DE60333367D1 - Sulfoniertes copolymer - Google Patents
Sulfoniertes copolymerInfo
- Publication number
- DE60333367D1 DE60333367D1 DE60333367T DE60333367T DE60333367D1 DE 60333367 D1 DE60333367 D1 DE 60333367D1 DE 60333367 T DE60333367 T DE 60333367T DE 60333367 T DE60333367 T DE 60333367T DE 60333367 D1 DE60333367 D1 DE 60333367D1
- Authority
- DE
- Germany
- Prior art keywords
- sulfoned
- copolymer
- useful
- polymer electrolyte
- relates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920001577 copolymer Polymers 0.000 title abstract 2
- 239000000446 fuel Substances 0.000 abstract 1
- 239000012528 membrane Substances 0.000 abstract 1
- 239000005518 polymer electrolyte Substances 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1025—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon and oxygen, e.g. polyethers, sulfonated polyetheretherketones [S-PEEK], sulfonated polysaccharides, sulfonated celluloses or sulfonated polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0081—After-treatment of organic or inorganic membranes
- B01D67/0088—Physical treatment with compounds, e.g. swelling, coating or impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/52—Polyethers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
- B01D71/82—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74 characterised by the presence of specified groups, e.g. introduced by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
- C08G65/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols
- C08G65/40—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols from phenols (I) and other compounds (II), e.g. OH-Ar-OH + X-Ar-X, where X is halogen atom, i.e. leaving group
- C08G65/4012—Other compound (II) containing a ketone group, e.g. X-Ar-C(=O)-Ar-X for polyetherketones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
- C08G65/48—Polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
- C08L81/06—Polysulfones; Polyethersulfones
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1027—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1032—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2650/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G2650/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterized by the type of post-polymerisation functionalisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2650/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G2650/28—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type
- C08G2650/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type containing oxygen in addition to the ether group
- C08G2650/40—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type containing oxygen in addition to the ether group containing ketone groups, e.g. polyarylethylketones, PEEK or PEK
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2650/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G2650/62—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the nature of monomer used
- C08G2650/64—Monomer containing functional groups not involved in polymerisation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0082—Organic polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8803—Supports for the deposition of the catalytic active composition
- H01M4/881—Electrolytic membranes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1009—Fuel cells with solid electrolytes with one of the reactants being liquid, solid or liquid-charged
- H01M8/1011—Direct alcohol fuel cells [DAFC], e.g. direct methanol fuel cells [DMFC]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Electrochemistry (AREA)
- Sustainable Energy (AREA)
