[go: up one dir, main page]

CN1473114A - 带图象的层压材料 - Google Patents

带图象的层压材料 Download PDF

Info

Publication number
CN1473114A
CN1473114A CNA018182852A CN01818285A CN1473114A CN 1473114 A CN1473114 A CN 1473114A CN A018182852 A CNA018182852 A CN A018182852A CN 01818285 A CN01818285 A CN 01818285A CN 1473114 A CN1473114 A CN 1473114A
Authority
CN
China
Prior art keywords
interlayer
image
sheet
described method
material piece
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CNA018182852A
Other languages
English (en)
Inventor
M・C・雷诺
M·C·雷诺
L・安德森
A·J·L·安德森
麦克卢斯基
G·M·麦克卢斯基
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DIGIGLASS PTY Ltd
Original Assignee
DIGIGLASS PTY Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27158241&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CN1473114(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from AUPQ9830A external-priority patent/AUPQ983000A0/en
Priority claimed from AUPR0567A external-priority patent/AUPR056700A0/en
Priority claimed from AUPR2194A external-priority patent/AUPR219400A0/en
Application filed by DIGIGLASS PTY Ltd filed Critical DIGIGLASS PTY Ltd
Priority to CN201310388396.7A priority Critical patent/CN103552321B/zh
Publication of CN1473114A publication Critical patent/CN1473114A/zh
Pending legal-status Critical Current

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10807—Making laminated safety glass or glazing; Apparatus therefor
    • B32B17/10899—Making laminated safety glass or glazing; Apparatus therefor by introducing interlayers of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165—Functional features of the laminated safety glass or glazing
    • B32B17/10247—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165—Functional features of the laminated safety glass or glazing
    • B32B17/10247—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons
    • B32B17/10256—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons created by printing techniques
    • B32B17/10275—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons created by printing techniques on interlayer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/1077—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing polyurethane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10807—Making laminated safety glass or glazing; Apparatus therefor
    • B32B17/10899—Making laminated safety glass or glazing; Apparatus therefor by introducing interlayers of synthetic resin
    • B32B17/10935—Making laminated safety glass or glazing; Apparatus therefor by introducing interlayers of synthetic resin as a preformed layer, e.g. formed by extrusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/0041—Digital printing on surfaces other than ordinary paper
    • B41M5/0047—Digital printing on surfaces other than ordinary paper by ink-jet printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/0041—Digital printing on surfaces other than ordinary paper
    • B41M5/0064—Digital printing on surfaces other than ordinary paper on plastics, horn, rubber, or other organic polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
    • B41M7/0027—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using protective coatings or layers by lamination or by fusion of the coatings or layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C3/00—Processes, not specifically provided for elsewhere, for producing ornamental structures
    • B44C3/02—Superimposing layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00—Processes for producing special ornamental bodies
    • B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
    • B44C5/0407—Ornamental plaques, e.g. decorative panels, decorative veneers containing glass elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00—Processes for producing special ornamental bodies
    • B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
    • B44C5/0446—Ornamental plaques, e.g. decorative panels, decorative veneers bearing graphical information
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44F—SPECIAL DESIGNS OR PICTURES
    • B44F1/00—Designs or pictures characterised by special or unusual light effects
    • B44F1/06—Designs or pictures characterised by special or unusual light effects produced by transmitted light, e.g. transparencies, imitations of glass paintings
    • B44F1/066—Designs or pictures characterised by special or unusual light effects produced by transmitted light, e.g. transparencies, imitations of glass paintings comprising at least two transparent elements, e.g. sheets, layers
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/001—General methods for coating; Devices therefor
    • C03C17/002—General methods for coating; Devices therefor for flat glass, e.g. float glass
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5263—Macromolecular coatings characterised by the use of polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • B41M5/5281—Polyurethanes or polyureas
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/40—Coatings comprising at least one inhomogeneous layer
    • C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
    • C03C2217/46—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
    • C03C2217/48—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase having a specific function
    • C03C2217/485—Pigments
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24851—Intermediate layer is discontinuous or differential
    • Y10T428/24868—Translucent outer layer
    • Y10T428/24876—Intermediate layer contains particulate material [e.g., pigment, etc.]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Ink Jet (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

一种制作带图象的层压材料(10)的方法和装置。用基于溶剂的墨、漆或染料系统把一图象(18)印刷在一聚乙烯醇缩丁醛夹层(16)上。该夹层(16)把两片材料(12、14)连接形成该层压制品。

