CN110294580A - A kind of method of biotic population and artificial swamp combination processing Sediments - Google Patents
A kind of method of biotic population and artificial swamp combination processing Sediments Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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Abstract
本发明公开了一种生物种群与人工湿地结合处理水体底泥的方法:将生物菌及蚯蚓特训动物种群加入脱水后的底泥中,并在底泥上覆盖植物残枝、落叶,将富集底泥污染物组分的植物种植在底泥表层,构建得到人工湿地;对人工湿地进行日常管理,控制所含底泥的含水率、土壤pH及土壤温度,直至底泥符合回收利用标准,并且表观无黑臭现象。本发明根据河道等水体底泥污染的特点,提出“生物菌、驯化蚯蚓动物种群与人工湿地结合处理底泥及资源化利用技术”,经过生物菌与驯化后动物种群协同处理,可消除底泥中恶臭气味,提高有机污染物分解效率,缩短底泥由黑变黄的时间,较外运、干化焚烧等传统处理方式成本降低。The invention discloses a method for treating water body sediment by combining biological populations and artificial wetlands: adding biological bacteria and earthworm specially trained animal populations into the dehydrated sediment, covering the residual plant branches and fallen leaves on the sediment, The plants that collect the pollutant components of the sediment are planted on the surface of the sediment to construct a constructed wetland; the constructed wetland is managed daily to control the moisture content of the sediment, soil pH and soil temperature until the sediment meets the recycling standards. And there is no black and odor phenomenon on the surface. According to the characteristics of sediment pollution in rivers and other water bodies, the present invention proposes "the combination of biological bacteria, domesticated earthworm animal populations and artificial wetlands to treat sediment and resource utilization technology", and through the cooperative treatment of biological bacteria and domesticated animal populations, the sediment can be eliminated Medium and foul odor, improve the decomposition efficiency of organic pollutants, shorten the time for the bottom sludge to turn from black to yellow, and reduce the cost compared with traditional treatment methods such as transshipment and dry incineration.
Description
技术领域technical field
本发明属于环境治理领域,具体涉及利用生物菌及动物种群(蚯蚓等)与人工湿地处理河道底泥的方法。The invention belongs to the field of environmental management, and in particular relates to a method for treating river channel sediment by using biological bacteria and animal populations (earthworms, etc.) and artificial wetlands.
背景技术Background technique
近年来,随着社会对河道污染问题的日益重视,河道整治与生态修复已取得明显成效,同时也暴露出河道底泥治理中存在的技术少、生态化治理难度大等现实问题,如“黑臭水体”处理问题。河道底泥作为河流生态系统的一部分,也是河道水中污染物质的“源”和“库”,进入水体的污染物质可通过沉淀、吸附、生物吸收等多种物理途径进入底泥,而河道底泥中的污染物质在一定的条件下又会从底泥中重新释放出来进入翻上水体,引发水环境问题。目前,应用于河道底泥治理的技术主要有:河道疏浚、掩蔽,以及微生物修复。In recent years, as the society has paid more and more attention to the problem of river pollution, river regulation and ecological restoration have achieved remarkable results. At the same time, it has also exposed practical problems such as the lack of technology and the difficulty of ecological governance in river sediment treatment, such as "black Smelly water body" treatment problem. As part of the river ecosystem, river sediment is also the "source" and "reservoir" of pollutants in river water. Pollutants entering the water body can enter the sediment through various physical channels such as sedimentation, adsorption, and biological absorption. Under certain conditions, the pollutants in the sediment will be re-released from the sediment and enter the upper water body, causing water environmental problems. At present, the technologies applied to river sediment treatment mainly include: river dredging, masking, and microbial remediation.
(1)疏浚(1) Dredging
传统的河道疏浚方式从早期人工开挖发展到目前应用较多的挖泥船水下采泥,河道淤泥清除对河道环境的干扰越来越小,但清淤底泥存在着比较严重的二次污染问题,运输过程中,会对途经的环境造成影响,也存在河道底泥的安置问题。而且在疏浚的过程中,会对河道原始的生态系统造成影响,将底栖生物、微生物一并带走,打破长期形成的生态平衡,中断生态系统中的食物链,造成生态系统的失调。The traditional river dredging method has developed from early manual excavation to underwater dredger dredging, which is widely used at present. The interference of river silt removal to the river environment is getting smaller and smaller, but there are serious secondary problems in dredging sediment. Pollution, during transportation, will affect the passing environment, and there is also the problem of resettlement of river sediment. Moreover, in the process of dredging, it will affect the original ecosystem of the river, take away benthic organisms and microorganisms, break the long-term ecological balance, interrupt the food chain in the ecosystem, and cause the imbalance of the ecosystem.
(2)掩蔽(2) Masking
掩蔽是在污染的底泥上放置若干层覆盖物,可以是不同的物质或者填料。使污染底泥与水体隔离,防止底泥污染物向水体转移。采用的覆盖物主要有未污染的底泥、沙、砾石或一些复杂的人造地基材料等。掩蔽花费较低,对环境潜在危害小,能有效防止底泥中污染物进入水体而造成二次污染,对水质有明显的改善作用。但是由于在处理过程中需要大量的填料,填料会增加河床高度,不利于河道的原位治理。Masking is the placing of several layers of coverings, which can be different substances or fillers, over the contaminated sediment. Isolate the polluted sediment from the water body and prevent the transfer of sediment pollutants to the water body. The coverings used mainly include unpolluted bottom mud, sand, gravel or some complex artificial foundation materials. The cost of covering is low, the potential harm to the environment is small, and it can effectively prevent the pollutants in the sediment from entering the water body to cause secondary pollution, and it can significantly improve the water quality. However, due to the need for a large amount of filler during the treatment process, the filler will increase the height of the river bed, which is not conducive to the in-situ treatment of the river.
(3)微生物修复(3) Microbial remediation
微生物修复是指在基本不破坏原有自然环境的条件下,通过向河道中投加实验室培养的具有亲合性的微生物或投加可促进底泥环境中原有微生物生长的营养物质,从而实现底泥原位修复的方法。虽然该方法不会产生二次污染,但是其对河道环境要求苛刻,大面积推广难度较大。Microbial remediation refers to the addition of laboratory-cultured microorganisms or nutrients that can promote the growth of original microorganisms in the sediment environment to the river without destroying the original natural environment. Method for in-situ remediation of sediment. Although this method does not produce secondary pollution, it has strict requirements on the river environment and is difficult to promote in a large area.
