CN114322616A - Radiator assembly with heat pipe - Google Patents
Radiator assembly with heat pipe Download PDFInfo
- Publication number
- CN114322616A CN114322616A CN202210103952.0A CN202210103952A CN114322616A CN 114322616 A CN114322616 A CN 114322616A CN 202210103952 A CN202210103952 A CN 202210103952A CN 114322616 A CN114322616 A CN 114322616A
- Authority
- CN
- China
- Prior art keywords
- channel
- heat pipe
- copper
- aluminum fin
- hole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 132
- 229910052802 copper Inorganic materials 0.000 claims abstract description 129
- 239000010949 copper Substances 0.000 claims abstract description 129
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 102
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 102
- 230000000149 penetrating effect Effects 0.000 claims description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract description 34
- 238000007747 plating Methods 0.000 abstract description 24
- 239000000463 material Substances 0.000 abstract description 22
- 229910052759 nickel Inorganic materials 0.000 abstract description 17
- 230000005496 eutectics Effects 0.000 abstract description 9
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 230000001737 promoting effect Effects 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 18
- 238000010586 diagram Methods 0.000 description 16
- 238000009830 intercalation Methods 0.000 description 13
- 230000002687 intercalation Effects 0.000 description 13
- 238000003466 welding Methods 0.000 description 13
- 230000017525 heat dissipation Effects 0.000 description 8
- 239000000243 solution Substances 0.000 description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 229910052698 phosphorus Inorganic materials 0.000 description 5
- 239000011574 phosphorus Substances 0.000 description 5
- 239000003440 toxic substance Substances 0.000 description 4
- 230000004913 activation Effects 0.000 description 3
- 238000009713 electroplating Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- OBSZRRSYVTXPNB-UHFFFAOYSA-N tetraphosphorus Chemical compound P12P3P1P32 OBSZRRSYVTXPNB-UHFFFAOYSA-N 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 229910000881 Cu alloy Inorganic materials 0.000 description 2
- 229910018563 CuAl2 Inorganic materials 0.000 description 2
- 206010070834 Sensitisation Diseases 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000008602 contraction Effects 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 239000002440 industrial waste Substances 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 230000008313 sensitization Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910000679 solder Inorganic materials 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- 208000001132 Osteoporosis Diseases 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 238000007743 anodising Methods 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 239000012295 chemical reaction liquid Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 235000011167 hydrochloric acid Nutrition 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000002715 modification method Methods 0.000 description 1
- 230000017074 necrotic cell death Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Images
Landscapes
- Cooling Or The Like Of Semiconductors Or Solid State Devices (AREA)
Abstract
本发明提供一种具有热管的散热器总成,包含:相异材质的至少一铝质鳍片组及至少一铜质热管,该铝质鳍片组包括至少一欲结合部位(例如透孔及/或槽道)设有一铜质置入层用来跟该铜质热管接触结合,借此促进相异材质的铝质鳍片组与该铜质热管的结合且改善铝质鳍片组的表面共晶粒问题及化学镀镍造成的环境污染问题。
The present invention provides a radiator assembly with heat pipes, comprising: at least one aluminum fin group and at least one copper heat pipe of different materials, the aluminum fin group includes at least one part to be combined (such as through holes and / or channel) is provided with a copper insert layer for contact and bonding with the copper heat pipe, thereby promoting the combination of aluminum fin groups of different materials and the copper heat pipe and improving the surface of the aluminum fin group Eutectic grain problem and environmental pollution caused by electroless nickel plating.
Description
技术领域technical field
本发明涉及散热器,尤其关于一种在铝质散热器的欲结合部位设有一铜质 置入层用来与铜材质热管结合的具有热管的散热器总成。The present invention relates to radiators, in particular to a radiator assembly with a heat pipe, which is provided with a copper embedded layer at the to-be-bonded part of the aluminum radiator to be combined with the copper heat pipe.
背景技术Background technique
散热器或散热鳍片通常被使用在将发热元件或系统中产生的热量利用热交 换散逸在外在空气中;而在热阻较低的情形下,则显示该散热片具有较高的散 热效率。一般来说,热阻由散热片内部的扩散热阻以及该散热片表面与大气环 境之间的对流热阻所构成。目前更有效率的散热机制系采用具有高导热效能的 热管与散热器的鳍片作组合,以有效解决散热问题。Heat sinks or fins are usually used to dissipate the heat generated in the heating element or system to the outside air by heat exchange; and in the case of low thermal resistance, it shows that the heat sink has higher heat dissipation efficiency. Generally speaking, the thermal resistance consists of the diffusion thermal resistance inside the heat sink and the convection thermal resistance between the surface of the heat sink and the atmosphere. At present, a more efficient heat dissipation mechanism uses a combination of heat pipes with high thermal conductivity and fins of the heat sink to effectively solve the heat dissipation problem.
一般具有热管的散热模块,包括至少一热管及复数间隔排列的鳍片组,且 每每每相邻的鳍片之间设有一流道。每一鳍片上开设有互相对齐的一透孔、一 上折边及一下折边。该上折边及该下折边分别设有至少一扣合部,每一鳍片借 由该扣合部扣接相邻鳍片的扣合部形成一扣鳍片式的散热器或散热鳍片组,进 而使所述的这些鳍片的上折边共同构成该散热器的一顶侧,该下折边共同构成 该散热器的一底侧。Generally, a heat dissipation module with a heat pipe includes at least one heat pipe and a plurality of fin groups arranged at intervals, and a flow channel is often arranged between adjacent fins. Each fin is provided with a through hole, an upper folded edge and a lower folded edge which are aligned with each other. The upper folded edge and the lower folded edge are respectively provided with at least one buckling portion, and each fin is buckled with the buckling portion of the adjacent fins through the buckling portion to form a finned heat sink or heat dissipation fin The upper folded edges of the fins together form a top side of the radiator, and the lower folded edges together form a bottom side of the radiator.