Description

带图象的层压材料
技术领域
本发明涉及带图象的层压材料的制作，可从该材料的一面或两面看到该图象。该材料可用任何合适基质如玻璃、聚碳酸酯、丙烯酸、纤维素醋酸丁酸酯(CAB)或其他热塑树脂制成。该图象可为图案、艺术作品、书写标记或任何其他可见物。
背景技术
层压材料，特别是层压玻璃，作为建筑材料有许多应用。比方说可用它们制作窗户、墙壁、门和屏风。也可用它们制作咖啡桌和其它类小家具。层压材料由于较之普通玻璃片其固有的安全性而用于多种场合。层压材料一般用一聚乙烯醇缩丁醛夹层或一基于聚醚的脂族热塑聚氨酯夹层如由Morton International，Inc.生产的PE399Krystalflex薄膜等将两张材料片连接而成。该生产过程一般包括两个步骤。在一个步骤中把该夹层置于这两张材料片之间后在通过压辊的同时加热，两压辊挤压这两张材料片而与该软化的夹层接触。另一个步骤是在一高压蒸锅中对如此形成的层压制品进行处理，完成该粘合过程。
在许多应用场合要求在该层压材料上生成某种图象。该图象可起装饰作用，也可以通过部分地或者完全地阻挡通过该层压板观看起到一功能性目的。迄今为止，制作带图象的层压材料的各种方法存在严重的实际问题。在层压材料如玻璃上形成图象的一种方法是用丝网印刷把该图象印刷到该制成的层压材料上。这一工艺很麻烦，所能生成的图象在颜色和细节方面受到限制。例如，多色图象需要分步印刷各种颜色。此外，图象只能形成在单块玻璃片上，这在实际上意味着，无法用通常方式形成图象，以便其后可任意切割玻璃片。
还有用其他方法在层压材料上形成图象的。这些方法是把其上有图象的一层材料引入该层压板中。该方法的缺点是，各张材料片之间的粘合强度直接受到影响。这是因为其上有图象的材料造成粘合面积减小。
在美国专利No.4,968,553所述另一种方法中，用一张印刷有图象的聚氨酯与两张玻璃片层压在一起形成一张带图象的层压制品。该张聚氨酯用基于非溶剂的墨印刷，从而不与尿烷起化学反应。这一工艺的商业应用由于需要使用聚氨酯片而非普通夹层如PVB而受到限制。
巴西专利申请9104893所述一种方法是直接在PVB夹层上印刷。该申请在层压前使用丙烯酸漆在PVB上形成一图象。但丙烯漆在层压时非常不利于该夹层与相邻玻璃表面之间的粘合。
发明内容
本发明的一个方面是提供一种制作带图象的层压材料的方法，包括如下步骤：使用基于溶剂的墨，油漆或者染料系统在一张夹层片的第一表面上形成一图象、把该片夹层置于两张材料片之间、通过激活该夹层把这两张材料片连接形成该层压制品。
本发明的第二方面是提供一张带图象的层压板，该层压板包括由一夹层连接的两张材料片，该图象由基于溶剂的墨、漆或染料系统形成在该夹层的第一表面上。
本发明的第三方面是提供一种夹层，在该夹层的第一表面上用基于溶剂的墨、漆或染料系统形成一图象。
该连接步骤可包括把另外的一层或多层夹层连接到该带图象夹层上。在本发明一种形式中，另外一夹层连接到该带图象夹层的带图象表面上。在本发明的另一种形式中，另外的夹层可连接到带图象夹层的两个表面上。也可在带图象夹层的两个表面上连接多层夹层。
这些夹层最好作为层压过程的一部分互相连接。
最好是，该夹层由聚乙烯醇缩丁醛制成。该夹层也可由基于聚醚的脂族热塑聚氨酯等制成。
本发明的另一方面提供一种制作带图象的层压材料的方法，包括下列步骤：机械稳定一张夹层片、在该夹层的第一表面上形成一图象、除去该机械稳定、把该夹层置于两张材料片之间、然后通过激活该夹层把这两张材料片连接成该层压制品。
该连接步骤可包括把另外一层或多层夹层连接到该带图象夹层上。在本发明一种形式中，另外一层夹层连接到该带图象夹层的带图象表面上。在本发明的另一种形式中，另外的夹层可连接到带图象夹层的两个表面上。也可在带图象夹层的两个表面上连接多层夹层。
这些夹层最好作为层压过程的一部分互相连接。
在这方面最好是，这些夹层由聚乙烯醇缩丁醛制成。这些夹层也可由基于聚醚的脂族热塑聚氨酯如PE399 Krystalflex薄膜制成。该图象最好使用基于溶剂的墨、漆或染料系统形成在该夹层上。这些系统可包括颜料和/或其他添加剂。
在本发明一种很优选的形式中，图象使用压电的转辙指令数字印刷方法印刷在该夹层上。这种方法使用基于溶剂的墨、漆或染料系统。
在本发明的一种形式中，用该夹层与一可除去膜片或基质之间的机械连接实现该机械稳定性。该可除去膜片可采用任何合适形式。该可除去膜片可为一张直接粘在该夹层上的衬纸。该可除去膜片也可为一张以任何合适方式粘接在该夹层边缘上的合适片材料。例如可用胶带进行该粘接。可除去的该衬底的合适材料也包括纤维强化乙烯树脂。在某些工艺中该机械稳定也可通过一连接提供给该印刷机的一部件上。
该可除去膜片或基质在图象形成过程中绷紧该夹层，使得夹层在形成图象的工艺期间被处理而不发生变形。适合于形成图象的工艺需要以一致的速率在一系统中移动该夹层，防止印刷时出现“磁头痕迹和遗漏”。此外，适合于在该夹层上形成图象的许多工艺涉及到使用热量。该夹层对热很敏感，在温度为60℃或以上时一般会失去其机械强度的大部分。使用衬底膜片或基质可在使用热量的系统中处理该夹层而不拉长或损坏该夹层。
本领域普通技术人员显然可知，本说明书中使用的术语“基于溶剂的墨、漆或染料系统”指这样一种系统，在该系统中，一合适有机溶剂或多种溶剂中含有着色剂。例如，在使用墨的情况下，一颜料扩散在一有机溶剂或多种溶剂中。这些墨包括所谓的“油基”墨。
用基于溶剂的墨、漆或染料系统在该夹层上形成图象不会影响该夹层与片材之间的粘合过程。其原因是，基于溶剂的墨、漆或染料系统蚀刻入夹层的表面，造成该夹层与相邻片材分离、从而不与相邻片材粘合的区域。这与例如汇集在夹层表面、从而使夹层表面网状化的基于丙烯酸的颜料载体成鲜明对照。这造成夹层的无法与相邻片材粘合的区域，从而无法形成层压制品。
在使用基于溶剂的墨、特别是油基墨的情况下，该有机溶剂被形成用来对颜料牢牢粘接到该夹层上起到重大作用。
在本发明的一种形式中使用另外夹层可提高该层压制品的粘合强度。这些另外的夹层可连接在该带图象夹层的一个表面上。该表面可为其上有图象的表面。
另外的夹层也可连接到带图象夹层的任一表面上或其两个表面上。
另外的夹层可作为层压过程的一部分连接到带图象夹层上。即，这些夹层(包括带图象夹层)一起放置或叠置在两张层压材料之间，从而当层压整个夹层-片材的夹心制品时粘合在一起。