综上所述,现有技术的缺陷和不足体现在:In summary, the defects and deficiencies of the prior art are reflected in:
1)河道底泥治理过程造成环境二次污染,不利于受污染河道的生态修复。1) The river sediment treatment process causes secondary pollution to the environment, which is not conducive to the ecological restoration of the polluted river.
2)河道污泥处理成本高,污泥资源化程度低。2) The cost of river sludge treatment is high, and the degree of sludge recycling is low.
3)微生物修复对实施环境要求苛刻,不适合大面积推广。3) Microbial remediation has strict requirements on the implementation environment and is not suitable for large-scale promotion.
4)针对河道等水体的污泥处理,尚缺乏有效的动物种群(例如,蚯蚓)驯化手段,导致蚯蚓在底泥中的存活率低,与微生物的协同性差,无法在短期内消除污泥黑臭、恢复土壤生态系统。4) For the sludge treatment of water bodies such as rivers, there is still a lack of effective domestication methods for animal populations (for example, earthworms), resulting in a low survival rate of earthworms in the bottom mud, poor synergy with microorganisms, and the inability to eliminate sludge black in a short period of time. odor and restore the soil ecosystem.
发明内容Contents of the invention
本发明的目的在于提供一种生物种群与人工湿地结合处理水体底泥的方法。The object of the present invention is to provide a method for treating water body sediment by combining biological populations and constructed wetlands.
为达到上述目的,本发明采用了以下技术方案:To achieve the above object, the present invention adopts the following technical solutions:
步骤一:将自水体底部采挖的底泥于处理床内脱水,将生物菌及蚯蚓特训动物种群加入脱水后的底泥中,并在底泥上覆盖植物残枝、落叶,待底泥表层符合种植条件后,将可以富集底泥污染物组分的土著植物种植在底泥表层,构建得到基于处理床的人工湿地;Step 1: Dehydrate the sediment excavated from the bottom of the water body in the treatment bed, add biological bacteria and earthworm special training animal populations to the dehydrated sediment, and cover the residual plant branches and leaves on the sediment, and wait for the sediment to After the surface layer meets the planting conditions, the indigenous plants that can enrich the pollutant components of the sediment are planted on the surface of the sediment to construct an artificial wetland based on the treatment bed;
其中,蚯蚓特训动物种群是通过将生物菌以及蚯蚓种群加入基质中,并通过逐渐增加基质中待处理底泥的比例,对蚯蚓种群进行诱导及驯化而得到的;生物菌为硝化细菌、芽孢杆菌、放线菌、反硝化细菌及聚磷菌;Among them, the special training animal population of earthworms is obtained by adding biological bacteria and earthworm populations into the substrate, and gradually increasing the proportion of the substrate to be treated in the substrate to induce and domesticate the earthworm populations; the biological bacteria are nitrifying bacteria, spores bacilli, actinomycetes, denitrifying bacteria and phosphorus accumulating bacteria;
步骤二:在对人工湿地进行日常管理中控制处理床内所含底泥的含水率、土壤pH及土壤温度,直至处理床内的底泥符合回收利用标准,并且表观无黑臭现象。Step 2: During the daily management of the artificial wetland, control the moisture content, soil pH and soil temperature of the sediment contained in the treatment bed until the sediment in the treatment bed meets the recycling standard, and there is no black and odor phenomenon on the surface.
优选的,所述生物菌是将硝化细菌、芽孢杆菌、放线菌、反硝化细菌及聚磷菌的出发菌株在添加有待处理底泥的培养基中培养驯化后而得到的。Preferably, the biological bacteria are obtained by cultivating and acclimating starting strains of nitrifying bacteria, bacillus, actinomycetes, denitrifying bacteria and phosphorus accumulating bacteria in a medium added with bottom sludge to be treated.
优选的,所述基质选自水体(例如,河道、湖泊)附近的表观无黑臭现象的旱地土壤。Preferably, the substrate is selected from dry land soils near water bodies (for example, rivers, lakes) that do not appear to have black and odorous phenomena.
优选的,所述处理床开挖于水体(例如,河道、湖泊)旁,开挖的立面设置有粒径由上至下逐渐增加的用于净化污水的多层填料,处理床底部设置有与外界连通的排水通道以及防渗层。Preferably, the treatment bed is excavated beside a water body (for example, a river, a lake), and the excavated façade is provided with multi-layer fillers for purifying sewage whose particle size gradually increases from top to bottom, and the bottom of the treatment bed is provided with Drainage channels and anti-seepage layers that communicate with the outside world.
优选的,所述脱水采用重力释水方式,脱水至含水率<80%,得到待处理底泥。Preferably, the dehydration adopts the method of gravity release, and the dehydration is performed until the water content is less than 80%, so as to obtain the untreated sediment.
优选的,所述特训动物种群按照1000~1500条/m2的投放比例加入至脱水后的底泥(即处理床内的待处理底泥)。Preferably, the specially trained animal population is added to the dehydrated bottom sludge (that is, the bottom sludge to be treated in the treatment bed) at a feeding ratio of 1000-1500 animals/m 2 .
优选的,所述步骤二中,在底泥的土壤pH为6.0~7.5,及土壤温度大于8℃情况下,控制底泥的含水率小于60%,从而缩短对底泥的处理周期(处理时间为2个月左右)。Preferably, in said step 2, when the soil pH of the bottom mud is 6.0~7.5, and the soil temperature is greater than 8°C, the moisture content of the bottom mud is controlled to be less than 60%, thereby shortening the treatment period (treatment time) of the bottom mud for about 2 months).
优选的,还包括以下步骤:将经过步骤二处理后得到的底泥,在分离蚯蚓种群和蚯蚓粪便后作为园林土壤或制作建筑砖材。Preferably, the following step is also included: use the bottom mud obtained after the treatment in the second step as garden soil or make building bricks after separating the earthworm population and earthworm droppings.
