DE102007045920B4 - Synergistic drug combinations - Google Patents

Abstract

Active substance combinations comprising the compound of the formula (I) in which A is 6-chloropyrid-3-yl andR is 2,2-difluoroethyl, and an active compound of groups (2) to (25) selected from (2 -1) Azoxystrobin (2-2) Fluoxastrobin (2-3) (2E) -2- (2 - {[6- (3-chloro-2-methylphenoxy) -5-fluoro-4-pyrimidinyl] oxy) phenyl) -2- (methoxyimino) -N-methylethaneamide (2-4) Trifloxystrobin (2-5) (2E) -2- (methoxyimine {[({(1E) -1 - [3- (trifluoromethyl) phenyl] ethylidene} amino ) oxy] methyl} phenyl) ethanamide (2-6) (2E) -2- (methoxyimino) -N-methyl-2- {2 - [(E) - ({1- [3- (trifluoromethyl) phenyl] - ethoxy} imino) methyl] phenyl} ethanamide (2-8) 5-methoxy-2-methyl-4- (2 - {[({(1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) -2,4-dihydro-3H-1,2,4-triazol-3-one (2-9) kresoxime-methyl (2-10) dimoxystrobin (2-11) picoxystrobin (2-12 ) Pyraclostrobin (2-13) Metominostrobin (3-3) Propiconazole (3-4) Difenoconazole (3-6) Cyproconazole (3-7) Hexaconazole (3-8) Penconazole (3-9) Myclobutanil (3-10) Tetraconazole (3-12) Epoxiconazoles (3-13) Fl usilazole (3-15) prothioconazole (3-16) fenbuconazole (3-17) tebuconazole (3-18) ipconazole (3-19) metconazole (3-20) triticonazole (3-21) bitertanol (3-22) triadimenol ( 3-23) Triadimefon (3-24) Fluquinconazole (4-1) Dichlofluanid (4-2) Tolylfluanid (5-1) Iprovalicarb (5-3) Benthiavalicarb (6-2) Boscalid (6-5) Ethaboxam (6- 6) Fenhexamide (6-7) Carpropamide (6-8) 2-Chloro-4 - [(2-fluoro-2-methylpropanoyl) amino] -N, N-dimethylbenzamide (6-9) Fluopicolide (6-10) Zoxamide (6-11) Isotianil (6-14) Penthiopyrad (6-16) N- [2- (1,3-dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1H-pyrrole-3-carboxamide ( 6-17) Flutolanil (6-18) N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide (6-25) Fluopyram (7 -1) Mancozeb (7-2) Maneb (7-4) Propyneb (7-5) Thiram (7-6) Zineb (8-1) Benalaxyl (8-2) Furalaxyl (8-3) Metalaxyl (8-4 ) Metalaxyl-M (8-5) Benalaxyl-M (9-1) Cyprodinil (9-2) Mepanipyrim (9-3) Pyrimethanil (10-1) 6-Chloro-5 - [(3,5-dimethylisoxazole-4 -yl) sulfonyl] -2,2-difluoro-5H- [1,3] dioxolo [4,5-f] benzimidazole (10-3) carbendazim (11-1) Diethofencarb (11-2) Propamocarb (11-3) Propamocarb-hydrochloride (11-4) Propamocarb-Fosetyl (11-5) Pyribencarb (12-2) Captan (12-3) Folpet (12-4) Iprodione (12-4) 5) procymidone (13-1) dodine (13-2) guazatine (13-3) iminoctadine triacetate (14-1) cyazofamide (14-2) prochloraz (14-3) triazoxide (14-5) fenamidone (15-4 ) Fenpropimorph (15-5) dimethomorph (15-6) flumorph (16-2) fludioxonil (17-1) fosetyl-Al (17-2) phosphonic acid (17-3) tolclofos-methyl (19-1) acibenzolar-S -methyl (19-2) chlorothalonil (19-3) cymoxanil (19-5) famoxadone (19-6) fluazinam (19-7) copper oxychloride (19-9) oxadixyl (19-10) spiroxamine (19-21) cyprosulfamide (19-22) Mandipropamide (20-1) Pencycuron (20-2) Thiophanate-methyl (22-1) 5-chloro-N - [(1S) -2,2,2-trifluoro-1-methylethyl] -6 - (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyrimidin-7-amine (22-2) 5-chloro-N - [(1R) -1,2- dimethylpropyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyrimidin-7-amine (22-4) 5-chloro-6- (2,4 , 6-trifluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine (23-1) 2-butoxy -6-iodo-3-propyl-benzopyran-4-one (23-2) 2-ethoxy-6-iodo-3-propyl-benzopyran-4-one (23-3) 6-iodo-2-propoxy-3 -propyl-benzopyran-4-one (24-1) N- (3 ', 4'-dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl- 1H-pyrazole-4-carboxamide (24-3) 3- (trifluoromethyl) -N- {3'-fluoro-4 '- [(E) - (methoxyimino) methyl] -1,1'-biphenyl-2-yl } -1-methyl-1H-pyrazole-4-carboxamide (24-7) N- (4'-bromo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1, 3-thiazole-5-carboxamide (24-9) bixafen and (25-1) amisulbrom.

Description

The present invention relates to novel drug combinations which contain a known compound of formula (I) on the one hand and at least one known fungicidal active ingredient on the other hand and are very well suited for controlling unwanted animal pests such as insects and unwanted phytopathogenic fungi.

in welcher

A

für Pyrid-2-yl oder Pyrid-4-yl steht oder für Pyrid-3-yl, welches gegebenenfalls in 6-Position substituiert ist durch Fluor, Chlor, Brom, Methyl, Trifluormethyl oder Trifluormethoxy oder für Pyridazin-3-yl, welches gegebenenfalls in 6-Position substituiert ist durch Chlor oder Methyl oder für Pyrazin-3-yl oder für 2-Chlor-pyrazin-5-yl oder für 1,3-Thiazol-5-yl, welches gegebenenfalls in 2-Position substituiert ist durch Chlor oder Methyl, oder

A

für einen Rest Pyrimidinyl, Pyrazolyl, Thiophenyl, Oxazolyl, Isoxazolyl, 1,2,4-Oxadiazolyl, Isothiazolyl, 1,2,4-Triazolyl oder 1,2,5-Thiadiazolyl steht, welcher gegebenenfalls durch Fluor, Chlor, Brom, Cyano, Nitro, C₁-C₄-Alkyl (welches gegebenenfalls durch Fluor und/oder Chlor substituiert ist), C₁-C₃-Alkylthio (welches gegebenenfalls durch Fluor und/oder Chlor substituiert ist), oder C₁-C₃-Alkylsulfonyl (welches gegebenenfalls durch Fluor und/oder Chlor substituiert ist), substituiert ist,

oder

A

für einen Rest

steht,

in welchem

X

für Halogen, Alkyl oder Halogenalkyl steht

Y

für Halogen, Alkyl, Halogenalkyl, Halogenalkoxy, Azido oder Cyan steht und

R¹

für Alkyl, Halogenalkyl, Alkenyl, Halogenalkenyl, Alkinyl, Cycloalkyl, Cycloalkylalkyl, Halogencycloalkyl, Alkoxy, Alkoxyalkyl, oder Halogencycloalkylalkyl steht,

insektizide Wirkung aufweisen (vgl. EP 0 539 588 und die nicht vor-veröffentlichten internationalen Patentanmeldungen PCT/ EP2007/002386 , PCT/ EP2007/002385 , PCT/ EP2007/002392 ).It is already known that compounds of the formula (I)

in which

A

is pyrid-2-yl or pyrid-4-yl or pyrid-3-yl, which is optionally substituted in the 6-position by fluorine, chlorine, bromine, methyl, trifluoromethyl or trifluoromethoxy or pyridazin-3-yl, which optionally substituted in the 6-position by chlorine or methyl or for pyrazine-3-yl or 2-chloro-pyrazine-5-yl or 1,3-thiazol-5-yl, which is optionally substituted in the 2-position Chlorine or methyl, or

A

a radical pyrimidinyl, pyrazolyl, thiophenyl, oxazolyl, isoxazolyl, 1,2,4-oxadiazolyl, isothiazolyl, 1,2,4-triazolyl or 1,2,5-thiadiazolyl, which is optionally substituted by fluorine, chlorine, bromine, cyano , Nitro, C ₁ -C ₄ -alkyl (which is optionally substituted by fluorine and / or chlorine), C ₁ -C ₃ -alkylthio (which is optionally substituted by fluorine and / or chlorine), or C ₁ -C ₃ - Alkylsulfonyl (which is optionally substituted by fluorine and / or chlorine),

or

A

for a rest

stands,

in which

X

represents halogen, alkyl or haloalkyl

Y

represents halogen, alkyl, haloalkyl, haloalkoxy, azido or cyano and

R ¹

is alkyl, haloalkyl, alkenyl, haloalkenyl, alkynyl, cycloalkyl, cycloalkylalkyl, halocycloalkyl, alkoxy, alkoxyalkyl, or halocycloalkylalkyl,

have insecticidal activity (cf. EP 0 539 588 and the unpublished International Patent Applications PCT / EP2007 / 002386 , PCT / EP2007 / 002385 , PCT / EP2007 / 002392 ).

Furthermore, it is already known that numerous triazole derivatives, aniline derivatives, dicarboximides and other heterocycles can be used to combat fungi (cf. EP-A 0 040 345 . DE-A 22 01 063 . DE-A 23 24 010 , Pesticide Manual, 9th. Edition (1991), pages 249 and 827, EP-A 0 382 375 . EP-A 0515 901 . DE-B2 2732257 ). The effect of these substances is not always sufficient at low application rates.

Furthermore, it is already known that 1- (3,5-dimethyl-isoxazole-4-sulfonyl) -2-chloro-6,6-difluoro [1,3] -dioxolo- [4,5f] -benzimidazole has fungicidal properties (see. WO 97/06171 ).

Finally, it is also known that substituted halopyrimidines have fungicidal properties (cf. DE-A1-196 46 407 . EP-B-712 396 ).

It has now been found that active compound combinations of the compound of the formula (I) in which A is 6-chloropyrid-3-yl and R ^{1 is} 2,2-difluoroethyl (compound of the formula (I-5) ), and at least one active ingredient selected from the following groups (2) to (25) are synergistically effective and have very good insecticidal and fungicidal properties.

in welcher

A¹

für eine der Gruppen

steht,

A²

für NH oder O steht,

A³

für N oder CH steht,

L

für eine der Gruppen

steht, wobei die Bindung, die mit einem Stern (*) markiert ist, an den Phenylring gebunden ist,

R¹¹

für jeweils gegebenenfalls einfach oder zweifach, gleich oder verschieden durch Chlor, Cyano, Methyl oder Trifluormethyl substituiertes Phenyl, Phenoxy oder Pyridinyl, oder für 1-(4-Chlorphenyl)-pyrazol-3-yl oder für 1,2-Propandion-bis(O-methyloxim)-1-yl steht,

R¹²

für Wasserstoff oder Fluor steht;

Group (2) strobilurins of the general formula (II)

in which

A ¹

for one of the groups

stands,

A ²

stands for NH or O,

A ³

stands for N or CH,

L

for one of the groups

wherein the bond marked with an asterisk (*) is bound to the phenyl ring,

R ¹¹

in each case optionally monosubstituted or disubstituted by identical or different chlorine, cyano, methyl or trifluoromethyl-substituted phenyl, phenoxy or pyridinyl, or for 1- (4-chlorophenyl) pyrazol-3-yl or 1,2-propanedione bis ( O-methyloxime) -1-yl,

R ¹²

is hydrogen or fluorine;

in welcher

Q

für Wasserstoff oder SH steht,

m

für 0 oder 1 steht,

R¹³

für Wasserstoff, Fluor, Chlor, Phenyl oder 4-Chlor-phenoxy steht,

R¹⁴

für Wasserstoff oder Chlor steht,

A⁴

für eine direkte Bindung, -CH₂-, -(CH₂)₂-, -O-, für *-CH₂-CHR¹⁷- oder *-CH=CR¹⁷- steht, wobei die mit * markierte Bindung mit dem Phenylring verknüpft ist, und

R¹⁵ und R¹⁷

dann zusammen für -CH₂-CH₂-CH[CH(CH₃)_2]- oder -CH₂-CH₂-C(CH₃)₂- stehen,

A⁵

für C oder Si (Silizium) steht,

A⁴

außerdem für -N(R¹⁷)- steht und A⁵ außerdem zusammen mit R¹⁵ und R¹⁶ für die Gruppe C=N-R¹⁸ steht, wobei R¹⁷ und R¹⁸ dann zusammen für die Gruppe

stehen, wobei die mit * markierte Bindung mit R¹⁷ verbunden ist,

R¹⁵

für Wasserstoff, Hydroxy oder Cyano steht,

R¹⁶

für 1-Cyclopropylethyl, 1-Chlorcyclopropyl, C₁-C₄-Alkyl, C₁-C₆-Hydroxyalkyl, C₁-C₄-Alkylcarbonyl, C₁-C₂-Halogenalkoxy-C₁-C₂-alkyl, Trimethylsilyl-C₁-C₂-alkyl, Monofluorphenyl, oder Phenyl steht,

R¹⁵ und R¹⁶

außerdem zusammen für -O-CH₂-CH(R¹⁸)-O-, -O-CH₂-CH(R¹⁸)-CH₂-, oder -O-CH-(2-Chlorphenyl)-stehen,

R¹⁸

für Wasserstoff, C₁-C₄-Alkyl oder Brom steht;

Group (3) triazoles of the general formula (III)

in which

Q

is hydrogen or SH,

m

stands for 0 or 1,

R ¹³

is hydrogen, fluorine, chlorine, phenyl or 4-chloro-phenoxy,

R ¹⁴

is hydrogen or chlorine,

A ⁴

for a direct bond, -CH ₂ -, - (CH ₂ ) ₂ -, -O-, for * -CH ₂ -CHR ¹⁷ - or * -CH = CR ¹⁷ -, wherein the * marked bond with the phenyl ring is linked, and

R ¹⁵ and R ¹⁷

then together represent -CH ₂ -CH ₂ -CH [CH (CH ₃ ) _2] - or -CH ₂ -CH ₂ -C (CH ₃ ) ₂ -,

A ⁵

is C or Si (silicon),

A ⁴

also represents -N (R ¹⁷ ) - and A ⁵ together with R ¹⁵ and R ^{16 also represents} the group C = NR ¹⁸ , where R ¹⁷ and R ¹⁸ then together represent the group

with the bond marked with * attached to R ¹⁷ ,

R ¹⁵

is hydrogen, hydroxy or cyano,

R ¹⁶

for 1-cyclopropylethyl, 1-chlorocyclopropyl, C ₁ -C ₄ -alkyl, C ₁ -C ₆ -hydroxyalkyl, C ₁ -C ₄ -alkylcarbonyl, C ₁ -C ₂ -haloalkoxy-C ₁ -C ₂ -alkyl, trimethylsilyl C ₁ -C ₂ alkyl, monofluorophenyl, or phenyl,

R ¹⁵ and R ¹⁶

also together represent -O-CH ₂ -CH (R ¹⁸ ) -O-, -O-CH ₂ -CH (R ¹⁸ ) -CH ₂ -, or -O-CH- (2-chlorophenyl) -,

R ¹⁸

is hydrogen, C ₁ -C ₄ alkyl or bromine;

in welcher R¹⁹ für Wasserstoff oder Methyl steht; Group (4) sulfenamides of the general formula (IV)

in which R ^{19 is} hydrogen or methyl;

• (5-1) Iprovalicarb
• (5-2) N¹-[2-(4-{[3-(4-chlorophenyl)-2-propynyl]oxy}-3-methoxyphenyl)ethyl]-N²-(methylsulfonyl)-D-valinamid
• (5-3) Benthiavalicarb

Group (5) Valinamide selected from

• (5-1) Iprovalicarb
• (5-2) N ¹ - [2- (4 - {[3- (4-chlorophenyl) -2-propynyl] oxy} -3-methoxyphenyl) ethyl] -N ² - (methylsulfonyl) -D-valinamide
• (5-3) Benthiavalicarb

in welcher

X

für 2-Chlor-3-pyridinyl, für 1-Methylpyrazol-4-yl, welches in 3-Position durch Methyl oder Trifluormethyl und in 5-Position durch Wasserstoff oder Chlor substituiert ist, für 4-Ethyl-2-ethylamino-1,3-thiazol-5-yl, für 1-Methyl-cyclohexyl, für 2,2-Dichlor-1-ethyl-3-methyl-cyclopropyl, für 2-Fluor-2-propyl, 3,4-Dichlor-isothiazol-5-yl, 5,6-Dihydro-2-methyl-1,4-oxathiin-3-yl, 4-Methyl-1,2,3-thiadiazol-5-yl, 4,5-Dimethyl-2-trimethylsilyl-thiophen-3-yl, 1-Methylpyrrol-3-yl, welches in 4-Position durch Methyl oder Trifluormethyl und in 5-Position durch Wasserstoff oder Chlor substituiert ist, oder für Phenyl steht, welches einfach bis dreifach, gleich oder verschieden durch Chlor, Methyl oder Trifluormethyl substituiert ist, steht,

Y

für eine direkte Bindung, gegebenenfalls durch Chlor, Cyano oder Oxo substituiertes C₁-C₆-Alkandiyl (Alkylen), für C₂-C₆-Alkendiyl (Alkenylen) oder Thiophendiyl steht,

Z

für Wasserstoff, C₁-C₆-Alkyl oder die Gruppe

steht, in welcher

A⁶

für CH oder N steht,

R²⁰

für Wasserstoff, Chlor, Cyano, C₁-C₆-Alkyl, durch gegebenenfalls einfach oder zweifach, gleich oder verschieden durch Chlor oder Di(C₁-C₃-alkyl)aminocarbonyl substituiertes Phenyl steht,

R²¹

für Wasserstoff, Chlor oder Isopropoxy steht,

R²²

für Wasserstoff, Chlor, Hydroxy, Methyl, Trifluormethyl oder Di(C₁-C₃-alkyl)aminocarbonyl steht,

R²⁰ und R²¹

außerdem gemeinsam für *-CH(CH₃)-CH₂-C(CH₃)₂- oder *-CH(CH₃)-O-C(CH₃)₂-stehen, wobei die mit * markierte Bindung mit R²⁰ verknüpft ist;

Group (6) Carboxamides of General Formula (V)

in which

X

for 2-chloro-3-pyridinyl, for 1-methylpyrazol-4-yl which is substituted in the 3-position by methyl or trifluoromethyl and in the 5-position by hydrogen or chlorine, for 4-ethyl-2-ethylamino-1, 3-thiazol-5-yl, for 1-methyl-cyclohexyl, for 2,2-dichloro-1-ethyl-3-methyl-cyclopropyl, for 2-fluoro-2-propyl, 3,4-dichloro-isothiazole-5 -yl, 5,6-dihydro-2-methyl-1,4-oxathiin-3-yl, 4-methyl-1,2,3-thiadiazol-5-yl, 4,5-dimethyl-2-trimethylsilyl-thiophene 3-yl, 1-methylpyrrol-3-yl which is substituted in the 4-position by methyl or trifluoromethyl and in the 5-position by hydrogen or chlorine, or represents phenyl which is monosubstituted to trisubstituted by identical or different chlorine, Methyl or trifluoromethyl is substituted, stands,

Y

represents a direct bond, optionally C ₁ -C ₆ -alkanediyl (alkylene) substituted by chlorine, cyano or oxo, C ₂ -C ₆ -alkendiyl (alkenylene) or thiophenediyl,

Z

is hydrogen, C ₁ -C ₆ alkyl or the group

stands in which

A ⁶

is CH or N,

R ²⁰

represents hydrogen, chlorine, cyano, C ₁ -C ₆ -alkyl, by optionally mono- or disubstituted by identical or different chlorine or di (C ₁ -C ₃ -alkyl) aminocarbonyl-substituted phenyl,

R ²¹

is hydrogen, chlorine or isopropoxy,

R ²²

is hydrogen, chlorine, hydroxyl, methyl, trifluoromethyl or di (C ₁ -C ₃ -alkyl) aminocarbonyl,

R ²⁰ and R ²¹

also together represent * -CH (CH ₃ ) -CH ₂ -C (CH ₃ ) ₂ - or * -CH (CH ₃ ) -OC (CH ₃ ) ₂ - wherein the bond marked with * is linked to R ²⁰ ;

• (7-1) Mancozeb
• (7-2) Maneb
• (7-3) Metiram
• (7-4) Propineb
• (7-5) Thiram
• (7-6) Zineb
• (7-7) Ziram

Group (7) dithiocarbamates selected from

• (7-1) Mancozeb
• (7-2) Maneb
• (7-3) Metiram
• (7-4) Propylene
• (7-5) Thiram
• (7-6) Zineb
• (7-7) Ziram

in welcher

*

ein Kohlenstoffatom in der (R)- oder der (S)-Konfiguration, bevorzugt in der (S)-Konfiguration, kennzeichnet,

R²³

für Benzyl, Furyl oder Methoxymethyl steht;

Group (8) acylalanines of the general formula (VI)

in which

*

denotes a carbon atom in the (R) or the (S) -configuration, preferably in the (S) -configuration,

R ²³

is benzyl, furyl or methoxymethyl;

in welcher

R²⁴

für Methyl, Cyclopropyl oder 1-Propinyl steht;

Group (9): anilino-pyrimidines of the general formula (VII)

in which

R ²⁴

is methyl, cyclopropyl or 1-propynyl;

in welcher

R²⁵ und R²⁶

jeweils für Wasserstoff oder zusammen für -O-CF₂-O- stehen,

R²⁷

für Wasserstoff, C₁-C₄-Alkylaminocarbonyl oder für 3,5-Dimethylisoxazol-4-ylsulfonyl steht,

R²⁸

für Chlor, Methoxycarbonylamino, Chlorphenyl, Furyl oder Thiazolyl steht;

Group (10): Benzimidazoles of the general formula (VIII)

in which

R ²⁵ and R ²⁶

are each hydrogen or together are -O-CF ₂ -O-,

R ²⁷

is hydrogen, C ₁ -C ₄ -alkylaminocarbonyl or 3,5-dimethylisoxazol-4-ylsulfonyl,

R ²⁸

is chloro, methoxycarbonylamino, chlorophenyl, furyl or thiazolyl;

in welcher

R²⁹

für n- oder iso-Propyl steht,

R³⁰

für Di(C₁-C₂-alkyl)amino-C₂-C₄-alkyl oder Diethoxyphenyl steht,

wobei auch Salze dieser Verbindungen eingeschlossen sind;
sowie das Carbamat Pyribencarb. Group (11): carbamates of the general formula (IX)

in which

R ²⁹

is n- or iso-propyl,

R ³⁰

is di (C ₁ -C ₂ -alkyl) amino-C ₂ -C ₄ -alkyl or diethoxyphenyl,

wherein also salts of these compounds are included;
as well as the carbamate pyribencarb.

• (12-1) Captafol
• (12-2) Captan
• (12-3) Folpet
• (12-4) Iprodione
• (12-5) Procymidone
• (12-6) Vinclozolin

Group (12): dicarboximides selected from

• (12-1) Captafol
• (12-2) Captan
• (12-3) Folpet
• (12-4) Iprodione
• (12-5) procymidones
• (12-6) Vinclozoline

• (13-1) Dodine
• (13-2) Guazatine
• (13-3) Iminoctadine triacetate
• (13-4) Iminoctadine tris(albesilate)

Group (13): guanidines selected from

• (13-1) Dodine
• (13-2) Guazatine
• (13-3) iminoctadine triacetate
• (13-4) iminoctadine tris (albesilate)

• (14-1) Cyazofamid
• (14-2) Prochloraz
• (14-3) Triazoxide
• (14-4) Pefurazoate
• (14-5) Fenamidone

Group (14): imidazoles selected from

• (14-1) Cyazofamide
• (14-2) prochloraz
• (14-3) triazoxide
• (14-4) Pefurazoate
• (14-5) fenamidone

in welcher

R³¹ und R³²

unabhängig voneinander für Wasserstoff oder Methyl stehen,

R³³

für C₁-C₁₄-Alkyl (bevorzugt C₁₂-C₁₄-Alkyl), C₅-C₁₂-Cycloalkyl (bevorzugt C₁₀-C₁₂-Cycloalkyl), Phenyl-C₁-C₄-alkyl, welches im Phenylteil durch Halogen oder C₁-C₄-Alkyl substituiert sein kann, oder für Acrylyl, welches durch Chlorphenyl und Dimethoxyphenyl substituiert ist, steht;

Group (15): morpholines of the general formula (X)

in which

^R31 and ^R32

independently of one another represent hydrogen or methyl,

R ³³

for C ₁ -C ₁₄ -alkyl (preferably C ₁₂ -C ₁₄ -alkyl), C ₅ -C ₁₂ -cycloalkyl (preferably C ₁₀ -C ₁₂ -cycloalkyl), phenyl-C ₁ -C ₄ -alkyl, which is in the phenyl part by halogen or C ₁ -C ₄ -alkyl, or by acrylyl which is substituted by chlorophenyl and dimethoxyphenyl;

in welcher

R³⁴

für Chlor oder Cyano steht,

R³⁵

für Chlor oder Nitro steht,

R³⁶

für Chlor steht,

R³⁵ und R³⁶

außerdem gemeinsam für -O-CF₂-O- stehen;

Group (16): Pyrroles of General Formula (XI)

in which

R ³⁴

represents chlorine or cyano,

R ³⁵

is chlorine or nitro,

R ³⁶

stands for chlorine,

R ³⁵ and R ³⁶

also together represent -O-CF ₂ -O-;

• (17-1) Fosetyl-Al,
• (17-2) Phosphonsäure,
• (17-3) Tolclophos-methyl;

Group (17): (thio) phosphonates selected from

• (17-1) fosetyl-Al,
• (17-2) phosphonic acid,
• (17-3) tolclophos-methyl;

in welcher

R³⁷

für unsubstituiertes oder durch Fluor, Chlor, Brom, Methyl oder Ethyl substituiertes Phenyl, 2-Naphthyl, 1,2,3,4-Tetrahydronaphthyl oder Indanyl steht;

Group (18): phenylethanamides of the general formula (XII)

in which

R ³⁷

is unsubstituted or substituted by fluorine, chlorine, bromine, methyl or ethyl phenyl, 2-naphthyl, 1,2,3,4-tetrahydronaphthyl or indanyl;

• (19-1) Acibenzolar-S-methyl
• (19-2) Chlorothalonil
• (19-3) Cymoxanil
• (19-4) Edifenphos
• (19-5) Famoxadone
• (19-6) Fluazinam
• (19-7) Kupferoxychlorid
• (19-8) Kupferhydroxid
• (19-9) Oxadixyl
• (19-10) Spiroxamine
• (19-11) Dithianon
• (19-12) Metrafenone
• (19-14) 2,3-Dibutyl-6-chlor-thieno[2,3-d]pyrimidin-4(3H)on
• (19-15) Probenazole
• (19-16) Isoprothiolane
• (19-17) Kasugamycin
• (19-18) Phthalide
• (19-19) Ferimzone
• (19-20) Tricyclazole
• (19-21) Cyprosulfamide
• (19-22) Mandipropamid
• (19-23) Quinoxyfen (bekannt aus EP-A 326 330 ) der Formel
  
• (19-24) Proquinazid (bekannt aus WO 94/26722 ) der Formel
  

Group (19): Fungicides selected from

• (19-1) acibenzolar S-methyl
• (19-2) chlorothalonil
• (19-3) cymoxanil
• (19-4) Edifenphos
• (19-5) Famoxadone
• (19-6) fluazinam
• (19-7) copper oxychloride
• (19-8) copper hydroxide
• (19-9) oxadixyl
• (19-10) spiroxamine
• (19-11) Dithianon
• (19-12) Metrafenone
• (19-14) 2,3-dibutyl-6-chlorothieno [2,3-d] pyrimidin-4 (3H) on
• (19-15) Sample azoles
• (19-16) isoprothiolanes
• (19-17) Kasugamycin
• (19-18) phthalides
• (19-19) Ferimzone
• (19-20) tricyclazole
• (19-21) Cyprosulfamide
• (19-22) Mandipropamide
• (19-23) Quinoxyfen (known from EP-A 326,330 ) of the formula
  
• (19-24) Proquinazide (known from WO 94/26722 ) of the formula
  

• (20-1) Pencycuron
• (20-2) Thiophanate-methyl
• (20-3) Thiophanate-ethyl

Group (20): (thio) urea derivatives selected from

• (20-1) Pencycuron
• (20-2) thiophanate-methyl
• (20-3) thiophanate ethyl

in welcher

A⁷

für eine direkte Bindung oder -O- steht,

A⁸

für -C(=O)NH- oder -NHC(=O)- steht,

R³⁸

für Wasserstoff oder C₁-C₄-Alkyl steht,

R³⁹

für C₁-C₆-Alkyl steht;

Group (21): amides of the general formula (XIII)

in which

A ⁷

stands for a direct bond or -O-,

A ⁸

is -C (= O) NH- or -NHC (= O) -,

R ³⁸

is hydrogen or C ₁ -C ₄ -alkyl,

R ³⁹

is C ₁ -C ₆ alkyl;

in welcher

R⁴⁰

für C₁-C₆-Alkyl oder C₂-C₆-Alkenyl steht,

R⁴¹

für C₁-C₆-Alkyl steht,

R⁴⁰ und R⁴¹

außerdem gemeinsam für C₄-C₅-Alkandiyl (Alkylen) stehen, welches einfach oder zweifach durch C₁-C₆-Alkyl substituiert ist,

R⁴²

für Brom oder Chlor steht,

R⁴³ und R⁴⁷

unabhängig voneinander für Wasserstoff, Fluor, Chlor oder Methyl stehen,

R⁴⁴ und R⁴⁶

unabhängig voneinander für Wasserstoff oder Fluor stehen,

R⁴⁵

für Wasserstoff, Fluor oder Methyl steht,

Group (22): triazolopyrimidines of the general formula (XIV)

in which

R ⁴⁰

is C ₁ -C ₆ -alkyl or C ₂ -C ₆ -alkenyl,

R ⁴¹

is C ₁ -C ₆ -alkyl,

R ⁴⁰ and R ⁴¹

together also represent C ₄ -C ₅ -alkanediyl (alkylene), which is monosubstituted or disubstituted by C ₁ -C ₆ -alkyl,

R ⁴²

is bromine or chlorine,

R ⁴³ and R ⁴⁷

independently of one another represent hydrogen, fluorine, chlorine or methyl,

R ⁴⁴ and R ⁴⁶

independently of one another represent hydrogen or fluorine,

R ⁴⁵

is hydrogen, fluorine or methyl,

in welcher

R⁴⁸

für C₁-C₆-Alkyl steht,

R⁴⁹

für C₁-C₆-Alkyl, C₂-C₆-Alkenyl oder C₂-C₆-Alkinyl steht;

Group (23): iodochromones of the general formula (XV)

in which

R ⁴⁸

is C ₁ -C ₆ -alkyl,

R ⁴⁹

is C ₁ -C ₆ alkyl, C ₂ -C ₆ alkenyl or C ₂ -C ₆ alkynyl;

in welcher

R⁵⁰

für Wasserstoff oder Fluor steht,

R⁵¹

für Fluor, Chlor, Brom, Methyl, Trifluormethyl, Trifluormethoxy, -CH=N-OMe oder -C(Me)=N-OMe steht,

R⁵²

für Wasserstoff, Fluor, Chlor, Brom, Methyl oder Trifluormethyl steht, Het für einen der folgenden Reste Hetl bis Het7 steht:

R⁵³

für Iod, Methyl, Difluormethyl oder Trifluormethyl steht,

R⁵⁴

für Wasserstoff, Fluor, Chlor oder Methyl steht,

R⁵⁵

für Methyl, Difluormethyl oder Trifluormethyl steht,

R⁵⁶

für Chlor, Brom, Iod, Methyl, Difluormethyl oder Trifluormethyl steht,

R⁵⁷

für Methyl oder Trifluormethyl steht.