此外，另外的夹层还可保护图象免受光、特别是阳光中的紫外线的照射。这有助于防止图象中的墨褪色、保持图象清晰、提高图象在该层压材料中的寿命。
最好是，在该层压工艺中，使用该夹层之前，使该图象固化在该夹层上。根据环境温度，在某些情况下固化时间达24小时或24小时以上是有利的。这一改进的原因据信是由于溶剂进一步蒸发，从而余下的墨、漆或染料进一步蚀刻入该夹层中。
可在任何合适的夹层上形成该图象。例如，图象可印刷在这样的夹层上，即一旦层压在两张材料片之间就透明的夹层上。也可使用比方说经上色而变得不透明或局部不透明的夹层。可使用适合于层压特殊片材的任何厚度的夹层。多个常用夹层的厚度为0.38mm的倍数。
下面结合附图和例子例示、说明本发明。
附图简要说明
图1为本发明一张层压安全玻璃第一实施例的示意图，为说明起见示出局部切去的各层；
图2为图1所述该张安全玻璃的示意剖面图；
图3为本发明一张层压安全玻璃第二实施例的示意图，为说明起见示出局部切去的各层；
图4为图3所述该张安全玻璃的示意剖面图；
图5为本发明一张层压安全玻璃第三实施例的示意图，为说明起见示出局部切去的各层；
图6为图5所述该张安全玻璃的示意剖面图；
图7为本发明一张层压安全玻璃第四实施例的示意图，为说明起见示出局部切去的各层；
图8为图7所述该张安全玻璃的示意剖面图；
图9为实现本发明方法所使用的第一印刷机的端视示意图；
图10为图9所示印刷机的正视图；
图11为实现本发明方法所使用的第二印刷机的端视示意图；
图12为类似图11的视图，示出如何把夹层传送给该印刷机；
图13为实现本发明方法所使用的第三印刷机的端视示意图；
图14为实现本发明方法所使用的第四印刷机的端视示意图；
图15为图14所示印刷机的端视示意图；
图16为图15的局部放大图；以及
图17为一玻璃层压工艺中的设备和步骤的示意图。
本发明最佳实施方式
以下说明和例子指按照本发明和使用本发明方法使用PVB夹层制作层压安全玻璃制品。本发明同样适用于其他层压材料和使用不同形式的夹层。
图1-8示出按照本发明形成的带图的层压安全玻璃的四个不同实施例。形成图象的过程下面结合图9-16说明，层压过程结合图17说明。
参见图1和2，层压安全玻璃10由其上使用基于溶剂的墨印刷一图象18的一PVB夹层16连接两张玻璃片12、14而成。
图3和4示出本发明一张层压安全玻璃的第二实施例。各附图中相同部件用同一标号表示。在本发明该形式中，其上不印刷图象的另外两层PVB夹层20、22插入在夹层16与对应玻璃片12、14之间。即，夹层16的其上印刷有图象18的表面与和该表面相邻的该张玻璃片12之间有第二张夹层片20。第三张夹层片22插入在夹层16的与其上有图象18的表面相反的表面与和该相反表面相邻的该张玻璃片14之间。
图5和6示出本发明一张层压玻璃的第三实施例。各附图中相同部件用同一标号表示。在本发明该形式中，另外只有一张其上不印刷图象的PVB夹层插入在夹层16的其上印刷有图象18的表面与相邻玻璃片12之间。
图7和8示出本发明一张层压安全玻璃的第四实施例。各附图中相同部件用同一标号表示。在本发明该形式中，另外一张PVB夹层24使用基于溶剂的墨印刷有图象18。印刷有图象18的夹层16与24相邻，另一张PVB夹层20插入在夹层16的其上印刷有图象18的表面和相邻玻璃片12之间。可用其上印刷有相间距图象18的两层夹层16、24提供当观看层压安全玻璃10时，在整个图象中的更大的深度。
图9-1 6示出可用来在一PVB夹层上形成图象的一些喷墨印刷机。这些印刷机为市场上有售的宽型喷墨印刷机。本领域普通技术人员显然可知，为了使用这些印刷机在任何基质上印刷一图象，必需以通常方式向该印刷机提供合适图象数据。在大多数情况下，这涉及首先获得或准备一数字化图象。可在一普通计算机上从一存储介质如CD或使用普通扫描技术扫描一原始图象来生成合适数字图象。使用合适计算机程序如AdobePhotoshop生成一PostScript文件。可通过合适界面用PostScript文件向该印刷机提供复制该图象所需数据。在某些情况下，在向该印刷机输出复制图象所需数据前可使用辅助软件如PosteshopRIP(光栅图象处理)定标和矫正颜色。作为本发明方法的一部分，下面说明四种不同印刷机的特征及其使用。
图9和10简示出一称为MMT(Metro Media TechnologiesInternational Inc.)喷漆系统的宽型喷墨印刷机的各部件。该印刷机使用大转鼓32，该大转鼓32用辐条36可转动地支撑在一轴38上。该印刷机的机架34紧靠一装在一滑架42上的印刷头40支撑该转鼓。如图10中箭头46所示，该滑架42响应印刷机控制装置(未示出)而轴向移动印刷头40。印刷头40如所公知地受印刷机电子器件(未示出)驱动。
在该过程中PVB夹层16因贴在转鼓32表面上而获得机械稳定。为此可把夹层16铺在转鼓上后使用虚线44所示普通胶带把该夹层的边缘粘在转鼓32上。我们发现，把PVB夹层如此连接在印刷机30的转鼓32上即可使它获得足够的机械稳定，从而可如所公知地随着转鼓32在印刷头40旁的转动进行精确印刷。
喷墨印刷机30使用基于溶剂的汽车漆，该溶剂为MIBK(甲基·异丁基酮)。
图10、11简示出一Idanit喷墨印刷机50。该喷墨印刷机5与结合图9和10所述印刷机相似，即一合适轴60支撑一转鼓58。一由一底座54和立柱52构成的机架把两印刷头56置于紧靠转鼓58的位置上。在该例中转鼓58上打有一连串孔(未示出)，真空作用在转鼓内部。用真空保持并机械稳定PVB夹层16。如图12所示，夹层16从一供料筒62经引导辊6 4装到该转鼓上。在大多数情况下，夹层16的前边缘首先用胶带粘在转鼓上，防止夹层与印刷头56接触。一旦一大段夹层16包在转鼓上，由孔(未示出)施加的真空保持夹层，然后如所公知，随着夹层16因转鼓58的转动而移动，印刷头56进行印刷。
印刷机50使用任何合适的基于溶剂的颜料墨。
图13简示出一压电的转辙指令的宽型Vutek5300数字印刷机。该印刷机由Vutek Inc.制造。
印刷机70运行时，待印刷的材料在一连串滚轮上通过并通过一印刷头90。印刷机70把待印刷材料张紧在滚轮82与84之间而提供一稳定的印刷表面。由于夹层16的特性，它在印刷过程中必需稳定。为此使用一与夹层16一起通过印刷机70的牺牲片材72。该牺牲片材72可为纤维强化的乙烯树脂或纸或在中等张力下不伸长的任何其他材料。在某些情况下，夹层16可用胶带粘在牺牲卷材72上。在其他情况下，夹层16与卷材72同时穿过印刷机即可提供所需机械稳定性。