优选的,所述生物菌及蚯蚓特训动物种群还可以通过以下方式加入脱水后的底泥中:将经过步骤二处理后得到的底泥,在不分离蚯蚓种群和蚯蚓粪便情况下,直接与后续继续经采挖及脱水后得到的底泥(处理床内的待处理底泥)混合,实现底泥的循环处理。Preferably, the biological bacteria and earthworm special training animal populations can also be added to the dehydrated bottom sludge in the following manner: the bottom sludge obtained after the treatment in step 2 is directly mixed with Subsequent mixing of the bottom sludge obtained after excavation and dehydration (the bottom sludge to be treated in the treatment bed) is continued to realize the circular treatment of the bottom sludge.
本发明的有益效果体现在:The beneficial effects of the present invention are reflected in:
本发明根据河道等水体底泥污染的特点,提出“生物菌、驯化蚯蚓动物种群与人工湿地结合处理底泥及资源化利用技术”,经过生物菌与驯化后动物种群协同处理下,可消除底泥中恶臭气味,提高有机污染物分解效率,缩短底泥由黑变黄的时间,较外运、干化焚烧等传统处理方式成本降低。本发明通过有机物、重金属减量及渗滤液减量,可以达到污泥减量化,除臭效果明显,没有二次污染,保证环境安全。利用生物菌、蚯蚓特训动物种群与人工湿地相结合的处理方式,可以有效去除氨氮,削减底泥COD类有机物,处理后的底泥可以当作有机肥料用于园林施肥,还可以制作生态砖,实现较高程度的资源化利用,使水体底泥(例如,河道底泥)得到充分合理地利用和稳妥处置。According to the characteristics of sediment pollution in rivers and other water bodies, the present invention proposes "the combination of biological bacteria, domesticated earthworm animal populations and artificial wetlands to treat sediment and resource utilization technology", and through the cooperative treatment of biological bacteria and domesticated animal populations, it can eliminate The foul smell in the mud improves the decomposition efficiency of organic pollutants, shortens the time for the bottom mud to turn from black to yellow, and reduces the cost compared with traditional treatment methods such as transshipment and dry incineration. The present invention can achieve sludge reduction through the reduction of organic matters, heavy metals and leachate, has obvious deodorizing effect, has no secondary pollution, and ensures environmental safety. The combination of biological bacteria, earthworm special training animal population and artificial wetland can effectively remove ammonia nitrogen and reduce COD organic matter in sediment. The treated sediment can be used as organic fertilizer for garden fertilization, and can also be used to make ecological bricks , to achieve a higher degree of resource utilization, so that the water body sediment (for example, river channel sediment) can be fully and reasonably utilized and safely disposed of.
本发明提出了利用人工湿地对因污染遭到破坏的河道底泥土壤生态环境进行修复,其中,通过蚯蚓动物种群的肠道消化分解,对河道底泥中的有机物进行分解和矿化,从而消除臭味和降低N、P含量,而且蚯蚓体内的黄色细胞可以富集使底泥变黑的重金属元素(如:Fe、Mn等),可有效降低底泥中有机物和重金属的含量;驯化后的动物种群与生物菌协同作用,动物可以增加孔隙度、含氧量,促进好氧微生物扩繁、生长,好氧发酵加快,促进生长,好氧生物菌(硝化菌、芽孢杆菌、乳酸菌)调节动物生存环境(土壤环境温度、pH、湿度等),有利于动物种群生长(特别是在冬季生长)。驯化后的蚯蚓动物种群与植物共同作用,实现对有机物负荷和N、P含量进一步去除,深度去除污泥中的残留有机物、重金属污染物。The present invention proposes to use the artificial wetland to restore the soil ecological environment of the river bottom mud destroyed by pollution, wherein, through the intestinal digestion and decomposition of the earthworm animal population, the organic matter in the river bottom mud is decomposed and mineralized, thereby eliminating Odor and reduce N, P content, and the yellow cells in the earthworm body can enrich the heavy metal elements (such as: Fe, Mn, etc.) that make the bottom mud black, which can effectively reduce the content of organic matter and heavy metals in the bottom mud; Animal populations and biological bacteria work together, animals can increase porosity and oxygen content, promote the proliferation and growth of aerobic microorganisms, accelerate aerobic fermentation, promote growth, and aerobic biological bacteria (nitrifying bacteria, bacillus, lactic acid bacteria) regulate animal The living environment (soil ambient temperature, pH, humidity, etc.) is conducive to the growth of animal populations (especially in winter). The domesticated earthworm animal populations work together with plants to further remove the organic matter load and N and P content, and deeply remove the residual organic matter and heavy metal pollutants in the sludge.
进一步的,处理床下层防渗处理,处理过程中的少量污泥渗流液通过植物吸收、蒸发,含水量减少,动物与植物分解、转化作用,使人工湿地的水质得到净化,使处理过程排放的地表水更加符合环境质量要求。Further, the anti-seepage treatment of the lower layer of the treatment bed, a small amount of sludge seepage liquid during the treatment process is absorbed and evaporated by plants, the water content is reduced, and animals and plants are decomposed and transformed, so that the water quality of the constructed wetland is purified, and the water discharged during the treatment process Surface water is more in line with environmental quality requirements.
附图说明Description of drawings
图1为生物种群的污泥处理流程图;Fig. 1 is the sludge treatment flowchart of biological population;
图2为人工湿地的结构示意图;Figure 2 is a schematic diagram of the structure of the constructed wetland;
图3为微生物、动物种群与人工湿地协同处理原理示意图;Figure 3 is a schematic diagram of the principle of collaborative treatment of microorganisms, animal populations and constructed wetlands;
图4为微生物与蚯蚓的协同作用原理示意图;Figure 4 is a schematic diagram of the principle of synergy between microorganisms and earthworms;
图5为蚯蚓与人工湿地植物的协同作用原理示意图;Figure 5 is a schematic diagram of the principle of synergy between earthworms and constructed wetland plants;
图6为环保清淤及淤泥(底泥)固化处理工艺图;Fig. 6 is environmental protection dredging and silt (bottom mud) solidification process diagram;
图中:1-植物,2-蚯蚓,3-生物菌,4-水池,5-沙,6-砾石,7-小石块,8-大石块,9-土工管袋,10-加药罐,W取值为4米,H取值为0~6米。In the figure: 1-plant, 2-earthworm, 3-biological bacteria, 4-pool, 5-sand, 6-gravel, 7-small stone, 8-big stone, 9-geotechnical tube bag, 10-dosing For tanks, the value of W is 4 meters, and the value of H is 0-6 meters.
