DE60336812D1 - Npolymerisation - Google Patents

Npolymerisation

Info

Publication number: DE60336812D1
Authority: DE; Germany
Prior art keywords: aluminoxane; disclosed; support material; activators; heterocyclic compound
Prior art date: 2002-06-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

DE60336812T

Other languages

English (en)

Inventor

Matthew W Holtcamp

David A Cano

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

ExxonMobil Chemical Patents Inc

Original Assignee

ExxonMobil Chemical Patents Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2002-06-28

Filing date

2003-06-26

Publication date

2011-06-01

2003-06-26 Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc

2011-06-01 Application granted granted Critical

2011-06-01 Publication of DE60336812D1 publication Critical patent/DE60336812D1/de

2023-06-27 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Toxicology (AREA)
Materials Engineering (AREA)
Engineering & Computer Science (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Polymerisation Methods In General (AREA)
Superconductors And Manufacturing Methods Therefor (AREA)
Tires In General (AREA)
Disintegrating Or Milling (AREA)
Indole Compounds (AREA)
Polyethers (AREA)

DE60336812T 2002-06-28 2003-06-26 Npolymerisation Expired - Lifetime DE60336812D1 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US10/186,361 US6703338B2 (en)	2002-06-28	2002-06-28	Polymerization catalyst activators, method of preparing, and their use in polymerization processes
PCT/US2003/020199 WO2004003037A1 (en)	2002-06-28	2003-06-26	Halogen substituted catalyst system for olefin polymerization

Publications (1)

Publication Number	Publication Date
DE60336812D1 true DE60336812D1 (en)	2011-06-01

Family

ID=29999290

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DE60336812T Expired - Lifetime DE60336812D1 (en)	2002-06-28	2003-06-26	Npolymerisation

Country Status (20)

Country	Link
US (2)	US6703338B2 (de)
EP (3)	EP1517930B1 (de)
JP (3)	JP4361862B2 (de)
KR (1)	KR100713748B1 (de)
CN (4)	CN1659193B (de)
AT (1)	ATE506381T1 (de)
AU (3)	AU2003238849B2 (de)
BR (3)	BR0305256A (de)
CA (3)	CA2488052C (de)
CZ (1)	CZ20041151A3 (de)
DE (1)	DE60336812D1 (de)
MX (1)	MXPA05000067A (de)
MY (1)	MY137541A (de)
NO (1)	NO20040872L (de)
PL (1)	PL373380A1 (de)
RU (1)	RU2293088C2 (de)
SG (1)	SG173215A1 (de)
TW (1)	TWI280252B (de)
WO (3)	WO2004003031A2 (de)
ZA (1)	ZA200409750B (de)

