EP1356247A1 - Support for parts to be heat treated in a furnace, and a heat treatment method for metal parts - Google Patents
Support for parts to be heat treated in a furnace, and a heat treatment method for metal partsInfo
- Publication number
- EP1356247A1 EP1356247A1 EP01995793A EP01995793A EP1356247A1 EP 1356247 A1 EP1356247 A1 EP 1356247A1 EP 01995793 A EP01995793 A EP 01995793A EP 01995793 A EP01995793 A EP 01995793A EP 1356247 A1 EP1356247 A1 EP 1356247A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- support
- ceramic
- metal
- metal body
- heat treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D5/00—Supports, screens or the like for the charge within the furnace
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0006—Details, accessories not peculiar to any of the following furnaces
- C21D9/0025—Supports; Baskets; Containers; Covers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S269/00—Work holders
- Y10S269/903—Work holder for electrical circuit assemblages or wiring systems
Definitions
- the present invention relates to a support intended to support a part, in particular a metal part, during a heat treatment of said part in an oven.
- the heat treatment is a low-pressure carburizing treatment of a steel part using, for example, gas, oil, etc.
- Patent application FR-A-2 772 467 discloses a device for supporting parts to be heat treated in an oven, comprising plates on each of which are mounted groups of metal pins. Each group of metal pins serves as support for a part to be treated in the form of a pinion. The trays are designed so that they can be stacked vertically.
- the parts are loaded onto the trays and the trays are superimposed on a robot.
- the robot presents the part above the group of pins, then releases it.
- the precision of the robot being limited, it sometimes happens that the part does not fall correctly on its group of support pins and finds itself, after its fall, badly positioned on it.
- the robot is equipped with a part presence detection system, it will detect an anomaly and lock up. Manual intervention will then be necessary to correctly position the part and restart the robot.
- the robot is not equipped with a part presence detection system, it will continue to load the parts on the tray but the superposition of the next tray will be hampered by the incorrectly positioned part. In some cases, the next plate may even break when it is put in place under the effect of conflicting constraints exerted by the robot and the incorrectly positioned part.
- the present invention aims firstly to provide a support which makes it possible to improve the efficiency of the loading of a part to be heat treated.
- a support intended to support, at least in part, a part during a heat treatment of said part, characterized in that it comprises a guide element making it possible to guide the part towards a surface or part of the support surface of said support when it is placed on the support.
- the support according to the invention can feel that it supports the part completely, or, as a variant, that it supports only said part in part. In the latter case, the support force is shared between the support according to the invention and one or more other supports, preferably identical to the support according to the invention.
- the guide element of the support according to the invention facilitates the positioning of the part to be treated, in particular when this positioning is robotized, and makes it possible to compensate for any imprecision of the robot.
- the guide element may consist of an elongate element extending from a base of the support substantially perpendicular to this base and comprising an end portion, opposite the base, in the form of a warhead. More particularly, the guide element can comprise a rod terminated by a head, the head constituting said end portion in the form of a warhead.
- the rod has a diameter smaller than that of the head.
- the end of the guide element opposite the base is rounded.
- the support according to the invention comprises a metal body, of which the guide element can be part, and a ceramic element embedded in the metal body and defining said support surface.
- a heat treatment operation of the part for example of the case hardening type (in particular when the part is made of steel ), can be performed without the support surface and the part sticking to each other. The unloading of the part, once the treatment is finished, is therefore facilitated.
- the fact of embedding the ceramic element in a metallic body makes it possible to increase the impact resistance of the ceramic. It is thus possible to load the part to be treated beforehand by placing this part above the support and then releasing it, all by means of a robot, and with a reduced risk of breakage of the ceramic.
- the ceramic element can be mounted in the metal body so that it can be replaced easily.
- the ceramic element can be crimped into the metal body, simply placed in a recess of the metal body without being attached to it, or placed in a recess of the metal body and retained in this recess by one or more points. (s) of solder or solder formed on or near an upper edge of the recess.
- the ceramic used in the present invention is mullite. This material indeed has good mechanical resistance.
- the ceramic element is embedded in the metal body with a clearance allowing the ceramic element and the metal body to expand freely.
- the ceramic element is embedded in a base of the metal body constituting the aforementioned base of the support.
- the ceramic element can thus consist of an annular part having an axis of symmetry common with the guide element.
- the support surface is inclined, or has an inclined part, in order to prevent lateral movement of the part when the latter rests, at least in part, flat on the support. This ensures good retention of the part on the support, under the effect of the gravitational force to which the part is subjected, while avoiding contact between the part and the guide element.