具体实施方式Detailed ways
下面结合附图和实施例对本发明做进一步详细说明。所述实施例仅用于解释本发明,而非对本发明保护范围的限制。The present invention will be described in further detail below in conjunction with the accompanying drawings and embodiments. The examples are only used to explain the present invention, not to limit the protection scope of the present invention.
为了能够对河道底泥进行经济化、资源化的修复,本发明提出了一种用生物菌、驯化蚯蚓等动物种群和人工湿地相互结合处理河道底泥的方法。In order to restore the river bottom mud economically and resourcefully, the present invention proposes a method for treating the river bottom mud by combining animal populations such as biological bacteria, domesticated earthworms and artificial wetlands.
(一)生物菌、动物种群驯化(1) Domestication of biological bacteria and animal populations
1)生物菌制剂1) Biological preparations
生物菌制剂采用微生物增殖培养得到的菌液,菌液中所含有的微生物可以不断的产生多种生物酶,避免使用单一生物酶因失活而降低处理能力。生物菌主要降解底泥中相对容易降解的有机物部分和致臭物质,对于难降解的高分子聚合物等有机物起到的降解作用有限(无法有效处理导致底内变黑的污染物)。The biological bacteria preparation adopts the bacterial liquid obtained by microbial proliferation and culture. The microorganisms contained in the bacterial liquid can continuously produce a variety of biological enzymes, avoiding the use of a single biological enzyme to reduce the processing capacity due to inactivation. Biological bacteria mainly degrade the organic parts and odor-causing substances that are relatively easy to degrade in the sediment, and have limited degradation effect on organic substances such as high molecular polymers that are difficult to degrade (the pollutants that cause the bottom to turn black cannot be effectively treated).
菌液A:Bacteria solution A:
1)取待处理河道底泥制成悬浮液,然后将悬浮液(底泥在最终培养体系内的质量分数为70%~85%)与硝化细菌、芽孢杆菌加入培养基(为去除底泥中的有机物,采用的培养基为牛肉膏蛋白胨琼脂培养基,分别提供相应的碳源和氮源,调整pH到7.2~7.6),在摇床上振荡培养(温度20~25℃,湿度60%~70%),使得硝化细菌、芽孢杆菌得到驯化并扩大种群规模。1) Take the river bottom mud to be treated to make a suspension, then add the suspension (the mass fraction of the bottom mud in the final culture system is 70% to 85%), nitrifying bacteria and bacillus to the culture medium (in order to remove Organic matter, the medium used is beef extract peptone agar medium, provide corresponding carbon source and nitrogen source respectively, adjust the pH to 7.2-7.6), shake culture on a shaker (temperature 20-25 ℃, humidity 60%-70 %), making nitrifying bacteria and bacillus domesticated and expanding the population size.
2)取待处理河道底泥制成悬浮液,然后将悬浮液(底泥在最终培养体系内的质量分数为70%~85%)与放线菌加入淀粉硝酸盐培养基,在摇床上振荡培养(温度20~25℃,湿度60%~70%),使得放线菌得到驯化并扩大种群规模。2) Take the river bottom mud to be treated to make a suspension, then add the suspension (the mass fraction of the bottom mud in the final culture system is 70% to 85%) and actinomycetes to the starch nitrate medium, and vibrate on a shaker Cultivation (temperature 20-25° C., humidity 60%-70%) enables the actinomycetes to be domesticated and the population size to be enlarged.
3)将硝化细菌、芽孢杆菌菌液与放线菌菌液混合(例如,按照等体积比混合)。3) Mix the nitrifying bacteria, the bacillus bacteria solution and the actinomycetes bacteria solution (for example, mix according to the equal volume ratio).
菌液B:Bacteria solution B:
取待处理河道底泥制成悬浮液,然后将悬浮液(底泥在最终培养体系内的质量分数为70%~85%)与反硝化细菌加入好氧反硝化细菌培养基,在摇床上振荡培养(温度20~25℃,湿度60%~70%),使得反硝化细菌得到驯化并扩大种群规模。Take the river bottom mud to be treated to make a suspension, then add the suspension (the mass fraction of the bottom mud in the final culture system is 70% to 85%) and the denitrifying bacteria into the aerobic denitrifying bacteria culture medium, and vibrate on the shaker Cultivation (temperature 20-25° C., humidity 60%-70%) enables the denitrifying bacteria to be domesticated and the population scale to be enlarged.
菌液C:Bacteria solution C:
取待处理河道底泥制成悬浮液,然后将悬浮液(底泥在最终培养体系内的质量分数70%~85%)与聚磷菌加入富磷培养基(pH为7.0~7.1),避光培养(温度20~25℃,湿度60%~70%),使得聚磷菌得到驯化并扩大种群规模。Take the river channel sediment to be treated to make a suspension, and then add the suspension (the mass fraction of the sediment in the final culture system is 70% to 85%) and phosphorus-accumulating bacteria into the phosphorus-rich medium (pH is 7.0 to 7.1), avoiding Light cultivation (temperature 20-25° C., humidity 60%-70%) enables the phosphorus-accumulating bacteria to be domesticated and the population size to be expanded.
将含有驯化后生物菌的菌液A、B、C混合(例如,按照等体积比混合),共同组成好氧生物菌制剂(单位体积菌体数为2×108~4×108个/mL)。Mix the bacteria liquids A, B, and C containing the domesticated biological bacteria (for example, mix according to the equal volume ratio) to form an aerobic biological bacteria preparation (the number of bacteria per unit volume is 2×10 8 to 4×10 8 / mL).
2)动物种群驯化2) Animal population domestication
根据动物的生活习性和生态位,结合污泥特点,通过驯化将蚯蚓等动物引入河道污泥治理工程。According to the living habits and ecological niche of animals, combined with the characteristics of sludge, animals such as earthworms are introduced into the river sludge treatment project through domestication.