再者,该鳍片透孔的周缘由一侧向另一侧凸伸形成设有一透孔凸缘,当该透孔 被该热管的一端贯穿后,该透孔凸缘系环绕在该热管的一端的外表面;热管的 另一端则延伸到该散热器或散热鳍片组的底侧或配合一底座。Furthermore, the peripheral edge of the fin through-hole protrudes from one side to the other side to form a through-hole flange. When the through-hole is penetrated by one end of the heat pipe, the through-hole flange surrounds the outer surface of one end of the heat pipe. ; The other end of the heat pipe is extended to the bottom side of the radiator or the heat dissipation fin group or matched with a base.
一般而言,所述的这些鳍片的透孔跟该热管的一端的结合系采惯用为紧配 结合或松配结合方式二种,其中紧配结合方式例如该透孔凸缘的内径略小于该 热管的一端的外径导致两者产生干涉结合。另有利用热胀冷缩的手段对鳍片加 热使该透孔凸缘的内径稍微大于该热管的一端的外径,然后在该热管插入该透 孔后,对该鳍片冷却使该透孔凸缘的内径缩回到原来尺寸与该热管紧配结合。Generally speaking, the combination of the through holes of the fins and one end of the heat pipe is usually a tight-fit combination or a loose-fit combination. The tight-fit combination, for example, the inner diameter of the through-hole flange is slightly smaller than the heat pipe. The outer diameter of one end causes the two to produce an interference bond. In addition, the fin is heated by means of thermal expansion and cold contraction, so that the inner diameter of the through-hole flange is slightly larger than the outer diameter of one end of the heat pipe, and then after the heat pipe is inserted into the through hole, the fin is cooled to make the through-hole flange The inner diameter of the flange Retracted to original size to fit snugly into the heat pipe.
另外,惯用的松配结合方式例如该透孔凸缘的内径略大于该热管一端的外 径且在鳍片的透孔与热管之间设有一介质(例如导热胶或锡膏或锡条填补空隙)。 介质设置的方式其中之一是将该介质设置在该透孔的内缘跟该热管的一端的外 表面;另一方式则在该透孔的边缘开设一填料孔,将该介质设置在该填料孔内。 于加工时,加热使该介质融化均匀布满于该导热管外表面及该透孔内缘之间填 补空隙。In addition, in a conventional loose-fit bonding method, for example, the inner diameter of the through-hole flange is slightly larger than the outer diameter of one end of the heat pipe, and a medium (such as thermal conductive glue or solder paste or tin strips to fill the gap) is provided between the through hole of the fin and the heat pipe. One of the ways of setting the medium is to set the medium on the inner edge of the through hole and the outer surface of one end of the heat pipe; the other way is to open a packing hole at the edge of the through hole, and set the medium on the packing inside the hole. During processing, heating makes the medium melt and spread evenly between the outer surface of the heat conduction pipe and the inner edge of the through hole to fill the gap.
再者,紧配结合方式也有利用一束口装置施压在该透孔凸缘上形成一波纹 状结构,该波纹状结构具有复数连续的凹部及凸部交错排列在该透孔凸缘的径 向周围,且该凸部与该凹部紧密束缚在该热管一端的外侧表面,并朝该热管径 向挤压使该热管的外表面变形,进而与该热管的外表面形成干涉,以令该透孔 凸缘与该热管紧密结合一起。In addition, the tight-fitting combination method also uses a bunching device to press on the through-hole flange to form a corrugated structure, and the corrugated structure has a plurality of continuous concave parts and convex parts arranged alternately around the radial direction of the through-hole flange, and The protruding portion and the concave portion are tightly bound to the outer surface of one end of the heat pipe, and are radially squeezed toward the heat pipe to deform the outer surface of the heat pipe, thereby interfering with the outer surface of the heat pipe, so that the through-hole flange and the The heat pipes are tightly bound together.
此外业者进一步考量整体散热器的整体重量及成本,为了获的较轻重量及 成本低的要求,通常鳍片或散热器或底座系选择为重量轻、成本低的铝质材料 构成,热管则利用高导热系数金属(如黄铜或铝、镍、不锈钢等等)所做成。In addition, the industry further considers the overall weight and cost of the overall radiator. In order to meet the requirements of lighter weight and lower cost, usually the fins, radiators or bases are made of light-weight and low-cost aluminum materials, and the heat pipes use Made of high thermal conductivity metals (such as brass or aluminum, nickel, stainless steel, etc.).
