EP1291463A1 - Procédé de préparation d'un feuille métallisée sélectivement, et le produit correspondant - Google Patents
Procédé de préparation d'un feuille métallisée sélectivement, et le produit correspondant Download PDFInfo
- Publication number
- EP1291463A1 EP1291463A1 EP02019580A EP02019580A EP1291463A1 EP 1291463 A1 EP1291463 A1 EP 1291463A1 EP 02019580 A EP02019580 A EP 02019580A EP 02019580 A EP02019580 A EP 02019580A EP 1291463 A1 EP1291463 A1 EP 1291463A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- carrier substrate
- paint
- film
- carrier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 41
- 239000011888 foil Substances 0.000 title description 7
- 239000000758 substrate Substances 0.000 claims abstract description 28
- 229910052751 metal Inorganic materials 0.000 claims abstract description 19
- 239000002184 metal Substances 0.000 claims abstract description 19
- 239000002904 solvent Substances 0.000 claims abstract description 13
- 239000004033 plastic Substances 0.000 claims abstract description 5
- 229920003023 plastic Polymers 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims abstract description 4
- 239000010410 layer Substances 0.000 claims description 57
- 239000003973 paint Substances 0.000 claims description 32
- 239000010408 film Substances 0.000 claims description 30
- 239000002346 layers by function Substances 0.000 claims description 16
- 239000011104 metalized film Substances 0.000 claims description 16
- 239000004922 lacquer Substances 0.000 claims description 12
- 239000002318 adhesion promoter Substances 0.000 claims description 11
- 229910045601 alloy Inorganic materials 0.000 claims description 11
- 239000000956 alloy Substances 0.000 claims description 11
- 238000000576 coating method Methods 0.000 claims description 11
- 239000011248 coating agent Substances 0.000 claims description 10
- 239000000853 adhesive Substances 0.000 claims description 9
- 239000012212 insulator Substances 0.000 claims description 8
- 150000002736 metal compounds Chemical class 0.000 claims description 8
- 230000001070 adhesive effect Effects 0.000 claims description 7
- 150000002739 metals Chemical class 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 239000004745 nonwoven fabric Substances 0.000 claims description 6
- 239000000123 paper Substances 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 6
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- -1 Cr-oxides Inorganic materials 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 230000003678 scratch resistant effect Effects 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 2
- 229910017518 Cu Zn Inorganic materials 0.000 claims description 2
- 229910017752 Cu-Zn Inorganic materials 0.000 claims description 2
- 229910017767 Cu—Al Inorganic materials 0.000 claims description 2
- 229910017943 Cu—Zn Inorganic materials 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 claims description 2
- 229910052737 gold Inorganic materials 0.000 claims description 2
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 claims description 2
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 229920000134 Metallised film Polymers 0.000 claims 2
- 239000012876 carrier material Substances 0.000 claims 2
- 238000009413 insulation Methods 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 10
- 238000007639 printing Methods 0.000 description 7
- 239000011651 chromium Substances 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 230000005855 radiation Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000004544 sputter deposition Methods 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 2
- 238000007646 gravure printing Methods 0.000 description 2
- 238000009832 plasma treatment Methods 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004696 Poly ether ether ketone Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- JUPQTSLXMOCDHR-UHFFFAOYSA-N benzene-1,4-diol;bis(4-fluorophenyl)methanone Chemical compound OC1=CC=C(O)C=C1.C1=CC(F)=CC=C1C(=O)C1=CC=C(F)C=C1 JUPQTSLXMOCDHR-UHFFFAOYSA-N 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- UOUJSJZBMCDAEU-UHFFFAOYSA-N chromium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Cr+3].[Cr+3] UOUJSJZBMCDAEU-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 229920002457 flexible plastic Polymers 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920001643 poly(ether ketone) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920006260 polyaryletherketone Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- 238000003847 radiation curing Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/0027—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using protective coatings or layers by lamination or by fusion of the coatings or layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/355—Security threads
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/40—Manufacture
- B42D25/405—Marking
- B42D25/43—Marking by removal of material
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06Q—DECORATING TEXTILES
- D06Q1/00—Decorating textiles
- D06Q1/04—Decorating textiles by metallising
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/40—Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
- D21H21/42—Ribbons or strips
-
- B42D2033/10—
Definitions
- the invention relates to a selectively metallized film, in particular for Use as a security element, especially in value documents, as well a method for producing the selectively metallized film.
