DE113281T1 - Verfahren zur reduktion von metallischen verbindungen unter verwendung von polyolen und auf diese weise hergestelltes metallisches pulver. - Google Patents
Verfahren zur reduktion von metallischen verbindungen unter verwendung von polyolen und auf diese weise hergestelltes metallisches pulver.Info
- Publication number
- DE113281T1 DE113281T1 DE198383402484T DE83402484T DE113281T1 DE 113281 T1 DE113281 T1 DE 113281T1 DE 198383402484 T DE198383402484 T DE 198383402484T DE 83402484 T DE83402484 T DE 83402484T DE 113281 T1 DE113281 T1 DE 113281T1
- Authority
- DE
- Germany
- Prior art keywords
- glycol
- salt
- polyol
- starting product
- cobalt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/16—Extraction of metal compounds from ores or concentrates by wet processes by leaching in organic solutions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/18—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
- B22F9/20—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from solid metal compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Geochemistry & Mineralogy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Removal Of Specific Substances (AREA)
- Catalysts (AREA)
- Manufacture And Refinement Of Metals (AREA)
Claims (14)
1. Verfahren zurELüssigphasenreduktion einer festen Zubereitung,
ausgewählt aus den Oxyden, Hydroxiden oder Metallsalzen, dadurch gekennzeichnet, daß man die Reduktion in
einem Polyol durchführt und die feste Metallzubereitung ausgewählt ist aus der Gruppe bestehend aus Gold, Palladium, Platin, Iridium, Osmium, Kupfer, Silber, Nickel, Kobalt,
Blei und Cadmium, wobei eine Suspension des Ausgangsmaterials in einem bei Reaktionstemperatur flüssigen Polyol
oder Polyolgemisch auf eine Temperatur von mindestens 85° C
liert.
85° C erwärmt und den gebildeten Metallniederschlag iso- ι
2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß man bei einer Temperatur von mindestens 100° C, insbesondere
100 bis 350° C arbeitet.
3. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß das
Polyol ein aliphatisches Glykol oder ein Polyäther des entsprechenden
Glykols ist, das bei der Reaktionstemperatur flüssig ist.
4. Verfahren nach Anspruch 3, dadurch gekennzeichnet, daß das
Glykol ein Alkylenglykol ist, das bis 6 Kohlenstoffatome in
der Hauptkette besitzt, oder ein Polyalkylenglykol, das von diesen Alkylenglykolen abgeleitet ist, darstellt.
5. Verfahren nach Anspruch 4, dadurch gekennzeichnet, daß das Glykol ausgewählt ist aus der Gruppe bestehend aus
Äthylenglykol, Propylenglykole, Butandiole, Dipropylenglykol
und den bei Reaktionstemperatur flüssigen PoIyäthylenglykolen.
6. Verfahrennach Anspruch 5, dadurch gekennzeichnet, daß
das Polyäthylenglykol ausgewählt ist aus Diäthylenglykol, Triäthylenglykol,- Tetraäthylenglykol und Polyäthylenglykol
300.
7. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß das Polyol Glycerol ist.
8. Verfahren nach den vorhergehenden Ansprüchen, dadurch gekennzeichnet,
daß das Ausgangsprodukt Nickelhydroxid Ni(OH)0 oder ein Nickelsalz ist.
9. Verfahren nach den Ansprüchen 1 bis 7, dadurch gekennzeichnet, daß das Ausgangsprodukt Kupferoxid Cu(OH)2, ein Kupferoxid
CuO oder Cu2O oder ein Kupfersalz ist.
10. Verfahren nach den Ansprüchen 1 bis 7, dadurch gekennzeichnet,
daß das Ausgangsprodukt ein Silbersalz ist.
11. Verfahren nach den Ansprüchen 1 bis 7, dadurch gekennzeichnet,
daß das Ausgangsprodukt Kobalthydroxid Co(OH)2, Kobaltoxid Co,0^ oder ein Kobaltsalz ist.
12. Verfahren nach den Ansprüchen 1 bis 7, dadurch gekennzeichnet,
daß das Ausgangsprodukt Bleioxid oder ein Bleirsalz
ist.
13. Verfahren nach den Ansprüchen 1 bis 7, dadurch gekennzeichnet,
daß das Ausgangsprodukt Cadmiumhydroxid
Cd(OH)2 oder ein Cadmiumsalz ist.
Cd(OH)2 oder ein Cadmiumsalz ist.