Group (24): biphenylcarboxamides of the general formula (XVI)

in which

R ⁵⁰

is hydrogen or fluorine,

R ⁵¹

is fluorine, chlorine, bromine, methyl, trifluoromethyl, trifluoromethoxy, -CH = N-OMe or -C (Me) = N-OMe,

R ⁵²

is hydrogen, fluorine, chlorine, bromine, methyl or trifluoromethyl, Het is one of the following radicals Hetl to Het7:

R ⁵³

is iodine, methyl, difluoromethyl or trifluoromethyl,

R ⁵⁴

is hydrogen, fluorine, chlorine or methyl,

R ⁵⁵

is methyl, difluoromethyl or trifluoromethyl,

R ⁵⁶

represents chlorine, bromine, iodine, methyl, difluoromethyl or trifluoromethyl,

R ⁵⁷

is methyl or trifluoromethyl.

• (25-1) Amisulbrom

Group (25): sulfonamides

• (25-1) Amisulbrom

Surprisingly, the fungicidal action of the active compound combinations according to the invention is substantially higher than the sum of the effects of the individual active compounds. So there is an unpredictable, true synergistic effect and not just an effect supplement.

Surprisingly, the insecticidal activity of the active compound combinations according to the invention is likewise substantially higher than the sum of the effects of the individual active compounds. So there is an unpredictable, true synergistic effect and not just an effect supplement.

The active compound combinations according to the invention contain, in addition to the compound of the formula (I), at least one active compound of the abovementioned groups (2) to (25). The active compound combinations according to the invention preferably contain exactly one compound of the formula (I) and exactly one active compound of the above-mentioned groups (2) to (25). Also preferred are combinations of active ingredients which contain a compound of the formula (I) and two active compounds of the groups (2) to (25) listed above.

• • Verbindung (1-5), 4-{[(6-Chlorpyrid-3-yl)methyl](2,2-difluorethyl)aminolfuran-2(5H)-on, besitzt die Formel
  
  und ist bekannt aus der nicht vor-veröffentlichten internationalen Patentanmeldung PCT/ EP2007/002386 .

Specifically, the following compound of the general formula (I) may be mentioned:

• Compound (1-5), 4 - {[(6-chloropyrid-3-yl) methyl] (2,2-difluoroethyl) amino-furan-2 (5H) -one, has the formula
  
  and is known from the unpublished international patent application PCT / EP2007 / 002386 ,

• (2-1) Azoxystrobin (bekannt aus EP-A 0 382 375 ) der Formel
  
• (2-2) Fluoxastrobin (bekannt aus DE-A 196 02 095 ) der Formel
  
• (2-3) (2E)-2-(2-{[6-(3-Chior-2-methylphenoxy)-5-fluor-4-pyrimidinyl]oxy}phenyl)-2-(methoxyimino)-N-methylethanamid (bekannt aus DE-A 196 46 407 , EP-B 0 712 396 ) der Formel
  
• (2-4) Trifloxystrobin (bekannt aus EP-A 0 460 575 ) der Formel
  
• (2-5) (2E)-2-(Methoxyimino)-N-methyl-2-(2-{[({(1E)-1-[3-(trifluormethyl)phenyl]ethyliden}-amino)oxy]methyl}phenyl)ethanamid (bekannt aus EP-A 0 569 384 ) der Formel
  
• (2-6) (2E)-2-(Methoxyimino)-N-methyl-2-{2-[(E)-({1-[3-(trifluormethyl)phenyl]ethoxy}imino)-methyl]phenyl}ethanamid (bekannt aus EP-A 0 596 254 ) der Formel
  
• (2-7) Orysastrobin (bekannt aus DE-A 195 39 324 ) der Formel
  
• (2-8) 5-Methoxy-2-methyl-4-(2-{[({(1E)-1-[3-(trifluormethyl)phenyl]ethyliden}amino)oxy]-methyl}phenyl)-2,4-dihydro-3H-1,2,4-triazol-3-on (bekannt aus WO 98/23155 ) der Formel
  
• (2-9) Kresoxim-methyl (bekannt aus EP-A 0 253 213 ) der Formel
  
• (2-10) Dimoxystrobin (bekannt aus EP-A 0 398 692 ) der Formel
  
• (2-11) Picoxystrobin (bekannt aus EP-A 0 278 595 ) der Formel
  
• (2-12) Pyraclostrobin (bekannt aus DE-A 44 23 612 ) der Formel
  
• (2-13) Metominostrobin (bekannt aus EP-A 0 398 692 ) der Formel
  

The formula (II) comprises the following preferred combination partners of group (2):

• (2-1) Azoxystrobin (known from EP-A 0 382 375 ) of the formula
  
• (2-2) Fluoxastrobin (known from DE-A 196 02 095 ) of the formula
  
• (2-3) (2E) -2- (2 - {[6- (3-chloro-2-methylphenoxy) -5-fluoro-4-pyrimidinyl] oxy} phenyl) -2- (methoxyimino) -N-methylethanamide (known from DE-A 196 46 407 . EP-B 0 712 396 ) of the formula
  
• (2-4) Trifloxystrobin (known from EP-A 0 460 575 ) of the formula
  
• (2-5) (2E) -2- (methoxyimino) -N-methyl-2- (2 - {[({(1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl } phenyl) ethanamide (known from EP-A 0 569 384 ) of the formula
  
• (2-6) (2E) -2- (methoxyimino) -N-methyl-2- {2 - [(E) - ({1- [3- (trifluoromethyl) phenyl] ethoxy} imino) methyl] phenyl} ethanamide (known from EP-A 0 596 254 ) of the formula
  
• (2-7) Orysastrobin (known from DE-A 195 39 324 ) of the formula
  
• (2-8) 5-methoxy-2-methyl-4- (2 - {[({(1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) -2, 4-dihydro-3H-1,2,4-triazol-3-one (known from WO 98/23155 ) of the formula
  
• (2-9) kresoxim-methyl (known from EP-A 0 253 213 ) of the formula
  
• (2-10) dimoxystrobin (known from EP-A 0 398 692 ) of the formula
  
• (2-11) Picoxystrobin (known from EP-A 0 278 595 ) of the formula
  
• (2-12) Pyraclostrobin (known from DE-A 44 23 612 ) of the formula
  
• (2-13) Metominostrobin (known from EP-A 0 398 692 ) of the formula
  

• (3-1) Azaconazole (bekannt aus DE-A 25 51 560 ) der Formel
  
• (3-2) Etaconazole (bekannt aus DE-A 25 51 560 ) der Formel
  
• (3-3) Propiconazole (bekannt aus DE-A 25 51 560 ) der Formel
  
• (3-4) Difenoconazole (bekannt aus EP-A 0 112 284 ) der Formel
  
• (3-5) Bromuconazole (bekannt aus EP-A 0 258 161 ) der Formel
  
• (3-6) Cyproconazole (bekannt aus DE-A 34 06 993 ) der Formel
  
• (3-7) Hexaconazole (bekannt aus DE-A 30 42 303 ) der Formel
  
• (3-8) Penconazole (bekannt aus DE-A 27 35 872 ) der Formel
  
• (3-9) Myclobutanil (bekannt aus EP-A 0 145 294 ) der Formel
  
• (3-10) Tetraconazole (bekannt aus EP-A 0 234 242 ) der Formel
  
• (3-11) Flutriafol (bekannt aus EP-A 0 015 756 ) der Formel
  
• (3-12) Epoxiconazole (bekannt aus EP-A 0 196 038 ) der Formel
  
• (3-13) Flusilazole (bekannt aus EP-A 0 068 813 ) der Formel
  
• (3-14) Simeconazole (bekannt aus EP-A 0 537 957 ) der Formel
  
• (3-15) Prothioconazole (bekannt aus WO 96/16048 ) der Formel
  
• (3-16) Fenbuconazole (bekannt aus DE-A 37 21 786 ) der Formel
  
• (3-17) Tebuconazole (bekannt aus EP-A 0 040 345 ) der Formel
  
• (3-18) Ipconazole (bekannt aus EP-A 0 329 397 ) der Formel
  
• (3-19) Metconazole (bekannt aus EP-A 0 329 397 ) der Formel
  
• (3-20) Triticonazole (bekannt aus EP-A 0 378 953 ) der Formel
  
• (3-21) Bitertanol (bekannt aus DE-A 23 24 010 ) der Formel
  
• (3-22) Triadimenol (bekannt aus DE-A 23 24 010 ) der Formel
  
• (3-23) Triadimefon (bekannt aus DE-A 22 01 063 ) der Formel
  
• (3-24) Fluquinconazole (bekannt aus EP-A 0 183 458 ) der Formel
  
• (3-25) Quinconazole (bekannt aus EP-A 0 183 458 ) der Formel
  

The formula (III) comprises the following preferred combination partners of group (3):

• (3-1) Azaconazole (known from DE-A 25 51 560 ) of the formula
  
• (3-2) Etaconazole (known from DE-A 25 51 560 ) of the formula
  
• (3-3) propiconazole (known from DE-A 25 51 560 ) of the formula
  
• (3-4) Difenoconazole (known from EP-A 0 112 284 ) of the formula
  
• (3-5) Bromuconazoles (known from EP-A 0 258 161 ) of the formula
  
• (3-6) Cyproconazole (known from DE-A 34 06 993 ) of the formula
  
• (3-7) hexaconazole (known from DE-A 30 42 303 ) of the formula
  
• (3-8) Penconazole (known from DE-A 27 35 872 ) of the formula
  
• (3-9) myclobutanil (known from EP-A 0 145 294 ) of the formula
  
• (3-10) Tetraconazole (known from EP-A 0 234 242 ) of the formula
  
• (3-11) flutriafol (known from EP-A 0 015 756 ) of the formula
  
• (3-12) Epoxiconazoles (known from EP-A 0 196 038 ) of the formula
  
• (3-13) Flusilazole (known from EP-A 0 068 813 ) of the formula
  
• (3-14) Simeconazole (known from EP-A 0 537 957 ) of the formula
  
• (3-15) prothioconazole (known from WO 96/16048 ) of the formula
  
• (3-16) fenbuconazole (known from DE-A 37 21 786 ) of the formula
  
• (3-17) Tebuconazole (known from EP-A 0 040 345 ) of the formula
  
• (3-18) Ipconazole (known from EP-A 0 329 397 ) of the formula
  
• (3-19) Metconazole (known from EP-A 0 329 397 ) of the formula
  
• (3-20) Triticonazole (known from EP-A 0 378 953 ) of the formula
  
• (3-21) Bitertanol (known from DE-A 23 24 010 ) of the formula
  
• (3-22) Triadimenol (known from DE-A 23 24 010 ) of the formula
  
• (3-23) Triadphone (known from DE-A 22 01 063 ) of the formula
  
• (3-24) Fluquinconazole (known from EP-A 0 183 458 ) of the formula
  
• (3-25) Quinconazole (known from EP-A 0 183 458 ) of the formula
  

• (4-1) Dichlofluanid (bekannt aus DE-A 11 93 498 ) der Formel
  
• (4-2) Tolylfluanid (bekannt aus DE-A 11 93 498 ) der Formel
  

The formula (IV) comprises the following preferred combination partners of group (4):

• (4-1) Dichlofluanid (known from DE-A 11 93 498 ) of the formula
  
• (4-2) tolylfluanid (known from DE-A 11 93 498 ) of the formula
  

• (5-1) Iprovalicarb (bekannt aus DE-A 40 26 966 ) der Formel
  
• (5-3) Benthiavalicarb (bekannt aus WO 96/04252 ) der Formel
  

Preferred combination partners of group (5) are

• (5-1) Iprovalicarb (known from DE-A 40 26 966 ) of the formula
  
• (5-3) Benthiavalicarb (known from WO 96/04252 ) of the formula
  

• (6-1) 2-Chloro-N-(1,1,3-trimethyl-indan-4-yl)-nicotinamid (bekannt aus EP-A 0 256 503 ) der Formel
  
• (6-2) Boscalid (bekannt aus DE-A 195 31 813 ) der Formel
  
• (6-3) Furametpyr (bekannt aus EP-A 0 315 502 ) der Formel
  
• (6-4) 1-Methyl-3-trifluormethy1-1H-pyrazol-4-carbonsäure-(3-p-tolyl-thiophen-2-yl)-amid (bekannt aus EP-A 0 737 682 ) der Formel
  
• (6-5) Ethaboxam (bekannt aus EP-A 0 639 574 ) der Formel
  
• (6-6) Fenhexamid (bekannt aus EP-A 0 339 418 ) der Formel
  
• (6-7) Carpropamid (bekannt aus EP-A 0 341 475 ) der Formel
  
• (6-8) 2-Chlor-4-(2-fluor-2-methyl-propionylamino)-N,N-dimethyl-benzamid (bekannt aus EP-A 0 600 629 ) der Formel
  
• (6-9) Fluopicolid (bekannt aus WO 99/42447 ) der Formel
  
• (6-10) Zoxamide (bekannt aus EP-A 0 604 019 ) der Formel
  
• (6-11) Isotianil (ISO-proposed) (bekannt aus DE-OS 19750012 ) der Formel
  
• (6-12) Carboxin (bekannt aus US 3,249,499 ) der Formel
  
• (6-13) Tiadinil (bekannt aus US 6,616,054 ) der Formel
  
• (6-14) Penthiopyrad (bekannt aus EP-A 0 737 682 ) der Formel
  
• (6-15) Silthiofam (bekannt aus WO 96/18631 ) der Formel
  
• (6-16) N-[2-(1,3-Dimethylbutyl)phenyl]-1-methyl-4-(trifluormethyl)-1H-pyrrol-3-carboxamid (bekannt aus WO 02/38542 ) der Formel
  
• (6-17) Flutolanil (bekannt aus DE-A 27 31 522 ) der Formel
  
• (6-18) N-[2-(1,3-dimethylbutyl)phenyl]-5-fluor-1,3-dimethyl-1H-pyrazol-4-carboxamid (bekannt aus EP-A 1 414 803 ) der Formel
  
• (6-20) N-[2-(1,3-dimethylbutyl)phenyl]-2-(trifluormethyl)benzamid (bekannt aus EP-A 1 519 913 ) der Formel
  
• (6-21) N-[2-(1,3-dimethylbutyl)phenyl]-2-iodbenzamid (bekannt aus EP-A 1 519 913 ) der Formel
  
• (6-22) N-(4'-chlor-3'-fluorbiphenyl-2-yl)-4-(difluormethyl)-2-methyl-1,3-thiazol-5-carboxamid (bekannt aus EP-A 1 404 407 ) der Formel
  
• (6-23) N-[5-(4-chlorphenyl)pyrimidin-4-yl]-2-iod-N-(2-iodbenzoyl)benzamid der Formel
  
• (6-24) N-(3',4'-dichlorbiphenyl-2-yl)-2-methyl-4-(trifluormethyl)-1,3-thiazol-5-carboxamid (bekannt aus EP-A 1 474 406 ) der Formel
  
• (6-25) Fluopyram (ISO-proposed) N-[2-[3-chloro-5-(trifluoromethyl)-2-pyridinyl]ethyl]-2-(trifluoromethyl)benzamide (bekannt aus WO 2004016088 )
  

The formula (V) comprises the following preferred combination partners of group (6):

• (6-1) 2-chloro-N- (1,1,3-trimethyl-indan-4-yl) nicotinamide (known from EP-A 0 256 503 ) of the formula
  
• (6-2) Boscalid (known from DE-A 195 31 813 ) of the formula
  
• (6-3) furametpyr (known from EP-A 0 315 502 ) of the formula
  
• (6-4) 1-Methyl-3-trifluoromethyl-1-H-pyrazole-4-carboxylic acid (3-p-tolyl-thiophen-2-yl) -amide (known from EP-A 0 737 682 ) of the formula
  
• (6-5) ethaboxam (known from EP-A 0 639 574 ) of the formula
  
• (6-6) fenhexamide (known from EP-A 0 339 418 ) of the formula
  
• (6-7) Carpropamid (known from EP-A 0 341 475 ) of the formula
  
• (6-8) 2-Chloro-4- (2-fluoro-2-methylpropionylamino) -N, N-dimethylbenzamide (known from EP-A 0 600 629 ) of the formula
  
• (6-9) Fluopicolide (known from WO 99/42447 ) of the formula
  
• (6-10) Zoxamide (known from EP-A 0 604 019 ) of the formula
  
• (6-11) Isotianil (ISO-proposed) (known from DE-OS 19750012 ) of the formula
  
• (6-12) Carboxin (known from US 3,249,499 ) of the formula
  
• (6-13) Tiadinil (known from US 6,616,054 ) of the formula
  
• (6-14) Penthiopyrad (known from EP-A 0 737 682 ) of the formula
  
• (6-15) Silthiofam (known from WO 96/18631 ) of the formula
  
• (6-16) N- [2- (1,3-Dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1H-pyrrole-3-carboxamide (known from WO 02/38542 ) of the formula
  
• (6-17) Flutolanil (known from DE-A 27 31 522 ) of the formula
  
• (6-18) N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide (known from EP-A 1 414 803 ) of the formula
  
• (6-20) N- [2- (1,3-dimethylbutyl) phenyl] -2- (trifluoromethyl) benzamide (known from EP-A 1 519 913 ) of the formula
  
• (6-21) N- [2- (1,3-dimethylbutyl) phenyl] -2-iodobenzamide (known from EP-A 1 519 913 ) of the formula
  
• (6-22) N- (4'-chloro-3'-fluorobiphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide (known from EP-A 1 404 407 ) of the formula
  
• (6-23) N- [5- (4-chlorophenyl) pyrimidin-4-yl] -2-iodo-N- (2-iodobenzoyl) benzamide of the formula
  
• (6-24) N- (3 ', 4'-Dichlorobiphenyl-2-yl) -2-methyl-4- (trifluoromethyl) -1,3-thiazole-5-carboxamide (known from EP-A 1 474 406 ) of the formula
  
• (6-25) Fluopyram (ISO-proposed) N- [2- [3-chloro-5- (trifluoromethyl) -2-pyridinyl] ethyl] -2- (trifluoromethyl) benzamide (known from WO 2004016088 )
  

• (7-1) Mancozeb (bekannt aus DE-A 12 34 704 ) mit dem IUPAC-Namen Manganese ethylenebis(dithiocarbamate) (polymeric) complex with zinc salt
• (7-2) Maneb (bekannt aus US 2,504,404 ) der Formel
  
• (7-3) Metiram (bekannt aus DE-A 10 76 434 ) mit dem IUPAC-Namen Zinc ammoniate ethylenebis(dithiocarbamate) - poly(ethylenethiuram disulfide)
• (7-4) Propineb (bekannt aus GB 935 981 ) der Formel
  
• (7-5) Thiram (bekannt aus US 1,972,961 ) der Formel
  
• (7-6) Zineb (bekannt aus DE-A 10 81 446 ) der Formel
  
• (7-7) Ziram (bekannt aus US 2,588,428 ) der Formel
  

Preferred combination partners of group (7) are

• (7-1) Mancozeb (known from DE-A 12 34 704 ) with the IUPAC name Manganese ethylenebis (dithiocarbamate) (polymeric) complex with zinc salt
• (7-2) Maneb (known from US 2,504,404 ) of the formula
  
• (7-3) Metiram (known from DE-A 10 76 434 ) having the IUPAC name Zinc ammoniate ethylenebis (dithiocarbamate) - poly (ethylenethiuram disulfide)
• (7-4) Propineb (known from GB 935,981 ) of the formula
  
• (7-5) Thiram (known from US 1,972,961 ) of the formula
  
• (7-6) Zineb (known from DE-A 10 81 446 ) of the formula
  
• (7-7) Ziram (known from US 2,588,428 ) of the formula
  

• (8-1) Benalaxyl (bekannt aus DE-A 29 03 612 ) der Formel
  
• (8-2) Furalaxyl (bekannt aus DE-A 25 13 732 ) der Formel
  
• (8-3) Metalaxyl (bekannt aus DE-A 25 15 091 ) der Formel
  
• (8-4) Metalaxyl-M (bekannt aus WO 96/01559 ) der Formel
  
• (8-5) Benalaxyl-M der Formel
  

The formula (VI) comprises the following preferred combination partners of the group (8):

• (8-1) Benalaxyl (known from DE-A 29 03 612 ) of the formula
  
• (8-2) Furalaxyl (known from DE-A 25 13 732 ) of the formula
  
• (8-3) metalaxyl (known from DE-A 25 15 091 ) of the formula
  
• (8-4) metalaxyl-M (known from WO 96/01559 ) of the formula
  
• (8-5) Benalaxyl-M of the formula
  

• (9-1) Cyprodinil (bekannt aus EP-A 0 310 550 ) der Formel
  
• (9-2) Mepanipyrim (bekannt aus EP-A 0 270 111 ) der Formel
  
• (9-3) Pyrimethanil (bekannt aus DD 151 404 ) der Formel
  

The formula (VII) comprises the following preferred combination partners of the group (9):

• (9-1) Cyprodinil (known from EP-A 0 310 550 ) of the formula
  
• (9-2) mepanipyrim (known from EP-A 0 270 111 ) of the formula
  
• (9-3) pyrimethanil (known from DD 151 404 ) of the formula
  

• (10-1) 6-Chlor-5-[(3,5-dimethylisoxazol-4-yl)sulfonyl]-2,2-difluor-5H-[1,3]dioxolo[4,5-flbenzimidazol (bekannt aus WO 97/06171 ) der Formel
  
• (10-2) Benomyl (bekannt aus US 3,631,176 ) der Formel
  
• (10-3) Carbendazim (bekannt aus US 3,010,968 ) der Formel
  
• (10-4) Chlorfenazole der Formel
  
• (10-5) Fuberidazole (bekannt aus DE-A 12 09 799 ) der Formel
  
• (10-6) Thiabendazole (bekannt aus US 3,206,468 ) der Formel
  

The formula (VIII) comprises the following preferred combination partners of group (10):

• (10-1) 6-Chloro-5 - [(3,5-dimethylisoxazol-4-yl) sulfonyl] -2,2-difluoro-5H- [1,3] dioxolo [4,5-flbenzimidazole (known from WO 97/06171 ) of the formula
  
• (10-2) Benomyl (known from US 3,631,176 ) of the formula
  
• (10-3) Carbendazim (known from US 3,010,968 ) of the formula
  
• (10-4) Chlorfenazoles of the formula
  
• (10-5) Fuberidazole (known from DE-A 12 09 799 ) of the formula
  
• (10-6) Thiabendazole (known from US 3,206,468 ) of the formula
  

• (11-1) Diethofencarb (bekannt aus EP-A 0 078 663 ) der Formel
  
• (11-2) Propamocarb (bekannt aus US 3,513,241 ) der Formel
  
• (11-3) Propamocarb-hydrochloride (bekannt aus US 3,513,241 ) der Formel
  
• (11-4) Propamocarb-Fosetyl der Formel
  
• (11-5) Pyribencarb (ISO-proposed, KUF-1204) [[2-Chloro-5-[(1E)-1-[[(6-methyl-2-pyridinyl)methoxy]imino]ethyl]phenyl]methyl] carbamic acid methyl ester (bekannt aus WO 2001010825 )
  

The formula (IX) comprises the following preferred combination partners of the group (11):

• (11-1) Diethofencarb (known from EP-A 0 078 663 ) of the formula
  
• (11-2) Propamocarb (known from US 3,513,241 ) of the formula
  
• (11-3) Propamocarb hydrochloride (known from US 3,513,241 ) of the formula
  
• (11-4) Propamocarb-Fosetyl of the formula
  
• (11-5) pyribencarb (ISO-proposed, KUF-1204) [[2-chloro-5 - [(1E) -1 - [[(6-methyl-2-pyridinyl) methoxy] imino] ethyl] phenyl] methyl ] carbamic acid methyl ester (known from WO 2001010825 )
  

• (12-1) Captafol (bekannt aus US 3,178,447 ) der Formel
  
• (12-2) Captan (bekannt aus US 2,553,770 ) der Formel
  
• (12-3) Folpet (bekannt aus US 2,553,770 ) der Formel
  
• (12-4) Iprodione (bekannt aus DE-A 21 49 923 ) der Formel
  
• (12-5) Procymidone (bekannt aus DE-A 20 12 656 ) der Formel
  
• (12-6) Vinclozolin (bekannt aus DE-A 22 07 576 ) der Formel
  

Preferred combination partners of group (12) are

• (12-1) Captafol (known from US 3,178,447 ) of the formula
  
• (12-2) Captan (known from US 2,553,770 ) of the formula
  
• (12-3) Folpet (known from US 2,553,770 ) of the formula
  
• (12-4) Iprodione (known from DE-A 21 49 923 ) of the formula
  
• (12-5) procymidones (known from DE-A 20 12 656 ) of the formula
  
• (12-6) Vinclozoline (known from DE-A 22 07 576 ) of the formula
  

• (13-1) Dodine (bekannt aus GB 11 03 989 ) der Formel
  
• (13-2) Guazatine (bekannt aus GB 11 14 155 )
• (13-3) Iminoctadine triacetate (bekannt aus EP-A 0 155 509 ) der Formel
  

Preferred combination partners of group (13) are

• (13-1) Dodine (known from GB 11 03 989 ) of the formula
  
• (13-2) Guazatine (known from GB 11 14 155 )
• (13-3) iminoctadine triacetate (known from EP-A 0 155 509 ) of the formula
  