虽选用铝材质取代铜材质可借以改善了铜重量重及材料成本昂贵等问题, 但却衍生出其他问题例如铝表面易被氧化,在焊接过程中生成高熔点的氧化物, 使焊缝金属难以完全熔合,给施焊带来困难,若铜与铝直接进行焊接时,两材 料直接对接的部位,在焊接后容易因为脆性大而产生裂纹,并且在铜与铝进行 熔焊时,靠近铜材料这一侧的焊缝中很容易形成CuAl2等共晶,而CuAl2等共 晶结构仅分布于材料的晶界附近,容易产生晶界间的疲劳或裂纹,又由于铜与 铝两者的熔点温度及共晶温度相差甚大,在熔焊作业中,当铝熔化时而铜却保 持固体状态,当铜熔化时,铝已熔化很多了,无法以共融或共晶状态共存,增加焊接难度。另外,由于铜与铝的导热性都很好,焊接时熔池金属结晶快,高 温时的冶金反应气体来不及逸出,焊缝易产生气孔,故铜与铝材质间无法直接 进行焊接,则必须对该铝材质表面进行表面改质后使得以进行后续与铜材质或 其他材料焊接的作业。Although the use of aluminum material instead of copper material can improve the weight of copper and the high cost of materials, other problems arise, such as the aluminum surface is easily oxidized, and high melting point oxides are generated during the welding process, making it difficult for the weld metal. Complete fusion brings difficulties to welding. If copper and aluminum are directly welded, the parts where the two materials are directly butted are prone to cracks after welding due to their large brittleness, and when copper and aluminum are welded, close to the copper material. CuAl2 and other eutectic structures are easily formed in the weld on this side, while CuAl2 and other eutectic structures are only distributed near the grain boundaries of the material, which are prone to fatigue or cracks between grain boundaries. And the eutectic temperature is very different. In the fusion welding operation, when the aluminum is melted, the copper remains in a solid state. When the copper is melted, the aluminum has melted a lot and cannot coexist in a eutectic or eutectic state, which increases the difficulty of welding. In addition, due to the good thermal conductivity of copper and aluminum, the molten pool metal crystallizes quickly during welding, the metallurgical reaction gas at high temperature does not have time to escape, and the weld is prone to pores, so copper and aluminum cannot be directly welded. After the surface of the aluminum material is surface-modified, it can be used for subsequent welding operations with copper or other materials.
尤有进者为改善前述现有改用铝材质取代铜材质无法直接与铜或其他异材 质进行焊接的缺失,遂使用了化学镀镍(即无电镀镍)作为表面改质的技术工法。 一般而言,化学镀镍(即无电镀镍)有三种:低磷、中磷、高磷,其与电镀最大的 差异点是其工作环境是在没有电流条件下,利用溶液中的还原剂将金属离子还 原,而进行化学镀镍前必须对试片表面进行催化。化学镀镍液可分为下列三种: (1)活化敏化+酸性镀浴PH值在4~6之间的属于酸性镀液,其特色是蒸发量所引 起成分量的损失较少,虽然操作温度较高,但镀液较安全且容易控制,含磷量 高、镀率高,常为工业界所使用。(2)活化敏化+碱性镀液碱性镀浴的PH值在8~10 之间,因调整PH值的氨水容易挥发,在操作时须适时补充氨水来维持PH值的 稳定,含磷量较少,镀液较不稳,操作温度较低。(3)HPM+碱性镀浴HPM是将 硅晶片浸泡于DI-water:H2O2(aq):HCl(aq)=4:1:1的混合液中利用硅晶表面形成 的氧化层来取代敏化活化,在表面形成自我催化表面。In particular, in order to improve the above-mentioned defect of using aluminum material instead of copper material, which cannot be directly welded with copper or other dissimilar materials, electroless nickel plating (ie electroless nickel plating) is used as a technical method for surface modification. Generally speaking, there are three types of electroless nickel plating (ie, electroless nickel plating): low phosphorus, medium phosphorus, and high phosphorus. The biggest difference between them and electroplating is that the working environment is under the condition of no current, and the reducing agent in the solution is used. Metal ions are reduced, and the surface of the test piece must be catalyzed before electroless nickel plating. Electroless nickel plating solution can be divided into the following three types: (1) Activation sensitization + acid plating bath pH value between 4 and 6 belongs to acid plating solution, which is characterized by less loss of components caused by evaporation, although The operating temperature is high, but the plating solution is safe and easy to control, with high phosphorus content and high plating rate, and is often used in the industry. (2) Activation sensitization + alkaline plating solution The pH value of the alkaline plating bath is between 8 and 10. Because the ammonia water that adjusts the pH value is easy to volatilize, it is necessary to supplement the ammonia water in time to maintain the stability of the pH value during operation. The amount is less, the plating solution is less stable, and the operating temperature is lower. (3) HPM+Alkaline plating bath HPM is to immerse the silicon wafer in a mixed solution of DI-water:H 2 O 2 (aq):HCl(aq)=4:1:1 and utilize the oxide layer formed on the surface of the silicon wafer to Substitution sensitized activation to form an autocatalytic surface on the surface.
然而,在化学镀镍(即无电镀镍)制程中需使用大量的化学反应液体,并且在 化学镀镍制程后将会产生大量含有重金属或化学物质的工业废液,而工业废液 中都会产生大量的含有黄磷等有毒物质的废水无法回收使用。况且黄磷污水中 含有50~390mg/L浓度的黄磷是一种剧毒物质,进入人体对肝脏等器官危害极 大。长期饮用含磷的水可使人的骨质疏松,发生下颌骨坏死等病变。故现行各 国已开始禁用此项制程,并推广无毒制程借以保护环境。However, a large amount of chemical reaction liquid needs to be used in the process of electroless nickel plating (ie electroless nickel plating), and a large amount of industrial waste liquid containing heavy metals or chemical substances will be generated after the electroless nickel plating process, and the industrial waste liquid will produce A large amount of waste water containing toxic substances such as yellow phosphorus cannot be recycled. Moreover, yellow phosphorus with a concentration of 50-390 mg/L in yellow phosphorus sewage is a highly toxic substance, which is extremely harmful to the liver and other organs when it enters the human body. Long-term drinking of phosphorus-containing water can cause osteoporosis and other diseases such as mandibular necrosis. Therefore, countries have begun to ban this process and promote non-toxic processes to protect the environment.
