EP0146752B1 - Procédé et dispositif pour extruder les particules végétales, en particulier les particules en bois, mêlées avec l'adhésif - Google Patents
Procédé et dispositif pour extruder les particules végétales, en particulier les particules en bois, mêlées avec l'adhésif Download PDFInfo
- Publication number
- EP0146752B1 EP0146752B1 EP84113545A EP84113545A EP0146752B1 EP 0146752 B1 EP0146752 B1 EP 0146752B1 EP 84113545 A EP84113545 A EP 84113545A EP 84113545 A EP84113545 A EP 84113545A EP 0146752 B1 EP0146752 B1 EP 0146752B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- extrusion
- mixture
- webs
- axis
- piston
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000001125 extrusion Methods 0.000 title claims abstract description 96
- 239000011230 binding agent Substances 0.000 title claims abstract description 10
- 239000002023 wood Substances 0.000 title claims abstract 4
- 238000000034 method Methods 0.000 title claims description 22
- 239000002245 particle Substances 0.000 title claims description 8
- 230000006835 compression Effects 0.000 claims abstract description 28
- 238000007906 compression Methods 0.000 claims abstract description 28
- 239000000203 mixture Substances 0.000 claims abstract description 26
- 238000003825 pressing Methods 0.000 claims description 19
- 235000012438 extruded product Nutrition 0.000 claims description 18
- 230000035508 accumulation Effects 0.000 claims description 2
- 238000009825 accumulation Methods 0.000 claims description 2
- 235000013311 vegetables Nutrition 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 17
- 239000012792 core layer Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000013459 approach Methods 0.000 description 3
- 238000005452 bending Methods 0.000 description 3
- 238000000748 compression moulding Methods 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 239000011093 chipboard Substances 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000009950 felting Methods 0.000 description 1
- 238000005429 filling process Methods 0.000 description 1
- 210000001061 forehead Anatomy 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/08—Moulding or pressing
- B27N3/28—Moulding or pressing characterised by using extrusion presses
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/08—Moulding or pressing
- B27N3/10—Moulding of mats
- B27N3/14—Distributing or orienting the particles or fibres
Definitions
- the invention relates to methods and devices for the extrusion of vegetable small parts, especially small wooden parts, mixed with in particular weather-resistant binder, in a piston extrusion press in accordance with the features listed in the preamble of the main claim.
- the view of the previously known teaching that a considerable compression of the mixture during the pre-pressing process should lead to an increase in the bending strength of the extruded product should not be shared.
- the end face of the known extrusion piston is provided with a concavely recessed curvature, through which the end face of the individual extrusion section is mapped accordingly and a kind of tongue and groove connection of the sections results.
- the invention has for its object to develop the known extrusion process in such a way that a considerable increase in the bending strength of the extruded product in the longitudinal direction is achieved with improved connection of the individual extrusion section.
- the invention aims to produce high-quality, in particular thick-walled extruded sheets with reduced specific weight and weather-resistant gluing, which can be used, for example, for interior walls of buildings, stables and the like and which have the required strength for this.
- the invention is based on the knowledge that layers which are clearly distinguishable from one another must be pronounced in the finished extruded product, the longer chips in particular, at least in the outer layers, being intended to have a position which is predominantly oriented parallel to the extrusion direction. It is therefore not only important that the chips lie approximately parallel to the large surface of the strand. The strength is rather increased if this parallel position is directed longitudinally to the extrusion axis.
- the pre-orientation of the small parts is brought about in accordance with the exemplary embodiment of claim (3) during their free fall into the press space during filling. Surprisingly, this is achieved in a very simple manner by filling the batch through narrow shafts which extend longitudinally in the extrusion direction and which are formed by spaced-apart thin-walled and upright webs and which are arranged in a stationary manner.
- webs of the same height are used, which are arranged on both sides of the press space at a greater distance from one another than in the prior art.
- Another important idea of an embodiment of the invention is to press the batch accumulated in the baling chamber from both sides. Because of the arrangement of the aforementioned webs, the pre-press punches must therefore penetrate through the shafts present between the webs. At the same time, however, the press stroke of this pre-punch is limited by the height of the webs. Therefore, only a limited pre-compression of the outer layers is brought about by each pre-compression die, the compression ratio of which is considerably lower than that of DE-AS 12 47 002.
- the method according to the invention can both can be used with vertical as well as horizontal piston extrusion presses.
- An oblique pressing direction can also be carried out.
- horizontal extrusion is preferable, only one is assumed below, without the invention being restricted thereto.