• (14-1) Cyazofamid (bekannt aus EP-A 0 298 196 ) der Formel
  
• (14-2) Prochloraz (bekannt aus DE-A 24 29 523 ) der Formel
  
• (14-3) Triazoxide (bekannt aus DE-A 28 02 488 ) der Formel
  
• (14-4) Pefurazoate (bekannt aus EP-A 0 248 086 ) der Formel
  
• (14-5) Fenamidone (bekannt aus EP-A 00629616 ) der Formel
  

Preferred combination partners of group (14) are

• (14-1) Cyazofamide (known from EP-A 0 298 196 ) of the formula
  
• (14-2) prochloraz (known from DE-A 24 29 523 ) of the formula
  
• (14-3) triazoxides (known from DE-A 28 02 488 ) of the formula
  
• (14-4) Pefurazoate (known from EP-A 0 248 086 ) of the formula
  
• (14-5) Fenamidone (known from EP-A 00629616 ) of the formula
  

• (15-1) Aldimorph (bekannt aus DD 140 041 ) der Formel
  
• (15-2) Tridemorph (bekannt aus GB 988 630 ) der Formel
  
• (15-3) Dodemorph (bekannt aus DE-A 25 432 79 ) der Formel
  
• (15-4) Fenpropimorph (bekannt aus DE-A 26 56 747 ) der Formel
  
• (15-5) Dimethomorph (bekannt aus EP-A 0 219 756 ) der Formel
  
• (15-6) Flumorph (bekannt aus EP-A 0 860 438 ) der Formel
  

The formula (X) comprises the following preferred combination partners of group (15):

• (15-1) Aldimorph (known from DD 140 041 ) of the formula
  
• (15-2) Tridemorph (known from GB 988 630 ) of the formula
  
• (15-3) Dodemorph (known from DE-A 25 432 79 ) of the formula
  
• (15-4) fenpropimorph (known from DE-A 26 56 747 ) of the formula
  
• (15-5) dimethomorph (known from EP-A 0 219 756 ) of the formula
  
• (15-6) Flumorph (known from EP-A 0 860 438 ) of the formula
  

• (16-1) Fenpiclonil (bekannt aus EP-A 0 236 272 ) der Formel
  
• (16-2) Fludioxonil (bekannt aus EP-A 0 206 999 ) der Formel
  
• (16-3) Pyrrolnitrine (bekannt aus JP 65-25876 ) der Formel
  

The formula (XI) comprises the following preferred combination partners of group (16):

• (16-1) fenpiclonil (known from EP-A 0 236 272 ) of the formula
  
• (16-2) fludioxonil (known from EP-A 0 206 999 ) of the formula
  
• (16-3) pyrroline nitrines (known from JP 65-25876 ) of the formula
  

• (17-1) Fosetyl-Al (bekannt aus DE-A 24 56 627 ) der Formel
  
• (17-2) Phosphonsäure (bekannte Chemikalie) der Formel
  
• (17-3) Tolclofos-methyl (bekannt aus DE-A 25 01 040 ) der Formel
  

Preferred combination partners of group (17) are

• (17-1) Fosetyl-Al (known from DE-A 24 56 627 ) of the formula
  
• (17-2) phosphonic acid (known chemical) of the formula
  
• (17-3) Tolclofos-methyl (known from DE-A 25 01 040 ) of the formula
  

• (18-1) die Verbindung 2-(2,3-Dihydro-1H-inden-5-yl)-N-[2-(3,4-dimethoxyphenyl)ethyl]-2-(methoxyimino)acetamid der Formel
  
• (18-2) die Verbindung N-[2-(3,4-Dimethoxyphenyl)ethyl]-2-(methoxyimino)-2-(5,6,7,8-tetrahydronaphthalen-2-yl)acetamid der Formel
  
• (18-3) die Verbindung 2-(4-Chlorphenyl)-N-[2-(3,4-dimethoxyphenyl)ethyl]-2-(methoxyimino)-acetamid der Formel
  
• (18-4) die Verbindung 2-(4-Bromphenyl)-N-[2-(3,4-dimethoxyphenyl)ethyl]-2-(methoxyimino)-acetamid der Formel
  
• (18-5) die Verbindung 2-(4-Methylphenyl)-N-[2-(3,4-dimethoxyphenyl)ethyl]-2-(methoxyimino)-acetamid der Formel
  
• (18-6) die Verbindung 2-(4-Ethylphenyl)-N-[2-(3,4-dimethoxyphenyl)ethyl]-2-(methoxyimino)-acetamid der Formel
  

The formula (XII) comprises the following preferred combination partners of group (18), which consists of WO 96/23793 are known and may each be present as (E) - or (Z) isomers. Compounds of the formula (XII) can therefore be present as a mixture of different isomers or else in the form of a single isomer. Preference is given to compounds of the formula (XII) in the form of their (E) -isomer:

• (18-1) the compound 2- (2,3-dihydro-1H-inden-5-yl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide of the formula
  
• (18-2) the compound N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) -2- (5,6,7,8-tetrahydronaphthalen-2-yl) acetamide of the formula
  
• (18-3) the compound 2- (4-chlorophenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide of the formula
  
• (18-4) the compound 2- (4-bromophenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide of the formula
  
• (18-5) the compound 2- (4-methylphenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide of the formula
  
• (18-6) the compound 2- (4-ethylphenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide of the formula
  

• (19-1) Acibenzolar-S-methyl (bekannt aus EP-A 0 313 512 ) der Formel
  
• (19-2) Chlorothalonil (bekannt aus US 3,290,353 ) der Formel
  
• (19-3) Cymoxanil (bekannt aus DE-A 23 12 956 ) der Formel
  
• (19-4) Edifenphos (bekannt aus DE-A 14 93 736 ) der Formel
  
• (19-5) Famoxadone (bekannt aus EP-A 0 393 911 ) der Formel
  
• (19-6) Fluazinam (bekannt aus EP-A 0 031 257 ) der Formel
  
• (19-7) Kupferoxychlorid
• (19-9) Oxadixyl (bekannt aus DE-A 30 30 026 ) der Formel
  
• (19-10) Spiroxamine (bekannt aus DE-A 37 35 555 ) der Formel
  
• (19-11) Dithianon (bekannt aus JP-A 44-29464 ) der Formel
  
• (19-12) Metrafenone (bekannt aus EP-A 0 897 904 ) der Formel
  
• (19-13) 2,3-Dibutyl-6-chlor-thieno[2,3-d]pyrimidin-4(3H)on (bekannt aus WO 99/14202 ) der Formel
  
• (19-14) Probenazole (bekannt aus US 3,629,428 ) der Formel
  
• (19-15) Isoprothiolane (bekannt aus US 3,856,814 ) der Formel
  
• (19-16) Kasugamycin (bekannt aus GB 1 094 567 ) der Formel
  
• (19-17) Phthalide (bekannt aus JP-A 57-55844 ) der Formel
  
• (19-18) Ferimzone (bekannt aus EP-A 0 019 450 ) der Formel
  
• (19-19) Tricyclazole (bekannt aus DE-A 22 50 077 ) der Formel
  
• (19-20) Cyprosulfamide der Formel
  
• (19-21) Mandipropamid (bekannt aus WO 01/87822 ) der Formel
  

Preferred combination partners of group (19) are

• (19-1) acibenzolar-S-methyl (known from EP-A 0 313 512 ) of the formula
  
• (19-2) chlorothalonil (known from US 3,290,353 ) of the formula
  
• (19-3) Cymoxanil (known from DE-A 23 12 956 ) of the formula
  
• (19-4) Edifenphos (known from DE-A 14 93 736 ) of the formula
  
• (19-5) Famoxadone (known from EP-A 0 393 911 ) of the formula
  
• (19-6) fluazinam (known from EP-A 0 031 257 ) of the formula
  
• (19-7) copper oxychloride
• (19-9) oxadixyl (known from DE-A 30 30 026 ) of the formula
  
• (19-10) Spiroxamine (known from DE-A 37 35 555 ) of the formula
  
• (19-11) Dithianon (known from JP-A 44-29464 ) of the formula
  
• (19-12) Metrafenone (known from EP-A 0 897 904 ) of the formula
  
• (19-13) 2,3-dibutyl-6-chlorothieno [2,3-d] pyrimidin-4 (3H) on (known from WO 99/14202 ) of the formula
  
• (19-14) Probenazoles (known from US 3,629,428 ) of the formula
  
• (19-15) Isoprothiolane (known from US 3,856,814 ) of the formula
  
• (19-16) Kasugamycin (known from GB 1 094 567 ) of the formula
  
• (19-17) phthalides (known from JP-A 57-55844 ) of the formula
  
• (19-18) Ferimzone (known from EP-A 0 019 450 ) of the formula
  
• (19-19) Tricyclazole (known from DE-A 22 50 077 ) of the formula
  
• (19-20) Cyprosulfamides of the formula
  
• (19-21) Mandipropamide (known from WO 01/87822 ) of the formula
  

• (20-1) Pencycuron (bekannt aus DE-A 27 32 257 ) der Formel
  
• (20-2) Thiophanate-methyl (bekannt aus DE-A 18 06 123 ) der Formel
  
• (20-3) Thiophanate-ethyl (bekannt aus DE-A 18 06 123 ) der Formel
  

Preferred combination partners of group (20) are

• (20-1) Pencycuron (known from DE-A 27 32 257 ) of the formula
  
• (20-2) thiophanate-methyl (known from DE-A 18 06 123 ) of the formula
  
• (20-3) thiophanate-ethyl (known from DE-A 18 06 123 ) of the formula
  

• (21-1) Fenoxanil (bekannt aus EP-A 0 262 393 ) der Formel
  
• (21-2) Diclocymet (bekannt aus JP-A 7-206608 ) der Formel
  

Preferred combination partners of the group (21) are

• (21-1) fenoxanil (known from EP-A 0 262 393 ) of the formula
  
• (21-2) diclocymet (known from JP-A 7-206608 ) of the formula
  

• (22-1) 5-Chlor-N-[(1S)-2,2,2-trifluor-1-methylethyl]-6-(2,4,6-trifluorphenyl)[1,2,4]triazolo[1,5-a]-pyrimidin-7-amin (bekannt aus US 5,986,135 ) der Formel
  
• (22-2) 5-Chlor-N-[(1R)-1,2-dimethylpropyl]-6-(2,4,6-trifluorphenyl)[1,2,4]triazolo[1,5-a]pyrimidin-7-amin (bekannt aus WO 02/38565 ) der Formel
  
• (22-3) 5-Chlor-6-(2-chlor-6-fluorphenyl)-7-(4-methylpiperidin-1-yl)[1,2,4]triazolo[1,5-a]pyrimidin (bekannt aus US 5,593,996 ) der Formel
  
• (22-4) 5-Chlor-6-(2,4,6-trifluorphenyl)-7-(4-methylpiperidin-1-yl)[1,2,4]triazolo[1,5-a]pyrimidin (bekannt aus DE-A 101 24 208 ) der Formel
  

Preferred combination partners of the group (22) are

• (22-1) 5-Chloro-N - [(1S) -2,2,2-trifluoro-1-methylethyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1 , 5-a] -pyrimidin-7-amine (known from US 5,986,135 ) of the formula
  
• (22-2) 5-Chloro-N - [(1R) -1,2-dimethylpropyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyrimidine -7-amine (known from WO 02/38565 ) of the formula
  
• (22-3) 5-Chloro-6- (2-chloro-6-fluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine (known out US 5,593,996 ) of the formula
  
• (22-4) 5-Chloro-6- (2,4,6-trifluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine (known out DE-A 101 24 208 ) of the formula
  

• (23-1) 2-Butoxy-6-iod-3-propyl-benzopyran-4-on (bekannt aus WO 03/014103 ) der Formel
  
• (23-2) 2-Ethoxy-6-iod-3-propyl-benzopyran-4-on (bekannt aus WO 03/014103 ) der Formel
  
• (23-3) 6-Iod-2-propoxy-3-propyl-benzopyran-4-on (bekannt aus WO 03/014103 ) der Formel
  
• (23-4) 2-But-2-inyloxy-6-iod-3-propyl-benzopyran-4-on (bekannt aus WO 03/014103 ) der Formel
  
• (23-5) 6-Iod-2-(1-methyl-butoxy)-3-propyl-benzopyran-4-on (bekannt aus WO 03/014103 ) der Formel
  
• (23-6) 2-But-3-enyloxy-6-iod-benzopyran-4-on (bekannt aus WO 03/014103 ) der Formel
  
• (23-7) 3-Butyl-6-iod-2-isopropoxy-benzopyran-4-on (bekannt aus WO 03/014103 ) der Formel
  

Preferred combination partners of group (23) are

• (23-1) 2-Butoxy-6-iodo-3-propyl-benzopyran-4-one (known from WO 03/014103 ) of the formula
  
• (23-2) 2-Ethoxy-6-iodo-3-propyl-benzopyran-4-one (known from WO 03/014103 ) of the formula
  
• (23-3) 6-iodo-2-propoxy-3-propyl-benzopyran-4-one (known from WO 03/014103 ) of the formula
  
• (23-4) 2-But-2-ynyloxy-6-iodo-3-propyl-benzopyran-4-one (known from WO 03/014103 ) of the formula
  
• (23-5) 6-iodo-2- (1-methyl-butoxy) -3-propyl-benzopyran-4-one (known from WO 03/014103 ) of the formula
  
• (23-6) 2-But-3-enyloxy-6-iodobenzopyran-4-one (known from WO 03/014103 ) of the formula
  
• (23-7) 3-butyl-6-iodo-2-isopropoxy-benzopyran-4-one (known from WO 03/014103 ) of the formula
  

• (24-1) N-(3',4'-Dichlor-5-fluor-1,1'-biphenyl-2-yl)-3-(difluormethyl)-1-methyl-1H-pyrazol-4-carboxamid (bekannt aus WO 03/070705 ) der Formel
  
• (24-2) 3-(Difluormethyl)-N-{3'-fluor-4'-[(E)-(methoxyimino)methyl]-1,1'-biphenyl-2-yl}-1-methyl-1H-pyrazol-4-carboxamid (bekannt aus WO 02/08197 ) der Formel
  
• (24-3) 3-(Trifluormethyl)-N-{3'-fluor-4'-[(E)-(methoxyimino)methyl]-1,1'-biphenyt-2-yl}-1-methyl-1H-pyrazol-4-carboxamid (bekannt aus WO 02/08197 ) der Formel
  
• (24-4) N (3',4'-Dichlor-1,1'-biphenyl-2-yl)-5-fluor-1,3-dimethyl-1H pyrazol-4-carboxamid (bekannt aus WO 00/14701 ) der Formel
  
• (24-5) N-(4'-Chlor-3'-fluor-1,1'-biphenyl-2-yl)-2-methyl-4-(trifluonnethyl)-1,3-thiazo1-5-carboxamid (bekannt aus WO 03/066609 ) der Formel
  
• (24-6) N-(4'-Chlor-1,1'-biphenyl-2-yl)-4-(difluormethyl)-2-methyl-l,3-thiazol-5-carboxamid (bekannt aus WO 03/066610 ) der Formel
  
• (24-7) N-(4'-Brom-1,1'-biphenyl-2-yl)-4-(difluormethyl)-2-methyl-1,3-thiazol-5-carboxamid (bekannt aus WO 03/066610 ) der Formel
  
• (24-8) 4-(Difluormethyl)-2-methyl-N-[4'-(trifluormethyl)-1,1'-biphenyl-2-yl]-1,3-thiazol-5-carboxamid (bekannt aus WO 03/066610 ) der Formel
  
• (24-9) Bixafen (ISO-proposed) N-(3',4'-dichloro-5-fluoro[1,1'-biphenyl]-2-yl)-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide (bekannt aus WO 2003070705 )
  

Preferred combination partners of group (24) are

• (24-1) N- (3 ', 4'-dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide ( known from WO 03/070705 ) of the formula
  
• (24-2) 3- (Difluoromethyl) -N- {3'-fluoro-4 '- [(E) - (methoxyimino) methyl] -1,1'-biphenyl-2-yl} -1-methyl-1H pyrazole-4-carboxamide (known from WO 02/08197 ) of the formula
  
• (24-3) 3- (Trifluoromethyl) -N- {3'-fluoro-4 '- [(E) - (methoxyimino) methyl] -1,1'-biphenyt-2-yl} -1-methyl-1H pyrazole-4-carboxamide (known from WO 02/08197 ) of the formula
  
• (24-4) N (3 ', 4'-dichloro-1,1'-biphenyl-2-yl) -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide (known from WO 00/14701 ) of the formula
  
• (24-5) N- (4'-chloro-3'-fluoro-1,1'-biphenyl-2-yl) -2-methyl-4- (trifluoro-ethyl) -1,3-thiazo1-5-carboxamide ( known from WO 03/066609 ) of the formula
  
• (24-6) N- (4'-chloro-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide (known from WO 03/066610 ) of the formula
  
• (24-7) N- (4'-Bromo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide (known from WO 03/066610 ) of the formula
  
• (24-8) 4- (Difluoromethyl) -2-methyl-N- [4 '- (trifluoromethyl) -1,1'-biphenyl-2-yl] -1,3-thiazole-5-carboxamide (known from WO 03/066610 ) of the formula
  
• (24-9) Bixafen (ISO-proposed) N- (3 ', 4'-dichloro-5-fluoro [1,1'-biphenyl] -2-yl) -3- (difluoromethyl) -1-methyl-1H pyrazole-4-carboxamides (known from WO 2003070705 )
  

• (25-1) Amisulbrom (ISO-proposed, NC-224) 3-[(3-Bromo-6-fluoro-2-methyl-1H-indol-1-yl)sulfonyl]-N,N-dimethyl-1H-1,2,4-triazole-1-sulfonamid (bekannt aus JP 2001187786 )
  

Preferred combination partner of the group (25)

• (25-1) Amisulbromo (ISO-proposed, NC-224) 3 - [(3-Bromo-6-fluoro-2-methyl-1H-indol-1-yl) sulfonyl] -N, N-dimethyl-1H- 1,2,4-triazole-1-sulfonamide (known from JP 2001187786 )
  

und
(1R,3S)-2,2-Dichlor-N-[(1R)-1-(4-chlorphenyl)ethyl]-1-ethyl-3-methylcyclopropancarboxamid der Formel

The compound (6-7) carpropamid has three asymmetric substituted carbon atoms. The compound (6-7) may therefore be present as a mixture of different isomers or in the form of a single component. Particularly preferred are the compounds
(1S, 3R) -2,2-dichloro-N - [(1R) -1- (4-chlorophenyl) ethyl] -1-ethyl-3-methylcyclopropanecarboxamide of the formula

and
(1R, 3S) -2,2-dichloro-N - [(1R) -1- (4-chlorophenyl) ethyl] -1-ethyl-3-methylcyclopropanecarboxamide of the formula

According to the invention, the active compound combinations according to the invention contain the compound of the formula (I) in which A is selected from 6-chloropyrid-3-yl and R ^{1 is} selected from 2,2-difluoroethyl, and an active ingredient selected from those above groups (2) to (25).

• (2-1) Azoxystrobin
• (2-2) Fluoxastrobin
• (2-3) (2E)-2-(2-{[6-(3-Chlor-2-methylphenoxy)-5-fluor-4-pyrimidinyl]oxy)phenyl)-2-(methoxyimino)-N-methylethanamid
• (2-4) Trifloxystrobin
• (2-5) (2E)-2-(Methoxyimin{[({(IE)-1-[3-(trifluormethyl)phenyl]ethyliden}amino)oxy]methyl}phenyl)ethanamid
• (2-6) (2E)-2-(Methoxyimino)-N-methyl-2-{2-[(E)-({1-[3-(trifluormethyl)phenyl]-ethoxy}imino)methyl]phenyl}ethanamid
• (2-8) 5-Methoxy-2-methyl-4-(2- {[({(1E)-1-[3-(trifluormethyl)phenyl]ethyliden}-amino)oxy]methyl}phenyl)-2,4-dihydro-3H-1,2,4-triazol-3-on
• (2-9) Kresoxim-methyl
• (2-10) Dimoxystrobin
• (2-11) Picoxystrobin
• (2-12) Pyraclostrobin
• (2-13) Metominostrobin
• (3-3) Propiconazole
• (3-4) Difenoconazole
• (3-6) Cyproconazole
• (3-7) Hexaconazole
• (3-8) Penconazole
• (3-9) Myclobutanil
• (3-10) Tetraconazole
• (3-12) Epoxiconazole
• (3-13) Flusilazole
• (3-15) Prothioconazole
• (3-16) Fenbuconazole
• (3-17) Tebuconazole
• (3-18) Ipconazole
• (3-19) Metconazole
• (3-20) Triticonazole
• (3-21) Bitertanol
• (3-22) Triadimenol
• (3-23) Triadimefon
• (3-24) Fluquinconazole
• (4-1) Dichlofluanid
• (4-2) Tolylfluanid
• (5-1) Iprovalicarb
• (5-3) Benthiavalicarb
• (6-2) Boscalid
• (6-5) Ethaboxam
• (6-6) Fenhexamid
• (6-7) Carpropamid
• (6-8) 2-Chlor-4-[(2-fluor-2-methylpropanoyl)amino]-N,N-dimethylbenzamid
• (6-9) Fluopicolid
• (6-10) Zoxamide
• (6-11) Isotianil
• (6-14) Penthiopyrad
• (6-16) N-[2-(1,3-Dimethylbutyl)phenyl]-1-methyl-4-(trifluormethyl)-1H-pyrrol-3-carboxarnid
• (6-17) Flutolanil
• (6-18) N-[2-(1,3-dimethylbutyl)phenyl]-5-fluor-1,3-dimethyl-IH-pyrazo1-4-carboxamid
• (6-25) Fluopyram
• (7-1) Mancozeb
• (7-2) Maneb
• (7-4) Propineb
• (7-5) Thiram
• (7-6) Zineb
• (8-1) Benalaxyl
• (8-2) Furalaxyl
• (8-3) Metalaxyl
• (8-4) Metalaxyl-M
• (8-5) Benalaxyl-M
• (9-1) Cyprodinil
• (9-2) Mepanipyrim
• (9-3) Pyrimethanil
• (10-1) 6-Chlor-5-[(3,5-dimethylisoxazol-4-yl)sulfonyl]-2,2-difluor-5H-[1,3]dioxolo[4,5-f]-benzimidazol
• (10-3) Carbendazim
• (11-1) Diethofencarb
• (11-2) Propamocarb
• (11-3) Propamocarb-hydrochloride
• (11-4) Propamocarb-Fosetyl
• (11-5) Pyribencarb
• (12-2) Captan
• (12-3) Folpet
• (12-4) Iprodione
• (12-5) Procymidone
• (13-1) Dodine
• (13-2) Guazatine
• (13-3) Iminoctadine triacetate
• (14-1) Cyazofamid
• (14-2) Prochloraz
• (14-3) Triazoxide
• (14-5) Fenamidone
• (15-4) Fenpropimorph
• (15-5) Dimethomorph
• (15-6) Flumorph
• (16-2) Fludioxonil
• (17-1) Fosetyl-Al
• (17-2) Phosphonsäure
• (17-3) Tolclofos-methyl
• (19-1) Acibenzolar-S-methyl
• (19-2) Chlorothalonil
• (19-3) Cymoxanil
• (19-5) Famoxadone
• (19-6) Fluazinam
• (19-7) Kupferoxychlorid
• (19-9) Oxadixyl
• (19-10) Spiroxamine
• (19-21) Cyprosulfamide
• (19-22) Mandipropamid
• (20-1) Pencycuron
• (20-2) Thiophanate-methyl
• (22-1) 5-Chlor-N-[(1S)-2,2,2-trifluor-1-methylethyl]-6-(2,4,6-trifluorphenyl)[1,2,4]triazolo[1,5-a]-pyrimidin-7-amin
• (22-2) 5-Chlor-N-[(1R)-1,2-dimethylpropyl]-6-(2,4,6-trifluorphenyl)[1,2,4]triazolo[1,5-a]pyrimidin-7-amin
• (22-4) 5-Chlor-6-(2,4,6-trifluorphenyl)-7-(4-methylpiperidin-1-yl)[1,2,4]triazolo[1,5-a]pyrimidin
• (23-1) 2-Butoxy-6-iod-3-propyl-benzopyran-4-on
• (23-2) 2-Ethoxy-6-iod-3-propyl-benzopyran-4-on
• (23-3) 6-Iod-2-propoxy-3-propyl-benzopyran-4-on
• (24-1) N-(3',4'-Dichlor-5-fluor-1,1'-biphenyl-2-yl)-3-(difluormethyl)-1-methyl-1H-pyrazol-4-carboxamid
• (24-3) 3-(Trifluormethyl)-N-{3'-fluor-4'-[(E)-(methoxyimino)methyl]-1,1'-biphenyl-2-yl}-1-methyl-1H-pyrazol-4-carboxamid
• (24-7) N-(4'-Brom-1,1'-biphenyl-2-yl)-4-(difluormethyl)-2-methyl-1,3-thiazol-5-carboxamid
• (24-9) Bixafen
• (25-1) Amisulbrom

As combination partners of groups (2) to (25), the following active substances are particularly preferred:

• (2-1) Azoxystrobin
• (2-2) Fluoxastrobin
• (2-3) (2E) -2- (2 - {[6- (3-chloro-2-methylphenoxy) -5-fluoro-4-pyrimidinyl] oxy) phenyl) -2- (methoxyimino) -N-methylethanamide
• (2-4) Trifloxystrobin
• (2-5) (2E) -2- (methoxyimine {[({(IE) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) ethanamide
• (2-6) (2E) -2- (methoxyimino) -N-methyl-2- {2 - [(E) - ({1- [3- (trifluoromethyl) phenyl] ethoxy} imino) methyl] phenyl} ethanamide
• (2-8) 5-methoxy-2-methyl-4- (2- {[({(1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) -2, 4-dihydro-3H-1,2,4-triazol-3-one
• (2-9) Kresoxim-methyl
• (2-10) dimoxystrobin
• (2-11) Picoxystrobin
• (2-12) Pyraclostrobin
• (2-13) Metominostrobin
• (3-3) propiconazole
• (3-4) difenoconazole
• (3-6) Cyproconazole
• (3-7) hexaconazole
• (3-8) Penconazole
• (3-9) myclobutanil
• (3-10) Tetraconazole
• (3-12) Epoxiconazoles
• (3-13) Flusilazole
• (3-15) prothioconazole
• (3-16) fenbuconazole
• (3-17) Tebuconazole
• (3-18) ipconazole
• (3-19) Metconazole
• (3-20) Triticonazole
• (3-21) Bitertanol
• (3-22) Triadimenol
• (3-23) Triadphone
• (3-24) Fluquinconazole
• (4-1) Dichlofluanid
• (4-2) tolylfluanid
• (5-1) Iprovalicarb
• (5-3) Benthiavalicarb
• (6-2) Boscalid
• (6-5) Ethaboxam
• (6-6) fenhexamide
• (6-7) carpropamide
• (6-8) 2-Chloro-4 - [(2-fluoro-2-methylpropanoyl) amino] -N, N-dimethylbenzamide
• (6-9) fluopicolide
• (6-10) Zoxamide
• (6-11) Isotianil
• (6-14) Penthiopyrad
• (6-16) N- [2- (1,3-Dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1H-pyrrole-3-carboxamide
• (6-17) Flutolanil
• (6-18) N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide
• (6-25) Fluopyram
• (7-1) Mancozeb
• (7-2) Maneb
• (7-4) Propylene
• (7-5) Thiram
• (7-6) Zineb
• (8-1) Benalaxyl
• (8-2) Furalaxyl
• (8-3) metalaxyl
• (8-4) metalaxyl-M
• (8-5) Benalaxyl-M
• (9-1) Cyprodinil
• (9-2) mepanipyrim
• (9-3) pyrimethanil
• (10-1) 6-Chloro-5 - [(3,5-dimethylisoxazol-4-yl) sulfonyl] -2,2-difluoro-5H- [1,3] dioxolo [4,5-f] benzimidazole
• (10-3) carbendazim
• (11-1) Diethofencarb
• (11-2) Propamocarb
• (11-3) Propamocarb hydrochloride
• (11-4) Propamocarb-Fosetyl
• (11-5) Pyribencarb
• (12-2) Captan
• (12-3) Folpet
• (12-4) Iprodione
• (12-5) procymidones
• (13-1) Dodine
• (13-2) Guazatine
• (13-3) iminoctadine triacetate
• (14-1) Cyazofamide
• (14-2) prochloraz
• (14-3) triazoxide
• (14-5) fenamidone
• (15-4) fenpropimorph
• (15-5) dimethomorph
• (15-6) Flumorphic
• (16-2) fludioxonil
• (17-1) fosetyl-Al
• (17-2) phosphonic acid
• (17-3) tolclofos-methyl
• (19-1) acibenzolar S-methyl
• (19-2) chlorothalonil
• (19-3) cymoxanil
• (19-5) Famoxadone
• (19-6) fluazinam
• (19-7) copper oxychloride
• (19-9) oxadixyl
• (19-10) spiroxamine
• (19-21) Cyprosulfamide
• (19-22) Mandipropamide
• (20-1) Pencycuron
• (20-2) thiophanate-methyl
• (22-1) 5-Chloro-N - [(1S) -2,2,2-trifluoro-1-methylethyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1 , 5-a] pyrimidin-7-amine
• (22-2) 5-Chloro-N - [(1R) -1,2-dimethylpropyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyrimidine -7-amine
• (22-4) 5-Chloro-6- (2,4,6-trifluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine
• (23-1) 2-Butoxy-6-iodo-3-propyl-benzopyran-4-one
• (23-2) 2-ethoxy-6-iodo-3-propyl-benzopyran-4-one
• (23-3) 6-iodo-2-propoxy-3-propyl-benzopyran-4-one
• (24-1) N- (3 ', 4'-dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide
• (24-3) 3- (trifluoromethyl) -N- {3'-fluoro-4 '- [(E) - (methoxyimino) methyl] -1,1'-biphenyl-2-yl} -1-methyl-1H pyrazole-4-carboxamide
• (24-7) N- (4'-Bromo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide
• (24-9) Bixafen
• (25-1) Amisulbrom