故如何提供一种可降低散热模块组合结构整体重量,以及取代化学镀镍作 为改善铝材质无法与其他异材质焊接的表面改质工法,同时有利于焊接作业且 又不额外产生环境污染物的方法,则为现阶段首重的目标。Therefore, how to provide a method that can reduce the overall weight of the combined structure of the heat dissipation module and replace the electroless nickel plating as a surface modification method that improves the inability of aluminum materials to be welded with other dissimilar materials, and is beneficial to welding operations without additional environmental pollutants. , is the primary goal at this stage.
是以,要如何解决上述的问题与缺失,即为本案的发明人与从事此行业的 相关厂商所亟欲研究改善的方向所在。Therefore, how to solve the above-mentioned problems and deficiencies is the direction that the inventor of this case and the relevant manufacturers engaged in this industry urgently want to study and improve.
发明内容SUMMARY OF THE INVENTION
为改善上述的问题,本发明的一目的系提供一种在铜铝相异材质构成不同 的元件之间,通过在该铝质鳍片组的至少一欲结合部位设置一铜质置入层用来 跟铜质热管接触结合,以使铜铝相异材质构成的不同元件可以直接焊接,铝质 的鳍片组不需要化学镀镍制程就可以跟铜质热管焊接结合,进而不会产生有毒 物质达到环保的效果,且改善现有形成共晶的问题。In order to improve the above-mentioned problems, an object of the present invention is to provide a method for disposing a copper intercalation layer at at least one of the parts to be joined in the aluminum fin group between components composed of different copper and aluminum materials. It can be combined with the copper heat pipe, so that different components composed of different materials of copper and aluminum can be directly welded. The aluminum fin group can be welded and combined with the copper heat pipe without electroless nickel plating process, and no toxic substances will be produced. The effect of environmental protection is achieved, and the existing problem of eutectic formation is improved.
本发明的一目的提供一种在铝质鳍片组用来跟铜质热管或基座其中任一或 两者结合的欲结合部位形成一铜质置入层,以使该铝质鳍片组不需要化学镀镍 制程就可以跟铜质热管或铜质基座焊接结合,进而降低结构整体重量且减少接 合处的热阻并提升热传导效率的具有热管的散热器总成。It is an object of the present invention to provide a method to form a copper intercalation layer on the part to be combined of the aluminum fin set with either or both of the copper heat pipe or the base, so that the aluminum fin set can be A heat sink assembly with a heat pipe that can be welded to a copper heat pipe or a copper base without the need for an electroless nickel plating process, thereby reducing the overall weight of the structure, reducing the thermal resistance of the joint and improving the heat conduction efficiency.
为达上述的目的,本发明提供一种具有热管的散热器总成,包含:至少一 铝质鳍片组,由复数铝质鳍片系扣接组合构成并具有一底面及一顶面,且在两 相邻铝质鳍片之间具有一流道,该底面设有至少一槽道,该槽道具有一槽道开 口及一槽道内侧面,且每一铝质鳍片上设有至少一贯穿的透孔,该透孔具有一 透孔凸缘由该铝质鳍片的一侧凸出,该槽道内侧面作为该铝质鳍片组与热管的 一欲结合部位设有一具有一深入面及一接触面的铜质置入层,且该置入层的深 入面结合该槽道内侧面并深入在该槽道内侧面的下;至少一铜质热管,具有一 第一端及一第二端分别贯穿该铝质鳍片组的该透孔及该槽道,且该第一端跟各 该透孔凸缘紧配结合,该第二端跟该槽道内侧面的该铜质置入层的接触面接触 结合。In order to achieve the above object, the present invention provides a radiator assembly with a heat pipe, comprising: at least one aluminum fin group, which is composed of a plurality of aluminum fins in a buckled combination and has a bottom surface and a top surface, and There is a flow channel between two adjacent aluminum fins, the bottom surface is provided with at least one channel, the channel has a channel opening and an inner side surface of the channel, and each aluminum fin is provided with at least one through-hole. The through-hole has a through-hole flange protruding from one side of the aluminum fin, and the inner side of the channel serves as a part to be combined with the aluminum fin group and the heat pipe. The copper embedded layer, and the deep surface of the embedded layer is combined with the inner side of the channel and penetrates under the inner side of the channel; at least one copper heat pipe has a first end and a second end respectively penetrating the aluminum The through-hole and the channel of the fin group, and the first end is tightly fitted with each of the through-hole flanges, and the second end is in contact with the contact surface of the copper embedded layer on the inner side of the channel.
前述该至少一铜质热管的该第二端具有一热管外露表面从该槽道开口外 露,及一热管接触表面跟该槽道内侧的该铜质置入层的接触面接触并通过焊接 结合。The second end of the aforesaid at least one copper heat pipe has a heat pipe exposed surface exposed from the opening of the channel, and a heat pipe contact surface is in contact with the contact surface of the copper embedded layer inside the channel and is bonded by welding.
前述该透孔凸缘环设有一波纹状或棘状结构紧密束缚在该第一端的该外表 面。The aforementioned through-hole flange ring is provided with a corrugated or spine-like structure tightly bound to the outer surface of the first end.