- the invention teaches with claims (11) and (12) to move the upper pre-press along the webs covering the filling opening for the pressing chamber so that the pressing chamber is released for the filling process.
- the invention teaches with claims (11) and (12) to move the upper pre-press along the webs covering the filling opening for the pressing chamber so that the pressing chamber is released for the filling process.
- part of the batch accumulates in free fall on the upper end faces of the webs. It is therefore expedient to provide a squeegee which is movable lengthwise or transversely to the webs and which scrapes the batch and helps to bring the small parts into the desired orientation.
- Fig. (1) of the drawing shows a partial perspective of an extruded product (1), which can have a considerable thickness, for example (8, 5) cm, and is preferably used as a screed, inner wall of a building, load-bearing plate and the like.
- the invention does not preclude the production of thin-walled extrusions according to the method described later.
- the product (1) produced along the extrusion axis (5) has a typical layer formation which is to be produced during extrusion.
- the upper cover layer (2) and the lower cover layer (3) should be pre-compressed with respect to the core layer (4). It is essential that at least in these cover layers (2, 3) especially the longer small parts have a chip orientation (6) oriented parallel or almost parallel to the extrusion axis (5).
- Fig. (2) a variant of the extruded product (1) is shown, which have longitudinally running and mutually parallel channels (7).
- the layer (8) forming the channel wall in turn has a higher compression than the core layer (4). If, according to FIG. (3), a section is taken along the plane 111-111 in FIG. (2) through the extruded product (1), then the aim is also in this sectional plane to have an orientation (6) oriented parallel to the extruding axis (5) to achieve longer chips or small parts.
- FIG. (4-6) it is assumed that a press chamber (10) of the press ram contour (12) of the usual extrusion piston is circumscribed.
- This extrusion piston (20) which is shown in more detail in FIGS. (9 and 10), has an in particular rectangular cross section designed in accordance with the extrusion product (1) of FIGS. (1) and (2). It is guided between the press room walls (11) perpendicular to the plane of the drawing in Fig. (4).
- a plurality of webs (13), which are at a certain distance, for example (8) mm, from one another, are relatively thin-walled and are fixed vertically upright on the top and bottom of the press ram contour (12). Because they are wearing parts, the use of a steel band suitable for the formation of saw blades is recommended.
- the webs (13) have the function of aligning the small parts of the mixture in the charging arrangement (14) during free fall, so that, as shown in FIGS. (1) and (2), they predominantly have a parallel chip orientation ( 6) to the extrusion axis (5).
- This chip orientation (6) is favored in that the loading arrangement (14) - as shown later in FIG. (6) - is moved back and forth along the webs (13) with its outlet opening (15).
- the lower edge of the loading arrangement (14) can be arranged at a distance from the upper edge of the upper webs (13). In this case it is to be expected that a small part of the batch will settle on the upper edge of the webs (13) to form a bridge.
- an upper pre-press die (19) is brought into a position between the upper webs (13) by a longitudinal displacement parallel to the extrusion press axis (5), which is approximately that of the lower pre-press die shown in Fig. (4) (16) corresponds.
- the mixture is pre-pressed in an approximately vertical direction (in the case of horizontal piston extrusion presses) with the aid of the pre-compression punches (16, 19).
- the strip-like approaches of the pre-press punches (16, 19) penetrate the shafts (18) between the webs (13) and reach their end position shown in FIG. (5), with the contour (12) of the extrusion piston shown in FIG. (4) matches.
- the outer layers (2, 3) are pre-compressed, but should only reach such an extent that the extrusion stroke to be carried out afterwards achieves a secure connection of the individual extrusion sections to one another should let.
- pre-compression in a ratio of 1: 2 has proven to be expedient. The consequence of this pre-compression is that the already longitudinally oriented small parts are fixed in their position and remain in this position during the extrusion stroke.
- FIG. (6) a vertical longitudinal section through the press arrangement is shown.
- the extrusion piston (20) is driven to reciprocate in the horizontal direction in accordance with the arrow (21).
- An extrusion technology according to DE-PS 29 32 406 is preferably used.
- the movement distance of the extrusion piston (20) is symbolized by the webs (13) arranged above and below, the position of the lower pre-compression ram (16) with its stroke direction (22) being made clear.
- a curing channel (25) which is preferably designed according to the teaching of DE-PS 25 35 989 and DE-PS 27 14 256.
- this loading arrangement (14) can be moved back and forth in the direction of the arrow (26).
- this loading arrangement (14) is arranged on a carriage (24) which also carries the upper press ram (19).
