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EP1798054A2 - Éléments de sécurité codés optiquement actives - Google Patents

Éléments de sécurité codés optiquement actives Download PDF

Info

Publication number
EP1798054A2
EP1798054A2 EP06025187A EP06025187A EP1798054A2 EP 1798054 A2 EP1798054 A2 EP 1798054A2 EP 06025187 A EP06025187 A EP 06025187A EP 06025187 A EP06025187 A EP 06025187A EP 1798054 A2 EP1798054 A2 EP 1798054A2
Authority
EP
European Patent Office
Prior art keywords
layer
security element
metal compound
element according
security
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP06025187A
Other languages
German (de)
English (en)
Other versions
EP1798054A3 (fr
Inventor
Matthias Müller
Gottfried Brandstetter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hueck Folien GmbH
Original Assignee
Hueck Folien GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hueck Folien GmbH filed Critical Hueck Folien GmbH
Publication of EP1798054A2 publication Critical patent/EP1798054A2/fr
Publication of EP1798054A3 publication Critical patent/EP1798054A3/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/30—Identification or security features, e.g. for preventing forgery
    • B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
    • B42D25/373—Metallic materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
    • B42D25/29—Securities; Bank notes
    • B42D2033/10—
    • B42D2033/18—
    • B42D2033/20—
    • B42D2035/24—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/30—Identification or security features, e.g. for preventing forgery
    • B42D25/328—Diffraction gratings; Holograms