前述该鳍片组的该底面系作为该鳍片组的另一欲结合部位设有该铜质置入 层。The bottom surface of the aforementioned fin set is used as another part to be combined with the fin set with the copper embedded layer.
本发明另外提供一种具有热管的散热器总成,包含:至少一铝质鳍片组, 具有一底面及一顶面,在两相邻铝质鳍片之间具有一流道,该底面设有至少一 槽道,该槽道具有一槽道开口及一槽道内侧面,且每一鳍片上设有至少一透孔 贯穿该铝质鳍片,该透孔具有一透孔凸缘由该铝质鳍片的一侧凸出且界定一凸 缘内侧面,该槽道内侧面及该凸缘内侧面分别分别作为该铝质鳍片组的一欲结 合部位设有一铜质置入层,该铜质置入层具有一深入面及一接触面,且该深入 面分别结合该槽道内侧面及该凸缘内侧面并深入该槽道内侧面及该凸缘内侧面 之内;至少一铜质热管具有一第一端及一第二端分别贯穿该铝质鳍片组的该透 孔及该槽道,该第一端跟该透孔凸缘采松配结合并与该凸缘内侧面的该铜质置 入层的该接触面接触以焊接结合,该第二端跟该槽道内侧面的该铜质置入层的 该接触面接触也通过焊接结合二。The present invention further provides a heat sink assembly with a heat pipe, comprising: at least one set of aluminum fins, with a bottom surface and a top surface, a flow channel between two adjacent aluminum fins, and the bottom surface is provided with a bottom surface and a top surface. At least one channel, the channel has a channel opening and an inner side surface of the channel, and each fin is provided with at least one through hole penetrating the aluminum fin, the through hole has a through hole flange from the aluminum fin One side protrudes and defines an inner side of a flange, the inner side of the channel and the inner side of the flange are respectively used as a part of the aluminum fin group to be combined with a copper insert layer, the copper insert The layer has a deep surface and a contact surface, and the deep surface is respectively combined with the inner side of the channel and the inner side of the flange and penetrates into the inner side of the channel and the inner side of the flange; at least one copper heat pipe has a first The end and a second end respectively pass through the through hole and the channel of the aluminum fin group, and the first end is loosely combined with the through hole flange and is connected with the copper embedded layer on the inner side of the flange. The contact surface is in contact with the contact surface by welding, and the second end and the contact surface of the copper embedded layer on the inner side of the channel are also connected by welding.
前述至少一热管的该第二端具有一热管外露表面从该槽道开口外露,及一 热管接触表面跟该槽道内侧面的该铜质置入层的接触面接触结合。The second end of the at least one heat pipe has an exposed surface of the heat pipe exposed from the opening of the channel, and a contact surface of the heat pipe is in contact with the contact surface of the copper embedded layer on the inner side of the channel.
前述该鳍片组的该底面系作为该鳍片组的另一欲结合部位设有该铜质置入 层。The bottom surface of the aforementioned fin set is used as another part to be combined with the fin set with the copper embedded layer.
总之,本发明提供一种具有热管的散热器总成,包含:相异材质的至少一 铝质鳍片组及至少一铜质热管,该铝质鳍片组包括至少一欲结合部位(例如透 孔及/或槽道)设有一铜质置入层用来跟该铜质热管接触结合,借此促进相异材 质的铝质鳍片组与该铜质热管的结合且改善铝质鳍片组的表面共晶粒问题及化 学镀镍造成的环境污染问题。In conclusion, the present invention provides a heat sink assembly with heat pipes, comprising: at least one aluminum fin group and at least one copper heat pipe made of different materials, the aluminum fin group including at least one part to be combined (for example, transparent hole and/or channel) is provided with a copper insert layer for contacting and bonding with the copper heat pipe, thereby promoting the combination of aluminum fin sets of different materials and the copper heat pipe and improving the aluminum fin set The problem of surface eutectic grains and environmental pollution caused by electroless nickel plating.
附图说明Description of drawings
图1A及图1B为本发明立体分解及组合示意图;1A and FIG. 1B are three-dimensional exploded and assembled schematic diagrams of the present invention;
图1C为本发明立体组合另一视角示意图;1C is a schematic diagram of another perspective view of the three-dimensional combination of the present invention;
图1D为本发明铝质鳍片组的最外侧设有一倒扣鳍片示意图;1D is a schematic diagram of an inverted fin provided on the outermost side of the aluminum fin group of the present invention;
图2A为本发明铝质鳍片组剖视示意图;2A is a schematic cross-sectional view of an aluminum fin group of the present invention;
图2B为本发明铝质鳍片组与铜质热管组合的剖视示意图;2B is a schematic cross-sectional view of the combination of an aluminum fin group and a copper heat pipe according to the present invention;
图3为本发明铝质鳍片与铜质热管紧配的实施示意图;Fig. 3 is the implementation schematic diagram of the tight fitting of aluminum fins and copper heat pipes of the present invention;
图4A及图4B为本发明铝质鳍片组设有铜质置入层的前与的后的示意图;FIG. 4A and FIG. 4B are schematic diagrams before and after the aluminum fin set of the present invention is provided with a copper intercalation layer;
图5为本发明底面跟一热传导元件接合的示意图;FIG. 5 is a schematic diagram of the bottom surface of the present invention being joined to a thermally conductive element;
图6为本发明另一替代实施的示意图;6 is a schematic diagram of another alternative implementation of the present invention;
图7A至图7C为本发明铝质鳍片组的透孔与铜质热管松配结合的示意图;7A to FIG. 7C are schematic diagrams showing the loose combination of through holes and copper heat pipes of the aluminum fin group of the present invention;
图8为本发明铜质热管另一替代实施的示意图。FIG. 8 is a schematic diagram of another alternative implementation of the copper heat pipe of the present invention.