• (2-1) Azoxystrobin
• (2-2) Fluoxastrobin
• (2-3) (2E)-2-(2-{[6-(3-Chlor-2-methylphenoxy)-5-fluor-4-pyrimidinyl]oxy)phenyl)-2-(methoxyimino)-N-methylethanamid
• (2-4) Trifloxystrobin
• (3-15) Prothioconazole
• (3-17) Tebuconazole
• (3-18) Ipconazole
• (3-20) Triticonazole
• (3-21) Bitertanol
• (3-22) Triadimenol
• (3-24) Fluquinconazole
• (4-1) Dichlofluanid
• (4-2) Tolylfluanid
• (5-1) Iprovalicarb
• (6-6) Fenhexamid
• (6-7) Carpropamid
• (6-9) Fluopicolid
• (6-11) Isotianil
• (6-14) Penthiopyrad
• (6-17) Flutolanil
• (6-18) N-[2-(1,3-dimethylbutyl)phenyl]-5-fluor-1,3-dimethyl-1H-pyrazo1-4-carboxamid
• (6-25) Fluopyram
• (7-4) Propineb
• (7-5) Thiram
• (8-3) Metalaxyl
• (8-4) Metalaxyl-M
• (8-5) Benalaxyl-M
• (9-3) Pyrimethanil
• (10-3) Carbendazim
• (11-2) Propamocarb
• (11-4) Propamocarb-Fosetyl
• (11-5) Pyribencarb
• (12-4) Iprodione
• (14-2) Prochloraz
• (14-3) Triazoxide
• (14-5) Fenamidone
• (16-2) Fludioxonil
• (17-1) Fosetyl-Al
• (17-3) Tolclofos-methyl
• (19-10) Spiroxamine
• (19-21) Cyprosulfamide
• (19-22) Mandipropamid
• (20-1) Pencycuron
• (22-4) 5-Chlor-6-(2,4,6-trifluorphenyl)-7-(4-methylpiperidin-1-yl)[1,2,4]triazolo[1,5-a]pyrimidin
• (24-1) N-(3',4'-Dichlor-5-fluor-1,1'-biphenyl-2-yl)-3-(difluormethyl)-3-methyl-1H-pyrazol-4-carboxamid
• (24-9) Bixafen
• (25-1) Amisulbrom

As combination partners of groups (2) to (25), the following active substances are very particularly preferred:

• (2-1) Azoxystrobin
• (2-2) Fluoxastrobin
• (2-3) (2E) -2- (2 - {[6- (3-chloro-2-methylphenoxy) -5-fluoro-4-pyrimidinyl] oxy) phenyl) -2- (methoxyimino) -N-methylethanamide
• (2-4) Trifloxystrobin
• (3-15) prothioconazole
• (3-17) Tebuconazole
• (3-18) ipconazole
• (3-20) Triticonazole
• (3-21) Bitertanol
• (3-22) Triadimenol
• (3-24) Fluquinconazole
• (4-1) Dichlofluanid
• (4-2) tolylfluanid
• (5-1) Iprovalicarb
• (6-6) fenhexamide
• (6-7) carpropamide
• (6-9) fluopicolide
• (6-11) Isotianil
• (6-14) Penthiopyrad
• (6-17) Flutolanil
• (6-18) N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide
• (6-25) Fluopyram
• (7-4) Propylene
• (7-5) Thiram
• (8-3) metalaxyl
• (8-4) metalaxyl-M
• (8-5) Benalaxyl-M
• (9-3) pyrimethanil
• (10-3) carbendazim
• (11-2) Propamocarb
• (11-4) Propamocarb-Fosetyl
• (11-5) Pyribencarb
• (12-4) Iprodione
• (14-2) prochloraz
• (14-3) triazoxide
• (14-5) fenamidone
• (16-2) fludioxonil
• (17-1) fosetyl-Al
• (17-3) tolclofos-methyl
• (19-10) spiroxamine
• (19-21) Cyprosulfamide
• (19-22) Mandipropamide
• (20-1) Pencycuron
• (22-4) 5-Chloro-6- (2,4,6-trifluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine
• (24-1) N- (3 ', 4'-dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -3-methyl-1H-pyrazole-4-carboxamide
• (24-9) Bixafen
• (25-1) Amisulbrom

• (2-1) Azoxystrobin
• (2-2) Fluoxastrobin
• (2-4) Trifloxystrobin
• (3-15) Prothioconazole
• (3-17) Tebuconazole
• (3-18) Ipconazole
• (3-20) Triticonazole
• (3-22) Triadimenol
• (4-2) Tolylfluanid
• (5-1) Iprovalicarb
• (6-7) Carpropamid
• (6-9) Fluopicolid
• (6-11) Isotianil
• (6-18) N-[2-(1,3-dimethylbutyl)phenyl]-5-fluor-1,3-dimethyl-1H-pyrazol-4-carboxamid
• (6-25) Fluopyram
• (7-5) Thiram
• (8-3) Metalaxyl
• (8-4) Metalaxyl-M
• (11-2) Propamocarb
• (11-5) Pyribencarb
• (12-4) Iprodione
• (14-5) Fenamidone
• (16-2) Fludioxonil
• (17-1) Fosetyl-Al
• (19-10) Spiroxamine
• (19-21) Cyprosulfamide
• (20-1) Pencycuron
• (24-1) N-(3',4'-Dichlor-5-fluor-1,1'-biphenyl-2-yl)-3-(difluormethyl)-1-methyl-1H-pyrazol-4-carboxamid
• (24-9) Bixafen
• (25-1) Amisulbrom

As combination partners of groups (2) to (25), the following active substances are particularly preferred:

• (2-1) Azoxystrobin
• (2-2) Fluoxastrobin
• (2-4) Trifloxystrobin
• (3-15) prothioconazole
• (3-17) Tebuconazole
• (3-18) ipconazole
• (3-20) Triticonazole
• (3-22) Triadimenol
• (4-2) tolylfluanid
• (5-1) Iprovalicarb
• (6-7) carpropamide
• (6-9) fluopicolide
• (6-11) Isotianil
• (6-18) N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide
• (6-25) Fluopyram
• (7-5) Thiram
• (8-3) metalaxyl
• (8-4) metalaxyl-M
• (11-2) Propamocarb
• (11-5) Pyribencarb
• (12-4) Iprodione
• (14-5) fenamidone
• (16-2) fludioxonil
• (17-1) fosetyl-Al
• (19-10) spiroxamine
• (19-21) Cyprosulfamide
• (20-1) Pencycuron
• (24-1) N- (3 ', 4'-dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide
• (24-9) Bixafen
• (25-1) Amisulbrom

This gives the combinations listed in Table 5, each combination represents a preferred embodiment of the invention itself. Containing active ingredient combination No combination of active ingredients Compound of formula I Active substance of groups 2 to 25 5-1 1-5 and (2-1) Azoxystrobin 5-2 1-5 and (2-2) Fluoxastrobin 5-3 1-5 and (2-3) (2E) -2- (2 - {[6- (3-chloro-2-methylphenoxy) -5-fluoro-4-pyrimidinyl] oxy} phenyl) -2- (methoxyimino) -N-methylethanamide 5-4 1-5 and (2-4) Trifloxystrobin 5-5 I-5 and (3-15) prothioconazole 5-6 1-5 and (3-17) Tebuconazole 5-7 1-5 and (3-18) ipconazole 5-8 1-5 and (3-20) Triticonazole 5-9 1-5 and (3-21) Bitertanol 5-10 1-5 and (3-22) Triadimenol 5-11 1-5 and (3-24) Fluquinconazole 5-12 I-5 and (4-1) Dichlofluanid 5-13 1-5 and (4-2) tolylfluanid 5-14 1-5 and (5-1) Iprovalicarb 5-15 1-5 and (6-6) fenhexamide 5-16 1-5 and (6-7) carpropamide 5-17 1-5 and (6-9) fluopicolide 5-18 1-5 and (6-11) Isotianil 5-19 1-5 and (6-14) Penthiopyrad 5-20 1-5 and (6-17) Flutolanil 5-21 1-5 (6-18) N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide 5-22 1-5 (6-25) Fluopyram 5-23 1-5 (7-4) Propylene 5-24 I-5 and (7-5) Thiram 5-25 1-5 and (8-3) metalaxyl 5-26 I-5 and (8-4) metalaxyl-M 5-27 I-5 and (8-5) Benalaxyl-M 5-28 I-5 and (9-3) pyrimethanil 5-29 I-5 and (10-3) carbendazim 5-30 1-5 and (11-2) Propamocarb 5-31 I-5 and (11-4) Propamocarb-Fosetyl 5-32 I-5 and (11-5) Pyribencarb 5-33 I-5 and (12-4) Iprodione 5-34 I-5 and (14-2) prochloraz 5-35 I-5 and (14-3) triazoxide 5-36 I-5 and (14-5) fenamidone 5-37 I-5 and (16-2) fludioxonil 5-38 I-5 and (17-1) fosetyl-Al 5-39 I-5 and (17-3) tolclofos-methyl 5-40 I-5 and (19-10) spiroxamine 5-41 I-5 and (19-21) Cyprosulfamide 5-42 I-5 and (19-22) Mandipropamide 5-43 I-5 and (20-1) Pencycuron 5-44 I-5 and (22-4) 5-Chloro-6- (2,4,6-trifluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine 5-45 I-5 and (24-1) N- (3 ', 4'-dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide 5-46 I-5 and (24-9) Bixafen 5-47 I-5 and (25-1) Amisulbrom

Preferred embodiments of the invention for the treatment of seed are active compound combinations comprising the compound of the formula (I-5) and fluoxastrobin (2-2) and / or trifloxystrobin (2-4) and / or prothioconazole (3-15) and / or tebuconazole ( 3-17) and / or ipconazoles (3-18) and / or triticonazoles (3-20) and / or triadimenol (3-22) and / or carpropamide (6-7) and / or N- [2- (1 , 3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide (6-18) and / or thiram (7-5) and / or metalaxyl (8-3) and / or metalaxyl-M (8-4) and / or N- ({4 - [(cyclopropylamino) -carbonyl] -phenyl} -sulfonyl) -2-methoxy-benzamide (19-21) and / or pencycuron (20-1 ) and / or N- (3 ', 4'-dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl) -1H-pyrazole-4-carboxamide ( 24-1).

The active compound combinations according to the invention contain, in addition to the compound of the formula (I), at least one active compound of the groups (2) to (25). You may also contain other fungicidal Zumischkomponenten.

If the active ingredients in the active compound combinations according to the invention are present in certain weight ratios, the synergistic effect is particularly pronounced. However, the weight ratios of the active ingredients in the drug combinations can be varied within a relatively wide range. In general, the combinations according to the invention contain compounds of the formula (I) and a combination partner from one of the groups (2) to (25) in the mixing ratios exemplified in the table below.

The mixing ratios are based on weight ratios. The ratio is to be understood as compound of the formula (I): combination partner combination partners preferred mixing ratio particularly preferred mixing ratio Group (2): strobilurins 125: 1 to 1: 2000 50: 1 to 1: 1000 Group (3): triazoles 125: 1 to 1: 2000 50: 1 to 1: 1000 Group (4): sulphenamides 500: 1 to 1:25 250: 1 to 1: 1 Group (5): Valinamide 125: 1 to 1: 2000 50: 1 to 1: 1000 Group (6): Carboxamides without (6-6) 125: 1 to 1: 2000 50: 1 to 1: 1000 (6-6): 500: 1 to 1:25 250: 1 to 1: 1 Group (7): dithiocarbamates 500: 1 to 1:25 250: 1 to 1: 1 Group (8): acylalanines 125: 1 to 1: 2000 50: 1 to 1: 1000 Group (9): Anilino-pyrimidine 500: 1 to 1:25 250 1 to 1: 1 Group (10): benzimidazoles 125: 1 to 1: 2000 50: 1 to 1: 1000 Group (11): carbamates 500: 1 to 1:25 250: 1 to 1: 1 Group (12): Group (13): Dicarboximide guanidines 500: 1 125: 1 until to 1: 25 1: 2000 250: 1 50: 1 until to 1: 1 1: 1000 Group (14): imidazoles 125: 1 to 1: 2000 50: 1 to 1: 1000 Group (15): morpholines 125: 1 to 1: 2000 50: 1 to 1: 1000 Group (16): pyrroles 125: 1 to 1: 2000 50: 1 to 1: 1000 Group (17): (Thio) phosphonates 500: 1 to 1:25 250: 1 to 1: 1 Group (18): Phenylethanamide 125: 1 to 1: 2000 50: 1 to 1: 1000 (19-1): Acibenzolar-S-methyl 125: 1 to 1: 2000 50: 1 to 1: 1000 (19-2): chlorothalonil 500: 1 to 1:25 250: 1 to 1: 1 (19-3): cymoxanil 125: 1 to 1: 2000 50: 1 to 1: 1000 (19-4): edifenphos 125: 1 to 1: 2000 50: 1 to 1: 1000 (19-5): famoxadone 125: 1 to 1: 2000 50: 1 to 1: 1000 (19-6): fluazinam 125: 1 to 1: 2000 50: 1 to 1: 1000 (19-7): copper oxychloride 500: 1 to 1:25 250: 1 to 1: 1 (19-8): copper hydroxide 500: 1 to 1:25 250: 1 to 1: 1 (19-9): oxadixyl 125: 1 to 1: 2000 50: 1 to 1: 1000 (19-10): spiroxamine 125: 1 to 1: 2000 50: 1 to 1: 1000 (19-11) dithianon 500: 1 to 1:25 250: 1 to 1: 1 (19-12) metrafenone 125: 1 to 1: 2000 50: 1 to 1: 1000 (19-14): 2,3-dibutyl-6-chloro-thieno [2,3-d] pyrimidin-4 (3H) -one 125: 1 to 1: 2000 50: 1 to 1: 1000 (19-15): Probenazole 125: 1 to 1: 2000 50: 1 to 1: 1000 (19-16): isoprothiolane 125: 1 to 1: 2000 50: 1 to 1: 1000 (19-17): kasugamycin 125: 1 to 1: 2000 50: 1 to 1: 1000 (19-18): phthalides 125: 1 to 1: 2000 50: 1 to 1: 1000 (19-19): Ferimzone 125: 1 to 1: 2000 50: 1 to 1: 1000 (19-20): Tricyclazole 125: 1 to 1: 2000 50: 1 to 1: 1000 (19-21): cyprosulfamide 125: 1 to 1: 2000 50: 1 to 1: 1000 (19-22) 2- (4-Chloro-phenyl) -N- {2- [3-methoxy-4- (prop-2-yn-1-yloxy) -phenyl] -ethyl} -2- (prop-2-yn-1-yloxy) -acetamide 125: 1 to 1: 2000 50: 1 to 1: 1000 Group (20): (Thio) urea derivatives 125: 1 to 1: 2000 50: 1 to 1: 1000 Group (21): amides 125: 1 to 1: 2000 50: 1 to 1: 1000 Group (22): Triazolopvrimidine 125: 1 to 1: 2000 50: 1 to 1: 1000 Group (23): Iodochromones 125: 1 to 1: 2000 50: 1 to 1: 1000 Group (24): biphenylcarboxamides 125: 1 to 1: 2000 50: 1 to 1: 1000

The compounds of the formula (I) or the active compounds from the abovementioned groups (2) to (25) having at least one basic center are capable of forming, for example, acid addition salts, for example with strong inorganic acids such as mineral acids, eg perchloric acid, sulfuric acid , Nitric acid, nitrous acid, a phosphoric acid or a hydrohalic acid, with strong organic carboxylic acids such as unsubstituted or substituted, eg halogen-substituted, C ₁ -C ₄ alkanecarboxylic acids, for example acetic acid, saturated or unsaturated dicarboxylic acids, for example oxalic acid, malonic acid, succinic acid, maleic acid, fumaric acid and phthalic acid, hydroxycarboxylic acids, for example ascorbic acid, lactic acid, malic acid, tartaric acid and citric acid, or benzoic acid, or with organic sulfonic acids such as unsubstituted or substituted, for example halogen-substituted, C ₁ -C ₄ -alkanoic or arylsulfonic acids, for example methane- or p-toluenesulfonic acid. The compounds of the formula (I) or the active compounds from the abovementioned groups (2) to (25) having at least one acidic group are capable of forming, for example, salts with bases, for example metal salts such as alkali metal or alkaline earth metal salts, eg Sodium, potassium or magnesium salts, or salts with ammonia or an organic amine such as morpholine, piperidine, pyrrolidine, a lower mono-, di- or trialkylamine, for example ethyl, diethyl, triethyl or dimethylpropylamine, or a lower mono- , Di- or trihydroxyalkylamine, for example mono-, di- or triethanolamine. In addition, if appropriate, corresponding internal salts can be formed. Agrochemically advantageous salts are preferred in the context of the invention. In view of the close relationship between the compounds of formula (I) or the active compounds of the above groups (2) to (25) in free form and in the form of their salts, above and below any reference to the free compounds of formula (I ) or to free active compounds from the abovementioned groups (2) to (25) or their salts, so that the corresponding salts or the free compounds of the formula (I) or the free active compounds from the groups listed above ( 2) to (25), if appropriate and appropriate. This also applies correspondingly to tautomers of the compounds of the formula (I) or of the active compounds from the abovementioned groups (2) to (25) and to their salts.

In the context of the present invention, the term "active substance combination" stands for different combinations of compounds of the formula (I) and active compounds from the above-mentioned groups (2) to (25), e.g. in the form of a single ready-mix, in a combined spray mixture composed of separate formulations of the individual active ingredients, e.g. a tank mix or in a combined use of the individual active ingredients when applied sequentially, e.g. successively within a reasonably short period of time, e.g. a few hours or days. In a preferred embodiment, the order of application of the compounds of formula (I) and the active compounds of groups (2) to (25) listed above is not critical to the practice of the present invention.

When using the active compound combinations according to the invention as fungicides, insecticides or acaricides, the application rates can be varied within a relatively wide range, depending on the mode of administration. The application rate of the active compound combinations according to the invention is in the treatment of parts of plants, eg leaves from 0.1 to 10,000 g / ha, preferably from 10 to 1,000 g / ha, particularly preferably from 50 to 300 g / ha (when applied by pouring or drops the application rate can even be reduced, especially if inert substrates such as rockwool or perlite are used); in seed treatment from 2 to 200 g per 100 kg of seed, preferably from 3 to 150 g per 100 kg of seed, more preferably from 2.5 to 25 g of pro 100 kg of seed, most preferably from 2.5 to 12.5 g per 100 kg of seed; in the soil treatment from 0.1 to 10,000 g / ha, preferably from 1 to 5,000 g / ha.

These application rates are given by way of example only and not by way of limitation within the meaning of the invention.

The active compound combinations according to the invention can be used to protect plants within a certain period of time after the treatment against attack by phytopathogenic fungi and / or animal pests. The period of time within which protection is afforded generally ranges from 1 to 28 days, preferably from 1 to 14 days, more preferably from 1 to 10 days, most preferably from 1 to 7 days after treatment of the plants with the active ingredients or up to 200 days after seed treatment.

The active compound combinations according to the invention are suitable for plant tolerance, favorable warm-blooded toxicity and good environmental compatibility for the protection of plants and plant organs, for increasing crop yields, improving the quality of the crop and for controlling phytopathogenic fungi such as Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes, etc., and animal pests, in particular insects, arachnids, helminths, nematodes and molluscs, which are found in agriculture, horticulture, livestock, forests, gardens and recreational facilities, in the protection of materials and materials and in the hygiene sector. They can preferably be used as crop protection agents. They are effective against normally sensitive and resistant species as well as against all or individual stages of development.

The active compound combinations according to the invention have very good fungicidal properties and can be used for controlling phytopathogenic fungi, such as Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes, etc.

The active compound combinations according to the invention are particularly suitable for controlling Phytophthora infestans, Plasmopara viticola and Botrytis cinerea.

By way of example, but not by way of limitation, some pathogens of fungal and bacterial diseases, which fall under the abovementioned generic terms, are mentioned:

Fungicides can be used in crop protection to combat Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes and Deuteromycetes.

Bactericides can be used in crop protection for controlling Pseudomonadaceae, Rhizobiaceae, Enterobacteriaceae, Corynebacteriaceae and Streptomycetaceae.

• Erkrankungen, hervorgerufen durch Erreger des Echten Mehltaus wie z.B.
• Blumeria-Arten, wie beispielsweise Blumeria graminis;
• Podosphaera-Arten, wie beispielsweise Podosphaera leucotricha;
• Sphaerotheca-Arten, wie beispielsweise Sphaerotheca fuliginea;
• Uncinula-Arten, wie beispielsweise Uncinula necator;
• Erkrankungen, hervorgerufen durch Erreger von Rostkrankheiten wie z.B.
• Gymnosporangium-Arten, wie beispielsweise Gymnosporangium sabinae
• Hemileia-Arten, wie beispielsweise Hemileia vastatrix;
• Phakopsora-Arten, wie beispielsweise Phakopsora pachyrhizi und Phakopsora meibomiae;
• Puccinia-Arten, wie beispielsweise Puccinia recondita;
• Uromyces-Arten, wie beispielsweise Uromyces appendiculatus;
• Erkrankungen, hervorgerufen durch Erreger der Gruppe der Oomyceten wie z.B.
• Bremia-Arten, wie beispielsweise Bremia lactucae;
• Peronospora-Arten, wie beispielsweise Peronospora pisi oder P. brassicae;
• Phytophthora-Arten, wie beispielsweise Phytophthora infestans;
• Plasmopara-Arten, wie beispielsweise Plasmopara viticola;
• Pseudoperonospora-Arten, wie beispielsweise Pseudoperonospora humuli oder
• Pseudoperonospora cubensis;
• Pythium-Arten, wie beispielsweise Pythium ultimum;
• Blattfleckenkrankheiten und Blattwelken, hervorgerufen durch z.B.
• Alternaria-Arten, wie beispielsweise Alternaria solani;
• Cercospora-Arten, wie beispielsweise Cercospora beticola;
• Cladiosporum-Arten, wie beispielsweise Cladiosporium cucumerinum;
• Cochliobolus-Arten, wie beispielsweise Cochliobolus sativus
• (Konidienform: Drechslera, Syn: Helminthosporium);
• Colletotrichum-Arten, wie beispielsweise Colletotrichum lindemuthanium;
• Cycloconium-Arten, wie beispielsweise Cycloconium oleaginum;
• Diaporthe-Arten, wie beispielsweise Diaporthe citri;
• Elsinoe-Arten, wie beispielsweise Elsinoe fawcettii;
• Gloeosporium-Arten, wie beispielsweise Gloeosporium laeticolor;
• Glomerella-Arten, wie beispielsweise Glomerella cingulata;
• Guignardia-Arten, wie beispielsweise Guignardia bidwelli;
• Leptosphaeria-Arten, wie beispielsweise Leptosphaeria maculans;
• Magnaporthe-Arten, wie beispielsweise Magnaporthe grisea;
• Mycosphaerella-Arten, wie beispielsweise Mycosphaerelle graminicola;
• Phaeosphaeria-Arten, wie beispielsweise Phaeosphaeria nodorum;
• Pyrenophora-Arten, wie beispielsweise Pyrenophora teres;
• Ramularia-Arten, wie beispielsweise Ramularia collo-cygni;
• Rhynchosporium-Arten, wie beispielsweise Rhynchosporium secalis;
• Septoria-Arten, wie beispielsweise Septoria apii;
• Typhula-Arten, wie beispielsweise Typhula incarnata;
• Venturia-Arten, wie beispielsweise Venturia inaequalis;
• Wurzel- und Stengelkrankheiten, hervorgerufen durch z.B.
• Corticium-Arten, wie beispielsweise Corticium graminearum;
• Fusarium-Arten, wie beispielsweise Fusarium oxysporum;
• Gaeumannomyces-Arten, wie beispielsweise Gaeumannomyces graminis;
• Rhizoctonia-Arten, wie beispielsweise Rhizoctonia solani;
• Tapesia-Arten, wie beispielsweise Tapesia acuformis;
• Thielaviopsis-Arten, wie beispielsweise Thielaviopsis basicola;
• Ähren- und Rispenerkrankungen (inklusive Maiskolben), hervorgerufen durch z.B.
• Alternaria-Arten, wie beispielsweise Alternaria spp.;
• Aspergillus-Arten, wie beispielsweise Aspergillus flavus;
• Cladosporium-Arten, wie beispielsweise Cladosporium spp.;
• Claviceps-Arten, wie beispielsweise Claviceps purpurea;
• Fusarium-Arten, wie beispielsweise Fusarium culmorum;
• Gibberella-Arten, wie beispielsweise Gibberella zeae;
• Monographella-Arten, wie beispielsweise Monographella nivalis;
• Erkrankungen, hervorgerufen durch Brandpilze wie z.B.
• Sphacelotheca-Arten, wie beispielsweise Sphacelotheca reiliana;
• Tilletia-Arten, wie beispielsweise Tilletia caries;
• Urocystis-Arten, wie beispielsweise Urocystis occulta;
• Ustilago-Arten, wie beispielsweise Ustilago nuda;
• Fruchtfäule hervorgerufen durch z.B.
• Aspergillus-Arten, wie beispielsweise Aspergillus flavus;
• Botrytis-Arten, wie beispielsweise Botrytis cinerea;
• Penicillium-Arten, wie beispielsweise Penicillium expansum;
• Sclerotinia-Arten, wie beispielsweise Sclerotinia sclerotiorum;
• Verticilium-Arten, wie beispielsweise Verticilium alboatrum;
• Samen- und bodenbürtige Fäulen und Welken, sowie Sämlingserkrankungen, hervorgerufen durch z.B.
• Fusarium-Arten, wie beispielsweise Fusarium culmorum;
• Phytophthora Arten, wie beispielsweise Phytophthora cactorum;
• Pythium-Arten, wie beispielsweise Pythium ultimum;
• Rhizoctonia-Arten, wie beispielsweise Rhizoctonia solani;
• Sclerotium-Arten, wie beispielsweise Sclerotium rolfsii;
• Krebserkrankungen, Gallen und Hexenbesen, hervorgerufen durch z.B.
• Nectria-Arten, wie beispielsweise Nectria galligena;
• Welkeerkrankungen hervorgerufen durch z.B.
• Monilinia-Arten, wie beispielsweise Monilinia laxa;
• Deformationen von Blättern, Blüten und Früchten, hervorgerufen durch z.B.
• Taphrina-Arten, wie beispielsweise Taphrina deformans;
• Degenerationserkrankungen holziger pflanzen, hervorgerufen durch z.B.
• Esca-Arten, wie beispielsweise Phaemoniella clamydospora;
• Blüten- und Samenerkrankungen, hervorgerufen durch z.B.
• Botrytis-Arten, wie beispielsweise Botrytis cinerea;
• Erkrankungen von Pflanzenknollen, hervorgerufen durch z.B.
• Rhizoctonia-Arten, wie beispielsweise Rhizoctonia solani;
• Erkrankungen, hervorgerufen durch bakterielle Erreger wie z.B.
• Xanthomonas-Arten, wie beispielsweise Xanthomonas campestris pv. oryzae;
• Pseudomonas-Arten, wie beispielsweise Pseudomonas syringae pv. lachrymans;
• Erwinia-Arten, wie beispielsweise Erwinia amylovora;
• Bevorzugt können die folgenden Krankheiten von Soja-Bohnen bekämpft werden:
  • Pilzkrankheiten an Blättern, Stängeln, Schoten und Samen verursacht durch z.B.
  • Alternaria leaf spot (Alternaria spec. atrans tenuissima), Anthracnose (Colletotrichum gloeosporoides dematium var. truncatum), Brown spot (Septoria glycines), Cercospora leaf spot and blight (Cercospora kikuchii), Choanephora leaf blight (Choanephora infundibulifera trispora (Syn.)), Dactuliophora leaf spot (Dactuliophora glycines), Downy Mildew (Peronospora manshurica), Drechslera blight (Drechslera glycini), Frogeye Leaf spot (Cercospora sojina), Leptosphaerulina Leaf Spot (Leptosphaerulina trifolii), Phyllostica Leaf Spot (Phyllosticta sojaecola), Powdery Mildew (Microsphaera diffusa), Pyrenochaeta Leaf Spot (Pyrenochaeta glycines), Rhizoctonia Aerial, Foliage, and Web Blight (Rhizoctonia solani), Rust (Phakopsora pachyrhizi), Scab (Sphaceloma glycines), Stemphylium Leaf Blight (Stemphylium botryosum), Target Spot (Corynespora cassiicola).