- the support surface is shaped to ensure contact only at one or more discrete points with an annular part when such an annular part rests, at least in part, flat on the support.
- the support surface can have, for example, a frustoconical shape, or be in the form of a spherical surface part.
- the ceramic element is embedded in the end part of the guide element.
- the support according to the invention can be in the form of a pin.
- the support according to the invention also typically comprises means for fixing to a support plate.
- Such fixing means may comprise a projection of the support, intended to be introduced into a corresponding transverse hole of the support plate, from a first end of this hole, and comprising a thin frustoconical part capable of cooperating with a chamfer provided at a second end, opposite the first, of the transverse hole.
- the present invention also relates to support equipment comprising a support plate and at least one support as defined above, mounted on the support plate.
- the support plate is preferably made of a thermo-structural composite material, such as a carbon-carbon composite material.
- the or each support, and more particularly the metal body thereof, is advantageously mounted on the support plate by crimping and with a clearance.
- the point of intersection between an axis of symmetry of the or each support and the plane of a surface of the support plate receiving the or each support is substantially coincident with the apex of the cone defined by an external surface of the part thin frustoconical.
- the support equipment according to the invention comprises at least one group of three supports arranged in a triangle.
- the present invention further aims to provide a method of heat treatment of a metal part which facilitates, in a sustainable manner, the unloading of the part at the end of the heat treatment.
- a method of heat treatment of a metal part characterized in that one uses, to support said part, at least one support having a ceramic surface, preferably mullite, on which rests , at least in part, said part.
- the metal part is in contact with the ceramic surface only at one or more discrete points.
- the heat treatment consists in a case hardening operation of a steel part. It has been observed that, when such a case-hardening operation was carried out with a purely metallic support for the technique previous, a phenomenon of micro-diffusion of carbon occurred at the level of the support, which tended to lower the melting point of the latter and consequently caused a sticking of the part on the support.
- FIG. 1 is a half-sectional view along the plane I of Figure 2 of a portion of support equipment according to a first embodiment of the invention, on which rests an annular part;
- FIG. 3 shows, in the same type of view as Figure 1, a variant of the first embodiment of the invention
- FIG. 4 shows, in top view, another way of positioning an annular part on the support equipment according to the invention
- FIG. 5 shows, in section, how can be positioned an elongated vertical piece in the shape of a piston on the support equipment according to the invention
- FIG. 6 shows, in section, yet another way of positioning an annular part on the support equipment according to the invention
- FIG. 7 shows, in section, another way of positioning an elongated vertical piece in the shape of a piston on the support equipment according to the invention
- - Figure 8 is a sectional view of part of a support equipment according to a second embodiment of the invention
- FIGS. 9 and 10 are sectional views of part of a support equipment according to a third embodiment of the invention.
- - Figure 11 is a partial sectional view showing support equipment according to the third embodiment of the invention supporting a part;
- FIG. 12 is a sectional view of part of a support equipment according to a fourth embodiment of the invention.
- support equipment for the heat treatment of a metal part, such as the carburizing of a steel part, comprises a support plate 1 and supports in the form of pawns 2 mounted on the support plate 1.
- the pawns 2 are grouped in threes. In each group of pawns (only one group is represented in FIG. 2), the pawns 2 are arranged in a triangle, preferably in an equilateral triangle.
- the support plate 1 is preferably designed in a thermo-structural composite material, such as a carbon-carbon composite material. Alternatively, it can however be made of metal.
- Each pin 2 comprises a metal body 20 consisting of a projecting lower part 21 housed in a corresponding cylindrical transverse hole 10 in the support plate 1, and an upper part 22 extending beyond the upper surface, designated by the reference 11, of the support plate 1, and perpendicular to this surface.
- the body 20 is preferably monolithic.
- each pin 2 is fixed to the support plate 1 by crimping.
- the lower part 21 comprises, at its lower end, a thin frustoconical part 210 cooperating with a chamfer 12 formed on the lower edge of the transverse hole 10.
- the support equipment according to the invention is assembled by presenting each pin 2 above the corresponding transverse hole 10, then by introducing the lower part 21 into the hole 10, downwards, until the frustoconical part 210 come to cooperate with chamfer 12.
- each pin 2 has a skirt-shaped base 220 which rests on the upper surface 11 of the support plate 1, and a central and elongate guide element 221 extending perpendicular to the support plate 1 and at base 220 from the upper end of base 220, along an axis of symmetry AS1 of pin 2.
- the base 220 is cylindrical in the lower part, and frustoconical in the upper part. It further comprises a recess in which is housed a ceramic element 23 which is in the form of an annular pellet having a frustoconical upper surface 230.