以蚯蚓种群的驯化为例,参见图1:Take the domestication of earthworm populations as an example, see Figure 1:
2.1)诱导2.1) Induction
将取自河道附近的旱地土壤(无污染导致的黑臭)铺于培养床内,控制土壤的铺层厚度(0.2~1.5米)、含水率(<80%)、土壤pH(6.0~7.5)、土壤温度(>8℃),将蚯蚓投放到土壤内,同时将以上制备的生物菌制剂接种(300~500mL/m2)入该土壤内,待蚯蚓种群在土壤内正常生长后(本步骤大致需要12~24小时),转至步骤2.2;Lay the dry land soil near the river (no black odor caused by pollution) in the cultivation bed, and control the thickness of the soil layer (0.2-1.5 meters), moisture content (<80%), and soil pH (6.0-7.5) , soil temperature (>8°C), put earthworms into the soil, and at the same time inoculate (300-500mL/m 2 ) the biological preparation prepared above into the soil, and wait for the earthworm population to grow normally in the soil (this step It takes about 12 to 24 hours), go to step 2.2;
2.2)50%、75%、90%污泥驯化2.2) 50%, 75%, 90% sludge domestication
2.2.1)将生长蚯蚓种群的土壤按照1:1的体积比与待处理河道底泥混合,重新铺于培养床内(作N个批次,N≥10),采用相同的控制条件,筛选在混合土壤(50%污泥)中正常生长的蚯蚓种群(本步骤大致需要12~120小时);2.2.1) Mix the soil of the growing earthworm population with the river sediment to be treated according to the volume ratio of 1:1, and respread it in the culture bed (make N batches, N≥10), and use the same control conditions to screen Earthworm populations normally growing in mixed soil (50% sludge) (this step takes approximately 12 to 120 hours);
2.2.2)将步骤2.2.1筛选后的生长蚯蚓种群的混合土壤按照1:3的体积比与待处理河道底泥混合,重新铺于培养床内(作N个批次,N≥5),采用相同的控制条件,筛选在混合土壤(75%污泥)中正常生长的蚯蚓种群(本步骤大致需要24~72小时);2.2.2) Mix the mixed soil of the growing earthworm population screened in step 2.2.1 with the river sediment to be treated according to the volume ratio of 1:3, and respread in the culture bed (make N batches, N≥5) , using the same control conditions to screen the normal growth earthworm populations in mixed soil (75% sludge) (this step generally takes 24 to 72 hours);
2.2.3)将步骤2.2.2筛选后的生长蚯蚓种群的混合土壤按照1:9的体积比与待处理河道底泥混合,重新铺于培养床内(作N个批次,N≥3),采用相同的控制条件,筛选在混合土壤(90%污泥)中正常生长的蚯蚓种群(本步骤大致需要12~120小时);转至步骤2.3;2.2.3) Mix the mixed soil of the growing earthworm population screened in step 2.2.2 with the river sediment to be treated according to the volume ratio of 1:9, and respread in the culture bed (make N batches, N≥3) , using the same control conditions, screen the normal growth of earthworm populations in mixed soil (90% sludge) (this step generally takes 12 to 120 hours); go to step 2.3;
2.3)100%污泥驯化2.3) 100% sludge domestication
将步骤2.2.3筛选后的混合土壤中的蚯蚓种群分离,重新投放至待处理河道底泥(100%污泥,作N个批次,N≥10)内,采用相同的控制条件继续筛选(本步骤大致需要24~120小时)。The earthworm population in the mixed soil after the screening of step 2.2.3 is separated, put into the bottom mud of the river course to be treated again (100% sludge, make N batches, N≥10), adopt the same control condition to continue screening ( This step generally takes 24 to 120 hours).
最终,由驯化后的蚯蚓与生物菌制剂(硝化细菌、芽孢杆菌、放线菌、反硝化细菌和聚磷菌)组成稳定的生物菌、特训动物种群种子,其中,蚯蚓利用自身丰富的酶系统可以将有机污染物迅速分解,转化成易于利用的营养物质,污泥(河道底泥)经过驯化后的蚯蚓处理后,有机质含量增加,水溶性的物质增加(低分子量的有机酸和氨基酸等),加速了堆肥稳定化过程,增加微生物活性(使得以上生物菌可以以待处理底泥作为碳源、氮源及其他营养物质的来源,并通过生物转化降解底泥中所含的一定的污染物,而且使用生物菌降解底泥中的污染物不会引入二次污染)。动物与微生物的协同作用可加速有机物的分解,并快速除臭及恢复底泥本身颜色(例如,去除黑色物质)。Finally, stable biological bacteria and specially trained animal population seeds are composed of domesticated earthworms and biological bacteria preparations (nitrifying bacteria, bacillus, actinomycetes, denitrifying bacteria, and phosphorus-accumulating bacteria). Among them, earthworms use their own abundant enzymes to The system can quickly decompose organic pollutants and convert them into easily available nutrients. After the sludge (river sediment) is treated by domesticated earthworms, the organic matter content increases, and the water-soluble substances increase (low molecular weight organic acids and amino acids, etc.) ), accelerated the compost stabilization process, and increased microbial activity (so that the above biological bacteria can use the bottom mud to be treated as a source of carbon, nitrogen and other nutrients, and degrade certain pollution contained in the bottom mud through biotransformation substances, and the use of biological bacteria to degrade the pollutants in the sediment will not introduce secondary pollution). The synergistic effect of animals and microorganisms can accelerate the decomposition of organic matter, and quickly deodorize and restore the color of the sediment itself (for example, remove black matter).
(二)人工湿地植物筛选(2) Screening of Constructed Wetland Plants
移植土著植物1,通过试验筛选出对氮去除效果比较好的品种,例如,菖蒲、马兰、石菖蒲,以及对磷去除效果比较好的品种,例如,马兰、萱草、菖蒲;依据当地气候环境选择适宜污染环境生长、生物量较大的品种,例如,鸭舌草、田皂角、芦苇、蒲草等。Transplant indigenous plants 1, and select varieties with better nitrogen removal effects through experiments, such as Calamus, Malan, and Shichangpu, and varieties with better phosphorus removal effects, such as Malan, Hemerocallis, and Calamus; choose according to the local climate environment It is suitable for species with large biomass that grow in polluted environment, for example, bermudagrass, saponins, reeds, cattails, etc.