- This press ram (19) dips a certain distance into the shafts (18) between the upper webs (13) (cf. Fig. 4) and also has the function of accumulating during the reciprocating movement of the carriage (24) of the batch introduced into the baling chamber (10) to have a balancing effect.
- Stroke generators (23) are arranged on the slide (24) and move the upper pre-compression die (19) into the end position shown in FIG. (5) in the direction of the arrows (22).
- the two prepress rams (16, 19) remain in their position shown in Fig. (5) when the extrusion stroke of the extrusion piston (20) is subsequently carried out.
- the loading arrangement (14) can be designed in such a way that it covers the entire filling area of the pressing space (10). It is then conceivable to set the webs (13) in vibrations along their longitudinal direction, which could have a low amplitude but a high frequency. This measure also makes it possible to achieve a longitudinal orientation (6) parallel to the extrusion axis (5) of the small parts without the dynamic flow effect of the movable loading arrangement (14) shown in FIG. (6) being used. Such a movement is possible in that the webs (13) are connected on one end face to a vibration-generating arrangement, for example a vibrating magnet. It would serve the same goal if the webs (13) remained stationary, whereas the loading arrangement (14) was set in vibration along the extrusion axis (5).
- FIGS. (9) and (10) show schematic, perspective partial views of an extrusion piston (20). From DE-AS 12 47 002 it is known to concave the end face of the extrusion piston. Instead, Fig. (9) teaches a convex design by a protruding end profile (35) and two slightly recessed intermediate profiles (36) that merge continuously. In contrast to the previously known teaching, however, the edge areas between the alignment lines (37, 38) are provided with undulating deviations (39), which has the advantage that the teeth of the extruded sections to be connected to one another are more intensive without the chip orientation (6) being significantly increased influence.
- a concave curvature (41) of the end face of the extrusion piston (20) is shown, which merges into sawtooth-like profiles (42) along the piston edges, which are very rounded.
- the end profiles of the extrusion die can be designed as strip profiles and screwed onto the actual die bodies. It has proven to be advantageous if the above screw heads are used because their impression in the molding compound promotes the interlocking of the extruded sections pressed against one another.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
- Press-Shaping Or Shaping Using Conveyers (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Polishing Bodies And Polishing Tools (AREA)
- Crushing And Grinding (AREA)
- Control Of Motors That Do Not Use Commutators (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Furan Compounds (AREA)
- Pretreatment Of Seeds And Plants (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Medicines Containing Plant Substances (AREA)
- General Preparation And Processing Of Foods (AREA)
- Sealing Material Composition (AREA)
Claims (17)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT84113545T ATE58501T1 (de) | 1983-12-22 | 1984-11-09 | Verfahren und vorrichtung zum strangpressen von mit bindemittel vermengten pflanzlichen kleinteilen, insbesondere holzkleinteilen. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3346469A DE3346469C2 (de) | 1983-12-22 | 1983-12-22 | Verfahren und Vorrichtung zum Strangpressen von mit Bindemittel vermengten pflanzlichen Kleinteilen, insbesondere Holzkleinteilen |
DE3346469 | 1983-12-22 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0146752A1 EP0146752A1 (fr) | 1985-07-03 |
EP0146752B1 true EP0146752B1 (fr) | 1990-11-22 |
Family
ID=6217740
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP84113545A Expired - Lifetime EP0146752B1 (fr) | 1983-12-22 | 1984-11-09 | Procédé et dispositif pour extruder les particules végétales, en particulier les particules en bois, mêlées avec l'adhésif |
Country Status (15)
Country | Link |
---|---|
US (2) | US4645631A (fr) |