- the ceramic pellet 23 is more particularly set at the base 220, by cooperation between a chamfer made on the upper external edge of the pad 23 and a projection 222 of an annular edge 223 of the base 220.
- the ceramic pad 23 can nevertheless be mounted differently in the recess of the base 220. It can for example be simply placed in this recess, without being crimped or fixed in any other way, in order to facilitate its replacement in the event of breakage. It can also be placed in the recess and retained therein simply by one or more weld or solder point (s) 224 formed on or near an upper edge of the recess, as illustrated in Figure 3.
- the frusto-conical upper surface 230 of the ceramic pad 23 is flush with the upper face of the base 220, so that it can feel a support surface, and is arranged so that the apex (not shown) of the cone defined by this surface is directed towards the upper end of pin 2, along the axis AS1.
- the guide element 221 comprises a rod 225 terminated, at its upper end, opposite the base 220, by a head 226.
- the shape of the head 226 is chosen to allow effective guidance when positioning a workpiece on the pin 2.
- the head 226 has a shell or warhead shape, preferably a warhead shape as illustrated in the figures.
- the upper end 226a of the head 226 is rounded rather than pointed.
- the diameter of the rod 225 is less than that of the head 226.
- each pin 2 is arranged relative to the plate 1 so that the point of intersection, designated in FIG. 1 by the mark O, between the axis of symmetry AS1 of the pin 2 and the plane geometric defined by the upper surface 11 of the plate 1 is substantially coincident with the top of the cone defined by the external surface (in contact with the chamfer 12) of the thin frustoconical part 210.
- a slight clearance 211 can be provided between the outer face of the projecting lower part 21 of each pin 2 and the inner face of the corresponding hole 10.
- each pin 2 can be absorbed by a slight lateral clearance 231 between the inner and / or outer faces of the pad 23 and the corresponding wall or walls of the annular recess of the body 20.
- annular metal part 3 to be heat treated such as a pinion, is placed flat on a group of three pins 2 so as to come to bear on the frustoconical ceramic surfaces 230 of the pins 2.
- flat is meant that the axis of symmetry (designated by the reference AS2) of the annular part 3 is perpendicular to the support plate 1 or, in other words, parallel to the axis of symmetry AS1 of each pawn 2.
- the contact between the part 3 and each of the surfaces of ceramic support 230 is punctual.
- the part 3 is thus supported by the support equipment 1, 2 according to the invention at three discrete points A, B and C.
- the guide elements 221 are inscribed inside the internal surface 30 of the part 3 and are distant from this internal surface, that is to say that they do not enter no place in contact with the part 3. Thanks to the inclination of the surfaces of support 230, the part 3 is well maintained on the pins 2 under the effect of gravitation. In particular, the part 3 cannot move laterally to come into contact with the guide elements 221.
- the positioning of the part 3 on the pins 2 is preferably carried out by means of a robot, which places the part 3 above the pins 2 and then releases it so that it falls on the latter.
- the part 3 is guided by the respective heads 226 in the form of an ogive of the guide elements 221. Due to the difference in diameter between the rods 225 and the heads 226 (the rods 225 are narrower than the heads 226), the part 3, after having been guided by the heads 226, is no longer in contact with the guide elements 221. This facilitates the fall of the part 3 towards the surfaces support 230.
- the ceramic pad 23 of each pin 2 is embedded in the metal body 20, that is to say is mounted in a recess of the body 20, increases the impact resistance of the pad 23. Therefore, the risk of ceramic breakage when the part 3 comes into contact with the pins 2 is reduced.
- the latter is designed in mullite.
- the annular part 3 and the pins 2 are arranged so that the guide elements 21 fit into the central empty space of the part 3 delimited by the inner annular surface of it.
- the pins 2 can be arranged so that the guide elements 221 are located beyond the outer annular face of the part 3.
- the part 3 is not necessarily annular, but can also be cylindrical.
- FIG. 5 shows, also by way of example, support pins 2 according to the invention supporting an elongated vertical part 4 in the shape of a piston. Although only two pins 2 are shown in FIG. 5, at least three are used to ensure good maintenance of the part 4.
- FIG. 6 shows another type of configuration, in which each pin 2 fully supports, and no longer only partially as in the arrangements of FIGS. 1 to 5, an annular metal part 5.
- the axis of symmetry of the annular part 5 is thus confused with the axis AS1 of pin 2.
- FIG. 7 shows a pin 2 according to the invention completely supporting a part 6 in the form of a piston comprising an annular lower part 60.
- the pins 2 are intended for a use as illustrated in FIGS. 6 and 7, it can be envisaged to conform their ceramic support surfaces 230 so as to ensure contact between each pin 2 and the corresponding part 5, 6 at discrete points only.