(三)污泥生物处理床施工(3) Construction of sludge biological treatment bed
参见图2,处理床为在河道旁开挖、建设的水池4,水池4底部具有出水管道(用于排水),并铺设防渗层(土工膜防渗),水池4侧壁依次堆叠四层透水填料,填料层自下而上依次采用的材料为大石块8、小石块7、砾石6及沙5,由此构建出粒径由上至下逐渐增加的净化污水的装置。Referring to Fig. 2, the treatment bed is a pool 4 excavated and built beside the river, the bottom of the pool 4 has an outlet pipe (for drainage), and an anti-seepage layer (seepage-proof geomembrane) is laid, and the side walls of the pool 4 are stacked in four layers Permeable packing, the materials used in the packing layer from bottom to top are large stones 8, small stones 7, gravel 6 and sand 5, thus constructing a device for purifying sewage with particle sizes gradually increasing from top to bottom.
(四)生物菌、特训动物种群和人工湿地相互协同处理河道底泥(4) Biological bacteria, specially trained animal populations and constructed wetlands cooperate with each other to treat river sediment
1)采挖底泥及脱水1) Excavation and dehydration of sediment
参见图6,将采挖的底泥脱水(例如,利用土工管袋9进行静置、排水并自然固化,可利用加药罐10,在采挖的底泥中预先加入絮凝剂,加速脱水),固化中分离的污水经处理床壁面的填料层过滤,使排出的水得到净化,有效避免采挖底泥造成的对河道水体的二次污染。Referring to Fig. 6, the excavated bottom mud is dehydrated (for example, utilize the geotechnical tube bag 9 to stand still, drain and solidify naturally, and can utilize the dosing tank 10 to add flocculant in advance in the excavated bottom mud to accelerate dehydration) , The sewage separated during solidification is filtered by the packing layer on the wall of the treatment bed to purify the discharged water, effectively avoiding the secondary pollution of the river water body caused by excavating the sediment.
2)人工湿地施工2) Constructed wetland construction
自然固化一定时间后(24~72小时,含水率小于80%),即为待处理河道底泥(处理床内底泥的厚度可设置为0.2~1.5米)。将生物菌3、特训动物种群种子(好氧生物菌制剂300~500mL/m2,,蚯蚓2的投放比例为1000~1500条/m2)投放至待处理的河道底泥中,河道底泥表面可覆盖收集自河道内及河道附近的植物残枝、落叶。日常生产管理中控制含水量(例如,含水率小于60%)并定期检测处理床内土壤的理化指标(例如,土壤pH为6.0~7.5、土壤温度大于8℃),参照《城镇污水处理厂污泥处置土地改良用泥质》(GB/T24600-2009),待河道底泥表层土壤检测合格,在处理床内河道底泥表层种植筛选的植物品种(例如,适宜处理有机物和吸收重金属效果较好的芦苇、蒲草),利用植物对土壤中的氮、磷进行去除,植物底部根生态系统中食物链,不仅发挥了植物对重金属的富集作用,也促进植物底部分布的蚯蚓等生物种群对重金属的二次富集。After natural solidification for a certain period of time (24-72 hours, water content less than 80%), it is the river bottom mud to be treated (the thickness of the bottom mud in the treatment bed can be set to 0.2-1.5 meters). Put biological bacteria 3 and seeds of specially trained animal populations (300-500mL/m 2 for aerobic biological bacteria preparation, and 1000-1500 earthworms 2/m 2 ) into the river bottom mud to be treated. The mud surface can be covered with plant residues and fallen leaves collected in and near the river. In daily production management, control the water content (for example, the moisture content is less than 60%) and regularly detect the physical and chemical indicators of the soil in the treatment bed (for example, the soil pH is 6.0-7.5, and the soil temperature is greater than 8°C). Mud Quality for Land Improvement for Mud Disposal (GB/T24600-2009), after the surface soil of the river bottom mud is tested to be qualified, the selected plant species are planted on the surface of the river bottom mud in the treatment bed (for example, suitable for treating organic matter and having a good effect on absorbing heavy metals Reeds and cattail grasses) use plants to remove nitrogen and phosphorus in the soil. The food chain in the root ecosystem at the bottom of plants not only plays a role in the enrichment of heavy metals by plants, but also promotes the accumulation of heavy metals by earthworms and other biological populations distributed at the bottom of plants. secondary enrichment.
3)回收利用及循环处理3) Recycling and recycling
参照《城镇污水处理厂污泥处置土地改良用泥质》(GB/T 24600-2009),处理床内底泥全部合格后,因污染遭到破坏的河道底泥土壤生态环境得到修复,可以经提取蚯蚓及蚯蚓粪后,作为园林土壤或制作用于城市建设的雨水构筑物系统中生态砖,实现较高程度资源化利用,同时回收的含有生物种群的处理合格的河道底泥,可直接与新采挖并自然固化的河道底泥按比例(体积比1:1~1:2)搅拌混合,循环处理底泥,加快处理进程。Referring to the "Mud Quality for Land Improvement of Sludge Disposal in Urban Sewage Treatment Plants" (GB/T 24600-2009), after all the bottom sludge in the treatment bed is qualified, the ecological environment of the river bottom sludge damaged by pollution will be restored and can be recovered by After extracting earthworms and vermicompost, use them as garden soil or make ecological bricks in the rainwater structure system for urban construction to achieve a high degree of resource utilization. At the same time, the recycled river sediment containing biological populations can be directly used with new The excavated and naturally solidified river channel sediment is mixed in proportion (volume ratio 1:1 to 1:2), and the sediment is recycled to speed up the processing process.