- EP-A 0 330 733 are security elements, in particular Security threads consisting of a translucent plastic film, a extending over the entire security element extending opaque Coating, the recesses in the form of the coding to be introduced, especially in the form of characters and patterns known. At least in the areas defined by the recesses can be congruent coloring and / or luminescent substances may be present, through which the coding of the opaque coating under appropriate The influence of light differs in a contrasting color.
- security elements for use as security elements for value documents, in particular banknotes, identity documents and the like, it is necessary that these security elements, for example in thread or tape form as inconspicuous as possible in the carrier, in particular paper or the like, can be integrated. Therefore, it is necessary to strive for the smallest possible thickness of the security elements. Furthermore, however, at the same time a great precision in the dimensions of the recesses to be produced is necessary to ensure sufficient security against counterfeiting, since irregularities in the dimensions of the recesses forming a coding make it difficult to clearly establish the authenticity or any imitation. Furthermore, it is sometimes also desirable to register corresponding coatings and codings on both sides of the carrier substrate of the security element in order to ensure a mutual identification of the authenticity.
- the object of the invention is therefore to metallized films and a method to To provide their preparation, the disadvantages described above avoids and in particular due to the small thickness and at the same time high precision are particularly suitable as security elements in Value documents to be integrated.
- the task of Invention a metallized film and a method for their preparation to provide, the film is almost independent of the substrate structured layers of different metals, metal compounds, Alloys or insulators on one or both sides of the carrier substrate optionally, wherein the structured layers accurate registration should be produced.
- the invention therefore provides a selectively metallized film by providing a carrier substrate, applying one in one Solvent-soluble partial paint application with recesses in the form of a (negative) coding, treating the printed carrier film by means of a Inline plasma, corona or flame process, applying a thin Covering layer of metals, metal compounds, alloys and / or Insulators and detachment of the paint by the action of a Solvent optionally combined with a mechanical action.
- Another object is a method for producing a selectively metallized film, characterized in that on a carrier substrate in a first step, a paint application which is soluble in a solvent is applied to one or both sides of the carrier substrate in a second step, this layer is treated by means of an in-line plasma, corona or flame process, and in a third step, a layer of a material to be structured is applied, which layer may consist of metals, metal compounds, alloys or insulators, whereupon, in a fourth step, the paint application is removed by means of a solvent, optionally combined with a mechanical action.
- carrier foils are preferably flexible plastic foils, for example, from Pl, PP, MOPP, PE, PPS, PEEK, PEK, PEI, PSU, PAEK, LCP, PEN, PBT, PET, PA, PC, COC, POM, ABS, PVC in question.
- the carrier films preferably have a thickness of 5 to 700 .mu.m, preferably 8 to 200 .mu.m, more preferably 12 to 50 .mu.m.
- metal foils for example Al, Cu, Sn, Ni, Fe or stainless steel foils having a thickness of 5-200 ⁇ m, preferably 10 to 80 ⁇ m, particularly preferably 20-50 ⁇ m, may also serve as the carrier substrate.
- the films can also be surface-treated, coated or laminated, for example, with plastics or painted.
- carrier substrates also paper or composites with paper, for example, composites with plastics with a grammage 20-500 g / m 2, preferably 40-200 g / m 2. be used.
- nonwovens such as continuous fiber webs, staple fiber webs and the like, which may optionally be needled or calendered, can be used as carrier substrates.
- nonwovens consist of plastics, such as PP, PET, PA, PPS and the like, but it is also possible to use nonwovens of natural, optionally treated fibers, such as viscose fiber webs.
- the nonwovens used have a basis weight of about 20 g / m 2 to 500 g / m 2 .
- the carrier substrates may additionally comprise a lacquer layer which unstructured or structured, for example can be embossed Die Paint layer, for example, an adhesive paint layer or a be releasable transfer lacquer layer, it can by radiation, For example, UV radiation, thermally or reactively crosslinked or crosslinkable and additional properties such as e.g. Scratch-resistant and / or antistatic Have equipment or chemical resistance.