EP (1) | EP0146752B1 (fr) |
JP (1) | JPS60157806A (fr) |
AT (1) | ATE58501T1 (fr) |
CA (1) | CA1249706A (fr) |
CS (1) | CS251091B2 (fr) |
DD (1) | DD232452A5 (fr) |
DE (2) | DE3346469C2 (fr) |
DK (1) | DK161684C (fr) |
ES (1) | ES8608993A1 (fr) |
FI (1) | FI74233C (fr) |
NO (1) | NO163729C (fr) |
PT (1) | PT79695A (fr) |
SU (1) | SU1384190A3 (fr) |
YU (2) | YU43393B (fr) |
Families Citing this family (54)
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SE468278B (sv) * | 1989-11-21 | 1992-12-07 | Curt Andersson | Saett och anordning foer att av en komprimerbar materialblandning medelst ett munstycke och en formande roerlig matris framstaella en laangstraeckt balk |
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US5413746A (en) * | 1992-06-10 | 1995-05-09 | Birjukov; Mikhail V. | Method for molding shaped products and an apparatus for carrying out same |
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CA2100320C (fr) * | 1992-08-31 | 2011-02-08 | Michael J. Deaner | Composite perfectionne de polymere et de bois |
CA2100319C (fr) * | 1992-08-31 | 2003-10-07 | Michael J. Deaner | Element de structure perfectionne en composite polymere/bois |
US5406768A (en) * | 1992-09-01 | 1995-04-18 | Andersen Corporation | Advanced polymer and wood fiber composite structural component |
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US5948524A (en) * | 1996-01-08 | 1999-09-07 | Andersen Corporation | Advanced engineering resin and wood fiber composite |
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US5847016A (en) * | 1996-05-16 | 1998-12-08 | Marley Mouldings Inc. | Polymer and wood flour composite extrusion |
US5827462A (en) * | 1996-10-22 | 1998-10-27 | Crane Plastics Company Limited Partnership | Balanced cooling of extruded synthetic wood material |
US5866264A (en) * | 1996-10-22 | 1999-02-02 | Crane Plastics Company Limited Partnership | Renewable surface for extruded synthetic wood material |
US6117924A (en) * | 1996-10-22 | 2000-09-12 | Crane Plastics Company Limited Partnership | Extrusion of synthetic wood material |
US6180257B1 (en) | 1996-10-29 | 2001-01-30 | Crane Plastics Company Limited Partnership | Compression molding of synthetic wood material |
US6344504B1 (en) | 1996-10-31 | 2002-02-05 | Crane Plastics Company Limited Partnership | Extrusion of synthetic wood material |
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US20030187102A1 (en) * | 1997-09-02 | 2003-10-02 | Marshall Medoff | Compositions and composites of cellulosic and lignocellulosic materials and resins, and methods of making the same |
US20020010229A1 (en) * | 1997-09-02 | 2002-01-24 | Marshall Medoff | Cellulosic and lignocellulosic materials and compositions and composites made therefrom |
US6464913B1 (en) | 1997-09-05 | 2002-10-15 | Crane Plastics Company Limited Partnership | In-line compounding and extrusion system |
US6344268B1 (en) | 1998-04-03 | 2002-02-05 | Certainteed Corporation | Foamed polymer-fiber composite |
US20060065993A1 (en) * | 1998-04-03 | 2006-03-30 | Certainteed Corporation | Foamed polymer-fiber composite |
CA2357755A1 (fr) | 1998-12-28 | 2000-07-06 | Burch E. Zehner | Composite de plastique cellulosique a charge minerale |
US6280667B1 (en) | 1999-04-19 | 2001-08-28 | Andersen Corporation | Process for making thermoplastic-biofiber composite materials and articles including a poly(vinylchloride) component |
US6971211B1 (en) | 1999-05-22 | 2005-12-06 | Crane Plastics Company Llc | Cellulosic/polymer composite material |
US7537826B2 (en) * | 1999-06-22 | 2009-05-26 | Xyleco, Inc. | Cellulosic and lignocellulosic materials and compositions and composites made therefrom |
DE20005186U1 (de) | 2000-03-21 | 2000-06-29 | Vießmann, Hans, Dr. Dr., 95030 Hof | Spanplatte |
US6662515B2 (en) | 2000-03-31 | 2003-12-16 | Crane Plastics Company Llc | Synthetic wood post cap |
US6579605B2 (en) | 2000-07-31 | 2003-06-17 | Crane Plastics Company Llc | Multilayer synthetic wood component |
US6524504B2 (en) * | 2001-01-04 | 2003-02-25 | Masonite Corporation | Method of producing cellulosic article having increased thickness, and product thereof |