Definitions

  • the invention relates to security elements and security features, which optionally have an optically active element and a colored coding, processes for their preparation and their use.
  • Data carriers and documents of value such as banknotes, identification papers or the like, or packaging materials for sensitive goods, such as electronic components, pharmaceutical products and the like, are provided with security elements, for example in the form of threads, strips, tapes, patches or other formats, for verifiability of their authenticity.
  • security elements for example in the form of threads, strips, tapes, patches or other formats, for verifiability of their authenticity.
  • the information and encodings such as electrical conductivity, magnetic encodings, holograms or diffractive structures, characters, patterns, recesses, color and / or luminescent effects or sequences and the like having these security features, are becoming increasingly complex and expensive for increased security against counterfeiting achieve and make an exact replica almost impossible.
  • an additional visually unambiguous and recognizable feature on the data carrier, the valuable document or the packaging which serves not only as an optional additional security feature.
  • an unambiguous assignment of the data carrier, the value document or the packaging For example, be provided for a particular place of origin, a particular value or content, a particular brand or the like.
  • the object of the invention was to propose a security element which has a colored metallic or metallic appearing coding and optionally an optically variable feature.
  • the invention therefore relates to a security element for uniquely assignable identification and identification of data carriers, value documents and / or packaging and the like, comprising a carrier substrate, characterized in that the security element optionally an optically active feature and at least one full or partial reflector or mirror layer and has at least one in the register to the optically active element or to another security feature applied colored or transparent metal compound layer.
  • Another object of the invention is a film material, characterized in that it comprises a security feature, optionally an optically active feature and at least one full or partial reflector or mirror layer and at least one in register with the optically active element or to another security element applied colored or transparent metal compound layer.
  • Transparent carrier foils for example, preferably made from Pl, PP, MOPP, PE, PPS, PEEK, PEK, PEI, PSU, PAEK, LCP, PEN, PBT, PET, PA, PC, COC, are used as the carrier substrate for the security feature according to the invention.
  • the Carrier films preferably have a thickness of 5 to 700 .mu.m, preferably 5 to 200 .mu.m, particularly preferably 5 to 50 .mu.m.
  • the security feature may include an optically active feature.
  • Optically active features are diffraction structures, diffraction structures, nanostructures, holograms, kinegrams and the like. Such structures can be produced, for example, by embossing the corresponding structure in a radiation-curable, for example UV-curable or thermoplastic lacquer.
  • the carrier substrate is coated with a radiation-curable lacquer in a coating process such as, for example, a screen-printing, gravure or flexographic printing process.
  • a coating process such as, for example, a screen-printing, gravure or flexographic printing process.
  • the coating can be selective or full-surface.
  • the radiation-curable lacquer can contain, for example, a radiation-curable lacquer system based on a polyester, an epoxy or polyurethane system containing 2 or more different photoinitiators known to the person skilled in the art, which can initiate curing of the lacquer system to varying degrees at different wavelengths.
  • a photoinitiator can be activated at a wavelength of 200 to 400 nm, the second photoinitiator then activatable at a wavelength of 370 to 600 nm. Sufficient difference should be maintained between the activation wavelengths of the two photoinitiators to prevent over-excitation of the second photoinitiator while the first photoinitiator is activated.
  • the region in which the second photoinitiator is excited should be in the transmission wavelength range of the carrier substrate used.
  • electron radiation can also be used for the main cure (activation of the second photoinitiator) electron radiation can also be used.
  • a water-thinnable varnish can also be used. Preference is given to polyester-based paint systems.
  • the impression of the surface structure, ie the diffraction, diffraction or relief structure, for example, at controlled temperature by means of a die or using a stamping die in the radiation-curable lacquer layer, which was pre-cured by activation of the first photoinitiator to the gel point and at the time of molding in this stage is located. If a water-dilutable radiation-curable lacquer is used, it is optionally possible to precede predrying, for example by means of IR radiators.
  • the layer thickness of the applied radiation-curable lacquer can vary depending on the requirements of the end product and thickness of the substrate and is generally between 0.5 and 50 .mu.m, preferably between 1 and 10 .mu.m, more preferably between 1 and 5 .mu.m.
  • the carrier material or the embossed element is partially printed with a soluble in a solvent color.
  • the printed image is selected so that only a part of the optically active structure, or another security element is covered by the subsequent application of a layer of a metal compound.
  • the application of the paint can be done by any method, for example by gravure printing, flexographic printing, screen printing, digital printing and the like.
  • the paint or ink used is soluble in a solvent, preferably water, but it may be a color soluble in any solvent, for example in alcohol, esters and the like may be used.
  • the color or the colored lacquer can be customary compositions based on natural or artificial macromolecules.
  • the soluble color may be pigmented or unpigmented.
  • pigments all known pigments can be used. Particularly suitable are TiO 2 , ZnS, kaolin and the like.
  • Suitable coating materials are metal compounds, for example oxides or sulfides.
  • metal compounds are oxides or sulfides (or chromates) of metals, in particular TiO 2 , Cr oxides, ZnS, ITO, Bi oxide, ATO, FTO, ZnO, Al 2 O 3 , Zn chromate, Fe oxides, CuO and the like, or silicon oxides.
  • the metal compounds may also be doped with rare earth metals. This gives in addition to the desired color in addition a luminescent effect.
  • copper color pigments such as azurite or malachite can be vapor-deposited.
  • the layer thickness of the (vapor-deposited) layer essentially depends on the desired color and is usually between 100 and 1000 nm, preferably 100 to 500 nm.
  • the metal compound can be applied in one or more layers, wherein the layer thickness determines the resulting color impression.
  • a Bi oxide layer approximately at least 160-230 nm thick, as well as a TiO 2 layer blue transparent, a ZnS layer green, a Cd layer yellow, an Al layer in conjunction with Fe 2 O 3 orange to purple , where the hue is controlled by the energy input. Will Cu evaporated under oxygen excess, the coating appears blue. Evaporated ZnO appears reddish transparent.
  • the coating is applied in a PVD or CVD process.
  • a PVD process the coating is applied under vacuum (to 10 -12 mbar, preferably 10 -2 to 10 -6 mbar) at a temperature dependent on the vapor pressure and the thickness of the applied coating on the carrier substrate, for example by thermal evaporation, arc or Electron beam evaporation deposited.
  • Another possibility is the application of the coating by AC or DC sputtering, wherein, depending on the thickness of the layer to be applied and the material used, the corresponding method is selected.