By way of example but not limitation, some pathogens of fungal and bacterial diseases, which fall under the above-enumerated generic terms, are named:

• Diseases caused by pathogens of powdery mildew such as
• Blumeria species, such as Blumeria graminis;
• Podosphaera species, such as Podosphaera leucotricha;
• Sphaerotheca species, such as Sphaerotheca fuliginea;
• Uncinula species, such as Uncinula necator;
• Diseases caused by causative agents of rust diseases such as
• Gymnosporangium species, such as Gymnosporangium sabinae
• Hemileia species, such as Hemileia vastatrix;
• Phakopsora species such as Phakopsora pachyrhizi and Phakopsora meibomiae;
• Puccinia species, such as Puccinia recondita;
• Uromyces species, such as Uromyces appendiculatus;
• Diseases caused by pathogens of the group of Oomycetes such as
• Bremia species, such as Bremia lactucae;
• Peronospora species such as Peronospora pisi or P. brassicae;
• Phytophthora species, such as Phytophthora infestans;
• Plasmopara species, such as Plasmopara viticola;
• Pseudoperonospora species, such as Pseudoperonospora humuli or
• Pseudoperonospora cubensis;
• Pythium species such as Pythium ultimum;
• Leaf spot diseases and leaf withering, caused by eg
• Alternaria species, such as Alternaria solani;
• Cercospora species, such as Cercospora beticola;
• Cladiosporum species, such as Cladiosporium cucumerinum;
• Cochliobolus species, such as Cochliobolus sativus
• (Conidia form: Drechslera, Syn: Helminthosporium);
• Colletotrichum species, such as Colletotrichum lindemuthanium;
• Cycloconium species such as cycloconium oleaginum;
• Diaporthe species, such as Diaporthe citri;
• Elsinoe species, such as Elsinoe fawcettii;
• Gloeosporium species, such as, for example, Gloeosporium laeticolor;
• Glomerella species, such as Glomerella cingulata;
• Guignardia species, such as Guignardia bidwelli;
• Leptosphaeria species, such as Leptosphaeria maculans;
• Magnaporthe species, such as Magnaporthe grisea;
• Mycosphaerella species, such as Mycosphaerelle graminicola;
• Phaeosphaeria species, such as Phaeosphaeria nodorum;
• Pyrenophora species, such as, for example, Pyrenophora teres;
• Ramularia species, such as Ramularia collo-cygni;
• Rhynchosporium species, such as Rhynchosporium secalis;
• Septoria species, such as Septoria apii;
• Typhula species, such as Typhula incarnata;
• Venturia species, such as Venturia inaequalis;
• Root and stem diseases, caused by eg
• Corticium species, such as Corticium graminearum;
• Fusarium species such as Fusarium oxysporum;
• Gaeumannomyces species such as Gaeumannomyces graminis;
• Rhizoctonia species, such as Rhizoctonia solani;
• Tapesia species, such as Tapesia acuformis;
• Thielaviopsis species, such as Thielaviopsis basicola;
• Ear and panicle diseases (including corncob), caused by eg
• Alternaria species, such as Alternaria spp .;
• Aspergillus species, such as Aspergillus flavus;
• Cladosporium species such as Cladosporium spp .;
• Claviceps species, such as Claviceps purpurea;
• Fusarium species such as Fusarium culmorum;
• Gibberella species, such as Gibberella zeae;
• Monographella species, such as Monographella nivalis;
• Diseases caused by fire fungi such as
• Sphacelotheca species, such as Sphacelotheca reiliana;
• Tilletia species, such as Tilletia caries;
• Urocystis species, such as Urocystis occulta;
• Ustilago species such as Ustilago nuda;
• Fruit rot caused by eg
• Aspergillus species, such as Aspergillus flavus;
• Botrytis species, such as Botrytis cinerea;
• Penicillium species such as Penicillium expansum;
• Sclerotinia species, such as Sclerotinia sclerotiorum;
• Verticilium species such as Verticilium alboatrum;
• Seed and soil-borne rots and wilting, and seedling diseases, caused by eg
• Fusarium species such as Fusarium culmorum;
• Phytophthora species, such as Phytophthora cactorum;
• Pythium species such as Pythium ultimum;
• Rhizoctonia species, such as Rhizoctonia solani;
• Sclerotium species, such as Sclerotium rolfsii;
• Cancers, galls and witches brooms, caused by eg
• Nectria species, such as Nectria galligena;
• Wilting diseases caused by eg
• Monilinia species, such as Monilinia laxa;
• Deformations of leaves, flowers and fruits, caused by eg
• Taphrina species, such as Taphrina deformans;
• Degenerative diseases woody plants, caused by eg
• Esca species, such as Phaemoniella clamydospora;
• Flower and seed diseases, caused by eg
• Botrytis species, such as Botrytis cinerea;
• Diseases of plant tubers, caused by eg
• Rhizoctonia species, such as Rhizoctonia solani;
• Diseases caused by bacterial pathogens such as
• Xanthomonas species, such as Xanthomonas campestris pv. Oryzae;
• Pseudomonas species, such as Pseudomonas syringae pv. Lachrymans;
• Erwinia species, such as Erwinia amylovora;
• Preferably, the following diseases of soybean beans can be controlled:
  • Fungal diseases on leaves, stems, pods and seeds caused by eg
  • Alternaria leaf spot (Alternaria spec. Atrans tenuissima), Anthracnose (Colletotrichum gloeosporoides dematium var. Truncatum), Brown spot (Septoria glycines), Cercospora leaf spot and blight (Cercospora kikuchii), Choanephora leaf blight (Choanephora infundibulifera trispora (Syn.)), Dactuliophora leaf spot (Dactuliophora glycines), Downy Mildew (Peronospora manshurica), Drechslera blight (Drechslera glycini), Frogeye leaf spot (Cercospora sojina), Leptosphaerulina leaf spot ( Leptosphaerulina trifolii), Phyllostica leaf spot (Phyllosticta sojaecola), Powdery Mildew (Microsphaera diffusa), Pyrenochaeta leaf spot (Pyrenochaeta glycines), Rhizoctonia aerial, Foliage, and Web Blight (Rhizoctonia solani), Rust (Phakopsora pachyrhizi), Scab (Sphaceloma glycines ), Stemphylium Leaf Blight (Stemphylium botryosum), Target Spot (Corynespora cassiicola).

Fungal diseases on roots and stem base caused by e.g.

Black Root Red (Calonectria crotalariae), Charcoal Red (Macrophomina phaseolina), Fusarium Blight or Wilt, Root Red, and Pod and Collar Red (Fusarium oxysporum, Fusarium orthoceras, Fusarium semitectum, Fusarium equiseti), Mycoleptodiscus Root Red (Mycoleptodiscus terrestris), Neocosmospora (Neocosmopspora vasinfecta), Pod and Stem Blight (Diaporthe phaseolorum), Stem Canker (Diaporthe phaseolorum var. Caulivora), Phytophthora red (Phytophthora megasperma), Brown Stem Red (Phialophora gregata), Pythium Red (Pythium aphanidermatum, Pythium irregulare, Pythium Debaryanum, Pythium myriotylum, Pythium ultimum), Rhizoctonia Root Red, Stem Decay, and Damping Off (Rhizoctonia solani), Sclerotinia Stem Decay (Sclerotinia sclerotiorum), Sclerotinia Southern Blight (Sclerotinia rolfsii), Thielaviopsis Root Red (Thielaviopsis basicola).

In this case, the active compound combinations according to the invention can be used particularly successfully for combating cereal diseases, such as, for example, against Puccinia species and diseases in the wine, fruit and vegetable growing, such. against Botrytis, Venturia or Alternaria species.

In addition, the active compound combinations according to the invention also have very good antifungal effects. They have a very broad antimycotic spectrum of activity, in particular against dermatophytes and yeasts, mold and diphasic fungi (eg against Candida species such as Candida albicans, Candida glabrata) and Epidermophyton floccosum, Aspergillus species such as Aspergillus niger and Aspergillus fumigatus, Trichophyton species such as Trichophyton mentagrophytes, Microsporon species such as Microsporon canis and audouinii. The list of these fungi is by no means a limitation of the detectable mycotic spectrum, but has only an explanatory character.

• Aus der Ordnung der Anoplura (Phthiraptera) z.B. Damalinia spp., Haematopinus spp., Linognathus spp., Pediculus spp., Trichodectes spp.
• Aus der Klasse der Arachnida z.B. Acarus siro, Aceria sheldoni, Aculops spp., Aculus spp., Amblyomma spp., Argas spp., Boophilus spp., Brevipalpus spp., Bryobia praetiosa, Chorioptes spp., Dermanyssus gallinae, Eotetranychus spp., Epitrimerus pyri, Eutetranychus spp., Eriophyes spp., Hemitarsonemus spp., Hyalomma spp., Ixodes spp., Latrodectus mactans, Metatetranychus spp., Oligonychus spp., Ornithodoros spp., Panonychus spp., Phyllocoptruta oleivora, Polyphagotarsonemus latus, Psoroptes spp., Rhipicephalus spp., Rhizoglyphus spp., Sarcoptes spp., Scorpio maurus, Stenotarsonemus spp., Tarsonemus spp., Tetranychus spp., Vasates lycopersici.
• Aus der Klasse der Bivalva z.B. Dreissena spp.
• Aus der Ordnung der Chilopoda z.B. Geophilus spp., Scutigera spp.
• Aus der Ordnung der Coleoptera z.B. Acanthoscelides obtectus, Adoretus spp., Agelastica alni, Agriotes spp., Amphimallon solstitialis, Anobium punctatum, Anoplophora spp., Anthonomus spp., Anthrenus spp., Apogonia spp., Atomaria spp., Attagenus spp., Bruchidius obtectus, Bruchus spp., Ceuthorhynchus spp., Cleonus mendicus, Conoderus spp., Cosmopolites spp., Costelytra zealandica, Curculio spp., Cryptorhynchus lapathi, Dermestes spp., Diabrotica spp., Epilachna spp., Faustinus cubae, Gibbium psylloides, Heteronychus arator, Hylamorpha elegans, Hylotrupes bajulus, Hypera postica, Hypothenemus spp., Lachnosterna consanguinea, Leptinotarsa decemlineata, Lissorhoptrus oryzophilus, Lixus spp., Lyctus spp., Meligethes aeneus, Melolontha melolontha, Migdolus spp., Monochamus spp., Naupactus xanthographus, Niptus hololeucus, Oryctes rhinoceros, Oryzaephilus surinamensis, Otiorrhynchus sulcatus, Oxycetonia jucunda, Phaedon cochleariae, Phyllophaga spp., Popillia japonica, Premnotrypes spp., Psylliodes chrysocephala, Ptinus spp., Rhizobius ventralis, Rhizopertha dominica, Sitophilus spp., Sphenophorus spp., Sternechus spp., Symphyletes spp., Tenebrio molitor, Tribolium spp., Trogoderma spp., Tychius spp., Xylotrechus spp., Zabrus spp.
• Aus der Ordnung der Collembola z.B. Onychiurus armatus.
• Aus der Ordnung der Dermaptera z.B. Forficula auricularia.
• Aus der Ordnung der Diplopoda z.B. Blaniulus guttulatus.
• Aus der Ordnung der Diptera z.B. Aedes spp., Anopheles spp., Bibio hortulanus, Calliphora erythrocephala, Ceratitis capitata, Chrysomyia spp., Cochliomyia spp., Cordylobia anthropophaga, Culex spp., Cuterebra spp., Dacus oleae, Dermatobia hominis, Drosophila spp., Fannia spp., Gastrophilus spp., Hylemyia spp., Hyppobosca spp., Hypoderma spp., Liriomyza spp.. Lucilia spp., Musca spp., Nezara spp., Oestrus spp., Oscinella frit, Pegomyia hyoscyami, Phorbia spp., Stomoxys spp., Tabanus spp., Tannia spp., Tipula paludosa, Wohlfahrtia spp.
• Aus der Klasse der Gastropoda z.B. Arion spp., Biomphalaria spp., Bulinus spp., Deroceras spp., Galba spp., Lymnaea spp., Oncomelania spp., Succinea spp.
• Aus der Klasse der Helminthen z.B. Ancylostoma duodenale, Ancylostoma ceylanicum, Acylostoma braziliensis, Ancylostoma spp., Ascaris lubricoides, Ascaris spp., Brugia malayi, Brugia timori, Bunostomum spp., Chabertia spp., Clonorchis spp., Cooperia spp., Dicrocoelium spp, Dictyocaulus filaria, Diphyllobothrium latum, Dracunculus medinensis, Echinococcus granulosus, Echinococcus multilocularis, Enterobius vermicularis, Faciola spp., Haemonchus spp., Heterakis spp., Hymenolepis nana, Hyostrongulus spp., Loa Loa, Nematodirus spp., Oesophagostomum spp., Opisthorchis spp., Onchocerca volvulus, Ostertagia spp., Paragonimus spp., Schistosomen spp, Strongyloides fuelleborni, Strongyloides stercoralis, Stronyloides spp., Taenia saginata, Taenia solium, Trichinella spiralis, Trichinella nativa, Trichinella britovi, Trichinella nelsoni, Trichinella pseudopsiralis, Trichostrongulus spp., Trichuris trichuria, Wuchereria bancrofti.
• Weiterhin lassen sich Protozoen, wie Eimeria, bekämpfen.
• Aus der Ordnung der Heteroptera z.B. Anasa tristis, Antestiopsis spp., Blissus spp., Calocoris spp., Campylomma livida, Cavelerius spp., Cimex spp., Creontiades dilutus, Dasynus piperis, Dichelops furcatus, Diconocoris hewetti, Dysdercus spp., Euschistus spp., Eurygaster spp., Heliopeltis spp., Horcias nobilellus, Leptocorisa spp., Leptoglossus phyllopus, Lygus spp., Macropes excavatus, Miridae, Nezara spp., Oebalus spp., Pentomidae, Piesma quadrata, Piezodorus spp., Psallus seriatus, Pseudacysta persea, Rhodnius spp., Sahlbergella singularis, Scotinophora spp., Stephanitis nashi, Tibraca spp., Triatoma spp.
• Aus der Ordnung der Homoptera z.B. Acyrthosipon spp., Aeneolamia spp., Agonoscena spp., Aleurodes spp., Aleurolobus barodensis, Aleurothrixus spp., Amrasca spp., Anuraphis cardui, Aonidiella spp., Aphanostigma piri, Aphis spp., Arboridia apicalis, Aspidiella spp., Aspidiotus spp., Atanus spp., Aulacorthum solani, Bemisia spp., Brachycaudus helichrysii, Brachycolus spp., Brevicoryne brassicae, Calligypona marginata, Carneocephala fulgida, Ceratovacuna lanigera, Cercopidae, Ceroplastes spp., Chaetosiphon fragaefolii, Chionaspis tegalensis, Chlorita onukii, Chromaphis juglandicola, Chrysomphalus ficus, Cicadulina mbila, Coccomytilus halli, Coccus spp., Cryptomyzus ribis, Dalbulus spp., Dialeurodes spp., Diaphorina spp., Diaspis spp., Doralis spp., Drosicha spp., Dysaphis spp., Dysmicoccus spp., Empoasca spp., Eriosoma spp., Erythroneura spp., Euscelis bilobatus, Geococcus coffeae, Homalodisca coagulata, Hyalopterus arundinis, Icerya spp., Idiocerus spp., Idioscopus spp., Laodelphax striatellus, Lecanium spp., Lepidosaphes spp., Lipaphis erysimi, Macrosiphum spp., Mahanarva fimbriolata, Melanaphis sacchari, Metcalfiella spp., Metopolophium dirhodum, Monellia costalis, Monelliopsis pecanis, Myzus spp., Nasonovia ribisnigri, Nephotettix spp., Nilaparvata lugens, Oncometopia spp., Orthezia praelonga, Parabemisia myricae, Paratrioza spp., Parlatoria spp., Pemphigus spp., Peregrinus maidis, Phenacoccus spp., Phloeomyzus passerinii, Phorodon humuli, Phylloxera spp., Pinnaspis aspidistrae, Planococcus spp., Protopulvinaria pyriformis, Pseudaulacaspis pentagona, Pseudococcus spp., Psylla spp., Pteromalus spp., Pyrilla spp., Quadraspidiotus spp., Quesada gigas, Rastrococcus spp., Rhopalosiphum spp., Saissetia spp., Scaphoides titanus, Schizaphis graminum, Selenaspidus articulatus, Sogata spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Tenalaphara malayensis, Tinocallis caryaefoliae, Tomaspis spp., Toxoptera spp., Trialeurodes vaporariorum, Trioza spp., Typhlocyba spp., Unaspis spp., Viteus vitifolii.
• Aus der Ordnung der Hymenoptera z.B. Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.
• Aus der Ordnung der Isopoda z.B. Armadillidium vulgare, Oniscus asellus, Porcellio scaber.
• Aus der Ordnung der Isoptera z.B. Reticulitermes spp., Odontotermes spp.
• Aus der Ordnung der Lepidoptera z.B. Acronicta major, Aedia leucomelas, Agrotis spp., Alabama argillacea, Anticarsia spp., Barathra brassicae, Bucculatrix thurberiella, Bupalus piniarius, Cacoecia podana, Capua reticulana, Carpocapsa pomonella, Cheimatobia brumata, Chilo spp., Choristoneura fumiferana, Clysia ambiguella, Cnaphalocerus spp., Earias insulana, Ephestia kuehniella, Euproctis chrysorrhoea, Euxoa spp., Feltia spp., Galleria mellonella, Helicoverpa spp., Heliothis spp., Hofmannophila pseudospretella, Homona magnanima, Hyponomeuta padella, Laphygma spp., Lithocolletis blancardella, Lithophane antennata, Loxagrotis albicosta, Lymantria spp., Malacosoma neustria, Mamestra brassicae, Mocis repanda, Mythimna separata, Oria spp., Oulema oryzae, Panolis flammea, Pectinophora gossypiella, Phyllocnistis citrella, Pieris spp., Plutella xylostella, Prodenia spp., Pseudaletia spp., Pseudoplusia includens, Pyrausta nubilalis, Spodoptera spp., Thermesia gemmatalis, Tinea pellionella, Tineola bisselliella, Tortrix viridana, Trichoplusia spp.
• Aus der Ordnung der Orthoptera z.B. Acheta domesticus, Blatta orientalis, Blattella germanica, Gryllotalpa spp., Leucophaea maderae, Locusta spp., Melanoplus spp., Periplaneta americana, Schistocerca gregaria.
• Aus der Ordnung der Siphonaptera z.B. Ceratophyllus spp., Xenopsylla cheopis.
• Aus der Ordnung der Symphyla z.B. Scutigerella immaculata.
• Aus der Ordnung der Thysanoptera z.B. Baliothrips biformis, Enneothrips flavens, Frankliniella spp., Heliothrips spp., Hercinothrips femoralis, Kakothrips spp., Rhipiphorothrips cruentatus, Scirtothrips spp., Taeniothrips cardamoni, Thrips spp.
• Aus der Ordnung der Thysanura z.B. Lepisma saccharina.

In addition, the active compound combinations according to the invention also have very good insecticidal effects. They have a very broad insecticidal activity spectrum, in particular against the following animal pests:

• From the order of the Anoplura (Phthiraptera) eg Damalinia spp., Haematopinus spp., Linognathus spp., Pediculus spp., Trichodectes spp.
• From the class of the Arachnida eg Acarus siro, Aceria sheldoni, Aculops spp., Aculus spp., Amblyomma spp., Argas spp., Boophilus spp., Brevipalpus spp., Bryobia praetiosa, Chorioptes spp., Dermanyssus gallinae, Eotetranychus spp. Epitrimerus pyri, Eutetranychus spp., Eriophyes spp., Hemitarsonemus spp., Hyalomma spp., Ixodes spp., Latrodectus mactans, Metatetranychus spp., Oligonychus spp., Ornithodoros spp., Panonychus spp., Phyllocoptruta oleivora, Polyphagotarsonemus latus, Psoroptes spp , Rhipicephalus spp., Rhizoglyphus spp., Sarcoptes spp., Scorpio maurus, Stenotarsonemus spp., Tarsonemus spp., Tetranychus spp., Vasates lycopersici.
• From the class of Bivalva eg Dreissena spp.
• From the order of Chilopoda eg Geophilus spp., Scutigera spp.
• From the order Coleoptera eg Acanthoscelides obtectus, Adoretus spp., Agelastica alni, Agriotes spp., Amphimallon solstitialis, Anobium punctatum, Anoplophora spp., Anthonomus spp., Anthrenus spp., Apogonia spp., Atomaria spp., Attagenus spp. Bruchidius obtectus, Bruchus spp., Ceuthorhynchus spp., Cleonus mendicus, Conoderus spp., Cosmopolites spp., Costelytra zealandica, Curculio spp., Cryptorhynchus lapathi, Dermestes spp., Diabrotica spp., Epilachna spp., Faustinus cubae, Gibbium psylloides, Heteronychus arator, Hylamorpha elegans, Hylotrupes bajulus, Hypera postica, Hypothenemus spp., Lachnosterna consanguinea, Leptinotarsa decemlineata, Lissorhoptrus oryzophilus, Lixus spp., Lyctus spp., Meligethes aeneus, Melolontha melolontha, Migdolus spp., Monochamus spp., Naupactus xanthographus, Niptus hololeucus, Oryctes rhinoceros, Oryzaephilus surinamensis, Otiorrhynchus sulcatus, Oxycetonia jucunda, Phaedon cochleariae, Phyllophaga spp., Popillia japonica, Premnotrypes spp., Psylli or chrysocephala, Ptinus spp., Rhizobius ventralis, Rhizopertha dominica, Sitophilus spp., Sphenophorus spp., Starchus spp., Symphyletes spp., Tenebrio molitor, Tribolium spp., Trogoderma spp., Tychius spp., Xylotrechus spp., Zabrus spp ,
• From the order of the Collembola eg Onychiurus armatus.
• From the order of the Dermaptera eg Forficula auricularia.
• From the order of Diplopoda eg Blaniulus guttulatus.
• From the order of Diptera eg Aedes spp., Anopheles spp., Bibio hortulanus, Calliphora erythrocephala, Ceratitis capitata, Chrysomyia spp., Cochliomyia spp., Cordylobia anthropophaga, Culex spp., Cuterebra spp., Dacus oleae, Dermatobia hominis, Drosophila spp , Fannia spp., Gastrophilus spp., Hylemyia spp., Hyppobosca spp., Hypoderma spp., Liriomyza spp. Lucilia spp., Musca spp., Nezara spp., Oestrus spp., Oscinella frit, Pegomyia hyoscyami, Phorbia spp , Stomoxys spp., Tabanus spp., Tannia spp., Tipula paludosa, Wohlfahrtia spp.
• From the class Gastropoda eg Arion spp., Biomphalaria spp., Bulinus spp., Deroceras spp., Galba spp., Lymnaea spp., Oncomelania spp., Succinea spp.
• From the class of helminths, for example, Ancylostoma duodenale, Ancylostoma ceylanicum, Acylostoma braziliensis, Ancylostoma spp., Ascaris lubricoides, Ascaris spp., Brugia malayi, Brugia timori, Bunostomum spp., Chabertia spp., Clonorchis spp., Cooperia spp., Dicrocoelium spp , Dictyocaulus filaria, Diphyllobothrium latum, Dracunculus medinensis, Echinococcus granulosus, Echinococcus multilocularis, Enterobius vermicularis, Faciola spp., Haemonchus spp., Heterakis spp., Hymenolepis nana, Hyostrongulus spp., Loa Loa, Nematodirus spp., Oesophagostomum spp., Opisthorchis spp., Onchocerca volvulus, Ostertagia spp., Paragonimus spp., Schistosome spp, Strongyloides fuelleborni, Strongyloides stercoralis, Stronyloides spp., Taenia saginata, Taenia solium, Trichinella spiralis, Trichinella nativa, Trichinella britovi, Trichinella nelsoni, Trichinella pseudopsiralis, Trichostrongulus spp ., Trichuris trichuria, Wuchereria bancrofti.
• Furthermore, protozoa, such as Eimeria, can be combated.
• From the order of the Heteroptera eg Anasa tristis, Antestiopsis spp., Blissus spp., Calocoris spp., Campylomma livida, Cavelerius spp., Cimex spp., Creontiades dilutus, Dasynus piperis, Dichelops furcatus, Diconocoris hewetti, Dysdercus spp., Euschistus spp , Eurygaster spp., Heliopeltis spp., Horcias nobilellus, Leptocorisa spp., Leptoglossus phyllopus, Lygus spp., Macropes excavatus, Miridae, Nezara spp., Oebalus spp., Pentomidae, Piesma quadrata, Piezodorus spp., Psallus seriatus, Pseudacysta persea, Rhodnius spp., Sahlbergella singularis, Scotinophora spp., Stephanitis nashi, Tibraca spp., Triatoma spp.
• From the order of Homoptera eg Acyrthosipon spp., Aeneolamia spp., Agonoscena spp., Aleurodes spp., Aleurolobus barodensis, Aleurothrixus spp., Amrasca spp., Anuraphis cardui, Aonidiella spp., Aphanostigma piri, Aphis spp., Arboridia apicalis, Aspidiella spp., Aspidiotus spp., Atanus spp., Aulacorthum solani, Bemisia spp., Brachycaudus helichrysii, Brachycolus spp., Brevicoryne brassicae, Calligypona marginata, Carneocephala fulgida, Ceratovacuna lanigera, Cercopidae, Ceroplastes spp., Chaetosiphon fragaefolii, Chionetis tegalensis, Chlorita onukii, Chromaphis juglandicola, Chrysomphalus ficus, Cicadulina mbila, Coccomytilus halli, Coccus spp., Cryptomyzus ribis, Dalbulus spp., Dialeurodes spp., Diaphorina spp., Diaspis spp., Doralis spp., Drosicha spp., Dysaphis spp. Dysmicoccus spp., Empoasca spp., Eriosoma spp., Erythroneura spp., Euscelis bilobatus, Geococcus coffeae, Homalodisca coagulata, Hyalopterus arundinis, Icerya spp., Idiocerus spp., Idioscopus spp., Laodelphax striatel lucid, Lecanium spp., Lepidosaphes spp., Lipaphis erysimi, Macrosiphum spp., Mahanarva fimbriolata, Melanaphis sacchari, Metcalfiella spp., Metopolophium dirhodum, Monellia costalis, Monelliopsis pecanis, Myzus spp., Nasonovia ribisnigri, Nephotettix spp., Nilaparvata lugens, Oncometopia spp., Orthezia praelonga, Parabemisia myricae, Paratrioza spp., Parlatoria spp., Pemphigus spp., Peregrinus maidis, Phenacoccus spp., Phloeomyzus passerinii, Phorodon humuli, Phylloxera spp., Pinnaspis aspidistrae, Planococcus spp., Protopulvinaria pyriformis, Pseudaulacaspis pentagona, Pseudococcus spp., Psylla spp., Pteromalus spp., Pyrilla spp., Quadraspidiotus spp., Quesada gigas, Rastrococcus spp., Rhopalosiphum spp., Saissetia spp., Scaphoides titanus, Schizaphis graminum, Selenaspidus articulatus, Sogata spp. Sogatella furcifera, Sogatodes spp., Stictocephala festina, Tenalaphara malayensis, Tinocallis caryaefoliae, Tomaspis spp., Toxoptera spp., Trialeurodes vaporariorum, Trioza spp., Typhlocyba spp., Unaspis spp., Viteus vitifolii.
• From the order of Hymenoptera eg Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.
• From the order of the Isopoda eg Armadillidium vulgare, Oniscus asellus, Porcellio scaber.
• From the order of the Isoptera eg Reticulitermes spp., Odontotermes spp.
• From the order of Lepidoptera, for example, Acronicta major, Aedia leucomelas, Agrotis spp., Alabama argillacea, Anticarsia spp., Barathra brassicae, Bucculatrix thurberiella, Bupalus piniarius, Cacoecia podana, Capua reticulana, Carpocapsa pomonella, Cheimatobia brumata, Chilo spp., Choristoneura fumiferana . Clysia ambiguella, Cnaphalocerus spp., Earias insulana, Ephestia kuehniella, Euproctis chrysorrhoea, Euxoa spp., Feltia spp., Galleria mellonella, Helicoverpa spp., Heliothis spp., Hofmannophila pseudospretella, Homona magnanima, Hyponomeuta padella, Laphygma spp., Lithocolletis blancardella , Lithophane antennata, Loxagrotis albicosta, Lymantria spp., Malacosoma neustria, Mamestra brassicae, Mocis repanda, Mythimna separata, Oria spp., Oulema oryzae, Panolis flammea, Pectinophora gossypiella, Phyllocnistis citrella, Pieris spp., Plutella xylostella, Prodenia spp. Pseudaletia spp., Pseudoplusia includens, Pyrausta nubilalis, Spodoptera spp., Thermesia gemmatalis, Tinea pellionella, Tineola bisselliella, Tortrix viridana, Trichoplusia spp.
• From the order of the Orthoptera eg Acheta domesticus, Blatta orientalis, Blattella germanica, Gryllotalpa spp., Leucophaea maderae, Locusta spp., Melanoplus spp., Periplaneta americana, Schistocerca gregaria.
• From the order of Siphonaptera eg Ceratophyllus spp., Xenopsylla cheopis.
• From the order of Symphyla eg Scutigerella immaculata.
• From the order of the Thysanoptera eg Baliothrips biformis, Enneothrips flavens, Frankliniella spp., Heliothrips spp., Hercinothrips femoralis, Kakothrips spp., Rhipiphorothrips cruentatus, Scirtothrips spp., Taeniothrips cardamoni, Thrips spp.
• From the order of Thysanura eg Lepisma saccharina.