4)修复河道底泥土壤生态环境的原理4) The principle of restoring the ecological environment of river bottom mud soil
4.1)生物菌、特训动物种群和人工湿地相互协同关系4.1) The synergistic relationship between biological bacteria, specially trained animal populations and constructed wetlands
如图3所示,用训化的蚯蚓特有的生理功能及其与环境中微生物的协同作用对有机物质进行生物降解,将底泥及残枝、落叶等废弃物中C、N等养分转化为更利于植物吸收的形态(固定态),蚯蚓对污泥有机物含量消减的同时,还可以对Cu、Zn、Cd、Fe等重金属进行有效的富集和转化,同时排出蚯蚓粪。生物菌、特训动物种群和人工湿地系统相互结合,不仅可以促进植物残枝、落叶及底泥中污染物的降解、有机物质的分解和矿化,还具有混合土壤、改善土壤结构、提高土壤透气性和田间持水量的能力,实现腐殖质的稳定化和污染物减量化,增强微生物多样性。从而,加速对因污染而遭到破坏的河道底泥土壤生态环境的修复。As shown in Figure 3, organic matter is biodegraded by using the unique physiological functions of trained earthworms and their synergy with microorganisms in the environment, and the nutrients such as C and N in the sediment, residual branches, fallen leaves and other wastes are converted into The form (fixed state) that is more conducive to plant absorption, while earthworms reduce the content of organic matter in sludge, can also effectively enrich and transform heavy metals such as Cu, Zn, Cd, Fe, etc., and discharge vermicompost at the same time. The combination of biological bacteria, specially trained animal populations and constructed wetland system can not only promote the degradation of plant residues, fallen leaves and pollutants in the sediment, the decomposition and mineralization of organic matter, but also have the functions of mixing soil, improving soil structure, and improving soil quality. The ability of air permeability and field water holding capacity, the stabilization of humus and the reduction of pollutants, and the enhancement of microbial diversity. Thus, the restoration of the ecological environment of the river bottom mud soil destroyed by pollution is accelerated.
修复主要包括三个阶段。第一阶段,生物菌、特训动物种群中的蚯蚓的吞噬、消化作用将污泥中的大颗粒物质破碎,并将其中的难降解成分转化为易降解成分,然后再由微生物群落吸收利用、氧化分解,如将不溶性大分子有机物(蛋白质、脂类、多糖类等)转化为氨基酸、葡萄糖等水溶性有机物。第二阶段,蚯蚓的肠内壁分泌多种酶(脂肪酶、蛋白酶等),在这些酶和微生物的联合作用下,将有机物进一步水解,从而有利于有机物的去除。第三阶段,经过蚯蚓的消化作用,底泥中的有机物绝大部分被分解和消化,极少的未消化处理的有机物质则排除体外(形成蚯蚓粪)。检测合格后的河道底泥可以回收利用(例如,作为园林土壤),也可以与未处理的底泥搅拌混合,循环利用于第一阶段。Restoration mainly consists of three stages. In the first stage, the phagocytosis and digestion of biological bacteria and earthworms in specially trained animal populations break up the large particles in the sludge, and convert the refractory components into easily degradable components, which are then absorbed and utilized by the microbial community. Oxidative decomposition, such as converting insoluble macromolecular organic substances (proteins, lipids, polysaccharides, etc.) into water-soluble organic substances such as amino acids and glucose. In the second stage, the inner wall of the earthworm's intestine secretes various enzymes (lipase, protease, etc.), and under the joint action of these enzymes and microorganisms, the organic matter is further hydrolyzed, thereby facilitating the removal of the organic matter. In the third stage, through the digestion of earthworms, most of the organic matter in the bottom mud is decomposed and digested, and a very small amount of undigested organic matter is excreted from the body (forming vermicompost). The river channel sediment after passing the test can be recycled (for example, as garden soil), or mixed with untreated sediment, and recycled in the first stage.
4.2)生物菌与特训动物种群协同作用4.2) Synergy between biological bacteria and specially trained animal populations
参见图4,在河道底泥中微生物以胶体态、溶解性有机物为食,并形成生物膜。而蚯蚓以悬浮物(处理床底部存在少量积水)和微生物为食,疏松底泥。蚯蚓捕食分解生物膜,使污泥减量和稳定。蚯蚓在觅食过程中上下钻动,不仅有利于微生物迁移和对污染物的降解,而且可以增加处理床内的底泥中的氧含量,使其自然通风,可以取代传统污水处理中的曝气池。即在人工湿地系统中,微生物与蚯蚓在生物链中是一种协同互生的关系,经过微生物的消化行成的生物膜,又成为高营养级特训动物种群的食物来源,而蚯蚓的蠕动作用,又为微生物提供了氧环境,反过来有助于微生物的降解有机物。Referring to Figure 4, microorganisms feed on colloidal and dissolved organic matter in the channel sediment and form biofilms. Earthworms feed on suspended solids (a small amount of accumulated water at the bottom of the treatment bed) and microorganisms to loosen the bottom mud. Earthworms prey on and decompose biofilm, reducing and stabilizing sludge. Earthworms drill up and down during the foraging process, which is not only beneficial to the migration of microorganisms and the degradation of pollutants, but also increases the oxygen content in the sediment in the treatment bed to make it naturally ventilated, which can replace the aeration in traditional sewage treatment pool. That is to say, in the constructed wetland system, microorganisms and earthworms are in a synergistic relationship in the biological chain. The biofilm formed by the digestion of microorganisms becomes a food source for special training animal populations with high nutritional levels, while the creeping action of earthworms , and provides an oxygen environment for microorganisms, which in turn helps microorganisms to degrade organic matter.
4.3)特训动物种群与人工湿地植物的协同作用4.3) Synergy between specially trained animal populations and constructed wetland plants
参见图5,利用驯化后蚯蚓的“松土”作用改善内部的水力传导以及溶解氧的传输,提高微生物的功能,显著提高人工湿地植物去除污染物的能力。具体表现在:See Figure 5, using the "loosening" effect of domesticated earthworms to improve internal hydraulic conduction and dissolved oxygen transmission, improve the function of microorganisms, and significantly improve the ability of constructed wetland plants to remove pollutants. Specifically in:
1、人工湿地植物的生长改变处理床内的底泥的流态,植物根系和茎杆对水流的阻碍作用有利于均匀布水(处理床为露天状态,接收自然降雨),延长水力停留时间(HRT),通过对水力停留时间的延长,有更加充分的时间进行硝化与反硝化作用,更好的去除底泥中渗滤污水所含的氮。1. The growth of artificial wetland plants changes the flow state of the sediment in the treatment bed, and the obstruction of plant roots and stems to the water flow is conducive to uniform water distribution (the treatment bed is in the open state and receives natural rainfall), prolonging the hydraulic retention time ( HRT), through the extension of the hydraulic retention time, there is more time for nitrification and denitrification, and better removal of nitrogen contained in the percolation sewage in the sediment.