US6578368B1 (en) | 2001-01-19 | 2003-06-17 | Crane Plastics Company Llc | Cryogenic cooling of extruded and compression molded materials |
US20060012066A1 (en) * | 2001-01-19 | 2006-01-19 | Crane Plastics Company Llc | System and method for directing a fluid through a die |
US7017352B2 (en) * | 2001-01-19 | 2006-03-28 | Crane Plastics Company Llc | Cooling of extruded and compression molded materials |
US6637213B2 (en) | 2001-01-19 | 2003-10-28 | Crane Plastics Company Llc | Cooling of extruded and compression molded materials |
US20040148965A1 (en) * | 2001-01-19 | 2004-08-05 | Crane Plastics Company Llc | System and method for directing a fluid through a die |
US6632863B2 (en) | 2001-10-25 | 2003-10-14 | Crane Plastics Company Llc | Cellulose/polyolefin composite pellet |
US6780359B1 (en) | 2002-01-29 | 2004-08-24 | Crane Plastics Company Llc | Synthetic wood composite material and method for molding |
US20040026021A1 (en) * | 2002-05-31 | 2004-02-12 | Groh A. Anthony | Method of manufacturing a metal-reinforced plastic panel |
US7449229B2 (en) * | 2002-11-01 | 2008-11-11 | Jeld-Wen, Inc. | System and method for making extruded, composite material |
US20070235705A1 (en) * | 2003-02-27 | 2007-10-11 | Crane Plastics Company Llc | Composite fence |
US20060068053A1 (en) * | 2004-09-30 | 2006-03-30 | Crane Plastics Company Llc | Integrated belt puller and three-dimensional forming machine |
US8074339B1 (en) | 2004-11-22 | 2011-12-13 | The Crane Group Companies Limited | Methods of manufacturing a lattice having a distressed appearance |
DK2564932T3 (en) * | 2005-03-24 | 2016-08-29 | Xyleco Inc | A method for reducing biological overgrowth or rot or decay in a composite material |
US7708214B2 (en) | 2005-08-24 | 2010-05-04 | Xyleco, Inc. | Fibrous materials and composites |
US20150328347A1 (en) | 2005-03-24 | 2015-11-19 | Xyleco, Inc. | Fibrous materials and composites |
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-
1983
- 1983-12-22 DE DE3346469A patent/DE3346469C2/de not_active Expired
-
1984
- 1984-11-09 DE DE8484113545T patent/DE3483644D1/de not_active Expired - Lifetime
- 1984-11-09 EP EP84113545A patent/EP0146752B1/fr not_active Expired - Lifetime
- 1984-11-09 AT AT84113545T patent/ATE58501T1/de not_active IP Right Cessation
- 1984-11-23 FI FI844613A patent/FI74233C/fi not_active IP Right Cessation
- 1984-11-29 NO NO844757A patent/NO163729C/no unknown
- 1984-12-07 YU YU2074/84A patent/YU43393B/xx unknown
- 1984-12-10 DD DD84270549A patent/DD232452A5/de not_active IP Right Cessation
- 1984-12-12 ES ES538507A patent/ES8608993A1/es not_active Expired
- 1984-12-18 PT PT79695A patent/PT79695A/pt unknown
- 1984-12-18 CA CA000470459A patent/CA1249706A/fr not_active Expired
- 1984-12-18 CS CS849925A patent/CS251091B2/cs unknown
- 1984-12-20 US US06/684,013 patent/US4645631A/en not_active Expired - Lifetime
- 1984-12-20 DK DK614284A patent/DK161684C/da active
- 1984-12-20 SU SU843825253A patent/SU1384190A3/ru active
- 1984-12-21 JP JP59268677A patent/JPS60157806A/ja active Pending
-
1985
- 1985-09-10 US US06/764,846 patent/US4611979A/en not_active Expired - Fee Related
-
1986
- 1986-06-13 YU YU1030/86A patent/YU45015B/xx unknown
Also Published As
Publication number | Publication date |
---|---|
YU207484A (en) | 1987-12-31 |
DE3346469C2 (de) | 1987-02-26 |
DK161684B (da) | 1991-08-05 |
SU1384190A3 (ru) | 1988-03-23 |
DE3483644D1 (de) | 1991-01-03 |
ES8608993A1 (es) | 1986-09-01 |
YU103086A (en) | 1988-08-31 |
FI74233C (fi) | 1988-01-11 |
PT79695A (de) | 1985-01-01 |
CS251091B2 (en) | 1987-06-11 |
EP0146752A1 (fr) | 1985-07-03 |
CA1249706A (fr) | 1989-02-07 |
DE3346469A1 (de) | 1985-07-18 |
FI844613L (fi) | 1985-06-23 |
ES538507A0 (es) | 1986-09-01 |
YU43393B (en) | 1989-06-30 |
NO163729B (no) | 1990-04-02 |
YU45015B (en) | 1991-06-30 |
JPS60157806A (ja) | 1985-08-19 |
DD232452A5 (de) | 1986-01-29 |
FI74233B (fi) | 1987-09-30 |
NO844757L (no) | 1985-06-24 |
FI844613A0 (fi) | 1984-11-23 |
DK161684C (da) | 1992-01-27 |
DK614284A (da) | 1985-06-23 |
ATE58501T1 (de) | 1990-12-15 |
DK614284D0 (da) | 1984-12-20 |
US4645631A (en) | 1987-02-24 |
US4611979A (en) | 1986-09-16 |
NO163729C (no) | 1990-07-11 |
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