- Suitable are both aqueous and solvent-containing coating systems, in particular also Lacquer systems based on PE - acrylate, PET acrylate, urethane acrylate, PVC, PMMA or epoxy acrylate.
- the carrier substrate can on one or both sides with a hot or Be provided cold seal adhesive or a self-adhesive coating.
- the surface of the carrier substrate may be structured or unstructured, or for example, be embossed with micro or macrolines, that is on the Surface may optionally have two- or three-dimensional structures to be available.
- the application of the paint can be done by any method, for example by gravure printing, flexographic printing, screen printing, digital printing and the like.
- the color or lacquer used is soluble in a solvent, preferably water, but it is also possible to use a dye soluble in any solvent, for example in alcohol, esters and the like.
- the color or the colored lacquer can be customary compositions based on natural or artificial macromolecules.
- the soluble color may be pigmented or unpigmented.
- pigments all known pigments can be used. Particularly suitable are TiO 2 , ZnS, kaolin and the like.
- the printed carrier substrate is treated by means of an in-line plasma (low pressure or atmospheric plasma), corona or flame process.
- High-energy plasma for example Ar or Ar / O 2 plasma, cleans the surface of toning residues of the printing inks. The necessary sharp delimitation of the contours of the recesses, which is necessary for the necessary precision of the coding is achieved.
- the surface is activated. In this case, terminal polar groups are generated on the surface. This improves the adhesion of metals and the like to the surface.
- a thin metal or metal oxide layer can be applied as adhesion promoter, for example by sputtering or vapor deposition.
- adhesion promoter particularly suitable are Cr, Al, Ag, Ti, Cu, TiO 2 , Si oxides or chromium oxides.
- This adhesion promoter layer generally has a thickness of 0.1 nm to 5 nm, preferably 0.2 nm to 2 nm, particularly preferably 0.2 to 1 nm.
- This layer consists of a metal, a metal compound, an alloy or an insulator.
- the metal layer layers of Al, Cu, Fe, Ag, Au, Cr, Ni, Zn and the like are suitable.
- suitable metal compounds are oxides or sulfides of metals, in particular TiO 2 , Cr oxides, ZnS, ITO, ATO, FTO, ZnO, Al 2 O 3 or silicon oxides.
- Suitable alloys are, for example, Cu-Al alloys, Cu-Zn alloys and the like.
- the radiation-curing can be, for example, by heat or UV radiation, suitable.
- This functional layer can be prepared by known methods, for example by sputtering, sputtering, printing (gravure, flexo, screen, digital printing and the like), spraying, electroplating and the like.
- the Thickness of the functional layer is 0.001 to 50 ⁇ m, preferably 0.1 to 20 ⁇ m.
- the ink layer by a suitable solvent, the on the composition of the color layer is matched, removed.
- the paint is water-soluble.
- the replacement by mechanical action are supported.
- the thickness of this layer is about 0.01 - 5 microns.
- the desired end product is obtained.
- the carrier film can be applied.
- the layers applied one on top of the other can be used have different properties. It is possible by Combination of different properties of the individual layers, For example, layers with different conductivity, magnetizability, optical properties, absorption behavior and the like structures for Example of security features with several precise authentication features manufacture.
- adhesion promoter can be advantageous.
- the thus produced coated film also by a protective lacquer layer are protected or, for example, by laminating or the like further refined.
- the metallized films according to the invention are in particular as Security elements, in particular in value documents and data carriers, For example, banknotes, securities, identity documents, cards and used or as security elements or security labels in packaging, textiles, seals and the like.
- the films according to the invention are also suitable for producing Embedding in banknotes and the like suitable.
- the product can be applied with a sealable adhesive, such as a hot or cold seal adhesive to the appropriate substrate, or embedded in paper for security papers by conventional methods, for example.
- sealants can be equipped with visible or visible in the UV light, fluorescent, phosphorescent or laser and IR radiation absorbing features to increase the security against counterfeiting.
- These features may also be present in the form of patterns or characters or show color effects, in principle any number of colors, preferably 1 to 10 colors or color mixtures, are possible.