  • a CVD process by mixing the substance to be applied with a gas, plasma or with an activation gas, for example CO, CO 2 , oxygen, silanes, methane, ammonia and the like, for example: caused by a ion beam, a chemical reaction and the resulting material deposited on the carrier.
  • an activation gas for example CO, CO 2 , oxygen, silanes, methane, ammonia and the like, for example: caused by a ion beam, a chemical reaction and the resulting material deposited on the carrier.
  • the layer bearing the optically active feature is previously treated by means of an inline plasma, corona or flame process, and then the coating according to the invention is applied either inline or in a subsequent process step in a PVD or CVD process, sputtering or the like.
  • High-energy plasma for example Ar or Ar / O 2 plasma, cleans the surface of possibly existing toning residues.
  • the adhesion of the partial or full surface coatings is further improved.
  • the surface is activated. In this case, terminal polar groups are generated on the surface.
  • a thin metal or metal oxide layer can be applied as adhesion promoter, for example by sputtering or vapor deposition.
  • adhesion promoter particularly suitable are Cr, Al, Ag, Ti, Cu, TiO 2 , Si oxides or chromium oxides.
  • This adhesion promoter layer generally has a thickness of 0.1 nm to 5 nm, preferably 0.2 nm to 2 nm, particularly preferably 0.2 to 1 nm.
  • the paint application is removed by means of a solvent, optionally combined with a mechanical action.
  • a solvent optionally combined with a mechanical action.
  • the described process can be repeated using one or more further different metal compound layers, in those areas that were not covered by the first layer or at least partially overlapping to these areas.
  • the pure shades as well as mixed colors can be generated.
  • the application takes place in register, for example with an insetter method.
  • the coating of metal compounds can additionally have respectively defined features, for example recesses in the form of patterns, characters, lines, guilloches and the like.
  • a reflector or mirror layer is made preferably of a metallic layer, for example, Al, Cu, Fe, Ag, Au, Pt, Pd, Sn, Cr, Ni, Zn, and the like.
  • the optical density of the reflector or mirror layer is greater than 1.5 OD.
  • the coating is preferably applied in a PVD or CVD process, but it is also possible to apply it in a known printing process. If this reflector or mirror layer is to be applied only partially, the method is preferably carried out analogously to the method described above for applying a partial metal compound layer using a solvent-soluble ink.
  • coding can take place by defined application of different partial metal compound layers.
  • different metal compound layers can be applied in one plane.
  • these layers are then combined with a full-surface reflector or mirror layer.
  • multicolored appearing holograms, kinegrams, nanostructures, diffraction structures and the like can be generated.
  • such multicolor holograms can also be produced by applying a metal compound layer in different layer thicknesses.
  • hologram motifs with different metal compound layers or different layer thicknesses of the same metal compound layer can be deposited.
  • the different motifs different colors.
  • the metal compound layers, as well as the reflector or mirror layer may be applied over the entire surface or partially, with unique combinations resulting from different combinations.
  • the carrier substrate can already have defined functional layers or such functional layers can subsequently be applied to the carrier substrate.
  • These layers may, for example, have certain chemical, physical and also optical properties.
  • optical properties of a further layer can be visualized by visible dyes or pigments, luminescent dyes or pigments which fluoresce or phosphoresce in the visible, in the UV region or in the IR region, effect pigments, such as liquid crystals, bronzes and / or heat-sensitive inks or pigments influence. These can be used in all possible combinations.
  • phosphorescent pigments can also be used alone or in combination with other dyes and / or pigments.
  • partial electrically conductive layers may be present on the substrate, or to be applied subsequently, for example electrically conductive polymeric layers or conductive paint or lacquer layers.
  • metal pigments for example, copper, aluminum, silver, gold, iron, chromium and the like
  • metal alloys such as copper-zinc or Copper-aluminum or amorphous or crystalline ceramic pigments such as ITO, ATO, FTO and the like
  • doped or non-doped semiconductors such as, for example, silicon, germanium or doped or undoped polymeric semiconductors or ionic conductors such as amorphous or crystalline metal oxides or metal sulfides can be used as an additive.
  • polar or partially polar compounds such as surfactants, or nonpolar compounds such as silicone additives or hygroscopic or non-hygroscopic salts can be used or added to the paint for adjusting the electrical properties of the layer.
  • a partial metal layer can also be applied, wherein the partial application can be effected by means of an etching process (application of a full-surface metal layer and subsequent partial removal by etching) or by means of a demetallization process.
  • an electrically conductive polymer layer can also be applied as the electrically conductive layer.
  • the electrically conductive polymers may be, for example, polyaniline or polyethylenedioxythiophene. Particular preference is given to using PEDT / TS as the electrically conductive polymer.
  • paramagnetic, diamagnetic and also ferromagnetic materials such as iron, nickel, barium and cobalt or their compounds or salts (for example oxides or sulfides) may be used.
  • ferromagnetic materials such as iron, nickel, barium and cobalt or their compounds or salts (for example oxides or sulfides)
  • iron, nickel, barium and cobalt or their compounds or salts for example oxides or sulfides
  • Fe (II) and Fe (III) oxides barium or cobalt ferrites, rare earths and the like.
  • inventive security elements or film materials can be provided with a protective lacquer layer on one or both sides.
  • the protective lacquer may be pigmented or unpigmented, using as pigments all known pigments or dyes, for example TiO 2 , ZnS, kaolin, ATO, FTO, aluminum, chromium and silicon oxides or, for example, organic pigments such as pthalocyanine blue, i-indolid yellow, dioxazine violet and the like can be used.
  • luminescent dyes or pigments which fluoresce or phosphoresce in the visible, in the UV range or in the IR range, effect pigments such as liquid crystals, pearlescent, bronzes and / or multilayer color change pigments and heat-sensitive inks or pigments can be added. These can be used in all possible combinations.
  • luminescent pigments can also be used alone or in combination with other dyes and / or pigments.
  • the security element according to the invention may be provided on one or both sides with a hot or cold seal adhesive or a self-adhesive coating for application to or at least partial embedding in a substrate, which adhesive or adhesive coatings may be pigmented.
  • the security element according to the invention is characterized by high light resistance of the color impression achieved and high security against counterfeiting. Since reflecting colors result according to the invention, the security feature according to the invention can not be reproduced by color copying
  • the security element according to the invention can be used as easily recognizable security feature or authenticity or identification feature on data carriers, labels, in particular value documents, such as identity cards, cards, banknotes, on packaging materials in the pharmaceutical, electronics or food industry, original spare parts for cars, vehicles, aircraft become.
  • both the packaging and the product packed therein or, if appropriate, information which is packed with information, such as technical data sheets, instructions for use, assembly instructions and the like, are advantageously provided with a coating having a security feature with a defined color impression.

