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ATE506381T1 - Halogen-substituiertes katalysatorsystem zur olefinpolymerisation - Google Patents

Halogen-substituiertes katalysatorsystem zur olefinpolymerisation

Info

Publication number
ATE506381T1
ATE506381T1 AT03742245T AT03742245T ATE506381T1 AT E506381 T1 ATE506381 T1 AT E506381T1 AT 03742245 T AT03742245 T AT 03742245T AT 03742245 T AT03742245 T AT 03742245T AT E506381 T1 ATE506381 T1 AT E506381T1
Authority
AT
Austria
Prior art keywords
halogen
catalyst system
olefin polymerization
substituted
substituted catalyst
Prior art date
Application number
AT03742245T
Other languages
English (en)
Inventor
Matthew Holtcamp
david Cano
Original Assignee
Exxonmobil Chem Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Chem Patents Inc filed Critical Exxonmobil Chem Patents Inc
Application granted granted Critical
Publication of ATE506381T1 publication Critical patent/ATE506381T1/de

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642Component covered by group C08F4/64 with an organo-aluminium compound
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06Aluminium compounds
    • C07F5/061Aluminium compounds with C-aluminium linkage
    • C07F5/066Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Indole Compounds (AREA)
  • Tires In General (AREA)
  • Disintegrating Or Milling (AREA)
  • Superconductors And Manufacturing Methods Therefor (AREA)
  • Polyethers (AREA)
AT03742245T 2002-06-28 2003-06-26 Halogen-substituiertes katalysatorsystem zur olefinpolymerisation ATE506381T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/186,361 US6703338B2 (en) 2002-06-28 2002-06-28 Polymerization catalyst activators, method of preparing, and their use in polymerization processes
PCT/US2003/020199 WO2004003037A1 (en) 2002-06-28 2003-06-26 Halogen substituted catalyst system for olefin polymerization

Publications (1)

Publication Number Publication Date
ATE506381T1 true ATE506381T1 (de) 2011-05-15

Family

ID=29999290

Family Applications (1)

Application Number Title Priority Date Filing Date
AT03742245T ATE506381T1 (de) 2002-06-28 2003-06-26 Halogen-substituiertes katalysatorsystem zur olefinpolymerisation

Country Status (20)

Country Link
US (2) US6703338B2 (de)
EP (3) EP1517930B1 (de)
JP (3) JP4361862B2 (de)
KR (1) KR100713748B1 (de)
CN (4) CN1659193B (de)
AT (1) ATE506381T1 (de)
AU (3) AU2003238849B2 (de)
BR (3) BR0305256A (de)
CA (3) CA2488052C (de)
CZ (1) CZ20041151A3 (de)
DE (1) DE60336812D1 (de)
MX (1) MXPA05000067A (de)
MY (1) MY137541A (de)
NO (1) NO20040872L (de)
PL (1) PL373380A1 (de)
RU (1) RU2293088C2 (de)
SG (1) SG173215A1 (de)
TW (1) TWI280252B (de)
WO (3) WO2004003031A2 (de)
ZA (1) ZA200409750B (de)