14. Metallpulver, dadurch gekennzeichnet, daß sie nach dem Verfahren gemäß einem der vorhergehenden Ansprüche erhalten
worden sind.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8221483A FR2537898A1 (fr) | 1982-12-21 | 1982-12-21 | Procede de reduction de composes metalliques par les polyols, et poudres metalliques obtenues par ce procede |
Publications (1)
Publication Number | Publication Date |
---|---|
DE113281T1 true DE113281T1 (de) | 1985-08-29 |
Family
ID=9280354
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE8383402484T Expired DE3372939D1 (en) | 1982-12-21 | 1983-12-20 | Process for reducing metallic compounds using polyols, and metallic powders produced thereby |
DE198383402484T Pending DE113281T1 (de) | 1982-12-21 | 1983-12-20 | Verfahren zur reduktion von metallischen verbindungen unter verwendung von polyolen und auf diese weise hergestelltes metallisches pulver. |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE8383402484T Expired DE3372939D1 (en) | 1982-12-21 | 1983-12-20 | Process for reducing metallic compounds using polyols, and metallic powders produced thereby |
Country Status (6)
Country | Link |
---|---|
US (1) | US4539041A (de) |
EP (1) | EP0113281B1 (de) |
JP (1) | JPS59173206A (de) |
AT (1) | ATE28810T1 (de) |
DE (2) | DE3372939D1 (de) |
FR (1) | FR2537898A1 (de) |
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CN104755639B (zh) | 2012-08-31 | 2017-12-15 | 康宁股份有限公司 | 银回收方法和由此制备的银产物 |
US9670564B2 (en) | 2012-08-31 | 2017-06-06 | Corning Incorporated | Low-temperature dispersion-based syntheses of silver and silver products produced thereby |
EP2896474B1 (de) | 2012-09-12 | 2019-01-16 | M Technique Co., Ltd. | Verfahren zur herstellung von metallmikropartikeln |
US9700940B2 (en) * | 2012-09-27 | 2017-07-11 | Lockheed Martin Corporation | Metal nanoparticles formed around a nucleus and scalable processes for producing same |
WO2016077936A1 (es) * | 2014-11-18 | 2016-05-26 | Nano Innova Spa. | Método para la formación de nano-partículas de un metal, no-metal y/o un organo-metal; nanoparticulas derivadas del proceso; y su uso industrial |
KR101711601B1 (ko) * | 2015-02-17 | 2017-03-03 | 이화이앤지 주식회사 | 산화철의 변성에 의한 동 제조방법 |
KR101703958B1 (ko) * | 2015-04-08 | 2017-02-08 | 공주대학교 산학협력단 | 내부에 구리나노입자를 포함하는 중공 나노입자 및 이의 제조방법 |
JP6004034B1 (ja) * | 2015-04-21 | 2016-10-05 | 住友金属鉱山株式会社 | 銅粉末 |
CN107584137B (zh) * | 2017-09-14 | 2020-04-03 | 浙江大学 | 一种溶液法制备金属钴的方法 |
WO2019204707A1 (en) * | 2018-04-19 | 2019-10-24 | Georgia Tech Research Corporation | Systems and methods for recycling electrodes |
CN114309632A (zh) * | 2021-11-19 | 2022-04-12 | 长沙新材料产业研究院有限公司 | 一种微米级银粉及其制备方法 |
CN114131035A (zh) * | 2021-11-30 | 2022-03-04 | 长沙新材料产业研究院有限公司 | 一种银粉的制备方法及银粉 |
CN114682791A (zh) * | 2022-03-31 | 2022-07-01 | 长沙新材料产业研究院有限公司 | 一种金纳米颗粒分散体、金纳米颗粒及其制备方法 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3165397A (en) * | 1962-03-26 | 1965-01-12 | Continental Oil Co | Preparation of aluminum particles |
US3285734A (en) * | 1963-10-01 | 1966-11-15 | C K Williams & Co Inc | Method of producing homogeneous metal-containing solid mixtures |
FR1488295A (fr) * | 1966-04-13 | 1967-07-13 | Johnson | Procédé perfectionné de formation de revêtements de platine |
US3778252A (en) * | 1970-02-12 | 1973-12-11 | Golden Cycle Corp | Process for separation and recovery of gold |
US4004917A (en) * | 1973-09-28 | 1977-01-25 | Graham Magnetics Incorporated | Acicular metallic powders produced from the organometallic salts |
US4268302A (en) * | 1975-07-11 | 1981-05-19 | Graham Magnetics Incorporated | Method of producing acicular metal crystals |
US4349380A (en) * | 1981-04-01 | 1982-09-14 | The Franklin Institute | Method of recovering metals from metal containing materials |
JPS6051523B2 (ja) * | 1981-05-19 | 1985-11-14 | 三菱マテリアル株式会社 | 銀粉末の製造法 |
-
1982
- 1982-12-21 FR FR8221483A patent/FR2537898A1/fr active Granted
-
1983
- 1983-12-20 EP EP83402484A patent/EP0113281B1/de not_active Expired
- 1983-12-20 US US06/563,621 patent/US4539041A/en not_active Expired - Lifetime
- 1983-12-20 DE DE8383402484T patent/DE3372939D1/de not_active Expired
- 1983-12-20 DE DE198383402484T patent/DE113281T1/de active Pending
- 1983-12-20 AT AT83402484T patent/ATE28810T1/de not_active IP Right Cessation
- 1983-12-21 JP JP58243037A patent/JPS59173206A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
DE3372939D1 (en) | 1987-09-17 |
JPS59173206A (ja) | 1984-10-01 |
ATE28810T1 (de) | 1987-08-15 |
US4539041A (en) | 1985-09-03 |
JPH0424402B2 (de) | 1992-04-27 |
FR2537898B1 (de) | 1985-04-26 |
FR2537898A1 (fr) | 1984-06-22 |
EP0113281A1 (de) | 1984-07-11 |
EP0113281B1 (de) | 1987-08-12 |
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