Landscapes

  • Business, Economics & Management (AREA)
  • Accounting & Taxation (AREA)
  • Finance (AREA)
  • Credit Cards Or The Like (AREA)
  • Laminated Bodies (AREA)
EP06025187A 2005-12-13 2006-12-06 Éléments de sécurité codés optiquement actives Withdrawn EP1798054A3 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
AT0197805A AT503712A2 (de) 2005-12-13 2005-12-13 Codierte optisch aktive sicherheitselemente und sicherheitsmerkmale

Publications (2)

Publication Number Publication Date
EP1798054A2 true EP1798054A2 (fr) 2007-06-20
EP1798054A3 EP1798054A3 (fr) 2011-03-09

Family

ID=37714627

Family Applications (1)

Application Number Title Priority Date Filing Date
EP06025187A Withdrawn EP1798054A3 (fr) 2005-12-13 2006-12-06 Éléments de sécurité codés optiquement actives

Country Status (2)

Country Link
EP (1) EP1798054A3 (fr)
AT (1) AT503712A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010102755A1 (fr) * 2009-03-09 2010-09-16 Hueck Folien Ges.M.B.H. Feuille de sécurité ou étiquette de sécurité présentant une preuve de manipulation

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1327531A1 (fr) * 2002-01-15 2003-07-16 ELMIVA S.a.s. di Walter Mantegazza & C. Elément de sécurité contre la contrefaction et la falsification de type hologramme et élément de sécurité similaire pour documents en général
DE10308305A1 (de) * 2003-02-26 2004-09-09 Giesecke & Devrient Gmbh Sicherheitselement
WO2004110771A2 (fr) * 2003-06-18 2004-12-23 Hueck Folien Ges.M.B.H. Elements de securite et attributs de securite a effets chromatiques
EP1580297A2 (fr) * 2004-03-26 2005-09-28 Hueck Folien Gesellschaft m.b.H. Matériau en feuille en particulier pour éléments de securité
EP1652688A1 (fr) * 2004-10-29 2006-05-03 Arjowiggins Security Dispositif de sécurité
US7085058B2 (en) * 2002-01-18 2006-08-01 Giesecke & Devrient Gmbh Security element with flip-flop color change effect and magnetic properties, article compromising such a security element and method for producing said security element and said article

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1327531A1 (fr) * 2002-01-15 2003-07-16 ELMIVA S.a.s. di Walter Mantegazza & C. Elément de sécurité contre la contrefaction et la falsification de type hologramme et élément de sécurité similaire pour documents en général
US7085058B2 (en) * 2002-01-18 2006-08-01 Giesecke & Devrient Gmbh Security element with flip-flop color change effect and magnetic properties, article compromising such a security element and method for producing said security element and said article
DE10308305A1 (de) * 2003-02-26 2004-09-09 Giesecke & Devrient Gmbh Sicherheitselement
WO2004110771A2 (fr) * 2003-06-18 2004-12-23 Hueck Folien Ges.M.B.H. Elements de securite et attributs de securite a effets chromatiques
EP1580297A2 (fr) * 2004-03-26 2005-09-28 Hueck Folien Gesellschaft m.b.H. Matériau en feuille en particulier pour éléments de securité
EP1652688A1 (fr) * 2004-10-29 2006-05-03 Arjowiggins Security Dispositif de sécurité

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010102755A1 (fr) * 2009-03-09 2010-09-16 Hueck Folien Ges.M.B.H. Feuille de sécurité ou étiquette de sécurité présentant une preuve de manipulation
US8857856B2 (en) 2009-03-09 2014-10-14 Hueck Folien Ges.M.B.H. Security foil or security label comprising a manipulation detection system

Also Published As

Publication number Publication date
AT503712A2 (de) 2007-12-15
EP1798054A3 (fr) 2011-03-09

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