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US6274684B1 (en) *	1999-10-22	2001-08-14	Univation Technologies, Llc	Catalyst composition, method of polymerization, and polymer therefrom
US6841504B2 (en) *	2002-01-28	2005-01-11	Univation Technologies, Llc	Polymerization catalyst activator and its use in a polymerization process
US6559251B1 (en) *	2002-08-02	2003-05-06	Equistar Chemicals, Lp	Process for making low-density polyolefins
US7220695B2 (en) *	2004-01-07	2007-05-22	Exxonmobil Chemical Patents Inc.	Supported activator
US7741417B2 (en) *	2004-01-07	2010-06-22	Exxonmobil Chemical Patents Inc.	Preparation of polymerization catalyst activators utilizing indole-modified silica supports
WO2009061678A1 (en) *	2007-11-08	2009-05-14	Exxonmobil Chemicals Patents Inc.	Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes
US8022005B2 (en) *	2007-11-08	2011-09-20	Exxonmobil Chemical Patents Inc.	Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes
US8524846B1 (en)	2009-07-02	2013-09-03	The University Of Toledo	Trianionic ligand precursor compounds and uses thereof in constrained geometry catalysts
US8957172B2 (en)	2012-08-03	2015-02-17	Exxonmobil Chemical Patents Inc.	Nonsymmetric catalysts comprising salan ligands
US9365661B2 (en)	2012-08-03	2016-06-14	Exxonmobil Chemical Patents Inc.	Polyalphaolefins prepared using modified salan catalyst compounds
WO2014022012A1 (en)	2012-08-03	2014-02-06	Exxonmobil Chemical Patents Inc.	Vinyl terminated polyethylene with long chain branching
CN104364321A (zh)	2012-08-03	2015-02-18	埃克森美孚化学专利公司	含Salan 配体的卤化催化剂
WO2014022008A1 (en) *	2012-08-03	2014-02-06	Exxonmobil Chemical Patents Inc.	Catalysts comprising salan ligands
US9382349B2 (en)	2012-08-03	2016-07-05	Exxonmobil Chemical Patents Inc.	Polyalphaolefins prepared using modified Salan catalyst compounds
CN104428324B (zh)	2012-11-02	2018-08-17	埃克森美孚化学专利公司	负载型Salan催化剂
EP2970676B1 (de)	2013-03-13	2017-10-04	ExxonMobil Chemical Patents Inc.	Diphenylamin-salan-katalysator
CN105392776B (zh) *	2013-06-20	2019-02-12	埃克森美孚化学专利公司	硫代-Salalen催化剂
CN105142777B (zh)	2013-06-20	2017-12-26	埃克森美孚化学专利公司	长桥Salen催化剂
US9200099B2 (en)	2013-06-20	2015-12-01	Exxonmobil Chemical Patents Inc.	Salenol catalyst
WO2015088819A1 (en)	2013-12-13	2015-06-18	Exxonmobil Chemical Patents Inc.	Cyclopentadienyl-substituted salan catalysts
EP3126325B1 (de)	2014-03-31	2019-04-24	ExxonMobil Chemical Patents Inc.	Phenylenverbrückte salalenkatalysatoren
US10351647B2 (en)	2015-05-29	2019-07-16	Exxonmobil Chemical Patents Inc.	Polymerization process using bridged metallocene compounds supported on organoaluminum treated layered silicate supports
WO2017023722A1 (en)	2015-07-31	2017-02-09	Cargill, Incorporated	Citrus fibres with optimised water binding characteristics

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2002
- 2002-06-28 US US10/186,361 patent/US6703338B2/en not_active Expired - Fee Related
2003
- 2003-05-29 KR KR1020047019815A patent/KR100713748B1/ko not_active Expired - Fee Related
- 2003-05-29 CN CN038126850A patent/CN1659193B/zh not_active Expired - Fee Related
- 2003-05-29 SG SG2006090062A patent/SG173215A1/en unknown
- 2003-05-29 CA CA2488052A patent/CA2488052C/en not_active Expired - Fee Related
- 2003-05-29 WO PCT/US2003/017165 patent/WO2004003031A2/en active Application Filing
- 2003-05-29 RU RU2005102068/04A patent/RU2293088C2/ru not_active IP Right Cessation
- 2003-05-29 EP EP03734308.4A patent/EP1517930B1/de not_active Expired - Lifetime
- 2003-05-29 PL PL03373380A patent/PL373380A1/xx unknown
- 2003-05-29 JP JP2004517607A patent/JP4361862B2/ja not_active Expired - Fee Related
- 2003-05-29 BR BR0305256-7A patent/BR0305256A/pt not_active Application Discontinuation
- 2003-05-29 CZ CZ20041151A patent/CZ20041151A3/cs unknown
- 2003-05-29 AU AU2003238849A patent/AU2003238849B2/en not_active Ceased
- 2003-05-29 MX MXPA05000067A patent/MXPA05000067A/es active IP Right Grant
- 2003-06-23 TW TW092117000A patent/TWI280252B/zh not_active IP Right Cessation
- 2003-06-26 WO PCT/US2003/020199 patent/WO2004003037A1/en active Application Filing
- 2003-06-26 JP JP2004517963A patent/JP2005531670A/ja not_active Withdrawn
- 2003-06-26 AU AU2003280424A patent/AU2003280424A1/en not_active Abandoned
- 2003-06-26 DE DE60336812T patent/DE60336812D1/de not_active Expired - Lifetime
- 2003-06-26 CA CA002489240A patent/CA2489240C/en not_active Expired - Fee Related
- 2003-06-26 EP EP03742245A patent/EP1517931B1/de not_active Expired - Lifetime
- 2003-06-26 JP JP2004517894A patent/JP2005530907A/ja not_active Withdrawn
- 2003-06-26 CN CNB038151561A patent/CN1302029C/zh not_active Expired - Fee Related
- 2003-06-26 EP EP03742270A patent/EP1517932A2/de not_active Withdrawn
- 2003-06-26 AT AT03742245T patent/ATE506381T1/de not_active IP Right Cessation
- 2003-06-26 MY MYPI20032414A patent/MY137541A/en unknown
- 2003-06-26 BR BR0312263-8A patent/BR0312263A/pt not_active IP Right Cessation
- 2003-06-26 CA CA002488043A patent/CA2488043C/en not_active Expired - Fee Related
- 2003-06-26 WO PCT/US2003/020320 patent/WO2004003032A2/en active Application Filing
- 2003-06-26 CN CNB038151197A patent/CN100339403C/zh not_active Expired - Fee Related
- 2003-06-26 BR BRPI0312210-7A patent/BR0312210A/pt unknown
- 2003-06-26 CN CN200710102101XA patent/CN101054388B/zh not_active Expired - Fee Related
- 2003-06-26 AU AU2003280428A patent/AU2003280428A1/en not_active Abandoned
- 2003-12-12 US US10/734,871 patent/US6858689B2/en not_active Expired - Fee Related
2004
- 2004-02-27 NO NO20040872A patent/NO20040872L/no not_active Application Discontinuation
- 2004-12-01 ZA ZA200409750A patent/ZA200409750B/en unknown