The plant parasitic nematodes include e.g. Anguina spp., Aphelenchoides spp., Belonoaimus spp., Bursaphelenchus spp., Ditylenchus dipsaci, Globodera spp., Heliocotylenchus spp., Heterodera spp., Longidorus spp., Meloidogyne spp., Pratylenchus spp., Radopholus similis, Rotylenchus spp. Trichodorus spp., Tylenchorhynchus spp., Tylenchulus spp., Tylenchulus semipenetrans, Xiphinema spp.

In the protection of materials, the active compound combinations according to the invention can be used to protect industrial materials against infestation and destruction by undesired microorganisms.

Technical materials as used herein mean non-living materials that have been prepared for use in the art. For example, technical materials to be protected from microbial change or destruction by the active compounds of the invention may be adhesives, glues, paper and cardboard, textiles, leather, wood, paints and plastics, coolants, and other materials that may be infested or degraded by microorganisms , In the context of the materials to be protected are also parts of production plants, such as cooling water circuits, called, which can be affected by the proliferation of microorganisms. In the context of the present invention, technical materials which may be mentioned are preferably adhesives, glues, papers and cartons, leather, wood, paints, cooling lubricants and heat transfer fluids, particularly preferably wood.

As microorganisms that can cause degradation or a change in the technical materials, for example, bacteria, fungi, yeasts, algae and mucus organisms may be mentioned. The active compound combinations according to the invention preferably act against fungi, in particular molds, wood-discolouring and wood-destroying fungi (Basidiomycetes) and against slime organisms and algae.

• Alternaria, wie Alternaria tenuis,
• Aspergillus, wie Aspergillus niger,
• Chaetomium, wie Chaetomium globosum,
• Coniophora, wie Coniophora puetana,
• Lentinus, wie Lentinus tigrinus,
• Penicillium, wie Penicillium glaucum,
• Polyporus, wie Polyporus versicolor,
• Aureobasidium, wie Aureobasidium pullulans,
• Sclerophoma, wie Sclerophoma pityophila,
• Trichoderma, wie Trichoderma viride,
• Escherichia, wie Escherichia coli,
• Pseudomonas, wie Pseudomonas aeruginosa,
• Staphylococcus, wie Staphylococcus aureus.

There may be mentioned, for example, microorganisms of the following genera:

• Alternaria, such as Alternaria tenuis,
• Aspergillus, such as Aspergillus niger,
• Chaetomium, such as Chaetomium globosum,
• Coniophora, like Coniophora puetana,
• Lentinus, like Lentinus tigrinus,
• Penicillium, such as Penicillium glaucum,
• Polyporus, such as Polyporus versicolor,
• Aureobasidium, such as Aureobasidium pullulans,
• Sclerophoma, such as Sclerophoma pityophila,
• Trichoderma, like Trichoderma viride,
• Escherichia, like Escherichia coli,
• Pseudomonas, such as Pseudomonas aeruginosa,
• Staphylococcus, such as Staphylococcus aureus.

In addition, it has been found that the active compound combinations according to the invention have a high insecticidal activity against insects which destroy industrial materials.

By way of example and preferably without limiting however, the following insects are mentioned:

Beetles such as Hylotrupes bajulus, Chlorophorus pilosis, Anobium punctatum, Xestobium rufovillosum, Ptilinus pecticornis, Dendrobium pertinex, Ernobius mollis, Priobium carpini, Lyctus brunneus, Lyctus africanus, Lyctus planicollis, Lyctus linearis, Lyctus pubescens, Trogoxylon aequale, Minthes rugicollis, Xyleborus spec. Tryptodendron spec. Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon spec. Dinoderus minutus.

Hymenoptera such as Sirex juvencus, Urocerus gigas, Urocerus gigas taignus, Urocerus augur.

Termites such as Kalotermes flavicollis, Cryptotermes brevis, Heterotermes indicola, Reticulitermes flavipes, Reticulitermes santonensis, Reticulitermes lucifugus, Mastotermes darwiniensis, Zootermopsis nevadensis, Coptotermes formosanus.

Bristle tails like Lepisma saccharina.

Technical materials in the present context are non-living materials, such as preferably plastics, adhesives, glues, papers and cardboard, leather, wood, wood processing products and paints.

Most preferably, the material to be protected from insect attack is wood and woodworking products.

By wood and wood products, which can be protected by the active compound combinations according to the invention, is to be understood by way of example: timber, wooden beams, railway sleepers, bridge parts, boat jetties, wooden vehicles, crates, pallets, containers, telephone poles, wood cladding, wooden windows and doors, plywood, chipboard, Carpentry or wood products commonly used in home construction or joinery.

The active compound combinations can be used as such, in the form of concentrates or generally customary formulations such as powders, granules, solutions, suspensions, emulsions or pastes.

The formulations mentioned can be prepared in a manner known per se, e.g. by mixing the active compounds with at least one solvent or diluent, emulsifier, dispersing and / or binding or fixing agent, water repellent, optionally siccatives and UV stabilizers and optionally dyes and pigments, and further processing aids.

The insecticidal active ingredient combinations or concentrates used for the protection of wood and wood-based materials contain the active ingredient according to the invention in a concentration of 0.0001 to 95 wt .-%, in particular 0.001 to 60 wt .-%.

The amount of active ingredient combinations or concentrates used depends on the nature and occurrence of the insects and on the medium. The optimal amount used can be determined in each case by test series. In general, however, it is sufficient to use 0.0001 to 20% by weight, preferably 0.001 to 10% by weight, of the active ingredient, based on the material to be protected.

• Aus der Ordnung der Scorpionidea z.B. Buthus occitanus.
• Aus der Ordnung der Acarina z.B. Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophagoides pteronissimus, Dermatophagoides forinae.
• Aus der Ordnung der Araneae z.B. Aviculariidae, Araneidae.
• Aus der Ordnung der Opiliones z.B. Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium.
• Aus der Ordnung der Isopoda z.B. Oniscus asellus, Porcellio scaber.
• Aus der Ordnung der Diplopoda z.B. Blaniulus guttulatus, Polydesmus spp.
• Aus der Ordnung der Chilopoda z.B. Geophilus spp.
• Aus der Ordnung der Zygentoma z.B. Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus.
• Aus der Ordnung der Blattaria z.B. Blatta orientalies, Blattella germanica, Blattella asahinai, Leucophaea maderae, Panchlora spp., Parcoblatta spp., Periplaneta australasiae, Periplaneta americana, Periplaneta brunnea, Periplaneta fuliginosa, Supella longipalpa.
• Aus der Ordnung der Saltatoria z.B. Acheta domesticus.
• Aus der Ordnung der Dermaptera z.B. Forficula auricularia.
• Aus der Ordnung der Isoptera z.B. Kalotermes spp., Reticulitermes spp.
• Aus der Ordnung der Psocoptera z.B. Lepinatus spp., Liposcelis spp.
• Aus der Ordnung der Coleptera z.B. Anthrenus spp., Attagenus spp., Dermestes spp., Latheticus oryzae, Necrobia spp., Ptinus spp., Rhizopertha dominica, Sitophilus granarius, Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum.
• Aus der Ordnung der Diptera z.B. Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus spp., Sarcophaga carnaria, Simulium spp., Stomoxys calcitrans, Tipula paludosa.
• Aus der Ordnung der Lepidoptera z.B. Achroia grisella, Galleria mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella.
• Aus der Ordnung der Siphonaptera z.B. Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis.
• Aus der Ordnung der Hymenoptera z.B. Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetramorium caespitum.
• Aus der Ordnung der Anoplura z.B. Pediculus humanus capitis, Pediculus humanus corporis, Phthirus pubis.
• Aus der Ordnung der Heteroptera z.B. Cimex hemipterus, Cimex lectularius, Rhodinus prolixus, Triatoma infestans.

The active substance combinations are also suitable for controlling animal pests, in particular insects, arachnids and mites, which are used in enclosed spaces such as, for example, apartments, factory halls, offices, vehicle cabins and the like. occurrence. They can be used to control these pests in household insecticide products. They are effective against sensitive and resistant species and against all stages of development. These pests include:

• From the order of Scorpionidea eg Buthus occitanus.
• From the order of the Acarina eg Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophagoides pteronissimus, Dermatophagoides forinae.
• From the order of the Araneae eg Aviculariidae, Araneidae.
• From the order of the Opiliones eg Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium.
• From the order of the Isopoda eg Oniscus asellus, Porcellio scaber.
• From the order of the Diplopoda eg Blaniulus guttulatus, Polydesmus spp.
• From the order of Chilopoda eg Geophilus spp.
• From the order of Zygentoma eg Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus.
• From the order of the Blattaria eg Blatta orientalies, Blattella germanica, Blattella asahinai, Leucophaea maderae, Panchlora spp., Parcoblatta spp., Periplaneta australasiae, Periplaneta americana, Periplaneta brunnea, Periplaneta fuliginosa, Supella longipalpa.
• From the order of Saltatoria eg Acheta domesticus.
• From the order of the Dermaptera eg Forficula auricularia.
• From the order of the Isoptera eg Kalotermes spp., Reticulitermes spp.
• From the order of Psocoptera eg Lepinatus spp., Liposcelis spp.
• From the order of Coleptera, for example, Anthrenus spp., Attagenus spp., Dermestes spp., Latheticus oryzae, Necrobia spp., Ptinus spp., Rhizopertha dominica, Sitophilus granarius, Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum.
• From the order of Diptera eg Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus spp., Sarcophaga carnaria , Simulium spp., Stomoxys calcitrans, Tipula paludosa.
• From the order of Lepidoptera eg Achroia grisella, Galleria mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella.
• From the order of the Siphonaptera, for example, Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis.
• From the order of the Hymenoptera, for example, Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetramorium caespitum.
• From the order of Anoplura eg Pediculus humanus capitis, Pediculus humanus corporis, Phthirus pubis.
• From the order of Heteroptera eg Cimex hemipterus, Cimex lectularius, Rhodinus prolixus, Triatoma infestans.

Application is in aerosols, non-pressurized sprays, e.g. Pump and atomizer sprays, fog machines, foggers, foams, gels, evaporator products with cellulose or plastic evaporator plates, liquid evaporators, gel and membrane evaporators, propeller-driven evaporators, energy-less or passive evaporation systems, moth papers, moth cushions and moth gels, as granules or dusts, in litter or bait stations.

• Aus der Ordnung der Anoplurida z.B. Haematopinus spp., Linognathus spp., Pediculus spp., Phtirus spp., Solenopotes spp.
• Aus der Ordnung der Mallophagida und den Unterordnungen Amblycerina sowie Ischnocerina z.B. Trimenopon spp., Menopon spp., Trinoton spp., Bovicola spp., Werneckiella spp., Lepikentron spp., Damalina spp., Trichodectes spp., Felicola spp.
• Aus der Ordnung Diptera und den Unterordnungen Nematocerina sowie Brachycerina z.B. Aedes spp., Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., Hybomitra spp., Atylotus spp., Tabanus spp., Haematopota spp., Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp., Morellia spp., Fannia spp., Glossina spp., Calliphora spp., Lucilia spp., Chrysomyia spp., Wohlfahrtia spp., Sarcophaga spp., Oestrus spp., Hypoderma spp., Gasterophilus spp., Hippobosca spp., Lipoptena spp., Melophagus spp.
• Aus der Ordnung der Siphonapterida z.B. Pulex spp., Ctenocephalides spp., Xenopsylla spp., Ceratophyllus spp.
• Aus der Ordnung der Heteropterida z.B. Cimex spp., Triatoma spp., Rhodnius spp., Panstrongylus spp.
• Aus der Ordnung der Blattarida z.B. Blatta orientalis, Periplaneta americana, Blattela germanica, Supella spp.
• Aus der Unterklasse der Acaria (Acarida) und den Ordnungen der Meta- sowie Mesostigmata z.B. Argas spp., Ornithodorus spp., Otobius spp., Ixodes spp., Amblyomma spp., Boophilus spp., Dermacentor spp., Haemophysalis spp., Hyalomma spp., Rhipicephalus spp., Dermanyssus spp., Raillietia spp., Pneumonyssus spp., Sternostoma spp., Varroa spp.
• Aus der Ordnung der Actinedida (Prostigmata) und Acaridida (Astigmata) z.B. Acarapis spp., Cheyletiella spp., Ornithocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp., Tyrophagus spp., Caloglyphus spp., Hypodectes spp., Pterolichus spp., Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp., Laminosioptes spp.

The active compound combinations of the invention not only against plant, hygiene and storage pests, but also in the veterinary sector against animal parasites (ectoparasites) such as ticks, leather ticks, mange mites, mites, flies (stinging and licking), parasitic fly larvae, lice, hair pieces, Featherlings and fleas. These parasites include:

• From the order of the Anoplurida eg Haematopinus spp., Linognathus spp., Pediculus spp., Phtirus spp., Solenopotes spp.
• From the order of Mallophagida and the suborders Amblycerina and Ischnocerina eg Trimenopon spp., Menopon spp., Trinoton spp., Bovicola spp., Werneckiella spp., Lepikentron spp., Damalina spp., Trichodectes spp., Felicola spp.
• From the order Diptera and the suborders Nematocerina and Brachycerina eg Aedes spp., Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., Hybomitra spp. , Atylotus spp., Tabanus spp., Haematopota spp., Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp., Morellia spp., Fannia spp., Glossina spp., Calliphora Spp., Lucilia spp., Chrysomyia spp., Wohlfahrtia spp., Sarcophaga spp., Oestrus spp., Hypoderma spp., Gasterophilus spp., Hippobosca spp., Lipoptena spp., Melophagus spp.
• From the order of the siphon adapter eg Pulex spp., Ctenocephalides spp., Xenopsylla spp., Ceratophyllus spp.
• From the order of the Heteropterida eg Cimex spp., Triatoma spp., Rhodnius spp., Panstrongylus spp.
• From the order Blattarida eg Blatta orientalis, Periplaneta americana, Blattela germanica, Supella spp.
• From the subclass of Acaria (Acarida) and the orders of Meta and Mesostigmata eg Argas spp., Ornithodorus spp., Otobius spp., Ixodes spp., Amblyomma spp., Boophilus spp., Dermacentor spp., Haemophysalis spp., Hyalomma Spp., Rhipicephalus spp., Dermanyssus spp., Raillietia spp., Pneumonyssus spp., Sternostoma spp., Varroa spp.
• From the order of Actinedida (Prostigmata) and Acaridida (Astigmata) eg Acarapis spp., Cheyletiella spp., Ornithocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp. Tyrophagus spp., Caloglyphus spp., Hypodectes spp., Pterolichus spp., Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp., Laminosioptes spp.

The active compound combinations according to the invention are also suitable for controlling arthropods which are farm animals, such as e.g. Cattle, sheep, goats, horses, pigs, donkeys, camels, buffaloes, rabbits, chickens, turkeys, ducks, geese, bees, other pets such as e.g. Dogs, cats, caged birds, aquarium fish and so-called experimental animals, such. Hamsters, guinea pigs, rats and mice. By controlling these arthropods deaths and reductions in performance (in meat, milk, wool, hides, eggs, honey, etc.) are reduced so that a more economical and easier animal husbandry is possible through the use of the active compound combinations according to the invention.

The application of the active compound combinations according to the invention is done in the veterinary sector in a known manner by enteral administration in the form of, for example, tablets, capsules, infusions, Drenchen, granules, pastes, boluses, the feed-through process, suppositories, by parenteral administration, such as by Injections (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.), implants, by nasal application, by dermal application in the form of, for example, dipping or bathing (dipping), spraying, pouring and spot-on, washing , the powdering and with the help of active substance-containing moldings, such as collars, ear tags, tail marks, limb bands, holsters, marking devices, etc.

When used for livestock, poultry, pets, etc., the active ingredient combinations may be used as formulations (for example, powders, emulsions, flowables) containing the active ingredients in an amount of 1 to 80% by weight, directly or after 100 to 10,000 dilution or use as a chemical bath.

The active compound combinations according to the invention may optionally also be used in certain concentrations or application rates as herbicides, safeners, growth regulators or agents for improving plant properties, or as microbicides, for example as fungicides, antimycotics, bactericides, viricides (including anti-viral agents) or as anti-MLO agents ( Mycoplasma-like-organism) and RLO (Rickettsia-like-organism).

The active compounds can be converted into the customary formulations, such as solutions, emulsions, wettable powders, water- and oil-based suspensions, powders, dusts, pastes, soluble powders, soluble Granules, granulated granules, suspension-emulsion concentrates, active ingredient-impregnated natural substances, active substance-impregnated synthetic substances, fertilizers and Feinstverkapselungen in polymeric materials.

These formulations are prepared in a known manner, e.g. by mixing the active compounds with extenders, ie liquid solvents and / or solid carriers, if appropriate using surface-active agents, ie emulsifiers and / or dispersants and / or foam-forming agents. The preparation of the formulations is carried out either in suitable systems or before or during use.

Excipients which can be used are those which are suitable for imparting special properties to the composition itself and / or preparations derived therefrom (for example spray liquor, seed dressing), such as certain technical properties and / or specific biological properties. Typical auxiliaries are: extenders, solvents and carriers.

As extender, e.g. Water, polar and non-polar organic chemical liquids e.g. from the classes of aromatic and non-aromatic hydrocarbons (such as paraffins, alkylbenzenes, alkylnaphthalenes, chlorobenzenes), alcohols and polyols (which may also be substituted, etherified and / or esterified), ketones (such as acetone, cyclohexanone), Esters (including fats and oils) and (poly) ethers, simple and substituted amines, amides, lactams (such as N-alkylpyrrolidones) and lactones, sulfones and sulfoxides (such as dimethylsulfoxide).

In the case of using water as an extender, e.g. also organic solvents can be used as auxiliary solvent. As liquid solvents are essentially in question:

Aromatics such as xylene, toluene or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons such as cyclohexane or paraffins, e.g. Petroleum fractions, mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethyl sulfoxide, and water.

According to the invention, the carrier means a natural or synthetic, organic or inorganic substance which may be solid or liquid, with which the active ingredients are mixed or combined for better applicability, in particular for application to plants or plant parts or seeds. The solid or liquid carrier is generally inert and should be useful in agriculture.

Suitable solid or liquid carriers are:
For example, ammonium salts and ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic minerals, such as finely divided silica, alumina and silicates, as solid carriers for granules in question: eg broken and fractionated natural rocks such Calcite, marble, pumice, sepiolite, dolomite and synthetic granules of inorganic and organic flours and granules of organic material such as paper, sawdust, coconut shells, corn cobs and tobacco stalks; suitable emulsifiers and / or foam formers are: for example nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example alkylaryl polyglycol ethers, alkylsulfonates, alkyl sulfates, arylsulfonates and protein hydrolysates; suitable dispersants are nonionic and / or ionic substances, for example from the classes of alcohol POE and / or POP ethers, acid and / or POPPOE esters, alkylaryl and / or POP POE ethers, fatty and / or POP-POE adducts, POE and / or POP polyol derivatives, POE and / or POP sorbitol or sugar adducts, alkyl or aryl sulfates, sulfonates and phosphates or the corresponding PO-ether adducts. Further suitable oligo- or polymers, for example starting from vinylic monomers, from acrylic acid, from EO and / or PO alone or in combination with, for example, (poly) alcohols or (poly) amines. Furthermore, find use lignin and its sulfonic acid derivatives, simple and modified celluloses, aromatic and / or aliphatic sulfonic acids and their adducts with formaldehyde.

Adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex polymers such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids such as cephalins and lecithins and synthetic phospholipids may be used in the formulations.

Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.

Other additives may be fragrances, mineral or vegetable optionally modified oils, waxes and nutrients (also trace nutrients), such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.

Stabilizers such as cold stabilizers, preservatives, antioxidants, light stabilizers or other chemical and / or physical stability-improving agents may also be present.

The active substance content of the application forms prepared from the commercial formulations can vary within wide ranges. The active ingredient concentration of the use forms is in the range of 0.00000001 to 97 wt .-% of active ingredient, preferably in the range of 0.0000001 to 97 wt .-%, particularly preferably in the range of 0.000001 to 83 wt .-% or 0, 000001 to 5 wt .-% and most preferably in the range of 0.0001 to 1 wt .-%.

The active compound combinations according to the invention can be present in their commercially available formulations and in the formulations prepared from these formulations in admixture with other active ingredients such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth-regulating substances, herbicides, safeners, fertilizers or semiochemicals.

A mixture with other known active ingredients, such as herbicides, fertilizers, growth regulators, safeners, semiochemicals, or with agents for improving the plant properties is possible.

The active compound combinations according to the invention can furthermore be present in mixtures with synergists when used as fungicides and / or insecticides in their commercial formulations and in the forms of use prepared from these formulations. Synergists are compounds that increase the effect of the active ingredients without the added synergist itself having to be active.

When used as fungicides and / or insecticides, the active compound combinations according to the invention can also be present in their commercial formulations and in the forms of use prepared from these formulations in mixtures with inhibitors which inhibit degradation of the active substance after application in the environment of the plant, on the surface of plant parts or in plant tissues.

The application is done in a custom forms adapted to the application forms.

According to the invention, all plants and parts of plants can be treated. In this context, plants are understood as meaning all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants). Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant varieties which can or can not be protected by plant breeders' rights. Plant parts are to be understood as meaning all aboveground and underground parts and organs of the plants, such as shoot, leaf, flower and root, by way of example leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds, as well as roots, tubers and rhizomes. The plant parts also include crops and vegetative and generative propagation material, for example fruits, seeds, cuttings, tubers, rhizomes, offshoots, seeds, bulbs, sinkers and shoots.

The treatment according to the invention of the plants and plant parts with the active compound combinations takes place directly or by acting on their environment, habitat or storage space according to the usual treatment methods, e.g. by dipping, spraying, evaporating, atomizing, spreading, brushing, injecting and in propagating material, in particular in seeds, further by single or multilayer coating. In this case, the active ingredient combinations can be prepared before the treatment by mixing the individual active ingredients. Or the treatment is carried out successively by using first a compound of the formula (I) followed by the treatment with an active compound of the groups (2) to (25). However, it is also possible to first treat the plants or plant parts with an active compound of groups (2) to (25) and to attach the treatment with a compound of the formula I.

As plants which can be treated according to the invention, mention may be made of the following: cotton, flax, grapevine, fruits, vegetables, such as Rosaceae sp. (For example, core fruits such as apple and pear, but also drupes such as apricots, cherries, almonds and peaches and soft fruits such as strawberries), Ribesioidae sp., Juglandaceae sp., Betulaceae sp., Anacardiaceae sp., Fagaceae sp., Moraceae sp., Oleaceae sp., Actinidaceae sp., Lauraceae sp ., Musaceae sp. (for example, banana trees and plantations), Rubiaceae sp. (for example, coffee), Theaceae sp., Sterculiceae sp., Rutaceae sp. (for example, lemons, organs and grapefruit); Solanaceae sp. (for example tomatoes), Liliaceae sp., Asteraceae sp. (for example, lettuce), Umbelliferae sp., Cruciferae sp., Chenopodiaceae sp., Cucurbitaceae sp. (for example cucumber), Alliaceae sp. leek, onion), Papilionaceae sp. (for example, peas); Main crops, such as Gramineae sp. (for example corn, turf, cereals such as wheat, rye, rice, barley, oats, millet and triticale), Asteraceae sp. (for example sunflower), Brassicaceae sp. (for example, white cabbage, red cabbage, broccoli, cauliflower, Brussels sprouts, pak choi, kohlrabi, radishes and rapeseed, mustard, horseradish and cress), Fabacae sp. (for example, bean, peanuts), Papilionaceae sp. (for example, soybean), Solanaceae sp. (for example potatoes), Chenopodiaceae sp. (for example, sugar beet, fodder beet, Swiss chard, beet); Useful plants and ornamental plants in the garden and forest; and each genetically modified species of these plants.

The treatment method of the invention may be used for the treatment of genetically modified organisms (GMOs), e.g. As plants or seeds are used. Genetically modified plants (or transgenic plants) are plants in which a heterologous gene has been stably integrated into the genome. The term "heterologous gene" essentially refers to a gene which is provided or assembled outside the plant and which, when introduced into the nuclear genome, chloroplast genome or hypochondriacal genome, imparts new or improved agronomic or other properties to the transformed plant Expressing protein or polypeptide or that it is downregulating or shutting down another gene present in the plant or other genes present in the plant (for example by antisense technology, cosuppression technology or RNAi technology [RNA Interference]). A heterologous gene present in the genome is also referred to as a transgene. A transgene defined by its specific presence in the plant genome is referred to as a transformation or transgenic event.

Depending on the plant species or plant cultivars, their location and their growth conditions (soils, climate, vegetation period, diet), the treatment according to the invention can also lead to superadditive ("synergistic") effects. Thus, for example, the following effects are possible, which go beyond the expected effects: reduced application rates and / or extended spectrum of action and / or increased efficacy of the active ingredients and compositions that can be used according to the invention, better plant growth, increased tolerance to high or low Temperatures, increased tolerance to drought or water or soil salinity, increased flowering, harvest relief, ripening, higher yields, larger fruits, greater plant height, intense green color of the leaf, earlier flowering, higher quality and / or higher nutritional value of the harvested products, higher sugar concentration in the fruits, better storage and / or processability of the harvested products.

At certain application rates, the active compound combinations according to the invention can also exert a strengthening effect on plants. They are therefore suitable for mobilizing the plant defense system against attack by undesirable phytopathogenic fungi and / or microorganisms and / or viruses. This may optionally be one of the reasons for the increased effectiveness of the combinations according to the invention, for example against fungi. Plant-strengthening (resistance-inducing) substances in the present context should also mean those substances or combinations of substances which are able to stimulate the plant defense system such that the treated plants, when subsequently inoculated with undesirable phytopathogenic fungi and / or microorganisms and / or viruses a considerable degree of resistance to these unwanted phytopathogenic fungi and / or microorganisms and / or viruses. In the present case, phytopathogenic fungi, bacteria and viruses are understood to be undesirable phytopathogenic fungi and / or microorganisms and / or viruses. The substances according to the invention can therefore be employed for the protection of plants against attack by the mentioned pathogens within a certain period of time after the treatment. The period of time over which a protective effect is achieved generally extends from 1 to 10 days, preferably 1 to 7 days, after the treatment of the plants with the active substances.

Plants and plant varieties which are preferably treated according to the invention include all plants which have genetic material conferring on these plants particularly advantageous, useful features (whether obtained by breeding and / or biotechnology).

Plants and plant varieties which are also preferably treated according to the invention are resistant to one or more biotic stress factors, ie these plants have an improved defense against animal and microbial pests such as nematodes, insects, mites, phytopathogenic fungi, bacteria, viruses and / or viroids ,

Plants and plant varieties which can also be treated according to the invention are those plants which are resistant to one or more abiotic stress factors. Abiotic stress conditions may include, for example, drought, cold and heat conditions, osmotic stress, waterlogging, increased soil salinity, increased exposure to minerals, ozone conditions, high light conditions, limited availability of nitrogen nutrients, limited availability of phosphorous nutrients, or avoidance of shade.

Plants and plant varieties which can also be treated according to the invention are those plants which are characterized by increased yield properties. An increased yield can in these plants z. B. based on improved plant physiology, improved plant growth and improved plant development, such as water efficiency, water retention efficiency, improved nitrogen utilization, increased carbon assimilation, improved photosynthesis, increased germination and accelerated Abreife. The yield may be further influenced by improved plant architecture (under stress and non-stress conditions), including early flowering, flowering control for hybrid seed production, seedling vigor, plant size, internode count and spacing, root growth, seed size, fruit size, Pod size, pod or ear number, number of seeds per pod or ear, seed mass, increased seed filling, reduced seed drop, reduced pod popping and stability. Other yield-related traits include seed composition such as carbohydrate content, protein content, oil content and composition, nutritional value, reduction of nontoxic compounds, improved processability, and improved shelf life.