- the carrier substrate may be used after one-sided coating after application be removed or left on the product.
- the carrier film optionally specially equipped on the uncoated side be scratch resistant, antistatic and the like. The same applies to a possible lacquer layer on the carrier substrate.
- a water-soluble ink layer based on a thickness of 3 microns is applied by gravure, with recesses are provided in the form of letters.
- the printed film is subjected to a low-pressure plasma process with Ar plasma and simultaneously applied a layer of Cr as a primer with a thickness of 0.3 nm. Then it is steamed with Al.
- the layer thickness of the vapor-deposited layer is 0.2 ⁇ m.
- the film is washed with water and thus the paint application is removed with the adhesion promoter on the paint application and the metal layer located in this area.
- the finished product has a selective Al coating with a coding in the form of letters.
- a water-soluble ink based on 9 wt% TiO 2 pigments with recesses in the form of defined lines is applied.
- the printed film is subjected to a corona process and at the same time a layer of silicon dioxide is applied as a primer with a thickness of 0.3 nm.
- the thus treated film is vapor-deposited with Cu, wherein the thickness of the layer is 0.5 microns.
- the film is washed with water and thus the paint application is removed with the adhesion promoter on the paint application and the metal layer located in this area.
- the film now has a selective metallic coating in the form of defined lines.
- a film prepared according to Example 1 is subjected to a plasma treatment with Ar / O 2 plasma and then printed over the entire surface of a functional layer of a urethane coating system by gravure printing. Subsequently, the thus treated film is provided with a paint with an alcohol-soluble ink with 10% ZnS as a pigment, wherein partially with the recesses of the first inking overlapping recesses are provided in the form of a pattern. Subsequently, the film is again subjected to a plasma treatment with Ar / O 2 plasma and simultaneously applied a 0.2 nm thick layer of chromium (III) oxide as a primer. Subsequently, a layer of Al is sprayed with a layer thickness of 0.2 microns. Subsequently, a washing process is carried out with alcohol, which in turn the paint application is replaced with the layers thereon.
- Example 2 It is produced a film analogous to Example 1, although all there described process steps on both sides of the carrier film passer- and be carried out in register.
- the film thus produced is subsequently with a protective lacquer layer with a fluorescent color in UV light Mistake.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Laminated Bodies (AREA)
- Printing Methods (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10143523A DE10143523B4 (de) | 2001-09-05 | 2001-09-05 | Verfahren zur Herstellung einer selektiv metallisierten Folie |
| DE10143523 | 2001-09-05 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1291463A1 true EP1291463A1 (fr) | 2003-03-12 |
| EP1291463B1 EP1291463B1 (fr) | 2014-12-10 |
Family
ID=7697813
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP02019580.6A Expired - Lifetime EP1291463B1 (fr) | 2001-09-05 | 2002-09-02 | Procédé de préparation d'un feuille métallisée sélectivement, et le produit correspondant |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP1291463B1 (fr) |
| DE (1) | DE10143523B4 (fr) |
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1516957A1 (fr) * | 2003-09-17 | 2005-03-23 | Hueck Folien Ges.m.b.H | Element de securité avec indications colorées |
