DD205680A5 - Verfahren zur herstellung von methanol und hoeheren alkoholen - Google Patents

Verfahren zur herstellung von methanol und hoeheren alkoholen Download PDF

Info

Publication number: DD205680A5
Authority: DD; German Democratic Republic
Prior art keywords: catalyst; methanol; catalyst system; higher alcohols; alkali metal
Prior art date: 1981-12-02

Application number

DD82245316A

Other languages

German (de)

English (en)

Inventor

Vittorio Fattore

Bruno Notari

Alberto Paggini

Vincenzo Lagana

Original Assignee

Snam Progetti

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-12-02

Filing date

1982-11-29

Publication date

1984-01-04

1982-11-29 Application filed by Snam Progetti filed Critical Snam Progetti

1984-01-04 Publication of DD205680A5 publication Critical patent/DD205680A5/de

Links

150000001298 alcohols Chemical class 0.000 title claims abstract description 18
238000000034 method Methods 0.000 title claims abstract description 10
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title abstract description 48
238000004519 manufacturing process Methods 0.000 title abstract description 4
239000003054 catalyst Substances 0.000 claims abstract description 60
150000001340 alkali metals Chemical class 0.000 claims abstract description 8
229910052783 alkali metal Inorganic materials 0.000 claims abstract description 7
229910052751 metal Inorganic materials 0.000 claims abstract description 7
239000002184 metal Substances 0.000 claims abstract description 7
239000011261 inert gas Substances 0.000 claims abstract description 5
150000002739 metals Chemical class 0.000 claims abstract description 5
239000010949 copper Substances 0.000 claims description 13
239000011651 chromium Substances 0.000 claims description 12
239000011701 zinc Substances 0.000 claims description 11
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 9
229910052802 copper Inorganic materials 0.000 claims description 8
229910052804 chromium Inorganic materials 0.000 claims description 5
229910052739 hydrogen Inorganic materials 0.000 claims description 5
239000001257 hydrogen Substances 0.000 claims description 5
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 4
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
229910052720 vanadium Inorganic materials 0.000 claims description 4
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 4
229910052725 zinc Inorganic materials 0.000 claims description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 3
229910052700 potassium Inorganic materials 0.000 claims description 3
239000011591 potassium Substances 0.000 claims description 3
229910052684 Cerium Inorganic materials 0.000 claims description 2
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
229910052782 aluminium Inorganic materials 0.000 claims description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 2
229910052746 lanthanum Inorganic materials 0.000 claims description 2
FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 2
229910052750 molybdenum Inorganic materials 0.000 claims description 2
239000011733 molybdenum Substances 0.000 claims description 2
239000001301 oxygen Substances 0.000 claims description 2
229910052760 oxygen Inorganic materials 0.000 claims description 2
239000010936 titanium Substances 0.000 claims description 2
229910052719 titanium Inorganic materials 0.000 claims description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 2
229920006395 saturated elastomer Polymers 0.000 claims 2
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 1
229910002092 carbon dioxide Inorganic materials 0.000 claims 1
239000001569 carbon dioxide Substances 0.000 claims 1
229910002091 carbon monoxide Inorganic materials 0.000 claims 1
239000000203 mixture Substances 0.000 description 18
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 12
238000002360 preparation method Methods 0.000 description 11
239000000243 solution Substances 0.000 description 11
WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 8
230000015572 biosynthetic process Effects 0.000 description 8
239000007789 gas Substances 0.000 description 8
238000003786 synthesis reaction Methods 0.000 description 8
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 6
239000011787 zinc oxide Substances 0.000 description 6
239000008367 deionised water Substances 0.000 description 5
229910021641 deionized water Inorganic materials 0.000 description 5
239000008188 pellet Substances 0.000 description 5
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 5
230000004048 modification Effects 0.000 description 4
238000012986 modification Methods 0.000 description 4
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
150000003839 salts Chemical class 0.000 description 4
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