Plants which can be treated according to the invention are hybrid plants which already express the properties of heterosis or hybrid effect, which generally leads to higher yield, higher vigor, better health and better resistance to biotic and abiotic stress factors. Such plants are typically produced by crossing an inbred male sterile parental line (the female crossover partner) with another inbred male fertile parent line (the male crossbred partner). The hybrid seed is typically harvested from the male sterile plants and sold to propagators. Pollen sterile plants can sometimes be produced (eg in maize) by delaving (ie mechanical removal of the male reproductive organs or the male flowers); however, it is more common for male sterility to be due to genetic determinants in the plant genome. In this case, especially when the desired product, as one wants to harvest from the hybrid plants, is the seeds, it is usually beneficial to ensure that the pollen fertility in hybrid plants containing the genetic determinants responsible for male sterility , completely restored. This can be accomplished by ensuring that the male crossing partners possess appropriate fertility restorer genes capable of restoring pollen fertility in hybrid plants containing the genetic determinants responsible for male sterility. Genetic determinants of pollen sterility may be localized in the cytoplasm. Examples of cytoplasmic male sterility (CMS) have been described, for example, for Brassica species ( WO 1992/005251 . WO 1995/009910 . WO 1998/27806 . WO 2005/002324 . WO 2006/021972 and US 6,229,072 ). However, genetic determinants of pollen sterility may also be localized in the nuclear genome. Pollen sterile plants can also be obtained using plant biotechnology methods such as genetic engineering. A particularly favorable means for the production of male sterile plants is in WO 89/10396 For example, a ribonuclease such as a barnase is selectively expressed in the tapetum cells in the stamens.

The fertility can then be restorated by expression of a ribonuclease inhibitor such as barstar in the tapetum cells (eg. WO 1991/002069 ).

Plants or plant varieties (obtained by methods of plant biotechnology, such as genetic engineering) which can be treated according to the invention are herbicide-tolerant plants, i. H. Plants tolerant to one or more given herbicides. Such plants can be obtained either by genetic transformation or by selection of plants containing a mutation conferring such herbicide tolerance.

Herbicide-tolerant plants are, for example, glyphosate-tolerant plants, ie plants that have been tolerated to the herbicide glyphosate or its salts. So, for example glyphosate-tolerant plants by transformation of the plant with a gene encoding the enzyme 5-enolpyruvylshikimate-3-phosphate synthase (EPSPS). Examples of such EPSPS genes are the AroA gene (mutant CT7) of the bacterium Salmonella typhimurium ( Comai et al., Science (1983), 221, 370-371 ), the CP4 gene of the bacterium Agrobacterium sp. ( Barry et al., Curr. Topics Plant Physiol. (1992), 7, 139-145 ), the genes responsible for an EPSPS from the petunia ( Shah et al., Science (1986), 233, 478-481 ), for an EPSPS from the tomato ( Gasser et al., J. Biol. Chem. (1988), 263, 4280-4289 ) or for an EPSPS from Eleusine ( WO 2001/66704 ). It can also be a mutated EPSPS, such as those in EP-A 0837944 . WO 2000/066746 . WO 2000/066747 or WO 2002/026995 is described. Glyphosate-tolerant plants can also be obtained by expressing a gene encoding a glyphosate oxidoreductase enzyme as described in U.S. Pat US 5,776,760 and US 5,463,175 is encoded. Glyphosate-tolerant plants can also be obtained by expressing a gene encoding a glyphosate acetyltransferase enzyme as described in, e.g. B. WO 2002/036782 . WO 2003/092360 . WO 2005/012515 and WO 2007/024782 is encoded. Glyphosate-tolerant plants can also be obtained by culturing plants containing the naturally occurring mutations of the above-mentioned genes, as described, for example, in US Pat WO 2001/024615 or WO 2003/013226 are described, contain, selected.

Other herbicide-resistant plants are, for example, plants which have been tolerated to herbicides which inhibit the enzyme glutamine synthase, such as bialaphos, phosphinotricin or glufosinate. Such plants can be obtained by expressing an enzyme which detoxifies the herbicide or a mutant of the enzyme glutamine synthase, which is resistant to inhibition. Such an effective detoxifying enzyme is, for example, an enzyme encoding a phosphinotricin acetyltransferase (such as the bar or pat protein from Streptomyces species). Plants expressing an exogenous phosphinotricin acetyltransferase are, for example, in US 5,561,236 ; US 5,648,477 ; US 5,646,024 ; US 5,273,894 ; US 5,637,489 ; US 5,276,268 ; US 5,739,082 ; US 5,908,810 and US 7,112,665 described.

Further herbicide-tolerant plants are also plants tolerant to the herbicides which inhibit the enzyme hydroxyphenylpyruvate dioxygenase (HPPD). The hydroxyphenylpyruvate dioxygenases are enzymes that catalyze the reaction in which para-hydroxyphenylpyruvate (HPP) is converted to homogentisate. Plants tolerant to HPPD inhibitors may be treated with a gene encoding a naturally occurring resistant HPPD enzyme or a gene encoding a mutant HPPD enzyme as described in U.S. Pat WO 1996/038567 . WO 1999/024585 and WO 1999/024586 encoded, transformed. Tolerance to HPPD inhibitors can also be achieved by transforming plants with genes encoding certain enzymes that allow the formation of homogentisate despite inhibition of the native HPPD enzyme by the HPPD inhibitor. Such plants and genes are in WO 1999/034008 and WO 2002/36787 described. The tolerance of plants to HPPD inhibitors can also be improved by transforming plants, in addition to a gene coding for an HPPD-tolerant enzyme, with a gene coding for a prephenate dehydrogenase enzyme, as described in US Pat WO 2004/024928 is described.

Other herbicide-resistant plants are plants that have been tolerated to acetolactate synthase (ALS) inhibitors. Examples of known ALS inhibitors include sulfonylurea, imidazolinone, triazolopyrimidines, pyrimidinyloxy (thio) benzoates and / or sulfonylaminocarbonyltriazolinone herbicides. It is known that various mutations in the enzyme ALS (also known as acetohydroxy acid synthase, AHAS) confer tolerance to different herbicides or groups of herbicides, as for example in US Pat Tranel and Wright, Weed Science (2002), 50, 700-712 , but also in US 5,605,011 . US 5,378,824 . US 5,141,870 and US 5,013,659 , is described. The preparation of sulfonylurea tolerant plants and imidazolinone tolerant plants is known in US 5,605,011 ; US 5,013,659 ; US 5,141,870 ; US 5,767,361 ; US 5,731,180 ; US 5,304,732 ; US 4,761,373 ; US 5,331,107 ; US 5,928,937 ; and US 5,378,824 ; as well as in the international publication WO 1996/033270 described. Other imidazolinontolerante plants are also in z. B. WO 2004/040012 . WO 2004/106529 . WO 2005/020673 . WO 2005/093093 . WO 2006/007373 . WO 2006/015376 . WO 2006/024351 and WO 2006/060634 described. Other sulfonylurea and imidazolinone tolerant plants are also in eg WO 2007/024782 described.

Other plants which are tolerant to imidazolinone and / or sulfonylurea may be obtained by induced mutagenesis, selection in cell cultures in the presence of the herbicide or by mutation breeding, as for example for the soybean in US 5,084,082 , for rice in WO 1997/41218 , for the sugar beet in US 5,773,702 and WO 1999/057965 , for salad in US 5,198,599 or for the sunflower in WO 2001/065922 is described.

Plants or plant varieties (obtained by plant biotechnology methods such as genetic engineering) which can also be treated according to the invention are insect-resistant transgenic plants, ie plants which have been made resistant to attack by certain target insects. Such plants can be obtained by genetic transformation or by selection of plants containing a mutation conferring such insect resistance.

1. 1) ein insektizides Kristallprotein aus Bacillus thuringiensis oder einen insektiziden Teil davon, wie die insektiziden Kristallproteine, die von Crickmore et al., Microbiology and Molecular Biology Reviews (1998), 62, 807-813 , von Crickmore et al. (2005) in der Bacillus thuringiensis -Toxinnomenklatur aktualisiert, online bei: http://www.lifesci.sussex.ac.uk/Home/Neil_Crickmore/Bt/), zusammengestellt wurden, oder insektizide Teile davon, z.B. Proteine der Cry-Proteinklassen Cry1Ab, Cry1Ac, Cry1F, Cry2Ab, Cry3Ae oder Cry3Bb oder insektizide Teile davon ; oder
2. 2) ein Kristallprotein aus Bacillus thuringiensis oder einen Teil davon, der in Gegenwart eines zweiten, anderen Kristallproteins als Bacillus thuringiensis oder eines Teils davon insektizid wirkt, wie das binäre Toxin, das aus den Kristallproteinen Cy34 und Cy35 besteht ( Moellenbeck et al., Nat. Biotechnol. (2001), 19, 668-72; Schnepf et al., Applied Environm. Microb. (2006), 71, 1765-1774 ); oder
3. 3) ein insektizides Hybridprotein, das Teile von zwei unterschiedlichen insektiziden Kristallproteinen aus Bacillus thuringiensis umfaßt, wie zum Beispiel ein Hybrid aus den Proteinen von 1) oben oder ein Hybrid aus den Proteinen von 2) oben, z. B. das Protein Cry1A.105, das von dem Mais-Event MON98034 produziert wird ( WO 2007/027777 ); oder
4. 4) ein Protein gemäß einem der Punkte 1) bis 3) oben, in dem einige, insbesondere 1 bis 10, Aminosäuren durch eine andere Aminosäure ersetzt wurden, um eine höhere insektizide Wirksamkeit gegenüber einer Zielinsektenart zu erzielen und/oder um das Spektrum der entsprechenden Zielinsektenarten zu erweitern und/oder wegen Veränderungen, die in die Kodier- DNA während der Klonierung oder Transformation induziert wurden, wie das Protein Cry3Bb1 in Mais-Events MON863 oder MON88017 oder das Protein Cry3A im Mais-Event MIR 604; oder
5. 5) ein insektizides sezerniertes Protein aus Bacillus thuringiensis oder Bacillus cereus oder einen insektiziden Teil davon, wie die vegetativ wirkenden insektentoxischen Proteine (vegetative insekticidal proteins, VIP), die unter http://www.lifesci.sussex.ac.uk/Home/Neil_Crickmore/Bt/vip.html angeführt sind, z. B. Proteine der Proteinklasse VIP3Aa; oder
6. 6) ein sezerniertes Protein aus Bacillus thuringiensis oder Bacillus cereus, das in Gegenwart eines zweiten sezernierten Proteins aus Bacillus thuringiensis oder B. cereus insektizid wirkt, wie das binäre Toxin, das aus den Proteinen VIP1A und VIP2A besteht ( WO 1994/21795 ); oder
7. 7) ein insektizides Hybridprotein, das Teile von verschiedenen sezernierten Proteinen von Bacillus thuringiensis oder Bacillus cereus umfaßt, wie ein Hybrid der Proteine von 1) oder ein Hybrid der Proteine von 2) oben; oder
8. 8) ein Protein gemäß einem der Punkte 1) bis 3) oben, in dem einige, insbesondere 1 bis 10, Aminosäuren durch eine andere Aminosäure ersetzt wurden, um eine höhere insektizide Wirksamkeit gegenüber einer Zielinsektenart zu erzielen und/oder um das Spektrum der entsprechenden Zielinsektenarten zu erweitern und/oder wegen Veränderungen, die in die Kodier- DNA während der Klonierung oder Transformation induziert wurden (wobei die Kodierung für ein insektizides Protein erhalten bleibt), wie das Protein VIP3Aa im Baumwoll-Event COT 102.

The term "insect-resistant transgenic plant" as used herein includes any plant containing at least one transgene comprising a coding sequence encoding:

1. 1) an insecticidal crystal protein from Bacillus thuringiensis or an insecticidal part thereof, such as the insecticidal crystal proteins derived from Crickmore et al., Microbiology and Molecular Biology Reviews (1998), 62, 807-813 , from Crickmore et al. (2005) in the Bacillus thuringiensis toxin nomenclature, online at: http://www.lifesci.sussex.ac.uk/Home/Neil_Crickmore/Bt/), or insecticidal parts thereof, eg proteins of the Cry protein classes Cry1Ab, Cry1Ac, Cry1F, Cry2Ab, Cry3Ae or Cry3Bb or insecticidal parts thereof ; or
2. 2) a Bacillus thuringiensis crystal protein or a part thereof which is insecticidal in the presence of a second crystal protein other than Bacillus thuringiensis or a part thereof, such as the binary toxin consisting of the crystal proteins Cy34 and Cy35 ( Moellenbeck et al., Nat. Biotechnol. (2001), 19, 668-72; Schnepf et al., Applied Environm. Microb. (2006), 71, 1765-1774 ); or
3. 3) an insecticidal hybrid protein comprising parts of two different insecticidal crystal proteins from Bacillus thuringiensis, such as a hybrid of the proteins of 1) above or a hybrid of the proteins of 2) above, e.g. For example, the protein Cry1A.105 produced by the corn event MON98034 ( WO 2007/027777 ); or
4. 4) a protein according to any of items 1) to 3) above, in which some, in particular 1 to 10, amino acids have been replaced by another amino acid in order to achieve a higher insecticidal activity against a target insect species and / or the spectrum of the corresponding To expand target insect species and / or due to changes induced in the coding DNA during cloning or transformation, such as the protein Cry3Bb1 in maize events MON863 or MON88017 or the protein Cry3A in the maize event MIR 604; or
5. 5) an insecticidal secreted protein from Bacillus thuringiensis or Bacillus cereus or an insecticidal part thereof, such as the vegetative insecticidal proteins (VIPs) available at http://www.lifesci.sussex.ac.uk/home/ Neil_Crickmore / Bt / vip.html are cited, e.g. B. Proteins of protein class VIP3Aa; or
6. 6) a secreted protein from Bacillus thuringiensis or Bacillus cereus that is insecticidal in the presence of a second secreted protein from Bacillus thuringiensis or B. cereus, such as the binary toxin consisting of the proteins VIP1A and VIP2A ( WO 1994/21795 ); or
7. 7) a hybrid insecticidal protein comprising parts of various secreted proteins of Bacillus thuringiensis or Bacillus cereus, such as a hybrid of the proteins of 1) or a hybrid of the proteins of 2) above; or
8. 8) a protein according to any one of items 1) to 3) above, in which some, in particular 1 to 10, amino acids have been replaced by another amino acid in order to achieve a higher insecticidal activity against a target insect species and / or the spectrum of the corresponding To expand target insect species and / or due to alterations induced in the coding DNA during cloning or transformation (preserving coding for an insecticidal protein) such as protein VIP3Aa in cotton event COT 102.

Of course, insect-resistant transgenic plants in the present context also include any plant comprising a combination of genes encoding the proteins of any of the above classes 1 to 8. In one embodiment, an insect-resistant plant contains more than one transgene encoding a protein of any one of the above 1 to 8 in order to extend the spectrum of the corresponding target insect species or to delay the development of resistance of the insects to the plants by use different proteins which are insecticidal for the same target insect species, but have a different mode of action, such as binding to different receptor binding sites in the insect.

1. a. Pflanzen, die ein Transgen enthalten, das die Expression und/oder Aktivität des Gens für die Poly(ADP-ribose)polymerase (PARP) in den Pflanzenzellen oder Pflanzen zu reduzieren vermag, wie dies in WO 2000/004173 oder EP 04077984.5 oder EP 06009836.5 beschrieben ist.
2. b. Pflanzen, die ein streßtoleranzförderndes Transgen enthalten, das die Expression und/oder Aktivität der für PARG kodierenden Gene der Pflanzen oder Pflanzenzellen zu reduzieren vermag, wie dies z.B. in WO 2004/090140 beschrieben ist;
3. c. Pflanzen, die ein streßtoleranzförderndes Transgen enthalten, das für ein in Pflanzen funktionelles Enzym des Nicotinamidadenindinukleotid-Salvage-Biosynthesewegs kodiert, darunter Nicotinamidase, Nicotinatphosphoribosyltransferase, Nicotinsäuremononukleotidadenyltransferase, Nicotinamidadenindinukleotidsynthetase oder Nicotinamidphosphoribosyltransferase, wie dies z. B. in EP 04077624.7 oder WO 2006/133827 oder in der PCT/EP07/002433 beschrieben ist.

Plants or plant varieties (obtained by plant biotechnology methods such as genetic engineering) which can also be treated according to the invention are abiotic Stress factors tolerant. Such plants can be obtained by genetic transformation or by selection of plants containing a mutation conferring such stress resistance. Particularly useful plants with stress tolerance include the following:

1. a. Plants which contain a transgene capable of reducing the expression and / or activity of the poly (ADP-ribose) polymerase (PARP) gene in the plant cells or plants, as described in U.S. Pat WO 2000/004173 or EP 04077984.5 or EP 06009836.5 is described.
2. b. Plants which contain a stress tolerance-promoting transgene capable of reducing the expression and / or activity of the PARG-encoding genes of the plants or plant cells, as described, for example, in US Pat WO 2004/090140 is described;
3. c. Plants which contain a stress tolerance-enhancing transgene encoding a plant-functional enzyme of the nicotinamide adenine dinucleotide salvage biosynthetic pathway, including nicotinamidase, nicotinate phosphoribosyltransferase, nicotinic acid mononucleotide adenyltransferase, nicotinamide adenine dinucleotide synthetase or nicotinamide phosphoribosyltransferase as described e.g. In EP 04077624.7 or WO 2006/133827 or in the PCT / EP07 / 002433 is described.

1. 1) Transgene Pflanzen, die eine modifizierte Stärke synthetisieren, die bezüglich ihrer chemischphysikalischen Eigenschaften, insbesondere des Amylosegehalts oder des Amylose/Amylopektin-Verhältnisses, des Verzweigungsgrads, der durchschnittlichen Kettenlänge, der Verteilung der Seitenketten, des Viskositätsverhaltens, der Gelfestigkeit, der Stärkekorngröße und/oder Stärkekornmorphologie im Vergleich mit der synthetisierten Stärke in Wildtyppflanzenzellen oder -pflanzen verändert ist, so daß sich diese modifizierte Stärke besser für bestimmte Anwendungen eignet. Diese transgenen Pflanzen, die eine modifizierte Stärke synthetisieren, sind zum Beispiel in EP 0571427 , WO 1995/004826 , EP 0719338 , WO 1996/15248 , WO 1996/19581 , WO 1996/27674 , WO 1997/11188 , WO 1997/26362 , WO 1997/32985 , WO 1997/42328 , WO 1997/44472 , WO 1997/45545 , WO 1998/27212 , WO 1998/40503 , WO 99/58688 , WO 1999/58690 , WO 1999/58654 , WO 2000/008184 , WO 2000/008185 , WO 2000/28052 , WO 2000/77229 , WO 2001/12782 , WO 2001/12826 , WO 2002/101059 , WO 2003/071860 , WO 2004/056999 , WO 2005/030942 , WO 2005/030941 , WO 2005/095632 , WO 2005/095617 , WO 2005/095619 , WO 2005/095618 , WO 2005/123927 , WO 2006/018319 , WO 2006/103107 , WO 2006/108702 , WO 2007/009823 , WO 2000/22140 , WO 2006/063862 , WO 2006/072603 , WO 2002/034923 , EP 06090134.5 , EP 06090228.5 , EP 06090227.7 , EP 07090007.1 , EP 07090009.7 , WO 2001/14569 , WO 2002/79410 , WO 2003/33540 , WO 2004/078983 , WO 2001/19975 , WO 1995/26407 , WO 1996/34968 , WO 1998/20145 , WO 1999/12950 , WO 1999/66050 , WO 1999/53072 , US 6,734,341 , WO 2000/11192 , WO 1998/22604 , WO 1998/32326 , WO 2001/98509 , WO 2001/98509 , WO 2005/002359 , US 5,824,790 , US 6,013,861 , WO 1994/004693 , WO 1994/009144 , WO 1994/11520 , WO 1995/35026 bzw. WO 1997/20936 beschrieben.
2. 2) Transgene Pflanzen, die Nichtstärkekohlenhydratpolymere synthetisieren, oder Nichtstärkekohlenhydratpolymere, deren Eigenschaften im Vergleich zu Wildtyppflanzen ohne genetische Modifikation verändert sind. Beispiele sind Pflanzen, die Polyfructose, insbesondere des Inulin- und Levantyps, produzieren, wie dies in EP 0663956 , WO 1996/001904 , Wo 1996/021023, WO 1998/039460 und WO 1999/024593 beschrieben ist, Pflanzen, die alpha-1,4-Glucane produzieren, wie dies in WO 1995/031553 , US 2002/031826 , US 6,284,479 , US 5,712,107 , WO 1997/047806 , WO 1997/047807 , WO 1997/047808 und WO 2000/14249 beschrieben ist, Pflanzen, die alpha-1,6-verzweigte alpha-1,4-Glucane produzieren, wie dies in WO 2000/73422 beschrieben ist, und Pflanzen, die Alternan produzieren, wie dies in WO 2000/047727 , EP 06077301.7 , US 5,908,975 und EP 0728213 beschrieben ist.
3. 3) Transgene Pflanzen, die Hyaluronan produzieren, wie dies zum Beispiel in WO 2006/032538 , WO 2007/039314 , WO 2007/039315 , WO 2007/039316 , JP 2006/304779 und WO 2005/012529 beschrieben ist.

Plants or plant varieties (obtained by plant biotechnology methods such as genetic engineering) which can also be treated according to the invention have a changed amount, quality and / or storability of the harvested product and / or altered characteristics of certain components of the harvested product, such as:

1. 1) Transgenic plants which synthesize a modified starch with respect to their chemical-physical properties, in particular the amylose content or the amylose / amylopectin ratio, the degree of branching, the average chain length, the distribution of the side chains, the viscosity behavior, the gel strength, the starch grain size and / or starch grain morphology is altered in comparison to the synthesized starch in wild-type plant cells or plants, so that this modified starch is better suited for certain applications. These transgenic plants that synthesize a modified starch are, for example, in EP 0571427 . WO 1995/004826 . EP 0719338 . WO 1996/15248 . WO 1996/19581 . WO 1996/27674 . WO 1997/11188 . WO 1997/26362 . WO 1997/32985 . WO 1997/42328 . WO 1997/44472 . WO 1997/45545 . WO 1998/27212 . WO 1998/40503 . WO 99/58688 . WO 1999/58690 . WO 1999/58654 . WO 2000/008184 . WO 2000/008185 . WO 2000/28052 . WO 2000/77229 . WO 2001/12782 . WO 2001/12826 . WO 2002/101059 . WO 2003/071860 . WO 2004/056999 . WO 2005/030942 . WO 2005/030941 . WO 2005/095632 . WO 2005/095617 . WO 2005/095619 . WO 2005/095618 . WO 2005/123927 . WO 2006/018319 . WO 2006/103107 . WO 2006/108702 . WO 2007/009823 . WO 2000/22140 . WO 2006/063862 . WO 2006/072603 . WO 2002/034923 . EP 06090134.5 . EP 06090228.5 . EP 06090227.7 . EP 07090007.1 . EP 07090009.7 . WO 2001/14569 . WO 2002/79410 . WO 2003/33540 . WO 2004/078983 . WO 2001/19975 . WO 1995/26407 . WO 1996/34968 . WO 1998/20145 . WO 1999/12950 . WO 1999/66050 . WO 1999/53072 . US 6,734,341 . WO 2000/11192 . WO 1998/22604 . WO 1998/32326 . WO 2001/98509 . WO 2001/98509 . WO 2005/002359 . US 5,824,790 . US 6,013,861 . WO 1994/004693 . WO 1994/009144 . WO 1994/11520 . WO 1995/35026 respectively. WO 1997/20936 described.
2. 2) Transgenic plants that synthesize non-starch carbohydrate polymers or non-starch carbohydrate polymers whose properties are altered compared to wild-type plants without genetic modification. Examples are plants which produce polyfructose, in particular of the inulin and levan type, as described in US Pat EP 0663956 . WO 1996/001904 , Where 1996/021023, WO 1998/039460 and WO 1999/024593 described plants that produce alpha-1,4-glucans, as described in WO 1995/031553 . US 2002/031826 . US 6,284,479 . US 5,712,107 . WO 1997/047806 . WO 1997/047807 . WO 1997/047808 and WO 2000/14249 described plants that produce alpha-1,6-branched alpha-1,4-glucans, as shown in WO 2000/73422 and plants that produce alternan, as described in US Pat WO 2000/047727 . EP 06077301.7 . US 5,908,975 and EP 0728213 is described.
3. 3) Transgenic plants that produce hyaluronan, such as in WO 2006/032538 . WO 2007/039314 . WO 2007/039315 . WO 2007/039316 . JP 2006/304779 and WO 2005/012529 is described.

1. a) Pflanzen wie Baumwollpflanzen, die eine veränderte Form von Cellulosesynthasegenen enthalten, wie dies in WO 1998/000549 beschrieben ist,
2. b) Pflanzen wie Baumwollpflanzen, die eine veränderte Form von rsw2- oder rsw3-homologen Nukleinsäuren enthalten, wie dies in WO 2004/053219 beschrieben ist;
3. c) Pflanzen wie Baumwollpflanzen mit einer erhöhten Expression der Saccharosephosphatsynthase, wie dies in WO 2001/017333 beschrieben ist;
4. d) Pflanzen wie Baumwollpflanzen mit einer erhöhten Expression der Saccharosesynthase, wie dies in WO 02/45485 beschrieben ist;
5. e) Pflanzen wie Baumwollpflanzen bei denen der Zeitpunkt der Durchlaßsteuerung der Plasmodesmen an der Basis der Faserzelle verändert ist, z. B. durch Herunterregulieren der faserselektiven β-1,3-Glucanase, wie dies in WO 2005/017157 beschrieben ist;
6. f) Pflanzen wie Baumwollpflanzen mit Fasern mit veränderter Reaktivität, z. B. durch Expression des N-Acetylglucosamintransferasegens, darunter auch nodC, und von Chitinsynthasegenen, wie dies in WO 2006/136351 beschrieben ist.

Plants or plant varieties (obtained by plant biotechnology methods such as genetic engineering), which can also be treated according to the invention, are plants such as cotton plants with altered fiber properties. Such plants can be obtained by genetic transformation or by selection of plants containing a mutation conferring such altered fiber properties; these include:

1. a) plants, such as cotton plants, containing an altered form of cellulose synthase genes, as shown in WO 1998/000549 is described
2. b) plants, such as cotton plants, which contain an altered form of rsw2 or rsw3 homologous nucleic acids, as described in US Pat WO 2004/053219 is described;
3. c) plants such as cotton plants with increased expression of sucrose phosphate synthase, as described in US Pat WO 2001/017333 is described;
4. d) plants such as cotton plants with an increased expression of sucrose synthase, as described in WO 02/45485 is described;
5. e) plants such as cotton plants in which the timing of the passage control of the Plasmodesmen is changed at the base of the fiber cell, z. By down-regulating the fiber-selective β-1,3-glucanase, as described in U.S. Pat WO 2005/017157 is described;
6. f) plants such as cotton plants with modified reactivity fibers, e.g. By expression of the N-acetylglucosamine transferase gene, including nodC, and chitin synthase genes, as described in U.S. Pat WO 2006/136351 is described.

1. a) Pflanzen wie Rapspflanzen, die Öl mit einem hohen Ölsäuregehalt produzieren, wie dies zum Beispiel in US 5,969,169 , US 5,840,946 oder US 6,323,392 oder US 6,063 , 947 beschrieben ist;
2. b) Pflanzen wie Rapspflanzen, die Öl mit einem niedrigen Linolensäuregehalt produzieren, wie dies in US 6,270828 , US 6,169,190 oder US 5,965,755 beschrieben ist.
3. c) Pflanzen wie Rapspflanzen, die Öl mit einem niedrigen gesättigten Fettsäuregehalt produzieren, wie dies z. B. in US 5,434,283 beschrieben ist.

Plants or plant varieties (obtained by plant biotechnology methods such as genetic engineering) which can also be treated according to the invention are plants such as oilseed rape or related Brassica plants with altered oil composition properties. Such plants can be obtained by genetic transformation or by selection of plants containing a mutation conferring such altered oil properties; these include:

1. a) plants such as oilseed rape plants producing oil of high oleic acid content, such as in US 5,969,169 . US 5,840,946 or US 6,323,392 or US 6,063 . 947 is described;
2. (b) plants such as oilseed rape plants producing low linolenic acid oil, as in US 6,270,828 . US 6,169,190 or US 5,965,755 is described.
3. c) plants such as oilseed rape plants which produce oil with a low saturated fatty acid content, such as e.g. In US 5,434,283 is described.