如该图所示，夹层16由一座落在三个滚轮78中两个滚轮上的供料筒74供应。一牺牲支撑片材72由一也座落在滚轮78中两个滚轮上的类似筒76供应。这可确保两材料以大致相同的速度供应。夹层16和片材72在绕过在其间进行印刷的定位滚轮82和84前绕过张紧滚轮78和80。绕过滚轮84后夹层16、片材72在卷绕到卷取滚轮88前绕过另一滚轮86。印刷机70在滚轮82与84之间张紧片材72而提供稳定的印刷表面。夹层16紧贴片材，而片材72保持张紧，使得夹层16不受很大张力。与任何其他进行精确印刷的基质一样，这可确保夹层16在印刷头90前方通过时不伸长或变形。
印刷机70使用基于溶剂的颜料墨如可从Inkwear Inc.购得的墨。
一种称为ULTRAVU-3的合适墨可有如下颜色：
青色       淡青色
洋红IID    淡洋红HD
黄色       黑色
橘黄色     绿色
这些墨含有80％的乙二醇-丁醚乙酸、20％的环己酮、10％的甲基-2-吡咯烷酮(淡洋红HD)和制造商未公开的其他成分。
为另一种称为Arizona印刷机的类似印刷机生产的墨包括如下成分：
成分名称                                  百分比
2-buxtoxethyl乙酸                         70％
丙醇，1(或2)-(2-甲氧亚甲基乙氧基)-乙酸    30％
炭墨                                      1.0-5.0％
乙烯基氯-乙基乙酸聚合物                   1.0-5.0％
丙烯酸共聚物                              1.0-5.0％
NJ TS RN 12307-5038P                      1.0-5.0％
图14-16简示出一平台式压电的转辙指令的喷墨印刷机如台湾Eastech生产的Mutoh Falcon Jet 6100。该Falcon Jet 6100基本上为一台标准的Mutoh Falcon Jet 6000，只是印刷头稍有改动。该改动预热了印刷头中的墨以改变墨的粘度，使得墨合适流动。这一改动对于在该印刷机中使用油基墨是必要的。
如附图所示，平台式印刷机100有一支撑一上台板106的机架101。存储在一供料筒110上的夹层16越过台板106传给卷取辊112。夹层由分别位于印刷头108附近夹层上方和下方的一对夹辊102和104传动。下辊102如通常那样受驱而使夹层16以受控速度向前通过印刷头108。夹层16在夹辊104和102附近的平台106上的定位，机械稳定该夹层以受印刷头的印刷。即，夹层基本不受张力，可与印刷头108精确对齐，从而可360dpi或720dpi在夹层上印刷高质量图象。Mutoh Falcon Jet 6100印刷机通常被提供有来自一合适计算机的数据。为了驱动该印刷机，该计算机使用如OnyxPostershop的软件把postscript数据转换成光栅图象处理格式供该印刷机使用。MutohFalcon Jet 6100使用的墨由Eastech提供，其成分如下：
着色剂           8％
乙醇乙酯         30％
乙酸乙酯         8.5％
甲基乙基酮       7％
N-丁基乙酸       17.5％
Ethycese乙二醇-甲基     29％
一旦用上述任一技术在夹层上形成图象，就如所公知地用该夹层形成一张层压玻璃。图17简示出该层压过程。
该层压过程包括把玻璃片原料120从一台122上方传到一清洗机124。已印刷有图象的聚乙烯缩醇丁醛夹层通常在约6-7℃的受控湿度的温度中被存储在一存储区126中。玻璃片120传到一保持环境清洁的储藏室128中一台130上。然后把它们传到一传递台132上，在该传递台上，把带图象夹层叠置在第一张玻璃片的表面上。第二张玻璃片叠置到带图象夹层顶面上与第一张玻璃片对齐，形成一玻璃夹层(带图象)的玻璃夹层板。
也可把任何所需另外夹层插入在带图象夹层与各玻璃片之间。例如，可把一夹层叠置在第一玻璃片上，然后是带图象夹层、另一夹层和第二玻璃片。从而形成一玻璃片-夹层-带图象夹层-夹层-玻璃片夹层板。
该夹层板通过一工作温度为约200℃的炉子134后从压力约为10bar的两压辊之间通过，使得夹层软化、与两玻璃片粘接在一起。压辊确保除去该层压物中空气。然后把如此形成的夹层板传送到一工作在135℃温度、11.5bar压力下的高压蒸锅中一般高压蒸约3.5小时。
例1
使用结合图1和2所述单张0.38mm厚PVB夹层制备层压玻璃样本。该张玻璃片厚3mm。用使用结合图9和10(样本A)和图13(样本B)所述印刷机和方法制备的夹层制备样本。使用上述公知层压过程生成玻璃层压制品。所得玻璃层压制品的两种样本均有良好层压强度。夹层上的图象质量优越、很少变形。
例2
用使用结合图14-16所述转辙指令的平台式印刷机印刷的PVB夹层制备层压玻璃样本。使用上述公知层压过程按照结合图3和4所述实施例形成该层压制品(三层夹层，带图象夹层两表面上各有一夹层)。
下述层压图象质量优越、不变形。
按照澳大利亚层压安全玻璃标准AS2208-1996对这些样本进行测试，包括沸腾测试和碎裂测试。分别对夹层上印刷浅色和深色图象的层压玻璃制品进行这些测试。深色图象相当于夹层单位面积上的墨、漆或染料的数量大。结果这些样本都符合该澳大利亚标准。
尽管按照本发明制作的上述某些例子符合安全玻璃或层压玻璃A级应用场合澳大利亚测试标准，但本发明不限于这些应用场合。本发明玻璃也可用于无需符合安全玻璃或A级标准的其他应用场合。
此外如上所述，尽管所述例子涉及使用玻璃片制作层压玻璃，但在本发明范围内本发明可使用其他各种适合于层压的材料如聚碳酸酯、丙烯酸、CAB和其他热塑树脂。
该制作过程中可使用不同材料片获得同样结果。例如，可用一张聚碳酸酯和一张玻璃片形成聚碳酸酯-夹层-玻璃夹层板后粘接成层压制品。
此外，在本发明范围内还可把基于聚醚的脂族热塑聚氨酯之类合适材料用作夹层。例如可用PE399 Krystalflex薄膜形成夹层。
以上只是说明了本发明某些实施例，可在本发明范围内作出改动。