- Sustainable Development (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Polyethers (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Conductive Materials (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Inert Electrodes (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US38113602P | 2002-05-13 | 2002-05-13 | |
US42654002P | 2002-11-15 | 2002-11-15 | |
US44639503P | 2003-02-10 | 2003-02-10 | |
PCT/US2003/015178 WO2003095509A1 (en) | 2002-05-13 | 2003-05-13 | Sulfonated copolymer |
Publications (1)
Publication Number | Publication Date |
---|---|
DE60333367D1 true DE60333367D1 (de) | 2010-08-26 |
Family
ID=29424538
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE60333367T Expired - Lifetime DE60333367D1 (de) | 2002-05-13 | 2003-05-13 | Sulfoniertes copolymer |
Country Status (9)
Country | Link |
---|---|
US (1) | US7202001B2 (de) |
EP (1) | EP1517929B1 (de) |
JP (1) | JP2006506472A (de) |
CN (1) | CN100509875C (de) |
AT (1) | ATE474005T1 (de) |
AU (1) | AU2003237849B2 (de) |
CA (1) | CA2485727A1 (de) |
DE (1) | DE60333367D1 (de) |
WO (1) | WO2003095509A1 (de) |
Families Citing this family (46)
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US7572535B2 (en) | 2002-05-13 | 2009-08-11 | Polyfuel, Inc. | Ion conductive copolymers containing one or more hydrophobic oligomers |
CA2521712A1 (en) * | 2003-04-07 | 2004-10-21 | Mitsui Chemicals, Inc. | Crosslinkable ion conductive resins, and ion conductive polymer membranes, binders and fuel cells using the same resins |
WO2005001969A1 (ja) | 2003-06-25 | 2005-01-06 | Toray Industries, Inc. | 高分子電解質ならびにそれを用いた高分子電解質膜、膜電極複合体および高分子電解質型燃料電池 |
EP2088167B1 (de) * | 2003-09-30 | 2012-03-21 | Sumitomo Chemical Company, Limited | Blockcopolymer und seine Verwendung |
TW200518377A (en) * | 2003-10-17 | 2005-06-01 | Sumitomo Chemical Co | Block copolymer and applications thereof |
KR20060133990A (ko) | 2003-11-13 | 2006-12-27 | 폴리퓨얼, 인코포레이티드 | 이온 전도성 랜덤 공중합체 |
JP5076273B2 (ja) * | 2003-12-09 | 2012-11-21 | Jsr株式会社 | プロトン伝導膜 |
US7955758B2 (en) * | 2004-01-22 | 2011-06-07 | GM Global Technology Operations LLC | Membrane electrode assembly prepared by direct spray of catalyst to membrane |
WO2005082024A2 (en) * | 2004-02-24 | 2005-09-09 | Ini Power Systems, Inc. | Fuel cell apparatus and method of fabrication |
JP4729857B2 (ja) * | 2004-02-27 | 2011-07-20 | 東洋紡績株式会社 | イオン交換膜 |
US7504461B2 (en) | 2004-03-12 | 2009-03-17 | Polyfuel, Inc. | Ion-conductive copolymers containing one or more ion-conducting oligomers |
JP4821946B2 (ja) * | 2004-03-22 | 2011-11-24 | 東洋紡績株式会社 | 電解質膜及びその製造方法 |
JP2005281568A (ja) * | 2004-03-30 | 2005-10-13 | Hitachi Chem Co Ltd | 酸基含有高分子化合物、高分子電解質膜及びこれを用いた燃料電池 |
JP4742541B2 (ja) * | 2004-09-01 | 2011-08-10 | 東レ株式会社 | 耐熱性樹脂、ならびにそれを用いた樹脂組成物および成型体 |
JP5181474B2 (ja) * | 2004-09-03 | 2013-04-10 | 東レ株式会社 | 高分子電解質材料、高分子電解質部品、膜電極複合体、および高分子電解質型燃料電池 |
KR20070064610A (ko) * | 2004-09-15 | 2007-06-21 | 아이엔아이 파워 시스템즈, 인크 | 전기화학 전지 |
WO2006051749A1 (ja) | 2004-11-10 | 2006-05-18 | Toyo Boseki Kabushiki Kaisha | 芳香族炭化水素系プロトン交換膜およびこれを使用した直接メタノール型燃料電池 |
JP2006202598A (ja) * | 2005-01-20 | 2006-08-03 | Toray Ind Inc | 燃料電池用電極および燃料電池 |
TWI543202B (zh) | 2005-02-15 | 2016-07-21 | 東麗股份有限公司 | 高分子電解質材料、高分子電解質零件、膜電極複合體、高分子電解質型燃料電池及高分子電解質膜 |
US20060275638A1 (en) * | 2005-05-24 | 2006-12-07 | Polyfuel, Inc. | Ion conductive copolymers containing ion-conducting oligomers |
EP1883671A2 (de) * | 2005-05-27 | 2008-02-06 | Polyfuel, Inc. | Endgruppenverschlossene, ionenleitende polymere |
CN101185191A (zh) * | 2005-06-01 | 2008-05-21 | 复合燃料公司 | 含有离子导电共聚物和非离子聚合物的聚合物共混物 |
WO2006132207A1 (ja) * | 2005-06-09 | 2006-12-14 | Toyo Boseki Kabushiki Kaisha | スルホン酸基含有ポリマーおよびその製造方法、該スルホン酸基含有ポリマーを含有する樹脂組成物、高分子電解質膜、高分子電解質膜/電極接合体、燃料電池 |
JP4135728B2 (ja) * | 2005-06-09 | 2008-08-20 | 東洋紡績株式会社 | スルホン酸基含有ポリアリーレンエーテル系化合物およびその製造方法、該スルホン酸基含有ポリアリーレンエーテル系化合物を含有する樹脂組成物、高分子電解質膜、電解質膜/電極複合体、燃料電池および接着剤 |