238000003756 stirring Methods 0.000 description 4
229910002651 NO3 Inorganic materials 0.000 description 3
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 3
235000011056 potassium acetate Nutrition 0.000 description 3
239000002244 precipitate Substances 0.000 description 3
DOKGXWGIRVIEOI-UHFFFAOYSA-N 2-methylpropan-1-ol;propan-1-ol Chemical compound CCCO.CC(C)CO DOKGXWGIRVIEOI-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
239000003513 alkali Substances 0.000 description 2
229910000423 chromium oxide Inorganic materials 0.000 description 2
PHFQLYPOURZARY-UHFFFAOYSA-N chromium trinitrate Chemical compound [Cr+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PHFQLYPOURZARY-UHFFFAOYSA-N 0.000 description 2
238000002485 combustion reaction Methods 0.000 description 2
ZYBWTEQKHIADDQ-UHFFFAOYSA-N ethanol;methanol Chemical compound OC.CCO ZYBWTEQKHIADDQ-UHFFFAOYSA-N 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
229910000027 potassium carbonate Inorganic materials 0.000 description 2
239000002002 slurry Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
-1 16% Chemical compound 0.000 description 1
YPFNIPKMNMDDDB-UHFFFAOYSA-K 2-[2-[bis(carboxylatomethyl)amino]ethyl-(2-hydroxyethyl)amino]acetate;iron(3+) Chemical compound [Fe+3].OCCN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O YPFNIPKMNMDDDB-UHFFFAOYSA-K 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
229910052770 Uranium Inorganic materials 0.000 description 1
229910000272 alkali metal oxide Inorganic materials 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
JOSWYUNQBRPBDN-UHFFFAOYSA-P ammonium dichromate Chemical compound [NH4+].[NH4+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O JOSWYUNQBRPBDN-UHFFFAOYSA-P 0.000 description 1
235000011114 ammonium hydroxide Nutrition 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
239000007900 aqueous suspension Substances 0.000 description 1
239000000969 carrier Substances 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
238000004587 chromatography analysis Methods 0.000 description 1
239000003245 coal Substances 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
238000001816 cooling Methods 0.000 description 1
150000001879 copper Chemical class 0.000 description 1
229910052878 cordierite Inorganic materials 0.000 description 1
229910052593 corundum Inorganic materials 0.000 description 1
239000010431 corundum Substances 0.000 description 1
238000007865 diluting Methods 0.000 description 1
JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 1
KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000012065 filter cake Substances 0.000 description 1
239000012530 fluid Substances 0.000 description 1
239000000446 fuel Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
238000000265 homogenisation Methods 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
238000005984 hydrogenation reaction Methods 0.000 description 1
239000000543 intermediate Substances 0.000 description 1
239000007788 liquid Substances 0.000 description 1
238000011068 loading method Methods 0.000 description 1
229910052748 manganese Inorganic materials 0.000 description 1
239000011572 manganese Substances 0.000 description 1
229940071125 manganese acetate Drugs 0.000 description 1
UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 description 1
229910052863 mullite Inorganic materials 0.000 description 1
239000003345 natural gas Substances 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
238000005453 pelletization Methods 0.000 description 1
239000003209 petroleum derivative Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
239000000047 product Substances 0.000 description 1
239000010453 quartz Substances 0.000 description 1
239000004576 sand Substances 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
239000004332 silver Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
239000000725 suspension Substances 0.000 description 1
JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/885—Molybdenum and copper
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/86—Chromium
- B01J23/868—Chromium copper and chromium
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

DD82245316A 1981-12-02 1982-11-29 Verfahren zur herstellung von methanol und hoeheren alkoholen DD205680A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
IT25390/81A IT1169281B (it)	1981-12-02	1981-12-02	Sistema catalitico e procedimento per la produzione di miscele di metanolo ed alcoli superiori

Publications (1)

Publication Number	Publication Date
DD205680A5 true DD205680A5 (de)	1984-01-04

Family

ID=11216562

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD82245316A DD205680A5 (de)	1981-12-02	1982-11-29	Verfahren zur herstellung von methanol und hoeheren alkoholen

Country Status (32)

Country	Link
US (2)	US4513100A (da)
JP (1)	JPS58104635A (da)
KR (2)	KR860002159B1 (da)
AU (1)	AU550713B2 (da)
BE (1)	BE895208A (da)
BR (1)	BR8206776A (da)
CA (1)	CA1194013A (da)
CH (1)	CH650946A5 (da)
CS (1)	CS236697B2 (da)
CU (1)	CU21442A3 (da)
DD (1)	DD205680A5 (da)
DE (1)	DE3244313C2 (da)
DK (1)	DK531782A (da)
EG (1)	EG16016A (da)
ES (1)	ES8401436A1 (da)
FI (1)	FI71883C (da)
FR (1)	FR2517296A1 (da)
GB (1)	GB2110558B (da)
GR (1)	GR77106B (da)
IE (1)	IE53599B1 (da)
IN (1)	IN157897B (da)
IT (1)	IT1169281B (da)
LU (1)	LU84494A1 (da)
NO (1)	NO158722C (da)
NZ (1)	NZ202305A (da)
PH (1)	PH17792A (da)
PL (2)	PL137518B1 (da)
RO (1)	RO86064B (da)
SE (1)	SE451545B (da)
SU (1)	SU1279516A3 (da)
YU (1)	YU259682A (da)
ZA (1)	ZA827980B (da)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
AU565013B2 (en) *	1982-11-29	1987-09-03	Research Association For Petroleum Alternatives Development	Production of mixed alcohols
US4843101A (en) *	1983-06-01	1989-06-27	Lehigh University	Catalyst and method for producing methanol
DE3403491A1 (de) *	1984-02-02	1985-08-14	Süd-Chemie AG, 8000 München	Katalysator zur synthese von methanol und hoehere alkohole enthaltenden alkoholgemischen
US4752622A (en) *	1984-07-30	1988-06-21	The Dow Chemical Company	Process for producing alcohols from synthesis gas
US4831060A (en) *	1984-07-30	1989-05-16	The Dow Chemical Company	Mixed alcohols production from syngas
US4882360A (en) *	1984-07-30	1989-11-21	The Dow Chemical Company	Process for producing alcohols from synthesis gas
US4762858A (en) *	1985-09-16	1988-08-09	The Dow Chemical Company	Syngas conversion to oxygenates by reduced yttrium/lanthanide/actinide-modified catalyst
US4943551A (en) *	1985-11-08	1990-07-24	Union Carbide Chemicals And Plastics Company, Inc.	Catalyst for synthesis of mixtures of methanol and higher alcohols
US4681868A (en) *	1986-05-29	1987-07-21	The Standard Oil Company	Oxygenate condensation catalyst
US4789502A (en) *	1986-11-24	1988-12-06	Shell Oil Company	Carboxylic acid production
US4886651A (en) *	1988-05-18	1989-12-12	Air Products And Chemicals, Inc.	Process for co-production of higher alcohols, methanol and ammonia
US5345005A (en) *	1989-09-12	1994-09-06	Engelhard Corporation	Hydrogenation catalyst, process for preparing and process of using said catalyst
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1981
- 1981-12-02 IT IT25390/81A patent/IT1169281B/it active
1982
- 1982-10-28 NZ NZ202305A patent/NZ202305A/en unknown
- 1982-10-28 US US06/437,439 patent/US4513100A/en not_active Expired - Lifetime
- 1982-10-29 NO NO823601A patent/NO158722C/no unknown
- 1982-11-01 CA CA000414582A patent/CA1194013A/en not_active Expired
- 1982-11-01 ZA ZA827980A patent/ZA827980B/xx unknown
- 1982-11-03 SE SE8206257A patent/SE451545B/sv not_active IP Right Cessation
- 1982-11-04 AU AU90168/82A patent/AU550713B2/en not_active Ceased
- 1982-11-05 PH PH28093A patent/PH17792A/en unknown
- 1982-11-05 GB GB08231640A patent/GB2110558B/en not_active Expired
- 1982-11-09 GR GR69769A patent/GR77106B/el unknown
- 1982-11-09 KR KR8205053A patent/KR860002159B1/ko active
- 1982-11-19 ES ES517749A patent/ES8401436A1/es not_active Expired
- 1982-11-22 BR BR8206776A patent/BR8206776A/pt unknown
- 1982-11-22 YU YU02596/82A patent/YU259682A/xx unknown
- 1982-11-25 CS CS828464A patent/CS236697B2/cs unknown
- 1982-11-26 FR FR8219935A patent/FR2517296A1/fr active Granted
- 1982-11-26 SU SU3516802A patent/SU1279516A3/ru active
- 1982-11-29 LU LU84494A patent/LU84494A1/xx unknown
- 1982-11-29 DD DD82245316A patent/DD205680A5/de unknown
- 1982-11-30 DE DE3244313A patent/DE3244313C2/de not_active Expired
- 1982-11-30 DK DK531782A patent/DK531782A/da not_active Application Discontinuation
- 1982-11-30 RO RO109181A patent/RO86064B/ro unknown
- 1982-11-30 CH CH6960/82A patent/CH650946A5/it not_active IP Right Cessation
- 1982-12-01 EG EG708/82A patent/EG16016A/xx active
- 1982-12-01 IE IE2861/82A patent/IE53599B1/en unknown
- 1982-12-01 PL PL1982239300A patent/PL137518B1/pl unknown
- 1982-12-01 CU CU8125390AA patent/CU21442A3/es unknown
- 1982-12-01 BE BE0/209617A patent/BE895208A/fr not_active IP Right Cessation
- 1982-12-01 PL PL1982248949A patent/PL138697B1/pl unknown
- 1982-12-02 JP JP57210701A patent/JPS58104635A/ja active Granted
- 1982-12-02 IN IN1403/CAL/82A patent/IN157897B/en unknown
- 1982-12-02 FI FI824150A patent/FI71883C/fi not_active IP Right Cessation
1986
- 1986-10-16 US US06/918,668 patent/US4778827A/en not_active Expired - Fee Related
- 1986-10-24 KR KR1019860008931A patent/KR890004344B1/ko active IP Right Grant

Also Published As

Publication number	Publication date
GB2110558B (en)	1985-01-23
FI71883B (fi)	1986-11-28
KR860002159B1 (ko)	1986-12-22
FI824150L (fi)	1983-06-03
KR880005848A (ko)	1988-06-30
CU21442A3 (en)	1987-01-13
DK531782A (da)	1983-06-03
GR77106B (da)	1984-09-06
JPH0336571B2 (da)	1991-05-31
FI71883C (fi)	1987-03-09
KR840002259A (ko)	1984-06-25
NO158722B (no)	1988-07-18
RO86064B (ro)	1985-04-02
AU9016882A (en)	1983-06-09
SE451545B (sv)	1987-10-19
PL137518B1 (en)	1986-06-30
CH650946A5 (it)	1985-08-30
EG16016A (en)	1988-01-31
PL239300A1 (en)	1983-07-18
US4778827A (en)	1988-10-18
LU84494A1 (fr)	1983-09-08
KR890004344B1 (ko)	1989-10-31
IT8125390A0 (it)	1981-12-02
FR2517296A1 (fr)	1983-06-03
RO86064A (ro)	1985-03-15
ZA827980B (en)	1983-12-28
NO158722C (no)	1988-10-26
AU550713B2 (en)	1986-04-10
DE3244313A1 (de)	1983-06-16
SE8206257L (sv)	1983-06-03
ES517749A0 (es)	1983-12-16
IN157897B (da)	1986-07-19
YU259682A (en)	1985-06-30
JPS58104635A (ja)	1983-06-22
NZ202305A (en)	1985-07-31
NO823601L (no)	1983-06-03
IE822861L (en)	1983-06-02
PH17792A (en)	1984-12-13
ES8401436A1 (es)	1983-12-16
DE3244313C2 (de)	1986-02-06
BE895208A (fr)	1983-06-01
CA1194013A (en)	1985-09-24
SE8206257D0 (sv)	1982-11-03
IE53599B1 (en)	1988-12-21
IT1169281B (it)	1987-05-27
CS236697B2 (en)	1985-05-15
PL138697B1 (en)	1986-10-31
FI824150A0 (fi)	1982-12-02
SU1279516A3 (ru)	1986-12-23
GB2110558A (en)	1983-06-22
BR8206776A (pt)	1983-10-04
US4513100A (en)	1985-04-23
FR2517296B1 (da)	1985-04-19