2、人工湿地植物的根系形成了有利于微生物生长的微环境,在植物根系附近形成有利于硝化作用的好氧微区,同时在远离根系的厌氧区里含有大量可利用的碳源,这又提供了反硝化条件。2. The root system of constructed wetland plants forms a micro-environment that is conducive to the growth of microorganisms, and forms an aerobic micro-zone that is conducive to nitrification near the plant root system. At the same time, there is a large amount of available carbon source in the anaerobic zone far away from the root system. Also provides denitrification conditions.
3、人工湿地植物的生长对各种营养物尤其是硝酸盐氮(N-NO3-)具有吸收作用。3. The growth of constructed wetland plants can absorb various nutrients, especially nitrate nitrogen (N-NO 3 -).
(五)处理效果评价(5) Treatment effect evaluation
1、西安浐灞生态区河道底泥处理实验1. Experiment on river sediment treatment in Xi'an Chan-Ba Ecological Zone
取样点污泥采集:河底淤泥积厚约2米,污泥发黑、有刺鼻恶臭,采样时间:2018年7月20日。利用处理床处理30日后(植物是处理后第1日种植的),生物种群降解污染物效果明显,颜色由黑变黄,已无臭味。处理至60日后,生物种群降解污染物效果明显,底泥表观为黄色。Sludge collection at the sampling point: The river bottom silt is about 2 meters thick, the sludge is black, and has a pungent odor. Sampling time: July 20, 2018. After using the treatment bed for 30 days (the plants were planted on the first day after the treatment), the biological population degraded the pollutants effectively, the color changed from black to yellow, and there was no odor. After 60 days of treatment, the effect of biological populations on degrading pollutants was obvious, and the sediment appeared yellow.
将采集的样品(原样)与处理后的样品(处理样)委托具有检测资质的单位进行检测并出具检测报告,参见表1。The collected samples (original samples) and processed samples (processed samples) are entrusted to a unit with testing qualifications for testing and a testing report is issued, see Table 1.
表1河道底泥部分指标检测结果Table 1 Detection results of some indicators of river sediment
2、河道底泥处理实验结果评价2. Evaluation of experimental results of river sediment treatment
1)对导致底泥散发刺鼻恶臭味的有机物的处理率达69%,除臭效果明显。1) The treatment rate of the organic matter that causes the pungent and foul smell of the bottom mud is as high as 69%, and the deodorization effect is obvious.
2)河道底泥处理样中重金属含量低于国家标准《城镇污水处理厂污泥处置土地改良用泥质》(GB/T 24600-2009)。重金属富集于原位培养的微生物、特驯动物(蚯蚓)等生物种群内。2) The content of heavy metals in the river sediment treatment samples is lower than the national standard "Mud Quality for Land Improvement of Sludge Disposal in Urban Sewage Treatment Plants" (GB/T 24600-2009). Heavy metals are enriched in in situ cultured microorganisms, specially tamed animals (earthworms) and other biological populations.
3)处理陈本和效益比较参见表2。3) See Table 2 for the comparison of treatment costs and benefits.
表2.不同技术处理河道污泥成本、效益比较Table 2. Comparison of costs and benefits of different technologies for treating river sludge
(六)河道底泥处理技术特点(6) Technical characteristics of river sediment treatment
本发明提供了一种生物菌、特训动物种群与人工湿地结合处理河道底泥的方法。该方法主要有以下优势:The invention provides a method for treating river channel sediment by combining biological bacteria, specially trained animal populations and artificial wetlands. This method mainly has the following advantages:
1)用生物技术解决河道底泥污染物处理问题,变废弃物为生物有机质,可以用来加工有机肥料,蚯蚓可以做饲料、有机食品、医药和日用化学品,实现资源综合利用和循环发展。1) Use biotechnology to solve the problem of river sediment pollutant treatment, turn waste into bio-organic matter, which can be used to process organic fertilizers, and earthworms can be used as feed, organic food, medicine and daily chemicals to achieve comprehensive utilization of resources and circular development .
2)强化生物(微生物与特训动物种群)处理,增进动物、微生物、植物协同净化效应,提高对河道底泥污染物处理速率、效能,缩短处理时间。2) Strengthen biological (microbial and specially trained animal populations) treatment, enhance the synergistic purification effect of animals, microorganisms, and plants, improve the treatment rate and efficiency of river sediment pollutants, and shorten the treatment time.
3)基于食物链理论,通过引入生物群使食物链“加环”,利用动物与微生物的协调作用加速污染物分解转化。3) Based on the food chain theory, the food chain is "added" by introducing biota, and the coordination of animals and microorganisms is used to accelerate the decomposition and transformation of pollutants.
4)利用微生物与特训动物种群共同作用,实现污泥污染物快速减量、同时疏松土质、改善供氧状况,恢复河湖等水体底泥的生态系统,提高底泥利用价值。4) Use the joint action of microorganisms and specially trained animal populations to achieve rapid reduction of sludge pollutants, loosen soil quality, improve oxygen supply conditions, restore the ecosystem of sediments in rivers and lakes and other water bodies, and increase the utilization value of sediments.
5)提高微生物和蚯蚓对河道等水体底泥的适应性和存活率。5) Improve the adaptability and survival rate of microorganisms and earthworms to the sediment of water bodies such as river courses.
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CN109867364A (en) * | 2019-03-08 | 2019-06-11 | 上海海洋大学 | Combined in-situ control system and its method for the release of aquaculture system internal contamination |
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CN112840940A (en) * | 2021-02-03 | 2021-05-28 | 黄明甲 | Ecological restoration method for tailing pond |
CN113740511A (en) * | 2021-09-06 | 2021-12-03 | 宁波大学 | Method for obtaining soil animal activity biosensor for farmland soil health diagnosis |
CN113740511B (en) * | 2021-09-06 | 2023-09-08 | 宁波大学 | Method for obtaining soil animal active biosensor for farmland soil health diagnosis |
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