Claims (42)

1.一种带图象的层压材料制作方法，包括如下步骤：使用基于溶剂的墨、漆或染料系统在一张夹层片的第一表面上形成一图象、把该张夹层片插入在两张材料片之间，以及通过激活该夹层把这两张材料片连接成层压制品。
2.按权利要求1所述的方法，其特征在于，连接所述两张材料片的步骤包括把第二张夹层片插入在第一表面与与第一表面相邻的该张材料片之间。
3.按权利要求2所述的方法，其特征在于，连接所述两张材料片的步骤包括把第三张夹层片插入在与第一表面相反的该夹层的表面和与该相反表面相邻的该张材料片之间。
4.按权利要求1所述的方法，其特征在于，包括下列步骤：使用基于溶剂的墨、漆或染料系统分别在至少两张夹层片的第一表面上形成图象后把至少两张夹层片插入在所述两张材料片之间。
5.按上述任一权利要求所述的方法，其特征在于，包括下列步骤：在形成所述图象过程中机械稳定该张夹层片。
6.按权利要求5所述的方法，其特征在于，用压电的转辙指令数字印刷过程形成所述图象。
7.按权利要求6所述的方法，其特征在于，使该夹层通过一对位于所述数字印刷过程中使用的印刷头附近的夹辊，从而实现所述机械稳定步骤。
8.按权利要求5所述的方法，其特征在于，在形成图象过程中用一可除去膜片支撑该夹层，从而实现所述机械稳定步骤。
9.按权利要求8所述的方法，其特征在于，把该夹层临时连接在该膜片上。
10.按权利要求8或9所述的方法，其特征在于，该膜片选自纤维强化乙烯树脂和纸。
11.按权利要求5所述的方法，其特征在于，把该夹层可取下地连接在一印刷机的一部件上，从而实现所述机械稳定步骤。
12.按权利要求11所述的方法，其特征在于，该部件为一转鼓。
13.按上述任一权利要求所述的方法，其特征在于，所述两张材料片为玻璃。
14.按上述任一权利要求所述的方法，其特征在于，该夹层为聚乙烯醇缩丁醛或基于聚醚的脂族热塑聚氨酯。
15.一种带图象的层压安全玻璃制作方法，包括如下步骤：使用基于溶剂的墨、漆或染料系统在一张夹层片的第一表面上形成一图象，把该张夹层片插入在两张玻璃片之间以及通过加热该夹层连接这两张玻璃片。
16.按权利要求15所述的方法，其特征在于，用压电的转辙指令数字印刷过程形成所述图象。
17.一种带图象的层压材料制作方法，包括如下步骤：机械稳定一张夹层片，在该夹层的第一表面上形成一图象，除去该机械稳定性，把该张夹层片插入在两张材料片之间以及通过激活该夹层把这两张材料片连接成层压制品。
18.按权利要求17所述的方法，其特征在于，使该夹层通过一对位于在所述数字印刷过程中使用的印刷头附近的夹辊，从而实现所述机械稳定步骤。
19.按权利要求17所述的方法，其特征在于，在形成图象过程中用一可除去膜片支撑该夹层，从而实现所述机械稳定步骤。
20.按权利要求19所述的方法，其特征在于，把该夹层临时连接在该膜片上。
21.按权利要求19或20所述的方法，其特征在于，该膜片选自纤维强化乙烯树脂和纸。
22.按权利要求17所述的方法，其特征在于，把该夹层可取下地连接在一印刷机的一部件上，从而实现所述机械稳定步骤。
23.按权利要求22所述的方法，其特征在于，该部件为一转鼓。
24.按权利要求17-23中任一权利要求所述的方法，其特征在于，使用基于溶剂的墨、漆或染料系统形成所述图象。
25.按权利要求24所述的方法，其特征在于，用压电转辙步骤的数字印刷过程形成所述图象。
26.按权利要求17-25中任一权利要求所述的方法，其特征在于，连接所述两张材料片的步骤包括把第二张夹层片插入在第一表面和与第一表面相邻的该张材料片之间。
27.按权利要求26所述的方法，其特征在于，连接所述两张材料片的步骤包括把第三张夹层片插入在与第一表面相反的该夹层的表面和与该相反表面相邻的该张材料片之间。
28.按权利要求17所述的方法，其特征在于，包括下列步骤：使用基于溶剂的墨、漆或染料系统分别在至少两张夹层片的第一表面上形成图象，把至少两张夹层片插入在所述两张材料片之间。
29.按权利要求17-28中任一权利要求所述的方法，其特征在于，所述两张材料片为玻璃。
30.按权利要求17-29中任一权利要求所述的方法，其特征在于，该夹层为聚乙烯醇缩丁醛或基于聚醚的脂族热塑聚氨酯。
31.一种带图象的层压安全玻璃制作方法，包括如下步骤：机械稳定一张热软化夹层，使用基于溶剂的墨、漆或染料在该夹层的第一表面上形成一图象，除去该机械稳定性，把该夹层插入在两张玻璃片之间以及通过加热该夹层把这两张玻璃片连接成层压安全玻璃。
32.按权利要求31所述的方法，其特征在于，用压电转辙指令的数字印刷过程形成所述图象。
33.一张带图象的层压片，包括由一夹层连接的两张材料片，该图象用基于溶剂的墨、漆或染料系统形成在该夹层的第一表面上。
34.按权利要求33所述的带图象的层压片，其特征在于，进一步包括插入在该第一表面和与该第一表面相邻的该张材料片之间的第二张夹层片。
35.按权利要求34所述的带图象的层压片，其特征在于，进一步包括插入在与所述第一表面相反的该夹层的表面和与该相反表面相邻的该张材料片之间的第三张夹层片。
36.按权利要求33所述的带图象的层压片，其特征在于，进一步包括至少另一张插入在所述两张材料片之间的夹层，用基于溶剂的墨、漆或染料系统在所述另一张或多张夹层片的第一表面上形成相应另外的图象。
37.按权利要求33-36中任一权利要求所述的带图象的层压片，其特征在于，所述两张材料片为玻璃。
38.按权利要求33-37中任一权利要求所述的带图象的层压片，其特征在于，该夹层为聚乙烯醇缩丁醛或基于聚醚的脂族热塑聚氨酯。
39.一种带图象的层压安全玻璃，包括由一热软化夹层连接的两张玻璃片，该图象用基于溶剂的墨、漆或染料系统形成在该夹层的第一表面上。
40.按权利要求39所述的带图象的层压安全玻璃，其特征在于，该夹层为聚乙烯醇缩丁醛或基于聚醚的脂族热塑聚氨酯。
41.一夹层，其第一表面上使用基于溶剂的墨、漆或染料系统形成有一图象。
42.其第一表面上有一图象的一夹层，其中，该夹层为聚乙烯醇缩丁醛或基于聚醚的脂族热塑聚氨酯。
CNA018182852A 2000-09-01 2001-09-03 带图象的层压材料 Pending CN1473114A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310388396.7A CN103552321B (zh) 2000-09-01 2001-09-03 带图象的层压材料

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
AUPQ9830 2000-09-01
AUPQ9830A AUPQ983000A0 (en) 2000-09-01 2000-09-01 Image carrying laminated glass
AUPR0567A AUPR056700A0 (en) 2000-10-04 2000-10-04 Image carrying laminated material
AUPR0567 2000-10-04
AUPR2194 2000-12-20
AUPR2194A AUPR219400A0 (en) 2000-12-20 2000-12-20 Image carrying laminated material

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN201310388396.7A Division CN103552321B (zh) 2000-09-01 2001-09-03 带图象的层压材料

Publications (1)

Publication Number Publication Date
CN1473114A true CN1473114A (zh) 2004-02-04

Family

ID=27158241

Family Applications (2)

Application Number Title Priority Date Filing Date
CN201310388396.7A Expired - Lifetime CN103552321B (zh) 2000-09-01 2001-09-03 带图象的层压材料
CNA018182852A Pending CN1473114A (zh) 2000-09-01 2001-09-03 带图象的层压材料

Family Applications Before (1)

Application Number Title Priority Date Filing Date
CN201310388396.7A Expired - Lifetime CN103552321B (zh) 2000-09-01 2001-09-03 带图象的层压材料

Country Status (9)

Country Link
US (1) US9403346B2 (zh)
EP (2) EP1741552A1 (zh)
JP (1) JP5138142B2 (zh)
CN (2) CN103552321B (zh)
AU (1) AU2001285590B2 (zh)
CA (1) CA2420870C (zh)
DE (2) DE20122692U1 (zh)
NZ (1) NZ524898A (zh)
WO (1) WO2002018154A1 (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102407631A (zh) * 2011-10-09 2012-04-11 常熟市华夏建筑节能材料有限公司 一种夹层玻璃
CN107073901A (zh) * 2013-12-12 2017-08-18 爱克发印艺公司 层压安全玻璃