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US6841504B2 (en) * 2002-01-28 2005-01-11 Univation Technologies, Llc Polymerization catalyst activator and its use in a polymerization process
US6559251B1 (en) * 2002-08-02 2003-05-06 Equistar Chemicals, Lp Process for making low-density polyolefins
US7220695B2 (en) * 2004-01-07 2007-05-22 Exxonmobil Chemical Patents Inc. Supported activator
US7741417B2 (en) * 2004-01-07 2010-06-22 Exxonmobil Chemical Patents Inc. Preparation of polymerization catalyst activators utilizing indole-modified silica supports
WO2009061678A1 (en) * 2007-11-08 2009-05-14 Exxonmobil Chemicals Patents Inc. Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes
US8022005B2 (en) * 2007-11-08 2011-09-20 Exxonmobil Chemical Patents Inc. Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes
US8524846B1 (en) 2009-07-02 2013-09-03 The University Of Toledo Trianionic ligand precursor compounds and uses thereof in constrained geometry catalysts
US8957172B2 (en) 2012-08-03 2015-02-17 Exxonmobil Chemical Patents Inc. Nonsymmetric catalysts comprising salan ligands
US8952114B2 (en) 2012-08-03 2015-02-10 Exxonmobil Chemical Patents Inc. Halogenated catalysts comprising Salan ligands
US9365661B2 (en) 2012-08-03 2016-06-14 Exxonmobil Chemical Patents Inc. Polyalphaolefins prepared using modified salan catalyst compounds
US8957171B2 (en) 2012-08-03 2015-02-17 Exxonmobil Chemical Patents Inc. Catalysts comprising salan ligands
CN104379680B (zh) 2012-08-03 2017-11-28 埃克森美孚化学专利公司 具有长链支化的乙烯基封端的聚烯烃
US9382349B2 (en) 2012-08-03 2016-07-05 Exxonmobil Chemical Patents Inc. Polyalphaolefins prepared using modified Salan catalyst compounds
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WO2014143202A1 (en) 2013-03-13 2014-09-18 Exxonmobil Chemical Patents Inc. Diphenylamine salan catalyst
WO2014204624A1 (en) * 2013-06-20 2014-12-24 Exxonmobil Chemical Patents Inc. Thio-salalen catalyst
WO2014204681A1 (en) 2013-06-20 2014-12-24 Exxonmobil Chemical Patents Inc. Long-bridged salen catalyst
US9200099B2 (en) 2013-06-20 2015-12-01 Exxonmobil Chemical Patents Inc. Salenol catalyst
EP3080073B1 (de) 2013-12-13 2018-10-24 ExxonMobil Chemical Patents Inc. Cyclopentadienyl-substituierte salankatalysatoren
US9193813B2 (en) 2014-03-31 2015-11-24 Exxonmobil Chemical Patents Inc. Phenylene-bridged salalen catalysts
WO2016195824A1 (en) 2015-05-29 2016-12-08 Exxonmobil Chemical Patents Inc. Polymerization process using bridged metallocene compounds supported on organoaluminum treated layered silicate supports
BR112018001591B1 (pt) 2015-07-31 2022-09-27 Cargill, Incorporated Fibras cítricas com características aprimoradas de ligação à água, seu método de fabricação e composição alimentar contendo as mesmas

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Also Published As

Publication number Publication date
KR20050008796A (ko) 2005-01-21
JP4361862B2 (ja) 2009-11-11
JP2005530907A (ja) 2005-10-13
CA2488043C (en) 2009-12-08
TWI280252B (en) 2007-05-01
JP2005527695A (ja) 2005-09-15
EP1517931B1 (de) 2011-04-20
TW200403264A (en) 2004-03-01
RU2005102068A (ru) 2005-10-27
SG173215A1 (en) 2011-08-29
CN1665849A (zh) 2005-09-07
AU2003238849A1 (en) 2004-01-19
US20040167016A1 (en) 2004-08-26
AU2003280424A1 (en) 2004-01-19
BR0305256A (pt) 2004-10-05
WO2004003037A1 (en) 2004-01-08
CN1659193A (zh) 2005-08-24
CN1665850A (zh) 2005-09-07
JP2005531670A (ja) 2005-10-20
WO2004003031A3 (en) 2004-07-08
KR100713748B1 (ko) 2007-05-04
RU2293088C2 (ru) 2007-02-10
EP1517930A2 (de) 2005-03-30
CA2488043A1 (en) 2004-01-08
EP1517932A2 (de) 2005-03-30
EP1517931A1 (de) 2005-03-30
CA2488052C (en) 2010-08-03
CA2489240A1 (en) 2004-01-08
CN101054388A (zh) 2007-10-17
CN100339403C (zh) 2007-09-26
US20040005983A1 (en) 2004-01-08
CZ20041151A3 (cs) 2005-08-17
AU2003280428A1 (en) 2004-01-19
PL373380A1 (en) 2005-08-22
NO20040872L (no) 2004-04-27
EP1517930B1 (de) 2016-11-02
CA2489240C (en) 2009-09-22
DE60336812D1 (en) 2011-06-01
BR0312263A (pt) 2005-04-26
ZA200409750B (en) 2005-09-29
US6858689B2 (en) 2005-02-22
WO2004003031A2 (en) 2004-01-08
MXPA05000067A (es) 2005-04-08
BR0312210A (pt) 2007-05-29
WO2004003032A2 (en) 2004-01-08
CN101054388B (zh) 2012-09-26
MY137541A (en) 2009-02-27
AU2003238849B2 (en) 2007-02-15
CN1659193B (zh) 2012-06-20
AU2003280428A8 (en) 2004-01-19
WO2004003032A3 (en) 2004-07-29
CN1302029C (zh) 2007-02-28
US6703338B2 (en) 2004-03-09
CA2488052A1 (en) 2004-01-08

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