| EP1516956A1 (fr) * | 2003-09-17 | 2005-03-23 | Hueck Folien Ges.m.b.H | Element de securité avec indications colorées négatives |
| WO2005043965A2 (fr) * | 2003-10-29 | 2005-05-12 | Steiner Gmbh & Co. Kg | Transpondeur |
| WO2005082201A1 (fr) * | 2004-03-01 | 2005-09-09 | Schreiner Group Gmbh & Co. Kg | Porte-echantillons, de preference pour un produit cosmetique |
| EP1746208A1 (fr) | 2005-07-19 | 2007-01-24 | Hueck Folien GmbH & Co. KG | Procédé pour la fabrication d'un substrat partiellement metallisé |
| EP2135987A1 (fr) * | 2008-06-20 | 2009-12-23 | Commissariat à l'Energie Atomique (Etablissement Public) | Procédé de dépôt de capteurs sur un support poreux |
| EP2154084A1 (fr) | 2008-08-14 | 2010-02-17 | Hueck Folien Ges.m.b.H. | Feuille adaptée à la fabrication d'un sac tubulaire, sac tubulaire et procédé de fabrication de la feuille |
| WO2010041226A1 (fr) * | 2008-10-10 | 2010-04-15 | Arjowiggins Security | Procédé de fabrication d'un document de sécurité |
| EP2177645A1 (fr) | 2008-09-29 | 2010-04-21 | Hueck Folien Ges.m.b.H. | Procédé de structuration de couches anorganiques ou organiques |
| US7767591B2 (en) * | 2005-04-22 | 2010-08-03 | Steiner Gmbh & Co. Kg | Method and device for producing electronic components |
| CN101581061B (zh) * | 2008-05-13 | 2010-11-03 | 上海纳尔实业有限公司 | 一种导气槽车身贴的制作方法 |
| EP2251207A1 (fr) * | 2009-05-11 | 2010-11-17 | HUECK Folien Ges.m.b.H. | Caractéristique de sécurité et procédé destiné à sa fabrication |
| EP2420391A2 (fr) | 2010-07-19 | 2012-02-22 | Hueck Folien Ges.m.b.H. | Elément de sécurité doté d'une couche optiquement variable |
| WO2012153114A1 (fr) * | 2011-05-06 | 2012-11-15 | D W Spinks (Embossing) Limited | Dispositif de sécurité fenêtré |
| WO2014013410A1 (fr) | 2012-07-16 | 2014-01-23 | Arjowiggins Security | Structure de securite |
| EP2851194A1 (fr) | 2013-09-20 | 2015-03-25 | Hueck Folien Ges.m.b.H | Elément de sécurité, notamment étiquette de sécurité |
| GB2527764A (en) * | 2014-06-30 | 2016-01-06 | Innovia Films Ltd | Process |
| GB2527763A (en) * | 2014-06-30 | 2016-01-06 | Innovia Films Ltd | Process |
| EP1972462B2 (fr) † | 2007-01-05 | 2019-09-18 | Giesecke+Devrient Currency Technology GmbH | Procédé de fabrication de feuilles de sécurité, et feuilles de sécurité |
| DE102020207090A1 (de) | 2020-06-05 | 2021-12-09 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung eingetragener Verein | Verfahren zum Herstellen eines strukturierten Objekts auf einem flexiblen Substrat durch elektrohydrodynamisches Drucken |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT412273B (de) | 2001-12-07 | 2004-12-27 | Hueck Folien Gmbh | Verfahren zur herstellung von registergenau gedruckten multilayer-aufbauten, nach diesem verfahren hergestellte produkte und deren verwendung |
| AT412267B (de) | 2002-03-27 | 2004-12-27 | Hueck Folien Gmbh | Uv-kaschierter sicherheitsfaden |
| DE102008030409A1 (de) † | 2008-06-27 | 2009-12-31 | Giesecke & Devrient Gmbh | Sicherheitselement mit Aussparung und Verfahren zur Herstellung desselben |
| DE102011002077B4 (de) * | 2011-04-15 | 2020-12-10 | Kunststoff-Institut Für Die Mittelständische Wirtschaft Nrw Gmbh (Kimw Nrw Gmbh) | Verfahren zum Herstellen eines mit wenigstens einem elektrischen Funktionsteil versehenen Kunststoffwerkstückes |
| DE102013108666A1 (de) | 2013-08-09 | 2015-03-05 | Leonhard Kurz Stiftung & Co. Kg | Verfahren zur Herstellung eines Mehrschichtkörpers sowie Mehrschichtkörper |
| DE102015010744A1 (de) | 2015-08-17 | 2017-02-23 | Giesecke & Devrient Gmbh | Sicherheitselement, Verfahren zum Herstellen desselben und mit dem Sicherheitselement ausgestatteter Datenträger |