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6824868B2 (en) * 2002-04-30 2004-11-30 Solutia, Inc. Digital color-design composite for use in laminated glass
WO2004011271A1 (en) * 2002-07-31 2004-02-05 E.I. Du Pont De Nemours And Company Ink-jet printed rigid interlayer and a process for preparing same
US20070087137A9 (en) * 2003-06-26 2007-04-19 Elwakil Hamdy A Decorative laminated safety glass
DE60317083T2 (de) * 2002-08-20 2008-08-07 E.I. Du Pont De Nemours And Co., Wilmington Verbundsicherheitsdekorglas
US7041163B2 (en) 2003-03-28 2006-05-09 E.I. Du Pont De Nemours And Company Non-aqueous inkjet ink set
WO2005014280A1 (en) * 2003-08-07 2005-02-17 E.I. Dupont De Nemours And Company Decorative laminated safety glass utilizing a rigid interlayer and a process for preparing same
DE602005016785D1 (de) 2004-03-02 2009-11-05 Du Pont Mehrschichtdekorsicherheitsglas
WO2006010195A1 (en) * 2004-07-29 2006-02-02 Digiglass Pty Ltd Display structures
US20070172636A1 (en) * 2005-12-30 2007-07-26 Smith Rebecca L Decorative sheets having enhanced adhesion and laminates prepared therefrom
US7625627B2 (en) 2005-12-30 2009-12-01 E.I. Du Pont De Nemours And Company Decorative polyvinyl butyral solar control laminates
US20070172637A1 (en) * 2005-12-30 2007-07-26 Hayes Richard A Decorative sheets having enhanced adhesion and penetration resistant laminates prepared therefrom
US20070196630A1 (en) * 2005-12-30 2007-08-23 Hayes Richard A Decorative solar control laminates
US20080206504A1 (en) * 2007-02-28 2008-08-28 Richard Allen Hayes Decorative Safety Glass
US20080233352A1 (en) * 2007-03-19 2008-09-25 Smith Rebecca L High contrast decorative sheets and laminates
US20080233377A1 (en) * 2007-03-19 2008-09-25 Smith Rebecca L High contrast high strength decorative sheets and laminates
US20080233371A1 (en) * 2007-03-19 2008-09-25 Richard Allen Hayes Decorative safety glass
US20080233279A1 (en) * 2007-03-19 2008-09-25 Smith Rebecca L High contrast decorative films and laminates
US20080264558A1 (en) * 2007-04-25 2008-10-30 Richard Allen Hayes Decorative safety glass
US20080280076A1 (en) * 2007-05-11 2008-11-13 Richard Allen Hayes Decorative safety glass
US20080286542A1 (en) * 2007-05-17 2008-11-20 Richard Allen Hayes Decorative safety glass
DE202008005722U1 (de) * 2008-04-24 2009-09-03 Zander, Kristof Bildträger
TWI565646B (zh) 2010-11-30 2017-01-11 康寧公司 藉由張緊交插材料捲繞玻璃帶
DE102011004500A1 (de) * 2011-02-22 2012-08-23 Bayerische Motoren Werke Aktiengesellschaft Verfahren zur Herstellung einer bedruckten Fahrzeug-Verbundscheibe
EP2711346A1 (en) 2012-09-25 2014-03-26 Falco Technologies BVBA Multi-layered panel and method for manufacturing a multi-layered panel
CN104822533B (zh) * 2012-11-28 2017-06-30 瓦林格创新股份有限公司 利用数码印刷制造建筑镶板的方法
WO2014123766A1 (en) 2013-02-05 2014-08-14 3M Innovative Properties Company Graphic article
EP2905127A1 (de) * 2014-02-05 2015-08-12 Kuraray Europe GmbH Verfahren zur Herstellung von Verbundglaslaminaten aus einem Schichtkörper enthaltend eine weichmacherhaltige und eine weichmacherarme Polyvinylacetalfolie
US10232592B2 (en) 2014-12-18 2019-03-19 Agfa Nv Laminated glass articles
DE102016014469A1 (de) * 2016-10-21 2018-04-26 Schott Ag Dekorblende aus Flachglas
WO2018213213A1 (en) * 2017-05-15 2018-11-22 Corning Incorporated Laminate having organic ink decoration and high impact resistance
US20220001650A1 (en) * 2018-10-18 2022-01-06 Corning Incorporated Method of adhesive selection for cold forming product and process
DE102019109578A1 (de) * 2019-04-11 2020-10-15 Dr. Ing. H.C. F. Porsche Aktiengesellschaft Fahrzeugverbundglas
CN110154621A (zh) * 2019-04-26 2019-08-23 河北浩艺文化发展有限公司 透明亚克力丝网印刷挂画的制作工艺
WO2021254976A1 (de) 2020-06-16 2021-12-23 Saint-Gobain Glass France Verbundscheibe
WO2021254910A1 (de) 2020-06-16 2021-12-23 Saint-Gobain Glass France Verbundscheibe
CN114126857A (zh) 2020-06-16 2022-03-01 法国圣戈班玻璃厂 具有声阻尼性能的楔形多层中间层
CN112109480B (zh) * 2020-08-24 2022-04-29 浙江天画家居用品有限公司 一种立体线条装饰画的制作方法
EP4285178A1 (de) 2021-01-26 2023-12-06 Saint-Gobain Glass France Fahrzeugscheibe für head-up-display
DE202022002921U1 (de) 2021-06-25 2024-01-10 Saint-Gobain Glass France Verbundscheibe mit Funktionsfolie mit opakem Aufdruck
WO2023225194A1 (en) * 2022-05-18 2023-11-23 Acr Ii Glass America Inc. Glazing having an area for collection of information

