.
- FIGS. 1 to 3 security features according to the invention are shown. 1, the carrier substrate, 2 the soluble material application, 3, 4, 5, 6, the layers with different color impressions.
- Fig. 1 an exemplary structure is shown before demetalling.
- Fig. 2 is the in Fig. 1 shown structure after demetallization shown.
- Fig. 3 represents a structure with two different layer combinations.
- security features according to the invention if appropriate after appropriate assembly (for example into threads, tapes, strips, patches or other formats), can therefore be used as security features for at least partial embedding in or for application to data carriers, in particular value documents such as identity cards, cards, banknotes or labels, seals and the like but also used in packaging materials for sensitive goods such as pharmaceuticals, cosmetics, data carriers, electronic components and the like.
- the security features according to the invention can be used to particular advantage for the at least partial closing of openings in data carriers and value documents.
- the security element is visible both from the front and in the opening from the back and the different color impressions on the front and back are clearly recognizable and distinguishable.
- the two-sided color impression is particularly advantageous if it is glued on a transparent or translucent support.
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Laminated Bodies (AREA)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP09006340.5A EP2251207B1 (fr) | 2009-05-11 | 2009-05-11 | Procédé de fabrication d'une marque de sécurité |
PCT/EP2010/000818 WO2010130301A1 (fr) | 2009-05-11 | 2010-02-10 | Caractéristique de sécurité et son procédé de production |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP09006340.5A EP2251207B1 (fr) | 2009-05-11 | 2009-05-11 | Procédé de fabrication d'une marque de sécurité |
Publications (2)
Publication Number | Publication Date |
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EP2251207A1 true EP2251207A1 (fr) | 2010-11-17 |
EP2251207B1 EP2251207B1 (fr) | 2021-12-01 |
Family
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Application Number | Title | Priority Date | Filing Date |
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EP09006340.5A Active EP2251207B1 (fr) | 2009-05-11 | 2009-05-11 | Procédé de fabrication d'une marque de sécurité |
Country Status (2)
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EP (1) | EP2251207B1 (fr) |
WO (1) | WO2010130301A1 (fr) |
Families Citing this family (1)
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GB201301788D0 (en) | 2013-02-01 | 2013-03-20 | Rue De Int Ltd | Security devices and methods of manufacture thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3610379A1 (de) * | 1986-03-27 | 1987-10-01 | Helmuth Schmoock | Folie mit mindestens einer von einer metallschicht ueberdeckten oberflaeche sowie verfahren und vorrichtung zu ihrer herstellung |
EP0330733A1 (fr) | 1988-03-04 | 1989-09-06 | GAO Gesellschaft für Automation und Organisation mbH | Elément de sécurité en forme de fil ou de bande destiné à être incorporé dans un document de sécurité et procédé pour sa fabrication |
DE4041025A1 (de) * | 1990-12-20 | 1992-06-25 | Gao Ges Automation Org | Magnetischer, metallischer sicherheitsfaden mit negativschrift |
EP1291463A1 (fr) * | 2001-09-05 | 2003-03-12 | Hueck Folien Gesellschaft m.b.H. | Procédé de préparation d'un feuille métallisée sélectivement, et le produit correspondant |
DE102007055112A1 (de) * | 2007-01-05 | 2008-07-10 | Giesecke & Devrient Gmbh | Verfahren zur Herstellung von Sicherheitsfolien |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0490825B1 (fr) * | 1990-12-12 | 1995-03-15 | - Sihl - Zürcher Papierfabrik An Der Sihl | Papier de sécurité pour billets de banque ou similaires et procédé de fabrication |
ATE361844T1 (de) * | 2003-04-04 | 2007-06-15 | Landqart | Sicherheitsmerkmal |
-
2009
- 2009-05-11 EP EP09006340.5A patent/EP2251207B1/fr active Active
-
2010
- 2010-02-10 WO PCT/EP2010/000818 patent/WO2010130301A1/fr active Application Filing
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3610379A1 (de) * | 1986-03-27 | 1987-10-01 | Helmuth Schmoock | Folie mit mindestens einer von einer metallschicht ueberdeckten oberflaeche sowie verfahren und vorrichtung zu ihrer herstellung |
EP0330733A1 (fr) | 1988-03-04 | 1989-09-06 | GAO Gesellschaft für Automation und Organisation mbH | Elément de sécurité en forme de fil ou de bande destiné à être incorporé dans un document de sécurité et procédé pour sa fabrication |
DE4041025A1 (de) * | 1990-12-20 | 1992-06-25 | Gao Ges Automation Org | Magnetischer, metallischer sicherheitsfaden mit negativschrift |
EP1291463A1 (fr) * | 2001-09-05 | 2003-03-12 | Hueck Folien Gesellschaft m.b.H. | Procédé de préparation d'un feuille métallisée sélectivement, et le produit correspondant |
DE102007055112A1 (de) * | 2007-01-05 | 2008-07-10 | Giesecke & Devrient Gmbh | Verfahren zur Herstellung von Sicherheitsfolien |
Also Published As
Publication number | Publication date |
---|---|
WO2010130301A1 (fr) | 2010-11-18 |
EP2251207B1 (fr) | 2021-12-01 |
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