附图标记说明:散热器结构10;铝质鳍片组11;铝质鳍片111;上折边1111; 下折边1112;扣合部11111、11121;底面113;透孔114;透孔凸缘1141;波 纹状结构1142;凸缘内侧面1143;槽道115、115a;槽道开口1151;槽道内侧 面1152、1152a;顶面116;流道117;铜质热管121;第一端1211;第二端1212、 1212a;热管外露表面12121、12121a;热管接触表面12122、12122a;U形部位 1213;铜质置入层14;深入面141;接触面142;铜质热传导基座15;发热元 件16。Reference numeral description:
具体实施方式Detailed ways
本发明的上述目的及其结构与功能上的特性,将依据所附图式的较佳实施 例予以说明。The above objects of the present invention and their structural and functional characteristics will be described with reference to the preferred embodiments of the accompanying drawings.
请参阅图1A为本发明立体分解示意图;图1B为本发明立体组合示意图; 图1C为本发明立体组合另一视角示意图;图1D为本发明铝质鳍片组的最外侧 设有一扣接的外侧鳍片示意图;图2A为本发明铝质鳍片组剖视示意图;图2B 为本发明铝质鳍片组与铜质热管组合的剖视示意图。如图所示一散热器结构10 包括一铝质鳍片组11及至少一铜质热管121,该铝质鳍片组11具有一底面113 及一顶面116,该底面113设有至少一槽道115,在本实施表示两个槽道115, 该槽道115具有一槽道开口1151切齐该底面113,及一槽道内侧面1152往相反 该底面113的方向内凹设置,且该底面113及该槽道内侧面1152则分别作为该 鳍片组11与其他铜质零件结合的一欲结合部位(详述如后)。Please refer to FIG. 1A is a schematic exploded perspective view of the present invention; FIG. 1B is a schematic view of a three-dimensional assembly of the present invention; FIG. 1C is a schematic view of another perspective view of the three-dimensional assembly of the present invention; Schematic diagram of the outer fins; FIG. 2A is a schematic cross-sectional view of the aluminum fin group of the present invention; FIG. 2B is a cross-sectional schematic diagram of the combination of the aluminum fin group and the copper heat pipe of the present invention. As shown in the figure, a
详细而言,该铝质鳍片组11由复数铝或铝合金材质的鳍片111以水平或垂 直扣接构成,且在两相邻铝质鳍片111之间具有一流道117。在本图中表示每一 铝质鳍片111具有一上折边1111及一下折边1112凸伸对齐相邻的另一铝质鳍 片111的上折边1111及一下折边1112,且该上折边1111及该下折边1112分别 设有至少一扣合部11111、11121,该扣合部11111、11121在图中虽然表示凹凸 配合的结构但不限于此,也包括目前已知的技术手段。每一铝质鳍片111借由 该扣合部11111、11121水平扣接相邻铝质鳍片111的扣合部11111、11121形 成一扣合式鳍片(fin)的散热器结构。In detail, the
如此设置,所述的这些上折边1111共同构成该铝质鳍片组11的顶面116, 所述的这些下折边1112则共同构成所述的这些鳍片组11的底面113。再者,每 一铝质鳍片111的下折边1112设有至少一凹槽,在所述的这些铝质鳍片111扣 接后,所述的这些凹槽系彼此对齐构成位于该底面113的该槽道115。前述每一 铝质鳍片111上设有贯穿的至少一透孔114,所述的这些透孔114系彼此对齐, 该透孔114具有一透孔凸缘1141环设在该透孔114的一边缘且由该铝质鳍片111 的一侧凸出(在图中表示该鳍片111的一前侧)并界定一凸缘内侧面1143。另外, 不限于此,该铝质鳍片组11也可以是垂直扣接设置。再者,该铝质鳍片组11 的一最外侧设有一倒扣的铝质鳍片111以防止该上折边1111及该下折边1112 刮伤其他零件(如图1D)。In this way, the upper folded
该铜质热管121(在本图表示两根热管121)例如为U形热管,其中该铜质包 括铜及铜合金。详细而言,该铜质热管121(例如为圆形、D形、或扁平式热管) 具有一第一端1211及一第二端1212,该第一端1211系贯穿该透孔114与该透 孔凸缘114紧配结合(例如该透孔凸缘1141的凸缘内侧面1143的内径略小于该 铜质热管121的第一端1211外径导致两者产生干涉结合,或者利用热胀冷缩的 手段对该铝质鳍片111加热使该该透孔凸缘1141的内径尺寸扩大,然后令该铜 质热管121插入透孔114后,对该铝质鳍片111冷却使该透孔凸缘1141的内径 尺寸缩回到原来尺寸与该铜质热管121紧配结合),该第二端1212延伸到该鳍片 组11的该底面113并贯穿该槽道115。该第二端1212具有一热管外露表面12121 对应该槽道开口1151,及一热管接触表面12122面对该槽道内侧面1152。The copper heat pipes 121 (two
本发明选择设有一U形部位1213在该第一端1211及该第二端1212之间, 该U形部位1213从该第一段1211延伸到该第二端1212。该铜质热管121的第 一端1211系作为冷凝端,该第二端1212系作为蒸发端,且该铜质热管121内 容设有至少一毛细结构及一工作液体,该至少一毛细结构例如为沟槽、粉末烧 结体、网格体、纤维体、波浪板其中任一或组合,该毛细结构从该第一端1211 延伸到该第二端1212。The present invention chooses to provide a
再者,虽然图中表示该铜质热管121的第一端1211的截面是圆形,该第二 端1212的截面是D形或扁平形状,也就是该第二端1212的外露侧12121为一 平面(该平面例如用治具压平或铣刀铣削等机械加工手段实现),并对齐该铝质鳍 片组11的底面113。但不限于此,在其他替代实施,该第一端1211及第二端 1212的截面同为圆形或扁平形状。Furthermore, although the figure shows that the cross section of the
如图3所示,在另一替代实施,前述每一铝质鳍片111的透孔凸缘1141环 设有一波纹状(或棘状)结构1142紧密束缚在该铜质热管121的第一端1211的外 表面形成干涉结合,具体系在该铜质热管121的第一端1211插入该透孔114后, 利用一束口装置施压在该透孔凸缘1141形成该波纹状(或棘状)结构1142,借由 该波纹状(或棘状)结构1142具有复数连续的凹部及凸部交错排列在该透孔凸缘 1141的径向周围,并朝该铜质热管121径向挤压使该铜质热管121的外表面变 形,进而与该铜质热管121的外表面形成干涉,以使所述的这些铝质鳍片111 固定在该铜质热管121的第一端1211,防止该铜质热管121抽离该透孔114。As shown in FIG. 3 , in another alternative implementation, the through-