Family Cites Families (85)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2739080A (en) * 1951-08-28 1956-03-20 Monsanto Chemicals Process for dyeing a sheet of plasticized polyvinyl butyral resin and ink therefor
US3388032A (en) 1965-01-13 1968-06-11 Mobay Chemical Corp Laminated safety glass
US3563739A (en) 1965-09-13 1971-02-16 Polaroid Corp Novel products,processes and compositions comprising metal-complexed dye developers
FR1485713A (fr) * 1966-05-10 1967-06-23 Panneaux plastiques de vitrage avec décoration intangible
US3437552A (en) 1967-08-01 1969-04-08 Du Pont Glass laminate and interlayer
US3458388A (en) 1967-08-01 1969-07-29 Du Pont Glass-polyurethane-polyvinylbutyral-polyurethane-glass laminate
US3591406A (en) * 1969-10-17 1971-07-06 Du Pont Process for band-tinting plasticized polyvinyl butyral sheeting and product therefrom
US3629044A (en) * 1969-12-22 1971-12-21 Albert J Sanger Vehicle windshield carrying vehicle serial number
JPS5645777B2 (zh) 1973-10-11 1981-10-28
US3973058A (en) * 1974-12-23 1976-08-03 Monsanto Company Method for printing interlayers for laminated safety glass
US4035549A (en) * 1975-05-19 1977-07-12 Monsanto Company Interlayer for laminated safety glass
US4138284A (en) 1976-06-10 1979-02-06 Ppg Industries, Inc. Method of forming graded shade band on substrate
US4173672A (en) * 1977-09-06 1979-11-06 Mannheim Jose R Decorated safety glass
US4230775A (en) † 1977-12-16 1980-10-28 E. I. Du Pont De Nemours And Company Polyvinyl butyral ink formulation
US4391867A (en) 1977-12-16 1983-07-05 E. I. Du Pont De Nemours & Co. Polyvinyl butyral ink formulation
US4168254A (en) 1978-05-25 1979-09-18 American Can Company Videojet ink composition
JPS5632351A (en) 1979-08-23 1981-04-01 Sekisui Chem Co Ltd Manufacture of patterned laminated glass
US4339567A (en) 1980-03-07 1982-07-13 Ciba-Geigy Corporation Photopolymerization by means of sulphoxonium salts
JPS5946903B2 (ja) 1980-03-12 1984-11-15 積水化学工業株式会社 模様入り合せガラスの製造方法
US4303718A (en) * 1980-06-09 1981-12-01 Monsanto Company Printing ink formulations
US4398014A (en) 1980-11-04 1983-08-09 Ciba-Geigy Corporation Sulfoxonium salts and their use as polymerization catalysts
US4364786A (en) 1981-03-23 1982-12-21 Advanced Glass Systems Corp. Process for making safety glass laminates subject to nonsymmetrical thermal stress
DE3369398D1 (en) 1982-05-19 1987-02-26 Ciba Geigy Ag Curable compositions containing metallocen complexes, activated primers obtained therefrom and their use
JPS6016840A (ja) * 1983-07-06 1985-01-28 Sekisui Chem Co Ltd 合せガラス用模様付き中間膜
EP0153904B1 (de) 1984-02-10 1988-09-14 Ciba-Geigy Ag Verfahren zur Herstellung einer Schutzschicht oder einer Reliefabbildung
US4600627A (en) 1984-04-24 1986-07-15 Bridgstone Corporation Sandwich glasses
JPS62117665A (ja) * 1985-11-16 1987-05-29 Mitsubishi Monsanto Chem Co 着色または印刷した透明樹脂膜の製造方法
EP0254187A3 (de) 1986-07-21 1989-07-26 Siemens Aktiengesellschaft Pigmentierter Lack für Schreibsysteme
US4869966A (en) 1986-10-16 1989-09-26 Shell Oil Company Encapsulated assemblage and method of making
EP0319583B1 (en) * 1987-03-09 1994-06-15 Dai Nippon Insatsu Kabushiki Kaisha Method of producing decorative interlayer for laminated glass
CA1338550C (en) 1988-08-09 1996-08-27 Jurgen M. Kruse Jet printing ink compositions
US4968553A (en) * 1988-09-16 1990-11-06 Claudio Cesar Graphic architectural glass
IT8836036V0 (it) * 1988-11-28 1988-11-28 Siv Soc Italiana Vetro Disposizione di componenti di una vetratura di sicurezza
US5085698A (en) 1990-04-11 1992-02-04 E. I. Du Pont De Nemours And Company Aqueous pigmented inks for ink jet printers
US5049433A (en) 1990-05-17 1991-09-17 The Answer Corp. Architectural safety glass
IT1242070B (it) * 1990-10-11 1994-02-08 Siv Soc Italiana Vetro Procedimento per la fabbricazione di vetri laminati decorati di sicurezza
US5389723A (en) 1990-10-24 1995-02-14 Minnesota Mining And Manufacturing Company Transparent liquid absorbent materials for use as ink receptive layers
FR2675140B1 (fr) * 1991-04-09 1993-07-16 Saint Gobain Vitrage Int Vitrage feuillete.
BR9104893A (pt) 1991-11-11 1993-08-17 Mario Gordilho Fraga Processo para tratamento de chapas de vidro para aplicacoes,de impressoes grafico-pictoricas
US5231131A (en) 1991-12-24 1993-07-27 E. I. Du Pont De Nemours And Company Aqueous graft copolymer pigment dispersants
DE69325401T2 (de) 1992-02-20 1999-11-25 E.I. Du Pont De Nemours & Co., Inc. Dreiblock-Polymer Dispersionsmittel enthaltende Wasserdispersionen
JP2624094B2 (ja) 1992-08-24 1997-06-25 アキレス株式会社 残巻き数量表示床材およびその製造方法
FR2706446B1 (fr) 1993-06-18 1995-08-25 Saint Gobain Vitrage Int Vitrage feuilleté comportant un motif apparent.
US6077374A (en) 1993-08-16 2000-06-20 Monsanto Method of preparing prelaminate using rough-surfaced interlayer
JPH0768703A (ja) 1993-09-03 1995-03-14 Inax Corp 浴槽の加飾成形方法
US5795425A (en) 1993-09-03 1998-08-18 Rexam Graphics Incorporated Ink jet imaging process and recording element for use therein
US5766398A (en) 1993-09-03 1998-06-16 Rexam Graphics Incorporated Ink jet imaging process
US6001482A (en) 1993-09-03 1999-12-14 Rexam Graphics, Inc. Ink jet receptor element having a protective layer
US5455103A (en) 1994-01-24 1995-10-03 Monsanto Company Rough-surfaced interlayer
US6264321B1 (en) 1994-05-31 2001-07-24 Eastman Kodak Company Method of producing recorded images having enhanced durability on a variety of substrates
DE69502000T2 (de) † 1994-05-31 1998-11-12 Eastman Kodak Co Verfahrn zur herstellung von aufgenommenen bildern
US5747148A (en) 1994-09-12 1998-05-05 Minnesota Mining And Manufacturing Company Ink jet printing sheet
DE69518015T2 (de) 1995-03-14 2001-03-22 E.I. Du Pont De Nemours And Co., Wilmington Verfahren zur herstellung von polyvinylbutyralfolien
US5712672A (en) 1995-04-03 1998-01-27 Xerox Corporation Recording sheet transport and effluents removal system
US6159608A (en) 1995-09-28 2000-12-12 Saint-Gobain Performance Plastics Corporation Thermoplastic interlayer film
US5792560A (en) 1995-09-28 1998-08-11 Norton Performance Plastics Corporation Thermoplastic interlayer film
KR100387229B1 (ko) * 1995-11-01 2003-08-21 삼성전자주식회사 영상부호화장치
JPH09226974A (ja) * 1996-02-27 1997-09-02 Brother Ind Ltd 用紙搬送装置およびプリンタ
JP3604800B2 (ja) * 1996-03-26 2004-12-22 キヤノン株式会社 インクジェットプリント方法およびインクジェットプリント装置
EP0811505A1 (fr) 1996-06-03 1997-12-10 Seb S.A. Procédé pour la réalisation de pièces décorées par sublimation
US5721086A (en) 1996-07-25 1998-02-24 Minnesota Mining And Manufacturing Company Image receptor medium
TW459022B (en) * 1996-10-31 2001-10-11 Bayer Ag Pigment preparation useful for ink-jet printing, dispersing mixture used therein and ink-jet printing method
JP3890643B2 (ja) * 1996-12-26 2007-03-07 コニカミノルタホールディングス株式会社 インクジェット布帛印捺装置
EP0921012A4 (en) 1997-01-08 2000-03-15 Toshiba Tec Kk INK-JET PRINTER
US5698018A (en) 1997-01-29 1997-12-16 Eastman Kodak Company Heat transferring inkjet ink images
DE29706880U1 (de) * 1997-04-16 1997-05-28 Vegla Vereinigte Glaswerke Gmbh, 52066 Aachen Dekoratives Verbundglas
FR2762541B1 (fr) † 1997-04-24 1999-07-02 Saint Gobain Vitrage Procede de fabrication d'un vitrage feuillete
JPH10296906A (ja) 1997-04-25 1998-11-10 Mitsubishi Electric Corp 金属装飾パネル、その製造方法及び金属板用印刷装置
JPH10305456A (ja) 1997-05-07 1998-11-17 Seiko Epson Corp 絵付け成型用転写シート
DE19743804A1 (de) * 1997-10-02 1999-04-08 Politrust Ag Druckvorrichtung
JPH11286167A (ja) 1998-04-02 1999-10-19 Mitsubishi Paper Mills Ltd 油性インク用インクジェット記録シート
GB9810407D0 (en) † 1998-05-15 1998-07-15 Triplex Safety Glass Co Vehicle glazings
US6083310A (en) * 1998-05-28 2000-07-04 Marconi Data Systems, Inc. Colored inks comprising polymeric colorants for binary array printing and method of using
US6200647B1 (en) 1998-07-02 2001-03-13 3M Innovative Properties Company Image receptor medium
US6113679A (en) * 1998-10-06 2000-09-05 3M Innovative Properties Company Piezo inkjet inks and methods for making and using same
US6737151B1 (en) 1999-04-22 2004-05-18 E. I. Du Pont De Nemours And Company Glass laminates having improved structural integrity against severe impacts
EP1114734A1 (en) 1999-06-04 2001-07-11 DAICEL CHEMICAL INDUSTRIES, Ltd. Resin composition for ink-jet recording sheet and recording sheet made with the same
US6302523B1 (en) * 1999-07-19 2001-10-16 Xerox Corporation Ink jet printheads
WO2001030918A1 (en) 1999-10-28 2001-05-03 Cabot Corporation Ink jet inks, inks, and other compositions containing colored pigments
EP1228150B1 (en) 1999-10-28 2013-09-04 Cabot Corporation Ink jet inks, inks, and other compositions containing colored pigments
GB0003781D0 (en) 2000-02-18 2000-04-05 Pilkington Plc Laminated glazings
DE20100717U1 (de) * 2000-02-18 2001-04-05 Glas Engels Gmbh Verbundkörper aus einer mehrschichtigen Anordnung
EP1129844A1 (en) 2000-02-29 2001-09-05 Brevet 2000 Holding S.A. Composite stratified decorated panel from glass and/or transparent plastics
US6623677B1 (en) 2000-07-21 2003-09-23 Bayer Corporation Decorated article made by film insert molding
JP3591719B2 (ja) 2001-04-13 2004-11-24 信越ポリマー株式会社 成形用印刷シート及び押釦スイッチ用キートップ部材