Also Published As

Publication number	Publication date
CN100339403C (zh)	2007-09-26
ATE506381T1 (de)	2011-05-15
WO2004003037A1 (en)	2004-01-08
US6858689B2 (en)	2005-02-22
ZA200409750B (en)	2005-09-29
MXPA05000067A (es)	2005-04-08
BR0312210A (pt)	2007-05-29
CN1659193A (zh)	2005-08-24
US20040167016A1 (en)	2004-08-26
CN1665849A (zh)	2005-09-07
JP2005531670A (ja)	2005-10-20
JP4361862B2 (ja)	2009-11-11
AU2003280428A1 (en)	2004-01-19
BR0312263A (pt)	2005-04-26
CA2488052A1 (en)	2004-01-08
PL373380A1 (en)	2005-08-22
CN1302029C (zh)	2007-02-28
EP1517932A2 (de)	2005-03-30
TW200403264A (en)	2004-03-01
AU2003238849B2 (en)	2007-02-15
AU2003280424A1 (en)	2004-01-19
RU2005102068A (ru)	2005-10-27
SG173215A1 (en)	2011-08-29
CN101054388A (zh)	2007-10-17
US6703338B2 (en)	2004-03-09
WO2004003031A2 (en)	2004-01-08
CA2489240C (en)	2009-09-22
MY137541A (en)	2009-02-27
CN101054388B (zh)	2012-09-26
AU2003280428A8 (en)	2004-01-19
NO20040872L (no)	2004-04-27
CZ20041151A3 (cs)	2005-08-17
CN1659193B (zh)	2012-06-20
BR0305256A (pt)	2004-10-05
EP1517930A2 (de)	2005-03-30
EP1517930B1 (de)	2016-11-02
EP1517931B1 (de)	2011-04-20
KR20050008796A (ko)	2005-01-21
WO2004003031A3 (en)	2004-07-08
CN1665850A (zh)	2005-09-07
TWI280252B (en)	2007-05-01
WO2004003032A3 (en)	2004-07-29
CA2488043C (en)	2009-12-08
RU2293088C2 (ru)	2007-02-10
JP2005527695A (ja)	2005-09-15
US20040005983A1 (en)	2004-01-08
KR100713748B1 (ko)	2007-05-04
CA2488052C (en)	2010-08-03
CA2489240A1 (en)	2004-01-08
CA2488043A1 (en)	2004-01-08
EP1517931A1 (de)	2005-03-30
AU2003238849A1 (en)	2004-01-19
WO2004003032A2 (en)	2004-01-08
JP2005530907A (ja)	2005-10-13

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