请继续参考图4A及图4B为本发明鳍片组设有铜质置入层的前与的后的示 意图。如图所示,复参图1A-图1B及图2A-图2B所示,前述铝质鳍片组11的 槽道内侧面1152及该底面113分别作为一欲结合部位设有一铜质的置入层 (copper embedding layer)14,该铜质置入层14具有一深入面(deepening surface)141及一接触面(connecting surface)142分设于在该铜质置入层14的相反 两面,该深入面141结合(例如咬合或嵌入或埋设或沉积)该槽道内侧面1152及 该底面113,该接触面142作为该铜质置入层14的外露表面与其他元件接触结 合。在一些可行实施,该铜质置入层14是铜片或铜箔或铜粉粒或液态铜经过机 械加工(例如气压、液压、冲压或油压挤压或捶打制成)或表面处理制程(喷涂、 电镀或印刷)或化学加工处理(如电镀、阳极处理)结合在该槽道内侧面1152及该 底面113,且部分该铜质置入层14在结合的过程中直接咬合或或嵌入或埋入或 沉积在该槽道内侧面1152及该底面113以深入形成该深入面141。Please continue to refer to FIG. 4A and FIG. 4B , which are schematic diagrams of the fin group of the present invention before and after the copper intercalation layer is provided. As shown in the figures, referring back to FIGS. 1A-1B and FIGS. 2A-2B, the
如此,该铜质置入层14不仅结合在该槽道内侧面1152及该底面113,且该 深入面141更以咬合或嵌入或埋入或沉积的结合方式深入该槽道内侧面1152及 该底面113之内作为该铜质置入层14的根基,增强该铜质置入层14与该槽道 内侧面1152及该底面113的结合力(强度),更能防止该铜质置入层14从该槽道 内侧面1152及该底面113剥离脱落。In this way, the
借由上述的设置,该铝质鳍片组11的槽道15通过该槽道内侧面1152的铜 质置入层14的接触面142跟该铜质热管121的第二端1212的热管接触表面 12122接触接合(例如在该铜质置入层14的该接触面142及该铜质热管121的热 管接触表面12122之间设有焊料进而焊接结合,或者超音波焊接或雷射焊接), 借此使铝质鳍片组11不需要经过化学镀镍制程就能跟相异材质的铜质热管121 焊接结合。With the above arrangement, the
请继续参考图5为本发明底面跟一底板接合的立体示意图。如图所示,本 发明铝质鳍片组11的底面113系跟一铜质热传导基座15(例如实心底板或是空 心内设有工作液体的均温板)结合,其中该铜质包括铜或铜合金。如此,该底面 113经由该铜质置入层14的接触面142跟该铜质热传导基座15结合(例如焊接 结合),且该铜质热管121的第二端1212的热管外露表面12121也跟该铜质热传 导基座15结合(例如焊接结合),借此使相异材质的铝质鳍片组11不需要经过化 学镀镍制程就能跟铜质热传导基座15焊接结合。再者,该散热器结构10在制 造过程不会产生有毒物质达到环保的效果,并改善现有形成共晶的问题。Please continue to refer to FIG. 5 , which is a three-dimensional schematic diagram of the bottom surface of the present invention being joined to a bottom plate. As shown in the figure, the
请继续参考图6为本发明另一替代实施的示意图。前面虽举例该铜质置入 层14结合在该槽道内侧面1152及该底面113,但不限于此,在其他实施该铝质 鳍片组11的底面113的大致中央处开设单一槽道115a具有一槽道内侧面1152a 是平直设置,该铜质置入层14结合在该槽道内侧面1152a。复数铜质热管121(本 实施表示三根)的第二端1212a系贯穿该槽道115a且并排设置。再者,该第二端 1212a的截面是矩形以使所述的这些铜质热管121的第二端1212a的热管接触表 面12122a形成一共平面配合该槽道内侧面1152a,并跟该铜质置入层14的接触 面142接触结合(例如焊接结合,或者超音波焊接或雷射焊接)。再者,所述的这 些铜质热管121的第二端1212a的热管外露表面12121a形成一共平面接触一发 热元件16的上表面(例如中央处理器或微处理器等)。Please continue to refer to FIG. 6 for a schematic diagram of another alternative implementation of the present invention. Although the
请继续参考图7A至图7C为本发明铝质鳍片组的透孔与铜质热管松配结合 的示意图。虽然前面表示该铜质热管121的第一端1211跟该透孔凸缘1141紧 配结合,但不局限于此。在另一替代实施,该铜质热管121的第一端121贯穿 该透孔114与该透孔凸缘1141松配结合(也就是该透孔凸缘1141的凸缘内侧面 1143的内径略大于该铜质热管121的第一端1211的外径),且该凸缘内侧面1143 更作为该鳍片组11的另一欲结合部位,该铜质置入层(copper embedding layer)14 不仅设置在该槽道内侧面1152及该底面113也设置在该凸缘内侧面1143,该深 入面(deepening surface)141更以咬合或嵌入或埋入或沉积的结合方式结合在该 凸缘内侧面1143作为该铜质置入层14的根基,通过该深入面141深入结合在该凸缘内侧面1143之内以加强该铜质置入层(copper embedding layer)14与凸缘 内侧面1143之间的结合力,防止该铜质置入层14从该凸缘内侧面1143剥离脱 落。如此,该铝质鳍片组11的透孔114通过该凸缘内侧面1143的铜质置入层 14的接触面142跟该铜质热管121的第一端1211接触结合(例如焊接结合)。Please continue to refer to FIG. 7A to FIG. 7C , which are schematic diagrams of loose-fit combination of the through hole of the aluminum fin group and the copper heat pipe according to the present invention. Although it is shown above that the
请继续参考图8为本发明热管另一替代实施的示意图。前面虽然表示两根 铜质热管121从该铝质鳍片组11的单一侧穿设。但不局限于此,在其他替代实 施,散热器结构10包括复数根铜质热管121(图中表示4根),该铝质鳍片组11 开设等同所述的这些铜质热管121数量的透孔114及槽道115,且所述的这些铜 质热管121分别从该铝质鳍片组11的相对两侧交错或非交错排列的对穿进而跟 该铝质鳍片组11结合,如此提升该散热器结构10的散热效率。Please continue to refer to FIG. 8 for a schematic diagram of another alternative implementation of the heat pipe of the present invention. Although it is shown above that two