Particularly useful transgenic plants which can be treated according to the invention are plants with one or more genes coding for one or more toxins, the transgenic plants offered under the following commercial names: YIELD GARD® (for example maize, cotton, Soybeans), KnockOut® (for example corn), BiteGard® (for example maize), BT-Xtra® (for example corn), StarLink® (for example maize), Bollgard® (cotton), Nucotn® (cotton), Nucotn 33B® (cotton), NatureGard® (for example corn), Protecta® and NewLeaf® (potato). Herbicide-tolerant crops to be mentioned are, for example, corn, cotton and soybean varieties sold under the following tradenames: Roundup Ready® (glyphosate tolerance, for example corn, cotton, soybean), Liberty Link® (phosphinotricin tolerance, for example rapeseed) , IMI® (imidazolinone tolerance) and SCS® (sylphonylurea tolerance), for example corn.

Herbicide-resistant plants (plants traditionally grown for herbicide tolerance) to be mentioned include the varieties sold under the name Clearfield® (for example corn).

Particularly useful transgenic plants that can be treated according to the invention are plants that contain transformation events, or a combination of transformation events, and that are listed, for example, in the files of various national or regional authorities (see, for example, http: // /gmoinfo.jrc.it/gmp_browse.aspx and http://www.agbios.com/dbase.php).

In particular, the active compound combinations according to the invention are suitable for the treatment of seed. Preference is given to mention the combinations according to the invention mentioned above as being preferred or particularly preferred. Thus, a large part of the damage to crops caused by phytopathogenic fungi and / or animal pests already occurs through the infestation of the seed during storage and after introduction of the seed into the soil and during and immediately after germination of the plants. This phase is particularly critical, as the roots and shoots of the growing plant are particularly sensitive and even minor damage can lead to the death of the entire plant. There is therefore a particular interest in protecting the seed and the germinating plant by the use of suitable agents.

The control of phytopathogenic fungi and / or animal pests by the treatment of the seed of plants has long been known and is the subject of constant improvement. Nevertheless, there are a number of problems in the treatment of seeds that can not always be satisfactorily resolved. Thus, it is desirable to develop methods of protecting the seed and the germinating plant, which eliminate the need for additional crop protection after sowing or after emergence of the plants. It is also desirable to optimize the amount of active ingredient used so that the seed and the germinating plant are best protected against attack by phytopathogenic fungi and / or animal pests, but without damaging the plant itself by the active ingredient used. In particular, methods for treating seed should also include the intrinsic fungicidal and / or insecticidal properties of transgenic plants in order to achieve optimum protection of the seed and also the germinating plant with a minimum of pesticides.

The present invention therefore also relates, in particular, to a method for protecting seed and germinating plants from infestation by phytopathogenic fungi and / or animal pests by treating the seed with a combination of active substances according to the invention. The method according to the invention for protecting seed and germinating plants from attack by phytopathogenic fungi and / or animal pests comprises a method in which the seed is at the same time treated with a compound of the formula (I) and an active compound from the groups listed above (2 ) to (25). It also comprises a process in which the seed is treated at different times with a compound of formula (I) and an active ingredient from the groups (2) to (25) listed above.

The invention also relates to the use of the active compound combinations according to the invention for the treatment of seed for the protection of the seed and the germinating plant from phytopathogenic fungi and / or by phytopathogenic fungi and / or animal pests.

Furthermore, the invention relates to seed which has been treated with a combination of active substances according to the invention for protection against phytopathogenic fungi and / or animal pests. The invention also relates to seed treated at the same time with a compound of the formula (I) and an active ingredient from the groups (2) to (25) listed above. The invention further relates to seed which has been treated at different times with a compound of formula (I) and an active ingredient from groups (2) to (25) listed above. In the case of seed which has been treated at different times with a compound of the formula (I) and an active compound from groups (2) to (25) listed above, the individual active compounds of the active ingredient combination according to the invention may be present in different layers on the seed. In this case, the layers which comprise a compound of the formula (I) and an active compound from the abovementioned groups (2) to (25) may optionally be separated by an intermediate layer. The invention also relates to seed in which a compound of the formula (I) and an active compound from the abovementioned groups (2) to (25) are applied as a constituent of a coating or as a further layer or further layers in addition to a coating.

One of the advantages of the present invention is that due to the particular systemic properties of the active compound combinations according to the invention, the treatment of the seed with these active ingredient combinations protects not only the seed itself, but also the resulting plants after emergence from phytopathogenic fungi and / or animal pests. In this way, the immediate treatment of the culture at the time of sowing or shortly afterwards can be omitted.

Another advantage consists in the synergistic increase of the insecticidal activity of the active compound combinations according to the invention over the insecticidal single active substance, which goes beyond the expected efficacy of the two individually applied active ingredients.

Also advantageous is the synergistic increase in the fungicidal activity of the active compound combinations according to the invention compared with the fungicidal single active substance, which goes beyond the expected effectiveness of the individually applied active ingredient. This allows optimization of the amount of active ingredients used.

Likewise, it is considered to be advantageous that the active compound combinations according to the invention can be used in particular also in transgenic seed.

The active compound combinations according to the invention are suitable for the protection of seed of any plant variety as already mentioned above, which are used in agriculture, in the greenhouse, in forests or in the Horticulture is used. In particular, these are corn, peanut, canola, rapeseed, poppy, soybean, cotton, turnip (eg sugarbeet and fodder beet), rice, millet, wheat, barley, oats, rye, sunflower, tobacco, potatoes or vegetables ( eg tomatoes, cabbage). The active compound combinations according to the invention are likewise suitable for the treatment of the seed of fruit plants and vegetables as already mentioned above. Of particular importance is the treatment of the seeds of maize, soya, cotton, wheat and canola or rapeseed.

In the context of the present invention, the active ingredient combination according to the invention is applied to the seed alone or in a suitable formulation. Preferably, the seed is treated in a state where it is so stable that no damage occurs during the treatment. In general, the treatment of the seed can be done at any time between harvesting and sowing. Usually, seed is used which has been separated from the plant and freed from flasks, shells, stems, hull, wool or pulp. For example, seed may be used which has been harvested, cleaned and dried to a moisture content below 15% by weight. Alternatively, seed may also be used which, after drying, e.g. treated with water and then dried again.

In general, when treating the seed, care must be taken that the amount of the active ingredient combination and / or other additives applied to the seed is chosen so that germination of the seed is not impaired or the resulting plant is not damaged. This is especially important for active ingredients, which can show phytotoxic effects in certain application rates.

The agents according to the invention can be applied directly, ie without containing further components and without being diluted. In general, it is preferable to apply the agents to the seed in the form of a suitable formulation. Suitable formulations and methods for seed treatment are known to the person skilled in the art and are described, for example, in the following documents: US 4,272,417 A . US 4,245,432 A . US 4,808,430 A . US 5,876,739 A . US 2003/0176428 A1 . WO 2002/080675 A1 . WO 2002/028186 A2 ,

The active compounds which can be used according to the invention can be converted into the customary seed dressing formulations, such as solutions, emulsions, suspensions, powders, foams, slurries or other seed coating compositions, as well as ULV formulations.

These formulations are prepared in a known manner by mixing the active ingredients with conventional additives, such as conventional extenders and solvents or diluents, dyes, wetting agents, dispersants, emulsifiers, defoamers, preservatives, secondary thickeners, adhesives, gibberellins and water.

Dyes which may be present in the seed dressing formulations which can be used according to the invention are all dyes customary for such purposes. Both water-insoluble pigments and water-soluble dyes are useful in this case. Examples which may be mentioned under the names rhodamine B, C.I. Pigment Red 112 and C.I. Solvent Red 1 known dyes.

Suitable wetting agents which may be present in the seed dressing formulations which can be used according to the invention are all wetting-promoting substances customary for the formulation of agrochemical active compounds. Preferably usable are alkylnaphthalene sulfonates such as diisopropyl or diisobutylnaphthalene sulfonates.

Suitable dispersants and / or emulsifiers which may be present in the seed dressing formulations which can be used according to the invention are all nonionic, anionic and cationic dispersants customary for the formulation of agrochemical active compounds. Preferably usable are nonionic or anionic dispersants or mixtures of nonionic or anionic dispersants. Particularly suitable nonionic dispersants are, in particular, ethylene oxide-propylene oxide, block polymers, alkylphenol polyglycol ethers and tristryrylphenol polyglycol ethers and their phosphated or sulfated derivatives. Suitable anionic dispersants are in particular lignosulfonates, polyacrylic acid salts and arylsulfonate-formaldehyde condensates.

Defoamers which may be present in the seed-dressing formulations which can be used according to the invention are all foam-inhibiting substances customary for the formulation of agrochemical active compounds. Preferably usable are silicone defoamers and magnesium stearate.

Preservatives which may be present in the seed dressing formulations which can be used according to the invention are all substances which can be used for such purposes in agrochemical compositions. Examples include dichlorophen and Benzylalkoholhemiformal.

Suitable secondary thickeners which may be present in the seed dressing formulations which can be used according to the invention are all substances which can be used for such purposes in agrochemical compositions. Preference is given to cellulose derivatives, acrylic acid derivatives, xanthan, modified clays and finely divided silica.

Suitable adhesives which may be present in the seed dressing formulations which can be used according to the invention are all customary binders which can be used in pickling agents. Preferably mentioned are polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol and Tylose.

Gibberellins which may be present in the seed dressing formulations which can be used according to the invention are preferably the gibberellins A1, A3 (= gibberellic acid), A4 and A7, with particular preference gibberellic acid. The gibberellins are known (cf. R. Wegler "Chemie der Pflanzenschutz- und Schädlingsbekungsmittel", Vol. 2, Springer Verlag, 1970, p. 401-412 ).

The seed dressing formulations which can be used according to the invention can be used either directly or after prior dilution with water for the treatment of seed of various kinds, including seed of transgenic plants. In this case, additional synergistic effects may occur in interaction with the substances formed by expression.

For the treatment of seed with the seed dressing formulations which can be used according to the invention or the preparations prepared therefrom by the addition of water, all mixing devices customarily usable for the dressing can be considered. Specifically, in the pickling procedure, the seed is placed in a mixer which adds either desired amount of seed dressing formulations either as such or after prior dilution with water and mixes until evenly distributed the formulation on the seed. Optionally, a drying process follows.

The active compound combinations according to the invention are also suitable for increasing crop yield. They are also low toxicity and have good plant tolerance.

The active compound combinations according to the invention also have a strong tonic effect in plants. They are therefore suitable for mobilizing plant-own defenses against attack by unwanted microorganisms.

In the present context, plant-strengthening (resistance-inducing) substances are to be understood as meaning those substances which are capable of stimulating the defense system of plants in such a way that the treated plants exhibit extensive resistance to these microorganisms with subsequent inoculation with undesired microorganisms.

Undesirable microorganisms in the present case are phytopathogenic fungi, bacteria and viruses. The substances according to the invention can therefore be used to protect plants within a certain period of time after the treatment against the infestation by the said pathogens. The period within which protection is provided generally extends from 1 to 10 days, preferably 1 to 7 days after the treatment of the plants with the active ingredients.

The listed plants can be treated particularly advantageously according to the invention with the active substance mixtures according to the invention. The preferred ranges given above for the active substance combinations also apply to the treatment of these plants. Particularly emphasized is the plant treatment with the active ingredient combinations specifically mentioned in the present text.

The good insecticidal and fungicidal action of the active compound combinations according to the invention is evident from the examples below. While the individual active ingredients have weaknesses in their effect, the combinations show an effect that goes beyond a simple sum of effects.

A synergistic effect is always present in the case of insecticides and fungicides if the insecticidal or fungicidal action of the active substance combinations is greater than the sum of the effects of the individually applied active substances.

The expected insecticidal or fungicidal effect for a given combination of two drugs may be SR Colby ("Calculating Synergistic and Antagonistic Responses of Herbicidal Combinations", Weeds 1967, 15, 20-22) calculated as follows:

X

den Abtötungsgrad bzw. Wirkungsgrad, ausgedrückt in % der unbehandelten Kontrolle, beim Einsatz des Wirkstoffes A in einer Aufwandmenge von m ppm bzw. g/ha bedeutet,

Y

den Abtötungsgrad bzw. Wirkungsgrad, ausgedrückt in % der unbehandelten Kontrolle, beim Einsatz des Wirkstoffes B in einer Aufwandmenge von n ppm bzw. g/ha bedeutet und

E

den Abtötungsgrad bzw. Wirkungsgrad, ausgedrückt in % der unbehandelten Kontrolle, beim Einsatz der Wirkstoffe A und B in Aufwandmengen von m und n ppm bzw. g/ha bedeutet,

dann ist $$\text{E}=\text{X}+\text{Y}-\frac{\text{X}\times \text{Y}}{100}$$

If

X

the degree of killing or efficiency, expressed in% of the untreated control, when using the active substance A in an application rate of m ppm or g / ha,

Y

the degree of killing or efficiency, expressed in% of the untreated control, when using the active ingredient B in an application rate of n ppm or g / ha means and

e

the degree of killing or efficiency, expressed in% of the untreated control, when using the active compounds A and B at application rates of m and n ppm or g / ha,

then $$\text{e}=\text{X}+\text{Y}-\frac{\text{X}\times \text{Y}}{100}$$

The degree of kill or efficiency is determined in%. It means 0% a degree of kill or efficiency equal to that of the control, while a kill rate of 100% means that all animals are dead and an efficiency of 100% means that no infestation is observed.

If the actual fungicidal or insecticidal effect is greater than calculated, the effect of the combination is over-additive, i. there is a synergistic effect. In this case, the actual observed efficiency must be greater than the expected efficiency value (E) calculated from the above formula.

Example A

Myzus persicae test Solvent: 78 Parts by weight acetone 1.5 Parts by weight of dimethylformamide emulsifier: 0.5 Parts by weight of alkylaryl polyglycol ether

To prepare a suitable preparation of active compound, 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.

Cabbage leaves (Brassica oleracea) which are heavily infested with the green peach aphid (Myzus persicae) are treated by being dipped into the preparation of active compound of the desired concentration.

After the desired time the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed. The determined mortality values are calculated according to the Colby formula (see above).

In this test, z. B. the following drug combinations according to the present application a synergistically enhanced efficacy compared to the individually applied drugs: Table A, page 1 Plant damaging insects Myzus persicae - test active substance Concentration in g / ha Kill in% after 1 ^d Compound (I-5) 0.8 50 fluopyram 200 0 N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide 200 0 fenamidone 200 0 fludioxonil 200 0 iprodione 200 0 isotianil 200 0 metalaxyl 200 0 propamocarb 200 0 prothioconazole 200 0 tebuconazole 200 0 tolylfluanid 200 0 triadimenol 200 0 Compound (I-5) + fluopyram (1: 250) according to the invention 0.8 + 200 gef. * calc. ** 70 50 Compound (I-5) + N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide (1: 250) in the present invention 0.8 + 200 gef. * calc. ** 90 50 Compound (I-5) + Fenamidone (1: 250) according to the invention 0.8 + 200 gef. * calc. ** 90 50 Compound (I-5) + fludioxonil (1: 250) according to the invention 0.8 + 200 gef. * calc. ** 80 50 Compound (I-5) + Iprodione (1: 250) according to the invention 0.8 + 200 gef. * calc. ** 70 50 Compound (I-5) + metalaxyl (1: 250) according to Invention 0.8 + 200 gef. * calc. ** 80 50 Compound (I-5) + propamocarb (1: 250) according to the invention 0.8 + 200 gef. * calc. ** 70 50 Compound (I-5) + prothioconazole (1: 250) according to the invention 0.8 + 200 gef. * calc. ** 80 50 Compound (I-5) + tebuconazole (1: 250) according to the invention 0.8 + 200 gef. * calc. ** 90 50 Compound (I-5) + tolylfluanid (1: 250) according to the invention 0.8 + 200 gef. * calc. ** 80 50 * Found. = found effect ** calc. = calculated according to the Colby formula

Example B

Phaedon cochleariae - larval test Solvent: 78 Parts by weight acetone 1.5 Parts by weight of dimethylformamide emulsifier: 0.5 Parts by weight of alkylaryl polyglycol ether

To prepare a suitable preparation of active compound, 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.

Cabbage leaves (Brassica oleracea) are treated by being dipped into the preparation of active compound of the desired concentration and are populated with larvae of the horseradish leaf beetle (Phaedon cochleariae) while the leaves are still moist.

After the desired time the kill is determined in%. 100% means that all beetle larvae have been killed; 0% means that no beetle larvae have been killed. The determined mortality values are calculated according to the Colby formula (see above).

In this test, the following active ingredient combination according to the present application showed a synergistically enhanced effectiveness in comparison to the individually applied active ingredients: Table B, page 1 Plant damaging insects Phaedon cochleariae larvae test active substance Concentration in g / ha Kill% after 2 ^d Compound (I-5) 20 0 fenamidone 200 0 prothioconazole 200 0 trifloxystrobin 200 0 Compound (I-5) + fenamidone (1:10) according to the invention 20 + 200 gef. * calc. ** 33 0 Compound (I-5) + prothioconazole (1:10) According to the invention 20 + 200 gef. * calc. ** 33 0 * found effect ** calc. = calculated according to the Colby formula Table B, page 2 Plant damaging insects Phaedon cochleariae larvae test active substance Concentration in g / ha Kill% after 6 ^d Compound (I-5) 20 0 fluopyram 200 0 N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide 200 0 fludioxonil 200 17 Fosetyl-Al 200 0 iprodione 200 0 isotianil 200 0 metalaxyl 200 0 tebuconazole 200 0 tolylfluanid 200 17 triadimenol 200 0 trifloxystrobin 200 33 Compound (I-5) + fluopyram (1:10) according to the invention 20 + 200 gef. * calc. ** 33 0 Compound (I-5) + N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide (1:10) in the present invention 20 + 200 gef. * calc. ** 50 0 Compound (I-5) + fosetyl-Al (1:10) according to the invention 20 + 200 gef. * calc. ** 33 0 Compound (I-5) + Iprodione (1:10) according to the invention 20 + 200 gef. * calc. ** 50 0 Compound (I-5) + isotianil (1:10) according to the invention 20 + 200 gef. * calc. ** 50 0 Compound (I-5) + metalaxyl (1:10) according to the invention 20 + 200 gef. * calc. ** 33 0 Compound (I-5) + tebuconazole (1:10) according to the invention 20 + 200 gef. * calc. ** 50 0 Compound (I-5) + tolylfluanid (1:10) according to the invention 20 + 200 gef. * calc. ** 33 17 Compound (I-5) + triadimenol (1:10) according to the invention 20 + 200 gef. * calc. ** 100 0 Compound (I-5) + trifloxystrobin (1:10) according to the invention 20 + 200 gef. * calc. ** 67 33 * Found. = Found effective ** calc. = calculated according to the Colby formula

Example C

Spodoptera frugiperda - larval test Solvent: 78 Parts by weight acetone 1.5 Parts by weight of dimethylformamide emulsifier: 0.5 Parts by weight of alkylaryl polyglycol ether

To prepare a suitable preparation of active compound, 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.

Cabbage leaves (Brassica oleracea) are treated by spraying with the preparation of active compound in the desired concentration and are populated with larvae of the armyworm (Spodoptera frugiperda) while the leaves are still moist.

After the desired time the kill is determined in%. 100% means that all caterpillars have been killed; 0% means that no caterpillars have been killed. The determined mortality values are calculated according to the Colby formula (see above).

In this test, the following active ingredient combinations according to the present application show a synergistically enhanced effectiveness in comparison to the individually applied active ingredients: Table C, page 1 Plant damaging insects Spodoptera frugiperda larvae - test active substance Concentration in g: / ha Kill% after 6 ^d Fosetyl-Al 200 0 tolylfluanid 200 0 * gef. = found effect ** calc. = calculated according to the Colby formula

Example D

Tetranychus urticae - test (surgical-resistant / spray treatment) Solvent: 78 Parts by weight acetone 1.5 Parts by weight of dimethylformamide emulsifier: 0.5 Parts by weight of alkylaryl polyglycol ether

To prepare a suitable preparation of active compound, 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.

Bean leaf discs (Phaseolus vulgaris) infected by all stages of the common spider mite (Tetranychus urticae) are sprayed with an active compound preparation of the desired concentration.

After the desired time, the effect is determined in%. 100% means that all spider mites have been killed; 0% means that no spider mites have been killed.

In this test, the following active ingredient combination according to the present application showed a synergistically enhanced effectiveness in comparison to the individually applied active ingredients: Table D, page 1 Plant damaging mites Tetranychus urticae test active substance Concentration in g / ha Kill in% after 2 ^d Compound (I-5) 100 20 propamocarb 200 0 triadimenol 200 0 Compound (I-5) + triadimenol (1: 2) according to the invention 100 + 200 40 over. ** gef. * 0 * Found. = found effect ** calc. = calculated according to the Colby formula Table D, page 2 Plant damaging mites Tetranychus urticae test active substance Concentration in g: / ha Kill in% after 6 ^d Compound (I-5) 100 0 fluopyram 200 0 fludioxonil 200 0 iprodione 200 50 isotianil 200 0 metalaxyl 200 0 propamocarb 200 0 prothioconazole 200 0 tebuconazole 200 70 triadimenol 200 0 Compound (I-5) + fluopyram (1: 2) according to the invention 100 + 200 gef. * calc. ** 70 0 Compound (I-5) + fludioxonil (1: 2) according to the invention 100 + 200 gef. * calc. ** 70 0 Compound (I-5) + Iprodione (1: 2) according to the invention 100 + 200 gef. * calc. ** 70 50 Compound (I-5) + isotianil (1: 2) according to the invention 100 + 200 gef. * calc. ** 80 0 Compound (I-5) + propamocarb (1: 2) according to the invention 100 + 200 gef. * calc. ** 50 0 Compound (I-5) + metalaxyl (1: 2) according to the invention 100 + 200 gef. * calc. ** 70 0 Compound (I-5) + triadimenol (1: 2) according to Invention 100 + 200 gef. * calc. ** 80 0 * Found. = found effect ** calc. = calculated according to the Colby formula

Claims (11)

Active substance combinations containing the compound of the formula (I)

in which A is 6-chloropyrid-3-yl and R ^{1 is} 2,2-difluoroethyl, and an active compound of groups (2) to (25) selected from (2-1) azoxystrobin ( 2-2) Fluoxastrobin (2-3) (2E) -2- (2 - {[6- (3-chloro-2-methylphenoxy) -5-fluoro-4-pyrimidinyl] oxy) phenyl) -2- (methoxyimino ) -N-methylethanamide (2-4) trifloxystrobin (2-5) (2E) -2- (methoxyimine {[({(1E) -1 - [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) ethanamide (2-6) (2E) -2- (methoxyimino) -N-methyl-2- {2 - [(E) - ({1- [3- (trifluoromethyl) phenyl] ethoxy} imino) methyl ] phenyl} ethanamide (2-8) 5-methoxy-2-methyl-4- (2 - {[({(1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl ) -2,4-dihydro-3H-1,2,4-triazol-3-one (2-9) kresoxime-methyl (2-10) dimoxystrobin (2-11) picoxystrobin (2-12) pyraclostrobin (2- 13) Metominostrobin (3-3) Propiconazole (3-4) Difenoconazole (3-6) Cyproconazole (3-7) Hexaconazole (3-8) Penconazole (3-9) Myclobutanil (3-10) Tetraconazole (3-12) Epoxiconazoles (3-13) Flusilazoles (3-15) Prothioconazoles (3-1 6) Fenbuconazole (3-17) Tebuconazole (3-18) Ipconazole (3-19) Metconazole (3-20) Triticonazole (3-21) Bitertanol (3-22) Triadimenol (3-23) Triadimefon (3-24) Fluquinconazole (4-1) Dichlofluanid (4-2) Tolylfluanid (5-1) Iprovalicarb (5-3) Benthiavalicarb (6-2) Boscalid (6-5) Ethaboxam (6-6) Fenhexamide (6-7) Carpropamid ( 6-8) 2-Chloro-4 - [(2-fluoro-2-methylpropanoyl) amino] -N, N-dimethylbenzamide (6-9) Fluopicolide (6-10) Zoxamide (6-11) Isotianil (6-14 ) Penthiopyrad (6-16) N- [2- (1,3-dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1H-pyrrole-3-carboxamide (6-17) Flutolanil (6-18) N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide (6-25) Fluopyram ( 7-1) Mancozeb (7-2) Maneb (7-4) Propyneb (7-5) Thiram (7-6) Zineb (8-1) Benalaxyl (8-2) Furalaxyl (8-3) Metalaxyl (8- 4) metalaxyl-M (8-5) benalaxyl-M (9-1) cyprodinil (9-2) mepanipyrim (9-3) pyrimethanil (10-1) 6-chloro-5 - [(3,5-dimethylisoxazole) 4-yl) sulfonyl] -2,2-difluoro-5H- [1,3] dioxolo [4,5-f] benzimidazole (10-3) carbendazim (11-1) diethofenoc (11-2) propamocarb (11 -3) Propamocarb-hydrochloride (11-4) Propamocarb-Fosetyl (11-5) Pyribencarb (12-2) Captan (12-3) Folpet (12-4) Iprodione (12-5) Procymidone (13-1) Dodine (13-2) guazatine (13-3) iminoctadine triacetate (14-1) cyazofamide (14-2) prochloraz (14-3) triazoxide (14-5) fenamidone (15-4) fenpropimorph (15-5) dimethomorph ( 15-6) Flumorph (16-2) Fludioxonil (17-1) Fosetyl-Al (17-2) Phosphonic acid (17-3) Tolclofos-methyl (19-1) Acibenzolar-S-methyl (19-2) chlorothalonil ( 19-3) Cymoxanil (19-5) Famoxadone (19-6) Fluaz inam (19-7) copper oxychloride (19-9) oxadixyl (19-10) spiroxamine (19-21) cyprosulfamide (19-22) mandipropamide (20-1) pencycuron (20-2) thiophanate-methyl (22-1) 5-chloro-N - [(1S) -2,2,2-trifluoro-1-methylethyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyrimidin-7-amine (22-2) 5-chloro-N - [(1R) -1,2-dimethylpropyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1, 5-a] -pyrimidin-7-amine (22-4) 5-Chloro-6- (2,4,6-trifluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine (23-1) 2-butoxy-6-iodo-3-propyl-benzopyran-4-one (23-2) 2-ethoxy-6-iodo-3-propylbenzopyran 4-one (23-3) 6-iodo-2-propoxy-3-propyl-benzopyran-4-one (24-1) N- (3 ', 4'-dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide ( 24-3) 3- (trifluoromethyl) -N- {3'-fluoro-4 '- [(E) - (methoxyimino) methyl] -1,1'-biphenyl-2-yl} -1-methyl-1H- pyrazole-4-carboxamide (24-7) N- (4'-bromo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide ( 24-9) bixafen and (25-1) amisulbrom. Active ingredient combinations according to Claim 1 in which the active ingredient of groups (2) to (25) is selected from (2-4) trifloxystrobin (3-15) prothioconazole (3-17) tebuconazole (6-9) fluopicolide (6-25) fluopyram (11-2 Propamocarb (16-2) fludioxonil wherein the compound of formula (I) and the active ingredient of groups (2) to (16) are present in the following mixing weight ratio: Active substance of group (2) - (25) Mixing weight ratio (2-4) Trifloxystrobin 50: 1 to 1: 1000 (3-15) prothioconazole, (3-17) tebuconazole 50: 1 to 1: 1000 (6-9) fluopicolide, (6-25) fluopyram 50: 1 to 1: 1000 (11-2) Propamocarb 250: 1 to 1: 1 (16-2) fludioxonil 50: 1 to 1: 1000 Use of an active ingredient combination, as in one of Claims 1 to 2 defined, for controlling animal pests and / or phytopathogenic fungi. Method for protecting seed, characterized in that a combination of active ingredients, as in one of Claims 1 to 2 defined, act on seed. Method according to Claim 4 , characterized in that a compound of the formula (I) and an active compound of the groups (2) to (25) according to Claim 1 or 2 to act on seeds at the same time. Method according to Claim 4 , characterized in that a compound of the formula (I) and an active compound of the groups (2) to (25) according to Claim 1 or 2 to act on seeds at different times. Use of a drug combination according to any of Claims 1 to 2 for the treatment of transgenic plants. Use of a combination of active substances according to one of Claims 1 to 2 for the treatment of seeds of transgenic plants. Seed, which with an active ingredient combination according to one of Claims 1 to 2 was treated. Seed after Claim 9 containing at the same time a compound of formula (I) and an active compound of groups (2) to (25) according to Claim 1 or 2 was treated. Seed after Claim 9 which at different times with a compound of formula (I) and an active ingredient of groups (2) to (25) according to Claim 1 or 2 was treated.