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102407631A (zh) * 2011-10-09 2012-04-11 常熟市华夏建筑节能材料有限公司 一种夹层玻璃
CN107073901A (zh) * 2013-12-12 2017-08-18 爱克发印艺公司 层压安全玻璃

Also Published As

Publication number Publication date
JP2004506559A (ja) 2004-03-04
US20040234735A1 (en) 2004-11-25
US9403346B2 (en) 2016-08-02
NZ524898A (en) 2005-03-24
EP1322482B2 (en) 2014-11-19
DE60124287D1 (de) 2006-12-14
EP1322482A1 (en) 2003-07-02
CN103552321A (zh) 2014-02-05
EP1322482B1 (en) 2006-11-02
DE60124287T3 (de) 2015-03-19
CA2420870C (en) 2010-06-22
EP1322482A4 (en) 2004-06-23
WO2002018154A1 (en) 2002-03-07
DE20122692U1 (de) 2007-03-01
DE60124287T2 (de) 2007-04-05
CN103552321B (zh) 2017-07-04
EP1741552A1 (en) 2007-01-10
CA2420870A1 (en) 2002-03-07
AU2001285590B2 (en) 2009-10-15
JP5138142B2 (ja) 2013-02-06

Similar Documents

Publication Publication Date Title
CN1473114A (zh) 带图象的层压材料
AU2001285590A1 (en) Image carrying laminated material
RU2297330C2 (ru) Композит с цифровым конструированием цвета для использования в ламинированном стекле
EP1525099B1 (en) Ink-jet printed rigid interlayer and a process for preparing same
CN1305686C (zh) 数字打印的产品和方法
JP4452618B2 (ja) 装飾用積層安全ガラス
US9011628B2 (en) Decorative laminated safety glass
US20070172636A1 (en) Decorative sheets having enhanced adhesion and laminates prepared therefrom
CN1842414A (zh) 利用硬质夹层的装饰层压安全玻璃及其制备方法
US20070196630A1 (en) Decorative solar control laminates
JP2010533085A (ja) 装飾用ポリビニルブチラールソーラーコントロール積層体
US20070172637A1 (en) Decorative sheets having enhanced adhesion and penetration resistant laminates prepared therefrom
WO2024247770A1 (ja) 画像担持積層体、その製造方法、合わせガラス用中間膜、及び合わせガラス
JP2000052637A (ja) 被記録媒体、該被記録媒体を用いた画像形成方法、及び画像形成用媒体セット

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
REG Reference to a national code

Ref country code: HK

Ref legal event code: DE

Ref document number: 1062820

Country of ref document: HK

RJ01 Rejection of invention patent application after publication

Application publication date: 20040204

RJ01 Rejection of invention patent application after publication
REG Reference to a national code

Ref country code: HK

Ref legal event code: WD

Ref document number: 1062820

Country of ref document: HK