- each ceramic support surface 230 may include slight bosses in places intended to define points of contact with the part 5, 6.
- the invention is not limited to a particular shape for the ceramic support surfaces 230, and that there are many ways of shaping these surfaces so that they each provide contact only at one or more discrete points with an annular part when such an annular part rests flat, completely or in part, on the corresponding pin.
- FIG 8 shows, by way of example, a second embodiment of the invention, in which each 2 'pin (only one 2' pin is shown in Figure 8) has a ceramic support surface
- FIG. 9 and 10 show support pins 7 and 8 respectively according to a third embodiment of the invention.
- the pins 7, 8 differ from the pins 2, 2 'essentially in that their ceramic element is embedded in the head of the guide element, rather than in the base of the metal body (cf. marks 70 and 80).
- the ceramic element 70 (respectively 80) has a rounded support surface 71 (respectively 81) on which a piece can come to rest.
- the ceramic elements 70 and 80 are simply placed, without being fixed, in a recess in the head of the guide element, so that they can be replaced easily in the event of breakage. As a variant, they can nevertheless be crimped into the recess or blocked by one or more welding points in a manner comparable to the example in FIG. 3.
- Pawns 7, 8 can be used, for example, as illustrated in FIG. 11.
- a group of three support pawns of the type of pawns 7 or 8 supports, at three points of contact, a metal part 72 having an annular lower part and a solid cylindrical upper part.
- the contact between the part 72 and the pins 7 or 8 takes place between a metal bearing surface 73 of the part 72 and the ceramic surface 71 or 81 of each pin.
- the positioning of the part 72 on the pins 7 or 8 is facilitated by the guide elements.
- FIG. 12 illustrates a support pin 9 according to a fourth embodiment of the invention.
- the pin 9 consists of a metal body 90 and a ceramic coating layer 91 covering the head of a guide element of the metal body 90 and fixed to this head for example by gluing or brazing, as shown at the level of the reference 92.
- the ceramic element 91 is not embedded in the metal body.
- the pin 9 can also be used to support a metal part to be heat treated, such as a steel part to be cemented, for example in the manner illustrated in FIG. 11 for the pins 7, 8.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Furnace Charging Or Discharging (AREA)
- Heat Treatments In General, Especially Conveying And Cooling (AREA)
- Furnace Details (AREA)
- Heat Treatment Of Articles (AREA)
- Control Of Heat Treatment Processes (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0017168 | 2000-12-28 | ||
FR0017168A FR2819047B1 (en) | 2000-12-28 | 2000-12-28 | MEDIUM SUITABLE FOR THE HEAT TREATMENT OF A METAL PART AND A METHOD OF HEAT TREATMENT |
PCT/FR2001/004197 WO2002053997A1 (en) | 2000-12-28 | 2001-12-26 | Support for parts to be heat treated in a furnace, and a heat treatment method for metal parts |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1356247A1 true EP1356247A1 (en) | 2003-10-29 |
EP1356247B1 EP1356247B1 (en) | 2005-03-02 |
Family
ID=8858302
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP01995793A Expired - Lifetime EP1356247B1 (en) | 2000-12-28 | 2001-12-26 | Support for parts to be heat treated in a furnace, and a heat treatment method for metal parts |
Country Status (9)
Country | Link |
---|---|
US (1) | US6939131B2 (en) |
EP (1) | EP1356247B1 (en) |
JP (1) | JP2004535512A (en) |
KR (1) | KR20030067721A (en) |
AT (1) | ATE290196T1 (en) |
DE (1) | DE60109211T2 (en) |
ES (1) | ES2234931T3 (en) |
FR (1) | FR2819047B1 (en) |
WO (1) | WO2002053997A1 (en) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009084607A (en) * | 2007-09-28 | 2009-04-23 | Aisin Aw Co Ltd | Tool for decompression heat treatment, and decompression heat treatment method |