JP2007002016A (ja) * | 2005-06-21 | 2007-01-11 | Toyobo Co Ltd | スルホン酸基含有ポリアリーレンエーテル系化合物およびその用途、スルホン酸基含有ポリアリーレンエーテル系化合物の製造方法 |
JP5549712B2 (ja) * | 2005-07-29 | 2014-07-16 | 東レ株式会社 | 高分子電解質材料、高分子電解質部品、膜電極複合体および高分子電解質型燃料電池 |
US7901817B2 (en) * | 2006-02-14 | 2011-03-08 | Ini Power Systems, Inc. | System for flexible in situ control of water in fuel cells |
US8178590B2 (en) * | 2006-05-31 | 2012-05-15 | Sumitomo Chemical Company, Limited | Block copolymer and use thereof |
US20080004443A1 (en) * | 2006-07-03 | 2008-01-03 | General Electric Company | Sulfonated polyaryletherketone-block-polyethersulfone copolymers |
US8158300B2 (en) * | 2006-09-19 | 2012-04-17 | Ini Power Systems, Inc. | Permselective composite membrane for electrochemical cells |
US8551667B2 (en) * | 2007-04-17 | 2013-10-08 | Ini Power Systems, Inc. | Hydrogel barrier for fuel cells |
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US8362195B2 (en) * | 2007-10-26 | 2013-01-29 | Lalgudi Ramanathan S | Ionically conductive polymer for use in electrochemical devices |
US20090162724A1 (en) * | 2007-12-18 | 2009-06-25 | Polyfuel, Inc | Ion conducting copolymers with elastomeric and polyarylene segments |
JP5319220B2 (ja) * | 2008-01-22 | 2013-10-16 | 東レ株式会社 | 高分子電解質成型体の製造方法、高分子電解質部品、膜電極複合体および高分子電解質型燃料電池 |
KR101063215B1 (ko) * | 2008-02-20 | 2011-09-07 | 한국과학기술원 | 고분자 전해질 연료전지용 강화 복합막 |
US8268195B2 (en) * | 2008-09-29 | 2012-09-18 | Air Products And Chemicals, Inc. | Electrically conductive films formed from dispersions comprising polythiophenes and ether containing polymers |
US8163429B2 (en) * | 2009-02-05 | 2012-04-24 | Ini Power Systems, Inc. | High efficiency fuel cell system |
US8177884B2 (en) * | 2009-05-20 | 2012-05-15 | United Technologies Corporation | Fuel deoxygenator with porous support plate |
JP5181004B2 (ja) * | 2010-08-27 | 2013-04-10 | Jsr株式会社 | スルホン酸基を有するポリアリーレン系ブロック共重合体、ならびにその用途 |
US8783304B2 (en) | 2010-12-03 | 2014-07-22 | Ini Power Systems, Inc. | Liquid containers and apparatus for use with power producing devices |
US9065095B2 (en) | 2011-01-05 | 2015-06-23 | Ini Power Systems, Inc. | Method and apparatus for enhancing power density of direct liquid fuel cells |
US10233323B2 (en) | 2012-03-15 | 2019-03-19 | Kraton Polymers U.S. Llc | Blends of sulfonated block copolymers and particulate carbon and membranes, films, and coatings comprising them |
JP6272908B2 (ja) * | 2013-01-28 | 2018-01-31 | デルスパー リミテッド パートナーシップ | シーリングおよび耐摩耗性構成部材のための抗押出性組成物 |
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-
2003
- 2003-05-13 CN CNB038163497A patent/CN100509875C/zh not_active Expired - Fee Related
- 2003-05-13 CA CA002485727A patent/CA2485727A1/en not_active Abandoned
- 2003-05-13 DE DE60333367T patent/DE60333367D1/de not_active Expired - Lifetime
- 2003-05-13 JP JP2004503520A patent/JP2006506472A/ja active Pending
- 2003-05-13 US US10/438,186 patent/US7202001B2/en not_active Expired - Fee Related
- 2003-05-13 AU AU2003237849A patent/AU2003237849B2/en not_active Ceased
- 2003-05-13 WO PCT/US2003/015178 patent/WO2003095509A1/en active Search and Examination
- 2003-05-13 EP EP03736609A patent/EP1517929B1/de not_active Expired - Lifetime
- 2003-05-13 AT AT03736609T patent/ATE474005T1/de not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP1517929A1 (de) | 2005-03-30 |
US20040039148A1 (en) | 2004-02-26 |
CA2485727A1 (en) | 2003-11-20 |
CN100509875C (zh) | 2009-07-08 |
CN1668656A (zh) | 2005-09-14 |
WO2003095509A1 (en) | 2003-11-20 |
US7202001B2 (en) | 2007-04-10 |
JP2006506472A (ja) | 2006-02-23 |
ATE474005T1 (de) | 2010-07-15 |
AU2003237849A1 (en) | 2003-11-11 |
EP1517929B1 (de) | 2010-07-14 |
EP1517929A4 (de) | 2005-07-20 |
AU2003237849B2 (en) | 2009-07-02 |
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