以上说明对本发明而言只是说明性的,而非限制性的,本领域普通技术人 员理解,在不脱离权利要求所限定的精神和范围的情况下,可作出许多修改、 变化或等效,但都将落入本发明的保护范围之内。The above description is only illustrative rather than restrictive for the present invention, and those of ordinary skill in the art understand that many modifications, changes or equivalents can be made without departing from the spirit and scope defined by the claims. All will fall within the protection scope of the present invention.
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202210103952.0A CN114322616A (en) | 2022-01-28 | 2022-01-28 | Radiator assembly with heat pipe |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202210103952.0A CN114322616A (en) | 2022-01-28 | 2022-01-28 | Radiator assembly with heat pipe |
Publications (1)
Publication Number | Publication Date |
---|---|
CN114322616A true CN114322616A (en) | 2022-04-12 |
Family
ID=81031181
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202210103952.0A Pending CN114322616A (en) | 2022-01-28 | 2022-01-28 | Radiator assembly with heat pipe |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN114322616A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN116713706A (en) * | 2023-05-31 | 2023-09-08 | 深圳市鸿慷电子有限公司 | Fin type radiator processing method |
-
2022
- 2022-01-28 CN CN202210103952.0A patent/CN114322616A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN116713706A (en) * | 2023-05-31 | 2023-09-08 | 深圳市鸿慷电子有限公司 | Fin type radiator processing method |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN100499980C (en) | Radiation fin assembly and heat radiating device applied the same | |
TWM627850U (en) | Structure of heat-dissipating module | |
US20050189091A1 (en) | Brazed wick for a heat transfer device and method of making same | |
CN104347429A (en) | Micro channel heat sink manufacturing method | |
CN111163622A (en) | Radiator with folding fins and preparation method thereof | |
CN114322616A (en) | Radiator assembly with heat pipe | |
US12215934B2 (en) | Thermal module structure | |
JP4965242B2 (en) | Manufacturing method of aluminum heat sink | |
TWI824401B (en) | Heat dissipation device assembly | |
CN216820489U (en) | Cooling device combination | |
US20230243596A1 (en) | Heat dissipation device | |
TWM629047U (en) | Radiator assembly with heat pipe | |
TWM629048U (en) | Heat dissipation device assembly | |
TWI795199B (en) | Manufacturing method of thermal module | |
CN217210494U (en) | Radiator assembly with heat pipe | |
CN113056087A (en) | Printed circuit board embedded with micro-channel and preparation method thereof | |
TW202331184A (en) | Heat sink assembly with heat pipe | |
JP4243654B2 (en) | Liquid cooling plate for electronic device parts, method for manufacturing liquid cooling plate | |
TWI784877B (en) | Thermal module structure | |
CN216820488U (en) | cooling module | |
CN217037775U (en) | Combination structure of cooling module | |
CN216820486U (en) | heat sink | |
CN216925253U (en) | Heat radiation module structure | |
TWI861467B (en) | Thermal module assembling structure | |
TW202331187A (en) | Thermal module |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination |