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KR880005848A - 메탄올과 고급 알코올 혼합물의 제조방법 - Google Patents

메탄올과 고급 알코올 혼합물의 제조방법 Download PDF

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Publication number
KR880005848A
KR880005848A KR860008931A KR860008931A KR880005848A KR 880005848 A KR880005848 A KR 880005848A KR 860008931 A KR860008931 A KR 860008931A KR 860008931 A KR860008931 A KR 860008931A KR 880005848 A KR880005848 A KR 880005848A
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KR
South Korea
Prior art keywords
higher alcohol
alcohol mixtures
preparing methanol
000ghsv
kpa
Prior art date
Application number
KR860008931A
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English (en)
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KR890004344B1 (ko
Inventor
파토래 비토리오
노타리 부르노
파기니 알베르토
라가나 빈센조
Original Assignee
칼로 시오니
스남프로 게티 쏘시에떼 퍼 아찌오니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication of KR880005848A publication Critical patent/KR880005848A/ko
Application granted granted Critical
Publication of KR890004344B1 publication Critical patent/KR890004344B1/ko

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/885—Molybdenum and copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/868—Chromium copper and chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

메탄올과 고급 알코올 혼합물의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (2)

  1. 330°C-460°C, 특히 360°C-440°C의 온도에서, 가능하면, CO2및 비활성물질의 존재하에 0.2-10, 특히 0.5-3의 H2:CO몰비율로, H2및 CO를 반응대역으로 공급하는 것을 포함하는 메탄올 및 고급 알코올 제조 방법에 있어서, 2000-30,000KPa의 압력하에, 그리고 5000-30,000GHSV의 공간속도로 조작하는 것을 특징으로 하며, 더우기 아래의 조성을 가지는 촉매를 사용하는 것을 특징으로 하는 제조방법 :
    Zn.Crw.Cux.Ay.Mez.Ot
    여기서, w는 0.1-0.8이고, x는 0.005-0.5이고, y는 0.002-0.2이고, z는 0-0.1이고, t는 3.75-1.3인데, 이같은 여러가지 원소들이 촉매내에 나타내는 원자가를 만족시키기에 필요한 것이고, A는 알카리금속이며, Me는 다름 가능하게 사용할 수 있는 금속임.
  2. 제1항에 있어서, 압력이 6000-18,000KPa이고, 공간속도가 5000-15,000GHSV인 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860008931A 1981-12-02 1986-10-24 메탄올과 고급 알코올 혼합물의 제조방법 KR890004344B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT25390/81A IT1169281B (it) 1981-12-02 1981-12-02 Sistema catalitico e procedimento per la produzione di miscele di metanolo ed alcoli superiori
IT25390 1981-12-02

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
KR8205053A Division KR860002159B1 (ko) 1981-12-02 1982-11-09 메탄올과 고급 알코올 혼합물 제조용 촉매시스템

Publications (2)

Publication Number Publication Date
KR880005848A true KR880005848A (ko) 1988-06-30
KR890004344B1 KR890004344B1 (ko) 1989-10-31

Family

ID=11216562

Family Applications (2)

Application Number Title Priority Date Filing Date
KR8205053A KR860002159B1 (ko) 1981-12-02 1982-11-09 메탄올과 고급 알코올 혼합물 제조용 촉매시스템
KR1019860008931A KR890004344B1 (ko) 1981-12-02 1986-10-24 메탄올과 고급 알코올 혼합물의 제조방법

Family Applications Before (1)

Application Number Title Priority Date Filing Date
KR8205053A KR860002159B1 (ko) 1981-12-02 1982-11-09 메탄올과 고급 알코올 혼합물 제조용 촉매시스템

Country Status (32)

Country Link
US (2) US4513100A (ko)
JP (1) JPS58104635A (ko)
KR (2) KR860002159B1 (ko)
AU (1) AU550713B2 (ko)
BE (1) BE895208A (ko)
BR (1) BR8206776A (ko)
CA (1) CA1194013A (ko)
CH (1) CH650946A5 (ko)
CS (1) CS236697B2 (ko)
CU (1) CU21442A3 (ko)
DD (1) DD205680A5 (ko)
DE (1) DE3244313C2 (ko)
DK (1) DK531782A (ko)
EG (1) EG16016A (ko)
ES (1) ES517749A0 (ko)
FI (1) FI71883C (ko)
FR (1) FR2517296A1 (ko)
GB (1) GB2110558B (ko)
GR (1) GR77106B (ko)
IE (1) IE53599B1 (ko)
IN (1) IN157897B (ko)
IT (1) IT1169281B (ko)
LU (1) LU84494A1 (ko)
NO (1) NO158722C (ko)
NZ (1) NZ202305A (ko)
PH (1) PH17792A (ko)
PL (2) PL138697B1 (ko)
RO (1) RO86064B (ko)
SE (1) SE451545B (ko)
SU (1) SU1279516A3 (ko)
YU (1) YU259682A (ko)
ZA (1) ZA827980B (ko)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU565013B2 (en) * 1982-11-29 1987-09-03 Research Association For Petroleum Alternatives Development Production of mixed alcohols
US4843101A (en) * 1983-06-01 1989-06-27 Lehigh University Catalyst and method for producing methanol
DE3403491A1 (de) * 1984-02-02 1985-08-14 Süd-Chemie AG, 8000 München Katalysator zur synthese von methanol und hoehere alkohole enthaltenden alkoholgemischen
US4831060A (en) * 1984-07-30 1989-05-16 The Dow Chemical Company Mixed alcohols production from syngas
US4752622A (en) * 1984-07-30 1988-06-21 The Dow Chemical Company Process for producing alcohols from synthesis gas
US4882360A (en) * 1984-07-30 1989-11-21 The Dow Chemical Company Process for producing alcohols from synthesis gas
US4762858A (en) * 1985-09-16 1988-08-09 The Dow Chemical Company Syngas conversion to oxygenates by reduced yttrium/lanthanide/actinide-modified catalyst
US4943551A (en) * 1985-11-08 1990-07-24 Union Carbide Chemicals And Plastics Company, Inc. Catalyst for synthesis of mixtures of methanol and higher alcohols
US4681868A (en) * 1986-05-29 1987-07-21 The Standard Oil Company Oxygenate condensation catalyst
US4789502A (en) * 1986-11-24 1988-12-06 Shell Oil Company Carboxylic acid production
US4886651A (en) * 1988-05-18 1989-12-12 Air Products And Chemicals, Inc. Process for co-production of higher alcohols, methanol and ammonia
US5345005A (en) * 1989-09-12 1994-09-06 Engelhard Corporation Hydrogenation catalyst, process for preparing and process of using said catalyst
US5155086A (en) * 1989-09-12 1992-10-13 Engelhard Corporation Hydrogenation catalyst, process for preparing and process of using said catalyst
US5070058A (en) * 1990-01-22 1991-12-03 Texaco, Inc. Method for making a catalyst composition used in the production of lower aliphatic alcohols
US5134108A (en) * 1991-05-22 1992-07-28 Engelhard Corporation Process for preparing catalyst with copper or zinc and with chromium, molybdenum, tungsten, or vanadium, and product thereof
US5410015A (en) * 1991-06-22 1995-04-25 Basf Aktiengesellschaft Polyamides having a low water absorptivity
US5300695A (en) * 1992-12-07 1994-04-05 Amoco Corporation Process for preparing alcohols
IT1276931B1 (it) * 1995-10-13 1997-11-03 Snam Progetti Procedimento per produrre miscele di metanolo ed alcoli superiori
KR20030085284A (ko) * 2002-04-30 2003-11-05 고양복합영농조합법인 열무를 절단 포장하는 제조방법 및 그 포장 열무
TW200519073A (en) * 2003-08-21 2005-06-16 Pearson Technologies Inc Process and apparatus for the production of useful products from carbonaceous feedstock
US8394863B2 (en) 2003-08-21 2013-03-12 Pearson Technologies, Inc. Process and apparatus for the production of useful products from carbonaceous feedstock
CN101678329B (zh) * 2007-04-27 2013-09-18 沙特基础工业公司 将二氧化碳催化加氢成合成气混合物
US20090156392A1 (en) * 2007-12-14 2009-06-18 Range Fuels, Inc. Catalyst compositions and methods for alcohol production from synthesis gas
WO2012062338A1 (en) 2010-11-08 2012-05-18 Haldor Topsøe A/S Process for the selective preparation of iso-propanol, iso-butanol and other c3+ alcohols from synthesis gas and methanol
US10875820B2 (en) 2013-06-20 2020-12-29 Standard Alcohol Company Of America, Inc. Catalyst for converting syngas to mixed alcohols
US9290425B2 (en) 2013-06-20 2016-03-22 Standard Alcohol Company Of America, Inc. Production of mixed alcohols from synthesis gas
EP4112169A1 (en) 2021-07-03 2023-01-04 Studiengesellschaft Kohle mbH Process for converting synthesis gas to higher alcohols