| DE102021109967A1 (de) * | 2021-04-20 | 2022-10-20 | Leonhard Kurz Stiftung & Co. Kg | Verfahren zum Herstellen eines Mehrschichtkörpers, Mehrschichtkörper, Verwendung eines Mehrschichtkörpers, Verwendung einer ersten Schicht aus einem ersten Metall und einer zweiten Schicht aus einem zweiten Metall in einem Mehrschichtkörper sowie Verwendung einer Wärmebeaufschlagungsvorrichtung |
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| US4242378A (en) * | 1979-03-29 | 1980-12-30 | Reiko Co., Ltd. | Method of making a decorated film with a metal layer in the form of a given pattern |
| US4354911A (en) * | 1981-08-07 | 1982-10-19 | Western Electric Company Inc. | Method of selectively depositing a metal on a surface by means of sputtering |
| US4643912A (en) * | 1982-10-29 | 1987-02-17 | Marui Industry Co., Ltd. | Method for forming a metal layer with pattern on a substrate |
| US5697649A (en) * | 1995-05-11 | 1997-12-16 | Crane & Co., Inc. | Articles employing a magnetic security feature |
| DE19739193A1 (de) * | 1997-09-08 | 1999-03-11 | Giesecke & Devrient Gmbh | Sicherheitsfolien für Wertpapiere und Verfahren zu ihrer Herstellung |
| FR2801910A1 (fr) * | 1999-12-07 | 2001-06-08 | Banque De France | Document de securite fabrique avec papier dont la trame fibreuse est enrobee par une substance protectrice |
| WO2002031214A1 (fr) * | 2000-10-09 | 2002-04-18 | Hueck Folien | Film metallise, procede permettant de le produire et utilisation |
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| US2748031A (en) * | 1952-12-31 | 1956-05-29 | Kafig Emanuel | Reproduction of printed patterns by vacuum evaporation |
| EP0330733B1 (fr) * | 1988-03-04 | 1994-01-26 | GAO Gesellschaft für Automation und Organisation mbH | Elément de sécurité en forme de fil ou de bande destiné à être incorporé dans un document de sécurité et procédé pour sa fabrication |
| US5059454A (en) * | 1989-04-26 | 1991-10-22 | Flex Products, Inc. | Method for making patterned thin film |
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|---|---|---|---|---|
| US4242378A (en) * | 1979-03-29 | 1980-12-30 | Reiko Co., Ltd. | Method of making a decorated film with a metal layer in the form of a given pattern |
| US4354911A (en) * | 1981-08-07 | 1982-10-19 | Western Electric Company Inc. | Method of selectively depositing a metal on a surface by means of sputtering |
| US4643912A (en) * | 1982-10-29 | 1987-02-17 | Marui Industry Co., Ltd. | Method for forming a metal layer with pattern on a substrate |
| US5697649A (en) * | 1995-05-11 | 1997-12-16 | Crane & Co., Inc. | Articles employing a magnetic security feature |
| DE19739193A1 (de) * | 1997-09-08 | 1999-03-11 | Giesecke & Devrient Gmbh | Sicherheitsfolien für Wertpapiere und Verfahren zu ihrer Herstellung |
| FR2801910A1 (fr) * | 1999-12-07 | 2001-06-08 | Banque De France | Document de securite fabrique avec papier dont la trame fibreuse est enrobee par une substance protectrice |
| WO2002031214A1 (fr) * | 2000-10-09 | 2002-04-18 | Hueck Folien | Film metallise, procede permettant de le produire et utilisation |
Cited By (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1516956A1 (fr) * | 2003-09-17 | 2005-03-23 | Hueck Folien Ges.m.b.H | Element de securité avec indications colorées négatives |
| EP1516957A1 (fr) * | 2003-09-17 | 2005-03-23 | Hueck Folien Ges.m.b.H | Element de securité avec indications colorées |
| WO2005043965A2 (fr) * | 2003-10-29 | 2005-05-12 | Steiner Gmbh & Co. Kg | Transpondeur |
| DE10350648A1 (de) * | 2003-10-29 | 2005-06-16 | Steiner Gmbh & Co. Kg | Transponder |