Publication	Publication Date	Title
DD205680A5 (de)	1984-01-04	Verfahren zur herstellung von methanol und hoeheren alkoholen
DE2748097C3 (de)	1989-09-21	Verfahren zur herstellung von primaeren, gesaettigten und geradkettigen alkoholen
EP0604792B1 (de)	1996-04-17	Kupferkatalysator
EP0152809B1 (de)	1990-01-03	Katalysator zur Synthese von Methanol und höhere Alkohole enthaltenden Alkoholgemischen
DE2653863C2 (da)	1988-10-20
EP0034338B1 (de)	1982-12-22	Katalysator zur Synthese von Methanol und höhere Alkohole enthaltenden Alkoholgemischen
EP0528305B1 (de)	1995-03-08	Kupfer-Zinkoxid-Aluminiumoxid enthaltende Katalysatoren
DE69721944T2 (de)	2004-04-01	Katalysator für Dimethylether, Verfahren zur Katalysatorherstellung und Verfahren zur Herstellung von Dimethylether
DE2757788C3 (de)	1980-02-14	Verfahren zur Herstellung von Dimethyläther
DE1246688B (de)	1967-08-10	Verfahren zur Herstellung von wasserstoffhaltigen Gasgemischen
DE69118404T2 (de)	1996-09-19	Verfahren mit hoher konversion und hoher selektivität zur dampfphasen-hydrierung von maleinsäureanhydrid zu gamma-butyrolacton unter verwendung eines aktivierten katalysator
EP0324983A1 (de)	1989-07-26	Ruthenium-Trägerkatalysator, seine Herstellung und sein Einsatz bei der Herstellung von gegebenenfalls substituiertem Cyclohexylamin und gegebenenfalls substituiertem Dicyclohexylamin
DE3641666C2 (de)	1999-04-22	Verfahren zur Herstellung eines sekundären Amins
DE3837308A1 (de)	1990-05-10	Kupferhaltiger katalysator zur tieftemperaturkonvertierung
DE3203748C2 (de)	1985-10-31	Verfahren zur Herstellung von Methanol
DE2620554C3 (de)	1984-05-24	Verfahren zur Herstellung eines Kupfer-Nickel-Siliciumoxid-Katalysators und seine Verwendung
DE2202733A1 (de)	1973-07-26	Verfahren zur herstellung von acrolein und acrylsaeure
DE4238640C2 (de)	1996-04-04	Verfahren zur Hydrierung wenigstens einer der Verbindungen CO und CO¶2¶
DE69418609T2 (de)	2000-01-13	Ammoxydationskatalysatorzusammensetzung und verfahren zur herstellung von acrylonitril oder methacrylonitro unter deren anwendung
DE2952061C2 (da)	1990-08-30
EP0096796B1 (de)	1987-05-13	Kobalt enthaltende Trägerkatalysatoren, deren Herstellung und Verwendung
DE1258395B (de)	1968-01-11	Verfahren zur Herstellung eines Dehydrierungskatalysators
EP0096798B1 (de)	1985-01-30	Verfahren zur Herstellung von Cyclohexanol und Cyclohexanon
DE3210708A1 (de)	1983-10-06	Katalysator und seine verwendung zur herstellung von methylmethacrylat
DE2235992C3 (de)	1978-05-18	Verfahren zur Herstellung gesättigter aliphatischer Amine