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE553785C (de) * 1923-05-23 1932-07-01 I G Farbenindustrie Akt Ges Verfahren zur Herstellung von oeligen Produkten
US2960518A (en) * 1957-09-27 1960-11-15 Peters Kurt Ethylene production process
US3326956A (en) * 1962-06-08 1967-06-20 Ici Ltd Production of oxygenated hydrocarbons
FR1390776A (fr) * 1963-04-23 1965-02-26 British Petroleum Co Procédé de production d'un gaz contenant de l'hydrogène et gaz obtenu
JPS4937708B1 (ko) * 1970-12-31 1974-10-11
FR2369234A1 (fr) * 1976-10-29 1978-05-26 Inst Francais Du Petrole Procede de fabrication d'alc
US4107089A (en) * 1977-03-14 1978-08-15 Petr Grigorievich Bondar Catalyst for the synthesis of methanol and method for preparing same
DE2738269C3 (de) * 1977-08-25 1980-02-21 Chemische Werke Huels Ag, 4370 Marl Verfahren zur Herstellung von Aceton aus Isobutyraldehyd
FR2444654A1 (fr) * 1978-12-19 1980-07-18 Inst Francais Du Petrole Procede de fabrication d'alcools et plus particulierement d'alcools primaires, satures et lineaires, a partir de gaz de synthese
DE3005550A1 (de) * 1980-02-14 1981-08-20 Süd-Chemie AG, 8000 München Verfahren zur herstellung von olefinen
IT1140947B (it) * 1980-05-16 1986-10-10 Snam Progetti Processo per la produzione di una miscela di metanolo ed alcoli superiori "grado carburante"
IT1148864B (it) * 1980-05-16 1986-12-03 Snam Progetti Processo pe la produzione di una miscela di metanolo ed alcoli superiori grado carburante

Also Published As

Publication number Publication date
LU84494A1 (fr) 1983-09-08
PH17792A (en) 1984-12-13
GR77106B (ko) 1984-09-06
GB2110558A (en) 1983-06-22
NZ202305A (en) 1985-07-31
AU9016882A (en) 1983-06-09
CH650946A5 (it) 1985-08-30
RO86064A (ro) 1985-03-15
NO823601L (no) 1983-06-03
KR860002159B1 (ko) 1986-12-22
IT8125390A0 (it) 1981-12-02
IE53599B1 (en) 1988-12-21
ES8401436A1 (es) 1983-12-16
SE8206257L (sv) 1983-06-03
RO86064B (ro) 1985-04-02
YU259682A (en) 1985-06-30
SU1279516A3 (ru) 1986-12-23
US4778827A (en) 1988-10-18
US4513100A (en) 1985-04-23
ES517749A0 (es) 1983-12-16
KR890004344B1 (ko) 1989-10-31
JPH0336571B2 (ko) 1991-05-31
BE895208A (fr) 1983-06-01
ZA827980B (en) 1983-12-28
AU550713B2 (en) 1986-04-10
FI824150L (fi) 1983-06-03
PL138697B1 (en) 1986-10-31
EG16016A (en) 1988-01-31
DE3244313A1 (de) 1983-06-16
IT1169281B (it) 1987-05-27
JPS58104635A (ja) 1983-06-22
KR840002259A (ko) 1984-06-25
NO158722B (no) 1988-07-18
SE451545B (sv) 1987-10-19
IE822861L (en) 1983-06-02
CA1194013A (en) 1985-09-24
FI824150A0 (fi) 1982-12-02
NO158722C (no) 1988-10-26
FI71883C (fi) 1987-03-09
DE3244313C2 (de) 1986-02-06
FR2517296A1 (fr) 1983-06-03
PL137518B1 (en) 1986-06-30
CU21442A3 (en) 1987-01-13
GB2110558B (en) 1985-01-23
DD205680A5 (de) 1984-01-04
CS236697B2 (en) 1985-05-15
PL239300A1 (en) 1983-07-18
BR8206776A (pt) 1983-10-04
FR2517296B1 (ko) 1985-04-19
FI71883B (fi) 1986-11-28
IN157897B (ko) 1986-07-19
SE8206257D0 (sv) 1982-11-03
DK531782A (da) 1983-06-03

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