| WO2005043965A3 (fr) * | 2003-10-29 | 2005-06-30 | Steiner Gmbh & Co Kg | Transpondeur |
| WO2005082201A1 (fr) * | 2004-03-01 | 2005-09-09 | Schreiner Group Gmbh & Co. Kg | Porte-echantillons, de preference pour un produit cosmetique |
| US7767591B2 (en) * | 2005-04-22 | 2010-08-03 | Steiner Gmbh & Co. Kg | Method and device for producing electronic components |
| EP1746208A1 (fr) | 2005-07-19 | 2007-01-24 | Hueck Folien GmbH & Co. KG | Procédé pour la fabrication d'un substrat partiellement metallisé |
| EP1972462B2 (fr) † | 2007-01-05 | 2019-09-18 | Giesecke+Devrient Currency Technology GmbH | Procédé de fabrication de feuilles de sécurité, et feuilles de sécurité |
| CN101581061B (zh) * | 2008-05-13 | 2010-11-03 | 上海纳尔实业有限公司 | 一种导气槽车身贴的制作方法 |
| EP2135987A1 (fr) * | 2008-06-20 | 2009-12-23 | Commissariat à l'Energie Atomique (Etablissement Public) | Procédé de dépôt de capteurs sur un support poreux |
| FR2932823A1 (fr) * | 2008-06-20 | 2009-12-25 | Commissariat Energie Atomique | Procede de depot de capteurs sur un support poreux |
| US8257792B2 (en) | 2008-06-20 | 2012-09-04 | Commissariat A L'energie Atomique | Process for depositing sensors on a porous support |
| EP2154084A1 (fr) | 2008-08-14 | 2010-02-17 | Hueck Folien Ges.m.b.H. | Feuille adaptée à la fabrication d'un sac tubulaire, sac tubulaire et procédé de fabrication de la feuille |
| EP2177645A1 (fr) | 2008-09-29 | 2010-04-21 | Hueck Folien Ges.m.b.H. | Procédé de structuration de couches anorganiques ou organiques |
| WO2010041226A1 (fr) * | 2008-10-10 | 2010-04-15 | Arjowiggins Security | Procédé de fabrication d'un document de sécurité |
| FR2937058A1 (fr) * | 2008-10-10 | 2010-04-16 | Arjowiggins | Procede de fabrication d'un document de securite. |
| EP2251207A1 (fr) * | 2009-05-11 | 2010-11-17 | HUECK Folien Ges.m.b.H. | Caractéristique de sécurité et procédé destiné à sa fabrication |
| WO2010130301A1 (fr) * | 2009-05-11 | 2010-11-18 | Hueck Folien Ges.M.B.H. | Caractéristique de sécurité et son procédé de production |
| EP2420391A2 (fr) | 2010-07-19 | 2012-02-22 | Hueck Folien Ges.m.b.H. | Elément de sécurité doté d'une couche optiquement variable |
| WO2012153114A1 (fr) * | 2011-05-06 | 2012-11-15 | D W Spinks (Embossing) Limited | Dispositif de sécurité fenêtré |
| WO2014013410A1 (fr) | 2012-07-16 | 2014-01-23 | Arjowiggins Security | Structure de securite |
| US10583682B2 (en) | 2012-07-16 | 2020-03-10 | Oberthur Fiduciaire Sas | Security structure |
| EP2851194A1 (fr) | 2013-09-20 | 2015-03-25 | Hueck Folien Ges.m.b.H | Elément de sécurité, notamment étiquette de sécurité |
| WO2015039711A1 (fr) | 2013-09-20 | 2015-03-26 | Hueck Folien Ges.M.B.H. | Élément de sécurité, notmament étiquette de sécurité |
| GB2527764A (en) * | 2014-06-30 | 2016-01-06 | Innovia Films Ltd | Process |
| GB2527763A (en) * | 2014-06-30 | 2016-01-06 | Innovia Films Ltd | Process |
| GB2527764B (en) * | 2014-06-30 | 2017-02-22 | Innovia Films Ltd | Process for producing a security film |
| GB2527763B (en) * | 2014-06-30 | 2017-10-04 | Innovia Films Ltd | A process for producing a security film |
| DE102020207090A1 (de) | 2020-06-05 | 2021-12-09 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung eingetragener Verein | Verfahren zum Herstellen eines strukturierten Objekts auf einem flexiblen Substrat durch elektrohydrodynamisches Drucken |
Also Published As
| Publication number | Publication date |
|---|---|
| DE10143523A1 (de) | 2003-03-27 |
| DE10143523B4 (de) | 2008-08-21 |
| EP1291463B1 (fr) | 2014-12-10 |
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