US7780905B2 (en) * | 2008-03-04 | 2010-08-24 | Pcc Airfoils, Inc. | Supporting ceramic articles during firing |
DE202008008067U1 (en) * | 2008-06-18 | 2009-10-29 | Edag Gmbh & Co. Kgaa | Device for fixing a component during a heat treatment |
WO2015182552A1 (en) * | 2014-05-28 | 2015-12-03 | 京セラ株式会社 | Cutting insert manufacturing method |
FR3040476B1 (en) * | 2015-08-31 | 2018-08-31 | Safran Aircraft Engines | FRAMEWORK FOR HANDLING AUBES |
JP6697902B2 (en) * | 2016-02-26 | 2020-05-27 | 株式会社三井ハイテック | Tray and heat treatment method |
DE102016211775A1 (en) * | 2016-06-29 | 2018-01-04 | Schunk Kohlenstofftechnik Gmbh | Workpiece carrier and method for producing a workpiece carrier |
WO2018028776A1 (en) * | 2016-08-10 | 2018-02-15 | Härterei Reese Bochum Gmbh | Charging apparatus for the dimensionally stable heat treatment of workpieces |
DE102016216808B4 (en) | 2016-09-06 | 2018-11-22 | Bayerische Motoren Werke Aktiengesellschaft | Positioning device and positioning device |
JP6739417B2 (en) * | 2017-10-31 | 2020-08-12 | Dowaサーモテック株式会社 | Heat treatment equipment |
MX2021013795A (en) * | 2020-02-26 | 2021-12-10 | Nikko Kinzoku Co Ltd | Member for heat treatment and structure for heat treatment. |
WO2021172389A1 (en) * | 2020-02-26 | 2021-09-02 | 日光金属株式会社 | Member for heat treatment and structure for heat treatment |
US12037996B2 (en) * | 2020-09-29 | 2024-07-16 | Ut-Battelle, Llc | Fuel driven near isothermal compressor |
JP7592560B2 (en) | 2021-06-17 | 2024-12-02 | 芝浦メカトロニクス株式会社 | Heat Treatment Equipment |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1941941A (en) * | 1931-04-22 | 1934-01-02 | William W Irwin | Ware support for kilns |
GB486330A (en) * | 1937-01-23 | 1938-06-02 | George Woolliscroft & Son Ltd | Improvements in or relating to the production of tiles |
US2273475A (en) * | 1940-08-04 | 1942-02-17 | Armin L Schreiber | Pin for supporting ceramic ware |
GB678668A (en) * | 1951-04-05 | 1952-09-03 | Thomas C Wild And Sons Ltd | Improvements relating to potters' cranks |
US3266116A (en) * | 1963-08-12 | 1966-08-16 | Mayer China Company | Support for ceramic ware |
DE3516490A1 (en) * | 1985-05-08 | 1986-11-13 | Elektroschmelzwerk Kempten GmbH, 8000 München | FUEL AID |
US5603875A (en) * | 1993-06-11 | 1997-02-18 | Aerospace Coating Systems, Inc. | Method for producing ceramic-based components |
SE509984C2 (en) * | 1994-03-18 | 1999-03-29 | Sandvik Ab | Charging system for CVD |
US5752821A (en) * | 1996-07-02 | 1998-05-19 | Kia Motors Corporation | Tray for heat treatment furnace |
FR2772467B1 (en) * | 1997-12-15 | 2000-03-10 | Snecma | LOADING DEVICE FOR SUPPORTING PARTS TO BE HEAT TREATED IN AN OVEN |
-
2000
- 2000-12-28 FR FR0017168A patent/FR2819047B1/en not_active Expired - Fee Related
-
2001
- 2001-12-26 EP EP01995793A patent/EP1356247B1/en not_active Expired - Lifetime
- 2001-12-26 ES ES01995793T patent/ES2234931T3/en not_active Expired - Lifetime
- 2001-12-26 DE DE60109211T patent/DE60109211T2/en not_active Expired - Lifetime
- 2001-12-26 US US10/451,828 patent/US6939131B2/en not_active Expired - Fee Related
- 2001-12-26 WO PCT/FR2001/004197 patent/WO2002053997A1/en active IP Right Grant
- 2001-12-26 JP JP2002554458A patent/JP2004535512A/en active Pending
- 2001-12-26 AT AT01995793T patent/ATE290196T1/en active
- 2001-12-26 KR KR10-2003-7008619A patent/KR20030067721A/en not_active Application Discontinuation
Non-Patent Citations (1)
Title |
---|
See references of WO02053997A1 * |
Also Published As
Publication number | Publication date |
---|---|
ATE290196T1 (en) | 2005-03-15 |
JP2004535512A (en) | 2004-11-25 |
FR2819047B1 (en) | 2003-06-27 |
DE60109211D1 (en) | 2005-04-07 |
KR20030067721A (en) | 2003-08-14 |
FR2819047A1 (en) | 2002-07-05 |
US6939131B2 (en) | 2005-09-06 |
EP1356247B1 (en) | 2005-03-02 |
US20050100852A1 (en) | 2005-05-12 |
WO2002053997A1 (en) | 2002-07-11 |
DE60109211T2 (en) | 2006-02-16 |
ES2234931T3 (en) | 2005-07-01 |
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Legal Events
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